CN110395068B - Thermal transfer printing method for building wall surface - Google Patents
Thermal transfer printing method for building wall surface Download PDFInfo
- Publication number
- CN110395068B CN110395068B CN201910640234.5A CN201910640234A CN110395068B CN 110395068 B CN110395068 B CN 110395068B CN 201910640234 A CN201910640234 A CN 201910640234A CN 110395068 B CN110395068 B CN 110395068B
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- transfer printing
- thermal transfer
- wall surface
- building wall
- adhesive
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
- B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
- B44C1/17—Dry transfer
- B44C1/1712—Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive
- B44C1/172—Decalcomanias provided with a layer being specially adapted to facilitate their release from a temporary carrier
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
- B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
- B44C1/17—Dry transfer
- B44C1/1712—Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive
- B44C1/1729—Hot stamping techniques
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
- C09J163/10—Epoxy resins modified by unsaturated compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
- Finishing Walls (AREA)
- Decoration By Transfer Pictures (AREA)
Abstract
The invention discloses a heat transfer printing method for a building wall surface, which comprises the following steps: curing an adhesive containing polyvinylpyrrolidone until the curing rate is 40%, and preparing a thermal transfer printing flower film as an adhesive layer; coating raw paint on the building wall surface to be transfer-printed until the surface of the building wall surface to be transfer-printed is flat; the thermal transfer printing decorative film is attached to the building wall surface to be subjected to transfer printing within 1-5 minutes, ultraviolet irradiation treatment is carried out, the thermal transfer printing decorative film is cured, the adhesive force of the thermal transfer printing decorative surface and the wall surface is improved aiming at the building wall surface, the decorative surface after thermal transfer printing is kept consistent, the anti-sticking phenomenon is prevented, and UV curing can be realized without a photoinitiator.
Description
Technical Field
The invention relates to the field of wall surface processing in the field of buildings, in particular to a heat transfer printing method for a building wall surface.
Background
Building wall is owing to need print relevant image, can utilize the heat-transfer seal technique, and the heat-transfer seal technique means that the bonding layer melting on the flower membrane is the viscoelastic attitude under the effect of high temperature hot-rolling, and the pressure of hot-rolling is again with the bonding layer quick adhesion to treat the rendition material surface, and the rolling of flower membrane of cooling down rapidly thereafter, its separation layer department is torn, and the PET film is cleared up useless, and protection on the final flower membrane, layer, printing ink layer, adhesive linkage are attached to on treating the rendition material.
The hot melt adhesive is a plastic adhesive, is usually used as a thermal transfer adhesive material, is in a solid state at normal temperature, and can be quickly bonded after being heated and melted, but the bonding layer only using the hot melt adhesive usually needs to be pressed and bonded because the melt viscosity of the hot melt adhesive is generally higher and the wettability to a bonded material is poorer, so that the bonding strength is improved; in addition, the hot melt adhesive is easy to generate the phenomenon of ' anti-sticking ' in the curing process, namely, the adhesive layer is easy to stick to PET (back sticking ') after being hot-melted when the ambient temperature is higher, thereby limiting the application range of the hot melt adhesive to a certain extent.
For building wall surfaces, outer walls are often uneven, in the prior art, in order to improve the adhesive force of an adhesive layer and keep the consistency of a decoration surface after transfer printing, when other materials such as an aluminum plate, glass and the like are used as a heat transfer printing carrier, heat transfer printing glue is adopted to closely adhere heat transfer printing paper and the aluminum plate decoration surface, and the phenomenon of 'anti-adhesion' can occur; the other method is to use a tubular heat-resistant plastic expansion bag to be sleeved outside an aluminum plate on which the thermal transfer paper is laid in a dry mode, and then the thermal transfer paper is fully and effectively attached to the aluminum plate in a vacuumizing mode, but the area of the wall surface is too large, the movement is inconvenient, and the vacuumizing is used in the curing process.
In the prior art, a method of replacing thermal curing with adhesive layer UV curing is adopted, and the effect is poor because the adhesive layer UV cured does not generate an anti-sticking phenomenon due to the rise of the ambient temperature, but ultraviolet rays radiate the adhesive layer less ultraviolet rays after passing through an ink layer, so that the curing time is long, the curing is incomplete, the adhesive force is reduced, and the polymerization and curing of the adhesive can be caused only by adding a photoinitiator in the adhesive layer.
Disclosure of Invention
In order to solve the problems, the invention provides a thermal transfer printing method for a building wall surface, which aims at improving the adhesive force of a thermal transfer printing decorative surface and the wall surface of the building wall surface, keeping the consistency of the decorative surface after thermal transfer printing, preventing the phenomenon of reverse adhesion and realizing UV curing without a photoinitiator.
The technical scheme for solving the problem is to provide a heat transfer printing method for a building wall surface, which comprises the following steps:
(1) curing an adhesive containing polyvinylpyrrolidone until the curing rate is 40%, and preparing a thermal transfer printing flower film as an adhesive layer;
(2) coating raw paint on the building wall surface to be transfer-printed until the surface of the building wall surface to be transfer-printed is flat;
(3) and (3) adhering the thermal transfer printing decorative film to the wall surface of the building to be subjected to transfer printing within 1-5 minutes, carrying out ultraviolet irradiation treatment, and curing the thermal transfer printing decorative film.
Preferably, the adhesive comprises the following components in percentage by mass: 20-40 parts of polyvinyl pyrrolidone, 40-50 parts of photosensitive prepolymer and 5-10 parts of photoinitiator.
Preferably, the thermal transfer printing flower film comprises a PET film, a separation layer, a protective layer, an ink layer, a urushiol layer and an adhesive layer which are sequentially overlapped.
Preferably, the intensity of the ultraviolet radiation is 10-50mJ/cm 2. S.
Preferably, the photosensitive prepolymer comprises one or more of an acrylated epoxy resin, an unsaturated polyester, a polyurethane, a polythiol photocurable resin and a polyene photocurable resin.
Preferably, the photoinitiator is characterized by comprising one or more of benzoin and derivatives thereof, acetophenone derivatives and triarylsulfonium salts.
Preferably, the ink of the ink layer comprises pigment and initiator with different ultraviolet absorption wavelength from the pigment.
Preferably, the urushiol layer includes a photocurable resin component that is miscible with 30% urushiol.
Preferably, the pigment comprises one or more of phthalocyanine blue, lithol scarlet, benzidine yellow and carbon black.
In the scheme, raw lacquer is adopted to pretreat the building wall surface, the unevenness of the building wall surface is filled up by utilizing the fluid fluidity of the raw lacquer, meanwhile, the raw lacquer has the name of 'king of coating', as for an outer wall, the raw lacquer needs to be coated with outer wall paint to protect a building, urushiol in the raw lacquer is a main component, the urushiol is a mixture of long-side-chain catechol with different saturation degrees and 15-17 carbon atoms, and has active phenolic hydroxyl and unsaturated bonds on side chains; in the preparation of the transfer printing pattern film, a PET film, a separation layer, a protective layer, an ink layer, a urushiol layer and an adhesive layer which are sequentially overlapped are selected, wherein the adhesive layer comprises polyvinylpyrrolidone which is a non-ionic high molecular compound and has the general properties of a water-soluble high molecular compound, colloid protection, film forming property, cohesiveness, hygroscopicity, solubilization or condensation effect, in the scheme, a photosensitive prepolymer is used as a carrier of the polyvinylpyrrolidone, photocuring resin is used as a carrier of the urushiol, so that the physical form characteristics of the urushiol and the polyvinylpyrrolidone are more consistent with the practical operation, the urushiol and the polyvinylpyrrolidone have stronger hydrogen bonds, the urushiol and the polyvinylpyrrolidone form a precursor film, in addition, unsaturated bonds on a urushiol side chain can generate free radical polymerization under the irradiation of ultraviolet light, and at first, the hydroxyl of the urushiol is split into a urushiol semi-quinone free radical, initiating the growth of carbon-carbon double bonds on a side chain, forming a polymer with a two-dimensional structure by chain growth, simultaneously, further polymerizing unsaturated bonds on the side chain under the initiation of free radicals, passing through an adhesive layer containing polyvinylpyrrolidone, performing photopolymerization without a photoinitiator, forming a polymer with a semi-interpenetrating network structure, obtaining a structurally stable multi-layer ultrathin film with the semi-interpenetrating network structure, enabling the wall surface and the adhesive layer to be more firmly cured, and replacing thermosetting with UV curing, so that the phenomenon of 'anti-sticking' can not occur, in the prior art, a photoinitiator must be added into the adhesive layer to enable the adhesive layer polymer to be cross-linked and cured, in the scheme, due to the characteristic of urushiol, the photoinitiator is not needed, so that the polymerization between urushiol layers and the adhesive layer can be caused, and for a decorative surface with a thicker ink layer, the curing time is shortened and is more thorough, the adhesive force is improved.
In the prior art, because the adhesive is polymerized during curing, the plane defects are often caused by local stress and shrinkage generated in the polymerization process, in the scheme, the polymerized urushiol between adjacent layers is connected to form a semi-interpenetrating network structure, the space of a multilayer film is compressed under the combined action of two factors, the film thickness is reduced, the hardness of the film is improved due to structural change, and meanwhile, due to the skeleton supporting effect of PVPON macromolecules, the cured adhesive layer still has a flat surface, and the orderliness of the film is maintained.
The optimal conditions in the scheme can be selected, the pigment in the ink is in the range of an ultraviolet absorption wavelength region, so that one or more of phthalocyanine blue, lithol scarlet, benzidine yellow and carbon black are selected, ultraviolet light is not shielded, the absorption wavelength region of a free radical initiator in the ink is superposed with the maximum transmission wavelength region of the pigment, the UV can penetrate through the ink layer to cure the bonding layer, and the photoinitiator is added into the bonding agent, so that the reaction between the original active urushiol is easier to perform, and the influence of the ink layer on the ultraviolet penetration force is reduced.
The invention has the beneficial effects that: (1) the wall surface is pretreated by coating the raw paint, so that on one hand, the surface flatness of the wall surface is improved, the consistency of the transferred decorative surface is kept, on the other hand, the raw paint is in hydrogen bond connection with the adhesive layer, and the adhesion is high after curing; (2) a urushiol layer is usually added, a photoinitiator is not needed, a urushiol side chain penetrates through an adhesive layer containing polyvinylpyrrolidone, a stable-structure multilayer ultrathin film with a semi-interpenetrating network structure is obtained, the thickness is reduced, the hardness is increased, and the adhesion of a transfer printing flower film is firmer; (3) the ultraviolet curing is used for replacing the thermal curing, so that the anti-sticking is avoided, the polymerizable characteristic of urushiol without a photoinitiator is utilized, the curing condition is reduced, and the influence of the ink layer on the penetration rate during the ultraviolet curing is reduced; (4) the adhesive layer is cured in advance to achieve a certain curing degree, so that anti-sticking is effectively avoided, and the cured adhesive layer has higher stability; (5) due to the skeleton supporting effect of PVPON macromolecules, the cured bonding layer still has a flat surface, the orderliness of the film is kept, and plane defects caused by local stress and shrinkage generated in the polymerization process are avoided.
Detailed Description
In order to make the present invention more comprehensible, the technical solutions of the present invention are further described below with reference to specific embodiments, but the present invention is not limited thereto.
The raw materials used in the invention are all common commercial products and AR pure unless specified otherwise.
Example 1
Preparing a transfer printing film: coating materials of each layer at a coating speed of 5m/min, coating an acrylic resin two-in-one as a separation layer and a protective layer on a PET (polyethylene terephthalate) film serving as a substrate film, printing pre-related decorative pictures and texts on the acrylic resin by adopting ink containing 20% of phthalocyanine blue and 5% of I-10 initiator, coating bisphenol A type epoxy acrylate containing 30% of urushiol on the ink layer, directly coating a cured adhesive by using a coating machine, rolling, slitting and packaging a finished product, wherein the adhesive is prepared by uniformly stirring 20g of polyvinyl pyrrolidone and 40g of acrylated epoxy resin, and the curing process is to heat the prepared adhesive at 50 ℃ for 15min to obtain the adhesive with the curing rate of 40%;
wall surface pretreatment: coating raw paint on the wall surface to be transferred by roller, filling the hollow area and keeping the wall surface smooth;
thermal transfer printing: by utilizing the thermal transfer printing machine disclosed in CN202669152U, the transfer printing flower film is transferred to the building wall surface by the temperature and pressure provided by the thermal transfer printing machine, and the transfer printing temperature is 80 ℃.
And (3) curing: curing the transferred wall surface by ultraviolet irradiation with ultraviolet intensity of 10mJ/cm2S, irradiation time 5 min.
Example 2
Preparing a transfer printing film: coating materials of each layer at a coating speed of 5m/min, coating an acrylic resin two-in-one as a separation layer and a protective layer on a PET (polyethylene terephthalate) film serving as a substrate film, printing pre-related decorative pictures and texts on the acrylic resin by adopting ink containing 20% of lithol scarlet and 5% of I-39 initiator, coating bisphenol A type epoxy acrylate containing 30% of urushiol on the ink layer, directly coating a cured adhesive by using a coating machine, rolling, cutting and packaging a finished product, wherein the adhesive is prepared by uniformly stirring 20 parts of polyvinyl pyrrolidone, 40 parts of unsaturated polyester and 5 parts of benzoin, and the curing process is that the prepared adhesive is heated at 50 ℃ for 15min to obtain the adhesive with the curing rate of 40%;
wall surface pretreatment: coating raw paint on the wall surface to be transferred by roller, filling the hollow area and keeping the wall surface smooth;
thermal transfer printing: by utilizing the thermal transfer printing machine disclosed in CN202669152U, the transfer printing flower film is transferred onto the building wall surface by the temperature and pressure provided by the thermal transfer printing machine, and the transfer printing temperature is 100 ℃.
And (3) curing: curing the transferred wall surface by ultraviolet irradiation with ultraviolet intensity of 10mJ/cm2S, irradiation time 3 min.
Example 3
Preparing a transfer printing film: coating materials of each layer at a coating speed of 5m/min, coating an acrylic resin two-in-one as a separation layer and a protective layer on a PET (polyethylene terephthalate) film serving as a substrate film, printing pre-related decorative pictures and texts on the acrylic resin by adopting ink containing 20% of benzidine yellow and 5% of I-89 initiator, coating bisphenol A type epoxy acrylate containing 30% of urushiol on the ink layer, directly coating a cured adhesive by using a coating machine, rolling, slitting and packaging a finished product, wherein the adhesive is prepared by uniformly stirring 20 parts of polyvinyl pyrrolidone and 40 parts of unsaturated polyester, and the curing process is that the prepared adhesive is heated for 15min at 50 ℃ to obtain the adhesive with the curing rate of 40%;
wall surface pretreatment: coating raw paint on the wall surface to be transferred by roller, filling the hollow area and keeping the wall surface smooth;
thermal transfer printing: by utilizing the thermal transfer printing machine disclosed in CN202669152U, the transfer printing flower film is transferred onto the building wall surface by the temperature and pressure provided by the thermal transfer printing machine, and the transfer printing temperature is 120 ℃.
And (3) curing: curing the transferred wall surface by ultraviolet irradiation with intensity of 50mJ/cm2S, irradiation time 3 min.
Example 4
Preparing a transfer printing film: coating materials of each layer at a coating speed of 5m/min, coating an acrylic resin two-in-one as a separation layer and a protective layer on a PET film as a substrate film, printing pre-related decorative pictures and texts on the acrylic resin by adopting ink containing 20% of carbon black and 5% of I-39 initiator, coating bisphenol A type epoxy acrylate containing 30% of urushiol on the ink layer, directly coating a cured adhesive by using a coating machine, rolling, slitting and packaging to obtain a finished product, wherein the adhesive is prepared by uniformly mixing 30 parts of polyvinyl pyrrolidone, 45 parts of polythiol photocuring resin and 10g of triarylsulfur bell salt, and the curing process is that the prepared adhesive is heated at 50 ℃ for 15min to obtain the adhesive with the curing rate of 40%;
wall surface pretreatment: coating raw paint on the wall surface to be transferred by roller, filling the hollow area and keeping the wall surface smooth;
thermal transfer printing: by utilizing the thermal transfer printing machine disclosed in CN202669152U, the transfer printing flower film is transferred onto the building wall surface by the temperature and pressure provided by the thermal transfer printing machine, and the transfer printing temperature is 120 ℃.
And (3) curing: curing the transferred wall surface by ultraviolet irradiation with ultraviolet intensity of 30mJ/cm2S, irradiation time 3 min.
Example 4
Preparing a transfer printing film: coating materials of each layer at a coating speed of 5m/min, coating an acrylic resin two-in-one as a separation layer and a protective layer on a PET (polyethylene terephthalate) film serving as a substrate film, printing pre-related decorative pictures and texts on the acrylic resin by adopting ink containing 20% of carbon black and 5% of I-39 initiator, coating bisphenol A type epoxy acrylate containing 30% of urushiol on the ink layer, directly coating a cured adhesive by using a coating machine, rolling, slitting and packaging a finished product, wherein the adhesive is prepared by uniformly mixing 40 parts of polyvinyl pyrrolidone, 50 parts of polyene light-cured resin and 8g of acetophenone, and the curing process is that the prepared adhesive is heated at 50 ℃ for 15min to obtain the adhesive with the curing rate of 40%;
wall surface pretreatment: coating raw paint on the wall surface to be transferred by roller, filling the hollow area and keeping the wall surface smooth;
thermal transfer printing: by utilizing the thermal transfer printing machine disclosed in CN202669152U, the transfer printing flower film is transferred onto the building wall surface by the temperature and pressure provided by the thermal transfer printing machine, and the transfer printing temperature is 120 ℃.
And (3) curing: curing the transferred wall surface by ultraviolet irradiation with intensity of 20mJ/cm2S, irradiation time 5 min.
The above description is only a preferred embodiment of the present invention, and all equivalent changes and modifications made in accordance with the claims of the present invention should be covered by the present invention.
Claims (7)
1. A heat transfer printing method for a building wall surface is characterized by comprising the following steps:
(1) curing an adhesive containing polyvinylpyrrolidone until the curing rate is 40%, and preparing a thermal transfer printing film as an adhesive layer, wherein the adhesive comprises the following components in percentage by mass: 20-40 parts of polyvinylpyrrolidone and 40-50 parts of photosensitive prepolymer, wherein the heat transfer printing flower film comprises a PET film, a separation layer, a protective layer, an ink layer, a urushiol layer and an adhesive layer which are sequentially overlapped;
(2) coating raw paint on the building wall surface to be transfer-printed until the surface of the building wall surface to be transfer-printed is flat;
(3) and (3) adhering the thermal transfer printing decorative film to the wall surface of the building to be subjected to transfer printing within 1-5 minutes, carrying out ultraviolet irradiation treatment, and curing the thermal transfer printing decorative film.
2. The thermal transfer printing method for building wall surfaces as claimed in claim 1, wherein the intensity of the ultraviolet irradiation is 10-50mJ/cm2·S。
3. The method of claim 1, wherein the photosensitive prepolymer comprises one or more of an acrylated epoxy resin, an unsaturated polyester, a polyurethane, a polythiol photocurable resin, and a polyene photocurable resin.
4. The thermal transfer printing method for building wall surfaces as claimed in claim 1, wherein the adhesive further comprises 5-10 parts of a photoinitiator, and the photoinitiator comprises one or more of benzoin and derivatives thereof, acetophenone derivatives, and triarylsulfonium salts.
5. The thermal transfer printing method for building walls according to claim 1, wherein the ink layer comprises a pigment and an initiator with a different ultraviolet absorption wavelength from the pigment.
6. The thermal transfer printing method for building walls according to claim 1, wherein the urushiol layer includes a photo-curable resin component in which 30% urushiol is miscible.
7. The thermal transfer printing method for building wall surfaces as claimed in claim 5, wherein the pigment comprises one or more of phthalocyanine blue, lithol scarlet, benzidine yellow and carbon black.
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| US6284258B1 (en) * | 1997-12-08 | 2001-09-04 | Arizona Board Of Regents | Long-acting, chemical-resistant skin emollients, moisturizers, and strengtheners |
| JP4602519B2 (en) * | 2000-06-15 | 2010-12-22 | 共同印刷株式会社 | Crimp sheet |
| KR20040078106A (en) * | 2001-11-28 | 2004-09-08 | 제임스 하디 리서치 피티와이 리미티드 | Adhesive-edge building panel and method of manufacture |
| JP4302423B2 (en) * | 2003-04-18 | 2009-07-29 | 東京応化工業株式会社 | Resin for base material, base material, and multilayer resist pattern forming method |
| US20090163615A1 (en) * | 2005-08-31 | 2009-06-25 | Izhar Halahmi | Uv curable hybridcuring ink jet ink composition and solder mask using the same |
| US7361437B2 (en) * | 2006-09-01 | 2008-04-22 | E.I. Du Pont De Nemours And Company | Thermal transfer donor element with a carboxylated binder and a hydroxylated organic compound |
| EP2173327A2 (en) * | 2007-07-24 | 2010-04-14 | Nexbio, Inc. | Technology for the preparation of microparticles |
| CN103132671B (en) * | 2013-03-12 | 2015-06-24 | 河南卓亚新型材料科技有限公司 | Novel transfer printing ceramic tile and preparation method thereof |
| CN104057733B (en) * | 2014-06-28 | 2016-01-20 | 汕头市炽盛新材料有限公司 | Be applicable to the hot transfer printing printing carbon ribbon of full resin of multiple stock |
| US10286708B2 (en) * | 2015-05-19 | 2019-05-14 | Agfa-Gevaert | Laser markable compositions, articles and documents |
| CN106313923A (en) * | 2015-07-03 | 2017-01-11 | 禹辉（上海）转印材料股份有限公司 | Method for producing high abrasion-resistant solvent-resistant heat transfer film |
| CN106366921A (en) * | 2016-08-26 | 2017-02-01 | 太仓市美航涂料有限公司 | High-performance ultraviolet curing coating and coating curing process thereof |
| CN107779095B (en) * | 2016-08-30 | 2020-04-21 | 南京中森生物科技有限公司 | Preparation method of urushiol acrylate photocuring film |
| CN107083118B (en) * | 2017-04-19 | 2019-03-15 | 福建比美特环保集团有限公司 | A kind of special-purpose aqueous fiber coating of thermal transfer and preparation method thereof |
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