CN110359168A - A kind of scribbled and fabric of flame-retardant viscose fiber and acrylic fibers fire resistance fibre - Google Patents

A kind of scribbled and fabric of flame-retardant viscose fiber and acrylic fibers fire resistance fibre Download PDF

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Publication number
CN110359168A
CN110359168A CN201910750994.1A CN201910750994A CN110359168A CN 110359168 A CN110359168 A CN 110359168A CN 201910750994 A CN201910750994 A CN 201910750994A CN 110359168 A CN110359168 A CN 110359168A
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CN
China
Prior art keywords
parts
retardant
flame
acrylic fibers
fabric
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Pending
Application number
CN201910750994.1A
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Chinese (zh)
Inventor
李定玉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Baijin Textile Co Ltd
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Suzhou Baijin Textile Co Ltd
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Publication date
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Priority to CN201910750994.1A priority Critical patent/CN110359168A/en
Publication of CN110359168A publication Critical patent/CN110359168A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04Blended or other yarns or threads containing components made from different materials
    • D02G3/045Blended or other yarns or threads containing components made from different materials all components being made from artificial or synthetic material
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44Yarns or threads characterised by the purpose for which they are designed
    • D02G3/443Heat-resistant, fireproof or flame-retardant yarns or threads
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/513Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads heat-resistant or fireproof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/128Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with silicon polymers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/06Properties of the materials having thermal properties
    • D06N2209/067Flame resistant, fire resistant
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20Cellulose-derived artificial fibres
    • D10B2201/22Cellulose-derived artificial fibres made from cellulose solutions
    • D10B2201/24Viscose
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/10Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Woven Fabrics (AREA)

Abstract

The invention discloses the scribbleds and fabric of a kind of flame-retardant viscose fiber and acrylic fibers fire resistance fibre, by flame-retardant viscose fiber and acrylic fibers fire resistance fibre is blended forms, the flame-retardant viscose fiber includes following components by weight: 10-20 parts of cellulose, 5-8 parts of sial mixed gel solution, 0.5-1.2 parts of viscose glue auxiliary agent, 6~8 parts of fire retardant, 0.2-0.8 parts of thickener, 0.5-1.5 parts of sodium lignin sulfonate, surplus is water, the acrylic fibers fire resistance fibre includes 5-10 parts of polyacrylonitrile by weight, 3, 4- dimethoxy-4 ' ' 2-5 parts of-methoxyl biphenyl, 1.5-3.5 parts of lauryl amine polyoxyethylene ether, 8-12 parts of silica nitrogen heterocyclic compounds fire retardant, 0.8-1.5 parts of metallic compound, 1.2-1.6 parts of bleeding agent, surplus is water.A kind of fabric, the fabric are formed by weaving by warp thread and weft yarn, and the warp thread and weft yarn are formed by weaving by above-mentioned scribbled.The cost of material of the scribbled and fabric of the flame-retardant viscose fiber and acrylic fibers fire resistance fibre is lower, and manufacturing process is simple, and cost of manufacture is cheap, and anti-flammability is high.

Description

A kind of scribbled and fabric of flame-retardant viscose fiber and acrylic fibers fire resistance fibre
Technical field
The present invention relates to the scribbleds and fabric of a kind of flame-retardant viscose fiber and acrylic fibers fire resistance fibre, are related to inflaming retarding fabric Technical field.
Background technique
Current main inflaming retarding fabric has: after-finishing flame resistant fabric, such as pure cotton, polyester-cotton blend;Inherent flame retardant fabric, such as virtue Synthetic fibre, nitrile cotton, Du Pont's Kevlar, Nomex (Nomex nylon), Australia PR97 etc..Though inflaming retarding fabric production development prospect is good, right cost With being still principal concern, especially cost of material is being gradually risen, thus causes production cost higher, and many at present The flame retardant effect of inflaming retarding fabric is not satisfactory, thus reduces using experience degree.
Summary of the invention
The technical problems to be solved by the present invention are: providing a kind of effectively save production cost and the high viscose glue resistance of anti-flammability Fire the scribbled and fabric of fiber and acrylic fibers fire resistance fibre.
In order to solve the above-mentioned technical problem, the present invention is achieved by the following technical solutions:
A kind of scribbled of flame-retardant viscose fiber and acrylic fibers fire resistance fibre, by flame-retardant viscose fiber and the fire-retardant fibre of acrylic fibers Tie up it is blended form, the flame-retardant viscose fiber includes following components by weight: 10-20 parts of cellulose, sial mixed gel is molten 5-8 parts of liquid, 0.5-1.2 parts of viscose glue auxiliary agent, 6~8 parts of fire retardant, 0.2-0.8 parts of thickener, 0.5-1.5 parts of sodium lignin sulfonate, Surplus is water, and the acrylic fibers fire resistance fibre includes 5-10 parts of polyacrylonitrile by weight, 3,4- dimethoxy-4 's '-methoxyl group connection 2-5 parts of benzene, 1.5-3.5 parts of lauryl amine polyoxyethylene ether, 8-12 parts of silica nitrogen heterocyclic compounds fire retardant, metallic compound 0.8-1.5 parts, 1.2-1.6 parts of bleeding agent, surplus be water.
Preferably, the fire retardant is set as pyrophosphate based flame retardant.
Preferably, the thickener is set as cellulose thickener.
Preferably, the metallic compound is one of copper sulphate, borax, aluminum oxide or a variety of.
Preferably, the bleeding agent is alkyl phenol polyoxyethylene ether.
A kind of fabric, the fabric are formed by weaving by warp thread and weft yarn, and the warp thread and weft yarn are by aforesaid right It is required that the scribbled of a kind of described in any item flame-retardant viscose fibers of 1-5 and acrylic fibers fire resistance fibre is formed by weaving.
Preferably, the upper layer of the fabric and lower layer are coated with flame retardant coating.
Preferably, the flame retardant coating includes following components by weight, and 1-3 parts of film forming agent, silane coupling agent 2-5 Part, 1.5-3.5 parts of ammonium polyphosphate, 40-80 parts of ethyl alcohol, 3-6 parts of dimethyl silicone polymer, 2.5-4 parts of modified polyorganosiloxane are fire-retardant 5-8 parts of agent, 3-6 parts of oxidant, 1-3 parts of age resister.
Compared with prior art, usefulness of the present invention is: the flame-retardant viscose fiber and acrylic fibers fire resistance fibre it is mixed The cost of material of yarn and fabric is lower, and manufacturing process is simple, and cost of manufacture is cheap, and can effectively improve and prepare Fabric anti-flammability, thus effectively promoted fabric quality.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiments of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common Technical staff's all other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses:
Embodiment 1
A kind of scribbled of flame-retardant viscose fiber and acrylic fibers fire resistance fibre, by flame-retardant viscose fiber and the fire-retardant fibre of acrylic fibers Tie up it is blended form, the flame-retardant viscose fiber includes following components by weight: 10 parts of cellulose, sial mixed gel solution 5 Part, it is 0.5 part of viscose glue auxiliary agent, 6 parts of pyrophosphate based flame retardant, 0.2 part of cellulose thickener, 0.5 part of sodium lignin sulfonate, remaining Amount is water, and the acrylic fibers fire resistance fibre includes 5 parts of polyacrylonitrile by weight, 2 parts of 3,4- dimethoxy-4 's '-methoxyl biphenyl, 1.5 parts of lauryl amine polyoxyethylene ether, 8 parts of silica nitrogen heterocyclic compounds fire retardant, 0.8 part of sulfuric acid copper compound, alkyl phenol are poly- 1.2 parts of ethylene oxide ether bleeding agent, surplus are water.
A kind of fabric, the fabric are formed by weaving by warp thread and weft yarn, and the warp thread and weft yarn have above-mentioned viscose glue The scribbled of fire resistance fibre and acrylic fibers fire resistance fibre is formed by weaving, and the upper layer of the fabric and lower layer are coated with fire-retardant painting Layer, the flame retardant coating include following components by weight, and 1 part of film forming agent, 2 parts of silane coupling agent, 1.5 parts of ammonium polyphosphate, second 40 parts of alcohol, 3 parts of dimethyl silicone polymer, 2.5 parts of modified polyorganosiloxane, 5 parts of fire retardant, 3 parts of oxidant, 1 part of age resister.
The fabric experiment proves that, color fastness reaches 4 grades, fire-retardant to reach EN571 standard, and has preferable hand Feel comfort level.
Embodiment 2
A kind of scribbled of flame-retardant viscose fiber and acrylic fibers fire resistance fibre, by flame-retardant viscose fiber and the fire-retardant fibre of acrylic fibers Tie up it is blended form, the flame-retardant viscose fiber includes following components by weight: 20 parts of cellulose, sial mixed gel solution 8 Part, it is 1.2 parts of viscose glue auxiliary agent, 8 parts of pyrophosphate based flame retardant, 0.8 part of cellulose thickener, 1.5 parts of sodium lignin sulfonate, remaining Amount is water, and the acrylic fibers fire resistance fibre includes 10 parts of polyacrylonitrile by weight, 3,4- dimethoxy-4 's '-methoxyl biphenyl 5 Part, 3.5 parts of lauryl amine polyoxyethylene ether, 12 parts of silica nitrogen heterocyclic compounds fire retardant, 1.5 parts of sulfuric acid copper compound, alkyl 1.6 parts of phenol polyethenoxy ether bleeding agent, surplus are water.
A kind of fabric, the fabric are formed by weaving by warp thread and weft yarn, and the warp thread and weft yarn have above-mentioned viscose glue The scribbled of fire resistance fibre and acrylic fibers fire resistance fibre is formed by weaving, and the upper layer of the fabric and lower layer are coated with fire-retardant painting Layer, the flame retardant coating include following components by weight, and 3 parts of film forming agent, 5 parts of silane coupling agent, 3.5 parts of ammonium polyphosphate, second 80 parts of alcohol, 6 parts of dimethyl silicone polymer, 4 parts of modified polyorganosiloxane, 8 parts of fire retardant, 6 parts of oxidant, 3 parts of age resister.
The fabric experiment proves that, color fastness reaches 4 grades, fire-retardant to reach EN571 standard, and has preferable hand Feel comfort level.
Embodiment 3
A kind of scribbled of flame-retardant viscose fiber and acrylic fibers fire resistance fibre, by flame-retardant viscose fiber and the fire-retardant fibre of acrylic fibers Tie up it is blended form, the flame-retardant viscose fiber includes following components by weight: 15 parts of cellulose, sial mixed gel solution 7 Part, it is 0.8 part of viscose glue auxiliary agent, 7 parts of pyrophosphate based flame retardant, 0.6 part of cellulose thickener, 1.2 parts of sodium lignin sulfonate, remaining Amount is water, and the acrylic fibers fire resistance fibre includes 7 parts of polyacrylonitrile by weight, 4 parts of 3,4- dimethoxy-4 's '-methoxyl biphenyl, 2.5 parts of lauryl amine polyoxyethylene ether, 9 parts of silica nitrogen heterocyclic compounds fire retardant, 1.2 parts of sulfuric acid copper compound, alkyl phenol are poly- 1.4 parts of ethylene oxide ether bleeding agent, surplus are water.
A kind of fabric, the fabric are formed by weaving by warp thread and weft yarn, and the warp thread and weft yarn have above-mentioned viscose glue The scribbled of fire resistance fibre and acrylic fibers fire resistance fibre is formed by weaving, and the upper layer of the fabric and lower layer are coated with fire-retardant painting Layer, the flame retardant coating include following components by weight, and 2 parts of film forming agent, 3 parts of silane coupling agent, 2.5 parts of ammonium polyphosphate, second 60 parts of alcohol, 5 parts of dimethyl silicone polymer, 3.5 parts of modified polyorganosiloxane, 7 parts of fire retardant, 4.5 parts of oxidant, age resister 2.5 Part.
The fabric experiment proves that, color fastness reaches 4 grades, fire-retardant to reach EN571 standard, and has preferable hand Feel comfort level.
It is emphasized that: the above is only presently preferred embodiments of the present invention, not make in any form to the present invention Limitation, any simple modification, equivalent change and modification to the above embodiments according to the technical essence of the invention, All of which are still within the scope of the technical scheme of the invention.

Claims (8)

1. the scribbled of a kind of flame-retardant viscose fiber and acrylic fibers fire resistance fibre, it is characterised in that: by flame-retardant viscose fiber and Acrylic fibers fire resistance fibre is blended to be formed, and the flame-retardant viscose fiber includes following components by weight: 10-20 parts of cellulose, sial 5-8 parts of mixed gel solution, 0.5-1.2 parts of viscose glue auxiliary agent, 6~8 parts of fire retardant, 0.2-0.8 parts of thickener, sodium lignin sulfonate 0.5-1.5 parts, surplus is water, and the acrylic fibers fire resistance fibre includes 5-10 parts of polyacrylonitrile by weight, 3,4- dimethoxys- 4 ' -2-5 parts of methoxyl biphenyls, 1.5-3.5 parts of lauryl amine polyoxyethylene ether, 8-12 parts of silica nitrogen heterocyclic compounds fire retardant, 0.8-1.5 parts of metallic compound, 1.2-1.6 parts of bleeding agent, surplus are water.
2. the scribbled of a kind of flame-retardant viscose fiber and acrylic fibers fire resistance fibre according to claim 1, it is characterised in that: The fire retardant is set as pyrophosphate based flame retardant.
3. the scribbled of a kind of flame-retardant viscose fiber and acrylic fibers fire resistance fibre according to claim 1, it is characterised in that: The thickener is set as cellulose thickener.
4. the scribbled of a kind of flame-retardant viscose fiber and acrylic fibers fire resistance fibre according to claim 1, it is characterised in that: The metallic compound is one of copper sulphate, borax, aluminum oxide or a variety of.
5. the scribbled of a kind of flame-retardant viscose fiber and acrylic fibers fire resistance fibre according to claim 1, it is characterised in that: The bleeding agent is alkyl phenol polyoxyethylene ether.
6. a kind of fabric, it is characterised in that: the fabric is formed by weaving by warp thread and weft yarn, the warp thread and weft yarn by The scribbled of a kind of described in any item flame-retardant viscose fibers of the claims 1-5 and acrylic fibers fire resistance fibre is formed by weaving.
7. a kind of fabric according to claim 6, it is characterised in that: the upper layer of the fabric and lower layer are coated with resistance Fire coating.
8. a kind of fabric according to claim 7, it is characterised in that: the flame retardant coating includes with the following group by weight Point, 1-3 parts of film forming agent, 2-5 parts of silane coupling agent, 1.5-3.5 parts of ammonium polyphosphate, 40-80 parts of ethyl alcohol, dimethyl silicone polymer 3- 6 parts, 2.5-4 parts of modified polyorganosiloxane, 5-8 parts of fire retardant, 3-6 parts of oxidant, 1-3 parts of age resister.
CN201910750994.1A 2019-08-14 2019-08-14 A kind of scribbled and fabric of flame-retardant viscose fiber and acrylic fibers fire resistance fibre Pending CN110359168A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114908459A (en) * 2022-06-13 2022-08-16 赵国江 Antibacterial flame-retardant garment fabric and processing method thereof

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114908459A (en) * 2022-06-13 2022-08-16 赵国江 Antibacterial flame-retardant garment fabric and processing method thereof
CN114908459B (en) * 2022-06-13 2024-04-16 苏州西铁牛电子商务有限公司 Antibacterial flame-retardant garment fabric and processing method thereof

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Application publication date: 20191022