CN110356071A - A kind of camouflage composite material moulding process and application - Google Patents
A kind of camouflage composite material moulding process and application Download PDFInfo
- Publication number
- CN110356071A CN110356071A CN201810318322.9A CN201810318322A CN110356071A CN 110356071 A CN110356071 A CN 110356071A CN 201810318322 A CN201810318322 A CN 201810318322A CN 110356071 A CN110356071 A CN 110356071A
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- Prior art keywords
- glass fibre
- alkali
- layers
- free glass
- prepreg cloth
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- 239000002131 composite material Substances 0.000 title claims abstract description 16
- 238000000034 method Methods 0.000 title claims description 13
- 238000000465 moulding Methods 0.000 title claims description 12
- 230000008569 process Effects 0.000 title claims description 11
- 239000003365 glass fiber Substances 0.000 claims abstract description 39
- 239000004593 Epoxy Substances 0.000 claims abstract description 34
- 239000004744 fabric Substances 0.000 claims abstract description 27
- 229920006231 aramid fiber Polymers 0.000 claims abstract description 18
- 229920002396 Polyurea Polymers 0.000 claims abstract description 16
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052802 copper Inorganic materials 0.000 claims abstract description 11
- 239000010949 copper Substances 0.000 claims abstract description 11
- 239000010410 layer Substances 0.000 claims description 45
- 238000007789 sealing Methods 0.000 claims description 10
- 239000002356 single layer Substances 0.000 claims description 8
- 229920002430 Fibre-reinforced plastic Polymers 0.000 claims description 7
- 239000011521 glass Substances 0.000 claims description 6
- 239000000853 adhesive Substances 0.000 claims description 5
- 230000001070 adhesive effect Effects 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 4
- 238000009413 insulation Methods 0.000 claims description 4
- 229910000831 Steel Inorganic materials 0.000 claims description 3
- 238000005538 encapsulation Methods 0.000 claims description 3
- 239000010959 steel Substances 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000006229 carbon black Substances 0.000 claims description 2
- 235000019241 carbon black Nutrition 0.000 claims description 2
- 239000003822 epoxy resin Substances 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 229920000647 polyepoxide Polymers 0.000 claims description 2
- 239000004848 polyfunctional curative Substances 0.000 claims description 2
- 238000004321 preservation Methods 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims 1
- 238000010276 construction Methods 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 7
- 239000011162 core material Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 239000011152 fibreglass Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 230000037452 priming Effects 0.000 description 2
- 239000011253 protective coating Substances 0.000 description 2
- 239000012945 sealing adhesive Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 244000137852 Petrea volubilis Species 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000011358 absorbing material Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000010009 beating Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007123 defense Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000011900 installation process Methods 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000007903 penetration ability Effects 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
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- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
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- B32B3/085—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by added members at particular parts spaced apart pieces on the surface of a layer
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- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
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- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
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- B32B38/0004—Cutting, tearing or severing, e.g. bursting; Cutter details
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
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- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
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- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F41—WEAPONS
- F41H—ARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
- F41H3/00—Camouflage, i.e. means or methods for concealment or disguise
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F41—WEAPONS
- F41H—ARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
- F41H5/00—Armour; Armour plates
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- B32B2260/02—Composition of the impregnated, bonded or embedded layer
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- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/04—Impregnation, embedding, or binder material
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- B32B2262/10—Inorganic fibres
- B32B2262/101—Glass fibres
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- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/304—Insulating
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
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- B32B2571/00—Protective equipment
- B32B2571/02—Protective equipment defensive, e.g. armour plates, anti-ballistic clothing
Landscapes
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Laminated Bodies (AREA)
- Reinforced Plastic Materials (AREA)
- Aiming, Guidance, Guns With A Light Source, Armor, Camouflage, And Targets (AREA)
Abstract
The invention belongs to technical field of composite materials, in particular to a kind of camouflage composite material, from outside inward successively including: that polyurea protection layer (1), two layers of alkali-free glass fibre epoxy prepreg cloth (2,3), aramid fiber honeycomb are inhaled wave plate (4), two layers of alkali-free glass fibre epoxy prepreg cloth (5,6), 120 mesh copper sieves (7), are bonded between two layers of each layer of alkali-free glass fibre epoxy prepreg cloth (8,9), the present invention well inhales wave energy and long service life, construction efficiency are high.
Description
Technical field
The invention belongs to technical field of composite materials, in particular to a kind of Stealth Fighter material;
Background technique
In modern war, in order to more effectively " save oneself, eliminate enemy ", stealth technology has obtained tremendous development.
It has been applied to develop the various Stealth weapons such as invisbile plane, stealth missile, stealth tank, stealthy ship, some developments
Succeed and puts into battlefield use.With the development and application of stealth technology, will occur on future battlefield more and more various
Stealth weapons.This will greatly improve the survival ability, penetration ability and fighting efficiency of weaponry, and it is flat to break established attacking and defending
Weighing apparatus pushes the various detection systems in system of defense that major transformation occurs.The patent provides a kind of camouflage composite material molding work
Skill and application have been applied to the wheel hub cover of military combat tank at present, play stealthy protective action;
Summary of the invention
The technical scheme is that
A kind of camouflage composite material, it is characterized in that from outside inward successively including: polyurea protection layer (1), alkali-free glass fibre
Epoxy prepreg cloth (2,3), aramid fiber honeycomb inhale wave plate (4), alkali-free glass fibre epoxy prepreg cloth (5,6), 120 mesh copper sieves (7)
And it is bonded between alkali-free glass fibre epoxy prepreg cloth (8,9) each layer.
Further, the polyurea protection layer (1) is with a thickness of 0.9~1.1mm, two layers of alkali-free glass fibre epoxy prepreg cloth
(2,3) thickness in monolayer is 0.2mm, aramid fiber honeycomb inhales wave plate (3) with a thickness of 8.5mm or 4.0mm, two layers of alkali-free glass fibre ring
Oxygen prepreg cloth (5,6) thickness in monolayer is 0.2mm, 120 mesh copper sieves (7) are pre- with a thickness of 0.2mm, two layers of alkali-free glass fibre epoxy
Leaching cloth (8,9) thickness in monolayer is 0.2mm;
A kind of camouflage composite material moulding process as described above, it is characterized in that the following steps are included:
A. two layers of alkali-free glass fibre epoxy prepreg cloth (2,3), aramid fiber honeycomb are inhaled into wave plate (4), two in sequence
Layer alkali-free glass fibre epoxy prepreg cloth (5,6), 120 mesh copper sieves (7), two layers of alkali-free glass fibre epoxy prepreg cloth (8,9)
It is bonded between each layer.It is bonded under the vacuum pressure that pressure is -0.095~-0.1MPa, while heating 80~90 DEG C, protect
The warm dwell time is 100min~200min progress;
B. it cuts: stealthy plate after molding is cut by required compact dimensions requirement, and by the stealthy plate after cutting
The corresponding aramid fiber honeycomb of lateral profile inhales wave plate (4) and carries out drawing side processing, and drawing side depth is 3mm~7mm or so;
C., glass fibre reinforced plastic prop mounting hole is set at a certain distance, and seals adhering glass steel in place glass fibre reinforced plastic prop mounting hole
Column;
D. it is drawn in aramid fiber honeycomb suction wave plate (4) and is sealed processing at side;
E. the stealthy plate of encapsulation process is pasted with stealthy device is needed, blending bolt passes through glass fibre reinforced plastic prop will be described
Device is fixed;
F. polyurea protection layer (1) spraying is carried out in outermost layer.
Further, step C, the edge sealing putty of encapsulation process described in D are as follows: by epoxy resin JL220A, the glass of 120 mesh
Microballon, 400 mesh white carbon blacks are to carry out be deployed into mixed adhesive at 100: 15: 25 by weight;Again by the mixed adhesive with
Epoxy hardener JL220B is carried out being deployed into the edge sealing putty by 140: 25 parts by weight.
Further, it is bonded in described in step A under the vacuum pressure that pressure is -0.095~-0.1MPa, while heating 80
~90 DEG C, the heat-insulation pressure keeping time is 240min progress.
Further, using SPUA-M200, polyurea materials, the material are double groups to polyurea protection layer described in step F at a slow speed
Part aliphatic polyurea material, coating are made of component A and B component.The material need to be matched with D-31 priming paint, poly- to improve
The adhesive force of urea protective coating.
The present invention the beneficial effect is that: the present invention using structural wave-absorbing material as inhale wave layer, honeycomb sandwich structures,
Light weight, mechanical property is good, and has good heat preservation and insulation.Alkali-free glass fibre epoxy prepreg cloth is as panel
Layer can effectively protect and inhales wave layer, reduces influence of the external environment to suction wave layer performance, while having good wave, avoids
Outer bound pair inhales the influence of wave layer absorbing property, which can also match the suction of aramid fiber honeycomb well
Wave plate electrical performance characteristics, and then ensured decaying and absorption of the stealthy plate of lightweight to incident electromagnetic wave.Wherein 120 mesh copper sieves are made
The reflection of electromagnetic wave for inhaling wave layer can be will transmit through to inhaling in wave layer, to be fully absorbed after inhaling wave layer for reflecting layer.
Edge bonding method is taken in stealthy compound surrounding, core material inside effective protection avoids erosion of the outside environmental elements to core material, edge sealing
Used resin hardness is moderate, can meet the needs of later period installation polishing processing.
Inhaling wave layer as structure function has good absorbing property, can select the aramid fiber honeycomb of different-thickness according to demand
Wave plate is inhaled, determines final thickness.On the other hand, it inhales wave layer to be covered by glass epoxy covering, the erosion of external environment can be resisted, made
It is long with the service life, high reliablity;And the mode being connected by screw bolts is mounted on corresponding skeleton, and installation process is simple and efficient,
For subsequent repairing and replace condition of providing convenience.
In conclusion the present invention provides and a kind of inhales wave energy and the high one kind of long service life, construction efficiency with good
Camouflage composite material preparation method.
Detailed description of the invention
Fig. 1 is a kind of camouflage composite material structural representation.
In figure: 1 polyurea protection layer, 2 alkali-free glass fibre epoxy prepreg cloths, 3 alkali-free glass fibre epoxy prepreg cloths, 4 virtues
Synthetic fibre honeycomb inhales wave plate, 5 alkali-free glass fibre epoxy prepreg cloths, 6 alkali-free glass fibre epoxy prepreg cloths, 7 120 mesh copper sieves, 8
Alkali-free glass fibre epoxy prepreg cloth, 9 alkali-free glass fibre epoxy prepreg cloths, 10 fixed devices, 11 connection bolts.
Specific embodiment
Following embodiment is intended to further illustrate the content of present invention, rather than limits the scope of the invention.
1), raw material blanking: requiring according to design size, cuts alkali-free glass fibre epoxy prepreg cloth (thickness in monolayer
0.2mm), aramid fiber honeycomb inhales wave plate (all corner angle of honeycomb core will polish round and smooth) and copper sieve;
2), aramid fiber honeycomb inhales wave plate drying: 40~50 DEG C of 30 ± 5min of baking in hot room, and removal aramid fiber honeycomb is inhaled in wave plate
Moisture.
3), molding is laid with: 2 layers of alkali-free glass fibre epoxy prepreg cloth (thickness in monolayer 0.2mm) of laying → vacuumize (vacuum
Pressure controls between -0.095 to -0.1MP) it is compacted (compacting time >=15min ,≤45min).→ it is laid with 4mm thickness
Aramid fiber honeycomb inhales wave plate → repetition aforesaid operations, vacuum debulk;→ it is laid with 2 layers of alkali-free glass fibre epoxy prepreg cloth → laying 1
Layer 120 mesh copper sieves → 2 layers of laying alkali-free glass fibre epoxy prepreg cloth → repetition aforesaid operations, vacuumize compacting;It is passed through after
The vacuum pressure of -0.095~-0.1MPa is crossed, while heating 80~90 DEG C, the heat-insulation pressure keeping time is 120min molding;
4) it, cuts: stealthy plate after molding is cut by design size requirement.And by the stealthy plate foreign steamer after cutting
Aramid fiber honeycomb inhales wave plate and carries out drawing side processing in exterior feature, and depth is 5mm or so, about 3 honeycomb core grids.And it is wanted according to design
It asks, with the glass reinforced plastic post holes for beating φ 15 (inner hole is φ 9);
5), edge sealing and adhering glass steel column: the stealthy plate cut is subjected to edge sealing processing, is drawn at side in stealthy composite plate
Filling
Edge sealing adhesive simultaneously smoothes out, while edge sealing adhesive is inserted in glass reinforced plastic post holes, and glass fibre reinforced plastic prop is put into, ambient temperature curing
10~20h is polished with 200 mesh or so sand paper afterwards, repeats above-mentioned edge sealing process, until edge sealing is tight;
6), stealthy plate is connect with fixed device using the bolt of M8*30;
7), polyureas sprays: in stealthy plate outermost surfaces, grinding process, and being surface modified, uses polyureas after qualified
Protective coating polyurea materials and is matched at a slow speed using SPUA-M200 with D-31 priming paint, to improve the attached of polyurea protection coating
Put forth effort, sprays the polyurea coating of the coating layer thickness of (1.0 ± 0.1) mm;
The peel strength for the stealth material forming surface that the present embodiment is prepared is not less than 4N/cm, and absorbing property is seen below
Table;
Serial number | Fight radar | Radar reflectivity |
1 | S | ≤-2db |
2 | C | ≤-5db |
3 | X | ≤-10db |
4 | Ku | ≤-8db |
5 | Ka | ≤-5db |
Claims (5)
1. a kind of camouflage composite material, it is characterized in that from outside inward successively including: polyurea protection layer (1), two layers of alkali-free glass fibre
Tie up epoxy prepreg cloth (2,3), aramid fiber honeycomb inhales wave plate (4), two layers of alkali-free glass fibre epoxy prepreg cloth (5,6), 120 mesh copper sieve
It is bonded between net (7), two layers of each layer of alkali-free glass fibre epoxy prepreg cloth (8,9).
2. a kind of camouflage composite material as described in claim 1, it is characterized in that: the polyurea protection layer (1) with a thickness of 0.9~
1.1mm, two layers alkali-free glass fibre epoxy prepreg cloth (2,3) thickness in monolayer is 0.2mm, aramid fiber honeycomb inhale wave plate (3) with a thickness of
8.5mm or 4.0mm, two layers of alkali-free glass fibre epoxy prepreg cloth (5,6) thickness in monolayer are 0.2mm, 120 mesh copper sieves (7) are thick
Degree is 0.2mm, two layers of alkali-free glass fibre epoxy prepreg cloth (8,9) thickness in monolayer is to be bonded between each layer of 0.2mm.
3. a kind of moulding process of camouflage composite material as claimed in claim 2, it is characterized in that the following steps are included:
A. two layers of alkali-free glass fibre epoxy prepreg cloth (2,3), aramid fiber honeycomb are inhaled into wave plate (4), two layers of nothing in sequence
Alkali containing glass fibre epoxy prepreg cloth (5,6), 120 mesh copper sieves (7), two layers of each layer of alkali-free glass fibre epoxy prepreg cloth (8,9)
Between be bonded.It is bonded under the vacuum pressure that pressure is -0.095~-0.1MPa, while heating 80~90 DEG C, heat preservation is protected
Press the time for 100min~200min progress;
B. it cuts: stealthy plate after molding is cut by required compact dimensions requirement, and will be on the outside of the stealthy plate after cutting
The corresponding aramid fiber honeycomb of profile inhales wave plate (4) and carries out drawing side processing, and drawing side depth is 3mm~7mm or so;
C., glass fibre reinforced plastic prop mounting hole is set at a certain distance, and seals adhering glass steel column in place glass fibre reinforced plastic prop mounting hole;
D. it is drawn in aramid fiber honeycomb suction wave plate (4) and is sealed processing at side;
E. the stealthy plate of encapsulation process is pasted with stealthy device is needed, blending bolt passes through glass fibre reinforced plastic prop for described device
It is fixed;
F. polyurea protection layer (1) spraying is carried out in outermost layer.
4. a kind of moulding process of camouflage composite material as claimed in claim 3, it is characterized in that: at sealing described in step C, D
Reason edge sealing putty are as follows: by epoxy resin JL220A, the glass microballoon of 120 mesh, 400 mesh white carbon blacks be by weight 100: 15:
25 carry out being deployed into mixed adhesive;The mixed adhesive and epoxy hardener JL220B are carried out by 140: 25 parts by weight again
It is deployed into the edge sealing putty.
5. a kind of moulding process of camouflage composite material as claimed in claim 3, it is characterized in that: being bonded in pressure described in step A
Power be -0.095~-0.1MPa vacuum pressure under, while heat 80~90 DEG C, the heat-insulation pressure keeping time be 240min carry out.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN114234721A (en) * | 2021-12-29 | 2022-03-25 | 咸宁海威复合材料制品有限公司 | Fireproof, heat-insulating and flame-retardant ultrahigh molecular weight polyethylene bulletproof plate and manufacturing method thereof |
CN114909953A (en) * | 2022-05-20 | 2022-08-16 | 江南大学 | Core layer composite material for protecting flying stones |
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JPH0811130A (en) * | 1994-06-28 | 1996-01-16 | Hitachi Chem Co Ltd | Prepreg and manufacture of copper plated laminated sheet for which that prepreg is used |
CN105783599A (en) * | 2016-05-17 | 2016-07-20 | 长沙达菲新材料科技有限公司 | Light stealth armor and preparation method thereof |
CN107009710A (en) * | 2017-04-06 | 2017-08-04 | 南京大学 | A kind of lightweight broad-band structure inhales ripple plate and preparation method thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN114234721A (en) * | 2021-12-29 | 2022-03-25 | 咸宁海威复合材料制品有限公司 | Fireproof, heat-insulating and flame-retardant ultrahigh molecular weight polyethylene bulletproof plate and manufacturing method thereof |
CN114909953A (en) * | 2022-05-20 | 2022-08-16 | 江南大学 | Core layer composite material for protecting flying stones |
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