CN110356059A - A kind of antibacterial ultraviolet-resistannanofiber line fabric - Google Patents
A kind of antibacterial ultraviolet-resistannanofiber line fabric Download PDFInfo
- Publication number
- CN110356059A CN110356059A CN201910766823.8A CN201910766823A CN110356059A CN 110356059 A CN110356059 A CN 110356059A CN 201910766823 A CN201910766823 A CN 201910766823A CN 110356059 A CN110356059 A CN 110356059A
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- China
- Prior art keywords
- layer
- fiber
- nano
- fibre
- cellulose acetate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000004744 fabric Substances 0.000 title claims abstract description 93
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 68
- 239000000835 fiber Substances 0.000 claims abstract description 124
- 229920002301 cellulose acetate Polymers 0.000 claims abstract description 37
- 229920002994 synthetic fiber Polymers 0.000 claims abstract description 29
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000012209 synthetic fiber Substances 0.000 claims abstract description 25
- 239000006210 lotion Substances 0.000 claims abstract description 23
- 238000010521 absorption reaction Methods 0.000 claims abstract description 20
- 239000000178 monomer Substances 0.000 claims abstract description 8
- 230000004048 modification Effects 0.000 claims abstract description 7
- 238000012986 modification Methods 0.000 claims abstract description 7
- 230000000475 sunscreen effect Effects 0.000 claims abstract description 6
- 239000000516 sunscreening agent Substances 0.000 claims abstract description 6
- 239000000243 solution Substances 0.000 claims description 31
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 30
- 239000000203 mixture Substances 0.000 claims description 28
- 229920005862 polyol Polymers 0.000 claims description 18
- 150000003077 polyols Chemical class 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 15
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 13
- VHYFNPMBLIVWCW-UHFFFAOYSA-N 4-Dimethylaminopyridine Chemical compound CN(C)C1=CC=NC=C1 VHYFNPMBLIVWCW-UHFFFAOYSA-N 0.000 claims description 10
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 10
- 239000003960 organic solvent Substances 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 235000004431 Linum usitatissimum Nutrition 0.000 claims description 9
- 229920002972 Acrylic fiber Polymers 0.000 claims description 7
- 229920001747 Cellulose diacetate Polymers 0.000 claims description 7
- 229920000742 Cotton Polymers 0.000 claims description 7
- BAZVSMNPJJMILC-UHFFFAOYSA-N triadimenol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC1=CC=C(Cl)C=C1 BAZVSMNPJJMILC-UHFFFAOYSA-N 0.000 claims description 7
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 6
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 6
- 239000004677 Nylon Substances 0.000 claims description 6
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 6
- 229920002334 Spandex Polymers 0.000 claims description 6
- 239000011425 bamboo Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 229920001778 nylon Polymers 0.000 claims description 6
- 239000004759 spandex Substances 0.000 claims description 6
- 210000002268 wool Anatomy 0.000 claims description 6
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 5
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 claims description 5
- 241000894006 Bacteria Species 0.000 claims description 5
- 239000004593 Epoxy Substances 0.000 claims description 5
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 5
- 238000013019 agitation Methods 0.000 claims description 5
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims description 5
- 239000001099 ammonium carbonate Substances 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 238000000498 ball milling Methods 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 239000011259 mixed solution Substances 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 5
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- 230000001376 precipitating effect Effects 0.000 claims description 5
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- 230000035484 reaction time Effects 0.000 claims description 5
- 229910000077 silane Inorganic materials 0.000 claims description 5
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 4
- 239000003054 catalyst Substances 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- LMDZBCPBFSXMTL-UHFFFAOYSA-N 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide Chemical compound CCN=C=NCCCN(C)C LMDZBCPBFSXMTL-UHFFFAOYSA-N 0.000 claims description 2
- 229940031098 ethanolamine Drugs 0.000 claims description 2
- 240000006240 Linum usitatissimum Species 0.000 claims 1
- 244000082204 Phyllostachys viridis Species 0.000 claims 1
- 229920004933 Terylene® Polymers 0.000 claims 1
- 239000005020 polyethylene terephthalate Substances 0.000 claims 1
- 238000005406 washing Methods 0.000 abstract description 15
- 230000006750 UV protection Effects 0.000 abstract description 11
- 230000003115 biocidal effect Effects 0.000 abstract description 5
- 230000000052 comparative effect Effects 0.000 description 32
- 238000012360 testing method Methods 0.000 description 15
- 229960000583 acetic acid Drugs 0.000 description 14
- 241000208202 Linaceae Species 0.000 description 8
- 230000004224 protection Effects 0.000 description 8
- 229920002978 Vinylon Polymers 0.000 description 7
- 230000005855 radiation Effects 0.000 description 7
- 239000002086 nanomaterial Substances 0.000 description 6
- 241001330002 Bambuseae Species 0.000 description 5
- 230000003471 anti-radiation Effects 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 230000000845 anti-microbial effect Effects 0.000 description 4
- 229920002678 cellulose Polymers 0.000 description 4
- 239000001913 cellulose Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 230000035699 permeability Effects 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- -1 3- dimethylamino-propyl Chemical group 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000007908 nanoemulsion Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 229920006221 acetate fiber Polymers 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- 241000588724 Escherichia coli Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229910003978 SiClx Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000002440 hydroxy compounds Chemical class 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000012113 quantitative test Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/02—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from cellulose, cellulose derivatives, or proteins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0261—Polyamide fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0276—Polyester fibres
- B32B2262/0284—Polyethylene terephthalate [PET] or polybutylene terephthalate [PBT]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0292—Polyurethane fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/06—Vegetal fibres
- B32B2262/062—Cellulose fibres, e.g. cotton
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/06—Vegetal fibres
- B32B2262/062—Cellulose fibres, e.g. cotton
- B32B2262/065—Lignocellulosic fibres, e.g. jute, sisal, hemp, flax, bamboo
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/08—Animal fibres, e.g. hair, wool, silk
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
- B32B2307/21—Anti-static
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/71—Resistive to light or to UV
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
- B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2437/00—Clothing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/26—Polymers or copolymers of unsaturated carboxylic acids or derivatives thereof
- D06M2101/28—Acrylonitrile; Methacrylonitrile
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/38—Polyurethanes
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The present invention relates to a kind of antibacterial ultraviolet-resistannanofiber line fabrics, including base cloth layer, moisture absorption layer, grid air-permeable layer and superficial layer；The moisture absorption layer is set on the base cloth layer, in the grid air-permeable layer setting and the moisture absorption layer, in the sunscreen layer setting and the grid air-permeable layer；The base cloth layer is mutually perpendicular to interweave and is made by warp and weft, and warp is anti-bacterial fibre, and the anti-bacterial fibre is the modification cellulose acetate that antibacterial monomer is grafted on cellulose acetate side chain；The superficial layer is formed by the natural fiber and synthetic fibers that are impregnated with modified Nano lotion are blended.The uv resistance of antibacterial ultraviolet-resistannanofiber line fabric of the invention, antibiotic rate are still able to maintain excellent performance after washing 50 times.
Description
Technical field
The invention belongs to technical field of textile fabric, and in particular to a kind of antibacterial ultraviolet-resistannanofiber line fabric.
Background technique
Natural fabric material has the advantages that environmental protection, comfortable, good permeability and absorbing sweat, but also there is fabric to crease easily, color
The general disadvantage of fastness；Acetate fiber is to be formed by cellulose-containing natural material through chemical process, has sericeous style, wears
It is light comfortable, have good elasticity and elastic recovery, but should not wash, poor color fastness.Though and other synthetic fibers
So have dyeability good or prolonged endurable excellent properties, but does not improve grade and be chiefly used in low side garment material.
As function and performance requirement of the consumer to clothes are higher and higher, textile fabric is no longer limited to single function
Can, anti-radiation and antibacterial, anti-mite, waterproof or the performances such as fire-retardant are had both toward contact on the basis of comfortable, beautiful.
Existing radiation protection or antibacterial fabric, often only have single radiation protection or antibacterial functions, and its radiation protection or
Antibacterial functions are generally by will have the material of radiation protection or antibacterial functions to be applied directly on Base fabric, or are made into arrangement
Agent arranges fabric, but these methods are since functional material cannot be directly in conjunction with fiber, can be by with washing times increase
Gradually lose effect.And in the prior art also not using acetate fiber as primary raw material, be aided with natural fiber both has anti-spoke
Performance is penetrated, and there is anti-microbial property, and color fastness is high, has good elasticity, functional fabric comfortable and easy to wear.
Summary of the invention
In order to solve the above-mentioned problems in the prior art, the present invention provides a kind of antibacterial ultraviolet-resistannanofiber line fabrics.This
Technical problems to be solved by the inivention are achieved through the following technical solutions:
A kind of antibacterial ultraviolet-resistannanofiber line fabric, including base cloth layer, moisture absorption layer, grid air-permeable layer and superficial layer；The moisture absorption layer setting
In on the base cloth layer, on the moisture absorption layer, the sunscreen layer setting and the grid are ventilative for the grid air-permeable layer setting
On layer；
The base cloth layer is mutually perpendicular to interweave and is made by warp and weft, and warp is anti-bacterial fibre, and weft is by flax fiber and dimension
Synthetic fibre fiber is by weight 1:(2-3) composition, the diameter of warp is 48-51 microns, and the diameter of weft is 42-45 microns, and warp is close
Degree is 77-79 root/cm, and weft density is 50-55 root/cm；
The anti-bacterial fibre is the modification cellulose acetate that antibacterial monomer is grafted on cellulose acetate side chain；
The superficial layer is formed by the natural fiber and synthetic fibers that are impregnated with modified Nano lotion are blended.
Preferably, the anti-bacterial fibre preparation method the following steps are included:
(1) cellulose acetate is dissolved in organic solvent, obtains cellulose acetate solution；By the chloro- 2- of 2 ', 4 ', 4- tri-
[(α-acetic acid) ether]-diphenyl ether dissolves in organic solvent, and it is molten to obtain the chloro- 2- of 2 ', 4 ', 4- tri- [(α-acetic acid) ether]-diphenyl ether
Liquid；
(2) cellulose acetate solution and the chloro- 2- of 2 ', 4 ', the 4- tri- [(α-acetic acid) ether]-hexichol ethereal solution are mixed,
Catalyst is added dropwise simultaneously；It is reacted under conditions of 38-55 DEG C, the reaction time 3~5 hours；
(3) by the mixture after reaction, precipitating, adjusting pH value are neutrality in deionized water, are dried after filtering to get described anti-
Bacterium fiber.
Preferably, the cellulose acetate is the mixing of cellulose diacetate and Triafol T that mass ratio is 2:1
Object.
Preferably, it is (20-25) that the catalyst, which is mass ratio: 1 1- (3- dimethylamino-propyl) -3- ethyl carbon two is sub-
The mixture of amine and 4-dimethylaminopyridine.
Preferably, the modified Nano lotion is (2-3) by mass ratio: 1 nano-titanium dioxide, nano zine oxide are through more
Hydroxy compounds modification is prepared.
Preferably, the modified Nano lotion preparation method the following steps are included:
(1) nano-titanium dioxide and the nano zine oxide are weighed in proportion, are uniformly mixed, are obtained nano-mixture；
(2) solution of the nano-mixture and polyol is mixed, obtains a nanometer stirring thing；The nanometer is mixed
The mass ratio for closing the solution of object and the polyol is (1-2): (2-3)；The solution of the polyol is three
Ethanol amine and isopropanol volume ratio are (3-5): the mixed solution of (1:3)；
(3) the nanometer stirring thing is distributed to 3- (2,3- the third oxygen of epoxy) propyl trimethoxy containing 2% under high velocity agitation
In the water body of silane, pH to 8-9 is adjusted with ammonium hydrogen carbonate, continues to stir 20-30min, is put into ball mill ball milling 2-3h to get institute
State modified Nano lotion.
Preferably, the mass ratio of the natural fiber and synthetic fibers is 2:3.
Preferably, the natural fiber includes one of cotton fiber, bamboo fibre, flaxen fiber, silk fiber, wool fiber
Or it is a variety of.
Preferably, the synthetic fibers include one of polyester fiber, nylon fibre, acrylic fiber, spandex fibre or
It is a variety of.
Compared with prior art, beneficial effects of the present invention:
1, antibacterial ultraviolet-resistannanofiber line fabric of the invention, by the way that base cloth layer, moisture absorption layer, grid air-permeable layer and superficial layer, and base is arranged
Layer of cloth is interwoven using the weft that the warp of anti-bacterial fibre forms in proportion with flax fiber and vinylon fibre, and superficial layer is by soaking
Stain has the natural fiber of modified Nano lotion and synthetic fibers are blended forms, the uv resistance for the fabric being formed by weaving, antibiotic rate
Excellent performance is still able to maintain after washing 50 times；And the performances such as intensity, anti-fluffing and anti-pilling and air penetrability of fabric also equal table
It is now good.
2, antibacterial ultraviolet-resistannanofiber line fabric of the invention, using the warp and flax fiber and vinylon fibre of anti-bacterial fibre press than
The base cloth layer that the weft of example composition is interwoven was not only soft vertical ventilative comfortable along sense as the internal layer of fabric and skin contact；
Using by being impregnated with modified Nano lotion natural fiber and synthetic fibers as superficial layer, can more effectively improve the anti-spoke of fabric
Penetrate ability and ultraviolet resistance.
3, antibacterial ultraviolet-resistannanofiber line fabric of the invention, by being grafted antibacterial monomer on cellulose acetate side chain, so that vinegar
Acid cellulose had not only had excellent antibacterial activity, but also will not increase with washing times and lose antibacterial activity easily.
4, antibacterial ultraviolet-resistannanofiber line fabric of the invention, by using will have the nano material system of anti-radiation and antibacterial function
Standby at modified Nano lotion, the surface of each nano molecular is modified in advance, the hydroxyl on increase nano molecular surface, it is modified can
Combined with cellulosic molecule, improve nano molecular cellulose surface adhesive force so that fabric increase with washing times it is anti-
Radiation and anti-microbial property still keep excellent.
5, antibacterial ultraviolet-resistannanofiber line fabric of the invention, modified cellulose acetate are cellulose diacetate and Triafol T
Mixture in proportion, have many advantages, such as color is beautiful, hang down it is pliable it is good, be not easy pilling, be antistatic, and high temperature is unlikely to deform.
6, antibacterial ultraviolet-resistannanofiber line fabric of the invention, nano-titanium dioxide, the nano-silica of nano material selection in proportion
The mixture of SiClx and nano zine oxide, through polyol it is common it is modified act on natural fiber when, the anti-spoke of fabric
Penetrating property, uv resistance, antibiotic property, anti-corrugation property and anti-pilling are obviously improved when acting on than single nano material.
Specific embodiment
Further detailed description is done to the present invention combined with specific embodiments below, but embodiments of the present invention are not limited to
This.
Embodiment one
The antibacterial ultraviolet-resistannanofiber line fabric of the present embodiment, including base cloth layer, moisture absorption layer, grid air-permeable layer and superficial layer；The moisture absorption
Layer is set on the base cloth layer, and on the moisture absorption layer, the sunscreen layer is arranged and the net for the grid air-permeable layer setting
In lattice air-permeable layer.
The base cloth layer is mutually perpendicular to interweave and is made by warp and weft, and warp is anti-bacterial fibre, and weft is by flax fiber
It is formed with vinylon fibre by weight 1:2.5, the diameter of warp is 50 microns, and the diameter of weft is 43 microns, and warp density is
78/cm, weft density is 52/cm；
The anti-bacterial fibre is the modification cellulose acetate that antibacterial monomer is grafted on cellulose acetate side chain；The superficial layer by
It is impregnated with the natural fiber of modified Nano lotion and synthetic fibers is blended forms.
The preparation method of the anti-bacterial fibre of the present embodiment may comprise steps of:
(1) cellulose acetate is dissolved in organic solvent, obtains cellulose acetate solution；By the chloro- 2- of 2 ', 4 ', 4- tri-
[(α-acetic acid) ether]-diphenyl ether dissolves in organic solvent, and it is molten to obtain the chloro- 2- of 2 ', 4 ', 4- tri- [(α-acetic acid) ether]-diphenyl ether
Liquid；
(2) cellulose acetate solution and the chloro- 2- of 2 ', 4 ', the 4- tri- [(α-acetic acid) ether]-hexichol ethereal solution are mixed,
1- (3- the dimethylamino-propyl) -3- ethyl carbodiimide and 4-dimethylaminopyridine that mass ratio is 22:1 are added dropwise simultaneously；42
It is reacted under conditions of DEG C, reaction time 3.5h；
(3) by the mixture after reaction, precipitating, adjusting pH value are neutrality in deionized water, are dried after filtering to get described anti-
Bacterium fiber.
The cellulose acetate can be the mixture of cellulose diacetate and Triafol T that mass ratio is 2:1.
Modified Nano lotion is changed by the nano-titanium dioxide that mass ratio is 2.5:1, nano zine oxide through polyol
Property is prepared；Preparation method may comprise steps of:
(1) nano-titanium dioxide and the nano zine oxide are weighed in proportion, are uniformly mixed, are obtained nano-mixture；
(2) solution of the nano-mixture and polyol is mixed, obtains a nanometer stirring thing；The nanometer is mixed
The mass ratio for closing the solution of object and the polyol is 1.5:2.5；The solution of the polyol is three ethyl alcohol
The mixed solution that amine and isopropanol volume ratio are 2:1；
(3) the nanometer stirring thing is distributed to 3- (2,3- the third oxygen of epoxy) propyl trimethoxy containing 2% under high velocity agitation
In the water body of silane, pH to 8-9 is adjusted with ammonium hydrogen carbonate, continues to stir 25min, is put into ball mill ball milling 2.5h to get described
Modified Nano lotion.
The mass ratio of the natural fiber and synthetic fibers is 2:3.Natural fiber include cotton fiber, bamboo fibre, flaxen fiber,
One of silk fiber, wool fiber are a variety of；Natural fiber selects the mixing of cotton fiber and bamboo fibre fine in the present embodiment
Dimension.Synthetic fibers include one of polyester fiber, nylon fibre, acrylic fiber, spandex fibre or a variety of；It is closed in the present embodiment
The composite fibre of polyester fiber and nylon fibre is selected at fiber.
Embodiment two
The antibacterial ultraviolet-resistannanofiber line fabric of the present embodiment, including base cloth layer, moisture absorption layer, grid air-permeable layer and superficial layer；The moisture absorption
Layer is set on the base cloth layer, and on the moisture absorption layer, the sunscreen layer is arranged and the net for the grid air-permeable layer setting
In lattice air-permeable layer.
The base cloth layer is mutually perpendicular to interweave and is made by warp and weft, and warp is anti-bacterial fibre, and weft is by flax fiber
It is formed with vinylon fibre by weight 1:2, the diameter of warp is 48 microns, and the diameter of weft is 42 microns, warp density 77
Root/cm, weft density are 50/cm；
The anti-bacterial fibre is the modification cellulose acetate that antibacterial monomer is grafted on cellulose acetate side chain；The superficial layer by
It is impregnated with the natural fiber of modified Nano lotion and synthetic fibers is blended forms.
The preparation method of the anti-bacterial fibre of the present embodiment may comprise steps of:
(1) cellulose acetate is dissolved in organic solvent, obtains cellulose acetate solution；By the chloro- 2- of 2 ', 4 ', 4- tri-
[(α-acetic acid) ether]-diphenyl ether dissolves in organic solvent, and it is molten to obtain the chloro- 2- of 2 ', 4 ', 4- tri- [(α-acetic acid) ether]-diphenyl ether
Liquid；
(2) cellulose acetate solution and the chloro- 2- of 2 ', 4 ', the 4- tri- [(α-acetic acid) ether]-hexichol ethereal solution are mixed,
1- (3- the dimethylamino-propyl) -3- ethyl carbodiimide and 4-dimethylaminopyridine that mass ratio is 20:1 are added dropwise simultaneously；38
It is reacted under conditions of DEG C, reaction time 3h；
(3) by the mixture after reaction, precipitating, adjusting pH value are neutrality in deionized water, are dried after filtering to get described anti-
Bacterium fiber.
The cellulose acetate can be the mixture of cellulose diacetate and Triafol T that mass ratio is 2:1.
Modified Nano lotion is by the nano-titanium dioxide that mass ratio is 2:1, nano zine oxide through polyhydroxy compound modified
It is prepared；Preparation method may comprise steps of:
(1) nano-titanium dioxide and the nano zine oxide are weighed in proportion, are uniformly mixed, are obtained nano-mixture；
(2) solution of the nano-mixture and polyol is mixed, obtains a nanometer stirring thing；The nanometer is mixed
The mass ratio for closing the solution of object and the polyol is 1:2；The solution of the polyol be triethanolamine and
Isopropanol volume ratio is the mixed solution of 3:1；
(3) the nanometer stirring thing is distributed to 3- (2,3- the third oxygen of epoxy) propyl trimethoxy containing 2% under high velocity agitation
In the water body of silane, pH to 8-9 is adjusted with ammonium hydrogen carbonate, continues to stir 20min, is put into ball mill ball milling 3h and changes to get described
Property nanoemulsions.
The mass ratio of the natural fiber and synthetic fibers is 2:3.Natural fiber include cotton fiber, bamboo fibre, flaxen fiber,
One of silk fiber, wool fiber are a variety of；Natural fiber selects wool fiber in the present embodiment.Synthetic fibers include washing
One of synthetic fibre fiber, nylon fibre, acrylic fiber, spandex fibre are a variety of；Synthetic fibers select acrylic fibers fine in the present embodiment
The composite fibre of peacekeeping spandex fibre.
Embodiment three
The antibacterial ultraviolet-resistannanofiber line fabric of the present embodiment, including base cloth layer, moisture absorption layer, grid air-permeable layer and superficial layer；The moisture absorption
Layer is set on the base cloth layer, and on the moisture absorption layer, the sunscreen layer is arranged and the net for the grid air-permeable layer setting
In lattice air-permeable layer.
The base cloth layer is mutually perpendicular to interweave and is made by warp and weft, and warp is anti-bacterial fibre, and weft is by flax fiber
It is formed with vinylon fibre by weight 1:3, the diameter of warp is 51 microns, and the diameter of weft is 45 microns, warp density 79
Root/cm, weft density are 55/cm；
The anti-bacterial fibre is the modification cellulose acetate that antibacterial monomer is grafted on cellulose acetate side chain；The superficial layer by
It is impregnated with the natural fiber of modified Nano lotion and synthetic fibers is blended forms.
The preparation method of the anti-bacterial fibre of the present embodiment may comprise steps of:
(1) cellulose acetate is dissolved in organic solvent, obtains cellulose acetate solution；By the chloro- 2- of 2 ', 4 ', 4- tri-
[(α-acetic acid) ether]-diphenyl ether dissolves in organic solvent, and it is molten to obtain the chloro- 2- of 2 ', 4 ', 4- tri- [(α-acetic acid) ether]-diphenyl ether
Liquid；
(2) cellulose acetate solution and the chloro- 2- of 2 ', 4 ', the 4- tri- [(α-acetic acid) ether]-hexichol ethereal solution are mixed,
It is (20-25): 1 1- (3- dimethylamino-propyl) -3- ethyl carbodiimide and 4-dimethylaminopyridine that mass ratio is added dropwise simultaneously；
It is reacted under conditions of 55 DEG C, reaction time 3h；
(3) by the mixture after reaction, precipitating, adjusting pH value are neutrality in deionized water, are dried after filtering to get described anti-
Bacterium fiber.
The cellulose acetate can be the mixture of cellulose diacetate and Triafol T that mass ratio is 2:1.
Modified Nano lotion is by the nano-titanium dioxide that mass ratio is 3:1, nano zine oxide through polyhydroxy compound modified
It is prepared；Preparation method may comprise steps of:
(1) nano-titanium dioxide and the nano zine oxide are weighed in proportion, are uniformly mixed, are obtained nano-mixture；
(2) solution of the nano-mixture and polyol is mixed, obtains a nanometer stirring thing；The nanometer is mixed
The mass ratio for closing the solution of object and the polyol is 2:3；The solution of the polyol be triethanolamine and
Isopropanol volume ratio is the mixed solution of 5:3；
(3) the nanometer stirring thing is distributed to 3- (2,3- the third oxygen of epoxy) propyl trimethoxy containing 2% under high velocity agitation
In the water body of silane, pH to 8-9 is adjusted with ammonium hydrogen carbonate, continues to stir 30min, is put into ball mill ball milling 2h and changes to get described
Property nanoemulsions.
The mass ratio of the natural fiber and synthetic fibers is 2:3.Natural fiber include cotton fiber, bamboo fibre, flaxen fiber,
One of silk fiber, wool fiber are a variety of；Natural fiber selects silk fiber in the present embodiment.Synthetic fibers include washing
One of synthetic fibre fiber, nylon fibre, acrylic fiber, spandex fibre are a variety of；Synthetic fibers select polyamide fibre fine in the present embodiment
The composite fibre of peacekeeping acrylic fiber.
Comparative example one
The fabric of this comparative example and the difference of embodiment one are that the warp of base cloth layer is polyester fiber.
Comparative example two
The fabric of this comparative example and the difference of embodiment one are that superficial layer is formed by natural fiber and synthetic fibers are blended, day
Right fiber and synthetic fibers do not have modified nanoemulsions to act on.
Comparative example three
The fabric of this comparative example and the difference of embodiment one are that the warp of base cloth layer is common cellulose acetate.
Comparative example four
The fabric of this comparative example and the difference of embodiment one are that modified Nano lotion replaces with nano-titanium dioxide in superficial layer
With the solid powder of nano zine oxide, the solid powder of nano-titanium dioxide and nano zine oxide is coated on superficial layer through high-temperature shaping
Fiber surface.
Comparative example five
The fabric of this comparative example and the difference of embodiment one are, nanometer titanium dioxide is not contained in superficial layer modified Nano lotion
Titanium.
The fabric sample for choosing embodiment and comparative example carries out electromagnet shield effect, uv resistance energy, bacteriostasis rate, stretches by force
The test of the indexs such as power, Air permenbility.
Using national standard " the anti-radiation knitted product of GB/T 22583-2009 " standard and national standard " GB T
The evaluation of 18830-2009 ultraviolet resistance of fabric " testing example and comparative example cloth washing before, washing 30 times
With 50 electromagnet shield effects and ultraviolet resistances of washing；The testing result of embodiment and comparative example fabric is shown in Table 1.
The shielding property and ultraviolet resistance test result of 1 embodiment and comparative example fabric of table
Antibacterial is carried out using national standard " the evaluation third portion of GB/T20944.3-2008 antibacterial textile performance: succusion "
Property quantitative test, before the cloth washing of testing example and comparative example, washing 30 times and 50 times Escherichia coli bacteriostasis rates；Implement
Example and the testing result of comparative example fabric are shown in Table 2.
The anti-microbial property test result of 2 embodiment and comparative example fabric of table
Using the biopolishing of cotton fabrics " handle " testing example and comparative example cloth detection fibre strength and fluff
Ball test；The testing result of embodiment and comparative example fabric is shown in Table 3.
The fibre strength and pilling test result of 3 embodiment and comparative example fabric of table
| Strongly (cN/dtex) | Pilling | |
| Embodiment one | 65.7 | It does not rise |
| Embodiment two | 64.3 | It does not rise |
| Embodiment three | 63.8 | It does not rise |
| Comparative example one | 66.0 | It does not rise |
| Comparative example two | 52.5 | It rises |
| Comparative example three | 58.4 | It does not rise |
| Comparative example four | 51.9 | It does not rise |
| Comparative example five | 50.0 | It rises |
Fabric permeability test is carried out using national standard " test of GB/T 5453-1997 textile fabric gas permeability ", it is real
The testing result for applying example and comparative example fabric is shown in Table 4.
The permeability test result of 4 embodiment and comparative example fabric of table
| Air penetrability (mm/s) | |
| Embodiment one | 390 |
| Embodiment two | 385 |
| Embodiment three | 388 |
| Comparative example one | 302 |
| Comparative example two | 321 |
| Comparative example three | 355 |
| Comparative example four | 265 |
| Comparative example five | 315 |
Antibacterial ultraviolet-resistannanofiber line fabric of the invention, by the way that base cloth layer, moisture absorption layer, grid air-permeable layer and superficial layer, and base fabric is arranged
Layer is interwoven using the weft that the warp of anti-bacterial fibre forms in proportion with flax fiber and vinylon fibre, and superficial layer is by impregnating
There is the natural fiber of modified Nano lotion and synthetic fibers are blended forms, the uv resistance for the fabric being formed by weaving, antibiotic rate warp
Excellent performance is still able to maintain after washing 50 times；And the performances such as intensity, anti-fluffing and anti-pilling and air penetrability of fabric also show
Well.The base cloth layer being interwoven using the weft that the warp and flax fiber and vinylon fibre of anti-bacterial fibre form in proportion,
It is not only soft to hang down along sense but also breathe freely comfortable as the internal layer of fabric and skin contact；Using the day by being impregnated with modified Nano lotion
Right fiber and synthetic fibers can more effectively improve the radiation protection ability and ultraviolet resistance of fabric as superficial layer.By in acetic acid fibre
It ties up and is grafted antibacterial monomer on plain side chain, so that cellulose acetate had not only had excellent antibacterial activity, but also will not increase with washing times
Add and loses antibacterial activity easily.Modified Nano cream is prepared by using by the nano material with anti-radiation and antibacterial function
The surface of liquid, each nano molecular is modified in advance, increase nano molecular surface hydroxyl, it is modified can be with cellulosic molecule phase
In conjunction with, improve nano molecular cellulose surface adhesive force so that fabric increases radiation protection and anti-microbial property with washing times
It still keeps excellent.Modified cellulose acetate is the mixture of cellulose diacetate and Triafol T in proportion, has color
It is color it is beautiful, hang down it is pliable it is good, be not easy pilling, the advantages that antistatic and high temperature is unlikely to deform.Nano material selection receiving in proportion
The mixture of rice titanium dioxide, nano silica and nano zine oxide acts on day through polyol is jointly modified
When right fiber, radiation resistance, uv resistance, antibiotic property, anti-corrugation property and the anti-pilling of fabric are acted on than single nano material
When be obviously improved.
The above content is a further detailed description of the present invention in conjunction with specific preferred embodiments, and it cannot be said that
Specific implementation of the invention is only limited to these instructions.For those of ordinary skill in the art to which the present invention belongs, exist
Under the premise of not departing from present inventive concept, a number of simple deductions or replacements can also be made, all shall be regarded as belonging to of the invention
Protection scope.
Claims (9)
1. a kind of antibacterial ultraviolet-resistannanofiber line fabric, which is characterized in that including base cloth layer, moisture absorption layer, grid air-permeable layer and superficial layer；Institute
Moisture absorption layer is stated to be set on the base cloth layer, grid air-permeable layer setting on the moisture absorption layer, the sunscreen layer setting with
In the grid air-permeable layer；
The base cloth layer is mutually perpendicular to interweave and is made by warp and weft, and warp is anti-bacterial fibre, and weft is by flax fiber and dimension
Synthetic fibre fiber is by weight 1:(2-3) composition, the diameter of warp is 48-51 microns, and the diameter of weft is 42-45 microns, and warp is close
Degree is 77-79 root/cm, and weft density is 50-55 root/cm；
The anti-bacterial fibre is the modification cellulose acetate that antibacterial monomer is grafted on cellulose acetate side chain；
The superficial layer is formed by the natural fiber and synthetic fibers that are impregnated with modified Nano lotion are blended.
2. antibacterial ultraviolet-resistannanofiber line fabric according to claim 1, which is characterized in that the preparation method packet of the anti-bacterial fibre
Include following steps:
(1) cellulose acetate is dissolved in organic solvent, obtains cellulose acetate solution；By the chloro- 2- of 2 ', 4 ', 4- tri-
[(α-acetic acid) ether]-diphenyl ether dissolves in organic solvent, and it is molten to obtain the chloro- 2- of 2 ', 4 ', 4- tri- [(α-acetic acid) ether]-diphenyl ether
Liquid；
(2) cellulose acetate solution and the chloro- 2- of 2 ', 4 ', the 4- tri- [(α-acetic acid) ether]-hexichol ethereal solution are mixed,
Catalyst is added dropwise simultaneously；It is reacted under conditions of 38-55 DEG C, the reaction time 3~5 hours；
(3) by the mixture after reaction, precipitating, adjusting pH value are neutrality in deionized water, are dried after filtering to get described anti-
Bacterium fiber.
3. antibacterial ultraviolet-resistannanofiber line fabric according to claim 1, which is characterized in that the cellulose acetate is that mass ratio is
The cellulose diacetate of 2:1 and the mixture of Triafol T.
4. antibacterial ultraviolet-resistannanofiber line fabric according to claim 2, which is characterized in that the catalyst is that mass ratio is (20-
25): the mixture of 1 1- (3- dimethylamino-propyl) -3- ethyl carbodiimide and 4-dimethylaminopyridine.
5. antibacterial ultraviolet-resistannanofiber line fabric according to claim 1, which is characterized in that the modified Nano lotion is by mass ratio
For (2-3): 1 nano-titanium dioxide, nano zine oxide are prepared through polyhydroxy compound modified.
6. antibacterial ultraviolet-resistannanofiber line fabric according to claim 5, which is characterized in that the preparation side of the modified Nano lotion
Method the following steps are included:
(1) nano-titanium dioxide and the nano zine oxide are weighed in proportion, are uniformly mixed, are obtained nano-mixture；
(2) solution of the nano-mixture and polyol is mixed, obtains a nanometer stirring thing；The nanometer is mixed
The mass ratio for closing the solution of object and the polyol is (1-2): (2-3)；The solution of the polyol is three
Ethanol amine and isopropanol volume ratio are (3-5): the mixed solution of (1:3)；
(3) the nanometer stirring thing is distributed to 3- (2,3- the third oxygen of epoxy) propyl trimethoxy containing 2% under high velocity agitation
In the water body of silane, pH to 8-9 is adjusted with ammonium hydrogen carbonate, continues to stir 20-30min, is put into ball mill ball milling 2-3h to get institute
State modified Nano lotion.
7. antibacterial ultraviolet-resistannanofiber line fabric according to claim 1, which is characterized in that the natural fiber and synthetic fibers
Mass ratio is 2:3.
8. antibacterial ultraviolet-resistannanofiber line fabric according to claim 1, which is characterized in that the natural fiber include cotton fiber,
One of bamboo fibre, flaxen fiber, silk fiber, wool fiber are a variety of.
9. antibacterial ultraviolet-resistannanofiber line fabric according to claim 1, which is characterized in that the synthetic fibers include terylene fibre
One of dimension, nylon fibre, acrylic fiber, spandex fibre are a variety of.
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| CN111086312A (en) * | 2019-12-04 | 2020-05-01 | 江阴芗菲服饰有限公司 | Anti-ultraviolet composite knitted fabric and processing method thereof |
| CN111452460A (en) * | 2020-04-12 | 2020-07-28 | 山东天厚新材料科技有限公司 | Radiation-proof fabric |
| CN114559717A (en) * | 2022-03-09 | 2022-05-31 | 上海映皓实业有限公司 | Novel fiber garment material with ultraviolet resistance function |
| CN115287893A (en) * | 2022-06-21 | 2022-11-04 | 福建东方鑫威纺织科技有限公司 | Antibacterial composite textile fabric and preparation process thereof |
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| CN111086312A (en) * | 2019-12-04 | 2020-05-01 | 江阴芗菲服饰有限公司 | Anti-ultraviolet composite knitted fabric and processing method thereof |
| CN111452460A (en) * | 2020-04-12 | 2020-07-28 | 山东天厚新材料科技有限公司 | Radiation-proof fabric |
| CN114559717A (en) * | 2022-03-09 | 2022-05-31 | 上海映皓实业有限公司 | Novel fiber garment material with ultraviolet resistance function |
| CN115287893A (en) * | 2022-06-21 | 2022-11-04 | 福建东方鑫威纺织科技有限公司 | Antibacterial composite textile fabric and preparation process thereof |
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Denomination of invention: An antibacterial and ultraviolet resistant fabric Effective date of registration: 20210915 Granted publication date: 20210608 Pledgee: Zhejiang Chouzhou Commercial Bank Co.,Ltd. Pledgor: Zhejiang Renpai Garment Co.,Ltd. Registration number: Y2021330001606 |