CN110350203A - Cell bipolar plate - Google Patents

Cell bipolar plate Download PDF

Info

Publication number
CN110350203A
CN110350203A CN201810288159.6A CN201810288159A CN110350203A CN 110350203 A CN110350203 A CN 110350203A CN 201810288159 A CN201810288159 A CN 201810288159A CN 110350203 A CN110350203 A CN 110350203A
Authority
CN
China
Prior art keywords
bipolar plate
cell bipolar
dis
eff
carbon felt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810288159.6A
Other languages
Chinese (zh)
Inventor
高丽珠
戴新国
梁超
童浩
杨小中
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Foxconn Kunshan Computer Connector Co Ltd
Foxconn Interconnect Technology Ltd
Original Assignee
Foxconn Kunshan Computer Connector Co Ltd
Foxconn Interconnect Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Foxconn Kunshan Computer Connector Co Ltd, Foxconn Interconnect Technology Ltd filed Critical Foxconn Kunshan Computer Connector Co Ltd
Priority to CN201810288159.6A priority Critical patent/CN110350203A/en
Publication of CN110350203A publication Critical patent/CN110350203A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8605Porous electrodes
    • H01M4/8626Porous electrodes characterised by the form
    • H01M4/8631Bipolar electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/96Carbon-based electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/18Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
    • H01M8/184Regeneration by electrochemical means
    • H01M8/188Regeneration by electrochemical means by recharging of redox couples containing fluids; Redox flow type batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Abstract

A kind of cell bipolar plate, it includes dis-eff, it is bonded to the carbon felt layer of the dis-eff two sides, anode electrolyte and electrolyte liquid, the carbon felt layer is bonded to the dis-eff two sides by a kind of moulding material with compared with high adhesiveness, each dis-eff two sides are bonded with the carbon felt layer being closely sized to the dis-eff, so as to form a bipolarity matrix, the cell bipolar plate can be formed by the stacking of several bipolarity matrixes, fill anode electrolyte and electrolyte liquid respectively to form the anode and cathode of cell bipolar plate in the cell bipolar plate two sides, the positive electrode and negative electrode of the cell bipolar plate electrically conduct, the bipolar plate of redox flow battery for forming internal parallel is stacked by multiple bipolar matrixes, it is simple with structure, impedance reduces, the increased advantage of efficiency.

Description

Cell bipolar plate
[technical field]
The invention belongs to flow battery fields, specifically provide a kind of cell bipolar plate of flow battery.
[background technique]
Worldwide energy shortage and the exacerbated situation of environment promote countries in the world to develop and utilize renewable energy The cry in source grows to even greater heights.But no matter solar energy or wind energy, all there is the unstability of energy supply, need function admirable Energy-storage system is matched.Peak load shifting, the balanced load of power grid are also required to scale energy storage technology.The flow battery service life is long, can By property height, flexible design, without extreme terrain require, operation and maintenance cost it is lower, be ideal scale energy storage device.So And flow battery group impedance currently on the market is larger, such as No. CN103268945A revealed liquid stream of Chinese invention patent Cell Bipolar pole plate, it includes the flexible bezel equipped with cavity to bipolar plates, the bipolar plates being installed in cavity, and is passed through Glue layer is pasted on the carbon felt layer of two side of bipolar plates, and the entire graphite felt is placed in the bipolar plates, have compared with Big resistance affects the use efficiency of Cell Bipolar pole plate.
Therefore, it is necessary to a kind of new cell bipolar plate and its battery pack heap be designed, to improve the above problem.
[summary of the invention]
The purpose of the present invention is to provide a kind of cell bipolar plates for advantageously reducing impedance.
The purpose of the present invention is achieved through the following technical solutions: a kind of cell bipolar plate comprising dis-eff is bonded to Carbon felt layer, anode electrolyte and the electrolyte liquid of the dis-eff two sides, the carbon felt layer have higher glue by a kind of The moulding material of connecing property is bonded to the dis-eff two sides, and each dis-eff two sides are bonded with to be closely sized to the dis-eff Carbon felt layer the Cell Bipolar can be formed by the stacking of several bipolarity matrixes so as to form a bipolarity matrix Plate, the cell bipolar plate two sides fill anode electrolyte and electrolyte liquid respectively with formed the anode of cell bipolar plate and The positive electrode and negative electrode of cathode, the cell bipolar plate electrically conduct.
Further, the dis-eff includes the upper and lower surfaces being oppositely arranged and left and right side, and when stacking, one bipolar The upper surface of body with the lower surface of adjacent bipolar body is corresponding contacts, the cell bipolar plate can be formed by being stacked with this.
Further, the carbon felt layer is bonded to the left and right sides of the dis-eff in pairs, the width of the carbon felt layer and Length is respectively less than the width and length of the dis-eff.
Further, each dis-eff and carbon felt layer are in rectangular slat shape, and the cell bipolar plate is long in flat plate The longest edge of cube or square setting, the cuboid extends along the longitudinally of the carbon felt layer, and the cuboid is most Short side extends along the thickness direction of the carbon felt layer.
Further, the moulding material is made of a kind of material of waterproof and anticorrosion.
Further, the material of the waterproof and anticorrosion is conductive plastics or plastics dielectric material or glue.
Further, the material of the waterproof and anticorrosion is PVC material or ABS plastic or PP plastics.
Further, the moulding material sufficiently obstructs the carbon felt layer of the positive and negative anodes and the tolerable temperature of the carbon felt layer It is 100 degrees Celsius or more.
Further, the mode that the carbon felt layer is bonded to dis-eff two sides passes through fixed clamp, glue spraying, shearing or superposition One or more of.
Further, it electrically conducts between the adjacent bipolarity matrix that every two stacks, the moulding material is not broken The monolithic devices of the bad carbon felt layer, still have good conductive property between the anode electrolyte and electrolyte liquid.
Compared with prior art, the invention has the following beneficial effects: cell bipolar plates of the present invention by double described in several Pole matrix stacks composition and its internal formation parallel-connection structure, and the positive electrode and negative electrode of the cell bipolar plate are opposite on longitudinally to be set It sets, can effectively reduce the impedance of cell bipolar plate, led in addition, the cell bipolar plate is used as using the carbon felt layer of graphite felt material Body, graphite felt have single layer transverse direction stratiform organizer to the higher characteristic of conductivity, therefore carry out battery unit using this direction Parallel connection, can effectively reduce internal resistance, improve conductivity.
[Detailed description of the invention]
Fig. 1 is the perspective view of cell bipolar plate of the present invention.
Fig. 2 is the main view of cell bipolar plate shown in Fig. 1.
Fig. 3 is cell bipolar plate top view shown in Fig. 1.
Fig. 4 is the side view of cell bipolar plate shown in Fig. 1.
Fig. 5 is the perspective view of a bipolarity matrix of cell bipolar plate of the present invention.
Fig. 6 is the perspective view of bipolarity matrix shown in Fig. 5.
Fig. 7 is the top view of bipolarity matrix shown in Fig. 5.
Fig. 8 is the side view of bipolarity matrix shown in Fig. 5.
[main element symbol description]
100 bipolarity matrix 10 of cell bipolar plate
1 upper surface 11 of dis-eff
12 left side 13 of lower surface
14 carbon felt layer 2 of right side
The present invention that the following detailed description will be further explained with reference to the above drawings.
[specific embodiment]
Hereinafter, the specific embodiment that Fig. 1 to Fig. 8 will be combined to introduce cell bipolar plate 100 of the present invention.The present invention provides A kind of cell bipolar plate 100 for flow battery, the cell bipolar plate 100 include dis-eff 1, are bonded to the dis-eff The carbon felt layer 2 formed by graphite felt, anode electrolyte (not indicating) and the electrolyte liquid (not indicating) of 1 two sides.The electricity Pond bipolar plates 100 have lower internal resistance, so that the cell bipolar plate 100 has higher energy efficiency.
As shown in Figures 1 to 4, in the present embodiment, each dis-eff 1 and carbon felt layer 2 are in rectangular slat shape, each bipolar 1 two sides of body are bonded with the carbon felt layer 2 being closely sized to the dis-eff 1, with this so as to form a bipolarity matrix 10, mistake The stacking of several bipolarity matrixes 10 can form the cell bipolar plate 100, and 100 two sides of cell bipolar plate are filled respectively The anode electrolyte and the electrolyte liquid are to form the anode and cathode of cell bipolar plate 100, the Cell Bipolar The positive electrode and negative electrode of plate 100 electrically conduct.Wherein the carbon felt layer 2 of side absorb the anode electrolyte formed anode and the other side Carbon felt layer 2 absorb electrolyte liquid and form cathode, the carbon felt layer 2 is viscous by a kind of moulding material with compared with high adhesiveness It is connected to 1 two sides of dis-eff, wherein the moulding material is made of a kind of material of waterproof and anticorrosion, further, described anti- Water corrosion-resistant material is PVC (PolyVinyl Chloride) material or ABS (Acrylonitrile Butadiene Styrene) plastics or PP (PolyVinyl Chloride) plastics, the material of the waterproof and anticorrosion are conductive plastics or do not lead Electric plastics or glue etc. can sufficiently obstruct the material of the positive and negative anodes of the carbon felt layer 2 of 1 two sides of dis-eff, described to prevent The problems such as gas leakage leakage, mutually pollution, occurs for positive and negative electrode electrolyte.Temperature often increases cell bipolar plate 100 at work, And the resistant material needs to be bonded at the time of molding the surface of the carbon felt layer 2, therefore the material tool of the waterproof and anticorrosion Have that waterproof, corrosion-resistant, mobility is good and 100 DEG C of tolerable temperature with first-class characteristic.The material of the waterproof and anticorrosion can with but it is unlimited In PVC material or ABS plastic or PP plastic or other material.
Incorporated by reference to Fig. 5 to Fig. 8, the dis-eff 1 include the upper and lower surfaces 11,12 that are oppositely arranged and left and right side 13, 14, when stacking, the upper surface 11 of a dis-eff 1 is contacted with the lower surface 12 of adjacent bipolar body 1 correspondence, and being stacked with this can form The cell bipolar plate 100.The carbon felt layer 2 is bonded to the left and right sides of the dis-eff 1, the width of the carbon felt layer 2 in pairs Degree and length are respectively less than the width and length of the dis-eff 1.The mode that the carbon felt layer 2 is bonded to 1 two sides of dis-eff passes through One or more of fixed clamp, glue spraying, shearing or superposition.The cell bipolar plate 100 in flat plate cuboid or The longest edge of square setting, the cuboid extends along the longitudinally of the carbon felt layer 2, the most short side edge of the cuboid The thickness direction of the carbon felt layer 2 extends.The positive electrode and negative electrode are arranged in parallel on the longitudinally, what every two stacked Electrically conduct between adjacent bipolarity matrix 10, the moulding material does not destroy the monolithic devices of the carbon felt layer 2, it is described just It is still had good conductive property between pole electrolyte and electrolyte liquid.Therefore, when assembling required cell bipolar plate 100 Afterwards, several described dis-effs 1 practice the intermediate in alignment for forming a rectangle in the vertical direction, in the rectangle Mesosome two sides are bonded with several carbon felt layers 2 corresponding with aforementioned dis-eff 1, and wherein the carbon felt layer 2 of side constitutes described The anode of cell bipolar plate 100, the carbon felt layer 2 of the dis-eff other side constitute the cathode of the cell bipolar plate 100.
Whereby, the cell bipolar plate 100 is formed by several bipolarity matrixes 10 stacking, due to all positive polaritys Carbon felt layer 2 be located at the same side of the dis-eff 1, the carbon felt layer 2 of all negative polarity is located at and 2 phase of positive polarity carbon felt layer For the other side of the binary body 1, so as to form the positive and negative anodes being oppositely arranged, every bipolar matrix 10 and neighboring bipolar While matrix 10 electrically conducts, reach state in parallel two-by-two, is in parallel between final all bipolarity matrixes 10.Institute With, the present invention being specifically designed can reduce and even be eliminated due between monomer by the bipolar plate of redox flow battery 100 of internal parallel Potential difference caused by internal self discharge problem, electrolysis caused by the pressure seal being easily solved in series connection monomer structure is uneven The problems such as liquid leaks.The bipolar plate of redox flow battery structure of internal parallel can specification electrode reaction current distribution, alleviate monomer Strict demand in terms of consistency, easy to process and assembling, structure is simple, easy to maintain, can be used for being electrolysed, electroplating industry and liquid In galvanic battery system.Using the bipolar plate of redox flow battery 100 of internal parallel, thus overall impedance can be reduced, pass through bipolarity The target for reaching extension voltage and current in series and parallel between matrix 10;In addition, the cell bipolar plate 100 uses several carbon felts Layer 2 is used as conductor, since carbon felt layer 2 has single layer transverse direction stratiform organizer to the higher characteristic of conductivity, utilizes this side To the parallel connection for carrying out battery unit, internal resistance can be effectively reduced, improves conductivity.
The foregoing is merely some embodiments of the invention, the embodiment being not all of, ordinary skill people Any equivalent variation that member takes technical solution of the present invention by reading description of the invention, is right of the invention It is required that being covered.

Claims (10)

1. a kind of cell bipolar plate comprising dis-eff, the carbon felt layer for being bonded to the dis-eff two sides, anode electrolyte and Electrolyte liquid, the carbon felt layer are bonded to the dis-eff two sides by a kind of moulding material with compared with high adhesiveness, Be characterized in that: each dis-eff two sides are bonded with the carbon felt layer being closely sized to the dis-eff, bipolar so as to form one Property matrix, the cell bipolar plate can be formed by the stacking of several bipolarity matrixes, the cell bipolar plate two sides difference Anode electrolyte and electrolyte liquid are filled to form the anode and cathode of cell bipolar plate, the anode of the cell bipolar plate It electrically conducts with cathode.
2. cell bipolar plate as described in claim 1, it is characterised in that: the dis-eff includes the upper and lower table being oppositely arranged Face and left and right side, when stacking, the upper surface of a dis-eff with the lower surface of adjacent bipolar body is corresponding contacts, stacked with this The cell bipolar plate can be formed.
3. cell bipolar plate as claimed in claim 2, it is characterised in that: the carbon felt layer is bonded to the dis-eff in pairs The left and right sides, the width and length of the carbon felt layer are respectively less than the width and length of the dis-eff.
4. cell bipolar plate as described in claim 1, it is characterised in that: each dis-eff and carbon felt layer are in rectangular slat shape, The cell bipolar plate is arranged in flat plate cuboid or square, and the longest edge of the cuboid is along the carbon felt layer Longitudinally extends, and the most short side of the cuboid extends along the thickness direction of the carbon felt layer.
5. cell bipolar plate as described in claim 1, it is characterised in that: the moulding material by a kind of waterproof and anticorrosion material It is made.
6. cell bipolar plate as claimed in claim 5, it is characterised in that: the material of the waterproof and anticorrosion be conductive plastics or Plastics dielectric material or glue.
7. cell bipolar plate as claimed in claim 6, it is characterised in that: the material of the waterproof and anticorrosion is PVC material or ABS Plastics or PP plastics.
8. cell bipolar plate as described in claim 1, it is characterised in that: the moulding material sufficiently obstructs the positive and negative anodes The tolerable temperature of carbon felt layer and the carbon felt layer is 100 degrees Celsius or more.
9. cell bipolar plate as described in claim 1, it is characterised in that: the carbon felt layer is bonded to the mode of dis-eff two sides Pass through one or more of fixed clamp, glue spraying, shearing or superposition.
10. cell bipolar plate as described in claim 1, it is characterised in that: every two stack adjacent bipolarity matrix it Between electrically conduct, the moulding material does not destroy the monolithic devices of the carbon felt layer, the anode electrolyte and electrolyte liquid Between still have good conductive property.
CN201810288159.6A 2018-04-03 2018-04-03 Cell bipolar plate Pending CN110350203A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810288159.6A CN110350203A (en) 2018-04-03 2018-04-03 Cell bipolar plate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810288159.6A CN110350203A (en) 2018-04-03 2018-04-03 Cell bipolar plate

Publications (1)

Publication Number Publication Date
CN110350203A true CN110350203A (en) 2019-10-18

Family

ID=68172501

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810288159.6A Pending CN110350203A (en) 2018-04-03 2018-04-03 Cell bipolar plate

Country Status (1)

Country Link
CN (1) CN110350203A (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6656639B1 (en) * 1999-03-23 2003-12-02 Unisearch Limited Bipolar electrode having non-conductive electrode substrate and fibrous electrochemically active material
US20100297520A1 (en) * 2007-12-05 2010-11-25 Heinz Wenzl, Am Bergwaeldchen 27 Electrochemical energy conversion system
CN103268945A (en) * 2013-07-02 2013-08-28 成都赢创科技有限公司 Bipolar electrode for flow battery and manufacturing process thereof
CN104538661A (en) * 2015-01-05 2015-04-22 攀钢集团研究院有限公司 Vanadium cell, vanadium cell end collector plate, vanadium cell dual collector plate and preparation of vanadium cell end collector plate and vanadium cell dual collector plate
CN106654294A (en) * 2017-01-16 2017-05-10 中国东方电气集团有限公司 Bipolar plate, flow battery and flow battery stack

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6656639B1 (en) * 1999-03-23 2003-12-02 Unisearch Limited Bipolar electrode having non-conductive electrode substrate and fibrous electrochemically active material
US20100297520A1 (en) * 2007-12-05 2010-11-25 Heinz Wenzl, Am Bergwaeldchen 27 Electrochemical energy conversion system
CN103268945A (en) * 2013-07-02 2013-08-28 成都赢创科技有限公司 Bipolar electrode for flow battery and manufacturing process thereof
CN104538661A (en) * 2015-01-05 2015-04-22 攀钢集团研究院有限公司 Vanadium cell, vanadium cell end collector plate, vanadium cell dual collector plate and preparation of vanadium cell end collector plate and vanadium cell dual collector plate
CN106654294A (en) * 2017-01-16 2017-05-10 中国东方电气集团有限公司 Bipolar plate, flow battery and flow battery stack

Similar Documents

Publication Publication Date Title
CN101587959B (en) Electrode frame and all-vanadium redox flow battery pile
CN105531862A (en) Battery cell stack and redox flow battery
KR101335544B1 (en) Redox flow battery
WO2009040335A3 (en) High temperature electrolyser with temperature homogenisation device
CN104170146A (en) Separatorless storage battery
CN102867978B (en) Flow energy storage battery structure
CN104600340A (en) Electrode frame structure of single batteries in redox flow battery as well as single battery and electric pile
US20220102740A1 (en) Electrode structure including electrode fiber having higher density of vertical tows to parallel tows, flow battery stack including the same, and sealing structure including sealing gaskets connected by sealing wire
US10680254B2 (en) Redox flow battery
WO2012042288A1 (en) Frameless electrochemical cell stack having self centering rigid plastic bushings in aligned through holes of interconnects and membrane assemblies
CN106876765A (en) A kind of flow cell pile
CN102170008B (en) Non-current vanadium element secondary battery
CN111326758A (en) Zinc-bromine single flow battery
CN206711972U (en) All-vanadium flow battery
CN110350203A (en) Cell bipolar plate
CN208923281U (en) A kind of zinc bromine single flow battery
CN207977403U (en) A kind of proton exchange film fuel cell electric piling
CN105024032A (en) Matching structure of polar plate and electrode and flow battery with matching structure
CN215184083U (en) Single-pole plate sealing structure of flow battery
CN102324491B (en) Pole piece for laminated lithium ion battery and laminated fixture
TW201644087A (en) Cell module
WO2021203935A1 (en) Composite electrode for flow cell, flow cell, and pile
CN113948748A (en) Connecting plate and solid oxide fuel cell/electrolytic cell stack
CN211957803U (en) Fuel cell stack structure
CN209447939U (en) A kind of tandem electrode of liquid flow cell frame and its battery stack

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20191018

RJ01 Rejection of invention patent application after publication