CN110343436A - Anti scuffing piano black paint and preparation method thereof - Google Patents
Anti scuffing piano black paint and preparation method thereof Download PDFInfo
- Publication number
- CN110343436A CN110343436A CN201910629592.6A CN201910629592A CN110343436A CN 110343436 A CN110343436 A CN 110343436A CN 201910629592 A CN201910629592 A CN 201910629592A CN 110343436 A CN110343436 A CN 110343436A
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- CN
- China
- Prior art keywords
- acrylic resin
- black paint
- anti scuffing
- piano black
- initiator
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/062—Copolymers with monomers not covered by C09D133/06
- C09D133/066—Copolymers with monomers not covered by C09D133/06 containing -OH groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention discloses a kind of anti scuffing piano black paint and preparation method thereof, and anti scuffing piano black paint includes following materials in percentage by mass: acrylic resin 60-65%;OH base Hydroxylated acrylic resin 15-20%;Scratch resistance agent 1-2%;Nano color paste 10-12%;Remaining is ketone and esters solvent.Coating is prepared by using inventive formulation and method, its coating for being applied to automobile parts, after coating under the premise of guaranteeing to have preferable adhesive force, scratch resistance energy is greatlyd improve, glossiness is also more preferable, belong to high brilliant black, meet the needs used, and use ketone and esters solvent, VOC emission can be effectively reduced, VOC emission is extremely low, complies fully with environmental protection standard.
Description
Technical field
The present invention relates to paint field technology, a kind of anti scuffing piano black paint and preparation method thereof is referred in particular to.
Background technique
Coating is in architectural finish, Industrial Metal, agricultural and all widely applied chemical products of Architectural Equipment field of coating.
Synthetic resin be early start use, dosage it is maximum, one of widest coating of use, it possesses good weatherability, adhesive force
It is high, paint film is bright, the characteristics such as easy for construction.Due to the diversity of synthetic resin, thus produce a variety of dry or drying enamel paint,
Priming paint, finishing coat, varnish, the synthetic resin of these different performances is in the buildings such as bridge and machinery, vehicle, ship, instrument etc.
Field of coating realizes universal application.Synthetic resin coating, purposes are very extensive.It is anti-currently used for the coating on automobile parts
It is bad to scratch performance, is not able to satisfy the needs used.
Summary of the invention
In view of this, in view of the deficiencies of the prior art, the present invention aims to provide a kind of anti scuffings
Piano black paint and preparation method thereof can effectively solve the problem that existing coating scratch resistance can be bad.
To achieve the above object, the present invention is using following technical solution:
A kind of anti scuffing piano black paint includes following materials in percentage by mass: acrylic resin 60-65%;OH base hydroxyl
Acrylic resin 15-20%;Scratch resistance agent 1-2%;Nano color paste 10-12%;Remaining is ketone and esters solvent.
Preferably, the acrylic resin includes following materials in percentage by mass: methyl methacrylate 5-8%;Benzene
Ethylene 18-20%;Butyl acrylate 21-23%;- 2 hydroxyl ethyl ester 2-4% of methacrylic acid;Ethyl acrylate 8-10%, acrylic acid
6-8%;Ethylene glycol dimethacrylate 4-5%;Dipropylene glycol methyl ether 5-8%;Initiator 2-3%;N, N dimethyl ethanol amine 4-
5%;Remaining is deionized water.
Preferably, the methyl methacrylate, styrene, butyl acrylate, -2 hydroxyl ethyl ester of methacrylic acid, acrylic acid
The purity of ethyl ester, acrylic acid, ethylene glycol dimethacrylate, dipropylene glycol methyl ether, initiator and N, N dimethyl ethanol amine are equal
Greater than 99.5%.
Preferably, the initiator is organic peroxide evocating agent.
A kind of preparation method of anti scuffing piano black paint, which is characterized in that include following steps:
(1) using acrylic resin as substrate, be added OH base Hydroxylated acrylic resin, at 45-50 DEG C with blender first with
The revolving speed of 1500rpm stirs 15 minutes, then mentions to 2000rpm and stirring 20 minutes, and material dispersion is uniform;
(2) nano color paste and scratch resistance agent are sequentially added at 30-35 DEG C, is stirred 20 minutes with the revolving speed of 1000rpm;
(3) ketone and esters solvent are added at 25-30 DEG C, is dispersed with the revolving speed of 800rpm.
The present invention has obvious advantages and beneficial effects compared with the existing technology, specifically, by above-mentioned technical proposal
Known to:
Coating is prepared by using inventive formulation and method, is applied to the coating of automobile parts, is guaranteeing after coating
Under the premise of having preferable adhesive force, scratch resistance energy is greatlyd improve, glossiness is also more preferable, belongs to high brilliant black, meets and uses
Needs, and use ketone and esters solvent, VOC emission can be effectively reduced, VOC emission is extremely low, complies fully with environmental protection standard.
Specific embodiment
Present invention discloses a kind of anti scuffing piano black paints, include following materials in percentage by mass: acrylic resin
60-65%;OH base Hydroxylated acrylic resin 15-20%;Scratch resistance agent 1-2%;Nano color paste 10-12%;Remaining is ketone and esters
Solvent.The acrylic resin includes following materials in percentage by mass: methyl methacrylate 5-8%;Styrene 18-20%;
Butyl acrylate 21-23%;- 2 hydroxyl ethyl ester 2-4% of methacrylic acid;Ethyl acrylate 8-10%, acrylic acid 6-8%;Dimethyl
Acrylic acid glycol ester 4-5%;Dipropylene glycol methyl ether 5-8%;Initiator 2-3%;N, N dimethyl ethanol amine 4-5%;Remaining for go from
The preparation method of sub- water, acrylic resin is the prior art, is not described in detail at this to the preparation method of acrylic resin;Institute
State methyl methacrylate, styrene, butyl acrylate, -2 hydroxyl ethyl ester of methacrylic acid, ethyl acrylate, acrylic acid, diformazan
Base acrylic acid glycol ester, dipropylene glycol methyl ether, initiator and N, the purity of N dimethyl ethanol amine are all larger than 99.5%, described
Initiator is organic peroxide evocating agent.
The invention also discloses a kind of preparation methods of anti scuffing piano black paint, include following steps:
(1) using acrylic resin as substrate, be added OH base Hydroxylated acrylic resin, at 45-50 DEG C with blender first with
The revolving speed of 1500rpm stirs 15 minutes, then mentions to 2000rpm and stirring 20 minutes, and material dispersion is uniform.
(2) nano color paste and scratch resistance agent are sequentially added at 30-35 DEG C, is stirred 20 minutes with the revolving speed of 1000rpm.
(3) ketone and esters solvent are added at 25-30 DEG C, is dispersed with the revolving speed of 800rpm.
The present invention is described in further detail with multiple embodiments below:
Embodiment 1:
A kind of anti scuffing piano black paint includes following materials in percentage by mass: acrylic resin 60%;OH base hydroxy
Acid resin 20%;Scratch resistance agent 1%;Nano color paste 12%;Remaining is ketone and esters solvent.The acrylic resin include with
Lower materials in percentage by mass: methyl methacrylate 5%;Styrene 20%;Butyl acrylate 23%;- 2 hydroxyl ethyl ester of methacrylic acid
3%;Ethyl acrylate 10%, acrylic acid 7%;Ethylene glycol dimethacrylate 5%;Dipropylene glycol methyl ether 7%;Initiator 2%;N, N
Dimethylethanolamine 5%;Remaining is deionized water, and the preparation method of acrylic resin is the prior art, at this to acrylic resin
Preparation method be not described in detail;The methyl methacrylate, styrene, butyl acrylate, -2 hydroxyl second of methacrylic acid
Ester, ethyl acrylate, acrylic acid, ethylene glycol dimethacrylate, dipropylene glycol methyl ether, initiator and N, N dimethyl ethyl alcohol
The purity of amine is all larger than 99.5%, and the initiator is organic peroxide evocating agent.
A kind of preparation method of anti scuffing piano black paint, includes following steps:
(1) using acrylic resin as substrate, OH base Hydroxylated acrylic resin is added, with blender first with 1500rpm at 50 DEG C
Revolving speed stir 15 minutes, then mention to 2000rpm stir 20 minutes, material dispersion is uniform.
(2) nano color paste and scratch resistance agent are sequentially added at 35 DEG C, is stirred 20 minutes with the revolving speed of 1000rpm.
(3) ketone and esters solvent are added at 30 DEG C, is dispersed with the revolving speed of 800rpm.
Coating is prepared in the present embodiment to be coated automobile parts, adhesive force is carried out after solidification, 60 ° of gloss, is resisted
Scratch resistant test, test method are the prior art, are not described in detail at this to test method, test result are as follows: adhesive force
It is 0 grade, 60 ° of gloss are 93, and resistance to marring is preferably.
Embodiment 2:
A kind of anti scuffing piano black paint includes following materials in percentage by mass: acrylic resin 65%;OH base hydroxy
Acid resin 18%;Scratch resistance agent 2%;Nano color paste 11%;Remaining is ketone and esters solvent.The acrylic resin include with
Lower materials in percentage by mass: methyl methacrylate 6%;Styrene 19%;Butyl acrylate 21%;- 2 hydroxyl ethyl ester of methacrylic acid
2%;Ethyl acrylate 8%, acrylic acid 8%;Ethylene glycol dimethacrylate 4%;Dipropylene glycol methyl ether 8%;Initiator 3%;N, N
Dimethylethanolamine 4%;Remaining is deionized water, and the preparation method of acrylic resin is the prior art, at this to acrylic resin
Preparation method be not described in detail;The methyl methacrylate, styrene, butyl acrylate, -2 hydroxyl second of methacrylic acid
Ester, ethyl acrylate, acrylic acid, ethylene glycol dimethacrylate, dipropylene glycol methyl ether, initiator and N, N dimethyl ethyl alcohol
The purity of amine is all larger than 99.5%, and the initiator is organic peroxide evocating agent.
A kind of preparation method of anti scuffing piano black paint, includes following steps:
(1) using acrylic resin as substrate, OH base Hydroxylated acrylic resin is added, with blender first with 1500rpm at 45 DEG C
Revolving speed stir 15 minutes, then mention to 2000rpm stir 20 minutes, material dispersion is uniform.
(2) nano color paste and scratch resistance agent are sequentially added at 30 DEG C, is stirred 20 minutes with the revolving speed of 1000rpm.
(3) ketone and esters solvent are added at 25 DEG C, is dispersed with the revolving speed of 800rpm.
Coating is prepared in the present embodiment to be coated automobile parts, adhesive force is carried out after solidification, 60 ° of gloss, is resisted
Scratch resistant test, test method are the prior art, are not described in detail at this to test method, test result are as follows: adhesive force
It is 0 grade, 60 ° of gloss are 90, and resistance to marring is preferably.
Embodiment 3:
A kind of anti scuffing piano black paint includes following materials in percentage by mass: acrylic resin 61%;OH base hydroxy
Acid resin 150%;Scratch resistance agent 1.5%;Nano color paste 10%;Remaining is ketone and esters solvent.The acrylic resin includes
There is following materials in percentage by mass: methyl methacrylate 7%;Styrene 18%;Butyl acrylate 22%;- 2 hydroxyl of methacrylic acid
Ethyl ester 4%;Ethyl acrylate 9%, acrylic acid 6%;Ethylene glycol dimethacrylate 4.2%;Dipropylene glycol methyl ether 58%;Cause
Agent 2.2%;N, N dimethyl ethanol amine 4.2%;Remaining is deionized water, and the preparation method of acrylic resin is the prior art, herein
The preparation method of acrylic resin is not described in detail;The methyl methacrylate, styrene, butyl acrylate, methyl
- 2 hydroxyl ethyl ester of acrylic acid, ethyl acrylate, acrylic acid, ethylene glycol dimethacrylate, dipropylene glycol methyl ether, initiator and N,
The purity of N dimethyl ethanol amine is all larger than 99.5%, and the initiator is organic peroxide evocating agent.
A kind of preparation method of anti scuffing piano black paint, includes following steps:
(1) using acrylic resin as substrate, OH base Hydroxylated acrylic resin is added, with blender first with 1500rpm at 48 DEG C
Revolving speed stir 15 minutes, then mention to 2000rpm stir 20 minutes, material dispersion is uniform.
(2) nano color paste and scratch resistance agent are sequentially added at 32 DEG C, is stirred 20 minutes with the revolving speed of 1000rpm.
(3) ketone and esters solvent are added at 28 DEG C, is dispersed with the revolving speed of 800rpm.
Coating is prepared in the present embodiment to be coated automobile parts, adhesive force is carried out after solidification, 60 ° of gloss, is resisted
Scratch resistant test, test method are the prior art, are not described in detail at this to test method, test result are as follows: adhesive force
It is 0 grade, 60 ° of gloss are 91, and resistance to marring is preferably.
Embodiment 4:
A kind of anti scuffing piano black paint includes following materials in percentage by mass: acrylic resin 62%;OH base hydroxy
Acid resin 16%;Scratch resistance agent 1.3%;Nano color paste 10.5%;Remaining is ketone and esters solvent.The acrylic resin includes
There is following materials in percentage by mass: methyl methacrylate 8%;Styrene 18.5%;Butyl acrylate 21.5%;Metering system
Sour -2 hydroxyl ethyl esters 2.5%;Ethyl acrylate 8.5%, acrylic acid 6.5%;Ethylene glycol dimethacrylate 4.5%;Dipropylene glycol
Methyl ether 6%;Initiator 2.3%;N, N dimethyl ethanol amine 4.5%;Remaining is deionized water, and the preparation method of acrylic resin is existing
There is technology, preparation method of acrylic resin is not described in detail at this;The methyl methacrylate, styrene, propylene
Acid butyl ester, -2 hydroxyl ethyl ester of methacrylic acid, ethyl acrylate, acrylic acid, ethylene glycol dimethacrylate, dipropylene glycol first
Ether, initiator and N, the purity of N dimethyl ethanol amine are all larger than 99.5%, and the initiator is organic peroxide evocating agent.
A kind of preparation method of anti scuffing piano black paint, includes following steps:
(1) using acrylic resin as substrate, OH base Hydroxylated acrylic resin is added, with blender first with 1500rpm at 47 DEG C
Revolving speed stir 15 minutes, then mention to 2000rpm stir 20 minutes, material dispersion is uniform.
(2) nano color paste and scratch resistance agent are sequentially added at 33 DEG C, is stirred 20 minutes with the revolving speed of 1000rpm.
(3) ketone and esters solvent are added at 26 DEG C, is dispersed with the revolving speed of 800rpm.
Coating is prepared in the present embodiment to be coated automobile parts, adhesive force is carried out after solidification, 60 ° of gloss, is resisted
Scratch resistant test, test method are the prior art, are not described in detail at this to test method, test result are as follows: adhesive force
It is 0 grade, 60 ° of gloss are 90, and resistance to marring is preferably.
Embodiment 5:
A kind of anti scuffing piano black paint includes following materials in percentage by mass: acrylic resin 63%;OH base hydroxy
Acid resin 17%;Scratch resistance agent 1.8%;Nano color paste 11.2%;Remaining is ketone and esters solvent.The acrylic resin includes
There is following materials in percentage by mass: methyl methacrylate 5.5%;Styrene 19.5%;Butyl acrylate 22.8%;Metering system
Sour -2 hydroxyl ethyl esters 3.5%;Ethyl acrylate 9.5%, acrylic acid 7.5%;Ethylene glycol dimethacrylate 4.8%;Dipropylene glycol
Methyl ether 5.5%;Initiator 2.5%;N, N dimethyl ethanol amine 4.8%;Remaining is deionized water, and the preparation method of acrylic resin is
The prior art is not described in detail the preparation method of acrylic resin at this;The methyl methacrylate, styrene, third
Olefin(e) acid butyl ester, -2 hydroxyl ethyl ester of methacrylic acid, ethyl acrylate, acrylic acid, ethylene glycol dimethacrylate, dipropylene glycol first
Ether, initiator and N, the purity of N dimethyl ethanol amine are all larger than 99.5%, and the initiator is organic peroxide evocating agent.
A kind of preparation method of anti scuffing piano black paint, includes following steps:
(1) using acrylic resin as substrate, OH base Hydroxylated acrylic resin is added, with blender first with 1500rpm at 46 DEG C
Revolving speed stir 15 minutes, then mention to 2000rpm stir 20 minutes, material dispersion is uniform.
(2) nano color paste and scratch resistance agent are sequentially added at 31 DEG C, is stirred 20 minutes with the revolving speed of 1000rpm.
(3) ketone and esters solvent are added at 27 DEG C, is dispersed with the revolving speed of 800rpm.
Coating is prepared in the present embodiment to be coated automobile parts, adhesive force is carried out after solidification, 60 ° of gloss, is resisted
Scratch resistant test, test method are the prior art, are not described in detail at this to test method, test result are as follows: adhesive force
It is 0 grade, 60 ° of gloss are 91.3, and resistance to marring is preferably.
Embodiment 6:
A kind of anti scuffing piano black paint includes following materials in percentage by mass: acrylic resin 64%;OH base hydroxy
Acid resin 19%;Scratch resistance agent 1.9%;Nano color paste 10.8%;Remaining is ketone and esters solvent.The acrylic resin includes
There is following materials in percentage by mass: methyl methacrylate 6.5%;Styrene 19.3%;Butyl acrylate 21.8%;Metering system
Sour -2 hydroxyl ethyl esters 2.2%;Ethyl acrylate 9.8%, acrylic acid 7.8%;Ethylene glycol dimethacrylate 4.4%;Dipropylene glycol
Methyl ether 6.5%;Initiator 2.8%;N, N dimethyl ethanol amine 4.4%;Remaining is deionized water, and the preparation method of acrylic resin is
The prior art is not described in detail the preparation method of acrylic resin at this;The methyl methacrylate, styrene, third
Olefin(e) acid butyl ester, -2 hydroxyl ethyl ester of methacrylic acid, ethyl acrylate, acrylic acid, ethylene glycol dimethacrylate, dipropylene glycol first
Ether, initiator and N, the purity of N dimethyl ethanol amine are all larger than 99.5%, and the initiator is organic peroxide evocating agent.
A kind of preparation method of anti scuffing piano black paint, includes following steps:
(1) using acrylic resin as substrate, OH base Hydroxylated acrylic resin is added, with blender first with 1500rpm at 49 DEG C
Revolving speed stir 15 minutes, then mention to 2000rpm stir 20 minutes, material dispersion is uniform.
(2) nano color paste and scratch resistance agent are sequentially added at 34 DEG C, is stirred 20 minutes with the revolving speed of 1000rpm.
(3) ketone and esters solvent are added at 29 DEG C, is dispersed with the revolving speed of 800rpm.
Coating is prepared in the present embodiment to be coated automobile parts, adhesive force is carried out after solidification, 60 ° of gloss, is resisted
Scratch resistant test, test method are the prior art, are not described in detail at this to test method, test result are as follows: adhesive force
It is 0 grade, 60 ° of gloss are 90.8, and resistance to marring is preferably.
Design focal point of the invention is: coating is prepared by using inventive formulation and method, is applied to automobile
The coating of accessory greatlys improve scratch resistance energy after coating under the premise of guaranteeing to have preferable adhesive force, and glossiness is also more
It is good, belong to high brilliant black, meets the needs used, and use ketone and esters solvent, VOC emission can be effectively reduced, VOC emission
It is extremely low, comply fully with environmental protection standard.
The technical principle of the invention is described above in combination with a specific embodiment.These descriptions are intended merely to explain of the invention
Principle, and shall not be construed in any way as a limitation of the scope of protection of the invention.Based on the explanation herein, the technology of this field
Personnel can associate with other specific embodiments of the invention without creative labor, these modes are fallen within
Within protection scope of the present invention.
Claims (5)
1. a kind of anti scuffing piano black paint, it is characterised in that: include following materials in percentage by mass: acrylic resin 60-
65%;OH base Hydroxylated acrylic resin 15-20%;Scratch resistance agent 1-2%;Nano color paste 10-12%;Remaining is molten for ketone and esters
Agent.
2. anti scuffing piano black paint as described in claim 1, it is characterised in that: the acrylic resin includes following matter
Measure percentage raw material: methyl methacrylate 5-8%;Styrene 18-20%;Butyl acrylate 21-23%;- 2 hydroxyl of methacrylic acid
Ethyl ester 2-4%;Ethyl acrylate 8-10%, acrylic acid 6-8%;Ethylene glycol dimethacrylate 4-5%;Dipropylene glycol methyl ether
5-8%;Initiator 2-3%;N, N dimethyl ethanol amine 4-5%;Remaining is deionized water.
3. anti scuffing piano black paint as claimed in claim 2, it is characterised in that: the methyl methacrylate, styrene,
Butyl acrylate, -2 hydroxyl ethyl ester of methacrylic acid, ethyl acrylate, acrylic acid, ethylene glycol dimethacrylate, dipropylene glycol
The purity of methyl ether, initiator and N, N dimethyl ethanol amine are all larger than 99.5%.
4. anti scuffing piano black paint as claimed in claim 2, it is characterised in that: the initiator draws for organic peroxide
Send out agent.
5. a kind of preparation method of anti scuffing piano black paint according to any one of claims 1-4, which is characterized in that including
There are following steps:
(1) using acrylic resin as substrate, be added OH base Hydroxylated acrylic resin, at 45-50 DEG C with blender first with
The revolving speed of 1500rpm stirs 15 minutes, then mentions to 2000rpm and stirring 20 minutes, and material dispersion is uniform;
(2) nano color paste and scratch resistance agent are sequentially added at 30-35 DEG C, is stirred 20 minutes with the revolving speed of 1000rpm;
(3) ketone and esters solvent are added at 25-30 DEG C, is dispersed with the revolving speed of 800rpm.
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CN201910629592.6A CN110343436A (en) | 2019-07-12 | 2019-07-12 | Anti scuffing piano black paint and preparation method thereof |
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CN201910629592.6A CN110343436A (en) | 2019-07-12 | 2019-07-12 | Anti scuffing piano black paint and preparation method thereof |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114773934A (en) * | 2022-05-05 | 2022-07-22 | 雅图高新材料股份有限公司 | Single-component piano black paint and preparation method thereof |
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US20040214942A1 (en) * | 2003-03-03 | 2004-10-28 | Jos Huybrechts | Two-component coating compositions |
CN103497606A (en) * | 2013-10-14 | 2014-01-08 | 湖南湘江关西涂料有限公司 | Mark eliminating agent for repairing automobile body and bumper and preparation method of mark eliminating agent |
CN109081884A (en) * | 2018-06-20 | 2018-12-25 | 中山大桥化工集团有限公司 | A kind of cross-linking modified high glaze water-based acrylic resin and preparation method thereof |
-
2019
- 2019-07-12 CN CN201910629592.6A patent/CN110343436A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040214942A1 (en) * | 2003-03-03 | 2004-10-28 | Jos Huybrechts | Two-component coating compositions |
CN103497606A (en) * | 2013-10-14 | 2014-01-08 | 湖南湘江关西涂料有限公司 | Mark eliminating agent for repairing automobile body and bumper and preparation method of mark eliminating agent |
CN109081884A (en) * | 2018-06-20 | 2018-12-25 | 中山大桥化工集团有限公司 | A kind of cross-linking modified high glaze water-based acrylic resin and preparation method thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN114773934A (en) * | 2022-05-05 | 2022-07-22 | 雅图高新材料股份有限公司 | Single-component piano black paint and preparation method thereof |
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