CN110331345A - 600MPa grades of low yield strength ratio high-performance building steel plates and its production method - Google Patents

600MPa grades of low yield strength ratio high-performance building steel plates and its production method Download PDF

Info

Publication number
CN110331345A
CN110331345A CN201910636735.6A CN201910636735A CN110331345A CN 110331345 A CN110331345 A CN 110331345A CN 201910636735 A CN201910636735 A CN 201910636735A CN 110331345 A CN110331345 A CN 110331345A
Authority
CN
China
Prior art keywords
steel plate
production method
steel
temperature
yield strength
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910636735.6A
Other languages
Chinese (zh)
Inventor
王强
尹绍江
郑治秀
臧淼
张阔斌
杨小龙
薛强
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TANGSHAN ZHONGHOU BOARD MATERIALS CO Ltd
Tangshan Iron and Steel Group Co Ltd
HBIS Co Ltd Tangshan Branch
Original Assignee
TANGSHAN ZHONGHOU BOARD MATERIALS CO Ltd
Tangshan Iron and Steel Group Co Ltd
HBIS Co Ltd Tangshan Branch
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by TANGSHAN ZHONGHOU BOARD MATERIALS CO Ltd, Tangshan Iron and Steel Group Co Ltd, HBIS Co Ltd Tangshan Branch filed Critical TANGSHAN ZHONGHOU BOARD MATERIALS CO Ltd
Priority to CN201910636735.6A priority Critical patent/CN110331345A/en
Publication of CN110331345A publication Critical patent/CN110331345A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/04Removing impurities by adding a treating agent
    • C21C7/06Deoxidising, e.g. killing
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/10Handling in a vacuum
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/48Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/50Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/58Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/002Bainite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/005Ferrite

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

The invention discloses a kind of 600MPa grades of low yield strength ratio high-performance building steel and its production method, the chemical components of the construction(al)steel are as follows: C, Si, Mn, Als, S, P, Cr, Ni, Cu, Nb, Ti, remaining is Fe and inevitable impurity;The technological process of production of the steel plate are as follows: molten iron pretreatment → converter → LF refining → RH application of vacuum → slab slow cooling → rolling → steel plate heap is cold → examine storage.Present invention process process is short, and steel plate removes heat treatment procedure from the delivery of TMCP state, at low cost, and the steel plate has high intensity, low yield strength ratio, antidetonation, excellent corrosion resistance etc., and product has high added value.

Description

600MPa grades of low yield strength ratio high-performance building steel plates and its production method
Technical field
The invention belongs to metallurgical manufacturing fields, and in particular to a kind of 600MPa grades of low yield strength ratio high-performance building steel plate and Its production method.
Background technique
Cut deal product is widely used in high building structure, bridge, boilers and pressure vessel and its Marine engineering.Currently, Steel building has been widely used in workshop building, civil buildings and public building, in the prior art, equipment condition Under, high-performance building steel is developed, it is made to play the hot spot that bigger effect is current building trade concern in economic development Problem.
Currently, steel building is widely popularized at home, but it uses steel grade substantially based on 345 intensity ranks, part If Bird's Nest, Hangzhou Asian Games main venue have used 460 intensity ranks, 500GJ also never by engineer application, use by high-strength building structure Steel requires lower yield tensile ratio, has overload-resistant, anti-seismic performance and corrosion resistance.
Q500GJ, Q550GJ are included in this specification for the first time by GB/T 19879-2015 new edition, in the near future, high-strength to build Building will can be applied in terms of long span building engineering with steel.Currently, the Q500GJE of correlation intensity is mainly handed over quenched and tempered state Goods, compared with TMCP state, due to increasing heat treatment procedure, process is increasingly complex, and production cost is higher.Bulletin The invention " a kind of Q500GJD quenched and tempered state cast structure steel plate and its manufacturing method " of CN201710685006, it and it is of the invention Q500GJE the difference is that: (1) be it is complicated using quenched and tempered state production technology, long flow path is heat-treated at high cost;(2) impact etc. Grade is D grades, can not be applied under -40 DEG C of environment;(3) do not have excellent corrosion resisting property, needed in steel construction processing use process Do corrosion-inhibiting coating processing.
Summary of the invention
The purpose of the present invention is develop a kind of 600MPa grades to have low yield strength ratio, corrosion resistance, low-temperature flexibility contour additional The high-performance building structure that value is integrated Q500GJE steel and its low cost, the production method of short route.
The technical solution used in the present invention is:
A kind of 600MPa grades of low yield strength ratio high-performance building steel, the chemical component of the steel plate is C by mass percentage: 0.08~0.12, Si:0.20~0.30, Mn:1.40~1.60, Als:0.020~0.035, S≤0.010, P≤0.012, Cr: 0.30~0.50, Ni:0.17~0.22, Cu:0.25~0.32, Nb:0.020~0.040, Ti:0.015~0.025, remaining is Fe and inevitable impurity;Its trade mark is Q500GJE, and the condition of delivery is TMCP state.Als is dissolved aluminum.
20~40mm of building sheet thickness of the present invention, organization type are the acicular ferrite+island bainite+M-A structure At line and staff control, and the island M-A organize area percent≤2%.550~580MPa of its yield strength, tensile strength 680~ 720MPa, elongation >=20%;Yield tensile ratio≤0.85, -40 DEG C of ballistic works are more than or equal to 120J, value >=6.0 corrosion resistance index I.
The production method of steel plate of the present invention, including following process: molten iron pretreatment → converter → LF refining → RH is true Vacancy reason → slab slow cooling → rolling → steel plate heap is cold → examine storage.
Further, converter procedure of the present invention, is smelted using top and bottom complex blowing, converter terminal C≤0.06%, [C%] [O%] concentration product≤0.0024%, tapping process use the strong deoxidation of Al, and whole Argon stirring promotes deoxidation products floating removal.
Further, LF refining and RH application of vacuum process of the present invention, using LF+RH duplex refining treatment, molten steel Temperature >=1580 DEG C, total oxygen are less than 25ppm, hydrogen content≤2ppm, and the soft blow time >=10min carries out after RH vacuum breaker feeding at calcium Reason, to Al2O3Type impurity carries out Metamorphism treatment.
Further, slab slow cooling operation of the present invention, use Slab Caster production casting blank cross-section size for 280*1800mm, 0.85~0.95m/min of casting machine pulling rate stability contorting;Using electromagnetic agitation, slab equiaxial crystal ratio is improved, is used 30mm technique under the stagnation pressure of casting blank solidification forward position promotes slab consistency, is effectively improved inherent quality, the offline slow cooling of slab;
Further, rolling process of the present invention, blank heating is to 1200 DEG C, in furnace duration >=250min, using heating furnace Fast burning+high pressure water dephosphorization, effectively solves the problems, such as that copper bearing steel dephosphorization is not clean, plate surface quality is excellent;
Using roughing+finish rolling Stand Mill rolling, roughing start rolling temperature >=1020 DEG C, rough rolling step uses heavy reduction, guarantees thick It rolls single pass rolling reduction >=25mm, guarantees the ferrite crystal grain for obtaining fine uniform, to temperature thickness according to 2~3 times of finished product thicknesses, Steel speed 1m/s is thrown in finish rolling finishing temperature≤800 DEG C;
Further, steel plate heap cooling working procedure of the present invention rolls rear relaxation time 15s, using cold water-spraying control, opens cold temperature 750 DEG C~780 DEG C, final cooling temperature≤650 DEG C.
Further, inspection of the present invention is put in storage process, is covered using high temperature resistant tarpaulin, the hydrogen being released effectively in steel, Slow cooling 36 hours, ultrasonic examination grade reached I grades, storage.
Beneficial effects of the present invention:
Process flow of the present invention is short, at low cost, and steel plate has low yield strength ratio antidetonation, superior low-temperature toughness and corrosion-resistant height additional Value.
Detailed description of the invention
Fig. 1 is the steel plate metallographic structure figure of the embodiment of the present invention 1.
Specific embodiment
Present invention is further described in detail with reference to embodiments.
Embodiment 1
A kind of 600MPa grades of low yield strength ratio high-performance building steel and its production method are as described below.
Steel grade number is Q500GJE, steel plate thickness 20mm in this production.
The technological process of production of this thickness steel plate are as follows: molten iron pretreatment → converter → LF refining → RH application of vacuum → slab Slow cooling → rolling → steel plate heap is cold → examine storage.
The 20mm thickness Q500GJE chemical component is calculated as according to mass percent: C:0.12, Si:0.20, Mn:1.60, Als:0.025, S:0.002, P:0.010, Cr:0.30, Ni:0.20, Cu:0.30, Nb:0.025, Ti:0.018, remaining is Fe And inevitable impurity.
Converter procedure of the present invention, is smelted using top and bottom complex blowing, converter terminal C=0.06%, [C%] [O%] concentration product 0.0022%, tapping process uses the strong deoxidation of Al, and whole Argon stirs 30min, promotes deoxidation products to float and removes;
Refining procedure of the present invention, using LF+RH duplex refining treatment, effective control composition meets 20mm Q500GJE requirement And 1580 DEG C of liquid steel temperature, total oxygen 23ppm after RH application of vacuum, hydrogen content 2ppm, soft blow time 15min, RH vacuum breaker is laggard Row feeds Calcium treatment, and calcium content reaches 20ppm in steel, to Al2O3Type impurity carries out Metamorphism treatment;
Continuous casting working procedure of the present invention uses Slab Caster production casting blank cross-section size for 280*1800mm, and casting machine is drawn Fast stability contorting 0.85m/min;Using electromagnetic agitation, electric current 400A, frequency 5Hz effectively improve slab equiaxial crystal ratio, using casting 30mm technique under base solidification front stagnation pressure promotes slab consistency, is effectively improved inherent quality;
Heating process of the present invention, blank heating is to 1200 DEG C, in furnace duration 255min, using heating furnace burning+high pressure water fastly Dephosphorization >=20MPa effectively solves the problems, such as that copper bearing steel dephosphorization is not clean, and plate surface quality is excellent;
Rolling mill practice of the present invention is rolled, 1050 DEG C of roughing start rolling temperature, rough rolling step list using roughing+finish rolling Stand Mill Reduction in pass >=25mm 790 DEG C of finishing temperature, throws steel speed 1m/s, rolls rear relaxation time 15s to temperature thickness according to 50mm, Using ultrafast cold water-spraying control, 760 DEG C of cold temperature is opened, 630 DEG C of final cooling temperature.
The offline slow cooling of steel plate of the present invention, is covered using high temperature tarpaulin, and slow cooling 36 hours, ultrasonic examination grade reached I grades.Mechanical property of steel plate testing result is shown in Table 1, metallographic structure (acicular ferrite+island bainite+M-A line and staff control, wherein M- Organize area percentage≤2% in the island A) such as Fig. 1.
Embodiment 2
A kind of 600MPa grades of low yield strength ratio high-performance building steel and its production method are as described below.
Steel grade number is Q500GJEZ15, steel plate thickness 40mm in this production.
The technological process of production of this thickness steel plate are as follows: molten iron pretreatment → converter → LF refining → RH application of vacuum → slab Slow cooling → rolling → steel plate heap is cold → examine storage.
The 40mm thickness Q500GJEZ15 chemical component is calculated as according to mass percent: C:0.08, Si:0.30, Mn: 1.40, Als:0.035, S:0.003, P:0.009, Cr:0.50, Ni:0.22, Cu:0.25, Nb:0.040, Ti:0.025, remaining For Fe and inevitable impurity.
Converter procedure of the present invention, is smelted using top and bottom complex blowing, converter terminal C=0.045%, [C%] [O%] concentration product 0.0023%, tapping process uses the strong deoxidation of Al, and whole Argon stirs 35min, promotes deoxidation products to float and removes;
Refining procedure of the present invention, using LF+RH duplex refining treatment, effective control composition and 1585 DEG C of liquid steel temperature, RH Total oxygen 20ppm after vacuum processing, hydrogen content 1.8ppm carry out after soft blow time 13min, RH vacuum breaker feeding Calcium treatment, calcium in steel Content reaches 18ppm, carries out Metamorphism treatment to Al2O3 type impurity;
Continuous casting working procedure of the present invention uses Slab Caster production casting blank cross-section size for 280*1800mm, and casting machine is drawn Fast stability contorting 0.95m/min;Using electromagnetic agitation, electric current 400A, frequency 5Hz effectively improve slab equiaxial crystal ratio, using casting 30mm technique under base solidification front stagnation pressure promotes slab consistency, is effectively improved inherent quality;
Heating process of the present invention, blank heating is to 1200 DEG C, in furnace duration 260min, using heating furnace burning+high pressure water fastly Dephosphorization >=20MPa effectively solves the problems, such as that copper bearing steel dephosphorization is not clean, and plate surface quality is excellent;
Rolling mill practice of the present invention is rolled, 1080 DEG C of roughing start rolling temperature, rough rolling step list using roughing+finish rolling Stand Mill Reduction in pass >=25mm 780 DEG C of finishing temperature, throws steel speed 1m/s, rolls rear relaxation time to temperature thickness according to 100mm 15s opens 750 DEG C of cold temperature using ultrafast cold water-spraying control, and 600 DEG C of final cooling temperature.
The offline slow cooling of steel plate of the present invention, is covered using high temperature tarpaulin, and slow cooling 48 hours, ultrasonic examination grade reached I grades.Mechanical property of steel plate testing result is shown in Table 1.
Embodiment 3
A kind of 600MPa grades of low yield strength ratio high-performance building steel and its production method are as described below.
Steel grade number is Q500GJEZ15, steel plate thickness 25mm in this production.
The technological process of production of this thickness steel plate are as follows: molten iron pretreatment → converter → LF refining → RH application of vacuum → slab Slow cooling → rolling → steel plate heap is cold → examine storage.
The 25mm thickness Q500GJEZ15 chemical component is calculated as according to mass percent: C:0.09, Si:0.28, Mn: 1.46, Als:0.031, S:0.002, P:0.010, Cr:0.40, Ni:0.20, Cu:0.28, Nb:0.032, Ti:0.020, remaining For Fe and inevitable impurity.
Converter procedure of the present invention, is smelted using top and bottom complex blowing, converter terminal C=0.055%, [C%] [O%] concentration product 0.0024%, tapping process uses the strong deoxidation of Al, and whole Argon stirs 35min, promotes deoxidation products to float and removes;
Refining procedure of the present invention, using LF+RH duplex refining treatment, effective control composition and 1590 DEG C of liquid steel temperature, RH Total oxygen 20ppm after vacuum processing, hydrogen content 1.8ppm carry out after soft blow time 14min, RH vacuum breaker feeding Calcium treatment, calcium in steel Content reaches 18ppm, carries out Metamorphism treatment to Al2O3 type impurity;
Continuous casting working procedure of the present invention uses Slab Caster production casting blank cross-section size for 280*1800mm, and casting machine is drawn Fast stability contorting 0.95m/min;Using electromagnetic agitation, electric current 400A, frequency 5Hz effectively improve slab equiaxial crystal ratio, using casting 30mm technique under base solidification front stagnation pressure promotes slab consistency, is effectively improved inherent quality;
Heating process of the present invention, blank heating is to 1200 DEG C, in furnace duration 275min, using heating furnace burning+high pressure water fastly Dephosphorization >=20MPa effectively solves the problems, such as that copper bearing steel dephosphorization is not clean, and plate surface quality is excellent;
Rolling mill practice of the present invention is rolled, 1080 DEG C of roughing start rolling temperature, rough rolling step list using roughing+finish rolling Stand Mill Reduction in pass >=25mm 785 DEG C of finishing temperature, throws steel speed 1m/s, rolls rear relaxation time to temperature thickness according to 100mm 15s opens 760 DEG C of cold temperature using ultrafast cold water-spraying control, and 590 DEG C of final cooling temperature.
The offline slow cooling of steel plate of the present invention, is covered using high temperature tarpaulin, and slow cooling 48 hours, ultrasonic examination grade reached I grades.Mechanical property of steel plate testing result is shown in Table 1.
Embodiment 4
A kind of 600MPa grades of low yield strength ratio high-performance building steel and its production method are as described below.
Steel grade number is Q500GJEZ15, steel plate thickness 35mm in this production.
The technological process of production of this thickness steel plate are as follows: molten iron pretreatment → converter → LF refining → RH application of vacuum → slab Slow cooling → rolling → steel plate heap is cold → examine storage.
The 35mm thickness Q500GJEZ15 chemical component is calculated as according to mass percent: C:0.11, Si:0.30, Mn: 1.60, Als:0.035, S:0.003, P:0.009, Cr:0.50, Ni:0.22, Cu:0.30, Nb:0.035, Ti:0.018, remaining For Fe and inevitable impurity.
Converter procedure of the present invention, is smelted using top and bottom complex blowing, converter terminal C=0.050%, [C%] [O%] concentration product 0.0022%, tapping process uses the strong deoxidation of Al, and whole Argon stirs 25min, promotes deoxidation products to float and removes;
Refining procedure of the present invention, using LF+RH duplex refining treatment, effective control composition and liquid steel temperature, at RH vacuum Total oxygen 18ppm after reason, hydrogen content 1.4ppm carry out after soft blow time 15min, RH vacuum breaker feeding Calcium treatment, and calcium content reaches in steel To 28ppm, Metamorphism treatment is carried out to Al2O3 type impurity;
Continuous casting working procedure of the present invention uses Slab Caster production casting blank cross-section size for 280*1800mm, and casting machine is drawn Fast stability contorting 0.95m/min;Using electromagnetic agitation, electric current 400A, frequency 5Hz effectively improve slab equiaxial crystal ratio, using casting 30mm technique under base solidification front stagnation pressure promotes slab consistency, is effectively improved inherent quality;
Heating process of the present invention, blank heating is to 1200 DEG C, in furnace duration 265min, using heating furnace burning+high pressure water fastly Dephosphorization >=20MPa effectively solves the problems, such as that copper bearing steel dephosphorization is not clean, and plate surface quality is excellent;
Rolling mill practice of the present invention is rolled, 1050 DEG C of roughing start rolling temperature, rough rolling step list using roughing+finish rolling Stand Mill Reduction in pass >=25mm 770 DEG C of finishing temperature, throws steel speed 1m/s, rolls rear relaxation time to temperature thickness according to 105mm 20s opens 770 DEG C of cold temperature using ultrafast cold water-spraying control, and 580 DEG C of final cooling temperature.
The offline slow cooling of steel plate of the present invention, is covered using high temperature tarpaulin, and slow cooling 48 hours, ultrasonic examination grade reached I grades.Mechanical property of steel plate testing result is shown in Table 1.
Results of property table table 1

Claims (9)

1.600MPa grades of low yield strength ratio high-performance building steel plates, it is characterised in that: the chemical component of the steel plate presses quality hundred Ratio is divided to be calculated as, C:0.08~0.12%, Si:0.20~0.30%, Mn:1.40~1.60%, Als:0.020~0.035%, S≤ 0.010%, P≤0.012%, Cr:0.30~0.50%, Ni:0.17~0.22%, Cu:0.25~0.32%, Nb:0.020~ 0.040%, Ti:0.015~0.025:, surplus is Fe and inevitable impurity;Its trade mark is Q500GJE, and the condition of delivery is TMCP state.
2. 600MPa grades of low yield strength ratio high-performance building steel plate according to claim 1, which is characterized in that organization type For the line and staff control that the acicular ferrite+island bainite+M-A is constituted, and area percent≤2% is organized on the island M-A.
3. a kind of production method of 600MPa of any of claims 1 or 2 grades of low yield strength ratios high-performance building steel plate, feature It is, including following process: molten iron pretreatment → converter → LF refining → RH application of vacuum → slab slow cooling → rolling → steel plate Heap is cold → examine storage.
4. production method according to claim 3, which is characterized in that the converter procedure: using top and bottom combined blown converter smelting, turn Furnace terminal C≤0.06%, [C%] [O%] concentration product≤0.0024%, tapping process use the strong deoxidation of Al, whole Argon stirring.
5. production method according to claim 3, which is characterized in that the LF refining and RH application of vacuum process: using LF+RH Duplex refining treatment, liquid steel temperature >=1580 DEG C, total oxygen are less than 25ppm, hydrogen content≤2ppm.
6. production method according to claim 3, which is characterized in that the slab slow cooling operation: using Slab Caster Production casting blank cross-section size is 280*1800mm, 0.85~0.95m/min of casting machine pulling rate stability contorting;Using electromagnetic agitation and again Depress 30mm technique, the offline slow cooling of slab.
7. production method according to claim 3, which is characterized in that the rolling process: blank heating is to 1200 DEG C, in furnace Length >=250min is rolled, roughing start rolling temperature >=1020 DEG C using roughing and finish rolling Stand Mill, to temperature thickness according to 2~3 times at Steel speed 1m/s is thrown in product thickness, finish rolling finishing temperature≤800 DEG C.
8. production method according to claim 3, which is characterized in that the steel plate heap cooling working procedure: using cold water-spraying control, open cold 750 DEG C~780 DEG C of temperature, final cooling temperature≤650 DEG C.
9. production method according to claim 3, which is characterized in that the inspection is put in storage process: the offline slow cooling of steel plate, using covering with mat Cloth covers, and after slow cooling 36 hours expire, steel plate examines storage.
CN201910636735.6A 2019-07-15 2019-07-15 600MPa grades of low yield strength ratio high-performance building steel plates and its production method Pending CN110331345A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910636735.6A CN110331345A (en) 2019-07-15 2019-07-15 600MPa grades of low yield strength ratio high-performance building steel plates and its production method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910636735.6A CN110331345A (en) 2019-07-15 2019-07-15 600MPa grades of low yield strength ratio high-performance building steel plates and its production method

Publications (1)

Publication Number Publication Date
CN110331345A true CN110331345A (en) 2019-10-15

Family

ID=68145084

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910636735.6A Pending CN110331345A (en) 2019-07-15 2019-07-15 600MPa grades of low yield strength ratio high-performance building steel plates and its production method

Country Status (1)

Country Link
CN (1) CN110331345A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111172465A (en) * 2020-02-28 2020-05-19 鞍钢股份有限公司 Low-carbon equivalent large-thickness Q390GJ steel plate for building structure and manufacturing method thereof
CN111793777A (en) * 2020-08-20 2020-10-20 山东华星新材料科技有限公司 1000 MPa-level hot-rolled high-strength corrosion-resistant dual-phase steel plate and preparation method thereof
CN113684417A (en) * 2021-07-19 2021-11-23 中国科学院金属研究所 Economical 690 MPa-level low-alloy corrosion-resistant refractory steel
CN115198193A (en) * 2022-07-28 2022-10-18 湖南华菱湘潭钢铁有限公司 TMCP (thermal mechanical control processing) process extra-thick specification offshore wind power steel EH36 and production method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20160122844A1 (en) * 2013-06-19 2016-05-05 Baoshan Iron & Steel Co., Ltd. Ht550 steel plate with ultrahigh toughness and excellent weldability and manufacturing method of the same
CN106995905A (en) * 2015-11-09 2017-08-01 Posco公司 The excellent building structural steel material of flatness and its manufacture method
CN107385329A (en) * 2017-06-30 2017-11-24 江阴兴澄特种钢铁有限公司 A kind of big thickness Q500GJE high-strength buildings structural steel plate and its manufacture method
CN108315666A (en) * 2018-02-12 2018-07-24 舞阳钢铁有限责任公司 Low-welding crack-sensitive Q500GJE steel plates and its production method
CN109457097A (en) * 2018-12-11 2019-03-12 唐山中厚板材有限公司 A kind of production method of think gauge high-strength steel plate

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20160122844A1 (en) * 2013-06-19 2016-05-05 Baoshan Iron & Steel Co., Ltd. Ht550 steel plate with ultrahigh toughness and excellent weldability and manufacturing method of the same
CN106995905A (en) * 2015-11-09 2017-08-01 Posco公司 The excellent building structural steel material of flatness and its manufacture method
CN107385329A (en) * 2017-06-30 2017-11-24 江阴兴澄特种钢铁有限公司 A kind of big thickness Q500GJE high-strength buildings structural steel plate and its manufacture method
CN108315666A (en) * 2018-02-12 2018-07-24 舞阳钢铁有限责任公司 Low-welding crack-sensitive Q500GJE steel plates and its production method
CN109457097A (en) * 2018-12-11 2019-03-12 唐山中厚板材有限公司 A kind of production method of think gauge high-strength steel plate

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111172465A (en) * 2020-02-28 2020-05-19 鞍钢股份有限公司 Low-carbon equivalent large-thickness Q390GJ steel plate for building structure and manufacturing method thereof
CN111172465B (en) * 2020-02-28 2021-07-20 鞍钢股份有限公司 Low-carbon equivalent large-thickness Q390GJ steel plate for building structure and manufacturing method thereof
CN111793777A (en) * 2020-08-20 2020-10-20 山东华星新材料科技有限公司 1000 MPa-level hot-rolled high-strength corrosion-resistant dual-phase steel plate and preparation method thereof
CN113684417A (en) * 2021-07-19 2021-11-23 中国科学院金属研究所 Economical 690 MPa-level low-alloy corrosion-resistant refractory steel
CN115198193A (en) * 2022-07-28 2022-10-18 湖南华菱湘潭钢铁有限公司 TMCP (thermal mechanical control processing) process extra-thick specification offshore wind power steel EH36 and production method thereof

Similar Documents

Publication Publication Date Title
CN107419180B (en) A kind of the electrogalvanizing cold-rolled steel sheet and production method of yield strength >=250MPa
CN112981235B (en) Hardened and tempered steel plate with yield strength of 420MPa grade for building structure and production method thereof
CN110331345A (en) 600MPa grades of low yield strength ratio high-performance building steel plates and its production method
CN107326268B (en) A kind of economical deep-draw cold rolling Steel for enamel and production method
CN113481430B (en) 800 MPa-grade boron-containing hot-dip galvanized dual-phase steel with enhanced hole expansion performance and production method thereof
CN107475625B (en) A kind of the electrogalvanizing cold-rolled steel sheet and production method of yield strength >=350MPa
CN110273108A (en) A kind of deep-draw grade electrogalvanizing hot rolling acid-cleaning steel plate and its production method
CN112011737B (en) 390 MPa-grade-20-DEG C-resistant hot-rolled angle steel for bridge structure and production method thereof
CN107557678A (en) Inexpensive 550MPa levels hot rolling container weathering steel and its manufacture method
CN109182919A (en) A kind of production method of heterogeneous structure high-toughness ship plate steel EH47
CN104805352A (en) Production method of cold-rolled steel plate for electro-galvanization
CN104018064B (en) The production method of low cost Q345R steel plate
CN109182702A (en) A kind of production method of heterogeneous structure high-toughness ship plate steel EH40
CN113846260B (en) Production method of high-strength steel plate for engineering machinery
CN110551939A (en) Hot-dip galvanized steel plate with yield strength of 320MPa and production method thereof
CN109385576A (en) A kind of inexpensive X65 pipe line steel and its manufacturing method based on magnesium processing
CN110923550A (en) Hot-rolled structural steel with high surface quality, high strength and toughness produced by adopting short process and production method
CN109136752A (en) A kind of 420MPa grades of low yield strength ratio bridge steel plate of resistance to sea atmosphere corrosion and its production method
CN114196884B (en) 400 MPa-grade microalloyed corrosion-resistant reinforcing steel bar and production method thereof
CN107236905A (en) 600MPa grade high-strength low yield strength ratio structural steel and irons and its manufacture method
CN109355567A (en) A kind of low cost Q390D steel plate and preparation method thereof
CN104131238B (en) High molding high durable Ultra-thin hot rolled steel plate and CSP production technology thereof
CN113528936A (en) Method for producing hot-rolled H-shaped steel for DH36 ocean engineering structure by adopting special-shaped blank
CN110607476A (en) Manufacturing method of cold-rolled hot-galvanized high-strength structural steel with yield strength of 350MPa
CN113584375B (en) 600 MPa-grade low-manganese nickel-containing alloying hot-dip galvanized dual-phase steel with enhanced hole expansion performance and production method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20191015

RJ01 Rejection of invention patent application after publication