CN110330836A - A kind of ink and preparation method thereof for tempered glass - Google Patents
A kind of ink and preparation method thereof for tempered glass Download PDFInfo
- Publication number
- CN110330836A CN110330836A CN201910672263.XA CN201910672263A CN110330836A CN 110330836 A CN110330836 A CN 110330836A CN 201910672263 A CN201910672263 A CN 201910672263A CN 110330836 A CN110330836 A CN 110330836A
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- parts
- tempered glass
- ink
- bismuth
- glass
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
Abstract
The ink and preparation method thereof that the invention discloses a kind of for tempered glass, this is used for the ink of tempered glass, by weight, the raw material of the ink for being used for tempered glass is made of 20-35 parts of inorganic pigment, 15-35 parts of bismuth glass powder, 15-30 parts of n-tridecane, 6-10 parts of petroleum ether, 2-4 parts of dispersing agent, anti-settling wax 0.2-0.5 parts；Wherein, bismuth glass powder is made of bismuth oxide, boric acid, lithium metasilicate, sodium metasilicate, calcium oxide, phosphotungstic acid, isobutyl phenylacetate；The ink for being used for tempered glass can be applied on tempered glass and have the advantages that easily dispersion was not reunited, while the preparation method has the advantages that process is simply and easy to operate.
Description
Technical field
The present invention relates to tempered glass technical field of ink, a kind of ink for tempered glass and its preparation are particularly related to
Method.
Background technique
Tempered glass is to form compression in glass surface, glass bears first when external force by method chemically or physically
Skin stress is first offset, to improve bearing capacity, enhances glass itself wind pressure, cold and heat, impact etc.；With peace
The advantages that Quan Xing, high intensity, thermal stability, it is widely used in building, decoration, furniture manufacturing industry, electronics, auto manufacturing, day
Articles industry, special trade (military project use).Compared with simple glass, tempered glass has certain advantage in performance, still
It is that transparency, decorative effect are poor, strongly limits its application field.
In the prior art, although there are ink-jet printing ink, the connection of the ink and glass surface is that surface is attached
, belong to physical absorption range, adhesive force is small, the defects of easily peeling；Pigment used in this kind of ink is organic pigment mostly simultaneously,
Easily fade, loss of properties on aging.
Summary of the invention
In view of this, it is an object of the invention to propose a kind of ink and preparation method thereof for tempered glass, the use
It can be applied on tempered glass in the ink of tempered glass and have the advantages that easily dispersion was not reunited, while the preparation method
Have the advantages that process is simply and easy to operate.
It is by weight, described to be used for steel based on a kind of above-mentioned purpose ink for tempered glass provided by the invention
Change the raw material of the ink of glass by 20-35 parts of inorganic pigment, 15-35 parts of bismuth glass powder, 15-30 parts of n-tridecane, petroleum ether 6-
10 parts, 2-4 parts of dispersing agent, anti-settling wax 0.2-0.5 parts of compositions；
Wherein, the bismuth glass powder is by bismuth oxide, boric acid, lithium metasilicate, sodium metasilicate, calcium oxide, phosphotungstic acid, phenylacetic acid
Isobutyl ester composition.
Optionally, by weight, the raw material of the ink for tempered glass is by 27-28 parts of inorganic pigment, bismuth glass
29-31 parts of glass powder, 29-30 parts of n-tridecane, 8-9 parts of petroleum ether, 3-4 parts of dispersing agent, anti-settling wax 0.25-0.35 parts of compositions.
Optionally, by weight, the bismuth glass powder is by 60-75 parts of bismuth oxide, 10-16 parts of boric acid, lithium metasilicate
4-6 parts, 4-6 parts of sodium metasilicate, 5-6 parts of calcium oxide, 1.0-1.8 parts of phosphotungstic acid compositions；Isobutyl phenylacetate in the bismuth glass powder
Content be 1.5 weight %-2.5 weight %.
Optionally, the inorganic pigment is selected from least one of cobalt aluminate, cobalt oxide, titanium oxide, iron oxide, corundum.
Optionally, the dispersing agent is selected from least one of polyurethane, barium stearate, zinc stearate.
Optionally, the boiling point of the petroleum ether is 60-90 DEG C.
Optionally, the purity of the bismuth oxide is not less than 60 weight %.
A kind of preparation method of the ink for tempered glass characterized by comprising
1) bismuth oxide, boric acid, lithium metasilicate, sodium metasilicate, calcium oxide, phosphotungstic acid are mixed, melting, cooling, crushing, sieve
Sorting takes partial size≤2000 mesh powders to carry out ball milling；Then isobutyl phenylacetate is sprayed into the mixture after ball milling to be modified
To obtain bismuth glass powder；
2) inorganic pigment, bismuth glass powder, n-tridecane, petroleum ether, dispersing agent, anti-settling wax are subjected to mixing dispersion, then
Grinding is carried out until system average grain diameter≤250nm, viscosity≤25mpas, then successively with 10 microns, 5 microns, 1 micron of copper
Screen filtration is to obtain the ink for being used for tempered glass.
Optionally, in step 1), relative to mixture after the screening of 30g, the time of the ball milling is 5-7h；
In step 1), relative to the mixture after 30g grinding, the penetrating time of the isobutyl phenylacetate is 30-
50min。
Optionally, in step 2), the time of the mixing dispersion is 20-40min.
From the above it can be seen that a kind of ink and preparation method thereof for tempered glass provided by the invention, this
The ink of invention is to use for reference ceramic ink to be sintered principle on ceramics, and the sintering temperature of ceramics is generally at 1200 DEG C or more,
And glass cannot withstand such temperature.Glass begins to modification between 680-720 DEG C, at such a temperature inorganic pigment surface
It not yet melts, therefore is not sintered glass surface.Glass powder can be used as the binding material of inorganic pigment thus, when sintering temperature
When degree reaches 680-700 DEG C or so, glass powder melting, wherein by inorganic pigment cladding, glass powder and glass surface sintering
Together, to have the function that inorganic pigment sintering in glass surface, realizes the decorative effect of the colorful multiplicity of glass surface.
But common sodium, potash glass powder surface are charge too strong, and when dispersion easily reunites, and wanting for industrial products and user is not achieved
It asks, the present invention has made dispersed excellent bismuth glass powder by oneself and easily divided in addition being surface-treated when preparing glass ink
It dissipates, and after storage 6 months, does not roll into a ball pump substantially, average particle size≤250nm complies fully with the requirement of inkjet printing.
Detailed description of the invention
Fig. 1 is a kind of tempered glass schematic diagram that ink printed of the embodiment of the present invention goes out；
Fig. 2 is another tempered glass schematic diagram that the embodiment of the present invention shows that ink printed goes out.
Specific embodiment
For below by the description to embodiment, for example related manufacturing process of a specific embodiment of the invention and operation
Application method etc., is described in further detail, to help those skilled in the art to inventive concept of the invention, technical solution
There is more complete, accurate and deep understanding.
The present invention provides a kind of inks for tempered glass, and by weight, this is used for the ink of tempered glass
Raw material is by 20-35 parts of inorganic pigment, 15-35 parts of bismuth glass powder, 15-30 parts of n-tridecane, 6-10 parts of petroleum ether, dispersing agent 2-4
Part, anti-settling wax 0.2-0.5 parts of compositions；
Wherein, bismuth glass powder is by bismuth oxide, boric acid, lithium metasilicate, sodium metasilicate, calcium oxide, phosphotungstic acid, phenylacetic acid isobutyl
Ester composition.
In the present invention, the dosage of each component of ink can change within the above range, but in order to further increase
The dispersibility of ink obtained, it is preferable that by weight, this is used for the raw material of the ink of tempered glass by inorganic pigment 27-
28 parts, 29-31 parts of bismuth glass powder, 29-30 parts of n-tridecane, 8-9 parts of petroleum ether, 3-4 parts of dispersing agent, anti-settling wax 0.25-0.35
Part composition.
In the present invention, the dosage of each component of bismuth glass powder can change within the above range, but in order to further
Improve the dispersibility of ink obtained, it is preferable that by weight, bismuth glass powder is by 60-75 parts of bismuth oxide, boric acid 10-
16 parts, 4-6 parts of lithium metasilicate, 4-6 parts of sodium metasilicate, 5-6 parts of calcium oxide, 1.0-1.8 parts of phosphotungstic acid compositions；Phenylacetic acid in bismuth glass powder
The content of isobutyl ester is 1.5 weight %-2.5 weight %.
In the present invention, the specific type of inorganic pigment can change within the above range, but in order to further increase
The dispersibility of ink obtained, it is preferable that inorganic pigment in cobalt aluminate, cobalt oxide, titanium oxide, iron oxide, corundum extremely
Few one.
In the present invention, the specific type of dispersing agent can change within the above range, but in order to further increase system
The dispersibility of the ink obtained, it is preferable that dispersing agent is selected from least one of polyurethane, barium stearate, zinc stearate.
In the present invention, the specific type of petroleum ether can change within the above range, but in order to further increase system
The dispersibility of the ink obtained, it is preferable that the boiling point of petroleum ether is 60-90 DEG C.
In the present invention, the purity of bismuth oxide can change within the above range, but in order to further increase system
The dispersibility of the ink obtained, it is preferable that the purity of bismuth oxide is not less than 60 weight %.
The present invention also provides a kind of preparation methods such as the above-mentioned ink for tempered glass, which is characterized in that packet
It includes:
1) bismuth oxide, boric acid, lithium metasilicate, sodium metasilicate, calcium oxide, phosphotungstic acid are mixed, melting, cooling, crushing, sieve
Sorting takes partial size≤2000 mesh powders to carry out ball milling；Then isobutyl phenylacetate is sprayed into the mixture after ball milling to be modified
To obtain bismuth glass powder；
2) inorganic pigment, bismuth glass powder, n-tridecane, petroleum ether, dispersing agent, anti-settling wax are subjected to mixing dispersion, then
Grinding is carried out until system average grain diameter≤250nm, viscosity≤25mpas, then successively with 10 microns, 5 microns, 1 micron of copper
Screen filtration is to obtain the ink for tempered glass.
In the step 1) of above-mentioned preparation method, the time of ball milling can select in a wide range, but in order into one
Step improves the dispersibility of ink obtained, it is preferable that in step 1), relative to mixture after the screening of 30g, the time of ball milling
For 5-7h.
In the step 1) of above-mentioned preparation method, the penetrating time of isobutyl phenylacetate can select in a wide range,
But in order to further increase the dispersibility of ink obtained, it is preferable that in step 1), relative to the mixing after 30g grinding
Object, the penetrating time of isobutyl phenylacetate are 30-50min.
In the step 2) of above-mentioned preparation method, the time for mixing dispersion can select in a wide range, but in order to
Further increase the dispersibility of ink obtained, it is preferable that in step 2), the time for mixing dispersion is 20-40min.
The present invention will be described in detail by way of examples below.
Embodiment 1
1) by bismuth oxide, boric acid, lithium metasilicate, sodium metasilicate, calcium oxide, phosphotungstic acid according to 65:13:5:5:5.5:1.5
Weight ratio mixing, melt 70 minutes at 1180 DEG C, is cooled to 40 DEG C or so, crushes, screening selection partial size≤2000 mesh powders
It carries out making powder reach submicron order in ball milling 6 hours；Then isobutyl phenylacetate being sprayed into the mixture after ball milling, (30g is mixed
Object is closed, spray not less than 30 minutes) it is modified that (content of isobutyl phenylacetate is 2 in bismuth glass powder to obtain bismuth glass powder
Weight %)；
2) by 27.00g inorganic pigment (cobalt aluminate), 30.70g bismuth glass powder, 30.00g n-tridecane, 8.00g petroleum ether
(60-90 DEG C), 4.00g dispersing agent (polyurethane, barium stearate, zinc stearate), the anti-settling wax of 0.30g carry out mixing dispersion 30min,
Then grinding is carried out until system average grain diameter≤250nm, viscosity≤25mpas, then successively with 10 microns, 5 microns, 1 is micro-
Rice brass wire cloth filtering is to obtain the ink for tempered glass.
Embodiment 2
1) by bismuth oxide, boric acid, lithium metasilicate, sodium metasilicate, calcium oxide, phosphotungstic acid according to 60:10:4:4:5:1.0's
Weight ratio mixing, melt 60 minutes at 1180 DEG C, is cooled to 40 DEG C or so, crushes, screening selection partial size≤2000 mesh powders into
Powder is set to reach submicron order within row ball milling 6 hours；Then isobutyl phenylacetate (30g mixing is sprayed into the mixture after ball milling
Object spray not less than 30 minutes) it is modified that (content of isobutyl phenylacetate is 1.5 in bismuth glass powder to obtain bismuth glass powder
Weight %)；
2) by 28.00g inorganic pigment (iron oxide), 29.70g bismuth glass powder, 30.00g n-tridecane, 8.00g petroleum ether
(60-90 DEG C), 4.00g dispersing agent (polyurethane, barium stearate, zinc stearate), the anti-settling wax of 0.30g carry out mixing dispersion 30min,
Then grinding is carried out until system average grain diameter≤250nm, viscosity≤25mpas, then successively with 10 microns, 5 microns, 1 is micro-
Rice brass wire cloth filtering is to obtain the ink for tempered glass.
Embodiment 3
1) by bismuth oxide, boric acid, lithium metasilicate, sodium metasilicate, calcium oxide, phosphotungstic acid according to 75:16:6:6:6:1.8's
Weight ratio mixing, melt 90 minutes at 1180 DEG C, is cooled to 40 DEG C or so, crushes, screening selection partial size≤2000 mesh powders into
Powder is set to reach submicron order within row ball milling 6 hours；Then isobutyl phenylacetate (30g mixing is sprayed into the mixture after ball milling
Object spray not less than 30 minutes) it is modified that (content of isobutyl phenylacetate is 1.5 in bismuth glass powder to obtain bismuth glass powder
Weight %-2.5 weight %)；
2) by 28.00g inorganic pigment (corundum), 29.70g bismuth glass powder, 29.00g n-tridecane, 9.00g petroleum ether
(60-90 DEG C), 4.00g dispersing agent (polyurethane, barium stearate, zinc stearate), the anti-settling wax of 0.30g carry out mixing dispersion 30min,
Then grinding is carried out until system average grain diameter≤250nm, viscosity≤25mpas, then successively with 10 microns, 5 microns, 1 is micro-
Rice brass wire cloth filtering is to obtain the ink for tempered glass.
Detect example 1
1) color of ink made from above-described embodiment is observed；
2) measure the average grain diameter of above-mentioned ink by Malvern granularity Detection instrument, and after storage 6 months ink it is flat
Equal partial size；
3) viscosity of above-mentioned ink is measured by rotary viscosity；Testing result is shown in Table 1.
Application examples 1
The multiple color ink made from above-described embodiment prints simple glass, and 680-720 DEG C of sintering 30min is left
The tempered glass of Fig. 1 and Fig. 2 can be made in the right side；The ink can ideally decorate tempered glass as seen from the figure.
It should be understood by those ordinary skilled in the art that: the discussion of any of the above embodiment is exemplary only, not
It is intended to imply that the scope of the present disclosure (including claim) is limited to these examples；Under thinking of the invention, above embodiments
Or can also be combined between the technical characteristic in different embodiments, step can be realized with random order, and be existed such as
Many other variations of the upper different aspect of the invention, for simplicity, they are not provided in details.
The embodiment of the present invention be intended to cover fall into all such replacements within the broad range of appended claims,
Modifications and variations.Therefore, all within the spirits and principles of the present invention, any omission, modification, equivalent replacement, the improvement made
Deng should all be included in the protection scope of the present invention.
Claims (10)
1. a kind of ink for tempered glass, which is characterized in that by weight, the original of the ink for tempered glass
Material by 20-35 parts of inorganic pigment, 15-35 parts of bismuth glass powder, 15-30 parts of n-tridecane, 6-10 parts of petroleum ether, 2-4 parts of dispersing agent,
Anti-settling wax 0.2-0.5 parts of compositions；
Wherein, the bismuth glass powder is by bismuth oxide, boric acid, lithium metasilicate, sodium metasilicate, calcium oxide, phosphotungstic acid, phenylacetic acid isobutyl
Ester composition.
2. the ink according to claim 1 for tempered glass, wherein by weight, described to be used for tempered glass
Ink raw material by 27-28 parts of inorganic pigment, 29-31 parts of bismuth glass powder, 29-30 parts of n-tridecane, 8-9 parts of petroleum ether, point
3-4 parts of powder, anti-settling wax 0.25-0.35 parts of compositions.
3. the ink according to claim 1 for tempered glass, wherein by weight, the bismuth glass powder is by three
Aoxidize 60-75 parts of two bismuth, 10-16 parts of boric acid, 4-6 parts of lithium metasilicate, 4-6 parts of sodium metasilicate, 5-6 parts of calcium oxide, phosphotungstic acid 1.0-1.8
Part composition；The content of isobutyl phenylacetate is 1.5 weight %-2.5 weight % in the bismuth glass powder.
4. the ink according to claim 1 for tempered glass, wherein the inorganic pigment is selected from cobalt aluminate, oxidation
At least one of cobalt, titanium oxide, iron oxide, corundum.
5. the ink according to claim 1 for tempered glass, wherein the dispersing agent is selected from polyurethane, stearic acid
At least one of barium, zinc stearate.
6. the ink according to claim 1 for tempered glass, wherein the boiling point of the petroleum ether is 60-90 DEG C.
7. the ink according to claim 1 for tempered glass, wherein the purity of the bismuth oxide is not less than 60
Weight %.
8. a kind of preparation method of the ink for tempered glass as described in any one of claim 1-6, feature exist
In, comprising:
1) bismuth oxide, boric acid, lithium metasilicate, sodium metasilicate, calcium oxide, phosphotungstic acid mixed, melting, cooling, crushing, sieve and select
Partial size≤2000 mesh powders are taken to carry out ball milling；Then isobutyl phenylacetate is sprayed into the mixture after ball milling to be modified to obtain
To bismuth glass powder；
2) inorganic pigment, bismuth glass powder, n-tridecane, petroleum ether, dispersing agent, anti-settling wax are subjected to mixing dispersion, then carried out
Grinding is until system average grain diameter≤250nm, viscosity≤25mpas, then successively with 10 microns, 5 microns, 1 micron of brass wire cloth
Filtering is to obtain the ink for being used for tempered glass.
9. the ink according to claim 8 for tempered glass, wherein in step 1), after the screening of 30g
Mixture, the time of the ball milling are 5-7h；
In step 1), relative to the mixture after 30g grinding, the penetrating time of the isobutyl phenylacetate is 30-50min.
10. the ink according to claim 8 for tempered glass, wherein in step 2), it is described mixing dispersion when
Between be 20-40min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910672263.XA CN110330836A (en) | 2019-07-24 | 2019-07-24 | A kind of ink and preparation method thereof for tempered glass |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910672263.XA CN110330836A (en) | 2019-07-24 | 2019-07-24 | A kind of ink and preparation method thereof for tempered glass |
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| Publication Number | Publication Date |
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| CN110330836A true CN110330836A (en) | 2019-10-15 |
Family
ID=68147235
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| CN201910672263.XA Pending CN110330836A (en) | 2019-07-24 | 2019-07-24 | A kind of ink and preparation method thereof for tempered glass |
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| KR970010140A (en) * | 1995-08-25 | 1997-03-27 | 기타지마 요시토시 | Heat transfer sheet |
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| CN102964907A (en) * | 2012-10-31 | 2013-03-13 | 彩虹集团公司 | Environment-friendly ink paste for automobile glass and preparation method thereof |
| CN103980754A (en) * | 2014-05-16 | 2014-08-13 | 吴江市英力达塑料包装有限公司 | Pavement marker coating and preparation method thereof |
| CN104046121A (en) * | 2014-07-04 | 2014-09-17 | 繁昌县朱氏印务有限责任公司 | Tempered glass ink formula |
| CN106186698A (en) * | 2016-06-30 | 2016-12-07 | 安徽省德邦瓷业有限公司 | A kind of Celadon glaze material for domestic ceramic |
| CN106810937A (en) * | 2017-01-13 | 2017-06-09 | 郑州市亚美凯新材料有限公司 | A kind of aqueous highlighted environment-friendly type tempering glass ink and preparation method thereof |
| CN107201083A (en) * | 2017-05-25 | 2017-09-26 | 山东国瓷康立泰新材料科技有限公司 | A kind of ink-jet anti slip glass ink and preparation method thereof |
-
2019
- 2019-07-24 CN CN201910672263.XA patent/CN110330836A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR970010140A (en) * | 1995-08-25 | 1997-03-27 | 기타지마 요시토시 | Heat transfer sheet |
| US20080090034A1 (en) * | 2006-09-18 | 2008-04-17 | Harrison Daniel J | Colored glass frit |
| CN102964907A (en) * | 2012-10-31 | 2013-03-13 | 彩虹集团公司 | Environment-friendly ink paste for automobile glass and preparation method thereof |
| CN103980754A (en) * | 2014-05-16 | 2014-08-13 | 吴江市英力达塑料包装有限公司 | Pavement marker coating and preparation method thereof |
| CN104046121A (en) * | 2014-07-04 | 2014-09-17 | 繁昌县朱氏印务有限责任公司 | Tempered glass ink formula |
| CN106186698A (en) * | 2016-06-30 | 2016-12-07 | 安徽省德邦瓷业有限公司 | A kind of Celadon glaze material for domestic ceramic |
| CN106810937A (en) * | 2017-01-13 | 2017-06-09 | 郑州市亚美凯新材料有限公司 | A kind of aqueous highlighted environment-friendly type tempering glass ink and preparation method thereof |
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Application publication date: 20191015 |