CN110319719A - A kind of anti-incrustation pipe heat exchanger - Google Patents

A kind of anti-incrustation pipe heat exchanger Download PDF

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Publication number
CN110319719A
CN110319719A CN201910573655.0A CN201910573655A CN110319719A CN 110319719 A CN110319719 A CN 110319719A CN 201910573655 A CN201910573655 A CN 201910573655A CN 110319719 A CN110319719 A CN 110319719A
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China
Prior art keywords
heat exchanger
shell
solution cavity
perforated plate
exchanger tube
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Application number
CN201910573655.0A
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Chinese (zh)
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CN110319719B (en
Inventor
钱雪松
郑浩雯
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Changzhou Campus of Hohai University
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Changzhou Campus of Hohai University
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D7/16Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged in parallel spaced relation
    • F28D7/163Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged in parallel spaced relation with conduit assemblies having a particular shape, e.g. square or annular; with assemblies of conduits having different geometrical features; with multiple groups of conduits connected in series or parallel and arranged inside common casing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F13/00Arrangements for modifying heat-transfer, e.g. increasing, decreasing
    • F28F13/18Arrangements for modifying heat-transfer, e.g. increasing, decreasing by applying coatings, e.g. radiation-absorbing, radiation-reflecting; by surface treatment, e.g. polishing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Geometry (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of anti-incrustation pipe heat exchangers, several evenly arranged heat exchanger tubes are equipped in shell, the first solution cavity is equipped with above the upper perforated plate, the second solution cavity is equipped with below lower perforated plate, the both ends of the every heat exchanger tube pass through upper perforated plate and lower perforated plate is connected to the first solution cavity and the second solution cavity respectively, form heat exchanger channels, the inner wall of heat exchanger tube is uniformly coated with graphite ene coatings, several isolation boards disposed in parallel are equipped in shell, several isolation boards form " Z " type runner in shell, the heat exchanger tube is arranged in isolation board, the top of shell is equipped with heat transferring medium entrance, bottom is exported equipped with heat transferring medium, first solution cavity is equipped with fluid outlet, second solution cavity is equipped with fluid inlet.The present invention heating conduction and surface anti-fouling performance excellent using graphene, improve the heat exchanger effectiveness and corrosion resistance of heat exchanger tube.

Description

A kind of anti-incrustation pipe heat exchanger
Technical field
The present invention relates to a kind of anti-incrustation pipe heat exchangers, belong to technical field of heat dissipation.
Background technique
Shell-and-tube heat exchanger (shell and tube heat exchanger) is also known as tubular heat exchanger.It is to close Dividing wall type heat exchanger of the wall surface restrained in the housing as heat-transfer area.This heat exchanger structure is simple, low cost, flow area It is wider, be readily cleaned scale;It can be manufactured with various structural materials (mainly metal material), can use under high temperature and pressure, be Type most widely used at present.
Thermal interface material applications are the important components for constituting heat dissipation system between heat source and radiator.Hot interface Material can fill up the hole generated when heat source is contacted with two kinds of different materials of radiator, prevent heat spot, reduce the resistance of heat transmitting It is anti-, improve thermal diffusivity.The heat-transfer capability of thermal interfacial material is determined by its atomic structure, and crystal structure changes on nanoscale Become the thermal heat transfer capability that can influence thermal interfacial material.
Graphene is a kind of honeycomb flat film formed by carbon atom with SP2 hybrid form, and thickness only has 0.335nm, Young's modulus are about 42N/m-2, while having excellent conduction, heating conduction, most thin, most as what is be currently known Hard nano material, graphene have all obtained length in fields such as physics, materialogy, electronic information, computer, aerospaces The development of foot.
Summary of the invention
In view of the deficiencies of the prior art, the present invention provides a kind of anti-incrustation pipe heat exchanger, leads using graphene is excellent Hot property and surface anti-fouling performance improve the heat exchanger effectiveness and corrosion resistance of heat exchanger tube.
The technical solution mainly used in the present invention are as follows:
A kind of anti-incrustation pipe heat exchanger, including shell, the top and bottom end of the shell are respectively equipped with upper perforated plate and lower perforated plate, It is equipped with several evenly arranged heat exchanger tubes in the shell, is equipped with the first solution cavity above the upper perforated plate, under the lower perforated plate Side is equipped with the second solution cavity, the both ends of the every heat exchanger tube pass through upper perforated plate and lower perforated plate respectively with the first solution cavity and second Solution cavity connection, forms heat exchanger channels, and the inner wall of the heat exchanger tube is uniformly coated with graphite ene coatings, if being equipped in the shell Do isolation board disposed in parallel, the fixing end alternate intervals of the isolation board are fixed on two inner sidewalls of shell, free end away from One section of gap of side wall in shrinking away from theshell body, several isolation boards form " Z " type runner in shell, and the heat exchanger tube is arranged in described In isolation board, the top of the shell is equipped with heat transferring medium entrance, and bottom is exported equipped with heat transferring medium, on first solution cavity Equipped with fluid outlet, second solution cavity is equipped with fluid inlet.
Preferably, the heat exchanger tube is prepared using graphene composite pipe through drawing process.
Preferably, straight type pipe, bellows or wing pipe can be used in the heat exchanger tube.
Preferably, the outer wall of the heat exchanger tube is uniformly coated with graphite ene coatings.
Preferably, the raw material components of the graphite ene coatings and each component mass fraction are as follows:
Titanium dioxide: 100 ~ 140;
Graphene: 1 ~ 10;
Silicon powder: 20 ~ 70;
Ptfe emulsion: 30 ~ 60;
Pure-acrylic emulsion: 70 ~ 110;
Propylene glycol methyl ether acetate: 8 ~ 15;
Propylene glycol: 6 ~ 16;
PH stable agent: 0.2 ~ 1;
And adipic dihydrazide: 1.8 ~ 2.5;
Deionized water: 100.
Preferably, the graphite ene coatings with a thickness of 5-40 μm.
The utility model has the advantages that the present invention provides a kind of anti-incrustation pipe heat exchanger, using the excellent heating conduction of graphene and Surface anti-fouling performance improves the heat exchanger effectiveness and corrosion resistance of heat exchanger tube.
Detailed description of the invention
Fig. 1 is overall structure figure of the invention;
Fig. 2 is the room temperature thermal conductivity coefficient comparison diagram of graphite ene coatings and traditional material of the invention.
In figure: shell 1, upper perforated plate 1-1, lower perforated plate 1-2, isolation board 1-3, heat transferring medium entrance 1-4, heat transferring medium outlet 1-5, heat exchanger tube 2, the first solution cavity 3-1, the second solution cavity 3-2, fluid outlet 3-3, fluid inlet 3-4.
Specific embodiment
In order to make those skilled in the art better understand the technical solutions in the application, below to the embodiment of the present application In technical solution be clearly and completely described, it is clear that described embodiments are only a part of embodiments of the present application, Instead of all the embodiments.Based on the embodiment in the application, those of ordinary skill in the art are not making creative labor Every other embodiment obtained under the premise of dynamic, shall fall within the protection scope of the present application.
A kind of anti-incrustation pipe heat exchanger, including shell 1, the top and bottom end of the shell 1 are respectively equipped with upper perforated plate 1-1 With lower perforated plate 1-2, the shell 1 is interior to be equipped with several evenly arranged heat exchanger tubes 2, and it is molten to be equipped with first above the upper perforated plate 1-1 The second solution cavity 3-2 is equipped with below sap cavity 3-1, the lower perforated plate 1-2, the both ends of the every heat exchanger tube 2 pass through upper perforated plate 1-1 It is connected to respectively with the first solution cavity 3-1 and the second solution cavity 3-2 with lower perforated plate 1-2, forms heat exchanger channels, the heat exchanger tube 2 Inner wall is uniformly coated with graphite ene coatings, is equipped with several isolation board 1-3 disposed in parallel, the isolation board 1-3 in the shell 1 Fixing end alternate intervals be fixed on two inner sidewalls of shell, free end is several described apart from 1 inner sidewall of shell, one section of gap Isolation board 1-3 forms " Z " type runner in shell, and the heat exchanger tube is arranged in the isolation board 1-3, the shell 1 it is upper Portion is equipped with heat transferring medium entrance 1-4, and bottom is equipped with heat transferring medium and exports 1-5, and the first solution cavity 3-1 is equipped with fluid outlet 3-3, the second solution cavity 3-2 are equipped with fluid inlet 3-4.
Preferably, the heat exchanger tube 2 is prepared using graphene composite pipe through drawing process.
Preferably, the heat exchanger tube 2 is straight type pipe, bellows or wing pipe.
Preferably, the outer wall of the heat exchanger tube 2 is uniformly coated with graphite ene coatings.
Preferably, the raw material components of the graphite ene coatings and each component mass fraction are as follows:
Titanium dioxide: 100 ~ 140;
Graphene: 1 ~ 10;
Silicon powder: 20 ~ 70;
Ptfe emulsion: 30 ~ 60;
Pure-acrylic emulsion: 70 ~ 110;
Propylene glycol methyl ether acetate: 8 ~ 15;
Propylene glycol: 6 ~ 16;
PH stable agent: 0.2 ~ 1;
And adipic dihydrazide: 1.8 ~ 2.5;
Deionized water: 100.
Preferably, the graphite ene coatings with a thickness of 5-40 μm.
Embodiment 1:
As shown in Figure 1, fluid enters the second solution cavity from fluid inlet 3-4, enter the first solution cavity 3-1 through heat exchanger tube 2 after Afterwards from fluid outlet outflow (realizing the flowing of fluid using conventional liquid pump), at this point, heat transferring medium is from heat transferring medium entrance 1-4 Tube body is flowed into, " Z " the type runner formed along the isolation board 1-3 being staggered after flowing through each heat exchanger tube 2, is exported from heat transferring medium 1-5 outflow, fluid flow in opposite directions with heat transferring medium, realize heat exchange by graphite ene coatings.
In the present embodiment, the raw material components and each component mass fraction of graphite ene coatings are as follows:
Titanium dioxide: 115
Graphene: 5
Silicon powder: 60
Ptfe emulsion: 52
Pure-acrylic emulsion: 80
Propylene glycol methyl ether acetate: 10
Propylene glycol: 12
PH stable agent AMP-95:0.8
And adipic dihydrazide: 2.2
Deionized water: 100
The preparation of graphite ene coatings: in proportion by adipic dihydrazide and deionized water, stirring at low speed keeps adipic dihydrazide complete After fully dissolved, it is successively proportionally added into propylene glycol, pH stable agent AMP-95 continues to be uniformly mixed, then successively adds in proportion Add titanium dioxide, silicon powder and graphene, and slurry fineness is dispersed to 30 ~ 50 μm using dispersion machine, then in the case where stirring at low speed Ptfe emulsion, pure-acrylic emulsion, propylene glycol methyl ether acetate is added, finally stirs 30min, obtains graphene composite wood Material is sprayed on heat exchange tube wall using electrospray technology.Graphite ene coatings with a thickness of 20 ~ 30 μm.
It is illustrated in figure 2 the room temperature thermal conductivity coefficient comparison diagram of material and traditional material coated with graphite ene coatings.From figure In as can be seen that the thermal coefficient of graphene composite coating is about 42W/(mK), the 80 of conventional ceramic coatings thermal coefficient Times, about the 2 of the thermal coefficient of 304 stainless steels times.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered It is considered as protection scope of the present invention.

Claims (6)

1. a kind of anti-incrustation pipe heat exchanger, including shell, the top and bottom end of the shell are respectively equipped with upper perforated plate and down tube Plate, which is characterized in that be equipped with several evenly arranged heat exchanger tubes in the shell, be equipped with the first solution above the upper perforated plate Chamber, is equipped with the second solution cavity below the lower perforated plate, the both ends of the every heat exchanger tube pass through upper perforated plate and lower perforated plate respectively with First solution cavity and the connection of the second solution cavity, form heat exchanger channels, and the inner wall of the heat exchanger tube is uniformly coated with graphite ene coatings, Several isolation boards disposed in parallel are equipped in the shell, the fixing end alternate intervals of the isolation board are fixed in the two of shell On side wall, for free end apart from one section of gap of case inside wall, several isolation boards form " Z " type runner in shell, described Heat exchanger tube is arranged in the isolation board, and the top of the shell is equipped with heat transferring medium entrance, and bottom is exported equipped with heat transferring medium, First solution cavity is equipped with fluid outlet, and second solution cavity is equipped with fluid inlet.
2. a kind of anti-incrustation pipe heat exchanger according to claim 1, it is characterised in that: the heat exchanger tube uses graphene Composite pipe is prepared through drawing process.
3. a kind of anti-incrustation pipe heat exchanger according to claim 1 or 2, it is characterised in that: the heat exchanger tube is straight type Pipe, bellows or wing pipe.
4. a kind of anti-incrustation pipe heat exchanger according to claim 1 or 2, it is characterised in that: the outer wall of the heat exchanger tube Uniformly it is coated with graphite ene coatings.
5. a kind of anti-incrustation pipe heat exchanger according to claim 1 or 2, it is characterised in that: the graphite ene coatings Raw material components and each component mass fraction are as follows:
Titanium dioxide: 100 ~ 140;
Graphene: 1 ~ 10;
Silicon powder: 20 ~ 70;
Ptfe emulsion: 30 ~ 60;
Pure-acrylic emulsion: 70 ~ 110;
Propylene glycol methyl ether acetate: 8 ~ 15;
Propylene glycol: 6 ~ 16;
PH stable agent: 0.2 ~ 1;
And adipic dihydrazide: 1.8 ~ 2.5;
Deionized water: 100.
6. a kind of anti-incrustation pipe heat exchanger according to claim 5, it is characterised in that: the thickness of the graphite ene coatings It is 5-40 μm.
CN201910573655.0A 2019-06-28 2019-06-28 Anti-scaling tubular heat exchanger Expired - Fee Related CN110319719B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910573655.0A CN110319719B (en) 2019-06-28 2019-06-28 Anti-scaling tubular heat exchanger

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Application Number Priority Date Filing Date Title
CN201910573655.0A CN110319719B (en) 2019-06-28 2019-06-28 Anti-scaling tubular heat exchanger

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CN110319719A true CN110319719A (en) 2019-10-11
CN110319719B CN110319719B (en) 2020-11-17

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114702875A (en) * 2022-03-11 2022-07-05 中国地质科学院 Waterborne polyurethane scale-inhibiting coating and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103192072A (en) * 2013-03-19 2013-07-10 苏州格瑞丰纳米科技有限公司 Material adopting thin graphene and metal powder composite structure, preparation method and application thereof
JP5698438B2 (en) * 2008-11-10 2015-04-08 株式会社Uacj Aluminum fin material for heat exchanger and heat exchanger using the same
CN104710912A (en) * 2015-03-31 2015-06-17 东莞市闻誉实业有限公司 Cooling fin
CN107246815A (en) * 2017-07-11 2017-10-13 南京华电节能环保设备有限公司 A kind of anti-corrosion heat-condutive oil heat exchanger
WO2018086522A1 (en) * 2016-11-09 2018-05-17 中国科学院金属研究所 Hollow foam material and preparation method and application thereof
CN108300146A (en) * 2017-09-06 2018-07-20 海洋化工研究院有限公司 For precision steel structures part surface can scumbling two-component anticorrosive paint and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5698438B2 (en) * 2008-11-10 2015-04-08 株式会社Uacj Aluminum fin material for heat exchanger and heat exchanger using the same
CN103192072A (en) * 2013-03-19 2013-07-10 苏州格瑞丰纳米科技有限公司 Material adopting thin graphene and metal powder composite structure, preparation method and application thereof
CN104710912A (en) * 2015-03-31 2015-06-17 东莞市闻誉实业有限公司 Cooling fin
WO2018086522A1 (en) * 2016-11-09 2018-05-17 中国科学院金属研究所 Hollow foam material and preparation method and application thereof
CN107246815A (en) * 2017-07-11 2017-10-13 南京华电节能环保设备有限公司 A kind of anti-corrosion heat-condutive oil heat exchanger
CN108300146A (en) * 2017-09-06 2018-07-20 海洋化工研究院有限公司 For precision steel structures part surface can scumbling two-component anticorrosive paint and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114702875A (en) * 2022-03-11 2022-07-05 中国地质科学院 Waterborne polyurethane scale-inhibiting coating and preparation method thereof

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