CN110317514A - Coating and preparation method thereof - Google Patents
Coating and preparation method thereof Download PDFInfo
- Publication number
- CN110317514A CN110317514A CN201910419255.4A CN201910419255A CN110317514A CN 110317514 A CN110317514 A CN 110317514A CN 201910419255 A CN201910419255 A CN 201910419255A CN 110317514 A CN110317514 A CN 110317514A
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- parts
- coating
- hexagonal boron
- feed liquid
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/382—Boron-containing compounds and nitrogen
- C08K2003/385—Binary compounds of nitrogen with boron
Abstract
The disclosure provides a kind of coating and preparation method thereof.The coating includes 0.028-0.056 parts of hexagonal boron nitrides, 4.972-9.944 parts of tetrahydrofurans, 70-75 parts of resins, 15-20 parts of solvents by weight.The preparation method of the coating includes: to make 0.028-0.056 parts of hexagonal boron nitrides, 4.972-9.944 parts of tetrahydrofurans, 70-75 parts of resins and 15-20 parts of solvent mixing.The disclosure can be improved dispersion performance of the hexagonal boron nitride in coating, and improve the heat resistance that coating is formed by coating.
Description
Technical field
This disclosure relates to technical field of coatings more particularly to a kind of coating and preparation method thereof.
Background technique
Coating, which forms coating on the surface of object, can be improved the Corrosion Protection of object.Existing coating is formed by painting
Layer heat resistance is poor, is easy to crack and fall off under high temperature environment.
In order to improve the heat resistance of coating, heat-resisting hexagonal boron nitride is added into coating by researcher.However, six sides
There is between two neighboring lamella stronger Van der Waals force in boron nitride lamellar structure, be not easy hexagonal boron nitride in coating point
It dissipates, so that the heat resistance of the coating formed is difficult to meet requirement.
It should be noted that information is only used for reinforcing the reason to the background of the disclosure disclosed in above-mentioned background technology part
Solution, therefore may include the information not constituted to the prior art known to persons of ordinary skill in the art.
Summary of the invention
The disclosure is designed to provide a kind of coating and preparation method thereof, can be improved hexagonal boron nitride in coating
Dispersion performance, and improve the heat resistance that coating is formed by coating.
According to one aspect of the disclosure, a kind of coating is provided, the coating includes 0.028-0.056 part six by weight
Square boron nitride, 4.972-9.944 part tetrahydrofuran, 70-75 parts of resins and 15-20 parts of solvents.
In a kind of exemplary embodiment of the disclosure, the coating further includes 5-10 parts of coating additives by weight.
In a kind of exemplary embodiment of the disclosure, the coating further includes 20-25 parts of curing agent by weight.
In a kind of exemplary embodiment of the disclosure, the coating additive is selected from Tinuvin 1130, Tinuvin
292, one of GLYMO, dimethylbenzene, BYK-SILCLEAN 3700 or a variety of.
In a kind of exemplary embodiment of the disclosure, the curing agent is selected from AMEO, n-butanol, dimethylbenzene, acetic acid fourth
One of ester is a variety of.
In a kind of exemplary embodiment of the disclosure, the resin is selected from bisphenol A type epoxy resin, bisphenol F type epoxy
One of resin, organosilicon epoxy resin are a variety of.
According to one aspect of the disclosure, a kind of preparation method of coating is provided, comprising:
Make 0.028-0.056 parts of hexagonal boron nitrides, 4.972-9.944 parts of tetrahydrofurans, 70-75 parts of resins and 15-20
Part solvent mixing.
In a kind of exemplary embodiment of the disclosure, make 0.028-0.056 parts of hexagonal boron nitrides, 4.972-9.944 parts
Tetrahydrofuran, 70-75 part resin and 15-20 parts of solvent mixing include:
Make 0.028-0.056 parts of hexagonal boron nitrides and 4.972-9.944 parts of tetrahydrofuran mixing, forms the first feed liquid;
Make 70-75 parts of resins and 15-20 parts of solvent mixing, forms the second feed liquid;
Mix first feed liquid with second feed liquid.
In a kind of exemplary embodiment of the disclosure, make 0.028-0.056 parts of hexagonal boron nitrides and 4.972-9.944 parts
Tetrahydrofuran mixes
Mix 0.028-0.056 parts of hexagonal boron nitrides and 4.972-9.944 parts of tetrahydrofurans under ultrasound, ultrasound terminates
After be stirred, formed the first feed liquid.
In a kind of exemplary embodiment of the disclosure, makes 70-75 parts of resins and 15-20 parts of solvent mixing include:
Make 70-75 parts of resins, 15-20 parts of solvents and 5-10 parts of coating additive mixing, forms the second feed liquid.
Coating of the disclosure and preparation method thereof, it is total that the furan nucleus of tetrahydrofuran can generate p- π and π-π with hexagonal boron nitride
Yoke absorbs, and so that hexagonal boron nitride lamella is detached from the constraint of Van der Waals force, i.e., between the two neighboring lamella of hexagonal boron nitride
Van der Waals force is cancelled, and then improves dispersion performance of the hexagonal boron nitride in coating, and is improved coating and be formed by painting
The heat resistance of layer.
It should be understood that above general description and following detailed description be only it is exemplary and explanatory, not
The disclosure can be limited.
Detailed description of the invention
It is described in detail its exemplary embodiment by referring to accompanying drawing, the above and other feature and advantage of the disclosure will become
It obtains more obvious.It should be evident that the accompanying drawings in the following description is only some embodiments of the present disclosure, it is common for this field
For technical staff, without creative efforts, it is also possible to obtain other drawings based on these drawings.
Fig. 1 is the flow chart of the preparation method of the coating of disclosure embodiment.
Specific embodiment
Example embodiment is described more fully with reference to the drawings.However, example embodiment can be with a variety of shapes
Formula is implemented, and is not understood as limited to example set forth herein;On the contrary, thesing embodiments are provided so that the disclosure will be comprehensive
With it is complete, and the design of example embodiment is comprehensively communicated to those skilled in the art.Described feature or characteristic
It can be incorporated in any suitable manner in one or more embodiments.In the following description, it provides many specific thin
Section fully understands embodiment of the present disclosure to provide.It will be appreciated, however, by one skilled in the art that this can be practiced
Disclosed technical solution, or can be using other methods, material etc. without one or more in the specific detail.
Disclosure embodiment provides a kind of coating.The coating may include: six side's nitrogen of 0.028-0.056 part by weight
Change boron, 4.972-9.944 parts of tetrahydrofurans, 70-75 parts of resins and 15-20 parts of solvents.
The furan nucleus of the coating of disclosure embodiment, tetrahydrofuran can generate p- π and the pi-conjugated suction of π-with hexagonal boron nitride
It receives, hexagonal boron nitride lamella is allow to be detached from the constraint of Van der Waals force, i.e. model moral between the two neighboring lamella of hexagonal boron nitride
Hua Li is cancelled, and then improves dispersion performance of the hexagonal boron nitride in coating, and improve coating and be formed by coating
Heat resistance.
Each section of the coating of disclosure embodiment is described in detail below:
The hexagonal boron nitride has good heat resistance, and the piece diameter that is averaged is 10nm, and the number of plies is less than 10 layers.The resin can
Epoxy resin is thought, it is of course also possible to for silicone resin etc..The epoxy resin can be selected from bisphenol A type epoxy resin, Bisphenol F
One of type epoxy resin, organosilicon epoxy resin are a variety of.The solvent can be selected from n-butanol, ethyl alcohol, butyl acetate, two
One of toluene is a variety of.The coating of disclosure embodiment can also include coating additive.The coating additive can be selected from
One of Tinuvin 1130, Tinuvin 292, GLYMO, dimethylbenzene, BYK-SILCLEAN 3700 or a variety of.The disclosure
The coating of embodiment can also include curing agent, so that coating is formed by coating and can quickly solidify.The curing agent can be with
Selected from one of AMEO, n-butanol, dimethylbenzene, butyl acetate or a variety of.
The coating of disclosure embodiment may include 0.028-0.056 parts of hexagonal boron nitrides, 4.972- by weight
9.944 parts of tetrahydrofurans, 70-75 parts of resins, 15-20 parts of solvents, 5-10 parts of coating additives and 20-25 parts of curing agent.Wherein,
Hexagonal boron nitride can be with 0.028 part, 0.031 part, 0.032 part, 0.048 part, 0.056 part etc..Tetrahydrofuran can be 4.972
Part, 5.9 parts, 6.4 parts, 6.7 parts, 7.2 parts, 8.972 parts, 9.944 parts etc..Resin can be 70 parts, 71 parts, 72 parts, 73 parts, 74
Part, 75 parts etc..Solvent can be 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts etc..Coating additive can be 5 parts, 6 parts, 7
Part, 8 parts, 9 parts, 10 parts etc..Curing agent can be 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts etc..
Disclosure embodiment also provides a kind of preparation method of coating.The preparation method for coating may include: to make
0.028-0.056 parts of hexagonal boron nitrides, 4.972-9.944 parts of tetrahydrofurans, 70-75 parts of resins and 15-20 parts of solvent mixing.
The furan nucleus of the preparation method of the coating of disclosure embodiment, tetrahydrofuran can generate p- π with hexagonal boron nitride
With the pi-conjugated absorption of π-, hexagonal boron nitride lamella is allow to be detached from the constraint of Van der Waals force, the i.e. two neighboring lamella of hexagonal boron nitride
Between Van der Waals force be cancelled, and then improve dispersion performance of the hexagonal boron nitride in coating, and improve coating institute shape
At coating heat resistance.
The preparation method of the coating of disclosure embodiment is described in detail below:
The hexagonal boron nitride has good heat resistance, and the piece diameter that is averaged is 10nm, and the number of plies is less than 10 layers.
The resin can be epoxy resin, it is of course also possible to for silicone resin etc..The epoxy resin can be selected from bisphenol-A
One of type epoxy resin, bisphenol f type epoxy resin, organosilicon epoxy resin are a variety of.
The solvent can be selected from one of n-butanol, ethyl alcohol, butyl acetate, dimethylbenzene or a variety of.
As shown in Figure 1, making 0.028-0.056 parts of hexagonal boron nitrides, 4.972-9.944 parts of tetrahydros in disclosure embodiment
Furans, 70-75 part resin and 15-20 parts of solvent mixing may include:
Step S110, make 0.028-0.056 parts of hexagonal boron nitrides and the mixing of 4.972-9.944 parts of tetrahydrofurans, form the
One feed liquid.
For example, it can make 0.028-0.056 parts of hexagonal boron nitrides and 4.972-9.944 parts of tetrahydrofurans under ultrasound
Mixing, and be stirred after ultrasound, form the first feed liquid.The frequency of the ultrasonic wave can be 2MHz etc., ultrasonic time
It can be 15min etc..The revolving speed of the stirring can be 500r/min etc., and mixing time can be 20min etc..In addition, stirring
In the process, the temperature that can keep system is 30-40 DEG C.
Step S120, make 70-75 parts of resins and 15-20 parts of solvent mixing, form the second feed liquid.
In the mixed process of resin and solvent, 5-10 parts of coating additives can be added, it is, of course, also possible to which 20-25 is added
Part curing agent.The coating additive can be selected from Tinuvin 1130, Tinuvin 292, GLYMO, dimethylbenzene, BYK-SILCLEAN
One of 3700 or a variety of.The curing agent can be selected from one of AMEO, n-butanol, dimethylbenzene, butyl acetate or a variety of.
Step S130, the first feed liquid is mixed with the second feed liquid.
Disclosure embodiment is described further combined with specific embodiments below:
Embodiment 1
According to solid-liquid ratio 1g:200mL, hexagonal boron nitride powder is added in tetrahydrofuran and forms mixture, and makes to mix
Close object ultrasonic disperse 15min under the frequency of 2MHz makes mixture in temperature 30- after object temperature to be mixed is reduced to 20 DEG C
40 DEG C and revolving speed are that 20min is stirred under 500r/min, form the first feed liquid;15 parts of butyl acetates are taken, and as solvent and 70
Part bisphenol A type epoxy resin mixing, stirs 10min, 5 parts of Tinuvin 1130 is then added, in 30 DEG C, the revolving speed of 800r/min
Lower stirring 30min is subsequently added into 20 parts of AMEO, is mixed, and forms the second feed liquid;Take 5 part of first feed liquid, and with the second feed liquid
The surface that gained mixed liquor is coated on an aluminium sheet is formed coating by mixing, and the test data of relevant nature is shown in Table 1.
Embodiment 2
According to solid-liquid ratio 1g:200mL, hexagonal boron nitride powder is added in tetrahydrofuran and forms mixture, and makes to mix
Close object ultrasonic disperse 15min under the frequency of 2MHz makes mixture in temperature 30- after object temperature to be mixed is reduced to 20 DEG C
40 DEG C and revolving speed are that 20min is stirred under 500r/min, form the first feed liquid;Take the mixture 18 of butyl acetate and dimethylbenzene
Part, and mixed as solvent with 74 parts of organosilicon epoxy resins, 10min is stirred, the mixing of Tinuvin 1130 and GLYMO is added
8 parts of object, 30min then is stirred under 30 DEG C, the revolving speed of 800r/min, is subsequently added into 22 parts of AMEO, be mixed, forms second
Feed liquid;6 part of first feed liquid is taken, and is mixed with the second feed liquid, the surface that gained mixed liquor is coated on an aluminium sheet is formed into coating, phase
The test data for closing property is shown in Table 1.
Embodiment 3
According to solid-liquid ratio 1g:200mL, hexagonal boron nitride powder is added in tetrahydrofuran and forms mixture, and makes to mix
Close object ultrasonic disperse 15min under the frequency of 2MHz makes mixture in temperature 30- after object temperature to be mixed is reduced to 20 DEG C
40 DEG C and revolving speed are that 20min is stirred under 500r/min, form the first feed liquid;Take butyl acetate, dimethylbenzene and n-butanol
15 parts of mixture, and mixed as solvent with 75 parts of organosilicon epoxy resins, stirring 10min, addition Tinuvin 1130,
Then 10 parts of the mixture of GLYMO and Tinuvin 292 stirs 30min under 30 DEG C, the revolving speed of 800r/min, then plus
Enter 20 parts of mixture of AMEO and n-butanol, be mixed, forms the second feed liquid;5 part of first feed liquid is taken, and mixed with the second feed liquid
It closes, the surface that gained mixed liquor is coated on an aluminium sheet is formed into coating, the test data of relevant nature is shown in Table 1.
Embodiment 4
According to solid-liquid ratio 1g:200mL, hexagonal boron nitride powder is added in tetrahydrofuran and forms mixture, and makes to mix
Close object ultrasonic disperse 15min under the frequency of 2MHz makes mixture in temperature 30- after object temperature to be mixed is reduced to 20 DEG C
40 DEG C and revolving speed are that 20min is stirred under 500r/min, form the first feed liquid;Take the mixture 15 of butyl acetate and n-butanol
Part, and mix as solvent with 75 parts of organosilicon epoxy resins, stirring 10min, addition Tinuvin 1130, GLYMO,
Then 10 parts of the mixture of Tinuvin292 and BYK-SILCLEAN 3700 stirs under 30 DEG C, the revolving speed of 800r/min
30min is subsequently added into 20 parts of mixture of AMEO, n-butanol and butyl acetate, is mixed, and forms the second feed liquid;Take 5 parts
First feed liquid, and mixed with the second feed liquid, the surface that gained mixed liquor is coated on an aluminium sheet is formed into coating, the survey of relevant nature
Examination data are shown in Table 1.
Embodiment 5
According to solid-liquid ratio 1g:200mL, hexagonal boron nitride powder is added in tetrahydrofuran and forms mixture, and makes to mix
Close object ultrasonic disperse 15min under the frequency of 2MHz makes mixture in temperature 30- after object temperature to be mixed is reduced to 20 DEG C
40 DEG C and revolving speed are that 20min is stirred under 500r/min, form the first feed liquid;Take butyl acetate, n-butanol, dimethylbenzene and second
20 parts of the mixture of alcohol, and mixed as solvent with 70 parts of organosilicon epoxy resins, stirring 10min, addition Tinuvin 1130,
Then 15 parts of the mixture of GLYMO, dimethylbenzene and BYK-SILCLEAN 3700 stirs under 30 DEG C, the revolving speed of 800r/min
30min is subsequently added into 25 parts of mixture of AMEO and n-butanol, is mixed, and forms the second feed liquid;10 part of first feed liquid is taken,
And mixed with the second feed liquid, the surface that gained mixed liquor is coated on an aluminium sheet is formed into coating, the test data of relevant nature is shown in
Table 1.
Comparative example
According to solid-liquid ratio 1g:200mL, hexagonal boron nitride powder is added in dimethylbenzene and forms mixture, and makes to mix
Object ultrasonic disperse 15min under the frequency of 2MHz makes mixture in temperature 30-40 after object temperature to be mixed is reduced to 20 DEG C
DEG C and revolving speed be to stir 20min under 500r/min, form the first feed liquid;20 parts of dimethylbenzene are taken, and is had as solvent with 70 parts
The mixing of machine epoxy silicone, stirs 10min, is added 15 parts of coating additive dimethylbenzene, then under 30 DEG C, the revolving speed of 800r/min
30min is stirred, is subsequently added into 25 parts of curing agent dimethylbenzene, is mixed, the second feed liquid is formed;Take 10 part of first feed liquid, and with
The surface that gained mixed liquor is coated on an aluminium sheet is formed coating by the mixing of the second feed liquid, and the test data of relevant nature is shown in Table 1.
1 embodiment 1-5 of table and comparative example are formed by the physical and chemical index of coating
As shown in Table 1, the coating of the disclosure is formed by coating with good heat resistance.By the data of salt spray test
It is found that the coating has permanent Corrosion Protection.In addition, the coating also has, fast drying, flexibility are good, adhesive force is big, resistance to
The advantage that impact is strong, water absorption rate is low.
Those skilled in the art will readily occur to other embodiments of the disclosure after considering specification and practice.This
Application is intended to cover any variations, uses, or adaptations of the disclosure, these variations, uses, or adaptations are abided by
Follow the general principle of the disclosure and including common knowledge or conventional techniques in the art.Description and embodiments
It is considered only as illustratively, the true scope and spirit of the disclosure are pointed out by the attached claims.
Claims (10)
1. a kind of coating, which is characterized in that the coating includes 0.028-0.056 parts of hexagonal boron nitrides, 4.972- by weight
9.944 parts of tetrahydrofurans, 70-75 parts of resins and 15-20 parts of solvents.
2. coating according to claim 1, which is characterized in that the coating further includes that 5-10 parts of coating help by weight
Agent.
3. coating according to claim 2, which is characterized in that the coating further includes 20-25 parts of curing agent by weight.
4. coating according to claim 2, which is characterized in that the coating additive is selected from Tinuvin 1130, Tinuvin
292, one of GLYMO, dimethylbenzene, BYK-SILCLEAN 3700 or a variety of.
5. coating according to claim 3, which is characterized in that the curing agent is selected from AMEO, n-butanol, dimethylbenzene, second
One of acid butyl ester is a variety of.
6. coating according to claim 1, which is characterized in that the resin is selected from bisphenol A type epoxy resin, bisphenol-f type
One of epoxy resin, organosilicon epoxy resin are a variety of.
7. a kind of preparation method of coating characterized by comprising
Keep 0.028-0.056 parts of hexagonal boron nitrides, 4.972-9.944 parts of tetrahydrofurans, 70-75 parts of resins and 15-20 parts molten
Agent mixing.
8. the preparation method of coating according to claim 7, which is characterized in that make 0.028-0.056 parts of hexagonal boron nitrides,
4.972-9.944 parts of tetrahydrofurans, 70-75 parts of resins and 15-20 parts of solvent mixing include:
Make 0.028-0.056 parts of hexagonal boron nitrides and 4.972-9.944 parts of tetrahydrofuran mixing, forms the first feed liquid;
Make 70-75 parts of resins and 15-20 parts of solvent mixing, forms the second feed liquid;
Mix first feed liquid with second feed liquid.
9. the preparation method of coating according to claim 8, which is characterized in that make 0.028-0.056 parts of hexagonal boron nitrides
Include: with 4.972-9.944 parts of tetrahydrofuran mixing
Mix 0.028-0.056 parts of hexagonal boron nitrides and 4.972-9.944 parts of tetrahydrofurans under ultrasound, ultrasound terminates laggard
Row stirring, forms the first feed liquid.
10. the preparation method of coating according to claim 8, which is characterized in that make 70-75 parts of resins and 15-20 parts it is molten
Agent mixes
Make 70-75 parts of resins, 15-20 parts of solvents and 5-10 parts of coating additive mixing, forms the second feed liquid.
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106752673A (en) * | 2016-11-17 | 2017-05-31 | 中国科学院宁波材料技术与工程研究所 | Hexagonal boron nitride epoxy composite anticorrosive paint, its preparation method and application |
CN106752676A (en) * | 2016-11-17 | 2017-05-31 | 中国科学院宁波材料技术与工程研究所 | Hexagonal boron nitride epoxy anticorrosion wear-resistant paint and preparation method and application |
-
2019
- 2019-05-20 CN CN201910419255.4A patent/CN110317514A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106752673A (en) * | 2016-11-17 | 2017-05-31 | 中国科学院宁波材料技术与工程研究所 | Hexagonal boron nitride epoxy composite anticorrosive paint, its preparation method and application |
CN106752676A (en) * | 2016-11-17 | 2017-05-31 | 中国科学院宁波材料技术与工程研究所 | Hexagonal boron nitride epoxy anticorrosion wear-resistant paint and preparation method and application |
Non-Patent Citations (1)
Title |
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HUIJIAN YE等: "Liquid-Phase Exfoliation of Hexagonal Boron Nitride into Boron Nitride Nanosheets in Common Organic Solvents with Hyperbranched Polyethylene as Stabilizer", 《MACROMOLECULAR CHEMISTRY AND PHYSICS》 * |
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Application publication date: 20191011 |
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