CN110306283A - A kind of antistatic knitting fabric - Google Patents
A kind of antistatic knitting fabric Download PDFInfo
- Publication number
- CN110306283A CN110306283A CN201910515955.3A CN201910515955A CN110306283A CN 110306283 A CN110306283 A CN 110306283A CN 201910515955 A CN201910515955 A CN 201910515955A CN 110306283 A CN110306283 A CN 110306283A
- Authority
- CN
- China
- Prior art keywords
- antistatic
- added
- lotion
- weight
- cashmere fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
- D04B1/16—Other fabrics or articles characterised primarily by the use of particular thread materials synthetic threads
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
- D04B1/18—Other fabrics or articles characterised primarily by the use of particular thread materials elastic threads
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B21/00—Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B21/14—Fabrics characterised by the incorporation by knitting, in one or more thread, fleece, or fabric layers, of reinforcing, binding, or decorative threads; Fabrics incorporating small auxiliary elements, e.g. for decorative purposes
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B21/00—Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B21/14—Fabrics characterised by the incorporation by knitting, in one or more thread, fleece, or fabric layers, of reinforcing, binding, or decorative threads; Fabrics incorporating small auxiliary elements, e.g. for decorative purposes
- D04B21/16—Fabrics characterised by the incorporation by knitting, in one or more thread, fleece, or fabric layers, of reinforcing, binding, or decorative threads; Fabrics incorporating small auxiliary elements, e.g. for decorative purposes incorporating synthetic threads
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B21/00—Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B21/14—Fabrics characterised by the incorporation by knitting, in one or more thread, fleece, or fabric layers, of reinforcing, binding, or decorative threads; Fabrics incorporating small auxiliary elements, e.g. for decorative purposes
- D04B21/18—Fabrics characterised by the incorporation by knitting, in one or more thread, fleece, or fabric layers, of reinforcing, binding, or decorative threads; Fabrics incorporating small auxiliary elements, e.g. for decorative purposes incorporating elastic threads
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2211/00—Protein-based fibres, e.g. animal fibres
- D10B2211/01—Natural animal fibres, e.g. keratin fibres
- D10B2211/02—Wool
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/10—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyurethanes
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/06—Load-responsive characteristics
- D10B2401/061—Load-responsive characteristics elastic
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/16—Physical properties antistatic; conductive
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Knitting Of Fabric (AREA)
Abstract
The invention discloses a kind of antistatic knitting fabrics, the fabric by antistatic PET filament, spandex fibre, modified cashmere fiber is blended is made, wherein weight percent hundred shared by the antistatic PET filament be 55-60%, weight percent hundred shared by modified cashmere fiber be 20-30%, it is remaining be spandex fibre, the present invention is reacted by amine with sour, dispersion performance of the acetylene carbon black between polyethylene terephthalate matrix is not only improved, and obtained amidate can be further improved antistatic property.
Description
Technical field
The invention belongs to garment material fields, and in particular to a kind of antistatic knitting fabric.
Background technique
When people's activity, rubs mutually is understood between skin and clothes and between clothes and clothes, and electrostatic can be generated by rubbing,
It wears chemical fibre clothes and is more prone to produce electrostatic;Electrostatic charge caused by household electrical appliance can be absorbed and be accumulated by human skin and clothes simultaneously
It stores away, in addition wall and floor all primary dielectrics, under conditions of being air-dried, the electrostatic of generation is not easy to be released,
Therefore, clothing often will appear electrostatic phenomenon, have many methods that can eliminate electrostatic at present, however how from garment material itself
The research for improving electrostatic efficiency is more important and effective.
Summary of the invention
The object of the present invention is to provide a kind of antistatic knitting fabrics.
To achieve the above object, the invention adopts the following technical scheme:
A kind of antistatic knitting fabric, the fabric by antistatic PET filament, spandex fibre, modified cashmere fiber is blended is made,
Wherein weight percent hundred shared by the antistatic PET filament is 55-60%, weight percent hundred shared by modified cashmere fiber is 20-
30%, remaining is spandex fibre.
The antistatic PET filament is made of the raw material of following weight parts:
Polyethylene terephthalate 270-300, antistatic lotion 80-90, benzotriazole 1-2, coconut oil 3-5.
What the antistatic lotion was made of the raw material of following weight parts:
Acetylene carbon black 30-40, polyethyleneimine 2-5, octadecyl methacrylate 80-100, ammonium persulfate 2-3;
The preparation method of the antistatic lotion, comprising the following steps:
(1) ammonium persulfate is taken, is added in the deionized water of 60-70 times of its weight, stirs evenly;
(2) acetylene carbon black is taken, is added in the dimethylformamide of 15-20 times of its weight, it is 60-70 minutes ultrasonic, poly- second is added
Alkene imines is sent in 70-80 DEG C of water bath with thermostatic control, insulated and stirred 30-40 minutes, is filtered, filter cake is washed, air drying,
Acetylene carbon black must be pre-processed;
(3) octadecyl methacrylate, pretreatment acetylene carbon black mixing are taken, the deionized water of 8-11 times of mixture weight is added to
In, it stirs evenly, is sent in reaction kettle, be passed through nitrogen, adjusting temperature of reaction kettle is 65-70 DEG C, and it is water-soluble that ammonium persulfate is added
Liquid, insulated and stirred 4-6 hours, discharging was cooling to get the antistatic lotion.
The preparation method of the antistatic PET filament, comprising the following steps:
Coconut oil is taken, is added in above-mentioned antistatic lotion, stirs evenly, benzotriazole is added, raising temperature is 65-70
DEG C, insulated and stirred 1-2 hours, precipitating was washed, mixes, stir evenly with polyethylene terephthalate, be sent to by filtering
In extruder, heating melting is squeezed, and spinneret forms to get the antistatic PET filament.
The modified cashmere fiber the preparation method comprises the following steps:
Cashmere fiber is added in antistatic lotion described in claim 3,1-2 hours ultrasonic, discharging cooling is dry,
Up to the modified cashmere fiber.
Advantages of the present invention:
Fabric of the invention by antistatic PET filament, spandex fibre, modified cashmere fiber is blended is made, wherein resisting for introducing is quiet
Electric lotion, first using polyethyleneimine handle acetylene carbon black, then with octadecyl methacrylate monomer blend, in initiator
The lower polymerization of effect is reacted by amine with sour later with coconut oil blending reaction, not only improves acetylene carbon black poly- to benzene two
Dispersion performance between formic acid glycol ester matrix, and obtained amidate can be further improved antistatic property.
Specific embodiment
Embodiment 1
A kind of antistatic knitting fabric, the fabric by antistatic PET filament, spandex fibre, modified cashmere fiber is blended is made,
Wherein weight percent hundred shared by the antistatic PET filament is 55%, weight percent hundred shared by modified cashmere fiber is 20%, surplus
Remaining is spandex fibre.
The antistatic PET filament is made of the raw material of following weight parts:
Polyethylene terephthalate 270, antistatic lotion 80, benzotriazole 1, coconut oil 3.
What the antistatic lotion was made of the raw material of following weight parts:
Acetylene carbon black 30, polyethyleneimine 2, octadecyl methacrylate 80, ammonium persulfate 2;
The preparation method of the antistatic lotion, comprising the following steps:
(1) ammonium persulfate is taken, is added in the deionized water of 60 times of its weight, stirs evenly;
(2) acetylene carbon black is taken, is added in the dimethylformamide of 15 times of its weight, polyethyleneimine is added in ultrasound 60 minutes,
It is sent in 70 DEG C of water bath with thermostatic control, insulated and stirred 30 minutes, filters, filter cake is washed, air drying, acetylene charcoal must be pre-processed
It is black;
(3) octadecyl methacrylate, pretreatment acetylene carbon black mixing are taken, is added in 8 times of mixture weight of deionized water,
It stirs evenly, is sent in reaction kettle, be passed through nitrogen, adjusting temperature of reaction kettle is 65 DEG C, and ammonium persulfate aqueous solution, heat preservation is added
Stirring 4 hours, discharging are cooling to get the antistatic lotion.
The preparation method of the antistatic PET filament, comprising the following steps:
Coconut oil is taken, is added in above-mentioned antistatic lotion, stirs evenly, benzotriazole is added, increasing temperature is 65 DEG C, is protected
Precipitating is washed, mixes, stir evenly with polyethylene terephthalate, be sent to extruder by temperature stirring 1 hour, filtering
In, heating melting squeezes, and spinneret forms to get the antistatic PET filament.
The modified cashmere fiber the preparation method comprises the following steps:
Cashmere fiber is added in antistatic lotion described in claim 3, ultrasound 1 hour, discharging cooling is dry, i.e.,
Obtain the modified cashmere fiber.
Embodiment 2
A kind of antistatic knitting fabric, the fabric by antistatic PET filament, spandex fibre, modified cashmere fiber is blended is made,
Wherein weight percent hundred shared by the antistatic PET filament is 60%, weight percent hundred shared by modified cashmere fiber is 30%, surplus
Remaining is spandex fibre.
The antistatic PET filament is made of the raw material of following weight parts:
Polyethylene terephthalate 300, antistatic lotion 90, benzotriazole 2, coconut oil 5.
What the antistatic lotion was made of the raw material of following weight parts:
Acetylene carbon black 40, polyethyleneimine 5, octadecyl methacrylate 100, ammonium persulfate 3;
The preparation method of the antistatic lotion, comprising the following steps:
(1) ammonium persulfate is taken, is added in the deionized water of 70 times of its weight, stirs evenly;
(2) acetylene carbon black is taken, is added in the dimethylformamide of 20 times of its weight, polyethyleneimine is added in ultrasound 70 minutes,
It is sent in 80 DEG C of water bath with thermostatic control, insulated and stirred 40 minutes, filters, filter cake is washed, air drying, acetylene charcoal must be pre-processed
It is black;
(3) octadecyl methacrylate, pretreatment acetylene carbon black mixing are taken, 11 times of mixture weight of deionized water is added to
In, it stirs evenly, is sent in reaction kettle, be passed through nitrogen, adjusting temperature of reaction kettle is 70 DEG C, ammonium persulfate aqueous solution is added,
Insulated and stirred 6 hours, discharging was cooling to get the antistatic lotion.
The preparation method of the antistatic PET filament, comprising the following steps:
Coconut oil is taken, is added in above-mentioned antistatic lotion, stirs evenly, benzotriazole is added, increasing temperature is 70 DEG C, is protected
Precipitating is washed, mixes, stir evenly with polyethylene terephthalate, be sent to extruder by temperature stirring 2 hours, filtering
In, heating melting squeezes, and spinneret forms to get the antistatic PET filament.
The modified cashmere fiber the preparation method comprises the following steps:
Cashmere fiber is added in antistatic lotion described in claim 3, ultrasound 2 hours, discharging cooling is dry, i.e.,
Obtain the modified cashmere fiber.
Performance test:
The sheet resistance of the antistatic knitting fabric of embodiment 1: 5.7 × 109Ω;
The sheet resistance of the antistatic knitting fabric of embodiment 2: 9.3 × 109Ω。
Claims (5)
1. a kind of antistatic knitting fabric, which is characterized in that the fabric is by antistatic PET filament, spandex fibre, modified cashmere
Fiber blend is made, wherein weight percent hundred shared by the antistatic PET filament is 55-60%, weight shared by modified cashmere fiber
Amount be very 20-30%, it is remaining be spandex fibre.
2. a kind of antistatic knitting fabric according to claim 1, which is characterized in that the antistatic PET filament be by
The raw material composition of following weight parts:
Polyethylene terephthalate 270-300, antistatic lotion 80-90, benzotriazole 1-2, coconut oil 3-5.
3. a kind of antistatic knitting fabric according to claim 2, which is characterized in that the antistatic lotion is by following
The raw material composition of parts by weight:
Acetylene carbon black 30-40, polyethyleneimine 2-5, octadecyl methacrylate 80-100, ammonium persulfate 2-3;
The preparation method of the antistatic lotion, comprising the following steps:
(1) ammonium persulfate is taken, is added in the deionized water of 60-70 times of its weight, stirs evenly;
(2) acetylene carbon black is taken, is added in the dimethylformamide of 15-20 times of its weight, it is 60-70 minutes ultrasonic, poly- second is added
Alkene imines is sent in 70-80 DEG C of water bath with thermostatic control, insulated and stirred 30-40 minutes, is filtered, filter cake is washed, air drying,
Acetylene carbon black must be pre-processed;
(3) octadecyl methacrylate, pretreatment acetylene carbon black mixing are taken, the deionized water of 8-11 times of mixture weight is added to
In, it stirs evenly, is sent in reaction kettle, be passed through nitrogen, adjusting temperature of reaction kettle is 65-70 DEG C, and it is water-soluble that ammonium persulfate is added
Liquid, insulated and stirred 4-6 hours, discharging was cooling to get the antistatic lotion.
4. a kind of antistatic knitting fabric according to claim 2, which is characterized in that the system of the antistatic PET filament
Preparation Method, comprising the following steps:
Coconut oil is taken, is added in above-mentioned antistatic lotion, stirs evenly, benzotriazole is added, raising temperature is 65-70
DEG C, insulated and stirred 1-2 hours, precipitating was washed, mixes, stir evenly with polyethylene terephthalate, be sent to by filtering
In extruder, heating melting is squeezed, and spinneret forms to get the antistatic PET filament.
5. a kind of antistatic knitting fabric according to claim 1, which is characterized in that the preparation of the modified cashmere fiber
Method are as follows:
Cashmere fiber is added in antistatic lotion described in claim 3,1-2 hours ultrasonic, discharging cooling is dry,
Up to the modified cashmere fiber.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201910515955.3A CN110306283B (en) | 2019-06-14 | 2019-06-14 | Antistatic knitted fabric |
Applications Claiming Priority (1)
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CN201910515955.3A CN110306283B (en) | 2019-06-14 | 2019-06-14 | Antistatic knitted fabric |
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CN110306283A true CN110306283A (en) | 2019-10-08 |
CN110306283B CN110306283B (en) | 2020-11-10 |
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CN201910515955.3A Active CN110306283B (en) | 2019-06-14 | 2019-06-14 | Antistatic knitted fabric |
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Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102150962A (en) * | 2010-12-08 | 2011-08-17 | 吴江市合欣转移印花有限公司 | Anti-static thermal insulation fabric |
CN103898652A (en) * | 2014-03-20 | 2014-07-02 | 西安工程大学 | Four-component spandex covering composite yarn and preparation method of fabric made of four-component spandex covering composite yarns |
US20160039176A1 (en) * | 2012-09-06 | 2016-02-11 | Xamax Industries, Inc. | Composite sheet material and method for forming the same |
CN107373795A (en) * | 2017-08-02 | 2017-11-24 | 苏州凤霓绣叶文化艺术有限公司 | A kind of smooth antistatic ceremonial dress face fabric |
CN107699976A (en) * | 2017-11-01 | 2018-02-16 | 安徽创荣服装辅料有限公司 | A kind of antistatic PET filament and preparation method thereof |
CN109082724A (en) * | 2018-07-11 | 2018-12-25 | 桐城市新瑞建筑工程有限公司 | A kind of sulfonation fire proofing firbre and preparation method thereof |
CN109337340A (en) * | 2018-10-11 | 2019-02-15 | 郭天笑 | A kind of acetylation polyester modification conductive film and preparation method thereof |
-
2019
- 2019-06-14 CN CN201910515955.3A patent/CN110306283B/en active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102150962A (en) * | 2010-12-08 | 2011-08-17 | 吴江市合欣转移印花有限公司 | Anti-static thermal insulation fabric |
US20160039176A1 (en) * | 2012-09-06 | 2016-02-11 | Xamax Industries, Inc. | Composite sheet material and method for forming the same |
CN103898652A (en) * | 2014-03-20 | 2014-07-02 | 西安工程大学 | Four-component spandex covering composite yarn and preparation method of fabric made of four-component spandex covering composite yarns |
CN107373795A (en) * | 2017-08-02 | 2017-11-24 | 苏州凤霓绣叶文化艺术有限公司 | A kind of smooth antistatic ceremonial dress face fabric |
CN107699976A (en) * | 2017-11-01 | 2018-02-16 | 安徽创荣服装辅料有限公司 | A kind of antistatic PET filament and preparation method thereof |
CN109082724A (en) * | 2018-07-11 | 2018-12-25 | 桐城市新瑞建筑工程有限公司 | A kind of sulfonation fire proofing firbre and preparation method thereof |
CN109337340A (en) * | 2018-10-11 | 2019-02-15 | 郭天笑 | A kind of acetylation polyester modification conductive film and preparation method thereof |
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Effective date of registration: 20230406 Address after: 362000 Jinjing Zhennan Industrial Zone, Jinjiang City, Quanzhou City, Fujian Province Patentee after: FUJIAN SEPTWOLVES INDUSTRY Co.,Ltd. Address before: Jinjing District, Jinnan City, Fujian Province Patentee before: FUJIAN SEPTWOLVES INDUSTRY Co.,Ltd. Patentee before: Jinjiang Seven Wolves Garment Manufacturing Co.,Ltd. |