CN110284325A - A kind of flame-retardant blended fabric and preparation method thereof - Google Patents
A kind of flame-retardant blended fabric and preparation method thereof Download PDFInfo
- Publication number
- CN110284325A CN110284325A CN201910500761.6A CN201910500761A CN110284325A CN 110284325 A CN110284325 A CN 110284325A CN 201910500761 A CN201910500761 A CN 201910500761A CN 110284325 A CN110284325 A CN 110284325A
- Authority
- CN
- China
- Prior art keywords
- parts
- weight
- fabric
- retardant
- fire
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 241
- 239000003063 flame retardant Substances 0.000 title claims abstract description 201
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 79
- 238000002360 preparation method Methods 0.000 title claims description 19
- 238000004519 manufacturing process Methods 0.000 title description 3
- 239000000835 fiber Substances 0.000 claims abstract description 109
- 239000007788 liquid Substances 0.000 claims abstract description 61
- 239000004677 Nylon Substances 0.000 claims abstract description 39
- 229920001778 nylon Polymers 0.000 claims abstract description 39
- -1 polytetrafluoroethylene Polymers 0.000 claims abstract description 29
- 229920006305 unsaturated polyester Polymers 0.000 claims abstract description 26
- 239000004359 castor oil Substances 0.000 claims abstract description 15
- 235000019438 castor oil Nutrition 0.000 claims abstract description 15
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 claims abstract description 15
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 15
- 229930185605 Bisphenol Natural products 0.000 claims abstract description 14
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract description 14
- 239000004810 polytetrafluoroethylene Substances 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 238000012545 processing Methods 0.000 claims description 36
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 24
- 238000001035 drying Methods 0.000 claims description 24
- 238000004043 dyeing Methods 0.000 claims description 24
- 239000001913 cellulose Substances 0.000 claims description 16
- 229920002678 cellulose Polymers 0.000 claims description 16
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 16
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 239000012991 xanthate Substances 0.000 claims description 14
- 229920000877 Melamine resin Polymers 0.000 claims description 13
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 13
- 150000002148 esters Chemical class 0.000 claims description 13
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 13
- 235000019441 ethanol Nutrition 0.000 claims description 12
- 238000005096 rolling process Methods 0.000 claims description 12
- 238000007493 shaping process Methods 0.000 claims description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Natural products OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 11
- 230000003115 biocidal effect Effects 0.000 claims description 2
- 239000012530 fluid Substances 0.000 claims description 2
- 241000722948 Apocynum cannabinum Species 0.000 claims 1
- 229910052787 antimony Inorganic materials 0.000 claims 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims 1
- 238000010304 firing Methods 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 229920002994 synthetic fiber Polymers 0.000 claims 1
- 230000035699 permeability Effects 0.000 abstract description 5
- 239000000853 adhesive Substances 0.000 abstract description 3
- 230000001070 adhesive effect Effects 0.000 abstract description 3
- 230000000052 comparative effect Effects 0.000 description 15
- 241000722949 Apocynum Species 0.000 description 12
- 229910000410 antimony oxide Inorganic materials 0.000 description 12
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 11
- 238000002485 combustion reaction Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000004753 textile Substances 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 238000009987 spinning Methods 0.000 description 4
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 229920002488 Hemicellulose Polymers 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 2
- 229920005610 lignin Polymers 0.000 description 2
- 210000001161 mammalian embryo Anatomy 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000001814 pectin Substances 0.000 description 2
- 229920001277 pectin Polymers 0.000 description 2
- 235000010987 pectin Nutrition 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 231100000075 skin burn Toxicity 0.000 description 2
- 206010003497 Asphyxia Diseases 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229920006052 Chinlon® Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011707 mineral Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/90—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/47—Oxides or hydroxides of elements of Groups 5 or 15 of the Periodic Table; Vanadates; Niobates; Tantalates; Arsenates; Antimonates; Bismuthates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/262—Sulfated compounds thiosulfates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
- D06M13/358—Triazines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
- D06M15/07—Cellulose esters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/507—Polyesters
- D06M15/51—Unsaturated polymerisable polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/22—Polymers or copolymers of halogenated mono-olefins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
This case discloses a kind of flame-retardant blended fabric, and flame-retardant blended fabric pads fire-retardant treatment liquid by fabric and obtains；Fabric includes that the raw material hybrid woven of following weight parts forms: 36~40 parts by weight of nylon fibre；12~16 parts by weight of polytetrafluoroethylene fibre；6~8 parts by weight of PBI fibre；3~7 parts by weight of coir fibre.Fabric of the invention pads fire-retardant treatment liquid by fabric and obtains, and has preferable flame retardant property；Fire-retardant treatment liquid is with 2,4- diamino -6-(3,3,3- tri- bromopropyls) -1,3,5-triazines and decabromodiphenyl oxide collaboration be used as fire retardant, improve the flame retardant property of fire-retardant treatment liquid, sulfated castor oil improves permeability, improves fire-retardant treatment liquid in the adhesion property of fabric；The adhesive force of fire retardant is further increased by the way that the raising of bisphenol A-type unsaturated polyester (UP) is added.
Description
Technical field
The present invention relates to a kind of fabrics, more particularly to a kind of flame-retardant blended fabric and preparation method thereof.
Background technique
According to statistics, Fire in China death toll reaches thousands of people every year, and the fire as caused by textile accounts for about half, directly
500,000,000 yuan of economic loss.The main reason for wherein bedding, furniture decoration cloth and clothing articles are on fire, especially builds
Home fire, textile ratio shared by fire spread it is bigger.Textile garment is directly contacted with the mankind, once burning, gently then portion
Divide skin burn, by pain, heavy then widespread skin burns burn, threat to life.In addition, the nocuousness that textile combustion generates
Gas also endangers the life of people, such as carbon monoxide, carbon dioxide, hydrogen cyanide, nitrogen oxide, Ammonia and gaseous aldehyde, can all make
Adult asphyxia or murder by poisoning and death, existing fabric flame retardant property are bad.
Summary of the invention
In view of the above shortcomings, the purpose of the present invention is to provide a kind of flame-retardant blended fabrics and preparation method thereof.
Technical solution of the present invention is summarized as follows:
A kind of flame-retardant blended fabric, wherein the flame-retardant blended fabric pads fire-retardant treatment liquid by fabric and obtains；The fabric packet
The raw material hybrid woven for including following weight parts forms:
36~40 parts by weight of nylon fibre；
12~16 parts by weight of polytetrafluoroethylene fibre；
6~8 parts by weight of PBI fibre；
3~7 parts by weight of coir fibre.
Preferably, the flame-retardant blended fabric, wherein further include the Modal fiber of 2~4 parts by weight.
Preferably, the flame-retardant blended fabric, wherein further include the apocynum fibre of 2~4 parts by weight.
Preferably, the flame-retardant blended fabric, wherein fire retardant accounts for the nylon fibre in the nylon fibre
Quality percentage contains 3~5%, and the fire retardant is made of following components by mass parts:
20~30 parts of melamine；
12~16 parts of -1,3,5- triazine of 2,4,6- tri- (N- methylol)；
8~13 parts of ester of tricresyl phosphate (2,3- bis- chloropropyl).
Preferably, the flame-retardant blended fabric, wherein the fire-retardant treatment liquid includes following components in parts by weight:
2,4- diamino -6-(3,3,3- tri- bromopropyls) 30~40 parts by weight of -1,3,5-triazines；
12~15 parts by weight of decabromodiphenyl oxide；
1~3 parts by weight of sulfated castor oil；
2~4 parts by weight of cellulose xanthate；
8~15 parts by weight of ethyl alcohol；
100 parts by weight of water.
Preferably, the flame-retardant blended fabric, wherein further include the ethylene group bis-stearamides of 4~7 parts by weight.
Preferably, the flame-retardant blended fabric, wherein further include the antimony oxide of 0.5~1 parts by weight.
Preferably, the flame-retardant blended fabric, wherein further include 0.5~1 parts by weight bisphenol A-type unsaturation it is poly-
Ester.
A kind of preparation method of flame-retardant blended fabric, wherein the following steps are included:
1) fire-retardant treatment liquid is passed through the method padded to be applied on the fabric, then carries out drying and processing, had
Fire-retardant fabric fabric；
2) it will be immersed in dye liquor with fire-retardant fabric fabric and carry out dyeing processing, the base after drying, after being dyed
Cloth fabric；
3) the fabric fabric after dyeing is carried out shaping into processing, obtains finished product flame-retardant blended fabric.
Preferably, the preparation method of the flame-proof antibiotic fabric, wherein the fabric and the fire-retardant treatment liquid
Mass ratio is 100:8~10, and the mode padded is an immersing and rolling.
The beneficial effects of the present invention are: fabric of the invention, pads fire-retardant treatment liquid by fabric and obtain, there is preferable resistance
Fire performance；Fire-retardant treatment liquid is with 2,4- diamino -6-(3,3,3- tri- bromopropyls) -1,3,5-triazines and decabromodiphenyl oxide collaboration make
For fire retardant, the flame retardant property of fire-retardant treatment liquid is improved, sulfated castor oil improves permeability, improves fire-retardant treatment liquid in fabric
Adhesion property；Its anchorage substance as fabric fire-retardant treatment liquid of cellulose xanthate, under high temperature action, molecule segment
By anchor jail on the surface of embryo cloth, fabric flame retardant property is improved；Ethylene group bis-stearamides have good diffusivity, pass through addition
Ethylene group bis-stearamides improve permeability of the fire-retardant treatment liquid in fabric；It is improved by the way that bisphenol A-type unsaturated polyester (UP) is added
Further increase the adhesive force of fire retardant.
Specific embodiment
The present invention will be further described in detail below with reference to the embodiments, to enable those skilled in the art referring to specification
Text can be implemented accordingly.
The present invention provides a kind of flame-retardant blended fabric, and flame-retardant blended fabric pads fire-retardant treatment liquid by fabric and obtains；Fabric
Raw material hybrid woven including following weight parts forms:
36~40 parts by weight of nylon fibre；
12~16 parts by weight of polytetrafluoroethylene fibre；
6~8 parts by weight of PBI fibre；
3~7 parts by weight of coir fibre.
Nylon fibre has good comprehensive performance, including mechanical property, heat resistance, wear resistance, chemical resistance
And self-lubrication, and coefficient of friction is low, there is certain anti-flammability, polytetrafluoroethylene fibre improves the intensity and elongation percentage of fabric,
Chemical stability, corrosion resistance；PBI fibre improves that the high temperature resistant of fabric, chemicals-resistant burn into be fire-retardant and textile
Energy；Coir fibre is mainly made of cellulose, lignin, hemicellulose and pectin substance etc., and wherein content of cellulose accounts for 46%
~63%, lignin 31%~36%, hemicellulose 0.15%~0.25%, pectin 3%~4% and other miscellaneous sugars, minerals class etc.,
With excellent mechanical property, moisture-proof, heat resistance.
As the another embodiment of this case, wherein further include the Modal fiber of 2~4 parts by weight.By the way that Modal fiber is added
It is comfortable to improve fabric, elasticity, gas permeability.
As the another embodiment of this case, wherein further include the apocynum fibre of 2~4 parts by weight.Apocynum fibre improves face
The gloss of material, well-pressed performance, softness, malleability, and improve the anti-microbial property of fabric.
As the another embodiment of this case, wherein in nylon fibre fire retardant account for the quality percentage of the nylon fibre containing 3~
5%, the fire retardant is made of following components by mass parts:
20~30 parts of melamine；
12~16 parts of -1,3,5- triazine of 2,4,6- tri- (N- methylol)；
8~13 parts of ester of tricresyl phosphate (2,3- bis- chloropropyl).
Melamine, 2,4,6- tri- (N- methylol) -1,3,5-triazines and tricresyl phosphate (2,3- bis- chloropropyl) ester this
Three kinds of fire retardants are used in compounding, and flame retardant effect is synergistic, improve nylon fibre flame retardant effect.
The preparation of nylon fibre:
1) fire retardant is put into feed opening in the middle part of twin screw device by the front feed opening that polyamide is put into twin screw device
It is blended with Fypro, shear at high temperature obtains spinning melt；Wherein, temperature is 245 DEG C, pressure 22MPa in twin-screw,
The draw ratio of twin-screw is 45, and screw speed is 120 revs/min；
2) spinning melt is squeezed into filament spinning component, is dried in the environment middle ring of constant temperature and humidity, it is cooling, obtain as-spun fibre；Its
In, the environment temperature of constant temperature and humidity is 22 DEG C, humidity 60%, and the temperature of circular blow wind is 26 DEG C, wind speed 3m/s, godet speed
Degree is 900m/min, and the spinneret specification of filament spinning component is 2000 holes, aperture 0.2mm；
3) as-spun fibre is passed through to 190 DEG C of the drawing-off of hot oil level-one and boiling water second level drawing-off, thermal finalization is washed, dry, winding,
Obtain high-strength fire-retarding chinlon filament；Wherein, the drawing-off roller speed of hot oil level-one drawing-off is 3000m/min, boiling water second level drawing-off
Drawing-off roller speed is 3200m/min, and the draw ratio after second level drawing-off is 8 times, and the hot-air that thermal finalization is 90 DEG C is formed.It obtains
150d/144f fire-retardant polyamide fibre endless tow, 8 .6cN/dtex of filament strength.
As the another embodiment of this case, wherein fire-retardant treatment liquid includes following components in parts by weight:
2,4- diamino -6-(3,3,3- tri- bromopropyls) 30~40 parts by weight of -1,3,5-triazines；
12~15 parts by weight of decabromodiphenyl oxide；
1~3 parts by weight of sulfated castor oil；
2~4 parts by weight of cellulose xanthate；
8~15 parts by weight of ethyl alcohol；
100 parts by weight of water.
2,4- diamino -6-(3,3,3- tri- bromopropyls) -1,3,5-triazines and decabromodiphenyl oxide collaboration be used as fire retardant, mention
The flame retardant property of high fire-retardance treatment fluid, decabromodiphenyl oxide may act on gas-phase combustion area, capture the free radical in combustion reaction, from
And flame transmission is prevented, decline the flame intensity of combustion zone, finally makes combustion velocity decline until terminating; 2,4-
Diamino -6-(3,3,3- tri- bromopropyls) after -1,3,5-triazines thermally decomposed, easy non-flammable gases such as releasing ammonia, nitrogen, no
The generation of combustion property gas and fire retardant decompose heat absorption and take away most of heat, greatly reduce the surface temperature of polymer；Sulphation
Castor oil improves permeability, improves fire-retardant treatment liquid in the adhesion property of fabric；Cellulose xanthate its as the fire-retardant place of fabric
The anchorage substance for managing liquid, under high temperature action, molecule segment, on the surface of embryo cloth, improves the same of fabric flame retardant property by anchor jail
When, the feel of fabric will not be influenced, while there is very strong water-fastness fastness.
As the another embodiment of this case, wherein further include the ethylene group bis-stearamides of 4~7 parts by weight.Ethylene group is double hard
Acyl amine has good diffusivity, improves infiltration of the fire-retardant treatment liquid in fabric by the way that ethylene group bis-stearamides are added
Property.
As the another embodiment of this case, wherein further include the antimony oxide of 0.5~1 parts by weight.Antimony oxide conduct
Fire retardant can improve fabric flame retardant property by cellulose xanthate essence anchor on fabric.
As the another embodiment of this case, wherein further include the bisphenol A-type unsaturated polyester (UP) of 0.5~1 parts by weight.By adding
Enter bisphenol A-type unsaturated polyester (UP) and improves the adhesive force for further increasing fire retardant.
A kind of preparation method of flame-retardant blended fabric, wherein the following steps are included:
1) fire-retardant treatment liquid is passed through the method padded to be applied on fabric, then carries out drying and processing, obtain the base for having fire-retardant
Cloth fabric；
2) it will be immersed in dye liquor with fire-retardant fabric fabric and carry out dyeing processing, the base after drying, after being dyed
Cloth fabric；
3) the fabric fabric after dyeing is carried out shaping into processing, obtains finished product flame-retardant blended fabric.
As the another embodiment of this case, wherein the mass ratio of fabric and fire-retardant treatment liquid is 100:8~10, the side padded
Formula is an immersing and rolling.
Specific embodiment and comparative example is listed below:
Embodiment 1:
A kind of flame-retardant blended fabric, flame-retardant blended fabric pad fire-retardant treatment liquid by fabric and obtain；Fabric includes following weight parts
Raw material hybrid woven form:
36 parts by weight of nylon fibre；
12 parts by weight of polytetrafluoroethylene fibre；
6 parts by weight of PBI fibre；
3 parts by weight of coir fibre；
2 parts by weight of Modal fiber；
2 parts by weight of apocynum fibre；
The quality percentage that fire retardant accounts for nylon fibre in nylon fibre contains 3%, and fire retardant is made of following components by mass parts:
20 parts of melamine；
12 parts of -1,3,5- triazine of 2,4,6- tri- (N- methylol)；
8 parts of ester of tricresyl phosphate (2,3- bis- chloropropyl).
Fire-retardant treatment liquid includes following components in parts by weight:
2,4- diamino -6-(3,3,3- tri- bromopropyls) 30 parts by weight of -1,3,5-triazines；
12 parts by weight of decabromodiphenyl oxide；
1 parts by weight of sulfated castor oil；
2 parts by weight of cellulose xanthate；
8 parts by weight of ethyl alcohol；
100 parts by weight of water；
4 parts by weight of ethylene group bis-stearamides；
0.5 parts by weight of antimony oxide；
0.5 parts by weight of bisphenol A-type unsaturated polyester (UP)；
A kind of preparation method of flame-retardant blended fabric, comprising the following steps:
1) fire-retardant treatment liquid is passed through the method padded to be applied on fabric, then carries out drying and processing, obtain the base for having fire-retardant
Cloth fabric；The mass ratio of fabric and fire-retardant treatment liquid is 100:8, and the mode padded is an immersing and rolling；
2) it will be immersed in dye liquor with fire-retardant fabric fabric and carry out dyeing processing, the base after drying, after being dyed
Cloth fabric；
3) the fabric fabric after dyeing is carried out shaping into processing, obtains finished product flame-retardant blended fabric.
Embodiment 2:
A kind of flame-retardant blended fabric, flame-retardant blended fabric pad fire-retardant treatment liquid by fabric and obtain；Fabric includes following weight parts
Raw material hybrid woven form:
39 parts by weight of nylon fibre；
14 parts by weight of polytetrafluoroethylene fibre；
7 parts by weight of PBI fibre；
5 parts by weight of coir fibre；
3 parts by weight of Modal fiber；
3 parts by weight of apocynum fibre；
The quality percentage that fire retardant accounts for the nylon fibre in nylon fibre contains 4%, and fire retardant presses mass parts group by following components
At:
24 parts of melamine；
14 parts of -1,3,5- triazine of 2,4,6- tri- (N- methylol)；
10 parts of ester of tricresyl phosphate (2,3- bis- chloropropyl)；
Fire-retardant treatment liquid includes following components in parts by weight:
2,4- diamino -6-(3,3,3- tri- bromopropyls) 32 parts by weight of -1,3,5-triazines；
14 parts by weight of decabromodiphenyl oxide；
2 parts by weight of sulfated castor oil；
3 parts by weight of cellulose xanthate；
12 parts by weight of ethyl alcohol；
100 parts by weight of water；
5 parts by weight of ethylene group bis-stearamides；
0.7 parts by weight of antimony oxide；
0.8 parts by weight of bisphenol A-type unsaturated polyester (UP)；
A kind of preparation method of flame-retardant blended fabric, comprising the following steps:
1) fire-retardant treatment liquid is passed through the method padded to be applied on fabric, then carries out drying and processing, obtain the base for having fire-retardant
Cloth fabric；The mass ratio of fabric and fire-retardant treatment liquid is 100:9, and the mode padded is an immersing and rolling；
2) it will be immersed in dye liquor with fire-retardant fabric fabric and carry out dyeing processing, the base after drying, after being dyed
Cloth fabric；
3) the fabric fabric after dyeing is carried out shaping into processing, obtains finished product flame-retardant blended fabric.
Embodiment 3:
A kind of flame-retardant blended fabric, flame-retardant blended fabric pad fire-retardant treatment liquid by fabric and obtain；Fabric includes following weight parts
Raw material hybrid woven form:
40 parts by weight of nylon fibre；
16 parts by weight of polytetrafluoroethylene fibre；
8 parts by weight of PBI fibre；
7 parts by weight of coir fibre；
4 parts by weight of Modal fiber；
4 parts by weight of apocynum fibre；
The quality percentage that fire retardant accounts for the nylon fibre in nylon fibre contains 5%, and fire retardant presses mass parts group by following components
At:
30 parts of melamine；
16 parts of -1,3,5- triazine of 2,4,6- tri- (N- methylol)；
13 parts of ester of tricresyl phosphate (2,3- bis- chloropropyl)；
Fire-retardant treatment liquid includes following components in parts by weight:
2,4- diamino -6-(3,3,3- tri- bromopropyls) 40 parts by weight of -1,3,5-triazines；
15 parts by weight of decabromodiphenyl oxide；
3 parts by weight of sulfated castor oil；
4 parts by weight of cellulose xanthate；
15 parts by weight of ethyl alcohol；
100 parts by weight of water；
7 parts by weight of ethylene group bis-stearamides；
1 parts by weight of antimony oxide；
1 parts by weight of bisphenol A-type unsaturated polyester (UP)；
A kind of preparation method of flame-retardant blended fabric, comprising the following steps:
1) fire-retardant treatment liquid is passed through the method padded to be applied on fabric, then carries out drying and processing, obtain the base for having fire-retardant
Cloth fabric；The mass ratio of fabric and fire-retardant treatment liquid is 100:10, and the mode padded is an immersing and rolling；
2) it will be immersed in dye liquor with fire-retardant fabric fabric and carry out dyeing processing, the base after drying, after being dyed
Cloth fabric；
3) the fabric fabric after dyeing is carried out shaping into processing, obtains finished product flame-retardant blended fabric.
Comparative example 1:
A kind of flame-retardant blended fabric, flame-retardant blended fabric pad fire-retardant treatment liquid by fabric and obtain；Fabric includes following weight parts
Raw material hybrid woven form:
36 parts by weight of nylon fibre；
12 parts by weight of polytetrafluoroethylene fibre；
3 parts by weight of coir fibre；
2 parts by weight of Modal fiber；
2 parts by weight of apocynum fibre；
The quality percentage that fire retardant accounts for nylon fibre in nylon fibre contains 3%, and fire retardant is made of following components by mass parts:
20 parts of melamine；
12 parts of -1,3,5- triazine of 2,4,6- tri- (N- methylol)；
8 parts of ester of tricresyl phosphate (2,3- bis- chloropropyl).
Fire-retardant treatment liquid includes following components in parts by weight:
2,4- diamino -6-(3,3,3- tri- bromopropyls) 30 parts by weight of -1,3,5-triazines；
12 parts by weight of decabromodiphenyl oxide；
1 parts by weight of sulfated castor oil；
2 parts by weight of cellulose xanthate；
8 parts by weight of ethyl alcohol；
100 parts by weight of water；
4 parts by weight of ethylene group bis-stearamides；
0.5 parts by weight of antimony oxide；
0.5 parts by weight of bisphenol A-type unsaturated polyester (UP)；
A kind of preparation method of flame-retardant blended fabric, comprising the following steps:
1) fire-retardant treatment liquid is passed through the method padded to be applied on fabric, then carries out drying and processing, obtain the base for having fire-retardant
Cloth fabric；The mass ratio of fabric and fire-retardant treatment liquid is 100:8, and the mode padded is an immersing and rolling；
2) it will be immersed in dye liquor with fire-retardant fabric fabric and carry out dyeing processing, the base after drying, after being dyed
Cloth fabric；
3) the fabric fabric after dyeing is carried out shaping into processing, obtains finished product flame-retardant blended fabric.
Comparative example 2:
A kind of flame-retardant blended fabric, flame-retardant blended fabric pad fire-retardant treatment liquid by fabric and obtain；Fabric includes following weight parts
Raw material hybrid woven form:
36 parts by weight of nylon fibre；
12 parts by weight of polytetrafluoroethylene fibre；
6 parts by weight of PBI fibre；
2 parts by weight of Modal fiber；
2 parts by weight of apocynum fibre；
The quality percentage that fire retardant accounts for nylon fibre in nylon fibre contains 3%, and fire retardant is made of following components by mass parts:
20 parts of melamine；
12 parts of -1,3,5- triazine of 2,4,6- tri- (N- methylol)；
8 parts of ester of tricresyl phosphate (2,3- bis- chloropropyl).
Fire-retardant treatment liquid includes following components in parts by weight:
2,4- diamino -6-(3,3,3- tri- bromopropyls) 30 parts by weight of -1,3,5-triazines；
12 parts by weight of decabromodiphenyl oxide；
1 parts by weight of sulfated castor oil；
2 parts by weight of cellulose xanthate；
8 parts by weight of ethyl alcohol；
100 parts by weight of water；
4 parts by weight of ethylene group bis-stearamides；
0.5 parts by weight of antimony oxide；
0.5 parts by weight of bisphenol A-type unsaturated polyester (UP)；
A kind of preparation method of flame-retardant blended fabric, comprising the following steps:
1) fire-retardant treatment liquid is passed through the method padded to be applied on fabric, then carries out drying and processing, obtain the base for having fire-retardant
Cloth fabric；The mass ratio of fabric and fire-retardant treatment liquid is 100:8, and the mode padded is an immersing and rolling；
2) it will be immersed in dye liquor with fire-retardant fabric fabric and carry out dyeing processing, the base after drying, after being dyed
Cloth fabric；
3) the fabric fabric after dyeing is carried out shaping into processing, obtains finished product flame-retardant blended fabric.
Comparative example 3:
A kind of flame-retardant blended fabric, flame-retardant blended fabric pad fire-retardant treatment liquid by fabric and obtain；Fabric includes following weight parts
Raw material hybrid woven form:
39 parts by weight of nylon fibre；
14 parts by weight of polytetrafluoroethylene fibre；
7 parts by weight of PBI fibre；
5 parts by weight of coir fibre；
3 parts by weight of Modal fiber；
3 parts by weight of apocynum fibre；
The quality percentage that fire retardant accounts for nylon fibre in nylon fibre contains 4%, and fire retardant is made of following components by mass parts:
24 parts of melamine；
10 parts of ester of tricresyl phosphate (2,3- bis- chloropropyl)；
Fire-retardant treatment liquid includes following components in parts by weight:
2,4- diamino -6-(3,3,3- tri- bromopropyls) 32 parts by weight of -1,3,5-triazines；
14 parts by weight of decabromodiphenyl oxide；
2 parts by weight of sulfated castor oil；
3 parts by weight of cellulose xanthate；
12 parts by weight of ethyl alcohol；
100 parts by weight of water；
5 parts by weight of ethylene group bis-stearamides；
0.7 parts by weight of antimony oxide；
0.8 parts by weight of bisphenol A-type unsaturated polyester (UP)；
A kind of preparation method of flame-retardant blended fabric, comprising the following steps:
1) fire-retardant treatment liquid is passed through the method padded to be applied on fabric, then carries out drying and processing, obtain the base for having fire-retardant
Cloth fabric；The mass ratio of fabric and fire-retardant treatment liquid is 100:9, and the mode padded is an immersing and rolling；
2) it will be immersed in dye liquor with fire-retardant fabric fabric and carry out dyeing processing, the base after drying, after being dyed
Cloth fabric；
3) the fabric fabric after dyeing is carried out shaping into processing, obtains finished product flame-retardant blended fabric.
Comparative example 4:
A kind of flame-retardant blended fabric, flame-retardant blended fabric pad fire-retardant treatment liquid by fabric and obtain；Fabric includes following weight parts
Raw material hybrid woven form:
39 parts by weight of nylon fibre；
14 parts by weight of polytetrafluoroethylene fibre；
7 parts by weight of PBI fibre；
5 parts by weight of coir fibre；
3 parts by weight of Modal fiber；
3 parts by weight of apocynum fibre；
The quality percentage that fire retardant accounts for the nylon fibre in nylon fibre contains 4%, and fire retardant presses mass parts group by following components
At:
24 parts of melamine；
14 parts of -1,3,5- triazine of 2,4,6- tri- (N- methylol)；
10 parts of ester of tricresyl phosphate (2,3- bis- chloropropyl)；
Fire-retardant treatment liquid includes following components in parts by weight:
2,4- diamino -6-(3,3,3- tri- bromopropyls) 32 parts by weight of -1,3,5-triazines；
2 parts by weight of sulfated castor oil；
3 parts by weight of cellulose xanthate；
12 parts by weight of ethyl alcohol；
100 parts by weight of water；
5 parts by weight of ethylene group bis-stearamides；
0.7 parts by weight of antimony oxide；
0.8 parts by weight of bisphenol A-type unsaturated polyester (UP)；
A kind of preparation method of flame-retardant blended fabric, comprising the following steps:
1) fire-retardant treatment liquid is passed through the method padded to be applied on fabric, then carries out drying and processing, obtain the base for having fire-retardant
Cloth fabric；The mass ratio of fabric and fire-retardant treatment liquid is 100:9, and the mode padded is an immersing and rolling；
2) it will be immersed in dye liquor with fire-retardant fabric fabric and carry out dyeing processing, the base after drying, after being dyed
Cloth fabric；
3) the fabric fabric after dyeing is carried out shaping into processing, obtains finished product flame-retardant blended fabric.
Comparative example 5:
A kind of flame-retardant blended fabric, flame-retardant blended fabric pad fire-retardant treatment liquid by fabric and obtain；Fabric includes following weight parts
Raw material hybrid woven form:
40 parts by weight of nylon fibre；
16 parts by weight of polytetrafluoroethylene fibre；
8 parts by weight of PBI fibre；
7 parts by weight of coir fibre；
4 parts by weight of Modal fiber；
4 parts by weight of apocynum fibre；
The quality percentage that fire retardant accounts for the nylon fibre in nylon fibre contains 5%, and fire retardant presses mass parts group by following components
At:
30 parts of melamine；
16 parts of -1,3,5- triazine of 2,4,6- tri- (N- methylol)；
13 parts of ester of tricresyl phosphate (2,3- bis- chloropropyl)；
Fire-retardant treatment liquid includes following components in parts by weight:
2,4- diamino -6-(3,3,3- tri- bromopropyls) 40 parts by weight of -1,3,5-triazines；
15 parts by weight of decabromodiphenyl oxide；
3 parts by weight of sulfated castor oil；
15 parts by weight of ethyl alcohol；
100 parts by weight of water；
7 parts by weight of ethylene group bis-stearamides；
1 parts by weight of antimony oxide；
1 parts by weight of bisphenol A-type unsaturated polyester (UP)；
A kind of preparation method of flame-retardant blended fabric, comprising the following steps:
1) fire-retardant treatment liquid is passed through the method padded to be applied on fabric, then carries out drying and processing, obtain the base for having fire-retardant
Cloth fabric；The mass ratio of fabric and fire-retardant treatment liquid is 100:10, and the mode padded is an immersing and rolling；
2) it will be immersed in dye liquor with fire-retardant fabric fabric and carry out dyeing processing, the base after drying, after being dyed
Cloth fabric；
3) the fabric fabric after dyeing is carried out shaping into processing, obtains finished product flame-retardant blended fabric.
Comparative example 6:
A kind of flame-retardant blended fabric, flame-retardant blended fabric pad fire-retardant treatment liquid by fabric and obtain；Fabric includes following weight parts
Raw material hybrid woven form:
40 parts by weight of nylon fibre；
16 parts by weight of polytetrafluoroethylene fibre；
8 parts by weight of PBI fibre；
7 parts by weight of coir fibre；
4 parts by weight of Modal fiber；
4 parts by weight of apocynum fibre；
The quality percentage that fire retardant accounts for the nylon fibre in nylon fibre contains 5%, and fire retardant presses mass parts group by following components
At:
30 parts of melamine；
16 parts of -1,3,5- triazine of 2,4,6- tri- (N- methylol)；
13 parts of ester of tricresyl phosphate (2,3- bis- chloropropyl)；
Fire-retardant treatment liquid includes following components in parts by weight:
2,4- diamino -6-(3,3,3- tri- bromopropyls) 40 parts by weight of -1,3,5-triazines；
15 parts by weight of decabromodiphenyl oxide；
3 parts by weight of sulfated castor oil；
4 parts by weight of cellulose xanthate；
15 parts by weight of ethyl alcohol；
100 parts by weight of water；
7 parts by weight of ethylene group bis-stearamides；
1 parts by weight of antimony oxide；
A kind of preparation method of flame-retardant blended fabric, comprising the following steps:
1) fire-retardant treatment liquid is passed through the method padded to be applied on fabric, then carries out drying and processing, obtain the base for having fire-retardant
Cloth fabric；The mass ratio of fabric and fire-retardant treatment liquid is 100:10, and the mode padded is an immersing and rolling；
2) it will be immersed in dye liquor with fire-retardant fabric fabric and carry out dyeing processing, the base after drying, after being dyed
Cloth fabric；
3) the fabric fabric after dyeing is carried out shaping into processing, obtains finished product flame-retardant blended fabric.
The performance test results of embodiment and comparative example are listed below:
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 | Comparative example 4 | Comparative example 5 | Comparative example 6 | |
| Oxygen index (OI) LOI value, % | 29.8 | 31.4 | 32.7 | 24.3 | 28.7 | 26.1 | 27.3 | 30.4 | 28.6 |
By the test data in table 1 it is found that Examples 1 to 3 is compared with comparative example 1~6, flame retardant property is preferable, therefore can be more
It is good to be applied to require textile in fire-retardant field.
Although the embodiments of the present invention have been disclosed as above, but its is not only in the description and the implementation listed
With it can be fully applied to various fields suitable for the present invention, for those skilled in the art, can be easily
Realize other modification, therefore without departing from the general concept defined in the claims and the equivalent scope, the present invention is simultaneously unlimited
In specific details.
Claims (10)
1. a kind of flame-retardant blended fabric, which is characterized in that the flame-retardant blended fabric pads fire-retardant treatment liquid by fabric and obtains；Institute
The raw material hybrid woven that fabric includes following weight parts is stated to form:
36~40 parts by weight of nylon fibre；
12~16 parts by weight of polytetrafluoroethylene fibre；
6~8 parts by weight of PBI fibre；
3~7 parts by weight of coir fibre.
2. flame-retardant blended fabric according to claim 1, which is characterized in that further include the Modal fiber of 2~4 parts by weight.
3. flame-retardant blended fabric according to claim 1, which is characterized in that further include the bluish dogbane fibre of 2~4 parts by weight
Dimension.
4. flame-retardant blended fabric according to claim 1, which is characterized in that fire retardant accounts for the brocade in the nylon fibre
The quality percentage of synthetic fibre fiber contains 3~5%, and the fire retardant is made of following components by mass parts:
20~30 parts of melamine；
12~16 parts of -1,3,5- triazine of 2,4,6- tri- (N- methylol)；
8~13 parts of ester of tricresyl phosphate (2,3- bis- chloropropyl).
5. flame-retardant blended fabric according to claim 1, which is characterized in that the fire-retardant treatment liquid includes following weight parts
Component:
2,4- diamino -6-(3,3,3- tri- bromopropyls) 30~40 parts by weight of -1,3,5-triazines；
12~15 parts by weight of decabromodiphenyl oxide；
1~3 parts by weight of sulfated castor oil；
2~4 parts by weight of cellulose xanthate；
8~15 parts by weight of ethyl alcohol；
100 parts by weight of water.
6. flame-retardant blended fabric according to claim 5, which is characterized in that further include 4~7 parts by weight ethylene group it is double hard
Acyl amine.
7. flame-retardant blended fabric according to claim 5, which is characterized in that further include three oxidations two of 0.5~1 parts by weight
Antimony.
8. flame-retardant blended fabric according to claim 5, which is characterized in that further include the bisphenol A-type of 0.5~1 parts by weight
Unsaturated polyester (UP).
9. the preparation method of described in any item flame-retardant blended fabrics according to claim 1~8, which is characterized in that including following
Step:
1) fire-retardant treatment liquid is passed through the method padded to be applied on the fabric, then carries out drying and processing, had
Fire-retardant fabric fabric；
2) it will be immersed in dye liquor with fire-retardant fabric fabric and carry out dyeing processing, the base after drying, after being dyed
Cloth fabric；
3) the fabric fabric after dyeing is carried out shaping into processing, obtains finished product flame-retardant blended fabric.
10. the preparation method of flame-proof antibiotic fabric according to claim 9, which is characterized in that the fabric and the resistance
The mass ratio for firing treatment fluid is 100:8~10, and the mode padded is an immersing and rolling.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910500761.6A CN110284325A (en) | 2019-06-11 | 2019-06-11 | A kind of flame-retardant blended fabric and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910500761.6A CN110284325A (en) | 2019-06-11 | 2019-06-11 | A kind of flame-retardant blended fabric and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110284325A true CN110284325A (en) | 2019-09-27 |
Family
ID=68004313
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910500761.6A Pending CN110284325A (en) | 2019-06-11 | 2019-06-11 | A kind of flame-retardant blended fabric and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110284325A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110983566A (en) * | 2019-12-18 | 2020-04-10 | 晋江市远祥服装织造有限公司 | Bio-based nylon fabric and preparation method and product thereof |
| CN111016348A (en) * | 2019-11-25 | 2020-04-17 | 江苏惟妙纺织科技有限公司 | Antibacterial, mildew-proof and peculiar smell-eliminating lace |
| CN111041831A (en) * | 2019-12-11 | 2020-04-21 | 扬州博思特新材料科技有限公司 | Production process of base fabric with flame-retardant function |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110073331A1 (en) * | 2009-08-11 | 2011-03-31 | H & C Scientific Resources International, LLC | Ionic Liquid Flame Retardants |
| CN105919196A (en) * | 2016-06-17 | 2016-09-07 | 优纤科技（丹东）有限公司 | Flame-retardant chinlon blended fabric and making method thereof |
| CN109826009A (en) * | 2019-02-20 | 2019-05-31 | 南通薇星纺织科技有限公司 | A kind of flame-proof antibiotic fabric |
| CN109853230A (en) * | 2019-02-20 | 2019-06-07 | 南通薇星纺织科技有限公司 | A kind of temperature-resistant flame retarding fabric |
-
2019
- 2019-06-11 CN CN201910500761.6A patent/CN110284325A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110073331A1 (en) * | 2009-08-11 | 2011-03-31 | H & C Scientific Resources International, LLC | Ionic Liquid Flame Retardants |
| CN105919196A (en) * | 2016-06-17 | 2016-09-07 | 优纤科技（丹东）有限公司 | Flame-retardant chinlon blended fabric and making method thereof |
| CN109826009A (en) * | 2019-02-20 | 2019-05-31 | 南通薇星纺织科技有限公司 | A kind of flame-proof antibiotic fabric |
| CN109853230A (en) * | 2019-02-20 | 2019-06-07 | 南通薇星纺织科技有限公司 | A kind of temperature-resistant flame retarding fabric |
Non-Patent Citations (5)
| Title |
|---|
| 《实用化学品配方手册》编委会: "《实用化学品配方手册》", 31 January 2009, 四川科学技术出版社 * |
| 丹东市轻化工研究所: "《制革化工材料手册》", 31 December 1986, 轻工业出版社 * |
| 朱美芳等: "《中国战略性新兴产业 新材料 高性能纤维》", 30 November 2017, 中国铁道出版社 * |
| 欧育相: "《阻燃剂》", 30 September 2009, 国防工业出版社 * |
| 霍红等: "《纺织商品学（第2版）》", 30 June 2014, 中国财富出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111016348A (en) * | 2019-11-25 | 2020-04-17 | 江苏惟妙纺织科技有限公司 | Antibacterial, mildew-proof and peculiar smell-eliminating lace |
| CN111041831A (en) * | 2019-12-11 | 2020-04-21 | 扬州博思特新材料科技有限公司 | Production process of base fabric with flame-retardant function |
| CN110983566A (en) * | 2019-12-18 | 2020-04-10 | 晋江市远祥服装织造有限公司 | Bio-based nylon fabric and preparation method and product thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US8003555B2 (en) | Flame retardant synthetic fiber, flame retardant fiber composite, production method therefor and textile product | |
| CN110284325A (en) | A kind of flame-retardant blended fabric and preparation method thereof | |
| EP0533931B1 (en) | Fabric made from blended yarn comprising aromatic polyamide fiber and polyester fiber | |
| US20120270456A1 (en) | Flame retardant fabric for protective clothing | |
| CN102926155B (en) | Nitrile/cotton/wool acid-base resisting fire retardant fabric and manufacture method thereof | |
| CN107604658A (en) | The inflaming retarding fabric for producing the method for inflaming retarding fabric and obtaining | |
| CN107385544A (en) | A kind of flame-resistant terylene protective garment fabric | |
| TWI530597B (en) | A flame retardant fiber aggregate and a method for manufacturing the same, and a fiber product | |
| US20220167700A1 (en) | Flame-retardant fiber composite and flame-retardant working clothes | |
| US4014829A (en) | Flame resistant fiber blends | |
| CN105839267B (en) | PSA fiber flame-retardant blended fabric | |
| EP3245320B1 (en) | Flame resistant fabric | |
| EP1798318A1 (en) | Flame-retardant synthetic fiber, flame-retardant fiber composite, and upholstered furniture product made with the same | |
| CN105780260B (en) | PSA fiber flame-retardant blended fabric | |
| US10760185B2 (en) | Acrylonitrile-containing fiber dyeable with disperse dyes, method for producing same, and fiber product containing same | |
| JP2022003177A (en) | Dyed fabric and textile product | |
| CN104441811A (en) | High-strength low-shrinkage polyester filament | |
| CN107604657A (en) | The hotel sheet of flame-proof antibiotic is applied mechanically fabric and preparation method thereof | |
| US20070237953A1 (en) | Flame resistant synthetic fiber, flame resistant fiber composite and upholstered furniture products using the same | |
| CN210066038U (en) | Cotton gentle high strength blended yarn | |
| Economy | Phenolic fibers | |
| Kocak et al. | 18 Polymers for the Textile | |
| CN112267309A (en) | Knitting protective clothing weaving dyeing and finishing process | |
| WO2023171286A1 (en) | Flame retardant cloth and flame retardant work clothing | |
| CN113040454A (en) | Military uniform fabric |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190927 |