CN110270012A - Graphene hair tonic device - Google Patents
Graphene hair tonic device Download PDFInfo
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- CN110270012A CN110270012A CN201910417745.0A CN201910417745A CN110270012A CN 110270012 A CN110270012 A CN 110270012A CN 201910417745 A CN201910417745 A CN 201910417745A CN 110270012 A CN110270012 A CN 110270012A
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- graphene
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- heat generating
- powder
- hair tonic
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61H—PHYSICAL THERAPY APPARATUS, e.g. DEVICES FOR LOCATING OR STIMULATING REFLEX POINTS IN THE BODY; ARTIFICIAL RESPIRATION; MASSAGE; BATHING DEVICES FOR SPECIAL THERAPEUTIC OR HYGIENIC PURPOSES OR SPECIFIC PARTS OF THE BODY
- A61H23/00—Percussion or vibration massage, e.g. using supersonic vibration; Suction-vibration massage; Massage with moving diaphragms
- A61H23/02—Percussion or vibration massage, e.g. using supersonic vibration; Suction-vibration massage; Massage with moving diaphragms with electric or magnetic drive
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
- A61N5/00—Radiation therapy
- A61N5/06—Radiation therapy using light
- A61N5/0613—Apparatus adapted for a specific treatment
- A61N5/0616—Skin treatment other than tanning
- A61N5/0617—Hair treatment
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
- A61N5/00—Radiation therapy
- A61N5/06—Radiation therapy using light
- A61N5/0613—Apparatus adapted for a specific treatment
- A61N5/0625—Warming the body, e.g. hyperthermia treatment
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61H—PHYSICAL THERAPY APPARATUS, e.g. DEVICES FOR LOCATING OR STIMULATING REFLEX POINTS IN THE BODY; ARTIFICIAL RESPIRATION; MASSAGE; BATHING DEVICES FOR SPECIAL THERAPEUTIC OR HYGIENIC PURPOSES OR SPECIFIC PARTS OF THE BODY
- A61H2201/00—Characteristics of apparatus not provided for in the preceding codes
- A61H2201/16—Physical interface with patient
- A61H2201/1602—Physical interface with patient kind of interface, e.g. head rest, knee support or lumbar support
- A61H2201/1604—Head
- A61H2201/1607—Holding means therefor
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61H—PHYSICAL THERAPY APPARATUS, e.g. DEVICES FOR LOCATING OR STIMULATING REFLEX POINTS IN THE BODY; ARTIFICIAL RESPIRATION; MASSAGE; BATHING DEVICES FOR SPECIAL THERAPEUTIC OR HYGIENIC PURPOSES OR SPECIFIC PARTS OF THE BODY
- A61H2205/00—Devices for specific parts of the body
- A61H2205/02—Head
- A61H2205/021—Scalp
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
- A61N5/00—Radiation therapy
- A61N5/06—Radiation therapy using light
- A61N2005/0658—Radiation therapy using light characterised by the wavelength of light used
- A61N2005/0659—Radiation therapy using light characterised by the wavelength of light used infrared
- A61N2005/066—Radiation therapy using light characterised by the wavelength of light used infrared far infrared
Abstract
The invention belongs to physiotherapy products technical fields, more particularly to a kind of graphene hair tonic device, including shell, circuit board and graphene heat generating component, the shell is provided with head dummy chamber compatible with head shape, the graphene heat generating component and the circuit board are arranged at the inside of the shell, and the graphene heat generating component and the circuit board electrical connection, the side of the shell is provided with the electrical interface with the circuit board electrical connection.Graphene hair tonic device of the invention is when in use, after energization, thermogenetic effect and resonance effects can be generated on the head of human body by the far infrared that graphene heat generating component generates, head scalp location is set to generate high-frequency vibration, the free radical of oxidation can be removed profoundly by skin corium to epidermis, promote the blood circulation of scalp capilary, to realize the case where reducing alopecia generation, and auxiliary allows hair preferably to grow.
Description
Technical field
The invention belongs to physiotherapy products technical field more particularly to a kind of graphene hair tonic devices.
Background technique
Modern society, it is often excessive because of stress in life, work, learning process, it is nervous, often endure
The reason at night etc. causes the time of having a rest of people to reduce, and generates insomnia anxiety, so that it is tight to cause people to be chronically at spirit
Or the state of imbalance.And when people are chronically at spiritual tight or imbalance state, it also will cause falling off for hair, even
The good growth of hair is influenced, and then the spirit for further resulting in people is more tight or lacks of proper care, for a long time in this way, to people's
Life and work can all cause strong influence.
Summary of the invention
The purpose of the present invention is to provide a kind of graphene hair tonic devices, it is intended to solve people in the prior art and exist
The technical issues of hair is detached from and can not well grow.
To achieve the above object, a kind of graphene hair tonic device provided in an embodiment of the present invention, including shell, circuit board
With graphene heat generating component, the shell is provided with head dummy chamber compatible with head shape, the graphene heat generating component and
The circuit board is arranged at the inside of the shell, and the graphene heat generating component and the circuit board electrical connection, described
The side of shell is provided with the electrical interface with the circuit board electrical connection.
Said one or multiple technical solutions in graphene hair tonic device provided in an embodiment of the present invention at least have such as
One of lower technical effect: in use, shell is worn on the head of human body, wherein the head dummy chamber being arranged on shell and wearing
The head of person is adapted, and electrical interface is connect by power supply line with extraneous power supply, so realizes the graphite being electrically connected with electrical interface
The power supply of alkene heat generating component, graphene heat generating component may be implemented to be rapidly heated, and the far infrared that graphene heat generating component generates
Thermogenetic effect and resonance effects can be generated on the head of human body, head scalp location is made to generate high-frequency vibration, it can be by skin corium
It removes the free radical of oxidation profoundly to epidermis, promotes the blood circulation of scalp capilary, reduce alopecia to realize
It happens, and auxiliary allows hair preferably to grow.
To achieve the above object, another embodiment of the present invention provides a kind of graphene hair tonic device comprising shell,
Circuit board, battery and graphene heat generating component, the shell are provided with head dummy chamber compatible with head shape, the graphite
Alkene heat generating component, the battery and the circuit board are arranged at the inside of the shell, the graphene heat generating component and institute
State circuit board electrical connection, the battery and the circuit board electrical connection.
Said one or multiple technical solutions in graphene hair tonic device provided in an embodiment of the present invention at least have such as
One of lower technical effect: in use, shell is worn on the head of human body, wherein the head dummy chamber being arranged on shell and wearing
The head of person is adapted, and battery is the power supply of graphene heat generating component, and graphene heat generating component may be implemented to be rapidly heated, and stone
The far infrared that black alkene heat generating component generates can generate thermogenetic effect and resonance effects on the head of human body, make head scalp
Position generates high-frequency vibration, and the free radical of oxidation can be removed profoundly by skin corium to epidermis, promotes scalp capilary
Blood circulation, to realize the case where reducing alopecia generation, and auxiliary allows hair preferably to grow.
Detailed description of the invention
To describe the technical solutions in the embodiments of the present invention more clearly, embodiment or the prior art will be retouched below
Attached drawing needed in stating is briefly described, it should be apparent that, the accompanying drawings in the following description is only of the invention one
A little embodiments for those of ordinary skill in the art without any creative labor, can also basis
These attached drawings obtain other attached drawings.
Fig. 1 is the structural schematic diagram of graphene hair tonic device provided in an embodiment of the present invention.
Fig. 2 is the structural schematic diagram at another visual angle of the graphene hair tonic device in Fig. 1.
Fig. 3 is that the graphene hair tonic device in Fig. 1 hides the structural schematic diagram after upper cover.
Fig. 4 is the partial structurtes enlarged diagram at the A in Fig. 3.
Fig. 5 is the structural decomposition diagram of the graphene hair tonic device in Fig. 1.
Fig. 6 is the structural schematic diagram of the fixing seat of graphene hair tonic device provided in an embodiment of the present invention.
Fig. 7 is the cut away view of the graphene heat generating component of graphene hair tonic device provided in an embodiment of the present invention.
Fig. 8 is the exploded view of the graphene heat generating component of graphene hair tonic device provided in an embodiment of the present invention.
Wherein, each appended drawing reference in figure:
1-2-graphene of component body fever 10-shell of composite material
11-upper cover 12-liner, 20-graphene heat generating components
21-the first the 23-the second adhesive layer of 22-substrate layer of adhesive layer
24-conductive sheet 25-fever, 26-packaging insulating of line layer layers
40-electrical interface 50-fixing seat, 51-battery cavities
52-convex block 53-embedding slot, 60-batteries
70-circuit board 71-button, 101-head dummy chambers
102-ears avoid the annular block edge of 121-cabinet body of position 122-
1221-1222-emptiness avoiding holes of elastic card column.
Specific embodiment
The embodiment of the present invention is described below in detail, examples of the embodiments are shown in the accompanying drawings, wherein from beginning to end
Same or similar label indicates same or similar element or element with the same or similar functions.Below with reference to
The embodiment that attached drawing 1~8 describes is exemplary, it is intended to embodiment for explaining the present invention, and should not be understood as to this hair
Bright limitation.
In one embodiment of the invention, as shown in Fig. 1~5, a kind of graphene hair tonic device, including shell are provided
10, circuit board 70 and graphene heat generating component 20, the shell 10 are provided with head dummy chamber 101 compatible with head shape, lead to
Often, which is similar to semicircular structure, and the head that lid is located at human body can steadily place the entire stone
Black alkene hair tonic device.Further, the graphene heat generating component 20 and the circuit board 70 are arranged at the shell 10
Inside, shell 10 can accommodate graphene heat generating component 20 and circuit board 70, and it is possible to support graphene heat generating component 20
With with circuit board 70.Further, the graphene heat generating component 20 is electrically connected with the circuit board 70, the shell 10
Side is provided with the electrical interface 40 being electrically connected with the circuit board 70.Electrical interface 40 can connect extraneous electricity by power supply line
Source can realize power supply in this way for graphene heat generating component 20.Graphene hair tonic device provided in an embodiment of the present invention specifically makes
Shell 10 is worn on the head of human body by the used time, wherein the head phase of the head dummy chamber 101 being arranged on shell 10 and wearer
Adaptation, electrical interface 40 are connect by power supply line with extraneous power supply, so realize the graphene fever being electrically connected with electrical interface 40
Component 20 is powered, and graphene heat generating component 20 may be implemented to be rapidly heated, and the far infrared that graphene heat generating component 20 generates
Thermogenetic effect and resonance effects can be generated on the head of human body, head scalp location is made to generate high-frequency vibration, it can be by skin corium
It removes the free radical of oxidation profoundly to epidermis, promotes the blood circulation of scalp capilary, to realize reduction alopecia
The case where occur, and auxiliary allow hair preferably to grow.
Graphene heat generating component 20 provided in an embodiment of the present invention, uniformly, electric conversion efficiency is high for fever, heating speed
Degree is fast, and heating efficiency is high, and the first adhesive-layer can improve the whole bonding with component body of graphene fever composite material and stablize
Property, and the second adhesive-layer then improves the bonding stability between conductive sheet and substrate, in addition, two layers of glue-line carries out heat
Barrier, trap heat effect can be reduced the heat of fever output to component body and its internal transmitting, reduce the damage of heat
It loses, and heat is avoided to impact component body inside component, to graphene-copper composite conducting piece and fever route institute
The heat of generation plays the role of heat preservation, reduces heat transfer loss；And conductive sheet and fever line layer are set to graphene hair
The periphery of hot component 20, the heat sense of touch generated after electric heating conversion is obvious, and fever, heating use feeling are obvious；And it is outermost
Packaging insulating layer plays the role of insulation, avoids the electric current of conductive sheet and fever line layer and voltage from causing electric shock phenomenon, mentions
The high safety in utilization of graphene heat generating component 20.
Wherein, heating circuit layer is made by graphene heat generating pastes in the printing of the shapes such as " returning " shape, Z-shaped, snakelike.Institute
Stating component body can be laminating with graphene fever composite material to be rodlike, planar etc., and heating bar, heating film, hair is made
The electric heating products such as heat pad.
Preferably, the substrate layer is that outer surface and inner surface pass through the PET film of sided corona treatment, PVC film, PE
One of film, PC film, PEN film and PP film；First adhesive layer and the second adhesive layer can be organic silica gel
Adhesion coating, epoxy resin adhesive layer, polyurethane adhesive adhesion coating, polyamide hot melt adhesive layer, polyolefin hot-melt layer and EVA hot-melt adhesive
One of layer；The packaging insulating layer includes 40-60 parts of glass powders, 15-25 parts of silica, 3-8 parts of hydroxyethyl celluloses
With 60-80 parts of terpinols.
In the embodiment of the present invention, sided corona treatment is carried out by the both side surface to substrate layer, the first adhesive-layer can be improved
With the second adhesive-layer respectively to the adhesive force of substrate layer, improve between the first adhesive-layer and substrate layer, the second adhesive-layer and substrate
Bonding stability between layer；And use PET film, PVC film, PE film, PC film, PEN film or PP film as base
The raw material of material layer, thermal stability is high, and shrinking percentage is small, and the mechanical performances such as intensity, toughness, impact strength with foot prop, with
First adhesive-layer, the adhesive force of the second adhesive-layer are high, and bonding is stablized, and is not easily disconnected from or is layered；And the organic silicone adhesive used
Layer, epoxy resin adhesive layer, polyurethane adhesive adhesion coating, polyamide hot melt adhesive layer, polyolefin hot-melt layer and EVA hot-melt adhesive layer,
Adhesion strength is high, and thermal stability is high, can stablize with component body surface, substrate layer, conductive sheet and bond, it is de- to be less prone to interlayer
From the phenomenon that, and pyroconductivity is low, and heat insulation is good, effectively reduces thermally conductive sheet and the heat that route generates of generating heat is to component sheet
Internal portion's transmitting, reduces the loss of heat.
And the raw material of glass powder, silica, hydroxyethyl cellulose and terpinol as packaging insulating layer is used, it can mention
Height avoids electric shock phenomenon, causes safety accident to the Current Voltage insulating effect in fever route and conductive sheet；Wherein, it uses
Glass powder partial size it is small, structural disorder, chemical stability is high, and has stronger steric hindrance ability, can be uniformly dispersed in insulating layer
In system, the performances such as anti-flammability, insulating properties, weatherability and the resistance to scraping of insulating layer are improved；And the silica titanium dioxide used
The electrical insulation capability of silica glass is splendid, and at normal temperature, resistance is equivalent to 100 times of simple glass, to the dielectric absorption of whole frequencies
Very small, insulation compressive resistance is big, and packaging insulating effect is good；And the hydroxyethyl cellulose used can improve insulating layer system
Viscosity improves dispersibility and degree of adhesion between each raw material, so that the insulating layer of colloidal is formed, with fever route, conduction
Piece stablizes bonding connection.And the terpinol used can promote the dispersibility and degree of mixing of each raw material of insulating layer, improve insulating materials
Dispersing uniformity.
Preferably, the graphene-copper composite conducting piece includes the raw material of following parts by weight: black alkene nano-powder 15-20
Part, 30-40 parts of Nano metal powder, 50-60 parts of methyl vinyl silicone rubber, 0.5-1.5 parts of hydroxyl-terminated injecting two methyl siloxane,
4-8 parts of vinyltrimethoxysilane, 3-8 parts of precipitated silica, 5-10 parts of conductive black, 0.5-1.0 parts of hydroxy silicon oil, sulphur
0.5-1.0 parts of agent.
In the embodiment of the present invention, by using above-mentioned raw material as conductive sheet, conductive metal mixing is embedded in silicon rubber
In matrix body, the bond strength of the two is high, and anti-pressure ability is strong, and metal-powder is not fallen, and conductive sheet obtained is flexible high, leads
Electrically high, electron transfer flow rate is high, and intensity is high, and impact strength is good；Wherein, the graphene nano powder of use, nanometer
Metal powder resistivity is small, makes silicone rubber matrix electric conductivity with higher, and conductive black can improve the anti-of conductive sheet
Antistatic property avoids electrostatic from causing decaying etc. to influence the transmission of electric current, while conductive black and graphene nano powder, receiving
Rice metal powder is used in combination, and interparticle spacing becomes smaller, and the interparticle probability increase that contacts with each other increases the electric conductivity of silicon rubber,
Conductive black of the superconductive carbon black of use as antistatic silicone rubber, partial size is small, is used in combination with acetylene carbon black, and interparticle
Away from becoming smaller, the interparticle probability increase that contacts with each other increases the electric conductivity of silicone rubber matrix, keeps conductive sheet with higher
Conductivity.
And the hydroxyl-terminated injecting two methyl siloxane used is avoided that silicone rubber matrix is hardened, plasticity is lower, processing
The structuring phenomenons such as reduced performance improve the stability of silicone rubber matrix, and hydroxyl-terminated injecting two methyl siloxane and precipitating are white
The Si-OH base of carbon blacksurface reacts, and is allowed to hydrophobization, and more raising graphene nano powder, Nano metal powder and conductive black exist
Dispersibility in silicon rubber system, and inhibit the structuring of silicon rubber；And pass through strict control hydroxyl-terminated injecting two methyl siloxane
Dosage, the mechanical performances such as obtained conductive sheet intensity with higher, impact resistance can be made to reduce if dosage is excessive
The flexibility of conductive sheet, hardness is excessive, and plasticity and processing forming are lower；And if dosage is very few, reduces conductive material
Dispersibility and adhesive bond, are easy to appear structuring phenomenon.
And the vinyltrimethoxysilane used can promote the crosslinking coupling reaction of conductive tablet raw material, and make obtained
Conductive sheet surface is without sense is sticked, so that fever route slurry is easy to spread apart on conductive sheet surface, adhesive force is high, between the two
Bonding is stablized；And the precipitated silica used can be as the filler of silicone rubber matrix, and can improve the machine of silicone rubber matrix
Tool intensity, stability is high, but according to traditional gas-phase silica, can reduce the flexibility of silicon rubber, keep its hardness excessive,
Reduce the flexibility and processing forming of conductive sheet；And the hydroxy silicon oil used can improve powder (graphene nano powder is received
Rice metal powder, precipitated silica, conductive black) dispersibility in silicone rubber matrix, and the structure of silicone rubber matrix can be inhibited
Change, improves the plasticity and processing performance of conductive sheet obtained；And the vulcanizing agent used can then promote the molding of conductive sheet, surely
Qualitative height.
Preferably, the Nano metal powder is made of copper nanoparticle and nano-nickel powder with weight ratio for 5-6:1-2:2-3
Mixture, the spherical silver that the copper nanoparticle is surface to be coated by nano-silver powder coats copper powder；The methyl ethylene silicon rubber
The contents of ethylene of glue is 0.14-0.18%, and molecular weight is 55-65 ten thousand；The hydroxy radical content of the hydroxy silicon oil is 4-8%；Institute
Stating vulcanizing agent is 2,5- dimethyl -2,5- di-t-butyl hexane peroxide.
In the embodiment of the present invention, by using copper nanoparticle and nano-nickel powder as conductive metal powder, resistivity is small, leads
Electric rate is high, and fine size, and wherein the three-dimensional bead chain shape structure of nano-nickel powder can make silicone rubber matrix form stable conductive mesh
Network makes silicone rubber matrix conductivity with higher, and copper nanoparticle therein coats its surface by using nano-silver powder,
The silver layer volume resistivity that surface is coated is low, effectively reduces the volume resistivity of the entire particle of spherical silver coated copper, increases
The electric conductivity of conductive sheet.
And in the embodiment of the present invention, pass through the contents of ethylene and molecular weight of strict control methyl vinyl silicone rubber, benefit
With the long characteristic of its high molecular weight, main chain, intermolecular active force is larger, conductive sheet obtained can be made to have preferably mechanical
Intensity and processing forming；And the hydroxy radical content of strict control hydroxy silicon oil, it can make hydroxy silicon oil that there is lower viscosity, energy
Inhibit the structuring phenomenon of silicone rubber matrix, and combines the activity of terminal hydroxy group, the dispersibility of powder in raising system.And pass through
Using 2,5- dimethyl -2,5- di-t-butyl hexane peroxide as vulcanizing agent, the vulcanization crosslinking that can improve silicone rubber matrix is made
With it is mechanical strong to improve tensile strength, elongation at break, tearing strength of silicon rubber after molding etc. for significant shortening vulcanization time
Degree and stability.
Preferably, the graphene-copper composite conducting piece is made by following steps；
Step A: in parts by weight, being stirred mixing for methyl vinyl silicone rubber, and material A is made；
Step B: in parts by weight, the precipitated silica of the dosage of one third is added to material made from step A
In A, hydroxyl-terminated injecting two methyl siloxane, vinyltrimethoxysilane and hydroxy silicon oil are then sequentially added, every kind of raw material adds
It is uniform to enter to mix to stock dispersion, then remaining precipitated silica is added in two portions, is mixed evenly, is made
Material B；
Step C: in parts by weight, graphene nano powder, Nano metal powder and conductive black are added to step B
In material B obtained, stir mixing is agglomerating, and material C is made；
Step D: by the agglomerating rear material C heating refining glue obtained of step C mixing, discharging, mill is uniform, and sulphur is then added
Agent stirs evenly, and lower roll is cut, and graphene-copper composite conducting piece is made.
In the step A, the time for stirring mixing is 5-15min；In the step D, the heating refining glue specific steps
Are as follows: the agglomerating rear material C obtained of step C mixing is warming up to 90-100 DEG C, vacuumize process is then carried out, is made and mediates material,
Subsequent discharge process is carried out again；The time of the vacuumize process be 120-130min, vacuum degree be -0.06MPa~-
0.08MPa。
In the embodiment of the present invention, graphene-copper composite conducting piece is prepared by using above-mentioned steps, and strict control is each
Step parameter, convenient operation and control, quality are stablized, and high production efficiency, production cost is low, can make black alkene-copper composite guide obtained
Electric piece has lower resistivity and higher conductivity, and electric conductivity is good, while having preferable tensile strength, pulling apart and stretch
The mechanical performances such as long rate and tearing strength, stability is high, can large-scale industrial production；Wherein, pass through other objects of strict control
The addition sequence and processing parameter of material, first precipitated silica is added in equivalent in batches, can improve precipitated silica in silicon rubber base
Dispersibility in body improves the mechanical strength of silicone rubber matrix, and hydroxyl-terminated injecting two methyl siloxane and release agent energy is then added
It avoids precipitated silica that silicon rubber is made to be easy to structuring phenomenon occur when improving silicone rubber mechanical performance, inhibits silicon rubber
The structuring phenomenon of glue；Meanwhile vinyltrimethoxysilane and hydroxy silicon oil being added into silicone rubber matrix, promote object
The cross-linked polymeric of material and the dispersibility of mixed system improve the dispersing uniformity of the conductive metal powder of subsequent addition, improve silicon
The conductivity and processing forming of rubber matrix；The vulcanization crosslinking that vulcanizing agent promotes each material of silicon rubber is finally added, is improved
The mechanical strength and stability of silicone rubber matrix.
Preferably, the graphene heat generating pastes include the raw material of following parts by weight: modified graphene oxide nano-powder
20-40 parts, 10-15 parts of copper nanoparticle, 30-50 parts of epoxy resin, epoxy acrylate, 20-25 parts, 1-3 parts of methylimidazole,
1-3 parts of silane coupling agent, 0.5-2.0 parts of curing agent, 50-60 parts of solvent.
In the embodiment of the present invention, graphene heat generating pastes are prepared by using the raw material of mentioned kind, hair obtained can be made
Hot line road has preferable electric conductivity and thermal conductivity, and is easy to be coated on conductive sheet surface, and ductility is good, and heater is made to generate heat
Uniformly；Wherein, by using modified graphene oxide nano-powder, can with the graphene nano powder phase separation of conductive sheet,
Electron transfer rate is close, and the migration of electronics can be promoted to flow, and flows so that electric current migrates between conductive sheet and fever route
Electric conductivity bond strength that is smooth, realizing conductive sheet between the route that generates heat, electric conductivity is excellent, and heating efficiency is high.
Wherein, the main body by using epoxy resin and epoxy acrylate as slurry can be such that slurry has preferable
Adhesive force, ductility and mobility can uniformly and be steadily attached on conductive sheet, preferably be led so that fever route has
Electrical property and thermal conductivity, uniformly, heating efficiency is high, wherein containing one or two in the epoxy molecule structure used for fever
Stable tridimensional network system can be formed after above epoxy group, with curing agent crosslinking, improves fever route obtained
Stability, meanwhile, in the epoxy-resin systems after solidifying crosslinking, containing active biggish epoxy group, hydroxyl and ehter bond, amine
Key, ester bond isopolarity group, improving the graphene heat generating pastes after solidifying crosslinking has excellent adhesive force, steady with conductive sheet
Fixed bonding bonding, and shrinking percentage is small；And epoxy acrylate reactivity therein is high, crosslink density is big, hands over epoxy resin
Connection, can improve the electric conductivity and stability of graphene heat generating pastes, and preferably Epoxy Phenolic Acrylates.
And graphene oxide is difficult to be uniformly dispersed in the epoxy as two-dimension nano materials, and it is existing to be easy to happen reunion
As, the extension uniformity of graphene heat generating pastes is reduced, thus by carrying out modification to surface of graphene oxide group,
Its dispersing uniformity in epoxy resin-epoxy acrylate system can be improved, and combines the copper nanoparticle used, jointly
Improve the electric conductivity and heating efficiency of graphene heat generating pastes；And the methylimidazole used can promote graphene heat generating pastes
Mobility and extension uniformity avoid occurring the phenomenon that sagging on conductive sheet in printing process, while can coordinate epoxy resin
With the solidification of epoxy acrylate, the deficiency that the two solidifies crosslinking is made up, improves the stability of graphene heat generating pastes；And it adopts
Silane coupling agent can promote the coupling of the crosslinking between epoxy resin, epoxy acrylate and epoxy resin-epoxy third
Crosslinking between olefin(e) acid ester and curing agent couples, and improves the stability of graphene heat generating pastes；And the solvent used then improves
The dissolubility of each raw material promotes modified graphene oxide nano-powder and copper nanoparticle in epoxy resin-epoxy acrylate body
Solubility in system.
Preferably, the modified graphene oxide nano-powder is made by following steps:
Step (1): it disperses stannic oxide/graphene nano powder in alcoholic solvent, is uniformly mixed, obtain graphite oxide
Alkene dispersion liquid；
Step (2): being added dropwise 1- pyrene butyric acid, be added dropwise while stirring in the graphene oxide dispersion made from step (1),
Reaction solution is made after being added dropwise；
Step (3): hydrazine hydrate is added in the reaction solution made from step (2), the insulated and stirred in nitrogen protection atmosphere
20-30min is most filtered by vacuum afterwards, and modified graphene oxide nano-powder is made.
Preferably, in the step (1), the mixed proportion of stannic oxide/graphene nano powder and alcoholic solvent is 3-8:10, institute
Stating alcoholic solvent is at least one of n-butanol, methanol, ethyl alcohol and isopropanol；In the step (2), 1- pyrene butyric acid and oxidation
The mixed proportion of graphene dispersing solution is 2:3-4；In the step (3), the mixed proportion of hydrazine hydrate and reaction solution is 1:2-
5。
In the embodiment of the present invention, modified graphene oxide nano-powder is prepared through the above steps, and strict control respectively walks
Rapid material mixed proportion can improve solubility of the graphite oxide in epoxy resin-epoxy acrylate system, and have
Preferable conductivity；Wherein, it first disperses stannic oxide/graphene nano powder in alcoholic solvent, promotes stannic oxide/graphene nano powder
Then the dissolution of body is interacted using the pi-pi bond of the 1- pyrene butyric acid and graphene oxide with big pi-conjugated system, is carried out non-
Covalent modification improves dispersibility of the graphene oxide in solution system, promotes it in epoxy resin-epoxy acrylate
Dispersing and dissolving in system, and being restored using hydrazine hydrate, is filtered by vacuum, improve graphene oxide conductivity and
Toughness makes further graphene heat generating pastes obtained have preferable flexibility, is easy to be printed on conductive sheet, improves electricity
Transport factor and conductivity improve heating efficiency.
Preferably, every part of silane coupling agent includes 2-3 parts of gamma-aminopropyl-triethoxy-silanes, 2-3 parts of methyl three
Ethoxysilane, 1-2 parts of pyrophosphate titanate esters and 4-5 parts of vinyl three ('beta '-methoxy ethyoxyl) silane；The curing agent
For triethanolamine, 2-methylimidazole and epoxybutyl ether addition product, diamino diphenyl sulfone, m-phenylene diamine (MPD) and beta-hydroxyethyl second
At least one of diamines；The solvent is at least one of acetone, dimethylbenzene, isopropanol.
In the embodiment of the present invention, the above-mentioned silane coupling agent of use can improve profit of the material in graphene heat generating pastes
It is moist and dispersed, and promote crosslinking coupling between epoxy resin, epoxy acrylate, epoxy resin-epoxy acrylate
Between curing agent, crosslinking of the epoxy resin-between epoxy acrylate and conductive powder body couple, improve graphene fever slurry
The stability of material；Wherein, the gamma-aminopropyl-triethoxy-silane of use contains two different active groups --- amino and second
Oxygroup can effectively improve epoxy resin-epoxy acrylate and conductive powder body (modified graphene oxide nano-powder and nanometer
Copper powder) between crosslinking coupling, the caking property both enhanced improves the dispersing uniformity of conductive powder body；The vinyl three of use
('beta '-methoxy ethyoxyl) silane can effectively improve epoxy resin-epoxy acrylate and conductive powder body (modified graphene oxide
Nano-powder and copper nanoparticle) between crosslinking coupling.
And the above-mentioned curing agent used can be crosslinked with epoxy resin and epoxy acrylate solidification, improve graphene fever
The curing efficiency and curing molding stability of slurry, wherein the amido in the triethanolamine of use can be with the epoxy group in system
Crosslinking forms stable tridimensional network system, improves the stability of fever route obtained；And 2-methylimidazole and ring
Oxygen-butyl ether addition product is easy in conjunction with epoxy resin, epoxy acrylate, while the solidification of promotion system material, and energy
Improve the intensity and corrosion resistance of graphene heat generating pastes, excellent electrical property；The diamino diphenyl sulfone and m-phenylene diamine (MPD) of use
The electric conductivity and heat resistance of graphene heat generating pastes, excellent anti-corrosion performance can be improved；The beta-hydroxyethyl ethylenediamine and ring of use
The cross-linking and curing reaction of oxygroup is very fast, can effectively improve the curing efficiency of graphene heat generating pastes.
Preferably, the graphene heat generating pastes are made by following steps:
Step 1: in parts by weight, by epoxy resin, epoxy acrylate, silane coupling agent and curing agent be added to
It in solvent, is mixed, modified graphene oxide nano-powder is added to wherein after being uniformly dispersed, be 15000- in frequency
2-5h is stirred by ultrasonic under conditions of 18000HZ, mixture is made；
Step 2: in parts by weight, copper nanoparticle and methylimidazole being added into step 1. mixture obtained, mixed
Stirring is closed, graphene heat generating pastes is made after being uniformly dispersed
In the embodiment of the present invention, graphene heat generating pastes are prepared through the above steps, and epoxy is improved by silane coupling agent
The crosslinking degree of coupling of both resin, epoxy acrylate, promotion forms stable resin slurry system, and passes through curing agent pair
Epoxy resin, epoxy acrylate carry out crosslinking curing, improve the crosslinking conjugation of system, and promote the solidification of fever route
Molding, then modified graphene oxide nano-powder is added into resin system, good dispersion, and solubility is high, and with conduction
Graphene in piece improves mobility and flowing smoothness of the current electrons in conductive sheet and fever route at phase separation,
Conductivity and heating efficiency are improved, finally copper nanoparticle and methylimidazole are added thereto, improve dispersibility, the conduction of material
Property, make graphene heat generating pastes obtained that there is preferable mobility and extension uniformity, on conductive sheet in printing process not
There is the phenomenon that sagging, while the solidification of epoxy resin and epoxy acrylate can be coordinated, makes up the two solidification crosslinking not
Foot improves the stability of graphene heat generating pastes.
The embodiment of the present invention also provides a kind of preparation method of graphene heat generating component 20, includes the following steps:
Step is 1.: graphene heat generating pastes being printed on to the outer surface of conductive sheet, fever line layer is made after cured；
Step is 2.: taking a packaging insulating layer, is covered in the outer surface of fever line layer, composite layer is made；
Step is 3.: taking a substrate layer, sided corona treatment is carried out to the two sides of substrate layer respectively, then respectively in substrate layer two
Side adhesive coating, is made the first adhesive layer and the second adhesive layer respectively, while by the inner surface of composite layer and the second adhesive layer
Outer surface bond connection, the inner surface of component body outer surface and the first adhesive layer is bonded and is connected, through hot pressing, solidification
Graphene heat generating component 20 is made afterwards.
Preferably, the step 1. in, the solidification temperatures of graphene heat generating pastes is 110-120 DEG C, and curing time is
15-25s；The step 3. in, the temperature of hot pressing is 130-150 DEG C, pressing pressure 2-4KPa, pressing time 6-
12s。
In the embodiment of the present invention, graphene heat generating component 20, and the ginseng of each step of strict control are prepared through the above steps
Number, it is easy to operate, it is easy to control, production cost is reduced, product quality is high, and graphene heat generating component 20 obtained is made to generate heat
Uniformly, heating efficiency is high, and the mechanical performances such as intensity with higher and impact strength, by carrying out corona to substrate layer
Processing can effectively improve the first adhesive-layer and the second adhesive-layer respectively with the adhesion strength of substrate layer, and it is multiple to improve graphene fever
The ply adhesion stability of condensation material avoids the occurrence of phenomena such as interlayer is detached from, and graphene is generated heat again by hot pressing mode
Condensation material and component body bonding are stablized, so that 20 performance of graphene heat generating component is stablized, fever composite material is not easily to fall off,
Quality is stablized, and can be used for being mass produced.
The preparation method of graphene heat generating component 20 in the embodiment of the present invention, it is easy to operate, it is easy to control, it reduces
Production cost, product quality is high, so that graphene heat generating component 20 obtained is generated heat uniformly, heating efficiency is high, and with higher
The mechanical performances such as intensity and impact strength can effectively improve the first adhesive-layer and the by carrying out sided corona treatment to substrate layer
Two adhesive-layers with the adhesion strength of substrate layer, improve the ply adhesion stability of graphene fever composite material, avoid out respectively
Phenomena such as existing interlayer is detached from, and stablized graphene fever composite material and component body bonding by hot pressing mode, so that
20 performance of graphene heat generating component is stablized, and fever composite material is not easily to fall off, and quality is stablized, and can be used for being mass produced.
For the ease of the understanding of those skilled in the art, below with reference to 7~8 couples of present invention of specific embodiment and attached drawing
It is further described, the content that embodiment refers to not is limitation of the invention.
Embodiment 1
A kind of graphene heat generating component 20 including component body 1 and is set to the graphene of 1 outer surface of component body
Generate heat composite material 2, and the graphene fever composite material 2 includes the first adhesive layer 21, the substrate set gradually from the inside to the outside
The 22, second adhesive layer 23 of layer, conductive sheet 24, fever line layer 25 and packaging insulating layer 26, the interior table of first adhesive layer 21
Face and the outer surface of the component body 1, which bond, to be connected；The conductive sheet 24 is graphene-copper composite conducting piece, the fever
Line layer 25 is printed by graphene heat generating pastes to be made.The substrate layer 22 is that outer surface and inner surface pass through sided corona treatment
PVC film；First adhesive layer 21 and the second adhesive layer 23 are polyolefin hot-melt layer；The packaging insulating layer 26
Including 40 parts of glass powders, 15 parts of silica, 3 parts of hydroxyethyl celluloses and 60 parts of terpinols.The graphene-copper composite guide
Electric piece includes the raw material of following parts by weight: 15 parts of graphene nano powder, 30 parts of Nano metal powder, methyl vinyl silicone rubber
50 parts, 0.5 part of hydroxyl-terminated injecting two methyl siloxane, 4 parts of vinyltrimethoxysilane, 3 parts of precipitated silica, conductive black 5
Part, 0.5 part of hydroxy silicon oil, 0.5 part of vulcanizing agent.The Nano metal powder is with weight ratio by copper nanoparticle and nano-nickel powder for 5:
The mixture of 1-2:2 composition, the copper nanoparticle are that the spherical silver that surface is coated by nano-silver powder coats copper powder；The methyl
The contents of ethylene of vinylsiloxane rubber is 0.14%, and molecular weight is 550,000；The hydroxy radical content of the hydroxy silicon oil is 4%；Institute
Stating vulcanizing agent is 2,5- dimethyl -2,5- di-t-butyl hexane peroxide.
Embodiment 2
A kind of graphene heat generating component 20 including component body 1 and is set to the graphene of 1 outer surface of component body
Generate heat composite material 2, and the graphene fever composite material 2 includes the first adhesive layer 21, the substrate set gradually from the inside to the outside
The 22, second adhesive layer 23 of layer, conductive sheet 24, fever line layer 25 and packaging insulating layer 26, the interior table of first adhesive layer 21
Face and the outer surface of the component body 1, which bond, to be connected；The conductive sheet 24 is graphene-copper composite conducting piece, the fever
Line layer 25 is printed by graphene heat generating pastes to be made.The substrate layer 22 is that outer surface and inner surface pass through sided corona treatment
PE film；First adhesive layer 21 and the second adhesive layer 23 are polyamide hot melt adhesive layer；The packaging insulating layer 26
Including 45 parts of glass powders, 18 parts of silica, 4 parts of hydroxyethyl celluloses and 65 parts of terpinols.The graphene-copper composite guide
Electric piece includes the raw material of following parts by weight: 16 parts of graphene nano powder, 32 parts of Nano metal powder, methyl vinyl silicone rubber
52 parts, 0.8 part of hydroxyl-terminated injecting two methyl siloxane, 5 parts of vinyltrimethoxysilane, 4 parts of precipitated silica, conductive black 6
Part, 0.6 part of hydroxy silicon oil, 0.6 part of vulcanizing agent.The Nano metal powder is to be with weight ratio by copper nanoparticle and nano-nickel powder
The mixture of 5.2:1-2:2.2 composition, the copper nanoparticle are that the spherical silver that surface is coated by nano-silver powder coats copper powder；Institute
The contents of ethylene for stating methyl vinyl silicone rubber is 0.15%, and molecular weight is 580,000；The hydroxy radical content of the hydroxy silicon oil is
5%；The vulcanizing agent is 2,5- dimethyl -2,5- di-t-butyl hexane peroxide.
Embodiment 3
A kind of graphene heat generating component 20 including component body 1 and is set to the graphene of 1 outer surface of component body
Generate heat composite material 2, and the graphene fever composite material 2 includes the first adhesive layer 21, the substrate set gradually from the inside to the outside
The 22, second adhesive layer 23 of layer, conductive sheet 24, fever line layer 25 and packaging insulating layer 26, the interior table of first adhesive layer 21
Face and the outer surface of the component body 1, which bond, to be connected；The conductive sheet 24 is graphene-copper composite conducting piece, the fever
Line layer 25 is printed by graphene heat generating pastes to be made.The substrate layer 22 is that outer surface and inner surface pass through sided corona treatment
PET film or PP film；First adhesive layer 21 and the second adhesive layer 23 are polyurethane adhesive adhesion coating；The encapsulation is exhausted
Edge layer 26 includes 50 parts of glass powders, 20 parts of silica, 5 parts of hydroxyethyl celluloses and 70 parts of terpinols.Graphene-the copper
Composite conducting piece includes the raw material of following parts by weight: 18 parts of graphene nano powder, 35 parts of Nano metal powder, methyl ethylene
55 parts of silicon rubber, 6 parts of vinyltrimethoxysilane, 5 parts of precipitated silica, is led at 1.0 parts of hydroxyl-terminated injecting two methyl siloxane
8 parts of electric carbon black, 0.8 part of hydroxy silicon oil, 0.8 part of vulcanizing agent.The Nano metal powder is by copper nanoparticle and nano-nickel powder with weight
For amount than the mixture for 5.5:1-2:2.5 composition, the copper nanoparticle is the spherical silver coated copper that surface is coated by nano-silver powder
Powder；The contents of ethylene of the methyl vinyl silicone rubber is 0.16%, and molecular weight is 600,000；The hydroxyl of the hydroxy silicon oil
Content is 6%；The vulcanizing agent is 2,5- dimethyl -2,5- di-t-butyl hexane peroxide.
Embodiment 4
A kind of graphene heat generating component 20 including component body 1 and is set to the graphene of 1 outer surface of component body
Generate heat composite material 2, and the graphene fever composite material 2 includes the first adhesive layer 21, the substrate set gradually from the inside to the outside
The 22, second adhesive layer 23 of layer, conductive sheet 24, fever line layer 25 and packaging insulating layer 26, the interior table of first adhesive layer 21
Face and the outer surface of the component body 1, which bond, to be connected；The conductive sheet 24 is graphene-copper composite conducting piece, the fever
Line layer 25 is printed by graphene heat generating pastes to be made.The substrate layer 22 is that outer surface and inner surface pass through sided corona treatment
PC film；First adhesive layer 21 and the second adhesive layer 23 are organic silica gel adhesion coating or epoxy resin adhesive layer；It is described
Packaging insulating layer 26 includes 55 parts of glass powders, 23 parts of silica, 6 parts of hydroxyethyl celluloses and 75 parts of terpinols.The stone
Black alkene-copper composite conducting piece includes the raw material of following parts by weight: 19 parts of graphene nano powder, 38 parts of Nano metal powder, methyl
58 parts of vinylsiloxane rubber, 1.3 parts of hydroxyl-terminated injecting two methyl siloxane, 7 parts of vinyltrimethoxysilane, precipitated silica 7
Part, 9 parts of conductive black, 0.9 part of hydroxy silicon oil, 0.9 part of vulcanizing agent.The Nano metal powder is by copper nanoparticle and nano nickel
For powder with the mixture that weight ratio is that 5.8:1-2:2.8 is formed, the copper nanoparticle is the spherical silver that surface is coated by nano-silver powder
Coat copper powder；The contents of ethylene of the methyl vinyl silicone rubber is 0.17%, and molecular weight is 630,000；The hydroxy silicon oil
Hydroxy radical content be 7%；The vulcanizing agent is 2,5- dimethyl -2,5- di-t-butyl hexane peroxide.
Embodiment 5
A kind of graphene heat generating component 20 including component body 1 and is set to the graphene of 1 outer surface of component body
Generate heat composite material 2, and the graphene fever composite material 2 includes the first adhesive layer 21, the substrate set gradually from the inside to the outside
The 22, second adhesive layer 23 of layer, conductive sheet 24, fever line layer 25 and packaging insulating layer 26, the interior table of first adhesive layer 21
Face and the outer surface of the component body 1, which bond, to be connected；The conductive sheet 24 is graphene-copper composite conducting piece, the fever
Line layer 25 is printed by graphene heat generating pastes to be made.The substrate layer 22 is that outer surface and inner surface pass through sided corona treatment
PEN film；First adhesive layer 21 and the second adhesive layer 23 are EVA hot-melt adhesive layer；The packaging insulating layer 26 includes
60 parts of glass powders, 25 parts of silica, 8 parts of hydroxyethyl celluloses and 80 parts of terpinols.The graphene-copper composite conducting piece
Raw material including following parts by weight: 20 parts of graphene nano powder, 40 parts of Nano metal powder, 60 parts of methyl vinyl silicone rubber,
1.5 parts of hydroxyl-terminated injecting two methyl siloxane, 8 parts of vinyltrimethoxysilane, 8 parts of precipitated silica, 10 parts of conductive black,
1.0 parts of hydroxy silicon oil, 1.0 parts of vulcanizing agent.The Nano metal powder is with weight ratio by copper nanoparticle and nano-nickel powder for 6:1-
The mixture of 2:3 composition, the copper nanoparticle are that the spherical silver that surface is coated by nano-silver powder coats copper powder；The methyl second
The contents of ethylene of alkenyl silicon rubber is 0.18%, and molecular weight is 650,000；The hydroxy radical content of the hydroxy silicon oil is 8%；It is described
Vulcanizing agent is 2,5- dimethyl -2,5- di-t-butyl hexane peroxide.
Comparative example 1: this comparative example and the difference of above-described embodiment 3 are: the conductive sheet includes the original of following parts by weight
Material: 35 parts of Nano metal powder, 55 parts of methyl vinyl silicone rubber, 1.0 parts of hydroxyl-terminated injecting two methyl siloxane, vinyl front three
6 parts of oxysilane, 5 parts of precipitated silica, 8 parts of conductive black, 0.8 part of hydroxy silicon oil, 0.8 part of vulcanizing agent.Comparative example 2: this is right
Ratio and the difference of above-described embodiment 3 are: the graphene-copper composite conducting piece includes the raw material of following parts by weight: graphite
18 parts of alkene nano-powder, 35 parts of Nano metal powder, methyl vinyl silicone rubber, 55 parts, hydroxyl-terminated injecting two methyl siloxane 1.0
Part, 6 parts of vinyltrimethoxysilane, 5 parts of precipitated silica, 8 parts of conductive black, 0.8 part of hydroxy silicon oil, vulcanizing agent 0.8
Part.The mixture that the Nano metal powder is made of copper nanoparticle and nano-nickel powder with weight ratio for 5.5:1-2:2.5, receives
Rice Copper Powder Surface is not coated by nano-silver powder.Comparative example 3: this comparative example and the difference of above-described embodiment 3 are: the stone
Black alkene heat generating pastes include the raw material of following parts by weight: 30 parts of stannic oxide/graphene nano powder, 13 parts of copper nanoparticle, asphalt mixtures modified by epoxy resin
40 parts of rouge, 23 parts of epoxy acrylate, 2 parts of methylimidazole, 2 parts of silane coupling agent, 1.3 parts of curing agent, 55 parts of solvent.
By graphene made from embodiment 1-5 and comparative example 1-3 fever composite material carry out electron mobility, conductivity,
The performance tests such as thermal coefficient, it is shown that test result is as follows:
By above-mentioned data it is found that graphene produced by the present invention fever composite material electron mobility is up to 18630-
19200cm2/ (Vs), resistivity are 7.2-8.3 (Ω cm), and conductivity reaches 1.33*106~1.46*106(s/m), thermally conductive
Coefficient is up to 5780-5950W/ (mK), illustrates the conductive sheet 24 of the invention by using containing graphene nano-powder and contains
The fever route phase separation of modified graphene oxide nano-powder, the electronics that the graphene ingredient of the two promotes is in conductive sheet 24
It migrates and flows between fever line layer 25, improve conductivity and heating efficiency.
And wherein comparative example 1 compared with Example 3, does not have graphene nano powder in the conductive sheet 24 of comparative example 1, electricity
Transport factor, conductivity, thermal coefficient are remarkably decreased, and resistivity rises, and are illustrated without adding graphene nano powder constituents
Conductive sheet 24 and fever line layer 25 between electron transfer efficiency significantly reduce, also illustrate the present invention by using stone
The conductive sheet of black alkene nano-powder, can be with the fever route phase separation containing modified graphene oxide nano-powder, the stone of the two
Black alkene ingredient can promote electronics to migrate flowing between conductive sheet 24 and fever line layer 25, improve conductivity and heating efficiency.
And comparative example 2 is compared with Example 3, in the conductive sheet of comparative example 2, copper nanoparticle surface is not by nano-silver powder
Cladding, electron mobility, conductivity, thermal coefficient are declined, and resistivity rises, and illustrate the present invention by using nanometer
Silver powder coats copper nanoparticle surface, and the silver layer volume resistivity on surface is low, and the body on copper nanoparticle surface can be effectively reduced
Product resistivity, increases the electric conductivity of conductive sheet, improves conductivity and heating efficiency.
And comparative example 3 is compared with Example 3, and graphene oxide is used in the graphene heat generating pastes of comparative example 3, not
Have using the modified graphene oxide modified by pi-pi bond, under electron mobility obtained, conductivity, thermal coefficient are significant
Drop, resistivity rise, and illustrate that the graphene oxide being modified without progress pi-pi bond solubility in the epoxy systems of slurry is lower,
So that the performances such as conductivity, thermal coefficient decline, also illustrate the present invention by using modified graphene oxide nano powder
Slurry feedstock one of of the body as fever line layer, it is equal to improve its dispersion in epoxy resin-epoxy acrylate system
Even property, and the copper nanoparticle used is combined, the common electric conductivity and heating efficiency for improving graphene heat generating pastes.
In addition, it is (soft to carry out hardness, rebound degree to graphene made from embodiment 1-5-copper composite conducting piece simultaneously
Property), tensile strength, elongation at break, the mechanical and physical performances test such as tearing strength, shown in test result is as follows:
By upper table data it is found that graphene produced by the present invention-copper composite conducting piece, the mixing with conductive metal powder
Property good there is mechanical performances, the processing forming such as preferable tensile strength, resilience, elongation at break, tearing strength to be easy to
Machine-shaping prepares graphene fever composite material and heat generating component, and stability is high.
In another embodiment of the present invention, the electrical interface 40 of the graphene hair tonic device provided is magnetic
Interface or USB interface.Specifically, electrical interface 40 mainly connect with power supply line and connects extraneous power supply, controller or shifting
Dynamic terminal can be powered and control graphene heat generating component 20 for graphene heat generating component 20 in this way and graphene is sent out
Hot component 20 generates heat.Equally, according to actual production demand and the difference of model, magnetic interface or USB interface be can choose
The electrical interface 40 of black alkene generating device as the present embodiment uses.
In another embodiment of the present invention, as shown in Fig. 3 and Fig. 5~6, the graphene hair tonic device that provides
The inside of the shell 10 is additionally provided with fixing seat 50, and the circuit board 70 is connected in the fixing seat 50.Specifically, Gu
The setting of reservation 50, which can be convenient, is installed and fixed circuit board 70, in this way when using the graphene hair tonic device, i.e.,
Make constantly to shake shell 10 or shell 10 by certain external force, still need not worry about the circuit board 70 loosen or
Person falls off, and so ensures that the connection stability and reliability of circuit board 70 Yu graphene heat generating component 20.
In another embodiment of the present invention, as shown in Figure 3 and Figure 5, the graphene hair tonic device provided it is described
The inside of shell 10 is additionally provided with battery 60, and the battery 60 is electrically connected with the circuit board 70.Specifically, battery 60 is set
Setting directly to power for graphene heat generating component 20, connect in this way without using power supply line with electrical interface 40, can allow graphite
Alkene hair tonic device work, and it is possible to reduce power supply line when using the graphene hair tonic device and done caused by user
It disturbs, improves the comfort used.
In another embodiment of the present invention, the battery 60 of the graphene hair tonic device provided is dry cell 60.It adopts
It uses dry cell 60 to use as battery 60, is easy to use, and rapidly dry cell 60 can be replaced, to guarantee to be somebody's turn to do
The continuation of the journey of graphene hair tonic device.
In another embodiment of the present invention, the battery 60 of the graphene hair tonic device provided is rechargeable battery 60,
After power supply line connects power port, it can charge for rechargeable battery 60.
In another embodiment of the present invention, as shown in Fig. 5~6, the graphene hair tonic device that provides it is described solid
Battery cavities 51 are provided in reservation 50, the battery 60 is in the battery cavities 51.In this embodiment, 60 chamber of battery
Setting can accommodate and fix battery 60, it is ensured that battery 60 install after stability, pass through keep battery 60 install after position
The stability set improves the reliability that the graphene hair tonic device uses to ensure that battery 60 exports the stability of electricity
And stability.Specifically, there are two position correspondence and spaced embedding slot 53, circuit boards for the front side setting of fixing seat 50
70 two sides preceding respectively can be packed into two embedding slots 53.Meanwhile embedding slot 53 is strip structure, such circuit board 70
When being embedded in embedding slot 53, circuit board 70 is pushed to slide a distance relative to fixing seat 50, increases embedding slot 53 and electricity
The contact area of road plate 70 can steadily fix circuit board 70.
In another embodiment of the present invention, as shown in Figure 3 and Figure 5, the graphene hair tonic device provided it is described
The forward position inside shell 10 is arranged in fixing seat 50, and the forward position of the inside of shell 10 is referred to when the graphene is raw
When transmitting apparatus is worn on the head of human body, being positioned against direction always with the forehead of human body head is forward position.So
It is related to guarantee that battery 60 and circuit board 70 are also disposed at forward position, while the electrical interface 40 connecting with circuit board 70
It can be set in forward position, and then can be convenient user and hold power supply line and 40 grafting of electrical interface, while there is user
Just advantage.
In another embodiment of the present invention, as illustrated in figures 3-6, the shell of the graphene hair tonic device provided
Spaced apart elastic card column 1221 there are two being set in body 10, it is preferable that two elastic card columns 1221 are arranged in shell 10
The forward position in portion.Further, the opposite sides of the fixing seat 50 is provided with convex block 52, between two convex blocks 52
The distance values of spacing and two elastic card columns 1221 are close, in this way to guarantee that the fixing seat 50 is set to two elasticity
When between card column 1221, two convex blocks 52 are clamped with two elastic card columns 1221 respectively.Also, two elastic cards
Column 1221 has certain deformation elasticity capacity, in this way in mounting-fixing base 50, can first surrender two elastic card columns
1221, so that it is deformed, fixing seat 50 is set between two elastic card columns 1221 with this, removes two elastic cards of surrender
After the power of 1221 deformation of column, elastic card column 1221 resets under the resilient force of itself, so just distinguishes with two convex blocks 52
Clamping, and then realize the fixed and positioned of fixing seat 50.When needing to dismantle fixing seat 50, equally, two elastic card columns are surrendered
1221, so that two elastic card columns 1221 are detached from the clamping with two convex blocks 52, fixing seat 50 can be so taken out, and then complete
The disassembly of pairs of fixing seat 50.
In another embodiment of the present invention, as shown in Fig. 2, the shell of the graphene hair tonic device provided
Ear evacuation position 102 is provided on 10, ear avoids there are two positions 102, and two ear evacuation positions 102 are located at the head
The both sides of type chamber 101, two ear evacuation positions 102 are used to the ear evacuation position 102 of evacuation ear.Specifically, ear is kept away
The shape of resigning 102 is arc shape, and when may insure to be worn on graphene hair tonic device on head, the root edge of shell 10 is not
The ear of human body can be compressed, the comfort for using graphene hair tonic device is improved.
In another embodiment of the present invention, as shown in Figure 2 and Figure 5, the graphene hair tonic device provided it is described
Shell 10 includes liner 12 and upper cover 11, and the bottom of liner 12, liner is arranged in head dummy chamber 101 compatible with head shape
12 connect the shell 10 that one inside of formation has chamber with upper cover 11, wherein circuit board 70,20 and of graphene heat generating component
Battery 60 can be set in the chamber inside shell 10.The connection of liner 12 and upper cover 11 may be a fixed connection or
It is detachably connected.Such as can be bonding, ultrasonic bonding or fastener connection etc..
In another embodiment of the present invention, the liner 12 of the shell 10 of the graphene hair tonic device provided
It can be soft plastic manufacture, contacted when the liner 12 and the head of human body contact in this way to be soft, improved raw using the graphene
When transmitting apparatus, the comfort on head.
In another embodiment of the present invention, as shown in Figure 3 and Figure 5, the graphene hair tonic device provided it is described
The liner 12 of shell 10 includes 12 main body of liner and is arranged in the annular block edge 122 of 12 bottom part body periphery of liner, upper cover 11 with
The outer peripheral edge adaptation contact of annular block edge 122 forms an inside with chamber so that liner 12 is connect with upper cover 11
Shell 10.Further, elastic card column 1221 is arranged in annular block edge 122 and is located at the position of front side.Further, ring
The bottom of shape block edge 122 is provided with emptiness avoiding hole 1222, which accommodates and expose for button 71, so as to user behaviour
Press the button 71.In addition, ear evacuation position 102 is arranged in corresponding two bottom position of annular block edge 122.
Another embodiment of the present invention provides a kind of graphene hair tonic device, as shown in Fig. 1~5 comprising shell 10,
Circuit board 70, battery 60 and graphene heat generating component 20, the shell 10 are provided with head dummy chamber compatible with head shape
101, the graphene heat generating component 20, the battery 60 and the circuit board 70 are arranged at the inside of the shell 10, institute
It states graphene heat generating component 20 to be electrically connected with the circuit board 70, the battery 60 is electrically connected with the circuit board 70.The present invention
When the graphene hair tonic device that embodiment provides is specifically used, shell 10 is worn on the head of human body, wherein shell 10
The head dummy chamber 101 of upper setting is adapted with the head of wearer, and battery 60 is the power supply of graphene heat generating component 20, graphene hair
Hot component 20 may be implemented to be rapidly heated, and the far infrared that graphene heat generating component 20 generates can produce on the head of human body
Raw thermogenetic effect and resonance effects, make head scalp location generate high-frequency vibration, can be clear to the profound ground of epidermis by skin corium
Except the free radical of oxidation, promote the blood circulation of scalp capilary, to realize the case where reducing alopecia generation, and auxiliary
Hair is allowed preferably to grow.In this embodiment, the use of power supply line is not needed, the graphene hair tonic device can used
When, it reduces power supply line and is interfered caused by user, improve the comfort used.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Made any modifications, equivalent replacements, and improvements etc., should all be included in the protection scope of the present invention within mind and principle.
Claims (10)
1. a kind of graphene hair tonic device, it is characterised in that: including shell, circuit board and graphene heat generating component, the shell
It is provided with head dummy chamber compatible with head shape, the graphene heat generating component and the circuit board are arranged at the shell
Inside, and the graphene heat generating component and the circuit board electrical connection, the side of the shell is provided with and the circuit
The electrical interface of plate electrical connection.
2. graphene hair tonic device according to claim 1, it is characterised in that: the graphene heat generating component includes component
Ontology and the graphene fever composite material for being set to component body outer surface, graphene fever composite material include by
It is interior to the first adhesive layer set gradually outside, substrate layer, the second adhesive layer, conductive sheet, fever line layer and packaging insulating layer, institute
The outer surface bonding of the inner surface and the component body of stating the first adhesive layer connects；The conductive sheet is that graphene-copper is compound
Conductive sheet, the fever line layer is printed by graphene heat generating pastes to be made, and the fever line layer and electrical interface electricity
Property connection.
3. graphene hair tonic device according to claim 2, it is characterised in that: the substrate layer is outer surface and inner surface
One of PET film, PVC film, PE film, PC film, PEN film and PP film Jing Guo sided corona treatment；Described
One adhesive layer and the second adhesive layer can be organic silica gel adhesion coating, epoxy resin adhesive layer, polyurethane adhesive adhesion coating, polyamide hot melt
One of adhesive layer, polyolefin hot-melt layer and EVA hot-melt adhesive layer；The packaging insulating layer include 40-60 parts of glass powders,
15-25 parts of silica, 3-8 parts of hydroxyethyl celluloses and 60-80 parts of terpinols.
4. graphene hair tonic device according to claim 2, it is characterised in that: the graphene-copper composite conducting piece packet
Include the raw material of following parts by weight:
5. graphene hair tonic device according to claim 4, it is characterised in that: the Nano metal powder is by copper nanoparticle
The mixture formed with nano-nickel powder with weight ratio for 5-6:1-2:2-3, the copper nanoparticle is that surface is coated by nano-silver powder
Spherical silver coat copper powder；The contents of ethylene of the methyl vinyl silicone rubber is 0.14-0.18%, molecular weight 55-65
Ten thousand；The hydroxy radical content of the hydroxy silicon oil is 4-8%；The vulcanizing agent be 2,5- dimethyl -2,5- di-tert-butyl peroxide oneself
Alkane.
6. graphene hair tonic device according to claim 4, it is characterised in that: the graphene-copper composite conducting piece by
Following steps are made；
Step A: in parts by weight, being stirred mixing for methyl vinyl silicone rubber, and material A is made；
Step B: in parts by weight, the precipitated silica of the dosage of one third being added into material A made from step A,
Then hydroxyl-terminated injecting two methyl siloxane, vinyltrimethoxysilane and hydroxy silicon oil are sequentially added, every kind of raw material is added mixed
It is uniform to stock dispersion to close stirring, then remaining precipitated silica is added in two portions, is mixed evenly, material B is made；
Step C: in parts by weight, graphene nano powder, Nano metal powder and conductive black are added to made from step B
In material B, stir mixing is agglomerating, and material C is made；
Step D: by the agglomerating rear material C heating refining glue obtained of step C mixing, discharging, mill is uniform, and vulcanizing agent is then added,
It stirs evenly, lower roll is cut, and graphene-copper composite conducting piece 24 is made.
7. graphene hair tonic device according to claim 2, it is characterised in that: the graphene heat generating pastes include as follows
The raw material of parts by weight:
The modified graphene oxide nano-powder is made by following steps:
Step (1): dispersing stannic oxide/graphene nano powder in alcoholic solvent, be uniformly mixed, and obtains graphene oxide point
Dispersion liquid；
Step (2): 1- pyrene butyric acid is added dropwise in the graphene oxide dispersion made from step (1), is added dropwise, drips while stirring
Reaction solution is made after finishing；
Step (3): hydrazine hydrate is added in the reaction solution made from step (2), the insulated and stirred 20- in nitrogen protection atmosphere
30min is most filtered by vacuum afterwards, and modified graphene oxide nano-powder is made.
8. graphene hair tonic device according to claim 7, it is characterised in that: in the step (1), graphene oxide is received
The mixed proportion of rice flour body and alcoholic solvent be 3-8:10, the alcoholic solvent be n-butanol, methanol, ethyl alcohol and isopropanol at least
It is a kind of；In the step (2), the mixed proportion of 1- pyrene butyric acid and graphene oxide dispersion is 2:3-4；In the step (3),
The mixed proportion of hydrazine hydrate and reaction solution is 1:2-5.
9. graphene hair tonic device according to claim 6, it is characterised in that: every part of silane coupling agent includes 2-3
Part gamma-aminopropyl-triethoxy-silane, 2-3 parts of methyltriethoxysilane, 1-2 parts of pyrophosphate titanate esters and 4-5 parts of ethylene
Base three ('beta '-methoxy ethyoxyl) silane；The curing agent is triethanolamine, 2-methylimidazole and epoxybutyl ether addition product, two
At least one of aminodiphenyl base sulfone, m-phenylene diamine (MPD) and beta-hydroxyethyl ethylenediamine；The solvent is acetone, dimethylbenzene, isopropyl
At least one of alcohol.
10. a kind of graphene hair tonic device, it is characterised in that: including shell, circuit board, battery and graphene heat generating component, institute
It states shell and is provided with head dummy chamber compatible with head shape, the graphene heat generating component, the battery and the circuit board
It is arranged at the inside of the shell, the graphene heat generating component and the circuit board electrical connection, the battery and the electricity
The electrical connection of road plate.
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| CN201910417745.0A CN110270012A (en) | 2019-05-20 | 2019-05-20 | Graphene hair tonic device |
| PCT/CN2019/122431 WO2020233079A1 (en) | 2019-05-20 | 2019-12-02 | Graphene hair-growth device |
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| WO2020233079A1 (en) * | 2019-05-20 | 2020-11-26 | 东莞市雅思电子有限公司 | Graphene hair-growth device |
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| CN115928279A (en) * | 2022-12-31 | 2023-04-07 | 武汉纺织大学 | Graphene/silicone rubber coaxial fiber-based elastic core-spun yarn and preparation and application thereof |
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| CN210873767U (en) * | 2019-05-20 | 2020-06-30 | 东莞市雅思电子有限公司 | Graphene hair growing device |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020233079A1 (en) * | 2019-05-20 | 2020-11-26 | 东莞市雅思电子有限公司 | Graphene hair-growth device |
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| WO2020233079A1 (en) | 2020-11-26 |
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