CN110256795A - Novel high fire protecting performance damping material of olefinic carbon and the preparation method and application thereof - Google Patents
Novel high fire protecting performance damping material of olefinic carbon and the preparation method and application thereof Download PDFInfo
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Abstract
The invention discloses a kind of novel high fire protecting performance damping materials of olefinic carbon and the preparation method and application thereof, the high fire protecting performance damping material of the olefinic carbon is made of following weight proportion: 10-12 parts of acrylic rubber, 2-3 parts of antioxidant, graphene oxide or 2-4 parts of modified graphene oxide, 20-22 parts of mica, 20-22 parts of vermiculite power, 5-6 parts of calcium carbonate, 1-2 parts of bentonite, 5-6 parts of fire retardant A, 4-6 parts of fire retardant B.The present invention forms nano intercalated damping unit, polymer damping unit forms the twisting of relatively strength in layered inorganic nano material interlayer and synusia, enhances friction between lamella and turns heat, improves damping by the way that graphene is added in damping lamella.It is fire-retardant by graphene oxide and fire retardant synergistic, coordinate repression in terms of acid source, charcoal source, gas source, the inorganic acid of generation enhances layer of charcoal, the effect of oxygen barrier dilution oxygen concentration is played by generating a large amount of non-flammable gases, smoke density is effectively reduced, olefinic carbon damping damping material is made to have the condition of high fire protecting performance.
Description
(1) technical field
The present invention relates to a kind of high fire protecting performance olefinic carbon damping materials and preparation method thereof, and the damping material is mainly answered
In terms of the damping noise reduction material in high-speed rail.
(2) background technique
China's Electrified Railways develop 60 years and intelligent traction power supply technical forum on, Qian Qingquan academician thinks, pursues
High speed is that rail traffic develops eternal one of theme.In the high-speed rail epoch that nowadays represent speed and efficiency, Chinese high-speed rail is made
For the name cards that China's economic goes to the world, all checked on all the time with high accurately quality.But as people are to high-speed rail
Equipment requirement tends to high speed, efficient and automation, and caused vibration, noise and FATIGUE FRACTURE PROBLEMS are also more and more prominent therewith.
The raising of vibration and noise limitation high-speed rail capability of engineering equipment, the serious stability for destroying the operation of high-speed rail mechanical equipment and reliable
Property, endanger the physical and mental health of people.Therefore, vibration and noise reducing, the man-machine work living environment of improvement are a urgent problems to be solved.
Currently, common damping material can be divided into rubber and pitch two major classes, rubber-based products glass transition both at home and abroad
Temperature major part is in room temperature hereinafter, its vibration absorption peak is unable to reach optimal shock attenuation result far from temperature is commonly used;And
For asphalt product although cheap, effect of vibration and noise reduction is bad, and mechanical strength is not high.And high polymer is burned
Cheng Zhonghui generates a large amount of dense smoke, and some high polymer burnings can also generate a large amount of toxic gas, according to statistics 80% in fire
Death by accident is all as caused by cigarette and poisonous gas.But the fire retardant performance of damping material gets the brush-off always, greatly
Most damping materials is based only on the research of oxygen index (OI), in practical applications tribute of the influence of this index to fire protecting performance
Offer it is very little, moreover the damping material in high-speed rail application it is more stringent.
(3) technical solution
The present invention provides a kind of novel high fire protecting performance damping material of olefinic carbon and preparation method thereof, the preparation methods
It selects stratified nano materials modified graphene oxide (MGO), keeps Supramolecular Assembling damping unit melt nano intercalated, greatly improve
Damp peak value.The parent for forming aromatic series soot is bonded in metal-aromatic series compound securely by the way that molybdenum system is fire-retardant simultaneously
In, reduce the generation of smoke;From three kinds of acid source, gas source, carbon source fire-retardant approach, using compound flame retardant to olefinic carbon damping material into
Row inhibits the improvement of the fire protecting performances such as flame extension.
The present invention forms nano intercalated damping unit, base by the way that modified graphene oxide (MGO) is added in damping lamella
In the nano intercalated damping material with " the multiple constraint damp type structure " of fractal technology of polymer melt.The damping material of research and development
It is made of polymer and m laminated composite, laminated composite is rearranged by n nanometer damping-constraining type structural body;Wherein
Nanometer damping-constraining type structural body is to be inserted into layered inorganic nano material interlayer with intercalation method by polymer damping unit
It is obtained.The structure of entire damping material is made of many levels, and each level has similitude, latter level in structure
It is the epitome of previous level.Polymer damping unit forms the twisting of relatively strength in layered inorganic nano material interlayer and synusia,
In the effect by external force, between synusia and polymer due to shearing, friction and be converted into heat, and modified oxidation stone
Black alkene surface tension reduces, and reduces reunion, making it in the base has good dispersibility, thus greatly increases material
Damping.The polymer-based damping material structure schematic diagram of the modified graphene oxide nanometer damp type structure of multiple constraint
As shown in Figure 1.
Inhibit the generation of the smoke of olefinic carbon damping material, general polymerization in terms of fire protecting performance by molybdenum system column fire retardant first
Fragrance and polyenoid have biggish production cigarette trend in object, and molybdenum system column fire retardant can be secured by the parent for forming aromatic series soot
Ground is bonded in metal-aromatic series compound, reduces the generation of smoke.Molybdenum trioxide fire retardant and zinc borate in molybdenum system column simultaneously
With good synergistic effect, it can be used in compounding and obtain better smoke suppressing effect, and cost can also be reduced, because of zinc borate
Molecular formula be 2ZnO3B2O3·3.5H2O starts to deviate from the crystallization water at 300 DEG C, can play the cooling effect of heat absorption, in ZB
Zn there are about 38% with ZnO or Zn (OH)2Form enter gas phase, diluting effect is played to fuel gas, makes its burn rate
It reduces, further increases its anti-flammability, but zinc borate belongs to that gas phase is fire-retardant, it is limited to the reduction of smoke density, it is more association
The purpose that effect effect promotes molybdenum trioxide condensed phase fire-retardant reduces smoke density.Molybdenum system fire retardant is also contemplated that after solving the problems, such as suppression cigarette
The ammonium polyphosphate app being modified with alkylsiloxane is found through experiments that because there is height to contain in the fire-retardant problem of olefinic carbon damping material
The elements such as N, P of amount easily form fine and close layer of charcoal, have protective effect to damping material inside, can effectively reduce flame and prolong
The rate stretched, has greatly improved to flame retardant property.Intramolecule structure is set to contain P-O-Si later with alkylsiloxane is modified
Structure, have the function of it is hydrophobic moisture-proof, and alkylsiloxane structure have certain coupling effect, improve and polyolefin material
The compatibility of material preferably plays the flame retardant effect of material.
The main research approach of the present invention is as follows:
A kind of high fire protecting performance damping material of novel olefinic carbon, it is characterised in that: formed by following quality proportioning: acrylate
10-12 parts of rubber, 2-3 parts of antioxidant, 2-4 parts of graphene oxide (GO) or modified graphene oxide (MGO), 20-22 parts of mica,
20-22 parts of vermiculite power, 5-6 parts of calcium carbonate, 1-2 parts of bentonite, 5-6 parts of fire retardant A, 4-6 parts of fire retardant B.
Further, the acrylic rubber is epoxy type AR54 rubber.
Further, it is paracresol and dicyclopentadiene butylation product that the antioxidant, which is oligomeric phenol 616,.
Further, the fire retardant A is the product that molybdenum trioxide and zinc borate are compounded with the mass ratio of 4:1.
Further, the fire retardant B is the product that ammonium polyphosphate and poly- phosphamide are compounded with the mass ratio of 3:1.
The high fire protecting performance damping material of olefinic carbon of the present invention is prepared as follows:
(1) it weighs 10-12 parts of acrylic rubber and is kneaded 2-3min in 120-130 DEG C of two-roll mill, wait spread
After exhibition uniformly, 2-4 parts of graphene oxide (GO) or modified graphene oxide (MGO), 2-3 parts of antioxygen are sequentially added in order
Agent 616,20-22 parts of mica, 20-22 parts of vermiculite power, 5-6 parts of calcium carbonate, 1-2 parts of bentonite, 5-6 parts of A, 4-6 parts of fire retardant resistances
Fire agent B, mill 10-12min blanking;
(2) then corner material obtained by step (1) is put into mold, surface is protected with polytetrafluoroethylene film, is placed on temperature and is
In 120-130 DEG C of full-automatic vulcanizing press, pressure 10-12MPa preheats 3-5min, total pressure 5-8min, intermediate deflation 3-
5 times, after cooling down 2-3min, molding damping fin is taken out from mold and is down to room temperature to get the high fire protecting performance damping material of olefinic carbon
Material.
Further, graphene oxide of the present invention is prepared as follows:
A weighs 1-2g graphene and is added in the concentrated sulfuric acid solution that 12-15ml mass fraction is 98%, then successively to institute
3-5g potassium peroxydisulfate and 3-5g phosphorus pentoxide are added in the concentrated sulfuric acid solution stated, is subsequently placed in 80-100 DEG C of oil bath pan and reacts
6h or so obtains reaction solution and is filtered, and solid product washs to neutrality and is dried to obtain Strong oxdiative product;
Then the Strong oxdiative product of step a is added in 34-50ml concentrated sulfuric acid solution into the concentrated sulfuric acid solution by b
0.8-1g sodium nitrate is added, is placed in addition 5-10g potassium permanganate in ice-water bath, isothermal reaction 2 is small in 40-50 DEG C of water-bath
When, the hydrogen peroxide foaming and intumescing that 4-5ml concentration is 30% is added to glittering golden yellow, is washed with hydrochloric acid and deionized water into
Property, it is dissolved with deionized water ultrasonic disperse, the machine that is then centrifuged for is centrifuged 6-8min at 6000r/min, isolates and be not completely exfoliated
Graphite, take supernatant liquid graphene oxide (GO) aqueous dispersions;Finally graphene oxide aqueous dispersions are lyophilized at -78 DEG C
Layered graphite oxide alkene (GO) can be obtained after 36h.
Further, the preparation method of the graphene oxide of modification of the present invention carries out in accordance with the following steps:
Graphene oxide is dissolved in dehydrated alcohol, the graphene oxide dispersion of 1mg/ml is configured to, then to described
Graphene oxide dispersion in the ratio of silane coupling agent YDH-151 1:5 by volume, 60 DEG C of stirring 8h- of constant temperature are added
10h is to get the graphene oxide (MGO) for arriving modification;The graphene oxide dispersion and the silane coupling agent YDH-
151 volume ratio is 1:5.
Basis material of the invention uses a kind of high performance elastomer acrylic rubber, in material by shear strain
When, material can play the role of hysteresis damping by intermeshing molecular backbone friction energy-dissipating, while functionality is added and fills out
Material auxiliary improves damping capacity, significantly reduces damping material smoke density, flame with modified graphene oxide synergistic flame retardant
Important several fire prevention indexs such as Drawing rate.
Further, the high fire protecting performance damping material of olefinic carbon of the present invention answering in preparation high-speed rail damping noise reduction material
With.
Compared with prior art, beneficial effects of the present invention:
(1) it is single to form nano intercalated damping by the way that modified graphene oxide (MGO) is added in damping lamella by the present invention
Member, polymer damping unit forms the twisting of relatively strength in layered inorganic nano material interlayer and synusia, in the work by external force
Used time, between synusia and polymer due to shearing, friction and be converted into heat, thus greatly increase material damping effect
Fruit.
(2) fire-retardant by modified graphene oxide (MGO) and fire retardant synergistic, by acid source, charcoal source, gas in terms of principle
The inorganic acid of coordinate repression in terms of source, generation enhances layer of charcoal, has blocked hot release, by generating a large amount of noninflammability gas
Body plays the effect of oxygen barrier dilution oxygen concentration, and smoke density is effectively reduced, and olefinic carbon damping damping material is made to have high fire protecting performance
Condition.
Detailed description of the invention
The polymer-based damping material structure schematic diagram of Fig. 1 modified graphene oxide nanometer damp type structure;
Fig. 2 is graphene oxide (GO) and the SEM figure of modified graphene oxide (MGO);
Fig. 3 is the characterization of damping capacity fissipation factor in embodiment;
Fig. 4 is carbon sample after the burning of the olefinic carbon damping material of A containing fire retardant;
Carbon sample after Fig. 5 is A containing fire retardant and fire retardant B olefinic carbon damping material burns;
Fig. 6 is A containing fire retardant and A containing fire retardant and B olefinic carbon damping material combustion process heat release rate comparison diagram;
Fig. 7 is A containing fire retardant and A containing fire retardant and the total heat release rate comparison diagram of B olefinic carbon damping material combustion process;
Fig. 8 is A containing fire retardant and A containing fire retardant and B olefinic carbon damping material smoke density rate of release comparison diagram.
Specific embodiment
Below will by embodiment, the present invention is further illustrated, but the scope of the present invention is not limited thereto.
Antioxidant 616 of the present invention is purchased from the triumphant Mick new material in Zhejiang Science and Technology Ltd..
Embodiment 1
Graphene oxide is prepared first, is taken 1g graphene to be put into round-bottomed flask and is placed in the concentrated sulfuric acid environment of 12ml, by suitable
3g potassium peroxydisulfate and 3g phosphorus pentoxide is added in sequence, and charging, which finishes to be placed in 80 DEG C of oil bath pans, reacts 6h or so, then filters solid
Liquid separation, product wash to neutrality and are dried to obtain Strong oxdiative product.
Next using the Strong oxdiative product of above-mentioned synthesis as raw material, the improvement of obtained Strong oxdiative object is obtained into Hammers
Reaction, is added the concentrated sulfuric acid of 34ml in reaction beaker, and beaker is transferred to the height that 5g is added in ice-water bath by the sodium nitrate of 0.8g
Potassium manganate isothermal reaction 2 hours in 40 DEG C of water-bath, the hydrogen peroxide foaming and intumescing that addition 4ml concentration is 30% to glittering gold
Yellow is washed with hydrochloric acid and deionized water to neutrality, is dissolved with deionized water ultrasonic disperse, is then centrifuged for machine in 6000r/min
Lower centrifugation 6min, isolates the graphite not being completely exfoliated, takes supernatant liquid graphene oxide (GO) aqueous dispersions.It finally will oxidation
Layered graphite oxide alkene (GO) can be obtained in graphene aqueous dispersions after -78 DEG C of freeze-drying 36h.
Then modified graphene oxide, concrete mode are handled by surface silanization are as follows:
Graphene oxide is placed in dehydrated alcohol, the graphene oxide dispersion of 1mg/ml is configured to after ultrasonic dissolution,
Silane coupling agent YDH-151 is added in graphene oxide dispersion and the ratio of the volume ratio 1:5 of silane coupling agent YDH-151,
60 DEG C of constant temperature stirring 8h are to get the graphene oxide (MGO) for arriving modification.
After graphene oxide obtains, mill tabletting next is blended in material.
It weighs in 10 parts of acrylic rubber and 120 DEG C of two-roll mill and is kneaded 2min, after sprawling uniformly, by suitable
The modified graphene oxide (MGO) of 2 parts of sequence addition, 2 parts of antioxidant 616,20 parts of mica, 20 parts of vermiculite power, 5 parts of calcium carbonate,
1 part of bentonite, mill 10min blanking.
Then corner material is put into mold, surface is protected with polytetrafluoroethylene film, be placed on temperature be 120 DEG C it is full-automatic put down
In plate vulcanizer, pressure 10MPa preheats 3min, total pressure 5min, and centre is deflated 3 times, takes out after cooling 2min, molding
Damping fin takes out from mold and is down to room temperature, cuts out sample test.
The smoke density test result of product prepared by embodiment 1 is as shown in table 1.
Table 1
Smoke density effect | Oxygen index (OI) | Smoke density grade | Maximum smoke density |
Test result | 36 | 29.4 | 41.9 |
Standard is continued to use in subsequent fire line performance test: the danger of the fire protection requirement HL3 of EN45545-2 vehicle material and element
Class requirement, as shown in the picture.
Embodiment 2
The production method of modified graphene oxide (MGO) is the same as shown in embodiment 1.
It weighs in 10 parts of acrylic rubber and 120 DEG C of two-roll mill and is kneaded 2min, after sprawling uniformly, by suitable
The modified graphene oxide (MGO) of 2 parts of sequence addition, 2 parts of antioxidant 616,20 parts of mica, 20 parts of vermiculite power, 5 parts of calcium carbonate,
1 part of bentonite, 4 parts of molybdenum trioxide and 1 part of zinc borate, mill 10min blanking.
Then corner material is put into mold, surface is protected with polytetrafluoroethylene film, be placed on temperature be 120 DEG C it is full-automatic put down
In plate vulcanizer, pressure 10MPa preheats 3min, total pressure 5min, and centre is deflated 3 times, takes out after cooling 2min, molding
Damping fin takes out from mold and is down to room temperature, cuts out sample test.
The smoke density test result of product prepared by embodiment 2 is as shown in table 2.
Table 2
Smoke density effect | Oxygen index (OI) | Smoke density grade | Maximum smoke density |
Test result | 30 | 23 | 18.2 |
Embodiment 3
The production method of modified graphene oxide (MGO) is the same as shown in embodiment 1.
It weighs in 10 parts of acrylic rubber and 120 DEG C of two-roll mill and is kneaded 2min, after sprawling uniformly, by suitable
The modified graphene oxide (MGO) of 2 parts of sequence addition, 2 parts of antioxidant 616, mica 20 are 20 parts of vermiculite power, 5 parts of calcium carbonate, swollen
1 part of profit soil, 4 parts of molybdenum trioxide and 1 part of zinc borate, 3 parts of ammonium polyphosphate and 1 part of poly- phosphamide, mill 10-12min
Blanking.
Then corner material is put into mold, surface is protected with polytetrafluoroethylene film, be placed on temperature be 120 DEG C it is full-automatic put down
In plate vulcanizer, pressure 10MPa preheats 3min, total pressure 5min, and centre is deflated 3 times, takes out after cooling 2min, molding
Damping fin takes out from mold and is down to room temperature, cuts out sample test.
The smoke density test result of product prepared by embodiment 3 is as shown in table 3.
Table 3
Smoke density effect | Oxygen index (OI) | Smoke density grade | Maximum smoke density |
Test result | 36 | 0.6 | 2.3 |
Comparative example 1
The production method of graphene oxide (GO) is the same as shown in embodiment 1.
It weighs in 10 parts of acrylic rubber and 120 DEG C of two-roll mill and is kneaded 2min, after sprawling uniformly, by suitable
The graphene oxide (GO) of 2 parts of sequence addition, 2 parts of antioxidant 616,20 parts of mica, 20 parts of vermiculite power, 5 parts of calcium carbonate, bentonite
1 part, mill 10min blanking.
Then corner material is put into mold, surface is protected with polytetrafluoroethylene film, be placed on temperature be 120 DEG C it is full-automatic put down
In plate vulcanizer, pressure 10MPa preheats 3min, total pressure 5min, and centre is deflated 3 times, takes out after cooling 2min, molding
Damping fin takes out from mold and is down to room temperature, cuts out sample test.
The smoke density test result of the product of comparative example preparation is as shown in table 4.
Table 4
Smoke density effect | Oxygen index (OI) | Smoke density grade | Maximum smoke density |
Test result | 32 | 30.5 | 40.2 |
Comparative example 2
The production method of graphene oxide (GO) is the same as shown in embodiment 1.
It weighs in 10 parts of acrylic rubber and 120 DEG C of two-roll mill and is kneaded 2min, after sprawling uniformly, by suitable
The graphene oxide (GO) of 2 parts of sequence addition, 2 parts of antioxidant 616,20 parts of mica, 20 parts of vermiculite power, 5 parts of calcium carbonate, bentonite
1 part, 4 parts of molybdenum trioxide and 1 part of zinc borate, mill 10min blanking.
Then corner material is put into mold, surface is protected with polytetrafluoroethylene film, be placed on temperature be 120 DEG C it is full-automatic put down
In plate vulcanizer, pressure 10MPa preheats 3min, total pressure 5min, and centre is deflated 3 times, takes out after cooling 2min, molding
Damping fin takes out from mold and is down to room temperature, cuts out sample test.
The smoke density test result of the product of comparative example preparation is as shown in table 5.
Table 5
Smoke density effect | Oxygen index (OI) | Smoke density grade | Maximum smoke density |
Test result | 32 | 20 | 21.3 |
Embodiment 1 and comparative example 1 are the influences for verifying graphene oxide and modified graphene oxide to damping,
The modified dispersion be conducive in the base of graphene oxide, reduces the generation of reunion, and the compatibility of enhancing and matrix is modified
Damping is basically unchanged, and fissipation factor is 1 or so, but low temperature range damping property increases.And by attached drawing 2 in 5um
Electricity under the microscope can significantly find out that the fold of modified graphene oxide significantly reduces.The reason is that modified graphene oxide
Compatibility is more preferable in polymer matrix macromolecular chain, plays the role of " lubricating ", so to show as damping fin elasticity preferable, soft for print
It spends higher, glass transition temperature to decrease, is conducive to construction.
Pass through embodiment 2 and the research discovery of comparative example 2.The effect of smoke density is carried out due to cost considerations first
The compounding of test, molybdenum system column fire retardant and zinc borate has biggish improvement to maximum smoke density and smoke density grade, and oxygen refers to
Number, smoke density grade, maximum smoke density are up to standard, and modified graphene oxide (MGO) is because reduce surface tension, with
Matrix it is compatible much better, so reducing to the effect of smoke density much better, oxygen index (OI) can achieve 32, smoke density grade
Little with the variation of maximum smoke density, in addition modified graphene oxide (MGO) also has facilitation to damping, changes relative to nothing
The peak value of property graphene oxide damping loss factor improves 0.15 or so, but molybdenum trioxide fire retardant series has inhibition to damping
Effect, makes fissipation factor damping peak reduce 0.2 or so, in controlled range.Fire protecting performance has been carried out into one in embodiment 3
Step research, compounds synergistic with nitrogen phosphorus dilatancy app by graphene oxide, enhances layer of charcoal in terms of acid source and charcoal source, pass through
Shown in attached drawing 4 and attached drawing 5, being formed by layer of charcoal after further improving does not have fracture phenomena, compact and complete, effectively prevents flame
Further to propagate, attached drawing 6 is the entire heat release of 3 olefinic carbon damping material combustion process of comparative example 2 and comparative example
Rate curve, it has been found that there is the active combustion time after layer of charcoal barrier to be reduced to by the 40s-550s in comparative example 2
31s-375s in comparative example 3, from showing total cigarette rate of release by the 39.4MJ/m in comparative example 2 in attached drawing 7
It has been reduced to 28.4MJ/m, and total cigarette rate of release is the key that determine that flame extends index, flame Drawing rate is being prevented fires
Very important effect is played in the disaster relief, is obviously improved so fire protecting performance has before relatively improving.Attached drawing 8 is that entire cigarette is close
The release rate profile figure of degree arranges by comparison, it was found that nitrogen phosphorus intumescent app and graphene synergistic effect effect are more preferable compared with molybdenum system
Fire retardant and zinc borate, which are compounded, reduces 2/3rds for smoke density, and function and effect are significant, can be used as high fire protecting performance olefinic carbon
One spotlight of damping material.In short, olefinic carbon damping material efficiently solves the problems, such as fire protecting performance after improving step by step,
A guarantee is provided for security industry.
In embodiment described above and comparative example, in the scheme to verify the damping of olefinic carbon damping material and fire protecting performance,
It is all in polymeric matrix proportion, the material selection, processing method involved in the present invention arrived, any modification, equivalent, replacement improve
Deng should all be included in the protection scope of the present invention.
The measurement of the damping loss factor of above embodiment and comparative example carries out by the following method.
Test equipment: the Tritec2000's of the dynamic mechanical analyzer Trition Technology Ltd of Britain's production
Dynamic mechanical analyzer (DMA).
Test method: resonance method
Test condition: by each sample under the frequency of 2Hz and under the heating speed of 3 DEG C/min, by -40 DEG C -120 DEG C with pressure
Compressed mode measures its fissipation factor.
Fire protecting performance test method: cone calorimeter and smoke density method of testing
Standard is continued to use in fire line performance test: the danger classes of the fire protection requirement HL3 of EN45545-2 vehicle material and element
It is required that.
Claims (9)
1. a kind of high fire protecting performance damping material of novel olefinic carbon, it is characterised in that: the high fire protecting performance damping material of the olefinic carbon
It is made of following weight proportion: 10-12 parts of acrylic rubber, 2-3 parts of antioxidant, graphene oxide or modified graphene oxide
2-4 parts, 20-22 parts of mica, 20-22 parts of vermiculite power, 5-6 parts of calcium carbonate, 1-2 parts of bentonite, A5-6 parts of fire retardant, fire retardant
B4-6 parts.
2. the high fire protecting performance damping material of olefinic carbon as described in claim 1, it is characterised in that: the acrylic rubber is ring
Oxygen type AR54 rubber.
3. the high fire protecting performance damping material of olefinic carbon as described in claim 1, it is characterised in that: the antioxidant is oligomeric phenol
616。
4. the high fire protecting performance damping material of olefinic carbon as described in claim 1, it is characterised in that: the fire retardant A is three oxidations
The product that molybdenum and zinc borate are compounded with the mass ratio of 4:1.
5. the high fire protecting performance damping material of olefinic carbon as described in claim 1, it is characterised in that: the fire retardant B is polyphosphoric acid
The product that ammonium and poly- phosphamide are compounded with the mass ratio of 3:1.
6. the high fire protecting performance damping material of olefinic carbon as described in claim 1, it is characterised in that: the modified graphene oxide is
The graphene oxide of silanization treatment is passed through on surface.
7. the high fire protecting performance damping material of olefinic carbon as claimed in claim 6, it is characterised in that: the silanization treatment method
Are as follows:
Graphene oxide is dissolved in dehydrated alcohol, the graphene oxide dispersion of 1mg/ml is configured to, then to the oxygen
Silane coupling agent YDH-151 is added in graphite alkene dispersion liquid, 60 DEG C of constant temperature stirring 8h-10h are to get the graphite oxide for arriving modification
Alkene;The volume ratio of the graphene oxide dispersion and the silane coupling agent YDH-151 is 1:5.
8. a kind of preparation method of the novel high fire protecting performance damping material of olefinic carbon as described in claim 1, it is characterised in that: described
Method carry out in accordance with the following steps:
(1) it weighs 10-12 parts of acrylic rubber and is kneaded 2-3min in 120-130 DEG C of two-roll mill, wait sprawl
After even, 2-4 parts of graphene oxide or modified graphene oxide, 2-3 parts of antioxidant 616, mica 20- are sequentially added in order
22 parts, 20-22 parts of vermiculite power, 5-6 parts of calcium carbonate, 1-2 parts of bentonite, 5-6 parts of fire retardants A, 4-6 parts of fire retardant B, mill 10-
12min blanking;
(2) then corner material obtained by step (1) is put into mold, surface is protected with polytetrafluoroethylene film, and being placed on temperature is 120-
In 130 DEG C of full-automatic vulcanizing press, pressure 10-12MPa, preheat 3-5min, total pressure 5-8min, intermediate deflation 3-5 times,
After cooling 2-3min, molding damping fin is taken out from mold and is down to room temperature to get the high fire protecting performance damping material of olefinic carbon.
9. a kind of high fire protecting performance damping material of olefinic carbon as described in claim 1 answering in preparation high-speed rail damping noise reduction material
With.
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