CN110256682B - 有机发光材料及其制备方法 - Google Patents
有机发光材料及其制备方法 Download PDFInfo
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- CN110256682B CN110256682B CN201910152993.7A CN201910152993A CN110256682B CN 110256682 B CN110256682 B CN 110256682B CN 201910152993 A CN201910152993 A CN 201910152993A CN 110256682 B CN110256682 B CN 110256682B
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- rare earth
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- dimethylformamide
- organic light
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- 239000000463 material Substances 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims abstract description 102
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 63
- 239000007787 solid Substances 0.000 claims abstract description 36
- 238000006243 chemical reaction Methods 0.000 claims abstract description 32
- 239000011259 mixed solution Substances 0.000 claims abstract description 24
- 238000001035 drying Methods 0.000 claims abstract description 21
- 239000008367 deionised water Substances 0.000 claims abstract description 19
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000007864 aqueous solution Substances 0.000 claims abstract description 16
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 16
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims abstract description 14
- 239000001632 sodium acetate Substances 0.000 claims abstract description 14
- 235000017281 sodium acetate Nutrition 0.000 claims abstract description 14
- 238000010438 heat treatment Methods 0.000 claims abstract description 13
- 238000002791 soaking Methods 0.000 claims abstract description 13
- 238000001816 cooling Methods 0.000 claims abstract description 12
- 229910001404 rare earth metal oxide Inorganic materials 0.000 claims abstract description 11
- 238000003756 stirring Methods 0.000 claims abstract description 11
- -1 rare earth chloride Chemical class 0.000 claims abstract description 9
- 230000001376 precipitating effect Effects 0.000 claims abstract description 8
- 238000005406 washing Methods 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 7
- 229910016644 EuCl3 Inorganic materials 0.000 claims description 18
- NNMXSTWQJRPBJZ-UHFFFAOYSA-K europium(iii) chloride Chemical compound Cl[Eu](Cl)Cl NNMXSTWQJRPBJZ-UHFFFAOYSA-K 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 14
- 238000009210 therapy by ultrasound Methods 0.000 claims description 14
- 238000009835 boiling Methods 0.000 claims description 13
- 229910001940 europium oxide Inorganic materials 0.000 claims description 11
- AEBZCFFCDTZXHP-UHFFFAOYSA-N europium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Eu+3].[Eu+3] AEBZCFFCDTZXHP-UHFFFAOYSA-N 0.000 claims description 11
- 229910003443 lutetium oxide Inorganic materials 0.000 claims description 11
- MPARYNQUYZOBJM-UHFFFAOYSA-N oxo(oxolutetiooxy)lutetium Chemical compound O=[Lu]O[Lu]=O MPARYNQUYZOBJM-UHFFFAOYSA-N 0.000 claims description 11
- AEDROEGYZIARPU-UHFFFAOYSA-K lutetium(iii) chloride Chemical compound Cl[Lu](Cl)Cl AEDROEGYZIARPU-UHFFFAOYSA-K 0.000 claims description 10
- 238000001291 vacuum drying Methods 0.000 claims description 6
- 230000035484 reaction time Effects 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims 6
- 238000004020 luminiscence type Methods 0.000 description 12
- 238000001878 scanning electron micrograph Methods 0.000 description 8
- 230000005284 excitation Effects 0.000 description 7
- 150000002910 rare earth metals Chemical class 0.000 description 7
- 239000012621 metal-organic framework Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 238000000295 emission spectrum Methods 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- 238000005119 centrifugation Methods 0.000 description 4
- 239000012265 solid product Substances 0.000 description 4
- 229910000420 cerium oxide Inorganic materials 0.000 description 2
- 229910001938 gadolinium oxide Inorganic materials 0.000 description 2
- 229940075613 gadolinium oxide Drugs 0.000 description 2
- CMIHHWBVHJVIGI-UHFFFAOYSA-N gadolinium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[Gd+3].[Gd+3] CMIHHWBVHJVIGI-UHFFFAOYSA-N 0.000 description 2
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 229910003451 terbium oxide Inorganic materials 0.000 description 2
- SCRZPWWVSXWCMC-UHFFFAOYSA-N terbium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[Tb+3].[Tb+3] SCRZPWWVSXWCMC-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000012984 biological imaging Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000008832 photodamage Effects 0.000 description 1
- 238000002428 photodynamic therapy Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G83/00—Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
- C08G83/008—Supramolecular polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/18—Metal complexes
- C09K2211/182—Metal complexes of the rare earth metals, i.e. Sc, Y or lanthanide
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Luminescent Compositions (AREA)
Abstract
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CN110256682B true CN110256682B (zh) | 2021-09-21 |
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CN112457499B (zh) * | 2020-11-30 | 2022-03-25 | 华南理工大学 | 一种稀土基金属有机框架荧光纳米材料及其制备方法与应用 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101711265A (zh) * | 2007-06-06 | 2010-05-19 | 雷恩国家应用科学学院 | 基于热塑性或热固性高分子有机基质的材料的标记方法 |
CN102671553A (zh) * | 2012-05-02 | 2012-09-19 | 珠海市吉林大学无机合成与制备化学重点实验室 | 应用静电纺丝技术生长无机微孔分离膜的方法 |
CN105949226A (zh) * | 2016-06-23 | 2016-09-21 | 哈尔滨工业大学 | 铕铈共掺杂配合物荧光传感材料的制备方法及应用其检测有机小分子化合物 |
CN106497547A (zh) * | 2016-10-21 | 2017-03-15 | 中国科学院长春光学精密机械与物理研究所 | 一种稀土发光材料及其制备方法、应用 |
CN106822926A (zh) * | 2017-02-20 | 2017-06-13 | 武汉科技大学 | 一种用于磁共振成像的纳米Gd‑MOFs的制备方法 |
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2019
- 2019-02-28 CN CN201910152993.7A patent/CN110256682B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101711265A (zh) * | 2007-06-06 | 2010-05-19 | 雷恩国家应用科学学院 | 基于热塑性或热固性高分子有机基质的材料的标记方法 |
CN102671553A (zh) * | 2012-05-02 | 2012-09-19 | 珠海市吉林大学无机合成与制备化学重点实验室 | 应用静电纺丝技术生长无机微孔分离膜的方法 |
CN105949226A (zh) * | 2016-06-23 | 2016-09-21 | 哈尔滨工业大学 | 铕铈共掺杂配合物荧光传感材料的制备方法及应用其检测有机小分子化合物 |
CN106497547A (zh) * | 2016-10-21 | 2017-03-15 | 中国科学院长春光学精密机械与物理研究所 | 一种稀土发光材料及其制备方法、应用 |
CN106822926A (zh) * | 2017-02-20 | 2017-06-13 | 武汉科技大学 | 一种用于磁共振成像的纳米Gd‑MOFs的制备方法 |
Non-Patent Citations (2)
Title |
---|
均苯三甲酸铕及铕镧配合物的合成及荧光性质;王继业等;《发光学报》;20061031;第27卷(第5期);第817-821页 * |
基于稀土掺杂上转换发光材料的可控制备及其作为多功能药物载体的应用研究;刘雅娜;《中国优秀硕士学位论文全文数据库 工程科技I辑》;20190215(第2期);第B016-518页 * |
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Denomination of invention: Organic light-emitting materials and their preparation methods Effective date of registration: 20221116 Granted publication date: 20210921 Pledgee: Jiangsu Nantong Rural Commercial Bank Co.,Ltd. Development Zone sub branch Pledgor: JIANGSU LUOHUA NEW MATERIAL Co.,Ltd. Registration number: Y2022320000715 |
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Date of cancellation: 20231109 Granted publication date: 20210921 Pledgee: Jiangsu Nantong Rural Commercial Bank Co.,Ltd. Development Zone sub branch Pledgor: JIANGSU LUOHUA NEW MATERIAL Co.,Ltd. Registration number: Y2022320000715 |
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Denomination of invention: Organic luminescent materials and their preparation methods Effective date of registration: 20231110 Granted publication date: 20210921 Pledgee: Jiangsu Nantong Rural Commercial Bank Co.,Ltd. Development Zone sub branch Pledgor: JIANGSU LUOHUA NEW MATERIAL Co.,Ltd. Registration number: Y2023980065177 |