CN110246602A - Aqueous low surface tension high viscosity radioaerosol depressor and preparation method - Google Patents
Aqueous low surface tension high viscosity radioaerosol depressor and preparation method Download PDFInfo
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- CN110246602A CN110246602A CN201910525648.3A CN201910525648A CN110246602A CN 110246602 A CN110246602 A CN 110246602A CN 201910525648 A CN201910525648 A CN 201910525648A CN 110246602 A CN110246602 A CN 110246602A
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- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/02—Treating gases
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Abstract
The invention belongs to nuclear pollution decontamination technology fields, disclose a kind of aqueous low surface tension high viscosity radioaerosol depressor and preparation method, use acrylamide for principal monomer, acrylic acid and styrene are function modified monomer, the polymerization of self-emulsifying micro-emulsion liquid is carried out, aqueous low surface tension high viscosity radioaerosol depressor is obtained.Depressor of the present invention is water-soluble depressor, meets environmental-friendly feature；Depressor has lower surface tension, have to aerosol soak well it is wrapped, have both higher viscosity again simultaneously, depressor compacting aerosol falls to the ground rear film-forming, highly viscous depressor is more advantageous to the recycling of the solidification to pressed dust, secondary pollution will not be caused to environment, using the compacting efficiency of radioaerosol depressor prepared by the present invention in > 87.93%；It is provided simultaneously with good film forming, the application being more advantageous to during nuclear emergency.
Description
Technical field
The invention belongs to nuclear pollution decontamination technology field more particularly to a kind of aqueous low surface tension high viscosity radioactivity gas
Colloidal sol depressor and preparation method.
Background technique
Currently, the immediate prior art:
Radioaerosol refers to that easily diffusion is same containing radionuclide or by the aerosol of radionuclide contamination
When can enter human body by respiratory system and cause interior irradiation, therefore in nuclear accident and nuclear emergency response, removal radioactivity gas is molten
Glue stain is all critical issue.
It is usually mainly the method for physical cleaning to the removal processing mode of Conventional aerosol particulate matter (on-radiation), it is main
It to include mechanical dedusting, filtering type dedusting, wet process compacting, electrostatic precipitation these four types.The removal of radioaerosol was both
It is considered as its characteristic as aerosol, and it should be conceived to radioactive special harm.Radioactivity gas is molten in nuclear emergency
The generation of glue has time bursts, place Unpredictability, it is desirable that dedusting technology should have flexibility, mobility, convenient for behaviour
The features such as making.Wet sprinkling dedusting then substantially meets above-mentioned requirements, wet sprinkling dedusting refers to spray liquid is atomized after with dust-laden
Gas comes into full contact with, the method for washing and making gas purification for grit.Spray (mist) though dedusting have it is flexible, motor-driven, just
Meet the requirement removed to radioaerosol in the features such as operation.
But have following both sides insufficient again using water as spray liquid: firstly, after water atomization its drop surface tension
Greatly, it hinders water mist particle and aerosol particles to soak coalescence, reduces removal effect；Followed by after spraying and dedusting, water is due to it
Good fluidity, it is difficult to collect, be easily penetrated into underground after carrying radioaerosol particle secretly, cause the pollution of more depth.
In conclusion problem of the existing technology is:
(1) in the prior art, not over design polymer chain structure, drop has lower after being atomized its aqueous solution
Surface tension (surface energy), it is easier to soak coalescence with aerosol particles, cause to obtain more preferably aerosol compacting effect
Fruit.
(2) in the prior art, it cannot make the depressor of preparation while keeping compared with low surface tension, still have higher
Viscosity, cause spray atomizing dedusting land after mobility it is big, easily collecting, not can effectively solve radioactive diffusion pollution.
(3) the higher surface tension of existing depressor can make liquid-drop diameter after atomization larger, be equivalent in unit volume
The density of atomized drop is small, so that the collision frequency of drop Yu aerosol dust can be reduced, so that compacting efficiency is relatively low.
Solve the difficulty of above-mentioned technical problem:
(1) it selects suitable polymerization system to design polymer chain structure, while guaranteeing that compacting agent solution has well again
Film forming and rippability be one of difficulty of this patent.
(2) its viscosity can be made also to further decrease while reducing depressor solution surface tension under normal conditions, therefore
Prepare a kind of low surface tension and meanwhile have both viscosity higher depressor be this patent difficulty two.
Solve the meaning of above-mentioned technical problem:
One faced in the control of radioactive dust and the removal always elimination of nuclear facilities and nuclear emergency response is important to be asked
Topic, conventional more flexible method predominantly sprays wet process and suppresses decontamination, but the suppression performance of the depressor used at present
It need to be improved.Therefore prepare the radioaerosol depressor of high suppression performance a kind of, to the control of radioaerosol with
Removal has very important meaning.
Summary of the invention
In view of the problems of the existing technology, the present invention provides a kind of aqueous low surface tension high viscosity radioactivity gas is molten
Glue laminated preparation and preparation method.
The invention is realized in this way a kind of preparation side of aqueous low surface tension high viscosity radioaerosol depressor
Method, using acrylamide as the principal monomer in radical polymerization product, acrylic acid and styrene are radical polymerization product
In modified monomer, pass through self-emulsifying micro-emulsion liquid polymerization preparation.And in depressor process for preparation, by changing acrylic acid and benzene
The monomer ratio of ethylene, to adjust the surface tension and viscosity of radioaerosol depressor.
Further, group of the preparation method of the aqueous low surface tension high viscosity radioaerosol depressor to synthesize
Point 1 or the quality of component 2 be 50 parts of meters, specifically include:
1 preparation method of component: acrylamide and deionized water is added, being stirred at room temperature makes acryloyl in step 1 in beaker
After amine dissolution, macromolecule emulsifier is added, stirring dissolves it sufficiently at 25 DEG C of heating water bath, is then slowly added to benzene second
Alkene stirs pre-emulsification 2h at 40 DEG C, obtains colourless transparent liquid.Deionized water dosage: 31.55 parts；Acrylamide dosage: 9
Part；Macromolecule emulsifier dosage: 9 parts；Styrene dosage: 0.45 part.
2 preparation method of component: step 2 deionized water, acrylic acid and sodium hydroxide is added in beaker, stirs at room temperature
Dissolve it sufficiently.Obtain colourless transparent liquid.Deionized water dosage: 49.15 parts；Acrylic acid dosage: 0.55 part；Sodium hydroxide
Dosage: 0.30 part.
Step 3, the preparation of aqueous low surface tension high viscosity radioaerosol depressor: equipped with thermometer, stirring
Device, condenser pipe four-hole boiling flask in be added component 1, component 2, at 45 DEG C stir pre-emulsification 30min, then by temperature raising be
60 DEG C, when pot temperature is stablized, potassium peroxydisulfate is added into flask, reacting after continuing stirring 6 hours terminates.It obtains yellowish
Color radioaerosol depressor product.1 dosage of component: 50 parts；2 dosage of component: 50 parts；Potassium peroxydisulfate dosage: 0.1 part.
Further, the preparation method of the aqueous low surface tension high viscosity radioaerosol depressor is further to close
At component 3 or component 4 quality be 50 parts meter, specifically include:
3 preparation method of component: acrylamide and deionized water is added, being stirred at room temperature makes acryloyl in step 1 in beaker
After amine dissolution, lauryl sodium sulfate is added, stirring dissolves it sufficiently at 25 DEG C of heating water bath, is then slowly added to benzene
Ethylene stirs pre-emulsification 2h at 40 DEG C, obtains colourless transparent liquid.Deionized water dosage: 31.55 parts；Acrylamide dosage:
9 parts；Lauryl sodium sulfate dosage: 9 parts；Styrene dosage: 0.45 part.
4 preparation method of component: step 2 deionized water, acrylic acid and sodium hydroxide is added in beaker, stirs at room temperature
Dissolve it sufficiently.Initiator potassium persulfate is then added, heating stirring is uniformly dissolved at 25 DEG C of water-bath, obtains colorless and transparent liquid
Body.Deionized water dosage: 49.05 parts；Acrylic acid dosage: 0.55 part；Sodium hydroxide concentration: 0.30 part；Potassium peroxydisulfate dosage:
0.1 part.
Step 3, macromolecule emulsifier preparation: the addition group in the four-hole boiling flask that thermometer, blender, condenser pipe are housed
Points 3, component 4 stirs pre-emulsification 30min at 45 DEG C, and subsequent temperature is increased to 65 DEG C, be stirred to react after 6h obtain it is faint yellow
Prescribed liquid.Liquid is poured into and is settled out white solid in dehydrated alcohol, then white solid is dissolved in deionized water, continue thereafter with by
It, which is poured into, precipitates dissolution in dehydrated alcohol and deionized water, in triplicate, obtained white solid is dried in 80 DEG C of baking oven
White macromolecule emulsifier solid can be obtained.3 dosage of component: 50 parts；4 dosage of component: 50 parts；Deionized water dosage: 100 parts；Nothing
Water-ethanol dosage: 300 parts.
The aqueous low surface tension high viscosity radioaerosol is utilized another object of the present invention is to provide a kind of
The aqueous low surface tension high viscosity radioaerosol depressor of the preparation method of depressor.
In conclusion advantages of the present invention and good effect are as follows:
The present invention is synthetically prepared a kind of low surface tension high viscosity aqueous high molecular aerosol depressor, by designing high score
Subchain structure, drop has lower surface tension (surface) after so that its aqueous solution is atomized, it is easier to moisten with aerosol particles
Wet coalescence, so as to obtain more preferably aerosol pressing result；Make the depressor viscosity with higher of preparation simultaneously,
Spray atomizing dedusting landing after poor fluidity and can drying and forming-film, be easy to collect, not will cause radioactive diffusion pollution.
Preparation method of the invention uses self-emulsifying micro-emulsion liquid polymerization, prepared radioaerosol depressor surface
Tension is down to 26.2mN/m, viscosity up to 1260mPas, to the compacting rate of aerosol particle object 87% or more.The party simultaneously
Method is avoided in classical microemulsion polymerization process using excessive small-molecular emulsifier, is led compared with classical microemulsion polymerization
The problem of causing final radioaerosol depressor film forming caudacoria mechanics performance difference and being not easily stripped.The radioaerosol pressure
After preparation film forming, the tensile strength of membrane body is 18MPa, and elongation at break 471%, 180 ° of peel strengths are 0.489N/m, film
Body has good mechanical property and peel strength, is more advantageous to practical operation.
The preparation method advantage of aqueous low surface tension high viscosity radioaerosol depressor provided by the invention is into one
Step includes: the effects of droplet is by wetting, adherency, flocculation after depressor is atomized into droplet by atomization technique, will
Radioaerosol captures fall on body surface together, and after film-forming, radioaerosol is cured to the netted of membrane body
In structure, then membrane body is recycled, achievees the purpose that decontamination, secondary pollution will not be caused.This novel puts
Penetrating property aerosol depressor has lower surface tension, has preferably wetting capture property to the radioaerosol in air
Can, it is more advantageous to the compacting to radioaerosol.Have both the existing highly viscous advantage of aerosol depressor again simultaneously, suppresses
Agent compacting aerosol will not flow everywhere after falling on body surface, prevent radioaerosol from causing secondary pollution.The present invention into
The development of the aqueous low surface tension high viscosity radioaerosol depressor of row.The depressor is quasi- to pass through self-emulsifying by three kinds of monomers
Micro-emulsion polymerization forms: using acrylamide as the principal monomer in the polymerization of self-emulsifying micro-emulsion liquid, award high marks sub- solution one
Fixed film forming and flocculability；Using acrylic acid as the polar monomer in the polymerization of self-emulsifying micro-emulsion liquid, make in Polymer Solution
Strand has certain ductility, improves the viscosity of Polymer Solution by forming cross-linked structure between strand；Using benzene
Ethylene makes Polymer Solution have lower surface tension, is more advantageous to as the modified monomer in the polymerization of self-emulsifying micro-emulsion liquid
It improves depressor and performance is captured to the wetting of aerosol dust.Radioaerosol depressor of the invention has lower surface
Tension and higher viscosity can greatly improve the compacting efficiency of aerosol, while but also with good film forming, be more advantageous to core
Application in contingency procedure.
Detailed description of the invention
Fig. 1 is the preparation side of aqueous low surface tension high viscosity radioaerosol depressor provided in an embodiment of the present invention
Method flow chart.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to embodiments, to the present invention
It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to
Limit the present invention.
In the prior art, not over design polymer chain structure, drop has lower table after being atomized its aqueous solution
Face tension (surface energy), it is easier to soak coalescence with aerosol particles, cause to obtain more preferably aerosol pressing result；
The depressor viscosity with higher that cannot make preparation simultaneously, mobility is big after causing spray atomizing dedusting to land, not easily collecting,
Radioactive diffusion pollution is not can effectively solve.
To solve the above problems, being described in detail with reference to the accompanying drawing to technical solution of the present invention.
As shown in Figure 1, the preparation of the aqueous low surface tension high viscosity radioaerosol depressor of the embodiment of the present invention
Method by the quality of the component 1 or component 2 that synthesize be 50 parts in terms of, specifically includes the following steps:
S101: being added acrylamide and deionized water in beaker, is stirred at room temperature after dissolving acrylamide, adds height
Molecule emulsifier, stirring dissolves it sufficiently at 25 DEG C of heating water bath, is then slowly added to styrene, stirs at 40 DEG C pre-
2h is emulsified, colourless transparent liquid is obtained.Deionized water dosage: 31.55 parts.Acrylamide dosage: 9 parts.Macromolecule emulsifier is used
Amount: 9 parts.Styrene dosage: 0.45 part.
S102: being added deionized water, acrylic acid and sodium hydroxide in beaker, and stirring dissolves it sufficiently at room temperature.?
To colourless transparent liquid.Deionized water dosage: 49.15 parts.Acrylic acid dosage: 0.55 part.Sodium hydroxide concentration: 0.30 part.
S103: the preparation of aqueous low surface tension high viscosity radioaerosol depressor: equipped with thermometer, stirring
Device, condenser pipe four-hole boiling flask in be added component 1, component 2, at 45 DEG C stir pre-emulsification 30min, then by temperature raising be
60 DEG C, when pot temperature is stablized, potassium peroxydisulfate is added into flask, reacting after continuing stirring 6 hours terminates.It obtains yellowish
Color radioaerosol depressor product.1 dosage of component: 50 parts.2 dosage of component: 50 parts.Potassium peroxydisulfate dosage: 0.1 part.
In embodiments of the present invention, the preparation method of macromolecule emulsifier is with the quality of the component 3 or component 4 that synthesize for 50
Part meter.
3 preparation method of component includes: that acrylamide and deionized water are added in beaker, and being stirred at room temperature keeps acrylamide molten
Xie Hou adds lauryl sodium sulfate, and stirring dissolves it sufficiently at 25 DEG C of heating water bath, is then slowly added to benzene second
Alkene stirs pre-emulsification 2h at 40 DEG C, obtains colourless transparent liquid.Deionized water dosage: 31.55 parts.Acrylamide dosage: 9
Part.Lauryl sodium sulfate dosage: 9 parts.Styrene dosage: 0.45 part.
4 preparation method of component includes: that deionized water, acrylic acid and sodium hydroxide are added in beaker, and stirring makes at room temperature
It is sufficiently dissolved.Initiator potassium persulfate is then added, heating stirring is uniformly dissolved at 25 DEG C of water-bath, obtains colorless and transparent liquid
Body.Deionized water dosage: 49.05 parts.Acrylic acid dosage: 0.55 part.Sodium hydroxide concentration: 0.30 part.Potassium peroxydisulfate dosage:
0.1 part.
Macromolecule emulsifier preparation includes: that component 3 is added in the four-hole boiling flask that thermometer, blender, condenser pipe are housed,
Component 4, stirs pre-emulsification 30min at 45 DEG C, and subsequent temperature is increased to 65 DEG C, obtains pale yellow transparent liquid after being stirred to react 6h
Body.Liquid is poured into and is settled out white solid in dehydrated alcohol, then white solid is dissolved in deionized water, is continued thereafter with down
Enter and precipitate dissolution in dehydrated alcohol and deionized water, in triplicate, obtained white solid is dried in 80 DEG C of baking oven and can be obtained
White macromolecule emulsifier solid.3 dosage of component: 50 parts.4 dosage of component: 50 parts.Deionized water dosage: 100 parts.Anhydrous second
Alcohol dosage: 300 parts.
Application principle of the invention is further described combined with specific embodiments below.
Embodiment 1
Macromolecule emulsifier synthesis, comprising:
The preparation of 3 solution of component: 9g acrylamide and 31.55g deionized water are added in 100ml beaker, is stirred at room temperature
After dissolving acrylamide, 9g lauryl sodium sulfate is added, stirring dissolves it sufficiently at 25 DEG C of heating water bath, then
It is slowly added to 0.45g styrene, pre-emulsification 2h is stirred at 40 DEG C, obtains colourless transparent liquid.
The preparation of 4 solution of component: it is added in 100ml beaker and removes 49.05g ionized water, 0.55g acrylic acid and 0.30g hydrogen
Sodium oxide molybdena, stirring dissolves it sufficiently at room temperature.Initiator potassium persulfate 0.1g is then added, heating stirring is molten at 25 DEG C of water-bath
Solution uniformly, obtains colourless transparent liquid.
The preparation of macromolecule emulsifier solid: add in the 250ml four-hole boiling flask that thermometer, blender, condenser pipe are housed
Enter 50g component 3,50g component 4 stirs pre-emulsification 30min at 45 DEG C, and subsequent temperature is increased to 65 DEG C, obtains after being stirred to react 6h
To light yellow transparent liquid.Liquid is poured into the 500ml beaker equipped with 300g dehydrated alcohol and is settled out white solid, then will
White solid is dissolved in the 250ml beaker equipped with 100g deionized water and dissolving, continue thereafter be poured into equipped with dehydrated alcohol and
Dissolution is precipitated in the beaker of deionized water, in triplicate, obtained white solid is dried in 80 DEG C of baking oven can obtain white height
Molecule emulsifying agent solids.
Embodiment 2
In embodiments of the present invention, the preparation of radioaerosol depressor, comprising:
The preparation method of component 1: 9g acrylamide and 31.55g deionized water are added in 100ml beaker, is stirred at room temperature
After dissolving acrylamide, 9g macromolecule emulsifier is added, stirring dissolves it sufficiently at 25 DEG C of heating water bath, then slow
It is slow that 0.45g styrene is added, pre-emulsification 2h is stirred at 40 DEG C, obtains colourless transparent liquid.
The preparation method of component 2: 49.15g deionized water, 0.55g acrylic acid and 0.30g hydrogen are added in 100ml beaker
Sodium oxide molybdena, stirring dissolves it sufficiently at room temperature.Obtain colourless transparent liquid.
The preparation of radioaerosol depressor: in the 250ml four-hole boiling flask that thermometer, blender, condenser pipe are housed
50g component 1 is added, 50g component 2 stirs pre-emulsification 30min at 45 DEG C, and then increasing temperature is 60 DEG C, to warm in flask
When degree is stablized, 0.1g potassium peroxydisulfate is added into flask, reacting after continuing stirring 6 hours terminates.Obtain faint yellow radioactivity gas
Colloidal sol depressor product.
Effect of the invention is further described below with reference to aerosol depressor efficiency of dust collection test experience.
1. purpose: being measured to aerosol depressor efficiency of dust collection.
2. reference standard: there is no country or the professional standard of index of correlation at present.
The present invention is as follows to radioaerosol depressor pressing result assessment method: using Germany PALAS BEG-1000
2g experiment scheme design aerosol generator occurs in 1.4m type aerosol generating system3Inflatable confined space in, to dust
Concentration is stablized in 5000p/cm3When, atomizing spray depressor, the usage amount of depressor is 1L, and spray is completed in 10min, is protected
Mist flow is held in 100mL/min.Then under the conditions of undisturbed, existed with aerosol partial size spectrometer monitoring aerosol particles
Concentration changes with time in 15min.
3. being existed using aerosol particles after Germany PALAS WELAS-2000 aerosol partial size spectrometer monitoring atomizing spray
Concentration changes with time situation in 15min, and the aerosol partial size of detection is at 2~105 μm.Wherein the compacting efficiency of depressor is pressed
Formula (1) calculates:
4. detecting subject: aerosol depressor efficiency of dust collection.
5. experimental design includes: with step
Step 1: the preparation of aerosol depressor prepares the radioactivity gas of different surfaces tension and different viscosities in 5 respectively
Colloidal sol depressor sample, the surface tension and viscosity of sample are respectively 1#-35.654mN/m, 564mPas, 2#- in 5
32.546mN/m, 613mPas, 3#-30.149mN/m, 769mPas, 4#-28.762mN/m, 1003mPas, 5#-
26.113mN/m 1260mPas.
Step 2: test platform is built, and manual spray gun is connected with air compressor by hose, and compressed air is as spray
The power source of rifle, manual spray gun have sample jar (1L)；Gas net top portion sets movable circular open, and opening diameter 10cm is convenient
Gun slot sprays sample into gas account, and aerosol detection device sample tap is placed in inside gas account, is highly the general of gas account height,
Mouth down is sampled, aerosol particle concentration value can be continuously detected.
Step 3: the generation of aerosol.It weighs 2g dust to occur by aerosol generator to gas account, generation rate is
2g/min detects real-time aerosol concentration by granule aerosol detecting system, starts to carry out the 4th step after aerosol concentration is stablized.
Step 4: by gas net top portion carry out dust aerosol depressor atomizing spray, spray flow 1L, when spray
Between be 10min, stand after spray and keep 15min, the variation of real-time detection aerosol concentration in this process (25min).
Step 5: the calculating of aerosol efficiency of dust collection
The calculation formula of settling efficiency:
6. experimental result such as table 1.
1 depressor of table suppresses Efficiency testing result (2~105 μm)
7. analysis of experimental results: different viscosities and the depressor of surface tension are directed to the aerosol of 2~105 mu m wavebands,
Gross efficiency is suppressed between 87~93%.
Below with reference to effect, the invention will be further described.
Use acrylamide for principal monomer, acrylic acid and styrene are function modified monomer, pass through self-emulsifying micro-emulsion liquid
The method of polymerization synthesizes.Depressor of the present invention is water-soluble depressor, meets environmental-friendly feature.Depressor has lower
Surface tension has aerosol and soaks well wrapped, while having both higher viscosity again, depressor compacting aerosol is fallen
Film-forming after to ground, highly viscous depressor are more advantageous to the recycling of the solidification to pressed dust, will not make to environment
At secondary pollution, facilitate processing, in the preparation process of depressor, the styrene and acrylic monomers of different content is added, comes
Improve the surface tension and viscosity of compacting agent solution, improves depressor to the suppression performance of radioaerosol.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Made any modifications, equivalent replacements, and improvements etc., should all be included in the protection scope of the present invention within mind and principle.
Claims (10)
1. a kind of preparation method of aqueous low surface tension high viscosity radioaerosol depressor, which is characterized in that the water
Property low surface tension high viscosity radioaerosol depressor preparation method using acrylamide as radical polymerization product
In monomer, acrylic acid and styrene are the modified monomer in radical polymerization product, carry out the polymerization preparation of self-emulsifying micro-emulsion liquid；
It is molten to adjust radioactivity gas by changing the monomer ratio of acrylic acid and styrene simultaneously in depressor process for preparation
The surface tension and viscosity of glue laminated preparation.
2. the preparation method of aqueous low surface tension high viscosity radioaerosol depressor as described in claim 1, special
Sign is that the preparation method of the aqueous low surface tension high viscosity radioaerosol depressor further comprises:
Acrylamide and deionized water is added in step 1, the preparation of component 1 in beaker, and being stirred at room temperature dissolves acrylamide
Afterwards, macromolecule emulsifier is added, styrene is then added in stirring and dissolving, stirs pre-emulsification, obtains colourless transparent liquid；
Deionized water, acrylic acid and sodium hydroxide is added, at room temperature stirring and dissolving in step 2, the preparation of component 2；It obtains colourless
Transparency liquid；
Component 1 and component obtained is added in step 3, the preparation of aqueous low surface tension high viscosity radioaerosol depressor
2, pre-emulsification is stirred, then heat up, after temperature is stablized, potassium peroxydisulfate is added, continues to stir, reaction terminates, and obtains faint yellow put
Penetrating property aerosol depressor product.
3. the preparation method of aqueous low surface tension high viscosity radioaerosol depressor as claimed in claim 2, special
Sign is, in step 1, sufficiently dissolution is stirred at 25 DEG C of heating water bath, styrene is then added, pre- cream is stirred at 40 DEG C
Change 2h, obtains colourless transparent liquid；
It is used by 31.55 parts of mass parts deionized water dosage, 9 parts of acrylamide dosage, 9 parts of macromolecule emulsifier dosage and styrene
0.45 part of amount.
4. the preparation method of aqueous low surface tension high viscosity radioaerosol depressor as claimed in claim 2, special
Sign is, in step 2, by 49.15 parts of mass parts deionized water dosage, 0.55 part of acrylic acid dosage and sodium hydroxide concentration:
0.30 part；
Component 1 is added in the four-hole boiling flask that thermometer, blender, condenser pipe are housed, component 2 stirs pre-emulsification at 45 DEG C
30min, then increasing temperature is 60 DEG C, when pot temperature is stablized, potassium peroxydisulfate is added into flask, continues stirring 6
Reacting after hour terminates.
5. the preparation method of aqueous low surface tension high viscosity radioaerosol depressor as claimed in claim 2, special
Sign is, in step 3, by 50 parts of 1 dosage of content of component, 50 parts and 0.1 part of potassium peroxydisulfate dosage of 2 dosage of component.
6. the preparation method of aqueous low surface tension high viscosity radioaerosol depressor as claimed in claim 2, special
Sign is that the preparation method of the aqueous low surface tension high viscosity radioaerosol depressor further comprises:
Acrylamide and deionized water is added in the first step, the preparation of component 3 in beaker, and being stirred at room temperature dissolves acrylamide
Afterwards, lauryl sodium sulfate is added, stirring dissolves it sufficiently at 25 DEG C of heating water bath, it is then slowly added to styrene,
Pre-emulsification 2h is stirred at 40 DEG C, obtains colourless transparent liquid；
Deionized water, acrylic acid and sodium hydroxide is added in second step, 4 preparation method of component in beaker, and stirring makes molten at room temperature
Solution；Initiator potassium persulfate is then added, heating stirring is uniformly dissolved at 25 DEG C of water-bath, obtains colourless transparent liquid；
Component is added in the four-hole boiling flask that thermometer, blender, condenser pipe are housed in third step, the preparation of macromolecule emulsifier
3, component 4 stirs pre-emulsification 30min at 45 DEG C, and subsequent temperature is increased to 65 DEG C, obtains pale yellow transparent after being stirred to react 6h
Liquid；Liquid is poured into and is settled out white solid in dehydrated alcohol, then white solid is dissolved in deionized water, is continued thereafter with it
It pours into and precipitates dissolution in dehydrated alcohol and deionized water, in triplicate, obtained white solid is dried in 80 DEG C of baking oven
White macromolecule emulsifier solid.
7. the preparation method of aqueous low surface tension high viscosity radioaerosol depressor as claimed in claim 6, special
Sign is, in the first step, uses by 31.55 parts of mass parts deionized water dosage, 9 parts of acrylamide dosage, lauryl sodium sulfate
Amount 9 parts and styrene dosage: 0.45 part.
8. the preparation method of aqueous low surface tension high viscosity radioaerosol depressor as claimed in claim 6, special
Sign is, in second step, by 49.05 parts of mass parts deionized water dosage, 0.55 part of acrylic acid dosage, sodium hydroxide concentration 0.30
Part and potassium peroxydisulfate dosage: 0.1 part.
9. the preparation method of aqueous low surface tension high viscosity radioaerosol depressor as claimed in claim 6, special
Sign is, in third step, by 3 dosage of content of component: 50 parts, 50 parts of 4 dosage of component, 100 parts of deionized water dosage and anhydrous
300 parts of ethanol consumption.
10. a kind of utilize aqueous low surface tension high viscosity radioaerosol depressor described in claim 1~9 any one
Preparation method aqueous low surface tension high viscosity radioaerosol depressor.
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