CN110240775A - A kind of high-strength, high quality anti-corrosion composite daylighting and preparation method thereof - Google Patents
A kind of high-strength, high quality anti-corrosion composite daylighting and preparation method thereof Download PDFInfo
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- CN110240775A CN110240775A CN201910455113.3A CN201910455113A CN110240775A CN 110240775 A CN110240775 A CN 110240775A CN 201910455113 A CN201910455113 A CN 201910455113A CN 110240775 A CN110240775 A CN 110240775A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C08L33/12—Homopolymers or copolymers of methyl methacrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The present invention relates to technical field of polymer materials, and in particular to a kind of high-strength, high quality anti-corrosion composite daylighting and preparation method thereof；High-strength, high quality anti-corrosion composite daylighting the composition are as follows: mass fraction is 100-120 parts of matrix material, 6-10 parts of auxiliary reinforcing agent, 4-8 parts of auxiliary toughener, 2-5 parts of lubricant, 1-2 parts of color masterbatch, 10-15 parts other adjuvants.Its intensity of the composite daylighting of preparation prepared by the present invention is higher, ageing-resistant performance is preferable, phenomena such as being not in aging and light transmittance reduction after long-time use, it is with very high corrosion resistance simultaneously, it can be applied to the more severe place of environment, furthermore its preparation process is by a relatively simple, can carry out continous way large-scale production.
Description
Technical field
The invention belongs to technical field of polymer materials, and in particular to a kind of high-strength, high quality anti-corrosion composite daylighting and
Preparation method.
Background technique
Daylighting tile or plane skylight its mainly by film, strengthen the material compositions such as polyester and glass fibre, with non-
Often more advantage, e.g., the good characteristics such as light transmittance is good, acidproof, corrosion-resistant, while it is also green product, for saving
There is very big advantage in terms of the energy, is widely used in, the fields such as cultivation place, crop planting, decoration design for residence.But its
By prolonged use, it may occur that cracking, intensity decline are leaked, while the transparency of plane skylight can be gradually reduced, and be adopted
Luminosity cannot satisfy the use demand, therefore for these problems existing for plane skylight, the invention proposes a kind of high-strength, high quality
The preparation method of anti-corrosion composite daylighting can be good at solving these problems.
Summary of the invention
In order to achieve the purpose that in background technique, one kind proposed by the present invention is high-strength, high quality anti-corrosion composite daylighting and
Preparation method；
What the present invention realized by the following technical solutions:
A kind of high-strength, high quality anti-corrosion composite daylighting and preparation method thereof, which is characterized in that it is described it is high-strength, high quality is anti-
The composition of rotten composite daylighting are as follows: matrix material that mass fraction is 100-120 part, 6-10 parts assist reinforcing agent, 4-8 parts auxiliary
Help toughener, 2-5 parts of lubricant, 1-2 parts of color masterbatch, 10-15 parts other adjuvants；
Described one kind is high-strength, high quality anti-corrosion composite daylighting the preparation method comprises the following steps: the base for being 100-120 parts by mass fraction
Body material, 6-10 parts of auxiliary reinforcing agent, 4-8 parts of auxiliary toughener, 2-5 parts of lubricant, 1-2 parts of color masterbatch, 10-15 parts
Other adjuvants be added batch mixer in mixed, after mixing, will material be added twin-screw granulating extruder in carry out
It is granulated and squeezes out, obtain mixture grain, obtained particle is then subjected to heat fusing extrusion, it is cooling, it cuts, post-processes, packaging obtains
What is arrived is exactly high-strength, high quality anti-corrosion composite daylighting.
Further, the matrix material are as follows: polymethyl methacrylate, 30-50 by mass fraction for 100-120 parts
The polymethylacrylic acid fourth rouge of part, 20-30 parts of polyacrylic acid fourth rouge are added in anti-batch mixer, are obtained after mixing
Substance, the substance are exactly matrix material.
Further, the auxiliary reinforcing agent are as follows: by mass fraction be 15-20 parts bisphenol A-type polycarbonate (PC),
5-10 parts of polystyrene, 5-10 parts ABS, 60-80 part glass fibre be added batch mixer in, obtained after mixing
Substance, which is exactly to assist reinforcing agent.
Further, the auxiliary toughener are as follows: by mass fraction be 10-15 parts of polybutene rubbers, 6-8 parts of high glue
Powder, 3-6 parts of poly- butyronitrile, 15-20 parts of poly- carbonic acid fiber, 3-5 parts of polyvinyl alcohol enter in batch mixer, carry out after mixing
Obtained substance, the substance are exactly auxiliary toughener.
Further, the lubricant are as follows: by mass fraction be 3-5 parts of sodium sorbates, 3-4 parts G20,4-6 part
Stearic acid, 2-4 parts of G60 is added in reaction kettle, and reaction 2-3 hours is carried out under the conditions of 60-70 DEG C, is carried out after fully reacting cold
But, it is crushed after cooling, the substance obtained after crushing is exactly lubricant.
Further, the color masterbatch are as follows: its matrix material is polyacrylic acid lipid material, and pigment is assorted organic face
Material.
Further, other described adjuvants are as follows: by mass fraction be 6-10 part UV absorbers, 3-4 parts resist
Aging agent, 10-15 parts of polyurethane, 2-4 parts of polyphenyl, 2-4 parts of antistatic agent are added in batch mixer, carry out after mixing
Obtained substance, the substance are exactly other auxiliary.
Beneficial to benefit
Its intensity of the composite daylighting of preparation prepared by the present invention is higher, and ageing-resistant performance is preferable, will not go out after long-time use
Phenomena such as existing aging and light transmittance reduce, while it is more severe to can be applied to environment with very high corrosion resistance for it
Place, furthermore its preparation process is by a relatively simple, can carry out continous way large-scale production.
Specific embodiment
In order to keep the purpose of the present invention, technical scheme and beneficial effects clearer, below in conjunction with experimental data, to this
The preferred embodiment of invention is described in detail, to facilitate the technical staff to understand.
Embodiment 1
It is a kind of high-strength, high quality anti-corrosion composite daylighting the preparation method comprises the following steps:
It is 120 parts of matrix material, 10 parts of auxiliary reinforcing agent, 8 parts of auxiliary toughener, 5 parts of lubricant, 2 by mass fraction
The color masterbatch of part, 15 parts other adjuvants are added in batch mixer and are mixed, and after mixing, material addition twin-screw is made
Granulation extrusion is carried out in grain extruder, obtains mixture grain, obtained particle is then subjected to heat fusing extrusion, it is cooling, it cuts,
Post-processing, packaging, what is obtained is exactly high-strength, high quality anti-corrosion composite daylighting.
Further, the matrix material are as follows: by mass fraction be 120 parts polymethyl methacrylate, 50 parts poly-
Methacrylic acid fourth rouge, 30 parts of polyacrylic acid fourth rouge are added in anti-batch mixer, the substance obtained after mixing, the object
Matter is exactly matrix material.
Further, the auxiliary reinforcing agent are as follows: by mass fraction be 20 parts bisphenol A-type polycarbonate (PC), 10
The polystyrene, 10 parts of ABS, 80 parts of glass fibre of part are added in batch mixer, and the substance obtained after mixing should
Substance is exactly to assist reinforcing agent.
Further, the auxiliary toughener are as follows: by mass fraction be 15 parts of polybutene rubbers, 8 parts of high glue powder, 6
The poly- butyronitrile, 20 parts of poly- carbonic acid fiber, 5 parts of polyvinyl alcohol of part enter in batch mixer, the substance obtained after mixing,
The substance is exactly auxiliary toughener.
Further, the lubricant are as follows: by mass fraction be 5 parts of sodium sorbates, 4 parts of G20,6 parts of stearic acid,
4 parts of G60 is added in reaction kettle, and reaction 2-3 hours is carried out under the conditions of 60-70 DEG C, is cooled down after fully reacting, after cooling
It is crushed, the substance obtained after crushing is exactly lubricant.
Further, the color masterbatch are as follows: its matrix material is polyacrylic acid lipid material, and pigment is assorted organic face
Material.
Further, other described adjuvants are as follows: by mass fraction be 10 parts of UV absorbers, 4 parts anti-aging
Agent, 15 parts of polyurethane, 4 parts of polyphenyl, 4 parts of antistatic agent are added in batch mixer, the substance obtained after mixing,
The substance is exactly other auxiliary.
Embodiment 2
It is a kind of high-strength, high quality anti-corrosion composite daylighting the preparation method comprises the following steps:
It is 100 parts of matrix material, 6 parts of auxiliary reinforcing agent, 4 parts of auxiliary toughener, 2 parts of lubricant, 1 part by mass fraction
Color masterbatch, 10 parts other adjuvants be added batch mixer in mixed, after mixing, by material be added twin-screw be granulated
Granulation extrusion is carried out in extruder, obtains mixture grain, and obtained particle is then subjected to heat fusing extrusion, it is cooling, it cuts, after
Processing, packaging, what is obtained is exactly high-strength, high quality anti-corrosion composite daylighting.
Further, the matrix material are as follows: by mass fraction be 100 parts polymethyl methacrylate, 30-50 parts
Polymethylacrylic acid fourth rouge, 20 parts of polyacrylic acid fourth rouge are added in anti-batch mixer, and the substance obtained after mixing should
Substance is exactly matrix material.
Further, the auxiliary reinforcing agent are as follows: by mass fraction be 15 parts bisphenol A-type polycarbonate (PC), 5 parts
Polystyrene, 5 parts of ABS, 60 parts glass fibre be added batch mixer in, the substance obtained after mixing, the object
Matter is exactly to assist reinforcing agent.
Further, the auxiliary toughener are as follows: by mass fraction be 10 parts of polybutene rubbers, 6 parts of high glue powder, 3
The poly- butyronitrile, 15 parts of poly- carbonic acid fiber, 3 parts of polyvinyl alcohol of part enter in batch mixer, the substance obtained after mixing,
The substance is exactly auxiliary toughener.
Further, the lubricant are as follows: by mass fraction be 3 parts of sodium sorbates, 3 parts of G20,4 parts of stearic acid,
2 parts of G60 is added in reaction kettle, and reaction 2-3 hours is carried out under the conditions of 60-70 DEG C, is cooled down after fully reacting, after cooling
It is crushed, the substance obtained after crushing is exactly lubricant.
Further, the color masterbatch are as follows: its matrix material is polyacrylic acid lipid material, and pigment is assorted organic face
Material.
Further, other described adjuvants are as follows: by mass fraction be 6 parts of UV absorbers, 3 parts anti-aging
Agent, 10 parts of polyurethane, 2 parts of polyphenyl, 2 parts of antistatic agent are added in batch mixer, the substance obtained after mixing,
The substance is exactly other auxiliary.
Embodiment 3
It is a kind of high-strength, high quality anti-corrosion composite daylighting the preparation method comprises the following steps:
It is 110 parts of matrix material, 10 parts of auxiliary reinforcing agent, 5 parts of auxiliary toughener, 5 parts of lubricant, 1 by mass fraction
The color masterbatch of part, 10 parts other adjuvants are added in batch mixer and are mixed, and after mixing, material addition twin-screw is made
Granulation extrusion is carried out in grain extruder, obtains mixture grain, obtained particle is then subjected to heat fusing extrusion, it is cooling, it cuts,
Post-processing, packaging, what is obtained is exactly high-strength, high quality anti-corrosion composite daylighting.
Further, the matrix material are as follows: by mass fraction be 110 parts polymethyl methacrylate, 30 parts poly-
Methacrylic acid fourth rouge, 25 parts of polyacrylic acid fourth rouge are added in anti-batch mixer, the substance obtained after mixing, the object
Matter is exactly matrix material.
Further, the auxiliary reinforcing agent are as follows: by mass fraction be 18 parts bisphenol A-type polycarbonate (PC), 10
The polystyrene, 6 parts of ABS, 80 parts of glass fibre of part are added in batch mixer, and the substance obtained after mixing should
Substance is exactly to assist reinforcing agent.
Further, the auxiliary toughener are as follows: by mass fraction be 12 parts of polybutene rubbers, 8 parts of high glue powder, 5
The poly- butyronitrile, 15 parts of poly- carbonic acid fiber, 4 parts of polyvinyl alcohol of part enter in batch mixer, the substance obtained after mixing,
The substance is exactly auxiliary toughener.
Further, the lubricant are as follows: by mass fraction be 4 parts of sodium sorbates, 4 parts of G20,5 parts of stearic acid,
2 parts of G60 is added in reaction kettle, and reaction 2-3 hours is carried out under the conditions of 60-70 DEG C, is cooled down after fully reacting, after cooling
It is crushed, the substance obtained after crushing is exactly lubricant.
Further, the color masterbatch are as follows: its matrix material is polyacrylic acid lipid material, and pigment is assorted organic face
Material.
Further, other described adjuvants are as follows: by mass fraction be 8 parts of UV absorbers, 4 parts anti-aging
Agent, 12 parts of polyurethane, 2 parts of polyphenyl, 3 parts of antistatic agent are added in batch mixer, the substance obtained after mixing,
The substance is exactly other auxiliary.
Embodiment 4
It is a kind of high-strength, high quality anti-corrosion composite daylighting the preparation method comprises the following steps:
It is 100 parts of matrix material, 8 parts of auxiliary reinforcing agent, 8 parts of auxiliary toughener, 3 parts of lubricant, 1 part by mass fraction
Color masterbatch, 12 parts other adjuvants be added batch mixer in mixed, after mixing, by material be added twin-screw be granulated
Granulation extrusion is carried out in extruder, obtains mixture grain, and obtained particle is then subjected to heat fusing extrusion, it is cooling, it cuts, after
Processing, packaging, what is obtained is exactly high-strength, high quality anti-corrosion composite daylighting.
Further, the matrix material are as follows: by mass fraction be 120 parts polymethyl methacrylate, 40 parts poly-
Methacrylic acid fourth rouge, 30 parts of polyacrylic acid fourth rouge are added in anti-batch mixer, the substance obtained after mixing, the object
Matter is exactly matrix material.
Further, the auxiliary reinforcing agent are as follows: by mass fraction be 20 parts bisphenol A-type polycarbonate (PC), 6 parts
Polystyrene, 5 parts of ABS, 70 parts glass fibre be added batch mixer in, the substance obtained after mixing, the object
Matter is exactly to assist reinforcing agent.
Further, the auxiliary toughener are as follows: by mass fraction be 15 parts of polybutene rubbers, 7 parts of high glue powder, 3
The poly- butyronitrile, 18 parts of poly- carbonic acid fiber, 5 parts of polyvinyl alcohol of part enter in batch mixer, the substance obtained after mixing,
The substance is exactly auxiliary toughener.
Further, the lubricant are as follows: by mass fraction be 3 parts of sodium sorbates, 3 parts of G20,6 parts of stearic acid,
3 parts of G60 is added in reaction kettle, and reaction 2-3 hours is carried out under the conditions of 60-70 DEG C, is cooled down after fully reacting, after cooling
It is crushed, the substance obtained after crushing is exactly lubricant.
Further, the color masterbatch are as follows: its matrix material is polyacrylic acid lipid material, and pigment is assorted organic face
Material.
Further, other described adjuvants are as follows: by mass fraction be 10 parts of UV absorbers, 3 parts anti-aging
Agent, 10 parts of polyurethane, 3 parts of polyphenyl, 4 parts of antistatic agent are added in batch mixer, the substance obtained after mixing,
The substance is exactly other auxiliary.
Experimental analysis:
1, product mechanical property is tested
The similar plane skylight that the plane skylight of the preparation of embodiment 1-4 and market are bought is subjected to Mechanics Performance Testing, is tested, knot
Fruit is as shown in the table:
| Project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | The same product of market purchase |
| Tensile strength (MPa) | 325 | 316 | 345 | 324 | 275 |
| Punching intensity (MPa) | 231 | 228 | 228 | 232 | 186 |
| Shore hardness (D) | 87 | 86 | 86 | 86 | 82 |
| Bending strength (MPa) | 362 | 354 | 352 | 361 | 242 |
Above-mentioned test result it is found that its mechanical property of compound Colour light plate prepared by the present invention is more preferable compared with the performance than similar product,
It can be good at the product that substitution production is sold.
Finally, it is stated that preferred embodiment above is only used to illustrate the technical scheme of the present invention rather than limits, although logical
It crosses above preferred embodiment the present invention is described in detail, however, those skilled in the art should understand that, can be
Various changes are made to it in form and in details, without departing from defined by claims of the present invention.
Claims (7)
1. a kind of high-strength, high quality anti-corrosion composite daylighting and preparation method thereof, which is characterized in that high-strength, the high quality
The composition of anti-corrosion composite daylighting are as follows: matrix material that mass fraction is 100-120 part, 6-10 parts assist reinforcing agent, 4-8 parts
Auxiliary toughener, 2-5 parts of lubricant, 1-2 parts of color masterbatch, 10-15 parts other adjuvants；
Described one kind is high-strength, high quality anti-corrosion composite daylighting the preparation method comprises the following steps: the base for being 100-120 parts by mass fraction
Body material, 6-10 parts of auxiliary reinforcing agent, 4-8 parts of auxiliary toughener, 2-5 parts of lubricant, 1-2 parts of color masterbatch, 10-15 parts
Other adjuvants be added batch mixer in mixed, after mixing, will material be added twin-screw granulating extruder in carry out
It is granulated and squeezes out, obtain mixture grain, obtained particle is then subjected to heat fusing extrusion, it is cooling, it cuts, post-processes, packaging obtains
What is arrived is exactly high-strength, high quality anti-corrosion composite daylighting.
2. one kind according to claim 1 is high-strength, high quality anti-corrosion composite daylighting and preparation method thereof, feature exists
In the matrix material are as follows: by mass fraction be 100-120 parts of polymethyl methacrylate, 30-50 parts of polymethyl
Sour fourth rouge, 20-30 parts of polyacrylic acid fourth rouge are added in anti-batch mixer, and the substance obtained after mixing, the substance is just
It is matrix material.
3. one kind according to claim 1 is high-strength, high quality anti-corrosion composite daylighting and preparation method thereof, feature exists
In the auxiliary reinforcing agent are as follows: by mass fraction be 15-20 parts of bisphenol A-type polycarbonate (PC), 5-10 parts of polyphenyl second
The glass fibre of alkene, 5-10 parts ABS, 60-80 part is added in batch mixer, the substance obtained after mixing, the substance
Exactly assist reinforcing agent.
4. one kind according to claim 1 is high-strength, high quality anti-corrosion composite daylighting and preparation method thereof, feature exists
In the auxiliary toughener are as follows: by mass fraction be 10-15 parts of polybutene rubbers, 6-8 parts of high glue powder, 3-6 parts of poly- fourth
Nitrile, 15-20 parts of poly- carbonic acid fiber, 3-5 parts of polyvinyl alcohol enter in batch mixer, the substance obtained after mixing, should
Substance is exactly auxiliary toughener.
5. one kind according to claim 1 is high-strength, high quality anti-corrosion composite daylighting and preparation method thereof, feature exists
In the lubricant are as follows: by mass fraction be 3-5 parts of sodium sorbates, the stearic acid of 3-4 parts G20,4-6 part, 2-4 parts
G60 is added in reaction kettle, and reaction 2-3 hours is carried out under the conditions of 60-70 DEG C, is cooled down after fully reacting, by it after cooling
It is crushed, the substance obtained after crushing is exactly lubricant.
6. one kind according to claim 1 is high-strength, high quality anti-corrosion composite daylighting and preparation method thereof, feature exists
In the color masterbatch are as follows: its matrix material is polyacrylic acid lipid material, and pigment is assorted organic pigment.
7. one kind according to claim 1 is high-strength, high quality anti-corrosion composite daylighting and preparation method thereof, feature exists
In other described adjuvants are as follows: by mass fraction be 6-10 parts of UV absorbers, 3-4 parts of age resister, 10-15 parts
Polyurethane, 2-4 parts of polyphenyl, 2-4 parts antistatic agent be added batch mixer in, the substance obtained after mixing, this
Substance is exactly other auxiliary.
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| CN201910455113.3A CN110240775A (en) | 2019-05-29 | 2019-05-29 | A kind of high-strength, high quality anti-corrosion composite daylighting and preparation method thereof |
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| CN201910455113.3A CN110240775A (en) | 2019-05-29 | 2019-05-29 | A kind of high-strength, high quality anti-corrosion composite daylighting and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0354237A (en) * | 1989-05-26 | 1991-03-08 | Exxon Chem Patents Inc | Dynamically vulcanized alloy having improved rigidity/impact balance |
| CN105694326A (en) * | 2016-04-27 | 2016-06-22 | 广东东华光电科技有限公司 | Light guiding material and light guiding plate |
| CN109337243A (en) * | 2018-09-28 | 2019-02-15 | 贺州钟山县双文碳酸钙新材料有限公司 | Utilize the PVC calcium-plastic board material and preparation method thereof of modified calcium carbonate enhancing |
| CN109354799A (en) * | 2018-09-30 | 2019-02-19 | 常熟市景弘盛通信科技股份有限公司 | A kind of preparation method of the dedicated ultra-thin-wall PVC material of automotive line |
-
2019
- 2019-05-29 CN CN201910455113.3A patent/CN110240775A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0354237A (en) * | 1989-05-26 | 1991-03-08 | Exxon Chem Patents Inc | Dynamically vulcanized alloy having improved rigidity/impact balance |
| CN105694326A (en) * | 2016-04-27 | 2016-06-22 | 广东东华光电科技有限公司 | Light guiding material and light guiding plate |
| CN109337243A (en) * | 2018-09-28 | 2019-02-15 | 贺州钟山县双文碳酸钙新材料有限公司 | Utilize the PVC calcium-plastic board material and preparation method thereof of modified calcium carbonate enhancing |
| CN109354799A (en) * | 2018-09-30 | 2019-02-19 | 常熟市景弘盛通信科技股份有限公司 | A kind of preparation method of the dedicated ultra-thin-wall PVC material of automotive line |
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| Title |
|---|
| 田英良等: "《新编玻璃工艺学》", 30 June 2009, 中国轻工业出版社 * |
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Application publication date: 20190917 |