CN110229633A - High temperature resistant type waterproof roll - Google Patents
High temperature resistant type waterproof roll Download PDFInfo
- Publication number
- CN110229633A CN110229633A CN201910579440.XA CN201910579440A CN110229633A CN 110229633 A CN110229633 A CN 110229633A CN 201910579440 A CN201910579440 A CN 201910579440A CN 110229633 A CN110229633 A CN 110229633A
- Authority
- CN
- China
- Prior art keywords
- high temperature
- temperature resistant
- layer
- butyl
- waterproof roll
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000010410 layer Substances 0.000 claims abstract description 171
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- 239000000463 material Substances 0.000 claims abstract description 75
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 22
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 22
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 claims description 20
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- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 12
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 11
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 11
- 150000002148 esters Chemical class 0.000 claims description 11
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 11
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- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 10
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- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 8
- ICKWICRCANNIBI-UHFFFAOYSA-N 2,4-(1,1-dimethylethyl)-phenol Natural products CC(C)(C)C1=CC=C(O)C(C(C)(C)C)=C1 ICKWICRCANNIBI-UHFFFAOYSA-N 0.000 claims description 7
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- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 6
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- 229920000305 Nylon 6,10 Polymers 0.000 claims description 6
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 6
- 229920001568 phenolic resin Polymers 0.000 claims description 6
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- 229920003180 amino resin Polymers 0.000 claims description 5
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 4
- 239000012964 benzotriazole Substances 0.000 claims description 4
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 4
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- INJVFBCDVXYHGQ-UHFFFAOYSA-N n'-(3-triethoxysilylpropyl)ethane-1,2-diamine Chemical compound CCO[Si](OCC)(OCC)CCCNCCN INJVFBCDVXYHGQ-UHFFFAOYSA-N 0.000 claims description 4
- ZNOKGRXACCSDPY-UHFFFAOYSA-N tungsten trioxide Chemical compound O=[W](=O)=O ZNOKGRXACCSDPY-UHFFFAOYSA-N 0.000 claims description 3
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
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- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
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- 239000011737 fluorine Substances 0.000 description 4
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- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 2
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- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
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- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical group [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
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- DJOWTWWHMWQATC-KYHIUUMWSA-N Karpoxanthin Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1(O)C(C)(C)CC(O)CC1(C)O)C=CC=C(/C)C=CC2=C(C)CC(O)CC2(C)C DJOWTWWHMWQATC-KYHIUUMWSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 235000005128 Sapium sebiferum Nutrition 0.000 description 1
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- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
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- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C—CHEMISTRY; METALLURGY
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- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
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- C09J145/00—Adhesives based on homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic system; Adhesives based on derivatives of such polymers
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- C09J157/02—Copolymers of mineral oil hydrocarbons
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- C09J193/00—Adhesives based on natural resins; Adhesives based on derivatives thereof
- C09J193/04—Rosin
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
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- C09J7/29—Laminated material
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
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- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/16—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the structure of the carrier layer
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2400/00—Presence of inorganic and organic materials
- C09J2400/10—Presence of inorganic materials
- C09J2400/16—Metal
- C09J2400/163—Metal in the substrate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2467/00—Presence of polyester
- C09J2467/006—Presence of polyester in the substrate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to waterproof roll fields, disclose a kind of high temperature resistant type waterproof roll, including polymer base material layer, hot melt adhesive layer, metal foil layer and the heat-resisting butyl glue-line being cascading；Wherein, heat-resisting butyl glue-line includes each component of following mass parts: 15~30 parts of plasticizer, 10~40 parts of butyl rubber, 20~50 parts of high temperature resistant filler, 30~60 parts of tackifying resin, 0.5~2 part of coupling agent and 0.5~2 part of age resister.The butyl rubber of high molecular weight and the plasticizer of high molecular weight, it is equipped with the tackifying resin good with butyl rubber compatibility, reaction, which generates, has latticed butyl rubber, reduce intermolecular sliding rate, and the combination of coupling agent and high temperature resistant filler, so that high temperature resistant filler surface is wrapped up by oiliness group, improve the compatibility of high temperature resistant filler and butyl rubber, so that filler particles are uniformly embedded into the molecular network of latticed butyl rubber, reduce the deformation and sliding of the butyl rubber molecular network under high temperature action, to improve the heat resistance of heat-resisting butyl glue-line.
Description
Technical field
The present invention relates to waterproof roll fields, more particularly to a kind of high temperature resistant type waterproof roll.
Background technique
Waterproof roll, the coiled waterproof material made of pitch, rubber or other organic materials are commonly called as malthoid or oily hair
Felt.It has good waterproofness and preferable flexibility.Pitch class or high score subclass waterproof material are immersed on carcass, made
The waterproof material product being made, provides, referred to as waterproof roll as coils.It is different according to main composition material, it is divided into pitch
Waterproof roll, polymer modified bituminous waterproof sheet material and synthetic polymeric waterproofing material；It is divided into no carcass according to the difference of carcass
Coiled material, paper tire coiled material, glass fibre tire coiled material, glass cloth tire coiled material and polyethylene tire coiled material.Waterproof roll requires to have good
Water resistance, to the stability of temperature change (do not trickle under high temperature, it is not blistering, do not confuse, not embrittlement under low temperature), certain machinery
Intensity, extensibility and resistance to fracture will have certain flexibility and ageing resistance etc..
Traditional water proof roofing sheet mainly has asphalt water-proof coiled material, polymer modified bituminous waterproof sheet material, synthesizes high score
Sub- waterproof roll.Asphalt water-proof coiled material and polymer modified bituminous waterproof sheet material ageing resistance are poor, are easy embrittlement, lose waterproof effect
Fruit.
However, the adhesive-layer of traditional polymer membranes and the bonding force of roofing are weaker, waterproofness is poor, for a long time with
Water contact, can have an impact bond effect, so that the contact surface of glue and roofing is made to generate gap, it later will leak.Moreover,
The adhesive-layer heat resistance of traditional polymer membranes is poor, does not tolerate to light, heat, will occur more than 80 DEG C of temperature
Deformation is guttered down along roofing, and coiled material is caused to fail.
Summary of the invention
The purpose of the present invention is overcoming shortcoming in the prior art, provide it is a kind of with excellent heat resistance, it is anti-
The high temperature resistant type waterproof roll of ageing properties, adhesive property and waterproof performance.
The purpose of the present invention is achieved through the following technical solutions:
A kind of high temperature resistant type waterproof roll, including be cascading polymer base material layer, hot melt adhesive layer, metal foil layer
And heat-resisting butyl glue-line；
Wherein, the heat-resisting butyl glue-line includes each component of following mass parts: 15~30 parts of plasticizer, butyl rubber 10
~40 parts, 20~50 parts of high temperature resistant filler, 30~60 parts of tackifying resin, 0.5~2 part of coupling agent and 0.5~2 part of age resister.
In a kind of wherein embodiment, the plasticizer is polyisobutene, phthalic acid two (2- ethyl hexyl) ester, neighbour
At least one of dioctyl phthalate and BBP(Butyl Benzyl Phthalate.
In a kind of wherein embodiment, the high temperature resistant filler is calcium carbonate, mica powder, titanium dioxide, diatomite and cunning
At least one of mountain flour.
In a kind of wherein embodiment, the tackifying resin is rosin resin, terpene resin, phenolic resin and petroleum tree
At least one of rouge.
In a kind of wherein embodiment, the coupling agent is vinyl three ('beta '-methoxy ethyoxyl) silane, γ-ammonia third
Base trimethoxy silane, N- (β-aminoethyl)-gamma-aminopropyl-triethoxy-silane and γ-county methyl Bin Xi aminopropyl trimethoxy
At least one of base silane.
In a kind of wherein embodiment, the age resister is β (- 4 hydroxy phenyl of 3,5- di-t-butyl) propionic acid season penta
Double 2,2,6, the 6- tetramethyl piperidine alcohol esters of tetrol, three (2,4-DTBP) phosphite esters, decanedioic acid and 2- (2 ,-hydroxyl-
At least one of 5, methyl)-benzotriazole.
In a kind of wherein embodiment, the polymer base material layer is polyethylene terephthalate substrate, poly- pair
Benzene dicarboxylic acid butanediol ester substrate, high-density polyethylene resin substrate, butyl nitrile EP rubbers substrate, organic siliconresin substrate or
Person's amino resins substrate.
In a kind of wherein embodiment, the metal foil layer is aluminium foil, nickel foil or cobalt foil.
In a kind of wherein embodiment, the high temperature resistant type waterproof roll further includes release film layer, the hot melt adhesive layer
On one side coated on the polymer base material layer, the metal foil layer is attached to the hot melt adhesive layer far from the macromolecule
On the one side of substrate layer, the heat-resisting butyl glue-line is coated on one side of the metal foil layer far from the hot melt adhesive layer
On, the release film layer is attached on the heat-resisting one side of the butyl glue-line far from the metal foil layer.
In a kind of wherein embodiment, the thickness of the polymer base material layer, the hot melt adhesive layer and the metal foil layer
The sum of degree is 0.05mm~0.2mm.
Compared with prior art, the present invention has at least the following advantages:
1, this high temperature resistant type waterproof roll selects the butyl rubber of high molecular weight and the plasticizer of high molecular weight, is equipped with and fourth
The good tackifying resin of base rubber compatibility, reaction, which generates, has latticed butyl rubber, reduces intermolecular sliding rate, from
And it is higher than general pressure sensitive adhesive heat-resisting quantity.After butyl rubber, which is reacted with plasticizer, generates latticed butyl rubber, coupling agent with
High temperature resistant filler combines so that high temperature resistant filler surface is wrapped up by oiliness group, thus hydrophobization, improve high temperature resistant filler with
The compatibility of butyl rubber reduces under high temperature action, butyl rubber so that filler particles are uniformly embedded into the molecular network of butyl rubber
The deformation and sliding of molecular network, that is, improve the heat-resisting quantity of butyl rubber, to improve the heat-resisting quantity of coiled material.
2, the plasticizer of this high temperature resistant type waterproof roll can be improved the bonding force of butyl rubber, flexibility, resistance to ag(e)ing,
Air-tightness and electrical insulating property.Especially polyisobutene, since itself has good light resistance, heat resistance and inoxidizability,
The heat resistance of butyl rubber can be enhanced.
3, the tackifying resin of this high temperature resistant type waterproof roll has good viscosity, internal cohesiveness and heat resistance, can make
Plasticizer is well merged with butyl rubber, and can be improved the heat resistant adhesive power and heat resistance of butyl rubber.
4, the coupling agent tool of this high temperature resistant type waterproof roll two groups different there are two types of chemical property, one is close nothing
The group of machine object, easily with mineral surfaces chemically reactive；The other is organophilic group, it can be with butyl rubber
It learns reaction to be dissolved in wherein, to improve the interface interaction between inorganic matter and organic matter, that is, improves high temperature resistant filler and butyl
The compatibility of glue reduces under high temperature action, butyl so that high temperature resistant filler particles are uniformly embedded into the molecular network of butyl rubber
The deformation and sliding of xanthan molecule net, to greatly improve the heat resistance of butyl rubber.Other Jie such as water, air can also be prevented simultaneously
Matter is permeated into butyl rubber, is conducive to waterproofness, ageing-resistant, proof stress and the electrical insulation capability of butyl rubber.
5, on the one hand free radical can be absorbed in the age resister of this high temperature resistant type waterproof roll, prevents the latticed of butyl rubber
Long-chain is broken under the high temperature conditions, and light, thermal energy on the other hand can be absorbed, discharge in the form of heat, alleviates light, heat
Destruction to heat-resisting butyl glue-line, and then improve the weatherability and ageing resistance of coiled material.
Detailed description of the invention
In order to illustrate the technical solution of the embodiments of the present invention more clearly, below will be to needed in the embodiment attached
Figure is briefly described, it should be understood that the following drawings illustrates only certain embodiments of the present invention, therefore is not construed as pair
The restriction of range for those of ordinary skill in the art without creative efforts, can also be according to this
A little attached drawings obtain other relevant attached drawings.
Fig. 1 is the structural schematic diagram of the high temperature resistant type waterproof roll of one embodiment of the invention mode.
Specific embodiment
To facilitate the understanding of the present invention, a more comprehensive description of the invention is given in the following sections with reference to the relevant attached drawings.In attached drawing
Give better embodiment of the invention.But the invention can be realized in many different forms, however it is not limited to herein
Described embodiment.On the contrary, the purpose of providing these embodiments is that making to understand more the disclosure
Add thorough and comprehensive.
It should be noted that it can directly on the other element when element is referred to as " being fixed on " another element
Or there may also be elements placed in the middle.When an element is considered as " connection " another element, it, which can be, is directly connected to
To another element or it may be simultaneously present centering elements.Term as used herein " vertical ", " horizontal ", " left side ",
" right side " and similar statement for illustrative purposes only, are not meant to be the only embodiment.
Unless otherwise defined, all technical and scientific terms used herein and belong to technical field of the invention
The normally understood meaning of technical staff is identical.Term as used herein in the specification of the present invention is intended merely to description tool
The purpose of the embodiment of body, it is not intended that in the limitation present invention.Term " and or " used herein includes one or more
Any and all combinations of relevant listed item.
A kind of high temperature resistant type waterproof roll, including be cascading polymer base material layer, hot melt adhesive layer, metal foil layer
And heat-resisting butyl glue-line；Wherein, the heat-resisting butyl glue-line includes each component of following mass parts: 15~30 parts of plasticizer, fourth
10~40 parts of base rubber, 20~50 parts of high temperature resistant filler, 30~60 parts of tackifying resin, 0.5~2 part of coupling agent and age resister
0.5~2 part.
In order to be preferably illustrated to above-mentioned high temperature resistant type waterproof roll, to more fully understand above-mentioned high temperature resistant type waterproof
The design of coiled material.One embodiment, referring to Fig. 1, a kind of high temperature resistant type waterproof roll 10, including the high score being cascading
Sub- substrate layer 110, hot melt adhesive layer 120, metal foil layer 130 and heat-resisting butyl glue-line 140；Wherein, the heat-resisting butyl glue-line 140
Each component including following mass parts: 15~30 parts of plasticizer, 20~50 parts of high temperature resistant filler, increases 10~40 parts of butyl rubber
30~60 parts of viscosity resin, 0.5~2 part of coupling agent and 0.5~2 part of age resister.It should be noted that the resistance to height of present embodiment
Warm type waterproof roll selects the butyl rubber of high molecular weight and the plasticizer of high molecular weight, is equipped with good with butyl rubber compatibility
Tackifying resin reduces intermolecular sliding rate so that butyl rubber becomes reticular structure from chain structure, to improve
Its heat resistance.After butyl rubber is reacted with plasticizer generates latticed butyl rubber, coupling agent makes in conjunction with high temperature resistant filler
It obtains high temperature resistant filler surface to be wrapped up by oiliness group, so that hydrophobization, improves the compatibility of high temperature resistant filler and butyl rubber, make
It obtains filler particles to be uniformly embedded into the molecular network of butyl rubber, reduce under high temperature action, the deformation and cunning of butyl rubber molecular network
It is dynamic, so that the high temperature resistance of butyl rubber improves, to improve the heat-resisting quantity of coiled material.
One embodiment, the plasticizer are polyisobutene, phthalic acid two (2- ethyl hexyl) ester, phthalic acid two
At least one of monooctyl ester and BBP(Butyl Benzyl Phthalate.For example, plasticizer is polyisobutene, (the 2- ethyl of phthalic acid two
Oneself) ester, dioctyl phthalate and BBP(Butyl Benzyl Phthalate common mixture.For example, plasticizer is polyisobutene, neighbour
Phthalic acid two (2- ethyl hexyl) ester, dioctyl phthalate or BBP(Butyl Benzyl Phthalate.It should be noted that plasticising
Bonding force, flexibility, resistance to ag(e)ing, air-tightness and the electrical insulating property of butyl rubber can be improved in agent.Especially polyisobutene, by
There is good light resistance, heat resistance and inoxidizability in itself, the heat resistance of butyl rubber can be enhanced.
One embodiment, the high temperature resistant filler be calcium carbonate, mica powder, titanium dioxide, diatomite and talcum powder in extremely
Few one kind.For example, high temperature resistant filler is the common mixture of calcium carbonate, mica powder, titanium dioxide, diatomite and talcum powder.For example,
High temperature resistant filler is calcium carbonate, mica powder, titanium dioxide, diatomite or talcum powder.It should be noted that high temperature resistant filler is
The molecule of 3000 mesh can be uniformly embedded into the molecular network of butyl rubber, be reduced under high temperature action, butyl rubber molecular network
Deformation and sliding, to improve the heat-resisting quantity of butyl rubber.
One embodiment, the tackifying resin be rosin resin, terpene resin, phenolic resin and Petropols at least
It is a kind of.For example, tackifying resin is the common mixture of rosin resin, terpene resin, phenolic resin and Petropols.For example, increasing
Viscosity resin is rosin resin, terpene resin, phenolic resin or Petropols.It should be noted that tackifying resin has well
Viscosity, internal cohesiveness and heat resistance, plasticizer can be made well to merge with butyl rubber, and can be improved the resistance to of butyl rubber
Hot bonding force and heat resistance.
One embodiment, the coupling agent are vinyl three ('beta '-methoxy ethyoxyl) silane, γ-aminopropyl trimethoxy
In silane, N- (β-aminoethyl)-gamma-aminopropyl-triethoxy-silane and γ-county methyl Bin Xi aminopropyl trimethoxysilane
It is at least one.For example, coupling agent is vinyl three ('beta '-methoxy ethyoxyl) silane, γ-aminopropyltrimethoxysilane, N-
(β-aminoethyl)-gamma-aminopropyl-triethoxy-silane and the common mixing of the γ-county methyl Bin Xi aminopropyl trimethoxysilane
Object.For example, coupling agent is vinyl three ('beta '-methoxy ethyoxyl) silane, γ-aminopropyltrimethoxysilane, N- (β-ammonia second
Base)-gamma-aminopropyl-triethoxy-silane or the γ-county methyl Bin Xi aminopropyl trimethoxysilane.It should be noted that even
Join agent tool there are two types of different two groups of chemical property, one be close inorganic matter group, easily play chemistry with mineral surfaces
Reaction；The other is organophilic group, can occur with butyl rubber chemical reaction be dissolved in wherein, to improve inorganic matter with
Interface interaction between organic matter improves the compatibility of high temperature resistant filler and butyl rubber, so that high temperature resistant filler particles are equal
In the molecular network of even insertion butyl rubber, reduce under high temperature action, the deformation and sliding of butyl rubber molecular network, to mention significantly
The heat resistance of high butyl rubber.It can also prevent other media such as water, air from permeating into butyl rubber simultaneously, be conducive to butyl rubber
Waterproofness, ageing-resistant, proof stress and electrical insulation capability.
One embodiment, the age resister be β (- 4 hydroxy phenyl of 3,5- di-t-butyl) propionic acid pentaerythrite, three (2,
4- DI-tert-butylphenol compounds) phosphite ester, double 2,2,6, the 6- tetramethyl piperidine alcohol esters of decanedioic acid and 2- (2,-hydroxyl -5, methyl)-benzene
And at least one of triazole.For example, age resister be β (- 4 hydroxy phenyl of 3,5- di-t-butyl) propionic acid pentaerythrite, three (2,
4- DI-tert-butylphenol compounds) phosphite ester, double 2,2,6, the 6- tetramethyl piperidine alcohol esters of decanedioic acid and 2- (2,-hydroxyl -5, methyl)-benzene
And the common mixture of triazole.For example, age resister be β (- 4 hydroxy phenyl of 3,5- di-t-butyl) propionic acid pentaerythrite, three (2,
4- DI-tert-butylphenol compounds) phosphite ester, double 2,2,6, the 6- tetramethyl piperidine alcohol esters of decanedioic acid or 2- (2,-hydroxyl -5, methyl) -
Benzotriazole.It should be noted that β (- 4 hydroxy phenyl of 3,5- di-t-butyl) propionic acid pentaerythrite, three (2,4- di-tert-butyls
Phenol) phosphite ester, double 2,2,6, the 6- tetramethyl piperidine alcohol esters of decanedioic acid and 2- (2,-hydroxyl -5, methyl) uniform side of-benzotriazole
Free radical can be absorbed in face, prevents the latticed long-chain of butyl rubber from being broken under the high temperature conditions, light, heat on the other hand can be absorbed
Energy discharges in the form of heat, alleviates the destruction of light, heat to heat-resisting butyl glue-line, and then improve coiled material
Weatherability and ageing resistance.
One embodiment, the polymer base material layer are polyethylene terephthalate substrate, poly terephthalic acid fourth
Terephthalate substrate, high-density polyethylene resin substrate, butyl nitrile EP rubbers substrate, organic siliconresin substrate or amino resins
Substrate.It should be noted that polyethylene terephthalate, polybutylene terephthalate (PBT), high-density polyethylene resin,
Butyl nitrile EP rubbers, organic siliconresin and amino resins all have excellent mechanical strength and thermal stability, suitable for system
Make the polymer base material layer of waterproof roll.Wherein, polyethylene terephthalate has good mechanical property, impact strength
It is 3~5 times of other films, folding resistance is good, and flexibility is good, can preferably be bonded with building roof, and have excellent high temperature resistant
Performance can be used for a long time in 120 DEG C of temperature ranges, in addition, also having the absorption to ultraviolet light, it is right to alleviate light, heat
The destruction of heat-resisting butyl glue-line, and then improve the weatherability and ageing resistance of coiled material.
One embodiment, the metal foil layer are aluminium foil, nickel foil or cobalt foil.For example, metal foil layer is aluminium foil layer；Example
Such as, metal foil layer is nickel foil layer；For example, metal foil layer is cobalt layers of foil.It should be noted that aluminium foil layer, nickel foil layer and cobalt layers of foil
All have excellent antioxidation, not with air reaction, and it is smooth can be reflective, do not fear heat, alleviate light, heat to heat-resisting butyl
The destruction of glue-line, and then improve the weatherability and ageing resistance of coiled material.
One embodiment, referring to Fig. 1, a kind of high temperature resistant type waterproof roll 10, comprising: polymer base material layer 110；Hot melt
Glue-line 120, the hot melt adhesive layer 120 are coated on the one side of the polymer base material layer 110；Metal foil layer 130, the gold
Belong to layers of foil 130 to be attached on one side of the hot melt adhesive layer 120 far from the polymer base material layer 110；And heat-resisting butyl rubber
Layer 140, the heat-resisting butyl glue-line 140 are coated on one side of the metal foil layer 130 far from the hot melt adhesive layer 120.
It should be noted that polymer base material itself has excellent mechanical strength, heat resistance and anti-aging property.Metal foil layer light
Cunning can be reflective, does not fear heat, alleviates light, destruction of the heat to heat-resisting butyl glue-line, so improve coiled material weatherability and
Ageing resistance.Heat-resisting butyl glue-line is that the high temperature resistants such as calcium carbonate, mica powder, titanium dioxide, diatomite, talcum powder are added in butyl rubber
Filler is embedded in the molecular network of butyl rubber, to reduce the butyl rubber under high temperature action using the molecule of high temperature resistant filler
The deformation and sliding of molecular network, so that the high temperature resistance of butyl rubber improves, to improve the heat-resisting quantity of coiled material.
One embodiment, the sum of the polymer base material layer, the hot melt adhesive layer and thickness of the metal foil layer are
0.05mm~0.2mm.For example, the sum of thickness of polymer base material layer, hot melt adhesive layer and metal foil layer is 0.05mm；For example, high
The sum of thickness of molecule substrate layer, hot melt adhesive layer and metal foil layer is 0.1mm；For example, polymer base material layer, hot melt adhesive layer and gold
Belonging to the sum of thickness of layers of foil is 0.2mm.It should be noted that traditional composite high-molecular waterproof roll is blocked up, stress when molding
Aggregation, so that coiled material when with the yin-yang angle of building roof, male and fomale(M&F) stickup, is easy to warp and degumming.It is asked to solve this
Topic, by multinomial experiment find, when the sum of thickness of polymer base material layer, hot melt adhesive layer and metal foil layer be 0.05mm~
When 0.2mm, stress when coiled material forms is moderate, when with the yin-yang angle of building roof, male and fomale(M&F) stickup, soft docile property compared with
It is good, it is not easy to warp and degumming.
One embodiment, the polymer base material layer offer the first connection on the one side of the hot melt adhesive layer
Hole, the metal foil layer offer the second connecting hole on the one side of the hot melt adhesive layer, and the hot melt adhesive layer seeps respectively
Enter in first connecting hole and second connecting hole.Hot melt adhesive layer and polymer base material layer and metal foil layer can so be reinforced
Between connectivity so that polymer base material layer, hot melt adhesive layer and metal foil layer are closely joined together, to avoid polymer-based
Material layer warps and degumming.
One embodiment, the metal foil layer offer third connection on the one side of the heat-resisting butyl glue-line
Hole, the heat-resisting butyl glue-line penetrate into the third connecting hole.Can so it reinforce between heat-resisting butyl glue-line and metal foil layer
Connectivity so that polymer base material layer, hot melt adhesive layer, metal foil layer and heat-resisting butyl glue-line are closely connected as one, with
Polymer base material layer, hot melt adhesive layer and metal foil layer is avoided to warp and degumming.
One embodiment, referring to Fig. 1, the high temperature resistant type waterproof roll further includes release film layer 150, the hot melt adhesive
Layer 120 is coated on the one side of the polymer base material layer 110, and the metal foil layer 130 is attached to the hot melt adhesive layer 120
On one side far from the polymer base material layer 110, it is remote that the heat-resisting butyl glue-line 140 is coated on the metal foil layer 130
On one side from the hot melt adhesive layer 120, the release film layer 150 is attached to the heat-resisting butyl glue-line 140 far from described
On the one side of metal foil layer 130.It should be noted that release film layer is to heat-resisting butyl glue-line with anti-sticking, anti-pollution and anti-
The effect of scuffing.Release film layer can be polyethylene terephthalate substrate, polybutylene terephthalate (PBT) substrate, height
Density Polyethylene Resin substrate, butyl nitrile EP rubbers substrate, organic siliconresin substrate or amino resins substrate.
One embodiment, the edge of the polymer base material layer, the edge of the hot melt adhesive layer, the metal foil layer side
The alignment of the edge of edge and the heat-resisting butyl glue-line, the edge of the release film layer extends outwardly so that the release film layer
Width is greater than the width of the heat-resisting butyl glue-line.It, can be with so by the release film layer edge more bigger than heat-resisting butyl glue-line
The edge of release film layer two sides is pinched to remove release film layer, achievees the purpose that convenient to remove release film layer.
One embodiment, the release film layer include fluorine coating and polyester resin layer, and the fluorine coating is coated on described wash
On the one side of synthetic fibre resin layer, it is separate that the fluorine coating far from the one side of the polyester resin layer is attached to the butyl glue-line
On the one side of the aluminium metal coating.It should be noted that polyester resin layer is made of polyethylene terephthalate,
Itself there is excellent chemical stability, it is corrosion-resistant at room temperature.Fluorine coating is the off-type force in order to increase polyester resin layer.
One embodiment, the release film layer include silicon coating and polyester resin layer, and the silicon coating is coated on described wash
On the one side of synthetic fibre resin layer, it is separate that the silicon coating far from the one side of the polyester resin layer is attached to the butyl glue-line
On the one side of the aluminium metal coating.It should be noted that polyester resin layer is made of polyethylene terephthalate,
Itself there is excellent chemical stability, it is corrosion-resistant at room temperature.Silicon coating is the off-type force in order to increase polyester resin layer.
The manufacturing process of high temperature resistant type waterproof roll: polymer base material layer, hot melt adhesive layer and metal foil layer are used into hot pressing
After being combined into composite of water-proof coiled material, then use extrusion way that butyl rubber is coated on composite of water-proof coiled material, to form heat-resisting fourth
Base rubber layer is finally covered with release film layer on the surface of heat-resisting butyl glue-line, high temperature resistant type waterproof roll can be obtained.
Compared with prior art, the present invention has at least the following advantages:
1, this high temperature resistant type waterproof roll selects the butyl rubber of high molecular weight and the plasticizer of high molecular weight, is equipped with and fourth
The good tackifying resin of base rubber compatibility, reaction, which generates, has latticed butyl rubber, reduces intermolecular sliding rate, from
And it is higher than general pressure sensitive adhesive heat-resisting quantity.After butyl rubber, which is reacted with plasticizer, generates latticed butyl rubber, coupling agent with
High temperature resistant filler combines so that high temperature resistant filler surface is wrapped up by oiliness group, thus hydrophobization, improve high temperature resistant filler with
The compatibility of butyl rubber reduces under high temperature action, butyl rubber so that filler particles are uniformly embedded into the molecular network of butyl rubber
The deformation and sliding of molecular network, that is, improve the heat-resisting quantity of butyl rubber, to improve the heat-resisting quantity of coiled material.
2, the plasticizer of this high temperature resistant type waterproof roll can be improved the bonding force of butyl rubber, flexibility, resistance to ag(e)ing,
Air-tightness and electrical insulating property.Especially polyisobutene, since itself has good light resistance, heat resistance and inoxidizability,
The heat resistance of butyl rubber can be enhanced.
3, the tackifying resin of this high temperature resistant type waterproof roll has good viscosity, internal cohesiveness and heat resistance, can make
Plasticizer is well merged with butyl rubber, and can be improved the heat resistant adhesive power and heat resistance of butyl rubber.
4, the coupling agent tool of this high temperature resistant type waterproof roll two groups different there are two types of chemical property, one is close nothing
The group of machine object, easily with mineral surfaces chemically reactive；The other is organophilic group, it can be with butyl rubber
It learns reaction to be dissolved in wherein, to improve the interface interaction between inorganic matter and organic matter, that is, improves high temperature resistant filler and butyl
The compatibility of glue reduces under high temperature action, butyl so that high temperature resistant filler particles are uniformly embedded into the molecular network of butyl rubber
The deformation and sliding of xanthan molecule net, to greatly improve the heat resistance of butyl rubber.Other Jie such as water, air can also be prevented simultaneously
Matter is permeated into butyl rubber, is conducive to waterproofness, ageing-resistant, proof stress and the electrical insulation capability of butyl rubber.
5, on the one hand free radical can be absorbed in the age resister of this high temperature resistant type waterproof roll, prevents the latticed of butyl rubber
Long-chain is broken under the high temperature conditions, and light, thermal energy on the other hand can be absorbed, discharge in the form of heat, alleviates light, heat
Destruction to heat-resisting butyl glue-line, and then improve the weatherability and ageing resistance of coiled material.
The following are specific examples part
Embodiment 1
A kind of high temperature resistant type waterproof roll, including be cascading polymer base material layer, hot melt adhesive layer, metal foil layer
And heat-resisting butyl glue-line；Polymer base material layer is polyethylene terephthalate, and metal foil layer is aluminium foil；Wherein, described resistance to
Hot butyl glue-line includes each component of following mass parts: polyisobutene 15kg, butyl rubber 10kg, calcium carbonate 5kg, mica powder
5kg, titanium dioxide 5kg, diatomite 5kg, rosin resin 15kg, terpene resin 15kg, vinyl three ('beta '-methoxy ethyoxyl) silicon
Alkane 0.5kg and β (- 4 hydroxy phenyl of 3,5- di-t-butyl) propionic acid pentaerythrite 0.5kg.
Embodiment 2
A kind of high temperature resistant type waterproof roll, including be cascading polymer base material layer, hot melt adhesive layer, metal foil layer
And heat-resisting butyl glue-line；Polymer base material layer is polyethylene terephthalate, and metal foil layer is aluminium foil；Wherein, described resistance to
Hot butyl glue-line includes each component of following mass parts: polyisobutene 30kg, butyl rubber 40kg, calcium carbonate 15kg, mica powder
15kg, titanium dioxide 10kg, diatomite 10kg, rosin resin 30kg, terpene resin 30kg, vinyl three ('beta '-methoxy ethyoxyl)
Silane 2kg and β (- 4 hydroxy phenyl of 3,5- di-t-butyl) propionic acid pentaerythrite 2kg.
Embodiment 3
A kind of high temperature resistant type waterproof roll, including be cascading polymer base material layer, hot melt adhesive layer, metal foil layer
And heat-resisting butyl glue-line；Polymer base material layer is polyethylene terephthalate, and metal foil layer is aluminium foil；Wherein, described resistance to
Hot butyl glue-line includes each component of following mass parts: polyisobutene 25kg, butyl rubber 25kg, calcium carbonate 10kg, mica powder
8kg, titanium dioxide 7kg, diatomite 7kg, rosin resin 25kg, terpene resin 20kg, vinyl three ('beta '-methoxy ethyoxyl) silicon
Alkane 1kg and β (- 4 hydroxy phenyl of 3,5- di-t-butyl) propionic acid pentaerythrite 1kg.
Embodiment 4
A kind of high temperature resistant type waterproof roll, including be cascading polymer base material layer, hot melt adhesive layer, metal foil layer
And heat-resisting butyl glue-line；Polymer base material layer is polybutylene terephthalate (PBT), and metal foil layer is nickel foil；Wherein, described resistance to
Hot butyl glue-line includes each component of following mass parts: polyisobutene 25kg, butyl rubber 25kg, calcium carbonate 10kg, talcum powder
8kg, titanium dioxide 7kg, diatomite 7kg, Petropols 25kg, phenolic resin 20kg, γ-aminopropyltrimethoxysilane 1kg and
Three (2,4- DI-tert-butylphenol compounds) phosphite ester 1kg.
Comparative example 1
A kind of high temperature resistant type waterproof roll, including be cascading polymer base material layer, hot melt adhesive layer, metal foil layer
And heat-resisting butyl glue-line；Polymer base material layer is polyethylene terephthalate, and metal foil layer is aluminium foil；Wherein, described resistance to
Hot butyl glue-line includes each component of following mass parts: polyisobutene 25kg, butyl rubber 25kg, dicalcium powder 32kg, rosin tree
Rouge 25kg, terpene resin 20kg, ('beta '-methoxy ethyoxyl) silane 1kg and β (- 4 hydroxy benzenes of 3,5- di-t-butyl of vinyl three
Base) propionic acid pentaerythrite 1kg.
Comparative example 2
A kind of high temperature resistant type waterproof roll, including be cascading polymer base material layer, hot melt adhesive layer, metal foil layer
And heat-resisting butyl glue-line；Polymer base material layer is polyethylene terephthalate, and metal foil layer is aluminium foil；Wherein, described resistance to
Hot butyl glue-line includes each component of following mass parts: polyisobutene 10kg, butyl rubber 78.6kg, calcium carbonate 5kg, mica powder
4kg, titanium dioxide 3kg, diatomite 3kg, rosin resin 15kg, terpene resin 10kg, vinyl three ('beta '-methoxy ethyoxyl) silicon
Alkane 0.2kg and β (- 4 hydroxy phenyl of 3,5- di-t-butyl) propionic acid pentaerythrite 0.2kg.
Under the same conditions, using the high temperature resistant type waterproof roll of embodiment 3, comparative example 1 and comparative example 2 as sample
1, sample 2 and sample 3 carry out properties test, obtained test result such as 1 institute of table to sample 1, sample 2 and sample 3 respectively
Show.
Table 1 is the test data table that the properties of sample 1, sample 2 and sample 3 are tested
Sample 2 and the difference of sample 1 are: replacing high temperature resistant filler using dicalcium powder in the heat-resisting butyl glue-line of sample 2；
From the point of view of upper table test result, the heat resistance of the high temperature resistant type waterproof roll of embodiment 3 is much higher than the high temperature resistant type of comparative example 1
The heat resistance of waterproof roll, it can be seen that, high temperature resistant filler can largely improve heat-resisting butyl glue-line really
Heat resistance so that heat-resisting butyl glue-line can be applied under 120 DEG C of hot environment, and will not make the viscous of heat-resisting butyl glue-line
National standard is greatly reduced to hereinafter, making coiled material still can be persistently Nian Jie with building roof strength in relay.
Sample 3 is identical as the raw material of sample 1, but the proportion of each raw material of the proportion of each raw material of sample 3 and sample 1 is not
Together；From the point of view of upper table test result, the adhesive property of the high temperature resistant type waterproof roll of embodiment 3, anti-aging property, heat resistance
And it holds viscosity and much higher than the adhesive property of high temperature resistant type waterproof roll of comparative example 2, anti-aging property, heat resistance and holds viscous
Performance, it can be seen that, suitable each raw material can make coiled material have more excellent adhesive property, ageing resistance with Bizet
Energy, heat resistance and hold viscosity energy.
The embodiments described above only express several embodiments of the present invention, and the description thereof is more specific and detailed, but simultaneously
It cannot therefore be construed as limiting the scope of the patent.It should be pointed out that coming for those of ordinary skill in the art
It says, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to protection of the invention
Range.Therefore, the scope of protection of the patent of the invention shall be subject to the appended claims.
Claims (10)
1. a kind of high temperature resistant type waterproof roll, which is characterized in that including polymer base material layer, the hot melt adhesive being cascading
Layer, metal foil layer and heat-resisting butyl glue-line；
Wherein, the heat-resisting butyl glue-line includes each component of following mass parts: 15~30 parts of plasticizer, butyl rubber 10~40
Part, 20~50 parts of high temperature resistant filler, 30~60 parts of tackifying resin, 0.5~2 part of coupling agent and 0.5~2 part of age resister.
2. high temperature resistant type waterproof roll according to claim 1, which is characterized in that the plasticizer is polyisobutene, neighbour
At least one of phthalic acid two (2- ethyl hexyl) ester, dioctyl phthalate and BBP(Butyl Benzyl Phthalate.
3. high temperature resistant type waterproof roll according to claim 1, which is characterized in that the high temperature resistant filler be calcium carbonate,
At least one of mica powder, titanium dioxide, diatomite and talcum powder.
4. high temperature resistant type waterproof roll according to claim 1, which is characterized in that the tackifying resin be rosin resin,
At least one of terpene resin, phenolic resin and Petropols.
5. high temperature resistant type waterproof roll according to claim 1, which is characterized in that the coupling agent is three (β-of vinyl
Methoxy ethoxy) silane, γ-aminopropyltrimethoxysilane, N- (β-aminoethyl)-gamma-aminopropyl-triethoxy-silane and
At least one of the γ-county methyl Bin Xi aminopropyl trimethoxysilane.
6. high temperature resistant type waterproof roll according to claim 1, which is characterized in that the age resister is β (3,5- bis- uncles
- 4 hydroxy phenyl of butyl) propionic acid pentaerythrite, three (2,4- DI-tert-butylphenol compounds) phosphite esters, the double 2,2,6,6- tetramethyls of decanedioic acid
At least one of phenylpiperidines alcohol ester and 2- (2,-hydroxyl -5, methyl)-benzotriazole.
7. any high temperature resistant type waterproof roll according to claim 1~6, which is characterized in that the polymer base material layer
For polyethylene terephthalate substrate, polybutylene terephthalate (PBT) substrate, high-density polyethylene resin substrate, butyl
Nitrile EP rubbers substrate, organic siliconresin substrate or amino resins substrate.
8. any high temperature resistant type waterproof roll according to claim 1~6, which is characterized in that the metal foil layer is aluminium
Foil, nickel foil or cobalt foil.
9. any high temperature resistant type waterproof roll according to claim 1~6, which is characterized in that it further include release film layer, institute
Hot melt adhesive layer is stated coated on the one side of the polymer base material layer, it is separate that the metal foil layer is attached to the hot melt adhesive layer
On the one side of the polymer base material layer, the heat-resisting butyl glue-line is coated on the metal foil layer far from the hot melt adhesive layer
One side on, the release film layer is attached on the heat-resisting one side of the butyl glue-line far from the metal foil layer.
10. any high temperature resistant type waterproof roll according to claim 1~6, which is characterized in that the polymer base material
The sum of thickness of layer, the hot melt adhesive layer and the metal foil layer is 0.05mm~0.2mm.
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| CN201910579440.XA CN110229633A (en) | 2019-06-28 | 2019-06-28 | High temperature resistant type waterproof roll |
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| CN111138769A (en) * | 2019-12-05 | 2020-05-12 | 常州聚焦橡塑新材料有限公司 | Preparation process of non-vulcanized butyl rubber |
| CN111718669A (en) * | 2020-07-04 | 2020-09-29 | 富华防水科技股份有限公司 | Environment-friendly roof heat-insulating waterproof coiled material and preparation method thereof |
| CN112375512A (en) * | 2020-11-03 | 2021-02-19 | 广东能辉新材料科技有限公司 | Non-vulcanized butyl pressure-sensitive adhesive, preparation method and application thereof, and waterproof roll |
| WO2021189584A1 (en) * | 2020-03-27 | 2021-09-30 | 山东双圆密封科技有限公司 | Exposed weather-resistant aluminium foil heat-insulated self-adhesive waterproofing coiled material and preparation method therefor |
| CN113652182A (en) * | 2021-08-19 | 2021-11-16 | 重庆新天地华宇新材料集团有限公司 | Macromolecule butyl self-adhesive waterproof coiled material and preparation method thereof |
| CN114437650A (en) * | 2021-12-28 | 2022-05-06 | 佛山南宝高盛高新材料有限公司 | High-heat-resistant creep waterproof butyl pressure-sensitive adhesive and preparation method thereof |
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| CN111138769A (en) * | 2019-12-05 | 2020-05-12 | 常州聚焦橡塑新材料有限公司 | Preparation process of non-vulcanized butyl rubber |
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| CN111718669A (en) * | 2020-07-04 | 2020-09-29 | 富华防水科技股份有限公司 | Environment-friendly roof heat-insulating waterproof coiled material and preparation method thereof |
| CN112375512A (en) * | 2020-11-03 | 2021-02-19 | 广东能辉新材料科技有限公司 | Non-vulcanized butyl pressure-sensitive adhesive, preparation method and application thereof, and waterproof roll |
| CN113652182A (en) * | 2021-08-19 | 2021-11-16 | 重庆新天地华宇新材料集团有限公司 | Macromolecule butyl self-adhesive waterproof coiled material and preparation method thereof |
| CN114437650A (en) * | 2021-12-28 | 2022-05-06 | 佛山南宝高盛高新材料有限公司 | High-heat-resistant creep waterproof butyl pressure-sensitive adhesive and preparation method thereof |
| CN114437650B (en) * | 2021-12-28 | 2023-03-10 | 佛山南宝高盛高新材料有限公司 | High-heat-resistant creep waterproof butyl pressure-sensitive adhesive and preparation method thereof |
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