CN110218108B - Ice fertilizer prepared from cow urine, preparation method thereof and method for improving grassland - Google Patents

Ice fertilizer prepared from cow urine, preparation method thereof and method for improving grassland Download PDF

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CN110218108B
CN110218108B CN201910636727.1A CN201910636727A CN110218108B CN 110218108 B CN110218108 B CN 110218108B CN 201910636727 A CN201910636727 A CN 201910636727A CN 110218108 B CN110218108 B CN 110218108B
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ice
fertilizer
grassland
urine
cow urine
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CN110218108A (en
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张文浩
侯龙鱼
白文明
潘庆民
宋世环
张强强
任立飞
陶金
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Institute of Botany of CAS
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B1/00Superphosphates, i.e. fertilisers produced by reacting rock or bone phosphates with sulfuric or phosphoric acid in such amounts and concentrations as to yield solid products directly
    • C05B1/02Superphosphates
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/10Solid or semi-solid fertilisers, e.g. powders
    • C05G5/12Granules or flakes

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  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
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Abstract

The invention relates to the technical field of natural grassland improvement, in particular to an ice fertilizer prepared from cow urine, a preparation method thereof and a method for improving grassland. The ice fertilizer comprises cow urine, calcium superphosphate, ammonium molybdate and boric acid. The invention combines the nutrient characteristics and chemical properties of cow urine, the climatic characteristics of high latitude cold regions and the requirement rule of plants for nutrients, and the technical method for preparing the ice fertilizer formula and improving the natural grassland by utilizing the cow urine reduces the pollution of the cow urine, reasonably utilizes the nutrient characteristics, improves the cyclic utilization of the nutrients, improves the grassland, improves the productivity of the grassland and improves the yield of hay by 50-100 percent compared with the contrast.

Description

Ice fertilizer prepared from cow urine, preparation method thereof and method for improving grassland
Technical Field
The invention relates to the technical field of natural grassland improvement, in particular to an ice fertilizer prepared from cow urine, a preparation method thereof and a method for improving grassland.
Background
About 40-50 kg of fresh manure and about 20 kg of cow urine are excreted every day by each adult cow, and sewage is added, so that the manure liquid mainly containing cow urine can reach nearly 30 kg and nearly 10000 kg every year. By the increasingly serious environmental protection problem and the requirement of agricultural sustainable development, how to utilize the resources of cow urine becomes the problem which needs to be solved urgently in the current pastoral area. The cow urine not only contains rich nitrogen fertilizer and potassium fertilizer, but also contains medium element fertilizers such as copper and zinc, which are all fertilizers necessary for plant growth, but at present, no feasible method for utilizing the cow urine is available.
The excrement is recycled, so that the cost of the fertilizer is reduced, the soil quality is improved, and microorganisms in the soil can be maintained to a greater extent. Due to the consideration of the environment, the recycling of the excrement can reduce the influence of the livestock and poultry farm on the environment. In recent years, for better management of cow dung, dry-wet separation technology is often adopted, wherein dry samples are mainly grass meal, wet samples are mainly cow urine, cleaning sewage and soluble substances in excretion.
The grassland resource in China accounts for 40 percent of the land area in China. Over utilization for many years causes nutrient deficiency of grasslands, soil capability reduction, grassland vegetation degradation, productivity reduction, high-quality grass proportion reduction and the like, and more than 90 percent of the natural grassland can be utilized to be degraded in different degrees. Therefore, the method combines the characteristics of the cow urine fertilizer, reasonably prepares the ice fertilizer according to the utilization principle of plants on the fertilizer, and has important significance for recycling cow urine and other excrement liquid, improving the productivity of the grassland and reducing the environmental pollution by matching with a targeted natural grassland application technical method.
Disclosure of Invention
In view of the above, the invention provides an ice fertilizer prepared from cow urine, a preparation method thereof and a method for improving grassland. The method can effectively utilize feces such as cow urine, improve natural grassland productivity, and increase forage grass yield.
In order to achieve the above object, the present invention provides the following technical solutions:
the invention provides an ice fertilizer which comprises bovine urine, calcium superphosphate, ammonium molybdate and boric acid.
Preferably, the weight ratio of the bovine urine, the calcium superphosphate, the ammonium molybdate and the boric acid is (900-1100): (0.9-1.1): (0.9-1.1): (0.9-1.1).
Preferably, the mass ratio of the bovine urine, the calcium superphosphate, the ammonium molybdate and the boric acid is 1000: 1: 1: 1.
preferably, the cow urine is a wet cow dung sample after dry-wet separation, and comprises cow urine, cleaning sewage and cow dung soluble substances.
The invention also provides a preparation method of the ice fertilizer, which comprises the step of mixing the bovine urine, the calcium superphosphate, the ammonium molybdate and the boric acid to prepare ice particles.
Preferably, the ice particles have a particle size of less than 3 cm.
The invention also provides a method of modifying grass comprising: after being frozen in winter and before snowing, the ice fertilizer provided by the invention is applied to the surface of the grassland.
Preferably, the application amount of the ice fertilizer is 5-10 tons/mu.
In the present invention, the grassland is northern grassland frozen in winter.
In a particular embodiment of the invention, the grass is high latitude cold zone grass.
The invention provides an ice fertilizer prepared from cow urine, a preparation method thereof and a method for improving grasslands. The ice fertilizer comprises cow urine, calcium superphosphate, ammonium molybdate and boric acid. The invention has the technical effects that:
according to the ice fertilizer formula and the technical method for improving the grassland, provided by the invention, the pH value of the ice fertilizer is adjusted by increasing the content of the phosphate fertilizer, adjusting the proportion of nitrogen, phosphorus and potassium required by plant growth and increasing acidic nutrients and elements. Meanwhile, other fertilizers such as copper and zinc which are beneficial to the plant contained in the cow urine are also beneficial to the growth of the plant, and the growth of the root system and the growth of tillering buds of the natural grassland plant are promoted by increasing trace elements, the absorption and utilization of nitrogen by the plant are regulated and controlled, the improvement of the natural grassland is promoted, the productivity of the grassland is improved, and the yield of forage grass is improved. By applying the technology, the forage grass yield can be improved by 50-100%. Meanwhile, the technology combines the climatic conditions of high latitude cold regions, combines the application before freezing sealing in winter, promotes the absorption and utilization of nutrients through the alternation of winter snow coverage and spring freezing and thawing, reduces the volatilization and loss of nutrients, and particularly reduces the volatilization of ammonia nitrogen. In addition, the ice fertilizer formula and the application technology thereof fully utilize the nutrient advantages of cow urine and the like, promote the cyclic utilization of the fertilizer, solve the pollution problem of cow urine, repair the degradation of natural grasslands, ensure the sustainable utilization of grassland resources and realize the win-win of ecological value and economic value.
Detailed Description
The invention discloses an ice fertilizer prepared from cow urine, a preparation method thereof and a method for improving grasslands, and can be realized by appropriately improving process parameters by referring to the contents in the text. It is expressly intended that all such similar substitutes and modifications which would be obvious to one skilled in the art are deemed to be included in the invention. While the methods and applications of this invention have been described in terms of preferred embodiments, it will be apparent to those of ordinary skill in the art that variations and modifications in the methods and applications described herein, as well as other suitable variations and combinations, may be made to implement and use the techniques of this invention without departing from the spirit and scope of the invention.
The invention provides a technical method for preparing an ice fertilizer formula and improving natural grasslands by using cow urine, which comprises the following steps:
storage of cow urine
The prior pastures are all provided with matched dung storage tanks, and the dung is mainly wet liquid after dry-wet separation and mainly comprises cow urine, cleaning sewage and soluble substances in the dung.
Formula of ice fertilizer
Preparing cow urine liquid manure according to the mass ratio: calcium superphosphate: ammonium molybdate: boric acid 1000 kg: 1 kg: 1 g: 1g of the total weight of the composition.
Preparation of ice fertilizer
Before urine is transferred to a septic tank, certain mass of calcium superphosphate, ammonium molybdate and boric acid are added according to the proportion.
After being frozen in winter, the prepared urine is made into ice particles with the particle size less than 3cm by using corresponding machinery.
Four, application of ice fertilizer in field
Application time: after freezing in winter, the high latitude cold region is selected from the first ten days of November to the last ten days of November.
The application mode is as follows: and directly spraying the fertilizer on the surface layer of the grassland by using a fertilizer throwing machine.
Fertilizing amount: about 5-10 tons is applied per mu.
Management after administration
After the ice fertilizer is applied, the ice fertilizer is covered by snowfall, in the spring of the next year, along with freeze thawing alternation, the ice fertilizer is melted and diluted to enter a soil layer, and nutrient components are absorbed and utilized by the green turning growth of plants.
After one-time treatment, the water can be continuously utilized for 3 to 5 years.
The invention has the technical effects that:
according to the ice fertilizer formula and the technical method for improving the grassland, provided by the invention, the pH value of the ice fertilizer is adjusted by increasing the content of the phosphate fertilizer, adjusting the proportion of nitrogen, phosphorus and potassium required by plant growth and increasing acidic nutrients and elements. Meanwhile, other fertilizers such as copper and zinc which are beneficial to the plant contained in the cow urine are also beneficial to the growth of the plant, and the growth of the root system and the growth of tillering buds of the natural grassland plant are promoted by increasing trace elements, the absorption and utilization of nitrogen by the plant are regulated and controlled, the improvement of the natural grassland is promoted, the productivity of the grassland is improved, and the yield of forage grass is improved. By applying the technology, the forage grass yield can be improved by 50-100%. Meanwhile, the technology combines the climatic conditions of high latitude cold regions, combines the application before freezing sealing in winter, promotes the absorption and utilization of nutrients through the alternation of winter snow coverage and spring freezing and thawing, reduces the volatilization and loss of nutrients, and particularly reduces the volatilization of ammonia nitrogen. In addition, the ice fertilizer formula and the application technology thereof fully utilize the nutrient advantages of cow urine and the like, promote the cyclic utilization of the fertilizer, solve the pollution problem of cow urine, repair the degradation of natural grasslands, ensure the sustainable utilization of grassland resources and realize the win-win of ecological value and economic value.
The ice fertilizer prepared by using cow urine, the preparation method thereof and the method for improving the grassland provided by the invention can be purchased from the market.
The invention is further illustrated by the following examples:
example 1 Effect of icy manure application on Natural grassland forage yield
Test site: the natural grassland degenerated in the Shertalan second pasture;
the test method is as follows:
storage of cow urine
And the dung liquid is mainly wet liquid after dry-wet separation and mainly comprises cow urine, cleaning sewage and soluble substances in the dung.
Formula of ice fertilizer
Preparing cow urine liquid manure according to the mass ratio: calcium superphosphate: ammonium molybdate: boric acid 1000 kg: 1 kg: 1 g: 1g of the total weight of the composition.
Preparation of ice fertilizer
The ice fertilizer is prepared according to the formula, and is mechanically crushed and granulated, wherein the grain size is less than 3 cm.
Four, application of ice fertilizer in field
Application time: 2016 (11 months) and 20 days
The application mode is as follows: directly throwing the fertilizer on the surface of the grassland by using a fertilizer throwing machine.
Fertilizing amount: about 8 tons of fertilizer is applied per mu.
Management after administration
After application, forage grass production was measured in 2017 and 2018.
Comparative example 1: influence of cow urine directly applied in summer on natural grassland
Test site: degraded natural grassland of second pasture of Sherta
Storage of cow urine
And the dung liquid is mainly wet liquid after dry-wet separation and mainly comprises cow urine, cleaning sewage and soluble substances in the dung.
Second, the field application with urine
Application time: 6 months and 10 days in 2017;
the application mode is as follows: spraying by small-sized sprinkling irrigation equipment.
Fertilizing amount: about 8 tons of fertilizer is applied per mu.
Management after administration
After application, forage grass production was measured in 2017 and 2018.
Comparative example 2 unfertilized adjacent natural grass as a control
Comparative example 3 Effect of ice fertilizers made directly from cow urine on Natural grassland
The other treatments and application methods were the same as in example 1, except that calcium superphosphate, ammonium molybdate and boric acid were not added.
Test results
The natural grass field forage yield was compared to the ice manure and the control plot after treatment with the application technique. The ice fertilizer and the application technology remarkably improve the forage grass yield, the forage grass yield in 2017 is improved by 49.3%, the forage grass yield in 2018 is improved by 99.1%, the influence of cow urine on the biomass in 2017 by direct ice fertilizer is small, and the biomass in 2018 is increased by 39.5%; direct urine administration in summer reduced forage production, and the specific results are shown in table 1.
TABLE 1 Effect of ice foiling machine application technique on Natural grassland Biomass
Figure BDA0002130477360000051
Figure BDA0002130477360000061
The reason why the ice manure and the application technology improve the forage grass yield is analyzed. The fertilizer effect of the ice fertilizer mainly comprises the following points:
(1) the cow urine contains rich ammonia nitrogen and potassium fertilizers, and the proportion of nitrogen, phosphorus and potassium fertilizers is supplemented by increasing the content of phosphate fertilizers.
(2) The cow urine contains rich copper-zinc fertilizer, and the zinc fertilizer can improve the drought resistance and low-temperature resistance of crops and promote healthy growth of branches and leaves; and is involved in the synthesis of chlorophyll and auxin. Copper is a component of a plurality of oxidases in plants, particularly a main component of superoxide dismutase, participates in the oxidation-reduction reaction in plants, promotes the stabilization of phytoalexin and other pigments, and promotes the stress tolerance of plants.
(3) Molybdenum is a component of nitrate reductase, participates in the reduction of nitrate and nitrogen metabolism in plants, and is also a main component of nitrogen fixation enzyme, and the molybdenum fertilizer increases and promotes the nitrogen fixation capability of leguminous plants.
(4) The boric fertilizer can promote the growth of plant roots and the absorption of phosphate fertilizer, and simultaneously can improve the stress resistance and disease resistance of plants.
(5) The ice fertilizer contains more sodium, and the increased calcium in the calcium superphosphate can antagonize the ionic effect of the sodium.
(6) The added calcium superphosphate and boric acid are both acidic substances, the pH value of the urine can be adjusted, the pH value of the original urine is acidic at 8.0-8.5, and the pH value of the adjusted ice fertilizer is neutral.
The reason why the yield of the forage grass is improved by applying the ice fertilizer in winter. The conventional cow urine and the like are mostly used as environmental pollutants and are difficult to treat. The natural grassland applied in winter has the following advantages by the preparation of the ice fertilizer:
(1) after the ice fertilizer is prepared, the natural grassland is applied in winter, the volatilization of ammonia nitrogen and the like is reduced, and the accumulated snow in winter also plays a role in covering the ice fertilizer.
(2) The ice fertilizer is applied to the grassland, the freezing and thawing are performed alternately in spring, the nutrients of the ice fertilizer are gradually diluted along with the melting of snow water and uniformly permeate into a soil layer, and the absorption and utilization of the plants on the nutrients are ensured.
(3) Along with the green turning of the grassland, the ice fertilizer is melted and dispersed to the soil and around the root system, thereby providing nutrients for the rapid growth of plants and ensuring the yield of the forage grass in the whole growing season.
The ice fertilizer and the natural grassland utilization technology solve the problem that cow urine as a pollutant is difficult to treat, and meanwhile, the productivity of the natural grassland is improved by recycling nutrients, so that sufficient forage grass is provided for the development of animal husbandry.
Compared with the mode that the cow urine is directly applied to the grassland in summer, the biomass is reduced in 2017 and 2018, which shows that the grass yield is reduced when the cow urine is directly applied in summer. The main reasons are the following disadvantages:
(1) the high content of sodium ions in the cow urine causes salt damage, which is not beneficial to the normal and rapid growth of plants.
(2) The high pH of cow urine causes alkali damage to grasslands, which is not favorable for the normal and rapid growth of plants.
(3) When the nutrient solution is applied in summer, nutrients in the cow urine cannot rapidly enter underground soil on the ground surface, and the nutrients are lost in the form of ammonia gas and the like.
(4) The cow urine contains some bacteria and microorganisms which are not beneficial to plant growth, and the like, and causes certain pollution to the environment.
The cattle urine is directly used for ice fertilization (comparative example 3), and the forage grass yield in 2017 and 2018 is improved to a certain extent. The main reasons include:
(1) nutrients such as nitrogen and phosphorus fertilizers contained in the urine of the cattle can be absorbed and utilized by plants, the salt alkalinity harm caused by fertilization in summer is caused in a relative link of the application mode of the ice fertilizer, and the ice fertilizer is applied in a slow release effect.
(2) Although the saline-alkali property of the cow urine is relieved to some extent, the effect on the growth of plants is still influenced to some extent in a long-term mode.
The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, various modifications and decorations can be made without departing from the principle of the present invention, and these modifications and decorations should also be regarded as the protection scope of the present invention.

Claims (9)

1. The ice fertilizer is characterized by comprising bovine urine, calcium superphosphate, ammonium molybdate and boric acid;
the weight ratio of the bovine urine, the calcium superphosphate, the ammonium molybdate and the boric acid is (900-1100): (0.9-1.1): (0.9-1.1): (0.9-1.1).
2. The ice fertilizer as claimed in claim 1, wherein the mass ratio of the bovine urine, the calcium superphosphate, the ammonium molybdate and the boric acid is 1000: 1: 1: 1.
3. the ice fertilizer of claim 1 or 2, wherein the bovine urine is a wet sample of dry and wet separated bovine feces.
4. A method for preparing the ice fertilizer as claimed in any one of claims 1 to 3, characterized in that the bovine urine, the calcium superphosphate, the ammonium molybdate and the boric acid are mixed to form ice particles.
5. A method as claimed in claim 4, wherein said ice particles have a particle size of less than 3 cm.
6. A method of modifying grass comprising: applying the ice fertilizer according to any one of claims 1 to 3 to a grass surface after winter freezing until snow falls.
7. The method as claimed in claim 6, wherein the ice fertilizer is applied in an amount of 5-10 tons/mu.
8. The method of claim 6 or 7, wherein the grass is winter frozen northern grass.
9. The method of claim 8, wherein the grass is high latitudes and cold regions.
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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106508228A (en) * 2016-11-29 2017-03-22 中国科学院植物研究所 Special fertilizer for grassland and method for rapidly recovering deteriorated grassland

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106508228A (en) * 2016-11-29 2017-03-22 中国科学院植物研究所 Special fertilizer for grassland and method for rapidly recovering deteriorated grassland

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