CN110205060A - A kind of high-strength ceramic tile stone material gum and preparation method thereof - Google Patents

A kind of high-strength ceramic tile stone material gum and preparation method thereof Download PDF

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Publication number
CN110205060A
CN110205060A CN201910633786.3A CN201910633786A CN110205060A CN 110205060 A CN110205060 A CN 110205060A CN 201910633786 A CN201910633786 A CN 201910633786A CN 110205060 A CN110205060 A CN 110205060A
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CN
China
Prior art keywords
ceramic tile
stone material
gum
parts
strength ceramic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910633786.3A
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Chinese (zh)
Inventor
陈乐舟
陈雯琪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hubei Alkali New Material Co Ltd
Original Assignee
Hubei Alkali New Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hubei Alkali New Material Co Ltd filed Critical Hubei Alkali New Material Co Ltd
Priority to CN201910633786.3A priority Critical patent/CN110205060A/en
Publication of CN110205060A publication Critical patent/CN110205060A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J131/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
    • C09J131/02Homopolymers or copolymers of esters of monocarboxylic acids
    • C09J131/04Homopolymers or copolymers of vinyl acetate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention discloses a kind of high-strength ceramic tile stone material gums, according to parts by weight, its raw material composition includes: 15~25 parts of VAE lotion, 13~23 parts of polysulfide rubber lotion, 10~15 parts of aqueous epoxy resin emulsion, 40~55 parts of quartz sand, 0.5~1.5 part of surfactant, 0.2~0.4 part of fungicide, 0.1~0.3 part of mill base.The present invention also provides a kind of methods for preparing gum, comprising the following steps: will obtain mixed emulsion in VAE lotion, polysulfide rubber lotion, aqueous epoxy resin emulsion, surfactant investment reaction kettle;2) quartz sand, fungicide, mill base are put into be uniformly mixed in above-mentioned mixed emulsion and obtains gum.The problems such as ceramic tile stone material gum prepared by the present invention fully achieves the bonding requirement of vitrified tile, efficiently solves the hollowing occurred when vitrified tile bonds, flakes, falls off.

Description

A kind of high-strength ceramic tile stone material gum and preparation method thereof
Technical field
The invention belongs to building material technical fields, more particularly to a kind of high-strength ceramic tile stone material gum and its preparation side Method.
Background technique
Vitrified tile is fired according to a certain percentage by quartz sand, mud, is then polished bright but does not need to polish, Surface is smooth bright as glass-mirror.Its water absorption rate, straightness of sides, bending strength, in terms of it is better than general Logical glazed tile, polished bricks and general marble.Vitrified tile is a kind of good ornament materials, is used for interior decoration, is had very Good decorative effect.But since the water absorption rate of vitrified tile itself is lower than 5 ‰, so that very tired when it is pasted to cement layer surface It is difficult.Ceramic tile gum can effectively improve the adhesion strength at the vitrified tile back side and cement layer surface, be that current most effective interface is viscous Tie reinforcing material.However, ceramic tile gum is various in style currently on the market, quality is very different, will appear hollowing after use, rises Shell, the problems such as falling off, such as: the vitrified tile after bonding is easy to appear the phenomenon that falling off by after the etch of rainwater;Weather it is cold Thermal change makes cementitious material by the influence deformed, and cementitious material and vitrified tile interface is caused parting occur, and causes vitreous Brick falls off.
Summary of the invention
The present invention is directed to overcome one of the problems of the above-mentioned prior art, a kind of high-strength ceramic tile stone material gum is provided, According to parts by weight, raw material composition includes:
Preferably, the mesh number of the quartz sand is 40~70 mesh.
Preferably, the mill base is middle yellow pulp.
Preferably, the surfactant is one of polysorbate85 or this Pan 60.
Further, according to parts by weight, raw material composition includes:
0.2~0.4 part of fungicide,
0.1~0.3 part of mill base.
In addition, the present invention also provides a kind of methods for preparing above-mentioned high-strength ceramic tile stone material gum, comprising the following steps:
1) VAE lotion, polysulfide rubber lotion, aqueous epoxy resin emulsion, surfactant are put into reaction kettle with 40 ~60 revs/min of revolving speed stirs 6~8 hours and obtains mixed emulsion;
2) quartz sand, fungicide, mill base are put into above-mentioned mixed emulsion, reaction kettle continues with 40~60 revs/min Revolving speed stirs 15~25 minutes up to gum.
Ceramic tile stone material gum prepared by the present invention fully achieves the bonding requirement of vitrified tile, efficiently solves glass The problems such as changing the hollowing occurred when brick bonds, flaking, fall off.When VAE lotion, polysulfide rubber lotion, aqueous epoxy resin emulsion After mixing, the mercapto in polysulfide rubber lotion is chemically reacted with VAE lotion, to impart the epoxy resin after crosslinking With good flexibility, high shear strength and peel strength.
Specific embodiment
For a better understanding of the present invention, below with reference to the embodiment content that the present invention is furture elucidated, but it is of the invention Content is not limited solely to the following examples.
Embodiment 1:
A kind of high-strength ceramic tile stone material gum, according to parts by weight, raw material composition includes:
Wherein, the mesh number of the quartz sand is 40 mesh;The mill base is middle yellow pulp;The surfactant is polysorbate85 Or one of this Pan 60.
A method of preparing high-strength ceramic tile stone material gum, comprising the following steps:
1) VAE lotion, polysulfide rubber lotion, aqueous epoxy resin emulsion, surfactant are put into reaction kettle with 40 Rev/min revolving speed stir and obtain mixed emulsion in 6 hours;
2) quartz sand, fungicide, mill base are put into above-mentioned mixed emulsion, reaction kettle continues with 40 revs/min of revolving speed Stirring 15 minutes up to gum.
Embodiment 2:
A kind of high-strength ceramic tile stone material gum, according to parts by weight, raw material composition includes:
Wherein, the mesh number of the quartz sand is 50 mesh;The mill base is middle yellow pulp;The surfactant is polysorbate85 Or one of this Pan 60.
A method of preparing high-strength ceramic tile stone material gum, comprising the following steps:
1) VAE lotion, polysulfide rubber lotion, aqueous epoxy resin emulsion, surfactant are put into reaction kettle with 50 Rev/min revolving speed stir and obtain mixed emulsion in 7 hours;
2) quartz sand, fungicide, mill base are put into above-mentioned mixed emulsion, reaction kettle continues with 50 revs/min of revolving speed Stirring 20 minutes up to gum.
Embodiment 3:
A kind of high-strength ceramic tile stone material gum, according to parts by weight, raw material composition includes:
Wherein, the mesh number of the quartz sand is 60 mesh;The mill base is middle yellow pulp;The surfactant is polysorbate85 Or one of this Pan 60.
A method of preparing high-strength ceramic tile stone material gum, comprising the following steps:
1) VAE lotion, polysulfide rubber lotion, aqueous epoxy resin emulsion, surfactant are put into reaction kettle with 60 Rev/min revolving speed stir and obtain mixed emulsion in 8 hours;
2) quartz sand, fungicide, mill base are put into above-mentioned mixed emulsion, reaction kettle continues with 60 revs/min of revolving speed Stirring 25 minutes up to gum.
Embodiment 4:
A kind of high-strength ceramic tile stone material gum, according to parts by weight, raw material composition includes:
Wherein, the mesh number of the quartz sand is 70 mesh;The mill base is middle yellow pulp;The surfactant is polysorbate85 Or one of this Pan 60.
A method of preparing high-strength ceramic tile stone material gum, comprising the following steps:
1) VAE lotion, polysulfide rubber lotion, aqueous epoxy resin emulsion, surfactant are put into reaction kettle with 50 Rev/min revolving speed stir and obtain mixed emulsion in 6 hours;
2) quartz sand, fungicide, mill base are put into above-mentioned mixed emulsion, reaction kettle continues with 60 revs/min of revolving speed Stirring 25 minutes up to gum.
Embodiment 5:
Ceramic tile stone material gum made from above-described embodiment 1~4 is tested for the property, referring to JC/T547-2017 " ceramics Brick adhesive " criterion ceramic tile stone material gum is tested for the property, result is as shown in table 1 below:
Table 1
As can be seen from the above table, the present invention mentions prepared ceramic tile stone material gum, fully achieves the bonding of vitrified tile It is required that the problems such as efficiently solving the hollowing occurred when vitrified tile bonds, flaking, fall off, and construction is simple.
Although an embodiment of the present invention has been shown and described, it will be understood by those skilled in the art that: not A variety of change, modification, replacement and modification can be carried out to these embodiments in the case where being detached from the principle of the present invention and objective, this The range of invention is defined by the claims and their equivalents.

Claims (6)

1. a kind of high-strength ceramic tile stone material gum, which is characterized in that according to parts by weight, raw material composition includes:
2. high-strength ceramic tile stone material gum according to claim 1, which is characterized in that the mesh number of the quartz sand be 40~ 70 mesh.
3. high-strength ceramic tile stone material gum according to claim 2, which is characterized in that the mill base is middle yellow pulp.
4. high-strength ceramic tile stone material gum according to claim 3, which is characterized in that the surfactant is polysorbate85 Or one of this Pan 60.
5. high-strength ceramic tile stone material gum according to claim 1 to 4, which is characterized in that according to parts by weight, Raw material composition further include:
0.2~0.4 part of fungicide,
0.1~0.3 part of mill base.
6. a kind of method for preparing any high-strength ceramic tile stone material gum of claim 1 to 5, which is characterized in that including Following steps:
1) VAE lotion, polysulfide rubber lotion, aqueous epoxy resin emulsion, surfactant are put into reaction kettle with 40~60 Rev/min revolving speed stir and obtain mixed emulsion in 6~8 hours;
2) quartz sand, fungicide, mill base are put into above-mentioned mixed emulsion, reaction kettle continues with 40~60 revs/min of revolving speed Stirring 15~25 minutes up to gum.
CN201910633786.3A 2019-07-15 2019-07-15 A kind of high-strength ceramic tile stone material gum and preparation method thereof Pending CN110205060A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910633786.3A CN110205060A (en) 2019-07-15 2019-07-15 A kind of high-strength ceramic tile stone material gum and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910633786.3A CN110205060A (en) 2019-07-15 2019-07-15 A kind of high-strength ceramic tile stone material gum and preparation method thereof

Publications (1)

Publication Number Publication Date
CN110205060A true CN110205060A (en) 2019-09-06

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Country Status (1)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111995292A (en) * 2020-09-02 2020-11-27 *** Durable ceramic tile binder with good compressive strength and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070112117A1 (en) * 2005-11-17 2007-05-17 Wacker Chemie Ag Process for preparing lattices stabilized by polyvinyl alcohol
CN102815897A (en) * 2012-07-30 2012-12-12 丁力 Alkali seepage-resistant enhanced back adhesive for stone materials
CN105295794A (en) * 2015-10-29 2016-02-03 宁贻伟 Tile adhesive capable of solidifying fast

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070112117A1 (en) * 2005-11-17 2007-05-17 Wacker Chemie Ag Process for preparing lattices stabilized by polyvinyl alcohol
CN102815897A (en) * 2012-07-30 2012-12-12 丁力 Alkali seepage-resistant enhanced back adhesive for stone materials
CN105295794A (en) * 2015-10-29 2016-02-03 宁贻伟 Tile adhesive capable of solidifying fast

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111995292A (en) * 2020-09-02 2020-11-27 *** Durable ceramic tile binder with good compressive strength and preparation method thereof

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Application publication date: 20190906

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