CN110204969A - A kind of Teflon composite coating and preparation method thereof - Google Patents

A kind of Teflon composite coating and preparation method thereof Download PDF

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Publication number
CN110204969A
CN110204969A CN201910521022.5A CN201910521022A CN110204969A CN 110204969 A CN110204969 A CN 110204969A CN 201910521022 A CN201910521022 A CN 201910521022A CN 110204969 A CN110204969 A CN 110204969A
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teflon
coatings
composition
composite coating
alloy coat
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肖志兵
蔡建全
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Jinjiang Lanxin New Mstar Technology Ltd
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Jinjiang Lanxin New Mstar Technology Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/08Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface
    • B05D5/083Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface involving the use of fluoropolymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/24Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/52Two layers
    • B05D7/54No clear coat specified
    • B05D7/542No clear coat specified the two layers being cured or baked together
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C09D127/18Homopolymers or copolymers of tetrafluoroethene
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2451/00Type of carrier, type of coating (Multilayers)
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2506/00Halogenated polymers
    • B05D2506/10Fluorinated polymers
    • B05D2506/15Polytetrafluoroethylene [PTFE]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2601/00Inorganic fillers
    • B05D2601/20Inorganic fillers used for non-pigmentation effect
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Laminated Bodies (AREA)

Abstract

The present invention relates to technical field of coatings, a kind of Teflon composite coating and preparation method thereof is provided, solves the problems, such as that prior art teflon coatings wearability is insufficient.Teflon composite coating includes teflon coatings and alloy coat, the alloy coat is by following mass fraction at being grouped as: 52~60%Ni, 3~7%Fe, 2~6%Si, 14~18%Cr, 0.5~2%P, 6~10%Ti, 2.5~4.5%B, 3~7%Mn, 0.5~3%C, the teflon coatings are Teflon composition, the Teflon composition is by following mass fraction at being grouped as: 48~52% Teflons, 15~18% polyimides, 12~15% polycarbonate resins, 3~5% impact modifiers, 2~4% glass fibres, 2~4% antistatic agents, 8~12% aluminium oxide.

Description

A kind of Teflon composite coating and preparation method thereof
Technical field
The present invention relates to technical field of coatings more particularly to a kind of Teflon composite coating and preparation method thereof.
Background technique
Teflon (PTFE), i.e. polytetrafluoroethylene (PTFE) have excellent chemical stability, corrosion resistance, heat resistance, non-stick The features such as, referred to as " kings of plastics ".Teflon long paint is kind of a high performance coating, possesses the synthesis that other coating can not contend with Advantage is widely used in various industries, solves the problems, such as many of the fields such as chemical industry, petroleum, pharmacy.It applies for a patent 201711101095.6 disclose a kind of electroless nickel teflon coatings, it is made of the raw material of following parts by weight: thermoplastic poly 10-25 parts of vinylidene fluoride, 8-18 parts of Meltability polytetrafluorethyletubular, 2-6 parts of acrylic resin, 1-3 parts of silane coupling agent, surface 2.5-8 parts of activating agent, enhancing increase object 1.5-5 parts, which is applied to die surface, can reduce the friction system of die surface Number, improves the inoxidizability and corrosion resistance of die surface, provides effective preventive maintenance for mold, simplifies and reduce mold Maintenance cost.But the coating surface hardness is low, not damage resistant and abrasion, non-adhesion behavior wear-out failure quickly, the effect used and Service life is extremely limited, therefore wearability becomes the bottleneck of limitation teflon coatings application.
Summary of the invention
Therefore, for the above content, the present invention provides a kind of Teflon composite coating and preparation method thereof, solves existing skill The problem of art teflon coatings wearability deficiency.
In order to achieve the above objectives, the present invention is achieved by the following technical solutions: a kind of Teflon composite coating, including Teflon coatings and alloy coat, the alloy coat is by following mass fraction at being grouped as: 52~60%Ni, 3~7% Fe, 2~6%Si, 14~18%Cr, 0.5~2%P, 6~10%Ti, 2.5~4.5%B, 3~7%Mn, 0.5~3%C, institute Stating teflon coatings is Teflon composition, and the Teflon composition is by following mass fraction at being grouped as: 48~52% Teflon, 15~18% polyimides, 12~15% polycarbonate resins, 3~5% impact modifiers, 2~4% glass fibres, 2 ~4% antistatic agent, 8~12% aluminium oxide.
A further improvement is that: the alloy coat is by following mass fraction at being grouped as: 56%Ni, 5%Fe, 4% Si, 16%Cr, 1%P, 8%Ti, 3.5%B, 5%Mn, 1.5%C, the teflon coatings are Teflon composition, the spy Fluorine dragon composition is by following mass fraction at being grouped as: 50% Teflon, 17% polyimides, 14% polycarbonate resin, 4% impact modifier, 3% glass fibre, 2% antistatic agent, 10% aluminium oxide.
The preparation method of Teflon composite coating the following steps are included:
(1) preparation of Teflon composition:
Teflon, polyimides, polycarbonate resin, impact modifier, glass fibre, antistatic agent are weighed by mass fraction It is put into container, is stirred with blender, alumina powder is homogeneously added into whipping process, is then stirred 2~4h, Obtain teflon coatings;
(2) workpiece surface pre-processes:
Workpiece surface is cleaned first, degreasing degreasing, is then roughened workpiece surface with steel sand, obtains workpiece surface Certain roughness improves coating in the adhesive force of workpiece surface;
(3) alloy coat is sprayed:
Alloy coat composition is equably sprayed on workpiece surface with plasma spraying equipment;
(4) teflon coatings are sprayed:
It after workpiece cools, is polished with sand paper it, then with spray gun for paint by the uniform coating of Teflon composition On alloy coat, teflon coatings are formed;
(5) it is sintered:
The workpiece for having coated composite coating is subjected to baking sintering, 25~35min is sintered at a temperature of 320~380 DEG C, Composite coating is obtained after the completion of sintering.
A further improvement is that: the alloy coat with a thickness of 80~100 μm.
A further improvement is that: 200 mesh of model of the sand paper.
By using preceding solution, the beneficial effects of the present invention are:
Compared with the common teflon coatings of workpiece surface coating, Teflon composite coating prepared by the present invention has more excellent Different antistick characteristic, intensity, ageing-resistant ability and and wearability, can reduce because of friction bring abrasion in use process, effectively Anti-sticking, the wear-resisting and anti-aging degree for improving original workpiece, is particularly suitable for application to have some of strict demand to antistick characteristic It is needed on anti-sticking various workpiece on device, such as in sanitary napkin, paper diaper production process.In workpiece surface and teflon coatings Between increase alloy coat, to form composite coating, can be improved coating hardness and wearability, any surface finish compensates for list One teflon coatings adhesive force is not strong, the problem of being easy to fall off.Aluminium oxide is added in teflon coatings can be improved coating Wearability, addition polyimides can improve the degree of adhesion of teflon coatings and alloy coat.
Specific embodiment
Carry out the embodiment that the present invention will be described in detail below with reference to specific embodiment, how skill is applied to the present invention whereby Art means solve technical problem, and the realization process for reaching technical effect can fully understand and implement.
Unless otherwise specified, the conventional hand that technological means employed in embodiment is well known to those skilled in the art Section, used reagent and product are also available commercial.The source of agents useful for same, trade name and it is necessary to list it Constituent person is indicated on the first occurrence.
Embodiment one
A kind of Teflon composite coating, including teflon coatings and alloy coat, the alloy coat is by following quality point It is several at being grouped as: 52%Ni, 7%Fe, 2%Si, 18%Cr, 2%P, 9%Ti, 2.5%B, 7%Mn, 0.5%C, the spy Fluorine dragon coating is Teflon composition, and the Teflon composition is by following mass fraction at being grouped as: 48% Teflon, 18% polyimides, 15% polycarbonate resin, 3% Methyl methacrylate-butadiem-styrene copolymer, 2% glass Fiber, 3% dodecyl sodium sulfate, 11% aluminium oxide.
The preparation method of Teflon composite coating, comprising the following steps:
(1) preparation of Teflon composition:
Teflon, polyimides, polycarbonate resin, one butadiene of methyl methacrylate, one benzene are weighed by mass fraction Ethylene copolymer, glass fibre, dodecyl sodium sulfate are put into container, are stirred with blender, in whipping process uniformly Alumina powder is added in ground, is then stirred 2h, obtains teflon coatings;
(2) workpiece surface pre-processes:
Workpiece surface is cleaned first, degreasing degreasing, is then roughened workpiece surface with steel sand, obtains workpiece surface Certain roughness improves coating in the adhesive force of workpiece surface;
(3) alloy coat is sprayed:
Alloy coat composition is equably sprayed on workpiece surface with plasma spraying equipment, forms the conjunction of 80 μ m thicks Gold plating;
(4) teflon coatings are sprayed:
It after workpiece cools, is polished with 200 mesh sand paper it, then with spray gun for paint that Teflon composition is uniform It is painted on alloy coat, forms teflon coatings;
(5) it is sintered:
The workpiece for having coated composite coating is subjected to baking sintering, 35min is sintered at 320 DEG C, after the completion of sintering To composite coating.
Embodiment two
A kind of Teflon composite coating, including teflon coatings and alloy coat, the alloy coat is by following quality point It is several at being grouped as: 56%Ni, 5%Fe, 4%Si, 16%Cr, 1%P, 8%Ti, 3.5%B, 5%Mn, 1.5%C, the spy Fluorine dragon coating is Teflon composition, and the Teflon composition is by following mass fraction at being grouped as: 50% Teflon, 17% polyimides, 14% polycarbonate resin, 4% acrylonitrile and butadiene random copolymer, 3% glass fibre, 2% 18 Alkyl dimethyl ethoxy quaternary ammonium nitrate, 10% aluminium oxide.
The preparation method of Teflon composite coating, comprising the following steps:
(1) preparation of Teflon composition:
By mass fraction weigh Teflon, polyimides, polycarbonate resin, acrylonitrile and butadiene random copolymer, Glass fibre, octadecyldimethyl ethoxy quaternary ammonium nitrate are put into container, are stirred with blender, in whipping process It is homogeneously added into alumina powder, is then stirred 3h, obtains teflon coatings;
(2) workpiece surface pre-processes:
Workpiece surface is cleaned first, degreasing degreasing, is then roughened workpiece surface with steel sand, obtains workpiece surface Certain roughness improves coating in the adhesive force of workpiece surface;
(3) alloy coat is sprayed:
Alloy coat composition is equably sprayed on workpiece surface with plasma spraying equipment, forms the conjunction of 90 μ m thicks Gold plating;
(4) teflon coatings are sprayed:
It after workpiece cools, is polished with 200 mesh sand paper it, then with spray gun for paint that Teflon composition is uniform It is painted on alloy coat, forms teflon coatings;
(5) it is sintered:
The workpiece for having coated composite coating is subjected to baking sintering, 30min is sintered at 350 DEG C, after the completion of sintering To composite coating.
Embodiment three
A kind of Teflon composite coating, including teflon coatings and alloy coat, the alloy coat is by following quality point It is several at being grouped as: 60%Ni, 3%Fe, 6%Si, 14%Cr, 0.5%P, 6%Ti, 4.5%B, 3%Mn, 3%C, the spy Fluorine dragon coating is Teflon composition, and the Teflon composition is by following mass fraction at being grouped as: 52% Teflon, 15% polyimides, 12% polycarbonate resin, 5% haloflex, 4% glass fibre, 4% octadecyldiethanol amine, 8% aluminium oxide.
The preparation method of Teflon composite coating, comprising the following steps:
(1) preparation of Teflon composition:
Teflon, polyimides, polycarbonate resin, haloflex, glass fibre, octadecane are weighed by mass fraction Base diethanol amine is put into container, is stirred with blender, and alumina powder is homogeneously added into whipping process, is then stirred 4h is mixed, teflon coatings are obtained;
(2) workpiece surface pre-processes:
Workpiece surface is cleaned first, degreasing degreasing, is then roughened workpiece surface with steel sand, obtains workpiece surface Certain roughness improves coating in the adhesive force of workpiece surface;
(3) alloy coat is sprayed:
Alloy coat composition is equably sprayed on workpiece surface with plasma spraying equipment, forms 100 μ m thicks Alloy coat;
(4) teflon coatings are sprayed:
It after workpiece cools, is polished with 200 mesh sand paper it, then with spray gun for paint that Teflon composition is uniform It is painted on alloy coat, forms teflon coatings;
(5) it is sintered:
The workpiece for having coated composite coating is subjected to baking sintering, 25min is sintered at 380 DEG C, after the completion of sintering To composite coating.
Comparative example: common teflon coating commercially.
The coating that embodiment one to three and comparative example obtain is tested for the property, test result is as shown in table 1.Wearability Detected according to the measurement rotation rubber grinding wheel method of GB/T 1768-2006 paint and varnish wearability, wearability quality with After elastic grinding wheel recycles friction coatings for 200 times the mass loss of coating number indicate.Adhesive force is according to GB/T 9286- 1998 paint and varnish cross cut tests are tested.The antistick characteristic of coating measures the contact angle of coating and water to indicate.
1 coating performance test result of table
Embodiment one Embodiment two Embodiment three Comparative example
Wearability/mg 1.8 1.2 1.6 3.4
Adhesive force/grade 1 1 1 2
Antistick characteristic 112.9° 121.2° 115.8° 103.5°
It is seen from the above data that antistick characteristic, wearability, the adhesive force of Teflon composite coating prepared by the present invention are bright It is aobvious to be better than commercially available common teflon coating.
The foregoing descriptions are merely the embodiment using this origination techniques content, any those skilled in the art use this wound Make done modifications and changes, all belong to the scope of the patents of this creation opinion, and is not limited to those disclosed embodiments.

Claims (5)

1. a kind of Teflon composite coating, it is characterised in that: including teflon coatings and alloy coat, the alloy coat by with Lower mass fraction at being grouped as: 52~60%Ni, 3~7%Fe, 2~6%Si, 14~18%Cr, 0.5~2%P, 6~ 10%Ti, 2.5~4.5%B, 3~7%Mn, 0.5~3%C, the teflon coatings are Teflon composition, the Teflon Composition is by following mass fraction at being grouped as: 48~52% Teflons, 15~18% polyimides, 12~15% poly- carbonic acid Ester resin, 3~5% impact modifiers, 2~4% glass fibres, 2~4% antistatic agents, 8~12% aluminium oxide.
2. a kind of Teflon composite coating according to claim 1, it is characterised in that: the alloy coat is by following quality Score at being grouped as: 56%Ni, 5%Fe, 4%Si, 16%Cr, 1%P, 8%Ti, 3.5%B, 5%Mn, 1.5%C, it is described Teflon coatings are Teflon composition, and the Teflon composition is by following mass fraction at being grouped as: 50% Teflon, 17% polyimides, 14% polycarbonate resin, 4% impact modifier, 3% glass fibre, 2% antistatic agent, 10% aluminium oxide.
3. the preparation method of -2 described in any item Teflon composite coatings according to claim 1, it is characterised in that: including following Step:
(1) preparation of Teflon composition:
Teflon, polyimides, polycarbonate resin, impact modifier, glass fibre, antistatic agent is weighed by mass fraction to be put into It in container, is stirred with blender, alumina powder is homogeneously added into whipping process, is then stirred 2~4h, is obtained Teflon coatings;
(2) workpiece surface pre-processes:
Workpiece surface is cleaned first, degreasing degreasing, be then roughened workpiece surface with steel sand, obtains workpiece surface certain Roughness, improve coating workpiece surface adhesive force;
(3) alloy coat is sprayed:
Alloy coat composition is equably sprayed on workpiece surface with plasma spraying equipment;
(4) teflon coatings are sprayed:
It after workpiece cools, is polished with sand paper it, then Teflon composition is uniformly painted on conjunction with spray gun for paint On gold plating, teflon coatings are formed;
(5) it is sintered:
The workpiece for having coated composite coating is subjected to baking sintering, 25~35min, sintering are sintered at a temperature of 320~380 DEG C Composite coating is obtained after the completion.
4. the preparation method of Teflon composite coating according to claim 3, it is characterised in that: the thickness of the alloy coat Degree is 80~100 μm.
5. the preparation method of Teflon composite coating according to claim 3, it is characterised in that: the model of the sand paper 200 mesh.
CN201910521022.5A 2019-06-17 2019-06-17 A kind of Teflon composite coating and preparation method thereof Pending CN110204969A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111791554A (en) * 2020-06-03 2020-10-20 江苏隆宇新材料有限公司 Teflon coated metal net
CN113083648A (en) * 2021-03-25 2021-07-09 浙江智英石化技术有限公司 Treatment process of extruder die orifice plate
CN115975452A (en) * 2023-02-13 2023-04-18 承德天大钒业有限责任公司 Water-based emulsion paint containing aluminum-molybdenum intermediate alloy and preparation method and application thereof

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CN101571033A (en) * 2009-05-26 2009-11-04 铁岭米勒石油新材料有限公司 Polished sucker rod
CN201873737U (en) * 2010-11-12 2011-06-22 德清县武康镇创智热喷涂厂 Metal substrate with hot sprayed anti-sticking wear-resistant coating and transmission roller
CN104046938A (en) * 2013-03-11 2014-09-17 深圳市繁兴科技有限公司 Pan, and pan coat making method
CN108468013A (en) * 2018-06-25 2018-08-31 东莞市华鑫激光科技有限公司 A kind of preparation method of wear-resisting hydrophobic coating

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL27209A (en) * 1966-02-02 1971-01-28 Kidde & Co Walter Fluorocarbon coated metal surfaces
CN1802420A (en) * 2003-06-06 2006-07-12 阿克佐诺贝尔国际涂料股份有限公司 Non-stick powder coating
CN101571033A (en) * 2009-05-26 2009-11-04 铁岭米勒石油新材料有限公司 Polished sucker rod
CN201873737U (en) * 2010-11-12 2011-06-22 德清县武康镇创智热喷涂厂 Metal substrate with hot sprayed anti-sticking wear-resistant coating and transmission roller
CN104046938A (en) * 2013-03-11 2014-09-17 深圳市繁兴科技有限公司 Pan, and pan coat making method
CN108468013A (en) * 2018-06-25 2018-08-31 东莞市华鑫激光科技有限公司 A kind of preparation method of wear-resisting hydrophobic coating

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111791554A (en) * 2020-06-03 2020-10-20 江苏隆宇新材料有限公司 Teflon coated metal net
CN113083648A (en) * 2021-03-25 2021-07-09 浙江智英石化技术有限公司 Treatment process of extruder die orifice plate
CN113083648B (en) * 2021-03-25 2022-04-01 浙江智英石化技术有限公司 Treatment process of extruder die orifice plate
CN115975452A (en) * 2023-02-13 2023-04-18 承德天大钒业有限责任公司 Water-based emulsion paint containing aluminum-molybdenum intermediate alloy and preparation method and application thereof

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