CN110183923A - A kind of colorful water-water coating and preparation method thereof - Google Patents
A kind of colorful water-water coating and preparation method thereof Download PDFInfo
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- CN110183923A CN110183923A CN201910580504.8A CN201910580504A CN110183923A CN 110183923 A CN110183923 A CN 110183923A CN 201910580504 A CN201910580504 A CN 201910580504A CN 110183923 A CN110183923 A CN 110183923A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of colorful water-water coating, and by weight, raw material includes: 200-400 parts of 5% granulation protection sol solution, 400-600 parts of base paint, 250-350 parts of continuous phase.Described 5% is granulated the parts by weight of the component of protection sol solution and each component are as follows: 800-950 parts of water, 50-60 parts of protection rubber powder, 0.05-0.15 parts of fungicide, 0.05-0.15 parts of xanthan gum.The component of the base paint and the parts by weight of each component are as follows: 55-70 parts of water, 0.1-0.3 parts of fungicide, 1-3 parts of cellulose; 0.1-0.3 parts of ammonium salt dispersing agent; 0.1-0.3 parts of defoaming agent, 0.5-1 parts of propylene glycol, 0.5-1 parts of rutile titanium white powder; 0.5-1 parts of 1250 mesh kaolin; 0.1-0.2 parts of auxiliary agent, 10-30 parts of lotion, 1-3 parts of coalescing agent; 0.1-0.3 parts of defoaming agent, 5-10 parts of 7% protection sol solution.The present invention has good antipollution and resistance to scrub characteristic, and it is at present closest to the coating of granite complexion that the product after brushing can also be removed easily even if contaminated with aqueous detergent.
Description
Technical field
The invention belongs to water burnt-in sand paint fields, more specifically to a kind of colorful water-water coating and its preparation side
Method.
Background technique
Currently, water-soluble colorful coating is that coatings industry develops fast one field now in China, water-soluble colorful coating is being taken
It is prominent for having the advantages that in terms of cladding marble, it can reach 95% similarity degree in terms of imitation stone, cost is cladding
20% or so of stone material, construction requirement is also harsh like that without dry-hang stone, and extremely light self weight makes the risk that it does not fall off, but
Be most of coating producers production now water-soluble colorful coating in the prevalence of poor water resistance, resistance tocrocking is poor, and durability is poor,
The deficiencies of Storage period is short, not environmentally friendly enough, and production process is complicated, and construction requirement is harsh place.
Summary of the invention
In view of the deficiencies of the prior art, the present invention intends to provide a kind of colorful water-water coating and its system
Preparation Method.
To achieve the above object, the present invention provides the following technical scheme that
A kind of colorful water-water coating, it is characterised in that: by weight, raw material includes: 200-400 parts and 5% makes
Grain protection sol solution, 400-600 parts of base paint, 250-350 parts of continuous phase.
Wherein, described 5% the component of protection sol solution and the parts by weight of each component are granulated are as follows: 800-950 parts of water,
50-60 parts of protection rubber powder, 0.05-0.15 parts of fungicide, 0.05-0.15 parts of xanthan gum.
The component of the base paint and the parts by weight of each component are as follows: 55-70 parts of water, 0.1-0.3 parts of fungicide, 1-
3 parts of cellulose, 0.1-0.3 parts of ammonium salt dispersing agent, 0.1-0.3 parts of defoaming agent, 0.5-1 parts of propylene glycol, 0.5-1 parts
Rutile titanium white powder, 0.5-1 parts of 1250 mesh kaolin, 0.1-0.2 parts of auxiliary agent, 10-30 parts of lotion, 1-3 parts of film forming
Auxiliary agent, 0.1-0.3 parts of defoaming agent, 5-10 parts of 7% protection sol solution.
The component of the continuous phase and the parts by weight of each component are as follows: 15-30 parts of water, 60-75 parts of lotion, 3-5 parts
Coalescing agent, 1-3 parts of propylene glycol, 0.1-0.4 parts of defoaming agent, 3-7 parts of fungicide, 0.1-0.4 parts of multifunctional assistant
Agent, 0.2-1 parts of thickener.
As a kind of technical solution of optimization, the component of the 7% protection sol solution and the parts by weight of each component are as follows:
85-95 parts of water, 5-10 parts of protection rubber powder, 0.01-0.05 parts of fungicide.
As a kind of technical solution of optimization, the colorful water-water coating further includes that parts by weight are 10-20 parts hollow
Microballon.
As a kind of technical solution of optimization, described 5% is granulated protection sol solution, and fungicide is using lime Bordeaux
One of which in liquid, Kocide SD or cuprous oxide.
As a kind of technical solution of optimization, in the base paint, coalescing agent is alcohol vinegar 12, and lotion is pure C cream
At least one of liquid, silicone acrylic emulsion；Preservative is organic acid preservative, neutral compound class at least one of the preservatives.
As a kind of technical solution of optimization, in the continuous phase, multifunctional assistant is using AMP-95 multifunctional assistant
Agent.
The present invention also provides a kind of preparation methods of colorful water-water coating, which comprises the steps of:
Step 1: 5% is granulated protection sol solution preparation: according to the ratio by 949.9 parts of water, 50 parts of protection rubber powder, 0.05
The fungicide of part, high-speed stirred 10 minutes after 0.05 part of xanthan gum mixing, it is desirable that uniformly without agglomeration, then stir at low speed 5 again
Minute, toning filtering eliminates bubble, for use；
Step 2: 7% protection sol solution preparation: according to the ratio by 92.95 parts of water, 7 parts of protection rubber powder, 0.05 part kill
High-speed stirred 10 minutes after microbial inoculum mixing, bubble is eliminated, for use；
Step 3: prepared by base paint: according to the ratio by 60 parts of water, 0.2 part of fungicide, 2 parts of cellulose, 0.2 part
Ammonium salt dispersing agent, 0.1 part of defoaming agent, 0.7 part of propylene glycol, 0.8 part of rutile titanium white powder, 0.6 part of 1250 mesh kaolinites
Soil, 0.1 part of auxiliary agent, 30 parts of lotion, 2 parts of coalescing agent, 0.3 part of defoaming agent, 9 parts of 7% protection sol solution；It is added
Agitator tank is stirred at low speed to clear；
Step 4: prepared by continuous phase: according to the ratio by 24 parts of water, 68 parts of lotion, 5 parts of coalescing agent, the third the two of 2 parts
Alcohol, 0.3 part of defoaming agent, 4 parts of fungicide, 0.3 part of multifunctional assistant, 0.7 part of thickener stir evenly；
Step 5: prepared by colour particles:
1, according to the ratio by the 5% of 340 parts be granulated protection sol solution, 550 parts of base paint, 280 parts be continuously added to frame
In formula agitator tank；
2, it stirs at low speed, is granulated protection sol solution for 5% according to the ratio and is poured into dispersed phase fluid shape, gel 2~4 hours；
3, turn to be granulated using rotor 300-500, while base paint and continuous phase being added according to the ratio, until particle size conforms to
It asks；
4, AMP-95 multifunctional assistant is added under low speed and adjusts pH value=8, colorful water-water coating is finally made.
By adopting the above-described technical solution, compared with prior art, the beneficial effects of the present invention are:
1, the present invention has good antipollution and resistance to scrub characteristic, and the product after brushing can also use water even if contaminated
Property detergent is removed easily, is at present closest to the coating of granite complexion.
2, present invention addition cenosphere, further increases the wash-resistant property of water-water coating, resistance to artificial weathering aging
Performance improves the heat-proof quality of water-water coating using the hollow structure of cenosphere.
3, preparation method advantages of simple of the invention, sequence are mixed, and the coating quality being eventually fabricated is good, and mixing is equal
It is even, and can guarantee very high yield.
Specific embodiment
Embodiment 1
A kind of colorful water-water coating, by weight, raw material include: 300 parts of 5% granulation protection sol solution, 500
The base paint of part, 300 parts of continuous phase.
Described 5% is granulated the parts by weight of the component of protection sol solution and each component are as follows: 880 parts of water, 52 parts of protection
Rubber powder, 0.09 part of fungicide, 0.12 part of xanthan gum.
In said components, xanthan gum is to be fermented by carbohydrate through Xanthomonas campestris, the more pools of extracellular microorganism of generation.Due to it
Macromolecular special construction and colloid property, and have multiple functions, can be used as emulsifier, stabilizer, gelling thickener etc..It kills
Microbial inoculum is using the one of which in lime Bordeaux mixture, Kocide SD or cuprous oxide.
The component of the base paint and the parts by weight of each component are as follows: 60 parts of water, 0.3 part of fungicide, 2 parts of fiber
Element, 0.18 part of ammonium salt dispersing agent, 0.22 part of defoaming agent, 0.9 part of propylene glycol, 0.8 part of rutile titanium white powder, 0.7 part
1250 mesh kaolin, 0.14 part of auxiliary agent, 22 parts of lotion, 2 parts of coalescing agent, 0.21 part of defoaming agent, the 7% of 8 parts
Protect sol solution.The component of the 7% protection sol solution and the parts by weight of each component are as follows: 88 parts of water, 6 parts of protective glue
Powder, 0.04 part of fungicide.The colorful water-water coating further includes the cenosphere that parts by weight are 18 parts.It is added in base paint
Cellulose, water can make cellulose that limited swelling occur, and the aqueous solution of certain acid, alkali and salt can penetrate into fiber crystal region, generate
Infinite swelling makes cellulose dissolution.Cellulose and denseer inorganic acid play hydrolysis and generate glucose etc., with denseer causticity
Aqueous slkali effect generates alkali cellulose, acts on strong oxidizer and generates oxycellulose.It joined in base paint a certain proportion of
The stability of suspension can be improved in kaolin.
In the base paint, coalescing agent is alcohol vinegar 12, and lotion is at least one of pure-acrylic emulsion, silicone acrylic emulsion；
Preservative is organic acid preservative, neutral compound class at least one of the preservatives.
The component of the continuous phase and the parts by weight of each component are as follows: 22 parts of water, 68 parts of lotion, 3 parts of film forming help
Agent, 3 parts of propylene glycol, 0.25 defoaming agent, 6 parts of fungicide, 0.2 part of multifunctional assistant, 0.5 part of thickener.
In said components, what dispersing agent, defoaming agent, auxiliary agent used is all conventional technique.Lotion is using pure C alkene
Acid polymer lotion.Coalescing agent is alcohol vinegar 12, and lotion is at least one of pure-acrylic emulsion, silicone acrylic emulsion.Preservative is
Organic acid preservative, neutral compound class at least one of the preservatives.Multifunctional assistant is using AMP-95 multifunctional assistant
Agent.
Embodiment 2
A kind of colorful water-water coating, by weight, raw material include: 250 parts of 5% granulation protection sol solution, 550
The base paint of part, 330 parts of continuous phase.
Described 5% is granulated the parts by weight of the component of protection sol solution and each component are as follows: 880 parts of water, 52 parts of protection
Rubber powder, 0.09 part of fungicide, 0.12 part of xanthan gum.
In said components, xanthan gum is to be fermented by carbohydrate through Xanthomonas campestris, the more pools of extracellular microorganism of generation.Due to it
Macromolecular special construction and colloid property, and have multiple functions, can be used as emulsifier, stabilizer, gelling thickener etc..It kills
Microbial inoculum is using the one of which in lime Bordeaux mixture, Kocide SD or cuprous oxide.
The water that the component of the base paint and the parts by weight of each component are 60 parts, 0.1 part of fungicide, 1 part of fiber
Element, 0.3 part of ammonium salt dispersing agent, 0.3 part of defoaming agent, 0.8 part of propylene glycol, 0.9 part of rutile titanium white powder, 1 part
1250 mesh kaolin, 0.15 part of auxiliary agent, 20 parts of lotion, 3 parts of coalescing agent, 0.26 part of defoaming agent, the 7% of 9 parts are protected
Protect sol solution.The component of the 7% protection sol solution and the parts by weight of each component are as follows: 90 parts of water, 10 parts of protection rubber powder,
0.02 part of fungicide.The colorful water-water coating further includes the cenosphere that parts by weight are 12 parts.It joined in base paint
Cellulose, water can make cellulose that limited swelling occur, and the aqueous solution of certain acid, alkali and salt can penetrate into fiber crystal region, generate nothing
Limit swelling, makes cellulose dissolution.Cellulose and denseer inorganic acid play hydrolysis and generate glucose etc., with denseer caustic alkali
Solution effects generate alkali cellulose, act on strong oxidizer and generate oxycellulose.It joined in base paint a certain proportion of high
Ridge soil, can be improved the stability of suspension.
In the base paint, coalescing agent is alcohol vinegar 12, and lotion is at least one of pure-acrylic emulsion, silicone acrylic emulsion；
Preservative is organic acid preservative, neutral compound class at least one of the preservatives.
The component of the continuous phase and the parts by weight of each component are as follows: 25 parts of water, 70 parts of lotion, 4 parts of film forming help
Agent, 1 part of propylene glycol, 0.3 part of defoaming agent, 6 parts of fungicide, 0.4 part of multifunctional assistant, 0.8 part of thickener.
In said components, what dispersing agent, defoaming agent, auxiliary agent used is all conventional technique.Lotion is using pure C alkene
Acid polymer lotion.Coalescing agent is alcohol vinegar 12, and lotion is at least one of pure-acrylic emulsion, silicone acrylic emulsion.Preservative is
Organic acid preservative, neutral compound class at least one of the preservatives.Multifunctional assistant is using AMP-95 multifunctional assistant
Agent.
Embodiment 3
A kind of colorful water-water coating, by weight, raw material include: 200 parts of 5% granulation protection sol solution, 400
The base paint of part, 250 parts of continuous phase.
Described 5% is granulated the parts by weight of the component of protection sol solution and each component are as follows: 900 parts of water, 62 parts of protection
Rubber powder, 0.11 part of fungicide, 0.12 part of xanthan gum.
In said components, xanthan gum is to be fermented by carbohydrate through Xanthomonas campestris, the more pools of extracellular microorganism of generation.Due to it
Macromolecular special construction and colloid property, and have multiple functions, can be used as emulsifier, stabilizer, gelling thickener etc..It kills
Microbial inoculum is using the one of which in lime Bordeaux mixture, Kocide SD or cuprous oxide.
The water that the component of the base paint and the parts by weight of each component are 60 parts, 0.16 part of fungicide, 1.4 parts of fibre
Dimension element, 0.2 part of ammonium salt dispersing agent, 0.2 part of defoaming agent, 0.9 part of propylene glycol, 1 part of rutile titanium white powder, 1 part
1250 mesh kaolin, 0.1 part of auxiliary agent, 18 parts of lotion, 2 parts of coalescing agent, 0.1 part of defoaming agent, 6 parts of 7% protection
Sol solution.The component of the 7% protection sol solution and the parts by weight of each component are as follows: 91 parts of water, 8 parts of protection rubber powder,
0.02 part of fungicide.The colorful water-water coating further includes the cenosphere that parts by weight are 10 parts.It joined in base paint
Cellulose, water can make cellulose that limited swelling occur, and the aqueous solution of certain acid, alkali and salt can penetrate into fiber crystal region, generate nothing
Limit swelling, makes cellulose dissolution.Cellulose and denseer inorganic acid play hydrolysis and generate glucose etc., with denseer caustic alkali
Solution effects generate alkali cellulose, act on strong oxidizer and generate oxycellulose.It joined in base paint a certain proportion of high
Ridge soil, can be improved the stability of suspension.
In the base paint, coalescing agent is alcohol vinegar 12, and lotion is at least one of pure-acrylic emulsion, silicone acrylic emulsion；
Preservative is organic acid preservative, neutral compound class at least one of the preservatives.
The component of the continuous phase and the parts by weight of each component are as follows: 30 parts of water, 70 parts of lotion, 3 parts of film forming help
Agent, 1 part of propylene glycol, 0.3 part of defoaming agent, 4 parts of fungicide, 0.4 part of multifunctional assistant, 0.4 part of thickener.
In said components, what dispersing agent, defoaming agent, auxiliary agent used is all conventional technique.Lotion is using pure C alkene
Acid polymer lotion.Coalescing agent is alcohol vinegar 12, and lotion is at least one of pure-acrylic emulsion, silicone acrylic emulsion.Preservative is
Organic acid preservative, neutral compound class at least one of the preservatives.Multifunctional assistant is using AMP-95 multifunctional assistant
Agent.
All contain cenosphere in above-described embodiment.Cenosphere is also the point of a focused protection.It increases hollow micro-
After pearl, inert gas is contained in cenosphere, density is very low, can reduce the close of the colorful suspended particulate containing sand after addition
Degree, can realize and suspend in the solution.In practical applications, it has been found that inorganic quartz sand is micro- with organic polymer
There are problems that between ball can be because colorful grain occurs for two-phase laminated flow after compatibility, configured water-water multi-color containing sand are long placed in
The diffusing phenomenon of son.Addition polyphosphate chelating agent etc. can effectively solve the problem that problems, because polyphosphate can same sand
Sublist face is chelated, and hydrophobically modified block copolymer is easier affinity with polymer microballoon, in this way through organically-modified poly
When phosphate is combined with hydrophobically modified block copolymer, compatibility and combination of the inorganic sand with polymer microballoon are just greatly strengthened
Power is simultaneously because carried out hydrophobically modified to block copolymer, so that the suspended particulate formed after making a little has water resistance, it will not
It dissolves in a short time, to guarantee the effect of multi-color.Cenosphere buying is Eka Chemicals (Suzhou) Co., Ltd
The cenosphere of the hollow structure for including inert gas of production.The diameter of microballoon is 20 μm, scattered in multi-color, and
The appearance and using effect for not influencing multi-color, requirement can be reached by adding a small amount of microballoon.
The formula of above-mentioned three kinds of different proportions is three kinds of products of three kinds of different characteristics.The first is in southern moist ring
It is used under border.It is for second used in the dry environment in northwest.The third is used under the environment of northeast cold.
A kind of preparation method of colorful water-water coating, includes the following steps:
Step 1: 5% is granulated protection sol solution preparation: according to the ratio by 949.9 parts of water, 50 parts of protection rubber powder, 0.05
The fungicide of part, high-speed stirred 10 minutes after 0.05 part of xanthan gum mixing, it is desirable that uniformly without agglomeration, then stir at low speed 5 again
Minute, toning filtering eliminates bubble, for use.
Step 2: 7% protection sol solution preparation: according to the ratio by 92.95 parts of water, 7 parts of protection rubber powder, 0.05 part kill
High-speed stirred 10 minutes after microbial inoculum mixing, bubble is eliminated, for use.
Step 3: prepared by base paint: according to the ratio by 60 parts of water, 0.2 part of fungicide, 2 parts of cellulose, 0.2 part
Ammonium salt dispersing agent, 0.1 part of defoaming agent, 0.7 part of propylene glycol, 0.8 part of rutile titanium white powder, 0.6 part of 1250 mesh kaolinites
Soil, 0.1 part of auxiliary agent, 30 parts of lotion, 2 parts of coalescing agent, 0.3 part of defoaming agent, 9 parts of 7% protection sol solution；It is added
Agitator tank is stirred at low speed to clear.
Step 4: prepared by continuous phase: according to the ratio by 24 parts of water, 68 parts of lotion, 5 parts of coalescing agent, the third the two of 2 parts
Alcohol, 0.3 part of defoaming agent, 4 parts of fungicide, 0.3 part of multifunctional assistant, 0.7 part of thickener stir evenly.
Step 5: prepared by colour particles:
1, according to the ratio by the 5% of 340 parts be granulated protection sol solution, 550 parts of base paint, 280 parts be continuously added to frame
In formula agitator tank；
2, it stirs at low speed, is granulated protection sol solution for 5% according to the ratio and is poured into dispersed phase fluid shape, gel 2~4 hours；
3, turn to be granulated using rotor 300-500, while base paint and continuous phase being added according to the ratio, until particle size conforms to
It asks；
4, AMP-95 multifunctional assistant is added under low speed and adjusts pH value=8, colorful water-water coating is finally made.
The product of three kinds of different formulations is all proportionally to come, and greatly reduces cost.
The present invention has good antipollution and a resistance to scrub characteristic, product after brushing even if it is contaminated can also be with aqueous
Detergent is removed easily, is at present closest to the coating of granite complexion.
The present invention adds cenosphere, further increases wash-resistant property, the artificial weathering ageing resistance of water-water coating
Can, using the hollow structure of cenosphere, improve the heat-proof quality of water-water coating.
Preparation method advantages of simple of the invention, sequence are mixed, and the coating quality being eventually fabricated is good, are uniformly mixed,
And it can guarantee very high yield.
The surfacing of water-in-water multicolor coating containing color sand obtained by the present invention is not easy dust stratification, can keep whole more long
Aesthetic appearance has stain resistance；It is bright-coloured for a long time that special cladding gloss oil is able to maintain the surface color of water-in-water multicolor coating containing color sand,
With weatherability；Water-in-water multicolor coating containing color sand has good waterproofness and anti-corrosive properties, and rainy day metope is not absorbed, do not broken
Damage, protection building are moulded.
Protection scope of the present invention is not limited merely to above-described embodiment, and all technical solutions belonged under thinking of the present invention are equal
It belongs to the scope of protection of the present invention.It should be pointed out that for those skilled in the art, not departing from the present invention
Several improvements and modifications under the premise of principle, these modifications and embellishments should also be considered as the scope of protection of the present invention.
Claims (7)
1. a kind of colorful water-water coating, it is characterised in that:
By weight, raw material includes:
The 5% of 200-400 parts is granulated protection sol solution, 400-600 parts of base paint, 250-350 parts of continuous phase；
Wherein, described 5% the component of protection sol solution and the parts by weight of each component are granulated are as follows: 800-950 parts of water, 50-60
The protection rubber powder of part, 0.05-0.15 parts of fungicide, 0.05-0.15 parts of xanthan gum；
The component of the base paint and the parts by weight of each component are as follows: 55-70 parts of water, 0.1-0.3 parts of fungicide, 1-3 parts
Cellulose, 0.1-0.3 parts of ammonium salt dispersing agent, 0.1-0.3 parts of defoaming agent, 0.5-1 parts of propylene glycol, 0.5-1 parts of gold
Red stone titanium dioxide, 0.5-1 parts of 1250 mesh kaolin, 0.1-0.2 parts of auxiliary agent, 10-30 parts of lotion, 1-3 parts of film forming help
Agent, 0.1-0.3 parts of defoaming agent, 5-10 parts of 7% protection sol solution；
The component of the continuous phase and the parts by weight of each component are as follows: 15-30 parts of water, 60-75 parts of lotion, 3-5 parts at
Film auxiliary agent, 1-3 parts of propylene glycol, 0.1-0.4 parts of defoaming agent, 3-7 parts of fungicide, 0.1-0.4 parts of multifunctional assistant,
0.2-1 parts of thickener.
2. a kind of colorful water-water coating according to claim 1, it is characterised in that: the group of the 7% protection sol solution
Point and each component parts by weight are as follows: 85-95 parts of water, 5-10 parts of protection rubber powder, 0.01-0.05 parts of fungicide.
3. a kind of colorful water-water coating according to claim 2, it is characterised in that: the colorful water-water coating also wraps
Include the cenosphere that parts by weight are 10-20 parts.
4. a kind of colorful water-water coating according to claim 2, it is characterised in that: described 5% is granulated protection sol solution,
Fungicide is using the one of which in lime Bordeaux mixture, Kocide SD or cuprous oxide.
5. a kind of colorful water-water coating according to claim 2, it is characterised in that: in the base paint, coalescing agent
For alcohol vinegar 12, lotion is at least one of pure-acrylic emulsion, silicone acrylic emulsion；Preservative is organic acid preservative, neutral chemical combination
Species at least one of the preservatives.
6. a kind of colorful water-water coating according to claim 2, it is characterised in that: in the continuous phase, multifunctional assistant
Agent is using AMP-95 multifunctional assistant.
7. a kind of preparation method of colorful water-water coating, which comprises the steps of:
Step 1: 5% is granulated protection sol solution preparation: according to the ratio by 949.9 parts of water, 50 parts of protection rubber powder, 0.05 part
Fungicide, high-speed stirred 10 minutes after 0.05 part of xanthan gum mixing, it is desirable that uniformly without agglomeration, then stir at low speed again 5 minutes,
Toning filtering, eliminates bubble, for use；
Step 2: 7% protection sol solution preparation: according to the ratio by 92.95 parts of water, 7 parts of protection rubber powder, 0.05 part of fungicide
Bubble is eliminated, for use in high-speed stirred 10 minutes after mixing；
Step 3: prepared by base paint: according to the ratio by 60 parts of water, 0.2 part of fungicide, 2 parts of cellulose, 0.2 part of ammonium salt
Dispersing agent, 0.1 part of defoaming agent, 0.7 part of propylene glycol, 0.8 part of rutile titanium white powder, 0.6 part of 1250 mesh kaolin,
0.1 part of auxiliary agent, 30 parts of lotion, 2 parts of coalescing agent, 0.3 part of defoaming agent, 9 parts of 7% protection sol solution；Addition is stirred
Tank is mixed to stir at low speed to clear；
Step 4: prepared by continuous phase: according to the ratio by 24 parts of water, 68 parts of lotion, 5 parts of coalescing agent, 2 parts of propylene glycol,
0.3 part of defoaming agent, 4 parts of fungicide, 0.3 part of multifunctional assistant, 0.7 part of thickener stir evenly；
Step 5: prepared by colour particles:
1, according to the ratio by the 5% of 340 parts be granulated protection sol solution, 550 parts of base paint, 280 parts be continuously added to frame and stir
It mixes in tank；
2, it stirs at low speed, is granulated protection sol solution for 5% according to the ratio and is poured into dispersed phase fluid shape, gel 2~4 hours；
3, turn to be granulated using rotor 300-500, while base paint and continuous phase being added according to the ratio, until particle size meets the requirements；
4, AMP-95 multifunctional assistant is added under low speed and adjusts pH value=8, colorful water-water coating is finally made.
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| CN110903721A (en) * | 2019-06-29 | 2020-03-24 | 江苏七点建材有限公司 | Colorful sand-in-water coating and preparation method thereof |
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| CN111607274A (en) * | 2020-06-04 | 2020-09-01 | 豪冠(上海)国际贸易有限公司 | Preparation method of cover-free stain-resistant weather-resistant water-based multicolor building coating |
| CN112646408A (en) * | 2020-08-12 | 2021-04-13 | 安徽雅特兰新材料科技有限公司 | Preparation method of water-in-water colorful stone-like paint |
| CN112694771A (en) * | 2020-12-22 | 2021-04-23 | 广东顺德派齐新材料有限公司 | Inorganic fireproof heat-preservation multicolor paint synthesized by inorganic resin and preparation method thereof |
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| CN113502082A (en) * | 2021-08-04 | 2021-10-15 | 重庆凯茜蔓科技有限公司 | Pearlescent water-in-water artistic coating and preparation method thereof |
| CN113667367A (en) * | 2021-09-02 | 2021-11-19 | 浙江曼得丽涂料有限公司 | Water-based interior wall soft sand coating and preparation method thereof |
| CN114479587A (en) * | 2022-01-13 | 2022-05-13 | 河北三棵树涂料有限公司 | Watercolor stone environment-friendly coating and preparation method thereof |
| CN114316708A (en) * | 2022-01-21 | 2022-04-12 | 河南佰利新材料有限公司 | Preparation method of water-in-water colorful crackle paint |
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| CN115011151A (en) * | 2022-06-09 | 2022-09-06 | 厦门市好雅丽涂料有限公司 | Water-based colorful stone-like paint and preparation method thereof |
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