CN110181910A - 一种磁性阻燃环保型tpo合成革与制备 - Google Patents
一种磁性阻燃环保型tpo合成革与制备 Download PDFInfo
- Publication number
- CN110181910A CN110181910A CN201910512799.5A CN201910512799A CN110181910A CN 110181910 A CN110181910 A CN 110181910A CN 201910512799 A CN201910512799 A CN 201910512799A CN 110181910 A CN110181910 A CN 110181910A
- Authority
- CN
- China
- Prior art keywords
- parts
- tpo
- powder
- modified
- synthetic leather
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- 239000002649 leather substitute Substances 0.000 title claims abstract description 19
- 230000005389 magnetism Effects 0.000 title claims description 12
- 239000000843 powder Substances 0.000 claims abstract description 33
- 239000000758 substrate Substances 0.000 claims abstract description 30
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 22
- 229910052751 metal Inorganic materials 0.000 claims abstract description 20
- 239000002184 metal Substances 0.000 claims abstract description 20
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims abstract description 18
- -1 polypropylene Polymers 0.000 claims abstract description 16
- 239000004611 light stabiliser Substances 0.000 claims abstract description 15
- 239000004743 Polypropylene Substances 0.000 claims abstract description 14
- 229920001155 polypropylene Polymers 0.000 claims abstract description 14
- 229920006327 polystyrene foam Polymers 0.000 claims abstract description 13
- 238000012661 block copolymerization Methods 0.000 claims abstract description 12
- 239000000049 pigment Substances 0.000 claims abstract description 11
- 229920006124 polyolefin elastomer Polymers 0.000 claims abstract description 11
- 239000011248 coating agent Substances 0.000 claims abstract description 7
- 238000000576 coating method Methods 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims abstract description 7
- 239000004615 ingredient Substances 0.000 claims abstract description 6
- 238000007790 scraping Methods 0.000 claims abstract description 5
- 238000010521 absorption reaction Methods 0.000 claims abstract description 4
- 238000007731 hot pressing Methods 0.000 claims abstract description 3
- 238000001125 extrusion Methods 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 6
- 238000012986 modification Methods 0.000 claims description 6
- 230000004048 modification Effects 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 5
- 238000003851 corona treatment Methods 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- 239000003607 modifier Substances 0.000 claims description 5
- 238000006116 polymerization reaction Methods 0.000 claims description 5
- 238000003466 welding Methods 0.000 claims description 5
- 239000006260 foam Substances 0.000 claims description 4
- 229910044991 metal oxide Inorganic materials 0.000 claims description 3
- 150000004706 metal oxides Chemical class 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 2
- 239000012965 benzophenone Substances 0.000 claims description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- YIKSCQDJHCMVMK-UHFFFAOYSA-N Oxamide Chemical class NC(=O)C(N)=O YIKSCQDJHCMVMK-UHFFFAOYSA-N 0.000 claims 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-N Salicylic acid Natural products OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 150000008360 acrylonitriles Chemical class 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 229910052788 barium Inorganic materials 0.000 claims 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims 1
- 239000012964 benzotriazole Substances 0.000 claims 1
- 239000010931 gold Substances 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 claims 1
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 239000011777 magnesium Substances 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims 1
- 229960004889 salicylic acid Drugs 0.000 claims 1
- 229910052712 strontium Inorganic materials 0.000 claims 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 150000003918 triazines Chemical class 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 239000000853 adhesive Substances 0.000 abstract description 3
- 230000001070 adhesive effect Effects 0.000 abstract description 3
- 238000005034 decoration Methods 0.000 abstract description 2
- 239000000696 magnetic material Substances 0.000 abstract 1
- 239000010408 film Substances 0.000 description 24
- 230000007613 environmental effect Effects 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 238000010276 construction Methods 0.000 description 2
- 239000010985 leather Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000005192 partition Methods 0.000 description 2
- 238000012797 qualification Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 241000219000 Populus Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 239000006247 magnetic powder Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/0008—Electrical discharge treatment, e.g. corona, plasma treatment; wave energy or particle radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/18—Handling of layers or the laminate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/26—Polymeric coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2266/00—Composition of foam
- B32B2266/02—Organic
- B32B2266/0214—Materials belonging to B32B27/00
- B32B2266/0221—Vinyl resin
- B32B2266/0228—Aromatic vinyl resin, e.g. styrenic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
- B32B2307/208—Magnetic, paramagnetic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
- B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/552—Fatigue strength
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/584—Scratch resistance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/732—Dimensional properties
- B32B2307/734—Dimensional stability
Landscapes
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Engineering & Computer Science (AREA)
- Plasma & Fusion (AREA)
- Thermal Sciences (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
本发明公开了一种磁性阻燃环保型TPO合成革与制备，所述TPO合成革包括：TPO基材、位于所述TPO基材上表面的耐刮涂层、位于所述TPO基材下表面的具有磁性吸附的磁性层，所述TPO基材包括：改性TPO膜、和与所述改性TPO膜热压合在一起的聚苯乙烯泡沫，所述改性TPO膜包括如下重量份的成分：嵌段共聚聚丙烯40‑60份，聚烯烃弹性体10‑20份，Fe2O3粉末10‑30份，金属的粉末氧化物0.5‑5份，光稳定剂0.1‑0.5，耐磨剂5‑20份，颜料5‑10份。所述制备方法包括：(1)改性TPO膜制备；(2)TPO基材制备；(3)表面处理；通过上述方式，本发明无需添加任何胶黏剂，通过添加磁性材料或者可磁化材料，在同时制得的合成革时又使其具有装饰简便的优异性能。
Description
技术领域
本发明涉及合成革制造技术领域，特别是设计一种磁性阻燃环保TPO合成革及其制备方法。
背景技术
随着社会的发展和人们生活的提高，室内环境受到了越来越多的重视，目前用于室内隔墙、顶墙的外层装修大多为涂料、油漆等，其中含有大量的甲醛和其它致癌物质，对居民身体健康造成重大危害。TPO材料作为一种绿色、经济、环保的材料，具有保温、隔热等特点，在建筑装修领域获得了广泛的应用，尤其是在室内隔墙、顶墙的表层装修领域，而磁性TPO薄膜材料由于其本身具有磁性，只需要墙体具有磁性即可将磁性TPO薄膜固定，可随意更换、施工工期短获到了广泛的关注。
发明内容
本发明主要解决的技术问题是：针对现有技术的不足，提供一种磁性阻燃环保型TPO合成革及其制备方法，无需任何胶黏剂就可以进行装修覆盖，且无需添加任何阻燃剂就可以达到阻燃要求，同时制造成本低。
为解决上述技术问题，本发明采用的一个技术方案是：提供一种磁性阻燃环保型TPO合成革，包括：TPO基材、位于所述TPO基材上表面的耐刮涂层。所述TPO基材包括：改性TPO膜、和与所述改性TPO膜热压合在一起的聚丙烯泡沫，所述改性TPO膜包括如下重量份的成分：嵌段共聚聚丙烯40-60份，聚烯烃弹性体5-50份，Fe2O3磁性粉末20-50份，金属的粉末氧化物5-15份，光稳定剂0.5-1，耐磨剂1-5份，颜料1-15份。
在本发明一个较佳实施例中，所述改性TPO膜包括如下重量份的成分：嵌段共聚聚丙烯40-60份，聚烯烃弹性体5-50份，Fe2O3磁性粉末20-50份，金属的粉末氧化物5-15份，光稳定剂0.5-1，耐磨剂1-5份，颜料1-15份。在本发明一个较佳实施例中，所述光稳定剂为水杨酸脂类和二苯甲酮类光稳定剂。
在本发明一个较佳实施例中，所述聚丙烯泡沫的厚度为：1.0mm、1.5mm、2.0mm、2.5mm或3.0mm，宽度为1000-5000mm，发泡率为15、20、25或30倍。在本发明一个较佳实施例中，所述耐刮涂层包括依次附着在所述TPO基材上表面的底面处理剂层。
本发明还提供一种磁性阻燃环保型TPO合成革的制备方法，包括如下步骤：
(1)Fe2O3粉末、金属的粉末氧化物的聚合改性：采用原为聚合的方法制备外聚丙烯-金属粉末的改性物。
(2)改性TPO膜制备：嵌段共聚聚丙烯40-60份，聚烯烃弹性体5-50份，Fe2O3磁性粉末20-50份，金属的粉末氧化物5-15份，光稳定剂0.5-1，耐磨剂1-5份，颜料1-15份，加入挤出机，经挤出机混合、熔融挤出、压光、冷却、卷曲制成改性TPO膜片材；
(3)TPO基材制备：将改性TPO膜片材背面通过辊筒加热到110～180℃，将聚苯乙烯泡沫的表面通过辊筒或红外线加热到80～100℃，在压力为2～6MPa下将所述改性TPO膜片材与聚苯乙烯泡沫熔接复合在一起，得到TPO基材；
(4)表面处理：对上述制得的TPO基材的上表面进行电晕处理，在其表面涂覆底面处理剂，烘干后再涂覆表面处理剂，再次烘干，然后冷却；
本发明的有益效果是：通过优化TPO膜的原料及其配比，采用硫化TPO，其在吸附时不变形，花纹稳定性好，并且阻燃性好、耐热、耐候性好；同时加入嵌段共聚聚丙烯，起到花纹保持不变的作用，尺寸稳定性好；添加Fe2O3以及金属氧化物粉末，能够停止对胶黏剂的使用，利用金属氧化物及其粉末的可磁化性进行装修；并加入光稳定剂，能够防止阳光照射产生的光老化；上述原料通过挤出成型方式获得改性TPO膜片材，并与聚苯乙烯泡沫热复合获得的TPO基材，同时对TPO基材进行表面处理，使获得的TPO革具有磁性、阻燃性好、耐高低温、低气味、耐候性、环保可回收、加工性好、耐刮擦性、合格率高、成本低且与骨架粘结性好的优点。
附图说明
图1为一种磁性阻燃环保型TPO合成革的侧面图
图中：1-耐刮涂层；2-改性TPO膜；3-聚苯乙烯泡沫；4-磁性吸附层
具体实施方式
实例一：
(1)Fe2O3粉末、金属的粉末氧化物的聚合改性：采用原为聚合的方法制备外聚丙烯-金属粉末的改性物。
(2)改性TPO膜制备：嵌段共聚聚丙烯40份，聚烯烃弹性体15份，Fe2O3磁性粉末20份，金属的粉末氧化物5份，光稳定剂0.5份，耐磨剂1.5份，颜料2份，加入挤出机，经挤出机混合、熔融挤出、压光、冷却、卷曲制成改性TPO膜片材；
(3)TPO基材制备：将改性TPO膜片材背面通过辊筒加热到120℃，将聚苯乙烯泡沫的表面通过辊筒或红外线加热到80℃，在压力为3MPa下将所述改性TPO膜片材与聚苯乙烯泡沫熔接复合在一起，得到TPO基材；
(4)表面处理：对上述制得的TPO基材的上表面进行电晕处理，在其表面涂覆底面处理剂，烘干后再涂覆表面处理剂，再次烘干，然后冷却；
实例二：
(1)Fe2O3粉末、金属的粉末氧化物的聚合改性：采用原为聚合的方法制备外聚丙烯-金属粉末的改性物。
(2)改性TPO膜制备：嵌段共聚聚丙烯50份，聚烯烃弹性体10份，Fe2O3磁性粉末20份，金属的粉末氧化物10份，光稳定剂1，耐磨剂1.5份，颜料3份，加入挤出机，经挤出机混合、熔融挤出、压光、冷却、卷曲制成改性TPO膜片材；
(3)TPO基材制备：将改性TPO膜片材背面通过辊筒加热到130℃，将聚苯乙烯泡沫的表面通过辊筒或红外线加热到90℃，在压力为4MPa下将所述改性TPO膜片材与聚苯乙烯泡沫熔接复合在一起，得到TPO基材；
(4)表面处理：对上述制得的TPO基材的上表面进行电晕处理，在其表面涂覆底面处理剂，烘干后再涂覆表面处理剂，再次烘干，然后冷却；
实例三：
(1)Fe2O3粉末、金属的粉末氧化物的聚合改性：采用原为聚合的方法制备外聚丙烯-金属粉末的改性物。
(2)改性TPO膜制备：嵌段共聚聚丙烯60份，聚烯烃弹性体5份，Fe2O3磁性粉末25份，金属的粉末氧化物5份，光稳定剂1.5，耐磨剂1.5份，颜料1.5份，加入挤出机，经挤出机混合、熔融挤出、压光、冷却、卷曲制成改性TPO膜片材；
(3)TPO基材制备：将改性TPO膜片材背面通过辊筒加热到160℃，将聚苯乙烯泡沫的表面通过辊筒或红外线加热到100℃，在压力为6MPa下将所述改性TPO膜片材与聚苯乙烯泡沫熔接复合在一起，得到TPO基材；
(4)表面处理：对上述制得的TPO基材的上表面进行电晕处理，在其表面涂覆底面处理剂，烘干后再涂覆表面处理剂，再次烘干，然后冷却；
本发明揭示了一种磁性阻燃环保型TPO合成革及其制备方法，采用合理配比的原料成分、并通过挤出成型方式获得改性TPO膜片材，无需添加任何加工助剂，加工性能好、成本低；同时对TPO基材进行表面处理，使获得的TPO革具有可磁化性、阻燃性好、低雾性、低气味、环保可回收、加工性好、耐刮擦性、耐高低温、耐候性、合格率高、成本低且与骨架粘结性好的优点。以上所述仅为本发明的实施例，并非因此限制本发明的专利范围，凡是利用本发明说明书及附图内容所作的等效结构或等效流程变换，或直接或间接运用在其他相关的技术领域，均同理包括在本发明的专利保护范围内。
Claims (8)
1.一种磁性阻燃环保型TPO合成革与制备，其特征在于，包括TPO基材、位于所述TPO基材上表面的耐刮涂层、位于所述TPO基材下表面的具有磁性吸附的磁性层，所述TPO基材包括：改性TPO膜、和与所述改性TPO膜热压合在一起的聚苯乙烯泡沫，所述改性TPO膜包括如下重量份的成分：嵌段共聚聚丙烯40-60份，聚烯烃弹性体10-20份，Fe2O3粉末10-30份，金属的粉末氧化物0.5-5份，光稳定剂0.1-0.5，耐磨剂5-20份，颜料5-10份。
2.根据权利要求1所述的磁性阻燃环保型TPO合成革，其特征在于，所述改性TPO膜包括如下重量份的成分嵌段共聚聚丙烯40-60份，聚烯烃弹性体5-50份，Fe2O3磁性粉末20-50份，金属的粉末氧化物5-15份，光稳定剂0.5-1，耐磨剂1-5份，颜料1-15份。
3.根据权利要求1或2所述的磁性阻燃环保型TPO合成革，其特征在于，所述金属的粉末氧化物为锌、镁、钡、锶、铅金属的粉末氧化物。
4.根据权利要求1或2所述的磁性阻燃环保型TPO合成革，其特征在于，所述光稳定剂可以为水杨酸脂类、二苯甲酮类、苯并***类、三嗪类、取代丙烯晴类、草酰胺类、有机镍化合物类、受阻胺类。
5.根据权利要求1所述的磁性阻燃环保型TPO合成革，其特征在于，所述聚丙烯泡沫的厚度为：1.0mm、1.5mm、2.0mm、2.5mm或3.0mm，宽度为1000-5000mm，发泡率为15、20、25或30倍。
6.根据权利要求1所述的磁性阻燃环保型TPO合成革，其特征在于，磁性粉末为Fe2O3粉末。
7.改性TPO膜制备：其特征在于，包括如下步骤：
(1)Fe2O3粉末、金属的粉末氧化物的聚合改性：采用原为聚合的方法制备外聚丙烯-金属粉末的改性物。
(2)改性TPO膜制备：嵌段共聚聚丙烯40-60份，聚烯烃弹性体5-50 份，Fe2O3磁性粉末20-50份，金属的粉末氧化物5-15份，光稳定剂0.5-1，耐磨剂1-5份，颜料1-15份，加入挤出机，经挤出机混合、熔融挤出、压光、冷却、卷曲制成改性TPO膜片材；
(3)TPO基材制备：将改性TPO膜片材背面通过辊筒加热到110～180℃，将聚苯乙烯泡沫的表面通过辊筒或红外线加热到80～100℃，在压力为2～6MPa下将所述改性TPO膜片材与聚苯乙烯泡沫熔接复合在一起，得到TPO基材；
(4)表面处理：对上述制得的TPO基材的上表面进行电晕处理，在其表面涂覆底面处理剂，烘干后再涂覆表面处理剂，再次烘干，然后冷却。
8.根据权利要求6所述的磁性阻燃环保型TPO合成革的制备方法，其特征在于，所述步骤(2)中，嵌段共聚聚丙烯40-60份，聚烯烃弹性体5-50份，Fe2O3磁性粉末20-50份，金属的粉末氧化物5-15份，光稳定剂0.5-1，耐磨剂1-5份，颜料1-15份。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910512799.5A CN110181910A (zh) | 2019-06-13 | 2019-06-13 | 一种磁性阻燃环保型tpo合成革与制备 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910512799.5A CN110181910A (zh) | 2019-06-13 | 2019-06-13 | 一种磁性阻燃环保型tpo合成革与制备 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110181910A true CN110181910A (zh) | 2019-08-30 |
Family
ID=67721537
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910512799.5A Pending CN110181910A (zh) | 2019-06-13 | 2019-06-13 | 一种磁性阻燃环保型tpo合成革与制备 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110181910A (zh) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005290707A (ja) * | 2004-03-31 | 2005-10-20 | Nichirei Magnet Kk | 防火磁性壁面材及びそれを用いた防火磁性壁 |
| KR20080031792A (ko) * | 2006-10-05 | 2008-04-11 | 제이에스알 가부시끼가이샤 | 적층체 |
| US20150147553A1 (en) * | 2013-11-27 | 2015-05-28 | Ultraflex Systems, Inc. | Printable Magnetic Receptive Composite Sheet and Method of Making |
| CN105907323A (zh) * | 2016-05-30 | 2016-08-31 | 苏州瑞高新材料有限公司 | 一种阻燃环保型tpo合成革及其制备方法 |
| CN106221155A (zh) * | 2016-08-04 | 2016-12-14 | 苏州锐特捷化工制品有限公司 | 一种磁性塑型石墨烯的功能外墙板材料及其制备方法 |
| CN109057235A (zh) * | 2018-08-28 | 2018-12-21 | 江苏肯帝亚木业有限公司 | 一种磁性自吸地板及其安装方法 |
-
2019
- 2019-06-13 CN CN201910512799.5A patent/CN110181910A/zh active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005290707A (ja) * | 2004-03-31 | 2005-10-20 | Nichirei Magnet Kk | 防火磁性壁面材及びそれを用いた防火磁性壁 |
| KR20080031792A (ko) * | 2006-10-05 | 2008-04-11 | 제이에스알 가부시끼가이샤 | 적층체 |
| US20150147553A1 (en) * | 2013-11-27 | 2015-05-28 | Ultraflex Systems, Inc. | Printable Magnetic Receptive Composite Sheet and Method of Making |
| CN105907323A (zh) * | 2016-05-30 | 2016-08-31 | 苏州瑞高新材料有限公司 | 一种阻燃环保型tpo合成革及其制备方法 |
| CN106221155A (zh) * | 2016-08-04 | 2016-12-14 | 苏州锐特捷化工制品有限公司 | 一种磁性塑型石墨烯的功能外墙板材料及其制备方法 |
| CN109057235A (zh) * | 2018-08-28 | 2018-12-21 | 江苏肯帝亚木业有限公司 | 一种磁性自吸地板及其安装方法 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104060500A (zh) | 一种环保型抗菌防潮壁纸 | |
| CN105113336B (zh) | 环保壁纸的生产方法 | |
| CN103233395A (zh) | 一种制作珠光浸渍胶膜装饰物的方法 | |
| CN103233565B (zh) | 一种纳米竹炭·硅藻泥的发泡浮雕墙基布及其制备工艺 | |
| CN104005236B (zh) | 窗帘用遮光涂层及其使用方法 | |
| CN105755800A (zh) | 一种热反射涂层布 | |
| CN104404831A (zh) | 一种抗菌发泡墙纸及其制备方法 | |
| CN104060498A (zh) | 一种环保型阻燃壁纸 | |
| WO2015058419A1 (zh) | 环保型服装革及其制备方法 | |
| CN101906189A (zh) | 马铃薯淀粉接枝乳液及其制备和应用 | |
| CN103144325A (zh) | 高强度环保装饰墙布的生产工艺 | |
| CN104074102B (zh) | 一种绿色抗菌阻燃壁纸 | |
| CN104074100B (zh) | 一种可变色的抗菌环保型壁纸 | |
| CN110181910A (zh) | 一种磁性阻燃环保型tpo合成革与制备 | |
| CN105949805B (zh) | 一种具有空气净化调湿功能的内墙涂料卷材及其制备方法 | |
| CN205395301U (zh) | 一种抗高温防火树脂板 | |
| CN107603392A (zh) | 一种自动调节温度的水性环保变色艺术涂料及其制备方法 | |
| CN107841064A (zh) | 一种pvc台布塑料及其制备方法 | |
| CN105273542A (zh) | 一种阻燃乳胶涂料 | |
| CN104060499B (zh) | 一种透气性强的绿色环保型壁纸 | |
| CN203960676U (zh) | 一种可变色的抗菌环保型壁纸 | |
| CN106193484A (zh) | 一种湿敏变色墙纸及其制备工艺 | |
| CN203499173U (zh) | 一种稳定型室内墙面装饰材料 | |
| CN206217265U (zh) | 一种彩色防火复合橡塑绝热材料 | |
| CN208072822U (zh) | 一种可灭火的装饰板 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |