CN110165249A - A kind of hydrogen fuel cell air inlet humidifying device - Google Patents

A kind of hydrogen fuel cell air inlet humidifying device Download PDF

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Publication number
CN110165249A
CN110165249A CN201910526361.2A CN201910526361A CN110165249A CN 110165249 A CN110165249 A CN 110165249A CN 201910526361 A CN201910526361 A CN 201910526361A CN 110165249 A CN110165249 A CN 110165249A
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CN
China
Prior art keywords
air inlet
fuel cell
pipe
water
connect
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Pending
Application number
CN201910526361.2A
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Chinese (zh)
Inventor
张学锋
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Potential Plus (beijing) Technology Co Ltd
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Potential Plus (beijing) Technology Co Ltd
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Priority to CN201910526361.2A priority Critical patent/CN110165249A/en
Publication of CN110165249A publication Critical patent/CN110165249A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H01M8/04119Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with simultaneous supply or evacuation of electrolyte; Humidifying or dehumidifying
    • H01M8/04126Humidifying
    • H01M8/04141Humidifying by water containing exhaust gases
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)

Abstract

The invention discloses a kind of hydrogen fuel cell air inlet humidifying devices, including fuel cell and humidifying device, the humidifying device includes exhaust condensing unit and water pumping atomising device, the exhaust condensing unit includes expansion cell and moisture separator, the expansion cell is connect with the fuel cell tubes, the moisture separator is connect with the expansion cell pipe, the atomising device that pumps includes the water tank for collecting the liquid water of moisture separator outflow, for improving the water pump and air inlet atomizer of sprayer injection pressure, the water tank is connect with the moisture separator pipe, the water pump is connect with the water tank pipe, the air inlet atomizer is connect with the water pump pipe, the air inlet atomizer is connected with the air inlet pipe of fuel cell, one end of the air inlet pipe is connect with compression air supply system pipe, the other end and combustion Expect cell tube connection, is provided with spraying import in the air inlet pipe.

Description

A kind of hydrogen fuel cell air inlet humidifying device
Technical field
The present invention relates to hydrogen fuel cell system technical fields, and in particular to a kind of hydrogen fuel cell air inlet humidifying device.
Background technique
Proton Exchange Membrane Fuel Cells run when, proton through proton exchange membrane by anode reach cathode be combined with oxonium ion for Water completes chemical reaction, discharges electric energy.Proton must have water as its carrier when passing through exchange membrane, and the content of water is too low will The phenomenon that generating dry film, and then influence whether the transmission of proton, it usually needs it is electric to entering using additional humidification auxiliary system The reaction gas of pond group carries out humidification processing to keep the water content of proton exchange membrane.
For the main humidifying method used in fuel cell system at present for outer humidification, outer humidification enters electricity in reaction gas It is humidified before pond, common outer humidifying method, which has, is bubbled humidification, direct liquid water injection, plate membrane humidification or hollow Tunica fibrosa humidification, enthalpy wheel humidification and porous media humidification etc..Humidification is bubbled since the outlet for being easy in water container causes liquid The case where state water is assembled, therefore be typically only used for testing indoor research;Liquid water injection method is that water is directly injected to gas In the middle, since the gas of fuel cell inlet is the gas that have passed through compression, water spray can be vaporized by directly carrying out atomization, simultaneously Gas has also obtained cooling, and it is at present in large-scale fuel cell body that using for this method, which needs mature technology as carrier, A kind of method being widely adopted in system, but the method needs special outfit water storage device, leads to fuel cell system volume Increase, while the cost for manufacturing and safeguarding will increase;The be humidified core component of method of enthalpy wheel is porous ceramics runner, by showing The water-absorbent material of covering absorbs the heat and moisture in exhaust.When dry air enters enthalpy wheel, the moisture in enthalpy wheel is steamed Hair band walks to realize that air inlet is humidified.The method technology mature, humidification amount can control, and take full advantage of the moisture in exhaust, But its quality is not easy to seal greatly, while outside energy being needed to drive;Porous media humidification utilizes the hair of micropore in porous media Spy uses, and condenses the moisture in exhaust in the side of porous plate with the cooling fuel cell exhaust of supply gas, and in capillary force Under the action of by the porous plate other side (supply air side), and diffuse into supply dry air realization and it humidified.Using more Moisture in the fuel cell exhaust of high temperature and humidity is directly passed to supply air and humidified by hole dielectric-slab, saves space, But moisturization effect is relatively difficult to guarantee.
The problem of humidifying method of relative maturity is primarily present at present is following two points: injecting water into intake or vapor increase first It is wet to need that water storage device is separately provided, cause volume, cost to increase, the more difficult application in vehicle fuel battery dynamical system;Its Secondary enthalpy wheel humidification or porous media humidification can be vented moisture using fuel cell, but moisturization effect is difficult to guarantee.
Summary of the invention
The purpose of the present invention is to solve shortcomings in the prior art, provide a kind of hydrogen fuel cell air inlet increasing Wet device, using condensed fuel battery exhaust in moisture and be pumped to inlet end to air inlet carry out humidification processing device, store Water pot stores fuel cell and is vented condensed water, sprays into fuel cell air inlet pipe by sprayer, is humidified, is solved to air inlet There are the problem of water source and moisturization effect are humidified in humidifying method, the small volume of whole system, convenient for dynamic in vehicle fuel battery It is used in Force system.
To achieve the goals above, the invention adopts the following technical scheme: a kind of hydrogen fuel cell air inlet humidifying device, packet Fuel cell and humidifying device are included, the humidifying device includes exhaust condensing unit and pumps atomising device, and the exhaust condenses Device includes expansion cell and moisture separator, and expansion cell can reduce the temperature and pressure of gas, further will row Condensate moisture in gas is liquid water, and moisture separator is gentle separated by the water in pipeline, and the gas after separating passes through outlet Pipe discharge, water enter among water tank, and the expansion cell is that pipe is connect with the fuel cell, the moisture separator It is connect with the expansion cell pipe, the atomising device that pumps includes the storage for collecting the liquid water of moisture separator outflow Water pot, water pump and air inlet atomizer for improving sprayer injection pressure, the water tank and the moisture separator pipe Connection, the water pump are connect with the water tank pipe, and the air inlet atomizer is connect with the water pump pipe, the air inlet atomizer Be connected with the air inlet pipe of fuel cell, air inlet atomizer by the water of liquid become atomization water, one end of the air inlet pipe with The connection of air supply system pipe is compressed, the other end is connect with fuel cell tubes, and spraying import, air inlet atomization are provided in the air inlet pipe Device is communicated by spraying import with air inlet pipe, and the water of atomization is mixed into air.
Preferably, the expansion cell is throttle valve or turbine, the effect of expansion cell is the temperature in order to reduce exhaust Degree and pressure, the pressure at expulsion of fuel cell are generally 0.2~0.4MPa, and temperature is 100 DEG C~150 DEG C, in this status condition Under, the washiness in escape pipe is to exist in gaseous form, is reduced by making temperature and pressure after expansion cell all, will be gone out Condensate moisture in tracheae is liquid water.
Preferably, the moisture separator is centrifugal water gas separating device, centrifugal water gas separating device can be by outlet Gas and aqueous water in pipe from finally pumping to further can collect get up to be stored in water tank by liquid water again Air inlet humidification is carried out to air inlet sprayer to air inlet pipe.
Preferably, the water pump provides electric energy by fuel cell, the effect of water pump is the injection in order to improve sprayer Pressure exports electrical energy drive motor by fuel cell, water pump is worked normally.
Preferably, the compression air supply system is one or more levels for air compressor, cooperate air cleaning unit, it can Gas source is provided for fuel cell, selects one or more levels for air compressor as needed.
Preferably, the spraying import is located at level-one between air compressor and fuel cell, or it is located at multistage confession The afterbody of air compressor is between air compressor and fuel cell or being located at multistage between air compressor, air inlet atomizer Purpose in order to which liquid water fog-like is sprayed into fuel cell air inlet, enhance moisturization effect, water spray position is located at air inlet pressure Between contracting machine and fuel cell inlet.For multi-stage compression air supply system, position of spraying water can be located at after afterbody compressor, It may be alternatively located between compound compressor.
The advantageous effects that the present invention has are: using the moisture in the exhaust of condensed fuel battery and being pumped to inlet end To air inlet carry out humidification processing device, water tank store fuel cell be vented condensed water, by sprayer spray into fuel cell into Tracheae is humidified to air inlet, solves the problems, such as be humidified in existing humidifying method water source and moisturization effect, is convenient for vehicle fuel Cell power systems use.
Detailed description of the invention
Fig. 1 is a kind of structural schematic diagram of hydrogen fuel cell air inlet humidifying device of the present invention;
Fig. 2 is a kind of structural schematic diagram of hydrogen fuel cell air inlet humidifying device specific embodiment of the present invention;
In figure: air cleaning unit 1, compression air supply system 2, air inlet pipe 3, spraying import 4, fuel cell 5, expansion cell 6, water Air separation 7, escape pipe 8, water tank 9, water pump 10, air inlet atomizer 11, radiator 12.
Specific embodiment
The present invention will be further described with reference to the accompanying drawing, by the following description of the embodiment, will more help In the public understanding present invention, but the specific embodiment given by applicant should can't be considered as to the technology of the present invention side The definition of the limitation of case, any pair of component or technical characteristic be changed or to overall structure make form and immaterial transformation It is regarded as protection scope defined by technical solution of the present invention.
Embodiment 1:
As shown in Figure 1, a kind of hydrogen fuel cell air inlet humidifying device, including fuel cell and humidifying device, the humidifying device Including exhaust condensing unit and atomising device is pumped, the exhaust condensing unit includes expansion cell 6 and moisture separator 7, Expansion cell can reduce the temperature and pressure of gas, be further liquid water, aqueous vapor separation by the condensate moisture in exhaust Device is gentle separated by the water in pipeline, and the gas after separating is discharged by escape pipe, and water enters among water tank, described swollen Swollen unit is that pipe is connect with the fuel cell 5, and the moisture separator is connect with the expansion cell pipe, the water pumping mist Disguise the water tank 9 set including for collecting the liquid water that moisture separator flows out, for improving sprayer injection pressure Water pump 10 and air inlet atomizer 11, the water tank are connect with the moisture separator pipe, the water pump and the water tank Pipe connection, the air inlet atomizer are connect with the water pump pipe, and the air inlet atomizer is connected with the air inlet pipe 3 of fuel cell It connects, the water of liquid is become the water of atomization by air inlet atomizer, and one end of the air inlet pipe is connect with compression air supply system pipe, another End is connect with fuel cell tubes, spraying import is provided in the air inlet pipe, air inlet atomizer passes through spraying import 4 and air inlet pipe It communicates, the water of atomization is mixed into air;The expansion cell is throttle valve or turbine, and the effect of expansion cell is to drop Low pressure at expulsion, the pressure at expulsion of fuel cell are generally 0.2~0.4MPa, and temperature is 100 DEG C~150 DEG C, in this status bar Under part, the washiness in exhaust pipe exists in gaseous form, is reduced by temperature, pressure after expansion cell, the water in exhaust pipe Divide and is condensed into liquid water;The moisture separator be centrifugal water gas separating device, centrifugal water gas separating device can will exhaust with Aqueous water is from so as to get up to be pumped to air inlet sprayer progress air inlet humidification for liquid water collection;The water pump is by fuel Battery provides electric energy, and the effect of water pump is the injection pressure in order to improve sprayer, and by fuel cell output electrical energy drive electricity Machine, so that pump working;The compression air supply system is one or more levels for air compressor, is mentioned for air compressor for fuel cell Air supply source selects one or more levels for air compressor as needed;The spraying import is located at level-one for air compressor and fuel Between battery, or positioned at multistage for air compressor afterbody between air compressor and fuel cell or being located at multistage supply Between air compressor, the purpose of air inlet atomizer is in order to spray into liquid water fog-like in fuel cell air inlet, enhancing humidification Effect sprays water position between inlet air compressor and fuel cell inlet.For multi-stage compression air supply system, spraying water position can After afterbody compressor, it may be alternatively located between compound compressor.
Embodiment 2:
As shown in Fig. 2, a kind of hydrogen fuel cell air inlet humidifying device, including fuel cell and humidifying device, the humidifying device Including exhaust condensing unit and atomising device is pumped, the exhaust condensing unit includes radiator 12, fuel cell exhaust stream warp Radiator reduces temperature, and condensate moisture is liquid in exhaust, and the water pumping atomising device includes for collecting moisture separator The water tank of the liquid water of outflow, water pump and air inlet atomizer for improving sprayer injection pressure, the water tank and institute The connection of moisture separator pipe is stated, the water pump is connect with the water tank pipe, and the air inlet atomizer and the water pump pipe connect It connects, the air inlet atomizer is connected with the air inlet pipe of fuel cell, one end of the air inlet pipe and compression air supply system Guan Lian It connects, the other end is connect with fuel cell tubes, and spraying import is provided in the air inlet pipe;The moisture separator is centrifugal Moisture separator, centrifugal water gas separating device can be by exhausts and aqueous water from so as to which liquid water collection gets up to be pumped to Air inlet sprayer carries out air inlet humidification;The water pump provides electric energy by fuel cell, and the effect of water pump is to improve sprayer Injection pressure, and by fuel cell export electrical energy drive motor so that pump working;The compression air supply system be level-one or Multistage provides gas source for air compressor, for air compressor for fuel cell, selects one or more levels for air compressor as needed; The spraying import is located at level-one between air compressor and fuel cell, or positioned at multistage for the afterbody of air compressor For between air compressor and fuel cell or being located at multistage between air compressor, the purpose of air inlet atomizer is in order to will be fog-like Liquid water spray into fuel cell air inlet in, enhance moisturization effect, water spray position be located at inlet air compressor and fuel cell inlet Between.For multi-stage compression air supply system, position of spraying water can be located at after afterbody compressor, may be alternatively located at compound compressor Between.
In the present embodiment, a kind of hydrogen fuel cell air inlet humidifying device is provided, utilizes the water in the exhaust of condensed fuel battery Divide and be pumped to the device that inlet end carries out humidification processing to air inlet, water tank stores fuel cell and is vented condensed water, by spraying Device sprays into fuel cell air inlet pipe, is humidified to air inlet, solves be humidified in existing humidifying method water source and moisturization effect Problem uses convenient for vehicle fuel battery dynamical system.
Certainly, the present invention can also have other various embodiments, without deviating from the spirit and substance of the present invention, Those skilled in the art can make various corresponding changes and modifications according to the present invention, but these it is corresponding change and Deformation all should fall within the scope of protection of the appended claims of the present invention.

Claims (6)

1. a kind of hydrogen fuel cell air inlet humidifying device, including fuel cell and humidifying device, which is characterized in that the humidification dress It sets including exhaust condensing unit and pumps atomising device, the exhaust condensing unit includes that expansion cell (6) separates dress with aqueous vapor It sets (7), the expansion cell is connect with the fuel cell (5) pipe, the moisture separator and the expansion cell Guan Lian It connects, the atomising device that pumps includes for collecting the water tank (9) for the liquid water that moisture separator flows out, for improving spray Day with fog sprays the water pump (10) and air inlet atomizer (11) of pressure, and the water tank is connect with the moisture separator pipe, institute It states water pump to connect with the water tank pipe, the air inlet atomizer is connect with the water pump pipe, the air inlet atomizer and fuel The air inlet pipe (3) of battery is connected, and one end of the air inlet pipe is connect with compression air supply system pipe, the other end and fuel cell tubes It connects, is provided with spraying import (4) in the air inlet pipe.
2. a kind of hydrogen fuel cell air inlet humidifying device according to claim 1, which is characterized in that the expansion cell is Throttle valve or turbine.
3. a kind of hydrogen fuel cell air inlet humidifying device according to claim 1, which is characterized in that the aqueous vapor separation Device is centrifugal water gas separating device.
4. a kind of hydrogen fuel cell air inlet humidifying device according to claim 1, which is characterized in that the water pump is by fuel Battery provides electric energy.
5. a kind of hydrogen fuel cell air inlet humidifying device according to claim 1, which is characterized in that compression gas supply system System is one or more levels for air compressor.
6. a kind of hydrogen fuel cell air inlet humidifying device according to claim 1, which is characterized in that the spraying import position It for air compressor and is fired in level-one for the afterbody between air compressor and fuel cell, or positioned at multistage for air compressor Expect between battery or is located at multistage between air compressor.
CN201910526361.2A 2019-06-18 2019-06-18 A kind of hydrogen fuel cell air inlet humidifying device Pending CN110165249A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114420976A (en) * 2021-12-29 2022-04-29 上海重塑能源科技有限公司 Intake air humidifying system for fuel cell
CN115966730A (en) * 2023-03-16 2023-04-14 江苏重塑能源科技有限公司 Fuel cell system with water spray humidification and control method
WO2023138855A1 (en) * 2022-01-19 2023-07-27 Rolls-Royce Plc Fuel cell system

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2624414Y (en) * 2003-06-05 2004-07-07 西安交通大学 Water-heat combined control device for fuel battery
CN1753223A (en) * 2004-09-24 2006-03-29 上海神力科技有限公司 High efficiency fuel battery humidification device
CN103787469A (en) * 2014-01-16 2014-05-14 中国航天员科研训练中心 Integrated organic wastewater treatment and energy recovery system
CN108448136A (en) * 2018-02-08 2018-08-24 清华大学 A kind of air gas supply humidification ICS intercooler system for Proton Exchange Membrane Fuel Cells
CN109167087A (en) * 2018-09-17 2019-01-08 新乡市特美特热控技术股份有限公司 Fuel cell air management system
CN109372775A (en) * 2018-11-20 2019-02-22 势加透博(北京)科技有限公司 A kind of two stages of compression air supply system of fuel cell
CN209860060U (en) * 2019-06-18 2019-12-27 势加透博(北京)科技有限公司 Air inlet humidifying device for hydrogen fuel cell

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2624414Y (en) * 2003-06-05 2004-07-07 西安交通大学 Water-heat combined control device for fuel battery
CN1753223A (en) * 2004-09-24 2006-03-29 上海神力科技有限公司 High efficiency fuel battery humidification device
CN103787469A (en) * 2014-01-16 2014-05-14 中国航天员科研训练中心 Integrated organic wastewater treatment and energy recovery system
CN108448136A (en) * 2018-02-08 2018-08-24 清华大学 A kind of air gas supply humidification ICS intercooler system for Proton Exchange Membrane Fuel Cells
CN109167087A (en) * 2018-09-17 2019-01-08 新乡市特美特热控技术股份有限公司 Fuel cell air management system
CN109372775A (en) * 2018-11-20 2019-02-22 势加透博(北京)科技有限公司 A kind of two stages of compression air supply system of fuel cell
CN209860060U (en) * 2019-06-18 2019-12-27 势加透博(北京)科技有限公司 Air inlet humidifying device for hydrogen fuel cell

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114420976A (en) * 2021-12-29 2022-04-29 上海重塑能源科技有限公司 Intake air humidifying system for fuel cell
WO2023138855A1 (en) * 2022-01-19 2023-07-27 Rolls-Royce Plc Fuel cell system
CN115966730A (en) * 2023-03-16 2023-04-14 江苏重塑能源科技有限公司 Fuel cell system with water spray humidification and control method

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