CN110157335A - It is a kind of used for rail vehicle with anti-corrosion, damping, the water paint of fire-proof function and preparation method thereof - Google Patents

It is a kind of used for rail vehicle with anti-corrosion, damping, the water paint of fire-proof function and preparation method thereof Download PDF

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Publication number
CN110157335A
CN110157335A CN201910615943.8A CN201910615943A CN110157335A CN 110157335 A CN110157335 A CN 110157335A CN 201910615943 A CN201910615943 A CN 201910615943A CN 110157335 A CN110157335 A CN 110157335A
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China
Prior art keywords
fire
damping
agent
corrosion
proof function
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Pending
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CN201910615943.8A
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Chinese (zh)
Inventor
郭俊
范国栋
李德斌
黄立志
李彩云
陈翔宇
郭海涛
贺玉平
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ZHUZHOU FEILU HIGH-TECH MATERIALS Co Ltd
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ZHUZHOU FEILU HIGH-TECH MATERIALS Co Ltd
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Priority to CN201910615943.8A priority Critical patent/CN110157335A/en
Publication of CN110157335A publication Critical patent/CN110157335A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00Coating compositions based on unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/082Anti-corrosive paints characterised by the anti-corrosive pigment
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/082Anti-corrosive paints characterised by the anti-corrosive pigment
    • C09D5/084Inorganic compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20Diluents or solvents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds
    • C08K2003/321Phosphates
    • C08K2003/322Ammonium phosphate
    • C08K2003/323Ammonium polyphosphate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses it is a kind of it is used for rail vehicle with anti-corrosion, damping, fire-proof function water paint, include following component by mass fraction (%): aqueous damping lotion 20-30;Mono-component aqueous acrylate polymer emulsion 20-30 with fire-proof function;PH adjusting agent 0.1-0.5;Defoaming agent 0.3-0.6;Dispersing agent 0.3-0.5;Filler 38-63;Rust resisting pigment 5-8;Auxiliary rheological agents 1-3;Fungicide 0.2-0.6;Anti- flash rusting agent 0.1-0.6;Deionized water 5-10;The invention also includes the preparation methods of coating described above.The present invention is used as using the low smell aqueous damping lotion of low Tg and the mono-component aqueous acrylate polymer emulsion blending with fire-proof function into film base material, it does not need plus coalescing agent can form a film, using water as solvent, ignition point relative to oil-based solvent system is higher, it is more fire retardant, VOC is lower, more environmentally friendly, while the two blending, so that film forming matrix system has both anti-corrosion, fire prevention, damps three-in-one function.

Description

It is a kind of used for rail vehicle with anti-corrosion, damping, the water paint of fire-proof function and its system Preparation Method
Technical field
The present invention relates to a kind of coating and preparation method thereof, and in particular to one kind is used for rail vehicle to be had anti-corrosion, damping, prevent The water paint and preparation method thereof of fiery function.
Background technique
With the continuous improvement that current domestic people require trip comfort level, people imitate the damping noise reduction of the vehicles More stringent requirements are proposed for fruit, and domestic many automobiles, urban rail, motor-car, big passenger train all begin through the spraying of damping paint To carry out damping noise reduction.
Urban rail transit in China development is swift and violent, ends the first half of the year in 2016, in Chinese city rail transportation operation Journey has reached 3473.33km.On rail traffic vehicles are mainly runed in tunnel and are overhead, speed is fast and interior space is small operation Environmental quality determines that fire once occurs for vehicle, and passenger will face the danger bigger compared with superficial fire;Types of functionality by force and The nonmetallic materials of good decorative property are used on vehicle more and more, increase the wind of vehicle fire thereupon Danger;Therefore to the fire protection design of rail traffic vehicles, more stringent requirements are proposed.
And it is domestic at present, the chassis of rail vehicle generally uses two kinds of painting designs, and one kind is etching priming paint+aqueous damping Coating+closing finishing coat, another is then etching priming paint+aqueous fire-proof coating+closing finishing coat, both systems can not solve simultaneously Certainly sound insulation and noise reduction and the problem of fire prevention, so develop a kind of while having both anti-corrosion, damping, fireproof water-soluble multifunctional coating will be Very necessary, while the hot spot that will also be pursued as market, become the new trend of future development.
Summary of the invention
The technical problem to be solved by the present invention is to overcome the deficiencies in the prior art, provide a kind of used for rail vehicle with anti- Rotten, damping, the water paint of fire-proof function and preparation method thereof, it is using the low smell aqueous damping lotion of low Tg and has fire prevention Functional mono-component aqueous acrylate polymer emulsion blending is used as into film base material, does not need plus coalescing agent can be at Film, using water as solvent, the ignition point relative to oil-based solvent system is higher, it more difficult to fire, VOC is lower, more environmentally friendly, while the two Blending, so that film forming matrix system has both anti-corrosion, fire prevention, damps three-in-one function.
In order to solve the above technical problems, technical solution proposed by the present invention are as follows: a kind of used for rail vehicle with anti-corrosion, resistance Buddhist nun, fire-proof function water paint, include following component by mass fraction (%):
Aqueous damping lotion 20-30;
Mono-component aqueous acrylate polymer emulsion 20-30 with fire-proof function;
PH adjusting agent 0.1-0.5;
Defoaming agent 0.3-0.6;
Dispersing agent 0.3-0.5;
Filler 38-63;
Rust resisting pigment 5-8;
Auxiliary rheological agents 1-3;
Fungicide 0.2-0.6;
Anti- flash rusting agent 0.1-0.6;
Deionized water 5-10.
The further technical solution of the present invention are as follows: the filler includes following component by mass fraction (%):
Mica powder 5-10;
Cenosphere 5-10;
Melamine 6-9;
Pentaerythrite 9-12;
Ammonium polyphosphate 9-12;
Diatomite 1-5;
Expansible graphite 3-5;
Aluminium triphosphate 5-8.
Further, the pH adjusting agent is ammonium hydroxide or ammonia.
Further, the Tg of the aqueous damping lotion is -20~0 °.
Further, the defoaming agent is DH-202 general defoaming agent, Tego Airex 902W defoaming agent, BYK-024 aqueous The combination of one or more of defoaming agent.
Further, the dispersing agent is POLYRON NC dispersing agent, TegoDispers 760W dispersing agent, EFKA PU The combination of one or more of 4010 AN dispersing agents.
Further, the rust resisting pigment is aluminium triphosphate, ZF02 zinc-iron powder Composite Anticorrosive Pigment Using, SN-S800 efficiently prevent One or more of the pigment that becomes rusty combines.
Further, the auxiliary rheological agents are 837 anti-settling rheological agents, the aqueous auxiliary rheological agents of RHEOLATE299, RHEOLATE The combination of one or more of aqueous auxiliary rheological agents of 350D;The fungicide is DEUADD MB-11 waterborne preservative;It is described anti- Flash rusting agent is one or both of the anti-flash rusting agent of SC2190Z type, A3601 sudden strain of a muscle erosion agent combination.
It is a kind of it is used for rail vehicle with anti-corrosion, damping, fire-proof function water paint preparation method, using above-mentioned rail Road vehicle use with anti-corrosion, damping, fire-proof function water paint component, and including following operating procedure:
1) aqueous damping lotion and mono-component aqueous acrylate polymer emulsion are added in dispersion tank and are dispersed with stirring uniformly Afterwards, the pH value that pH adjusting agent adjustment mixed emulsion is added is 9.5-10;
2) defoaming agent and dispersing agent is added in the mixed emulsion after adjusting pH to step 1), is dispersed with stirring 20-30min, makes System is uniformly dispersed;
3) filler, rust resisting pigment and auxiliary rheological agents are added in gained system into step 2), and stir evenly, then add again Enter fungicide and anti-flash rusting agent, the consistency that mixed system is adjusted with deionized water is 8-14cm, is finally ground to carefully with colloid mill Discharge packaging after degree is qualified.
Further, the step 1), 2) and 3) in temperature be no more than 50 DEG C, it is broken to will appear water-based emulsion more than 50 DEG C Newborn phenomenon, step 1), 2) and 3) in mixing speed be 1000-1200r/min.
Compared with the prior art, the advantages of the present invention are as follows:
The present invention is poly- using the low smell aqueous damping lotion of low Tg and the mono-component aqueous acrylic acid with fire-proof function It closes object latex blend to be used as into film base material, does not need plus coalescing agent can form a film, it is molten relative to oiliness using water as solvent The ignition point of agent system is higher, it more difficult to fire, VOC is lower, more environmentally friendly, while the two blending so that film forming matrix system have both it is anti- Corruption prevents fires, damps three-in-one function.
Specific embodiment
To facilitate the understanding of the present invention, present invention work more comprehensively, is meticulously described below in conjunction with preferred embodiment, But the protection scope of the present invention is not limited to the following specific embodiments.
It is a kind of it is used for rail vehicle with anti-corrosion, damping, fire-proof function water paint, by mass fraction (%) including as follows Component (as shown in table 1):
Table 1: the present embodiment it is used for rail vehicle with anti-corrosion, damping, fire-proof function water paint component
It is above-mentioned it is used for rail vehicle with anti-corrosion, damping, fire-proof function water paint the preparation method comprises the following steps: serial number is hindered 1000-1200r/min high-speed stirred point in dispersion tank is added in damping paint lotion 0928, EXP-5510 acrylate polymer emulsion It dissipates uniformly, it is 9.5-10 that DeuAdd MA-95, which is added, and adjusts pH value.While stirring be added serial number DH-202 versatility defoaming agent, POLYRONNC dispersing agent, 1000-1200r/min disperse 20-30 minutes, and system is made to be uniformly dispersed.GB-2 wind is added while stirring Select sericite in powder, 200 mesh cenospheres, melamine, pentaerythrite, ammonium polyphosphate, diatomite, expansible graphite, trimerization phosphorus Powder materials are sufficiently stirred in sour aluminium and the aqueous auxiliary rheological agents of RHEOLATE299,1000-1200r/min high-speed stirred 20-30min Uniformly, DEUADD MB-11 waterborne preservative, the anti-flash rusting agent of SC2190Z type is added, adjusts consistency to 8-14cm with deionized water, Fineness qualification, discharging packaging are ground to colloid mill.Temperature is no more than 50 DEG C in above-mentioned entire production process.
A series of performances are carried out to the above-mentioned resulting water paint used for rail vehicle with anti-corrosion, damping, fire-proof function Detection, acquired results are as shown in table 2 below:
Table 2: the resulting water paint used for rail vehicle with anti-corrosion, damping, fire-proof function of the present embodiment carries out a system Column performance test results
By above-mentioned performance detection structure it can be seen that properties can meet the requirement of fireproof coating, while again Good damping capacity and antiseptic property are had both, is the good damping of one kind, anti-corrosion, fire prevention three-in-one multifunctional coating.

Claims (10)

1. it is a kind of it is used for rail vehicle with anti-corrosion, damping, fire-proof function water paint, which is characterized in that press mass fraction (%) includes following component:
Aqueous damping lotion 20-30;
Mono-component aqueous acrylate polymer emulsion 20-30 with fire-proof function;
PH adjusting agent 0.1-0.5;
Defoaming agent 0.3-0.6;
Dispersing agent 0.3-0.5;
Filler 38-63;
Rust resisting pigment 5-8;
Auxiliary rheological agents 1-3;
Fungicide 0.2-0.6;
Anti- flash rusting agent 0.1-0.6;
Deionized water 5-10.
2. it is according to claim 1 it is used for rail vehicle with anti-corrosion, damping, fire-proof function water paint, feature exists In the filler includes following component by mass fraction (%):
Mica powder 5-10;
Cenosphere 5-10;
Melamine 6-9;
Pentaerythrite 9-12;
Ammonium polyphosphate 9-12;
Diatomite 1-5;
Expansible graphite 3-5;
Aluminium triphosphate 5-8.
3. it is according to claim 1 or 2 it is used for rail vehicle with anti-corrosion, damping, fire-proof function water paint, feature It is, the pH adjusting agent is ammonium hydroxide or ammonia.
4. it is according to claim 1 or 2 it is used for rail vehicle with anti-corrosion, damping, fire-proof function water paint, feature It is, the Tg of the aqueous damping lotion is -20~0 °.
5. it is according to claim 1 or 2 it is used for rail vehicle with anti-corrosion, damping, fire-proof function water paint, feature It is, the defoaming agent is DH-202 general defoaming agent, in Tego Airex 902W defoaming agent, BYK-024 aqueous defoamer One or more combination.
6. it is according to claim 1 or 2 it is used for rail vehicle with anti-corrosion, damping, fire-proof function water paint, feature It is, the dispersing agent is POLYRON NC dispersing agent, TegoDispers 760W dispersing agent, 4010 AN of EFKA PU dispersion One or more of agent combination.
7. it is according to claim 1 or 2 it is used for rail vehicle with anti-corrosion, damping, fire-proof function water paint, feature It is, the rust resisting pigment is aluminium triphosphate, in ZF02 zinc-iron powder Composite Anticorrosive Pigment Using, SN-S800 high-efficiency rust-preventive pigment One or more combination.
8. it is according to claim 1 or 2 it is used for rail vehicle with anti-corrosion, damping, fire-proof function water paint, feature It is, the auxiliary rheological agents are 837 anti-settling rheological agents, the aqueous auxiliary rheological agents of RHEOLATE299, RHEOLATE 350D aqueous flow Become the combination of one or more of auxiliary agent;The fungicide is DEUADD MB-11 waterborne preservative;The anti-flash rusting agent is One or both of erosion agent combination is dodged in the anti-flash rusting agent of SC2190Z type, A3601.
9. it is a kind of it is used for rail vehicle with anti-corrosion, damping, fire-proof function water paint preparation method, which is characterized in that adopt Described in any one of the claims 1-8 it is used for rail vehicle with anti-corrosion, damping, fire-proof function water paint group Point, and including following operating procedure:
1) aqueous damping lotion and mono-component aqueous acrylate polymer emulsion are added in dispersion tank after being dispersed with stirring uniformly, are added The pH value for entering pH adjusting agent adjustment mixed emulsion is 9.5-10;
2) defoaming agent and dispersing agent is added in the mixed emulsion after adjusting pH to step 1), is dispersed with stirring 20-30min, makes system It is uniformly dispersed;
3) filler, rust resisting pigment and auxiliary rheological agents are added in gained system into step 2), and stir evenly, then add and kill Microbial inoculum and anti-flash rusting agent, the consistency that mixed system is adjusted with deionized water is 8-14cm, is finally ground to fineness with colloid mill and closes Discharge packaging after lattice.
10. it is according to claim 9 it is used for rail vehicle with anti-corrosion, damping, fire-proof function water paint preparation side Method, which is characterized in that the step 1), 2) and 3) in temperature be no more than 50 DEG C, step 1), 2) and 3) in mixing speed It is 1000-1200r/min.
CN201910615943.8A 2019-07-09 2019-07-09 It is a kind of used for rail vehicle with anti-corrosion, damping, the water paint of fire-proof function and preparation method thereof Pending CN110157335A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111607301A (en) * 2020-06-17 2020-09-01 湖南茵诺曼新材料有限公司 Modified acrylic acid water-based emulsion resin and preparation method and application thereof
CN113354998A (en) * 2021-06-25 2021-09-07 张家港市天源制漆涂装有限公司 Water-based fireproof damping coating
CN116179036A (en) * 2023-03-23 2023-05-30 青岛爱尔家佳新材料股份有限公司 Fireproof and noise-reduction water-based composite coating for rail transit vehicle

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CN106433352A (en) * 2016-10-31 2017-02-22 郑州安邦达水性材料有限公司 High-speed railway vehicle damping coating for spraying inner layer and preparation method of high-speed railway vehicle damping coating

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111607301A (en) * 2020-06-17 2020-09-01 湖南茵诺曼新材料有限公司 Modified acrylic acid water-based emulsion resin and preparation method and application thereof
CN113354998A (en) * 2021-06-25 2021-09-07 张家港市天源制漆涂装有限公司 Water-based fireproof damping coating
CN116179036A (en) * 2023-03-23 2023-05-30 青岛爱尔家佳新材料股份有限公司 Fireproof and noise-reduction water-based composite coating for rail transit vehicle
CN116179036B (en) * 2023-03-23 2024-03-12 青岛爱尔家佳新材料股份有限公司 Fireproof and noise-reduction water-based composite coating for rail transit vehicle

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