CN110157263A - A kind of environment-friendly type high abrasion high glaze water-based gloss oil and its preparation process - Google Patents
A kind of environment-friendly type high abrasion high glaze water-based gloss oil and its preparation process Download PDFInfo
- Publication number
- CN110157263A CN110157263A CN201910334137.3A CN201910334137A CN110157263A CN 110157263 A CN110157263 A CN 110157263A CN 201910334137 A CN201910334137 A CN 201910334137A CN 110157263 A CN110157263 A CN 110157263A
- Authority
- CN
- China
- Prior art keywords
- parts
- emulsion
- gloss oil
- high abrasion
- environment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of environment-friendly type high abrasion high glaze water-based gloss oil and its preparation processes; it is formulated by the raw material of following parts by weight meter: modified acroleic acid filming emulsion: 10-30 parts; modified acroleic acid not filming emulsion: 30-65 parts; elastic emulsion: 8-20 parts; waterborne film-forming auxiliary agent: 0.1-5 parts; colloid protective agent: 0.1-2 parts; bloom wax emulsion: 3-5 parts; high abrasion wax aqueous dispersion: 3-5 parts; defoaming agent: 0.1-0.5 parts; wetting agent: 0.5-1.5 parts, preservative: 0.1-0.5 parts, deionized water: 3-5 parts.The present invention has taken into account high abrasion and high glaze dual property while having had that flexibility is good, rate of drying is fast, conglutination-resistance printing is good, it can be used on singly recessed machine, the recessed machine of company, offset printing polisher, be a kind of nontoxic, pollution-free environment-friendly water-based gloss oil without noxious gas emission.
Description
Technical field
The present invention relates to water-based gloss oil fabricating technology fields, and in particular to a kind of printing industry, high molecular material neck
The aqueous, environmental protective high abrasion high glaze oil polish and its preparation process that domain, coating industry and Flexible-Packaging Industry use.
Background technique
With the enhancing of national related decree improved with Public environmental attitude, requirement of the existing market to product packaging is not
Disconnected to be promoted, the ingredient of traditional generally existing harm to the human body of solvent type oil polish contains alkylphenol compounds.In this feelings
Water-based gloss oil comes into being under condition, more and more extensive instead of traditional solvent type gloss oil.However circulate on the market at present
There are some defects, the gloss oil of high abrasion can not meet the requirement of high glaze for water-based gloss oil, and the gloss oil of high glaze can not meet again
The requirement of high abrasion.Water-based gloss oil technology of preparing all the time can not all solve this contradiction, lead to that satisfaction list can only be produced
The packaging material that the common substandard of one condition requires.
Summary of the invention
It is an object of the invention to overcome the shortcomings of the prior art, and provide a kind of environment-friendly type high abrasion high glaze water
Property gloss oil and its preparation process.
The object of the present invention is achieved by the following technical solutions: this aqueous light of environment-friendly type high abrasion high glaze
Oil is formulated by the raw material of following parts by weight meter: modified acroleic acid filming emulsion: 10-30 parts, modified acroleic acid does not form a film cream
Liquid: 30-65 parts, elastic emulsion: 8-20 parts, waterborne film-forming auxiliary agent: 0.1-5 parts, colloid protective agent: 0.1-2 parts, bloom wax cream
Liquid: 3-5 parts, high abrasion wax aqueous dispersion: 3-5 parts, defoaming agent: 0.1-0.5 parts, wetting agent: 0.5-1.5 parts, preservative: 0.1-
0.5 part, deionized water: 3-5 parts.
The modified acroleic acid filming emulsion is the one of modified pure acrylic acid filming emulsion or modified acroleic acid filming emulsion
Kind or two kinds of combinations, glass transition temperature are -15 DEG C~-30 DEG C, solid content 45-50%.
The modified acroleic acid filming emulsion is modified pure acrylic acid not filming emulsion or modified acroleic acid not filming emulsion
One or two kinds of combinations, glass transition temperature is 80 DEG C~150 DEG C, solid content 45-50%.
The elastic emulsion degree of cross linking is 2-8%, and glass transition temperature is -30 DEG C~0 DEG C, solid content 45-50%.
The waterborne film-forming auxiliary agent is one of ester alcohol 12 or dipropylene, ether solvent or a variety of groups
It closes.
The colloid protective agent is using polyvinyl alcohol or polyvinylpyrrolidone；The bloom wax emulsion is high density
Polythene wax emulsion, Fischer-Tropsch wax emulsion, the one or more of other artificial synthetic wax lotions, solid content 40-50%, partial size
Less than 0.1 micron.
The high abrasion wax aqueous dispersion is high density polyethylene waxes aqueous dispersion, other artificial synthetic wax aqueous dispersions
One or more combination, solid content 40-50%, partial size is between 6-8 microns.
The defoaming agent is defoaming agent, the polymer-type defoaming agent containing organosilicon or without organosilicon of aqueous mineral oils
One or more combination；The wetting agent is anion perfluorocarbon surface activating agent, two different pungent grade amber sodium sulfonate solutions, gathers
One or more combinations of ether modified polydimethyl alkanes aqueous wetting agent；The preservative is using Kathon CG preservative.
This environment-friendly type high abrasion of the present invention, high glaze water-based gloss oil preparation process, preparation process are as follows:
Step 1: by the modified acroleic acid filming emulsion in raw material, filming emulsion is not added modified acroleic acid by preset blending ratio
Enter in reactor, and being stirred with dispersion machine makes it be uniformly dispersed, rotating speed of agitator 500-700rpm/min, it is lasting to stir
Jitter time is 3-5 minutes；
Step 2: by the elastic emulsion in raw material, colloid protective agent, bloom wax emulsion, high abrasion wax aqueous dispersion, anti-corrosion
Agent is sequentially added in reactor by preset blending ratio, and continuing stirring makes it be uniformly dispersed, rotating speed of agitator 900-1500rpm/
Min, being persistently dispersed with stirring the time is 30-60 minutes；
Step 3: by the waterborne film-forming auxiliary agent in raw material, wetting agent and deionized water are successively slowly added to by preset blending ratio
In reactor, continuing stirring makes it be uniformly dispersed, and rotating speed of agitator 900-1500rpm/min, being persistently dispersed with stirring the time is
Revolving speed is turned down after 8-10 minutes to 150-300rpm/min, is added defoaming agent stirring 10 minutes or more and is eliminated foam；
Step 4: the viscosity of testing product, appearance, wear-resisting, glossiness, it is qualified after filtering be packed into packing container up to environmental protection
The water-based gloss oil finished product of type high abrasion high glaze.
The invention has the benefit that the present invention utilizes elastic emulsion and the high wear-resistant complementary raising of wax aqueous dispersion
The wear resistance of water-based gloss oil.Its glossiness is improved using modified acrylic acid emulsion and bloom wax emulsion, by reasonably matching
Than the contradictory problems to solve bloom Yu high abrasion quality inspection.The gloss oil abrasion-resistant degree that the present invention is prepared using the above scheme >=
600 times/4 pounds, 70 degree of glossiness ≈.
Specific embodiment
Below in conjunction with embodiment, the present invention will be described in detail:
Embodiment 1:
(1), environment-friendly type high abrasion high glaze water-based gloss oil formula (weight percent)
Modified acroleic acid filming emulsion: 10%
Modified acroleic acid not filming emulsion: 65%
Elastic emulsion: 8%
Waterborne film-forming auxiliary agent: 1%
Colloid protective agent: 1%
Bloom wax emulsion: 5%
High abrasion wax aqueous dispersion: 5%
Defoaming agent: 0.2%
Wetting agent: 0.5%
Preservative: 0.3%
Deionized water: 4%
(2), preparation method:
Step 1: by the modified acroleic acid filming emulsion in raw material, filming emulsion is not added modified acroleic acid by preset blending ratio
Enter in reactor, and being stirred with dispersion machine makes it be uniformly dispersed, rotating speed of agitator 500-700rpm/min, it is lasting to stir
Jitter time is 3-5 minutes.
Step 2: by the elastic emulsion in raw material, colloid protective agent, bloom wax emulsion, high abrasion wax aqueous dispersion, anti-corrosion
Agent is sequentially added in reactor by preset blending ratio, and continuing stirring makes it be uniformly dispersed, rotating speed of agitator 900-1500rpm/
Min, being persistently dispersed with stirring the time is 30-60 minutes.
Step 3: by the waterborne film-forming auxiliary agent in raw material, wetting agent and deionized water are successively slowly added to by preset blending ratio
In reactor, continuing stirring makes it be uniformly dispersed, and rotating speed of agitator 900-1500rpm/min, being persistently dispersed with stirring the time is
Revolving speed is turned down after 8-10 minutes to 150-300rpm/min, is added defoaming agent stirring 10 minutes or more and is eliminated foam.
Step 4: the viscosity of testing product, appearance, wear-resisting, glossiness, it is qualified after filtering be packed into packing container up to environmental protection
The water-based gloss oil finished product of type high abrasion high glaze.
Embodiment 2
(1), environment-friendly type high abrasion high glaze water-based gloss oil formula (weight percent)
Modified acroleic acid filming emulsion: 30%
Modified acroleic acid not filming emulsion: 30%
Elastic emulsion: 20%
Waterborne film-forming auxiliary agent: 2%
Colloid protective agent: 1%
Bloom wax emulsion: 5%
High abrasion wax aqueous dispersion: 5%
Defoaming agent: 0.3%
Wetting agent: 1.5%
Preservative: 0.2%
Deionized water: 5%
(2), preparation method: same as Example 1
Embodiment 3
(1), environment-friendly type high abrasion high glaze water-based gloss oil formula (weight percent)
Modified acroleic acid filming emulsion: 25%
Modified acroleic acid not filming emulsion: 45%
Elastic emulsion: 12%
Waterborne film-forming auxiliary agent: 2%
Colloid protective agent: 1%
Bloom wax emulsion: 5%
High abrasion wax aqueous dispersion: 5%
Defoaming agent: 0.1%
Wetting agent: 0.8%
Preservative: 0.1%
Deionized water: 4%
(2), preparation method: same as Example 1
Embodiment 4
(1), environment-friendly type high abrasion high glaze water-based gloss oil formula (weight percent)
Modified acroleic acid filming emulsion: 15%
Modified acroleic acid not filming emulsion: 47%
Elastic emulsion: 20%
Waterborne film-forming auxiliary agent: 5%
Colloid protective agent: 2%
Bloom wax emulsion: 3%
High abrasion wax aqueous dispersion: 3%
Defoaming agent: 0.5%
Wetting agent: 1%
Preservative: 0.5%
Deionized water: 3%
(2), preparation method: same as Example 1
Application implementation explanation
Gained environment-friendly type high abrasion high glaze water-based gloss oil in above embodiments, with 120LPI color spreading instrument in non-oil polish
One layer of gloss oil very thin in exhibition on black and white paper jam carries out the survey of gloss, anti-wear energy after varnish coating is sufficiently dry respectively
Examination, test result is as follows shown in table:
Above embodiments are used for illustrative purposes only, rather than limitation of the present invention, other any without departing from this hair
Modification, equivalent variations, modification, substitution, the combination made under bright spiritual essence and principle still fall within protection model of the invention
Within enclosing.
Claims (9)
1. a kind of environment-friendly type high abrasion high glaze water-based gloss oil, it is characterised in that: be formulated by the raw material of following parts by weight meter:
Modified acroleic acid filming emulsion: 10-30 parts, modified acroleic acid not filming emulsion: 30-65 parts, elastic emulsion: 8-20 parts, aqueous
Coalescing agent: 0.1-5 parts, colloid protective agent: 0.1-2 parts, bloom wax emulsion: 3-5 parts, high abrasion wax aqueous dispersion: 3-5 parts,
Defoaming agent: 0.1-0.5 parts, wetting agent: 0.5-1.5 parts, preservative: 0.1-0.5 parts, deionized water: 3-5 parts.
2. environment-friendly type high abrasion high glaze water-based gloss oil according to claim 1, it is characterised in that: the modified acroleic acid
Filming emulsion is one or two kinds of combinations of modified pure acrylic acid filming emulsion or modified acroleic acid filming emulsion, vitrifying conversion
Temperature is -15 DEG C~-30 DEG C, solid content 45-50%.
3. environment-friendly type high abrasion high glaze water-based gloss oil according to claim 1, it is characterised in that: the modified acroleic acid
Filming emulsion is that the one or two kinds of of filming emulsion do not combine modified pure acrylic acid for filming emulsion or modified acroleic acid, vitrifying
Inversion temperature is 80 DEG C~150 DEG C, solid content 45-50%.
4. environment-friendly type high abrasion high glaze water-based gloss oil according to claim 1, it is characterised in that: the elastic emulsion is handed over
Connection degree is 2-8%, and glass transition temperature is -30 DEG C~0 DEG C, solid content 45-50%.
5. environment-friendly type high abrasion according to claim 1, high glaze water-based gloss oil, it is characterised in that: the waterborne film-forming
Auxiliary agent is one of ester alcohol 12 or dipropylene, ether solvent or a variety of combinations.
6. environment-friendly type high abrasion high glaze water-based gloss oil according to claim 1, it is characterised in that: the colloid protective agent
Using polyvinyl alcohol or polyvinylpyrrolidone；The bloom wax emulsion is high density polyethylene waxes lotion, Fischer-Tropsch wax cream
The one or more of liquid, other artificial synthetic wax lotions, solid content 40-50%, partial size is less than 0.1 micron.
7. environment-friendly type high abrasion high glaze water-based gloss oil according to claim 1, it is characterised in that: the high abrasion wax water
Dispersion is the one or more combination of high density polyethylene waxes aqueous dispersion, other artificial synthetic wax aqueous dispersions, admittedly contain
Amount is 40-50%, and partial size is between 6-8 microns.
8. environment-friendly type high abrasion high glaze water-based gloss oil according to claim 1, it is characterised in that: the defoaming agent is water
The one or more combination of the defoaming agent of property mineral oils, polymer-type defoaming agent containing organosilicon or without organosilicon；It is described
Wetting agent is anion perfluorocarbon surface activating agent, two different pungent grade amber sodium sulfonate solutions, polyether-modified poly dimethyl alkanes water
One or more combinations of property wetting agent；The preservative is using Kathon CG preservative.
9. a kind of technique for preparing environment-friendly type high abrasion high glaze water-based gloss oil as described in claim 1, is characterized in that, preparation
Process is as follows:
Step 1: by the modified acroleic acid filming emulsion in raw material, filming emulsion is not added anti-modified acroleic acid by preset blending ratio
It answers in device, and being stirred with dispersion machine makes it be uniformly dispersed, rotating speed of agitator 500-700rpm/min is persistently dispersed with stirring
Time is 3-5 minutes；
Step 2: by the elastic emulsion in raw material, colloid protective agent, bloom wax emulsion, high abrasion wax aqueous dispersion, preservative pressed
Preset blending ratio sequentially adds in reactor, and continuing stirring makes it be uniformly dispersed, and rotating speed of agitator 900-1500rpm/min is held
It is continuous that be dispersed with stirring the time be 30-60 minutes；
Step 3: by the waterborne film-forming auxiliary agent in raw material, wetting agent and deionized water are successively slowly added to react by preset blending ratio
In device, continuing stirring makes it be uniformly dispersed, rotating speed of agitator 900-1500rpm/min, and being persistently dispersed with stirring the time is 8-10
Revolving speed is turned down after minute to 150-300rpm/min, is added defoaming agent stirring 10 minutes or more and is eliminated foam；
Step 4: the viscosity of testing product, appearance, wear-resisting, glossiness, it is qualified after filtering be packed into packing container up to environment-friendly type height
The water-based gloss oil finished product of wear-resisting high glaze.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910334137.3A CN110157263A (en) | 2019-04-24 | 2019-04-24 | A kind of environment-friendly type high abrasion high glaze water-based gloss oil and its preparation process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910334137.3A CN110157263A (en) | 2019-04-24 | 2019-04-24 | A kind of environment-friendly type high abrasion high glaze water-based gloss oil and its preparation process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110157263A true CN110157263A (en) | 2019-08-23 |
Family
ID=67639931
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910334137.3A Withdrawn CN110157263A (en) | 2019-04-24 | 2019-04-24 | A kind of environment-friendly type high abrasion high glaze water-based gloss oil and its preparation process |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110157263A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110406287A (en) * | 2019-08-28 | 2019-11-05 | 蚌埠市比优特包装印务有限责任公司 | The highlighted color face oil glazing process of one kind |
| CN114316722A (en) * | 2022-01-25 | 2022-04-12 | 北京金印联国际供应链管理有限公司 | High-wear-resistance water-based gloss oil and preparation method thereof |
| CN114922000A (en) * | 2022-06-17 | 2022-08-19 | 南京百聚科技有限公司 | Paper coating water-based varnish and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105524537A (en) * | 2016-01-19 | 2016-04-27 | 惠州市立美特环保油墨有限公司 | Environment-friendly high wear-resistant water-based polishing oil and preparation method thereof |
| CN108976945A (en) * | 2018-06-11 | 2018-12-11 | 杭州天龙油墨有限公司 | A kind of environment-friendly type high glaze, high abrasion water-based gloss oil and its preparation process |
-
2019
- 2019-04-24 CN CN201910334137.3A patent/CN110157263A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105524537A (en) * | 2016-01-19 | 2016-04-27 | 惠州市立美特环保油墨有限公司 | Environment-friendly high wear-resistant water-based polishing oil and preparation method thereof |
| CN108976945A (en) * | 2018-06-11 | 2018-12-11 | 杭州天龙油墨有限公司 | A kind of environment-friendly type high glaze, high abrasion water-based gloss oil and its preparation process |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110406287A (en) * | 2019-08-28 | 2019-11-05 | 蚌埠市比优特包装印务有限责任公司 | The highlighted color face oil glazing process of one kind |
| CN114316722A (en) * | 2022-01-25 | 2022-04-12 | 北京金印联国际供应链管理有限公司 | High-wear-resistance water-based gloss oil and preparation method thereof |
| CN114922000A (en) * | 2022-06-17 | 2022-08-19 | 南京百聚科技有限公司 | Paper coating water-based varnish and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108976945A (en) | A kind of environment-friendly type high glaze, high abrasion water-based gloss oil and its preparation process | |
| CN110157263A (en) | A kind of environment-friendly type high abrasion high glaze water-based gloss oil and its preparation process | |
| KR100364178B1 (en) | Water-base ballpoint ink having metallic glossy color | |
| CN113476344B (en) | Cosmetic composition, cosmetic, oil-in-water lip glaze and preparation method thereof | |
| EP0205961A2 (en) | Cosmetic composition | |
| CN105419606B (en) | A kind of aqueous polyurethane delustering agent and preparation method thereof | |
| JPH02169797A (en) | Improved aqueous over print varnish | |
| CN1290728A (en) | Water ink for plastic film relief printing and its producing method | |
| CN103183995A (en) | Water-based paint composition | |
| CN113462222A (en) | Water-based double-component matte hammer paint and preparation method thereof | |
| CN105238267A (en) | Stain-removing and furniture-servicing film plating oil and preparation method therefor | |
| TW460550B (en) | A W/O type dispersion ink | |
| US2536018A (en) | Coating compositions | |
| CN106368057B (en) | A kind of water-based lubricant and preparation method thereof | |
| CN104263076B (en) | Laughable red pair of PE ink of environment-friendly type and preparation method thereof | |
| CN108774915B (en) | High-temperature-resistant anti-adhesion finishing oil | |
| CN109679473B (en) | Environment-friendly water-based pencil color paint suitable for wood pencils and preparation method and application thereof | |
| CN111187541A (en) | Leather color-supplementing paste with injury-supplementing performance and simple operation and preparation method thereof | |
| US2719133A (en) | Oil-in-water, pigment-in-oil coating compositions and method of making them | |
| CN106245430B (en) | A kind of paper grade (stock) water-based lubricant and preparation method thereof | |
| CN114958093A (en) | Water-based organic color paste | |
| KR20100008815A (en) | Cosmetic composition for eye beauty makeup | |
| CN111481471A (en) | Water-resistant and sebum-resistant eyeliner and preparation method thereof | |
| CN115521672B (en) | Water-based environment-friendly aluminum foil varnish and preparation method thereof | |
| CN115197605B (en) | Printing ink with wrinkle texture effect and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20190823 |