CN110143799A - Inorganic traffic marking material of road and preparation method thereof - Google Patents

Inorganic traffic marking material of road and preparation method thereof Download PDF

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Publication number
CN110143799A
CN110143799A CN201910487563.0A CN201910487563A CN110143799A CN 110143799 A CN110143799 A CN 110143799A CN 201910487563 A CN201910487563 A CN 201910487563A CN 110143799 A CN110143799 A CN 110143799A
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inorganic
mixture
traffic marking
marking material
road
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刘研研
李云
王化
田兴友
陈林
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Hefei Institutes of Physical Science of CAS
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Hefei Institutes of Physical Science of CAS
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/10Lime cements or magnesium oxide cements
    • C04B28/105Magnesium oxide or magnesium carbonate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/60After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
    • C04B41/61Coating or impregnation
    • C04B41/65Coating or impregnation with inorganic materials
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01FADDITIONAL WORK, SUCH AS EQUIPPING ROADS OR THE CONSTRUCTION OF PLATFORMS, HELICOPTER LANDING STAGES, SIGNS, SNOW FENCES, OR THE LIKE
    • E01F9/00Arrangement of road signs or traffic signals; Arrangements for enforcing caution
    • E01F9/50Road surface markings; Kerbs or road edgings, specially adapted for alerting road users
    • E01F9/576Traffic lines
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials
    • C04B2111/00508Cement paints
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0075Uses not provided for elsewhere in C04B2111/00 for road construction
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/2038Resistance against physical degradation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/80Optical properties, e.g. transparency or reflexibility
    • C04B2111/82Coloured materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Road Signs Or Road Markings (AREA)

Abstract

The invention discloses inorganic traffic marking materials of a kind of road and preparation method thereof.The component and content of material are metal oxide 40-70 parts by weight, borate 5-20 parts by weight, dihydric phosphate 5-15 parts by weight, titanium dioxide 10-40 parts by weight, bead 10-40 parts by weight, grail 5-25 parts by weight, glass fibre 5-25 parts by weight, polyvinyl alcohol Water-based Water-repellent 1-3 parts by weight;Method is to stir after mixing metal oxide, borate, dihydric phosphate, titanium dioxide, bead, grail, glass fibre, obtains mixture;Later, water stirring is first added into mixture, then continues to stir after polyvinyl alcohol Water-based Water-repellent is added thereto, obtain intermediate product, intermediate product is placed in roadmarking template and is paved, after dry 30-40min, purpose product is made.It is good, environmentally protective with the compatibility of different kinds of roads, and it is convenient to construct, and is extremely easy to widely be commercialized the traffic marking as high performance graticule material applied to different kinds of roads.

Description

Inorganic traffic marking material of road and preparation method thereof
Technical field
The present invention relates to a kind of graticule material and preparation method, the inorganic traffic marking material of especially a kind of road and its system Preparation Method.
Background technique
Traffic marking refers on the road surface of road with lines, arrow, text, object marking, protuberant guide post and delineator Deng the mark to traffic informations such as traffic participant transmitting guidance, limitation, warnings;It is control and guidance traffic that it, which is acted on, can be with It is used cooperatively with mark, also can be used alone.Currently, domestic highway, I and II highway and city expressway, trunk Road is provided with reflecting traffic graticule by standard regulation, other roads also have traffic marking by standard setting as needed.These The traffic marking in road surface is delineated, because that need to be subjected to exposing to the sun and rain, wind and snow frost, by the pounding wear of vehicle, therefore to it Performance has strict requirements.In the recent period, people are made that unremitting effort, such as to obtain the traffic marking material of superior performance In " hot melt crack resistance type road traffic marking new material development and application ", Chunyan Luo, " highway communication science and technology " is on the 6th phase in 2017 A kind of disclosed traffic marking material and preparation method.The graticule material referred in this article is by thermoplastic resin, elastic resin and resists Split the composition such as auxiliary agent, pigment, filler, bead and titanium dioxide;When production, above-mentioned various raw materials are placed in hot melt reaction kettle and are added Heat is to 200 DEG C or so acquisition products.Though this product can be used as the material of traffic marking, there is shortcomings, firstly, producing The key reaction substance of object is organic resin, and the road of cement concrete pavement is mainly made of inorganic material, due to organic The problem of inorganic compatibility, being used by the graticule that product makes to the regular hour one system such as just will appear peeling, is broken, falls off Column problem;Secondly, containing organic matter in raw material, the pollution of environment is easily caused;Again, product not only needs during construction Will brush base oil, also need to heat product using pyroreaction kettle, not only consume energy, but also have safety problem.
Summary of the invention
The technical problem to be solved in the present invention in order to overcome the shortcomings in the prior art place, provide a kind of compatible with road Good, environmentally protective, the inorganic traffic marking material of convenient and fast road of constructing of property.
The invention solves another technical problem be that a kind of preparation of inorganic traffic marking material of above-mentioned road is provided Method.
To solve technical problem of the invention, used technical solution is the component of the inorganic traffic marking material of road And content are as follows:
Further improvement as the inorganic traffic marking material of road:
Preferably, metal oxide is the mixture of one or more of magnesia, aluminium oxide, calcium oxide.
Preferably, borate is one or both of sodium tetraborate, dipotassium tetraborate mixture.
Preferably, dihydric phosphate is potassium dihydrogen phosphate, ammonium dihydrogen phosphate, sodium dihydrogen phosphate, one in lithium dihydrogen phosphate Kind or two or more mixtures.
Preferably, titanium dioxide is ZR-110 rutile type titanium white, ZR-940 rutile type titanium white, ZR-945 rutile The mixture of one or more of type titanium dioxide.
To solve another technical problem of the invention, another used technical solution is the above-mentioned inorganic friendship of road Steps are as follows for the completion of the preparation method of logical graticule material:
Step 1, according to metal oxide, borate, dihydric phosphate, titanium dioxide, bead, grail, glass fibre Weight ratio be 40-70:5-20:5-15:10-40:10-40:5-25:5-25 ratio, by seven mixing after in 120-130r/ 2-4min is stirred under min, obtains mixture;
Step 2, water is first added into mixture and stirs 18-22s, then thereto after addition polyvinyl alcohol Water-based Water-repellent, Continue to stir 18-22s, wherein the weight ratio of water, polyvinyl alcohol Water-based Water-repellent and the glass fibre in mixture is 10-16: 1-3:5-25 obtains intermediate product;
Step 3, intermediate product is placed in roadmarking template after paving, the inorganic friendship of road is made in dry 30-40min Logical graticule material.
The further improvement of preparation method as the inorganic traffic marking material of road:
Preferably, after intermediate product is paved and before drying, 0.5-0.8kg/m is pressed thereon using air compressor2's Dosage sprayed glass pearl.
Preferably, metal oxide is the mixture of one or more of magnesia, aluminium oxide, calcium oxide.
Preferably, borate is one or both of sodium tetraborate, dipotassium tetraborate mixture.
Preferably, dihydric phosphate is potassium dihydrogen phosphate, ammonium dihydrogen phosphate, sodium dihydrogen phosphate, one in lithium dihydrogen phosphate Kind or two or more mixtures.
Preferably, titanium dioxide is ZR-110 rutile type titanium white, ZR-940 rutile type titanium white, ZR-945 rutile The mixture of one or more of type titanium dioxide.
Beneficial effect compared with the existing technology is:
First, using the purpose product of such raw materials size, component and content, both due to metal oxide and borate, The acid-base reaction of dihydric phosphate forms the cementitious material with viscous stickiness energy, and because the doping of titanium dioxide improves gelling material The whiteness and durability of material, due also to doped-glass pearl, grail and glass fibre improve the wearability and heavily fortified point of cementitious material Toughness promotes its stable structure, globality, more because the addition of polyvinyl alcohol Water-based Water-repellent improves drainage, enhances Skid resistance;The compatibility of purpose product and different kinds of roads is not only greatly improved, skid resistance is also improved.
Second, using purpose product obtained as traffic marking material, it is after actual measurement, whether inorganic --- coagulating cement Soil surface or organic --- bituminous pavement, purpose product all have fabulous compatibility, and durable, anti-skidding and environmentally friendly. Before purpose product is dry after the sprayed glass pearl of surface, retroreflection brightness coefficient > 300mcd ﹒ m-2﹒ lx-1
Third, preparation method is simple, scientific, efficient.It has not only been made good, environmentally protective with the compatibility of road, has constructed Convenient and fast purpose product --- the inorganic traffic marking material of road also adds non-skid property, more there is preparation and construction cost Cheap, safe feature;And then purpose product is made to be extremely easy to widely be commercialized as high performance graticule material applied to each The traffic marking of kind road.
Specific embodiment
Preferred embodiment of the invention is described in further detail below.
It buys from market or is voluntarily made first:
As the magnesia, aluminium oxide and calcium oxide of metal oxide, partial size is 0.3-0.5mm;
As the sodium tetraborate and dipotassium tetraborate of borate, partial size is 0.3-0.5mm;
As the potassium dihydrogen phosphate of dihydric phosphate, ammonium dihydrogen phosphate, sodium dihydrogen phosphate and lithium dihydrogen phosphate, partial size is equal For 0.3-0.5mm;
ZR-110 rutile type titanium white, ZR-940 rutile type titanium white and ZR-945 rutile-type as titanium dioxide Titanium dioxide, partial size are 0.7-1.1 μm;
The bead that partial size is 600-1000 μm;
The grail that partial size is 100-150 μm;
The glass fibre that length is 50-100 μm;
Polyvinyl alcohol Water-based Water-repellent;
Water.
Then:
Embodiment 1
The specific steps of preparation are as follows:
Step 1, according to metal oxide, borate, dihydric phosphate, titanium dioxide, bead, grail, glass fibre Weight ratio be 40:20:5:40:10:25:5 ratio, under 120r/min will stir 4min after seven mixing;Wherein, metal Oxide is magnesia, and borate is sodium tetraborate, and dihydric phosphate is potassium dihydrogen phosphate, and titanium dioxide is ZR-110 rutile-type Titanium dioxide obtains mixture.
Step 2, water is first added into mixture and stirs 18s, then continue after addition polyvinyl alcohol Water-based Water-repellent thereto Stir 22s;Wherein the weight ratio of water, polyvinyl alcohol Water-based Water-repellent and the glass fibre in mixture is 10:3:5, is obtained Between product.
Step 3, intermediate product is placed in roadmarking template after paving, the inorganic traffic mark of road is made in dry 30min Wire material.
Embodiment 2
The specific steps of preparation are as follows:
Step 1, according to metal oxide, borate, dihydric phosphate, titanium dioxide, bead, grail, glass fibre Weight ratio be 50:16:7.5:33:18:20:10 ratio, under 123r/min will stir 3.5min after seven mixing;Its In, metal oxide is magnesia, and borate is sodium tetraborate, and dihydric phosphate is potassium dihydrogen phosphate, titanium dioxide ZR-110 Rutile type titanium white obtains mixture.
Step 2, water is first added into mixture and stirs 19s, then continue after addition polyvinyl alcohol Water-based Water-repellent thereto Stir 21s;Wherein the weight ratio of water, polyvinyl alcohol Water-based Water-repellent and the glass fibre in mixture is 11.5:2.5:10, is obtained To intermediate product.
Step 3, intermediate product is placed in roadmarking template after paving, the inorganic traffic mark of road is made in dry 33min Wire material.
Embodiment 3
The specific steps of preparation are as follows:
Step 1, according to metal oxide, borate, dihydric phosphate, titanium dioxide, bead, grail, glass fibre Weight ratio be 55:12:10:25:25:15:15 ratio, under 125r/min will stir 3min after seven mixing;Wherein, golden Category oxide is magnesia, and borate is sodium tetraborate, and dihydric phosphate is potassium dihydrogen phosphate, and titanium dioxide is ZR-110 rutile Type titanium dioxide, obtains mixture.
Step 2, water is first added into mixture and stirs 20s, then continue after addition polyvinyl alcohol Water-based Water-repellent thereto Stir 20s;Wherein the weight ratio of water, polyvinyl alcohol Water-based Water-repellent and the glass fibre in mixture is 13:2:15, is obtained Between product.
Step 3, intermediate product is placed in roadmarking template after paving, the inorganic traffic mark of road is made in dry 35min Wire material.
Embodiment 4
The specific steps of preparation are as follows:
Step 1, according to metal oxide, borate, dihydric phosphate, titanium dioxide, bead, grail, glass fibre Weight ratio be 60:9:12.5:18:33:10:20 ratio, under 128r/min will stir 2.5min after seven mixing;Its In, metal oxide is magnesia, and borate is sodium tetraborate, and dihydric phosphate is potassium dihydrogen phosphate, titanium dioxide ZR-110 Rutile type titanium white obtains mixture.
Step 2, water is first added into mixture and stirs 21s, then continue after addition polyvinyl alcohol Water-based Water-repellent thereto Stir 19s;Wherein the weight ratio of water, polyvinyl alcohol Water-based Water-repellent and the glass fibre in mixture is 14.5:1.5:20, is obtained To intermediate product.
Step 3, intermediate product is placed in roadmarking template after paving, the inorganic traffic mark of road is made in dry 38min Wire material.
Embodiment 5
The specific steps of preparation are as follows:
Step 1, according to metal oxide, borate, dihydric phosphate, titanium dioxide, bead, grail, glass fibre Weight ratio be 70:5:15:10:40:5:25 ratio, under 130r/min will stir 2min after seven mixing;Wherein, metal Oxide is magnesia, and borate is sodium tetraborate, and dihydric phosphate is potassium dihydrogen phosphate, and titanium dioxide is ZR-110 rutile-type Titanium dioxide obtains mixture.
Step 2, water is first added into mixture and stirs 22s, then continue after addition polyvinyl alcohol Water-based Water-repellent thereto Stir 18s;Wherein the weight ratio of water, polyvinyl alcohol Water-based Water-repellent and the glass fibre in mixture is 16:1:25, is obtained Between product.
Step 3, intermediate product is placed in roadmarking template after paving, the inorganic traffic mark of road is made in dry 40min Wire material.
Select the mixed of one or more of magnesia, aluminium oxide, calcium oxide as metal oxide respectively again Object is closed, the di(2-ethylhexyl)phosphate as one or both of the sodium tetraborate of borate, dipotassium tetraborate mixture, as dihydric phosphate The mixture of one or more of hydrogen potassium, ammonium dihydrogen phosphate, sodium dihydrogen phosphate, lithium dihydrogen phosphate, as titanium dioxide One or both of ZR-110 rutile type titanium white, ZR-940 rutile type titanium white, ZR-945 rutile type titanium white Above mixture repeats above-described embodiment 1-5, the inorganic traffic marking material of road has equally been made.
If the retroreflection brightness coefficient for further improving purpose product, can be paved afterwards and before drying in intermediate product, 0.5-0.8kg/m is pressed thereon using air compressor2Dosage sprayed glass pearl.
Obviously, those skilled in the art can to inorganic traffic marking material of road of the invention and preparation method thereof into The various modification and variations of row are without departing from the spirit and scope of the present invention.If in this way, to these modifications and changes of the present invention Within the scope of the claims of the present invention and its equivalent technology, then the present invention is also intended to encompass these modification and variations and exists It is interior.

Claims (10)

1. a kind of inorganic traffic marking material of road, component and content are as follows:
2. the inorganic traffic marking material of road according to claim 1, it is characterized in that metal oxide is magnesia, oxidation The mixture of one or more of aluminium, calcium oxide.
3. the inorganic traffic marking material of road according to claim 1, it is characterized in that borate is sodium tetraborate, tetraboric acid One or both of potassium mixture.
4. the inorganic traffic marking material of road according to claim 1, it is characterized in that dihydric phosphate be potassium dihydrogen phosphate, The mixture of one or more of ammonium dihydrogen phosphate, sodium dihydrogen phosphate, lithium dihydrogen phosphate.
5. the inorganic traffic marking material of road according to claim 1, it is characterized in that titanium dioxide is ZR-110 rutile-type The mixture of one or more of titanium dioxide, ZR-940 rutile type titanium white, ZR-945 rutile type titanium white.
6. a kind of preparation method of the inorganic traffic marking material of road described in claim 1, it is characterised in that steps are as follows for completion:
Step 1, according to metal oxide, borate, dihydric phosphate, titanium dioxide, bead, grail, glass fibre weight Amount is than the ratio for 40-70:5-20:5-15:10-40:10-40:5-25:5-25, in 120-130r/min after seven are mixed Lower stirring 2-4min, obtains mixture;
Step 2, water is first added into mixture and stirs 18-22s, then continue after addition polyvinyl alcohol Water-based Water-repellent thereto 18-22s is stirred, wherein the weight ratio of water, polyvinyl alcohol Water-based Water-repellent and the glass fibre in mixture is 10-16:1-3: 5-25 obtains intermediate product;
Step 3, intermediate product is placed in roadmarking template after paving, the inorganic traffic mark of road is made in dry 30-40min Wire material.
7. the preparation method of the inorganic traffic marking material of road according to claim 6, it is characterized in that metal oxide is The mixture of one or more of magnesia, aluminium oxide, calcium oxide.
8. the preparation method of the inorganic traffic marking material of road according to claim 6, it is characterized in that borate is four boron One or both of sour sodium, dipotassium tetraborate mixture.
9. the preparation method of the inorganic traffic marking material of road according to claim 6, it is characterized in that dihydric phosphate is The mixture of one or more of potassium dihydrogen phosphate, ammonium dihydrogen phosphate, sodium dihydrogen phosphate, lithium dihydrogen phosphate.
10. the preparation method of the inorganic traffic marking material of road according to claim 6, it is characterized in that titanium dioxide is ZR- One or more of 110 rutile type titanium whites, ZR-940 rutile type titanium white, ZR-945 rutile type titanium white Mixture.
CN201910487563.0A 2019-06-05 2019-06-05 Inorganic traffic marking material of road and preparation method thereof Pending CN110143799A (en)

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Cited By (1)

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Publication number Priority date Publication date Assignee Title
CN112390615A (en) * 2020-11-18 2021-02-23 中国科学院合肥物质科学研究院 Inorganic wall fixing material and preparation method thereof

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JP2004052510A (en) * 2002-07-16 2004-02-19 Kazuo Saito White line for sign
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CN103508690A (en) * 2013-09-17 2014-01-15 安徽循环经济技术工程院 Novel inorganic binding material capable of bonding various substances and preparation method of novel inorganic binding material
CN104529378A (en) * 2014-12-08 2015-04-22 中国科学院合肥物质科学研究院 Novel water-resistant quick-hardened inorganic cementing material and preparation method thereof
CN106966687A (en) * 2017-04-07 2017-07-21 俞家欢 One kind is without strong cohesive force phosphate cement patching material of mobility rapid hardening and preparation method thereof
CN108751925A (en) * 2018-07-19 2018-11-06 贵州磷镁材料有限公司 A kind of roadmarking material and construction method based on phosphorus magnesium material

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004052510A (en) * 2002-07-16 2004-02-19 Kazuo Saito White line for sign
CN101284957A (en) * 2007-04-13 2008-10-15 张明德 Noctilucent nanometer coating of road marking lines and method for preparing same
CN103508690A (en) * 2013-09-17 2014-01-15 安徽循环经济技术工程院 Novel inorganic binding material capable of bonding various substances and preparation method of novel inorganic binding material
CN104529378A (en) * 2014-12-08 2015-04-22 中国科学院合肥物质科学研究院 Novel water-resistant quick-hardened inorganic cementing material and preparation method thereof
CN106966687A (en) * 2017-04-07 2017-07-21 俞家欢 One kind is without strong cohesive force phosphate cement patching material of mobility rapid hardening and preparation method thereof
CN108751925A (en) * 2018-07-19 2018-11-06 贵州磷镁材料有限公司 A kind of roadmarking material and construction method based on phosphorus magnesium material

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112390615A (en) * 2020-11-18 2021-02-23 中国科学院合肥物质科学研究院 Inorganic wall fixing material and preparation method thereof
CN112390615B (en) * 2020-11-18 2022-07-05 中国科学院合肥物质科学研究院 Inorganic wall fixing material and preparation method thereof

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Application publication date: 20190820