CN110105871A - A kind of preparation method pressing down ice coating using iron copper manganese Metal salt and nano silica as the super-hydrophobic photo-thermal of raw material - Google Patents
A kind of preparation method pressing down ice coating using iron copper manganese Metal salt and nano silica as the super-hydrophobic photo-thermal of raw material Download PDFInfo
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- CN110105871A CN110105871A CN201910483390.5A CN201910483390A CN110105871A CN 110105871 A CN110105871 A CN 110105871A CN 201910483390 A CN201910483390 A CN 201910483390A CN 110105871 A CN110105871 A CN 110105871A
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- 239000011248 coating agent Substances 0.000 title claims abstract description 109
- 238000000576 coating method Methods 0.000 title claims abstract description 109
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 85
- 239000000377 silicon dioxide Substances 0.000 title claims abstract description 63
- 230000003075 superhydrophobic effect Effects 0.000 title claims abstract description 63
- 238000002360 preparation method Methods 0.000 title claims abstract description 39
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 22
- 239000002184 metal Substances 0.000 title claims abstract description 22
- 239000002994 raw material Substances 0.000 title claims abstract description 22
- 150000003839 salts Chemical class 0.000 title claims abstract description 22
- BQCFCWXSRCETDO-UHFFFAOYSA-N [Fe].[Mn].[Cu] Chemical compound [Fe].[Mn].[Cu] BQCFCWXSRCETDO-UHFFFAOYSA-N 0.000 title claims abstract description 21
- 238000003825 pressing Methods 0.000 title claims abstract description 7
- 239000002105 nanoparticle Substances 0.000 claims abstract description 78
- 230000001629 suppression Effects 0.000 claims abstract description 50
- 239000007921 spray Substances 0.000 claims abstract description 45
- 239000000843 powder Substances 0.000 claims abstract description 33
- 239000011159 matrix material Substances 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 115
- 239000000243 solution Substances 0.000 claims description 51
- 229910052681 coesite Inorganic materials 0.000 claims description 41
- 229910052906 cristobalite Inorganic materials 0.000 claims description 41
- 229910052682 stishovite Inorganic materials 0.000 claims description 41
- 229910052905 tridymite Inorganic materials 0.000 claims description 41
- 238000005507 spraying Methods 0.000 claims description 30
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 26
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 25
- 229920005573 silicon-containing polymer Polymers 0.000 claims description 25
- 239000000758 substrate Substances 0.000 claims description 25
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 15
- 150000002823 nitrates Chemical class 0.000 claims description 15
- -1 Iron ion Chemical class 0.000 claims description 13
- 238000010438 heat treatment Methods 0.000 claims description 13
- 229960000583 acetic acid Drugs 0.000 claims description 12
- 229910052742 iron Inorganic materials 0.000 claims description 12
- 239000011259 mixed solution Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- 239000012362 glacial acetic acid Substances 0.000 claims description 11
- SXTLQDJHRPXDSB-UHFFFAOYSA-N copper;dinitrate;trihydrate Chemical compound O.O.O.[Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O SXTLQDJHRPXDSB-UHFFFAOYSA-N 0.000 claims description 10
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 claims description 10
- 239000000725 suspension Substances 0.000 claims description 10
- 238000010792 warming Methods 0.000 claims description 9
- CNFDGXZLMLFIJV-UHFFFAOYSA-L manganese(II) chloride tetrahydrate Chemical compound O.O.O.O.[Cl-].[Cl-].[Mn+2] CNFDGXZLMLFIJV-UHFFFAOYSA-L 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- RSKGMYDENCAJEN-UHFFFAOYSA-N hexadecyl(trimethoxy)silane Chemical compound CCCCCCCCCCCCCCCC[Si](OC)(OC)OC RSKGMYDENCAJEN-UHFFFAOYSA-N 0.000 claims description 7
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims description 6
- WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 claims description 6
- 239000012298 atmosphere Substances 0.000 claims description 6
- 229910001431 copper ion Inorganic materials 0.000 claims description 6
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 229910001437 manganese ion Inorganic materials 0.000 claims description 6
- 150000001450 anions Chemical class 0.000 claims description 4
- 238000000227 grinding Methods 0.000 claims description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- 239000002244 precipitate Substances 0.000 claims description 4
- 239000006228 supernatant Substances 0.000 claims description 4
- 150000002500 ions Chemical class 0.000 claims description 3
- 238000007711 solidification Methods 0.000 claims description 3
- 230000008023 solidification Effects 0.000 claims description 3
- 229910021380 Manganese Chloride Inorganic materials 0.000 claims 1
- 229910052738 indium Inorganic materials 0.000 claims 1
- 239000011565 manganese chloride Substances 0.000 claims 1
- 229940099607 manganese chloride Drugs 0.000 claims 1
- 235000002867 manganese chloride Nutrition 0.000 claims 1
- BZDIAFGKSAYYFC-UHFFFAOYSA-N manganese;hydrate Chemical compound O.[Mn] BZDIAFGKSAYYFC-UHFFFAOYSA-N 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 7
- 229910052724 xenon Inorganic materials 0.000 description 21
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 21
- 230000000694 effects Effects 0.000 description 15
- 235000013339 cereals Nutrition 0.000 description 10
- 238000002474 experimental method Methods 0.000 description 9
- 238000004088 simulation Methods 0.000 description 9
- 238000012360 testing method Methods 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 238000009776 industrial production Methods 0.000 description 4
- 239000000523 sample Substances 0.000 description 4
- 241000209094 Oryza Species 0.000 description 3
- 235000007164 Oryza sativa Nutrition 0.000 description 3
- 239000004411 aluminium Substances 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 235000009566 rice Nutrition 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000011017 operating method Methods 0.000 description 2
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000004886 process control Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000003760 hair shine Effects 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- ARYZCSRUUPFYMY-UHFFFAOYSA-N methoxysilane Chemical compound CO[SiH3] ARYZCSRUUPFYMY-UHFFFAOYSA-N 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
- B05D3/0254—After-treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/08—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/24—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/56—Three layers or more
- B05D7/58—No clear coat specified
- B05D7/584—No clear coat specified at least some layers being let to dry, at least partially, before applying the next layer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2518/00—Other type of polymers
- B05D2518/10—Silicon-containing polymers
- B05D2518/12—Ceramic precursors (polysiloxanes, polysilazanes)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Abstract
A kind of preparation method pressing down ice coating using iron copper manganese Metal salt and nano silica as the super-hydrophobic photo-thermal of raw material, the present invention relates to a kind of preparation methods of super-hydrophobic photo-thermal suppression ice coating.Solve the problem of existing suppression ice material result it is single can not reach simultaneously prevent freeze and freeze after can efficient deicing.Preparation method: one, solar energy optical-thermal powder is prepared;Two, nanoparticles solution is prepared;Three, solar heat matrix is prepared;Four, it sprays, obtains super-hydrophobic photo-thermal suppression ice coating.Preparation of the present invention for super-hydrophobic photo-thermal suppression ice coating.
Description
Technical field
The present invention relates to a kind of preparation methods of super-hydrophobic photo-thermal suppression ice coating.
Background technique
With the deterioration of global climate and the destruction of environment, the natural phenomena of icing certain fields of human society gradually
Develop into a problem, the formation of ice and snow often produces transportation, transmission line of electricity, aircraft, building and communal facility etc.
Raw tremendous influence.Therefore, new deicing, anti-icing system are researched and developed, avoid ice disaster caused by human society
Harm is of great significance.Wherein, the material for being related to pressing down ice is broadly divided into active deicing and passive deicing material, and every kind of material
Expect single effect, can not reach simultaneously prevent freeze and freeze after can efficiently deicing technical effect.
Summary of the invention
The invention solves existing suppression ice material result is single, can not reach simultaneously prevents from freezing and can efficiently remove after freezing
The problem of ice, and a kind of system for pressing down ice coating using iron copper manganese Metal salt and nano silica as the super-hydrophobic photo-thermal of raw material is provided
Preparation Method.
A kind of preparation method pressing down ice coating using iron copper manganese Metal salt and nano silica as the super-hydrophobic photo-thermal of raw material,
It is to sequentially include the following steps:
One, solar energy optical-thermal powder is prepared:
Nine water ferric nitrates, nitrate trihydrate copper, tetrahydrate manganese chloride and water are mixed, mixed solution is obtained, then by quality hundred
The sodium hydroxide solution that score is 3%~8% is instilled in container simultaneously and is stirred with mixed solution, obtains mixture, and be added dropwise
It is 10.5~11.5 that process control rate of addition, which keeps mixture pH, then mixture is stood 1h~4h at room temperature, discarded
Supernatant simultaneously filters, and is precipitated, and under conditions of temperature is 50 DEG C~120 DEG C, will precipitate dry 1h~3h, then grinds,
Finally with heating rate for 5 DEG C/min~20 DEG C/min, temperature is warming up to 600 DEG C~800 DEG C, and temperature be 600 DEG C~
Under 800 DEG C and air atmosphere, 1h~2h is calcined, solar energy optical-thermal powder is obtained;
The quality of the nine water ferric nitrates and the volume ratio of water are 1g:(10~20) mL;In the nine water ferric nitrates
Iron ion and nitrate trihydrate copper in copper ion molar ratio be 1:(0.9~2);Iron ion in the nine water ferric nitrates
Molar ratio with the manganese ion in tetrahydrate manganese chloride is 1:(0.9~2);The hydroxide that the mass percent is 3%~8%
Hydroxyl molal quantity in sodium solution is identical as the anion mol number in mixed solution;
Two, nanoparticles solution is prepared:
By gas phase SiO2Nano particle is added in hexamethylene, obtains gas phase SiO2Nanoparticles solution, by gas phase SiO2It receives
Rice grain solution ultrasonic disperse 5min~30min, obtains uniform SiO2Suspension, under room temperature and stirring condition, by 16
Alkyl trimethoxysilane and glacial acetic acid are added dropwise to uniform SiO2In suspension, stirs 1 day~2 days, obtain nanometer
Grain solution;
The gas phase SiO2The concentration of nanoparticles solution is 5mg/mL~25mg/mL;The gas phase SiO2Nanometer
The mass ratio of grain and hexadecyl trimethoxy silane is 1:(2~4);The gas phase SiO2The matter of nano particle and glacial acetic acid
Amount is than being 1:(0.5~1);
Three, solar heat matrix is prepared:
The curing agent of solar energy optical-thermal powder, dimethyl silicone polymer and dimethyl silicone polymer is mixed, then in ball
1h~3h is ground in grinding machine, obtains coating, and under conditions of being 100 μm~600 μm with coating thickness, coating is coated in substrate
On, obtain solar heat matrix;
The mass ratio of the solar energy optical-thermal powder and dimethyl silicone polymer is 1:(5~15);
Four, it sprays:
1., using nanoparticles solution as spray coating liquor, spray gun air pressure be 0.4MPa~0.7MPa and distance be 15cm~
Under conditions of 20cm, 15 layers~50 layers nanoparticle coating are sprayed in solar heat substrate upper surface, are then 100 DEG C in temperature
Under conditions of~135 DEG C, 10min~20min is heated, obtains the matrix after spraying for the first time;
2., using nanoparticles solution as spray coating liquor, spray gun air pressure be 0.4MPa~0.7MPa and distance be 15cm~
Under conditions of 20cm, the substrate upper surface after first time sprays continues to spray 15 layers~50 layers nanoparticle coating, then exists
Under conditions of temperature is 100 DEG C~135 DEG C, 20min~30min, the matrix after obtaining second of spraying are heated;
3., using nanoparticles solution as spray coating liquor, spray gun air pressure be 0.4MPa~0.7MPa and distance be 15cm~
Under conditions of 20cm, the substrate upper surface after spraying at second continues to spray 15 layers~50 layers nanoparticle coating, then exists
Under conditions of temperature is 100 DEG C~135 DEG C, 30min~50min is heated, obtains the matrix after third time sprays;
4., using nanoparticles solution as spray coating liquor, spray gun air pressure be 0.4MPa~0.7MPa and distance be 15cm~
Under conditions of 20cm, the substrate upper surface after third time sprays continues to spray 15 layers~50 layers nanoparticle coating, then exists
Under conditions of temperature is 100 DEG C~135 DEG C, solidify 1h~3h, obtains super-hydrophobic photo-thermal suppression ice coating.
Principle: single super hydrophobic surface is unable to reach excellent super-hydrophobic effect under high humidity, cryogenic conditions, but utilizes
The temperature that solar energy improves modified surface is a kind of method for effectively improving suppression ice performance.First by the nanoparticles solution of preparation
It is implanted in solar heat matrix, photo-thermal substrate is made to reach super-hydrophobic effect, assign its passive anti-icing performance.Simultaneously in sunlight
Under (or simulation sunlight) irradiation, surface temperature is increased using photothermal conversion effect, assigns coating active deicing by thermal compensation
Performance, to reach good suppression ice effect.
The beneficial effects of the present invention are:
The present invention is using iron copper manganese Metal salt and silica as raw material, the super-hydrophobic photo-thermal suppression ice coating being prepared, tool
There is the features such as economic cost is low, preparation process is simple, with short production cycle, photo-thermal effect is good, is a kind of novel suppression ice material.
1, use metal salt and silica as raw material, there are rich reserves, it is cheap and easy to get and environmental-friendly, easily
In recycling the features such as.
2, the photo-thermal super hydrophobic composite coating that the present invention is prepared, the contact angle with water are 157 °, and roll angle is 2 °;
In -15 DEG C of low temperature environments and certain Power Xenon Light (400mW/cm2) under irradiation, coating shows excellent super-hydrophobicity, heating
Amplitude keeps stable up to 40 DEG C or more, to reach suppression ice effect;It is 2000mW/cm using power in room temperature2Xenon lamp,
It adjusts the distance the super-hydrophobic photo-thermal suppression ice coating irradiation of xenon lamp 10cm, 185 DEG C can be warming up in the time of 180s, there is good liter
Temp effect;For the super-hydrophobic photo-thermal suppression ice coating coating of preparation in simulation sleet experiment in 25 minutes, surface does not form ice crystal,
It can achieve complete suppression ice effect under xenon lamp irradiation;Coating is under xenon lamp irradiation to the adhesion strength of ice down to 2.1KPa.
3, the photo-thermal super hydrophobic composite coating that the present invention is prepared can be widely applied to building appearance, industrial production
Anti-icing, pipeline suppression ice etc..
4, the method for the present invention feasibility is high, and operating procedure is simple, and capital investment is few, and short preparation period, reaction condition is mild,
Large-scale instrument and equipment is not needed, large-scale industrial production processing may be implemented, there is very broad application prospect, can be used as
The suppression ice coating of building or certain particular surfaces.
The present invention presses down ice coating using iron copper manganese Metal salt and nano silica as the super-hydrophobic photo-thermal of raw material for a kind of
Preparation method.
Detailed description of the invention
Fig. 1 is the photo in kind that super-hydrophobic photo-thermal prepared by embodiment one presses down ice coating;
Fig. 2 is that super-hydrophobic photo-thermal prepared by embodiment one presses down the electromicroscopic photograph that ice coating amplifies 50000 times;
Fig. 3 is that super-hydrophobic photo-thermal prepared by embodiment one presses down the electromicroscopic photograph that ice coating amplifies 100000 times;
Fig. 4 is the electromicroscopic photograph that the solar energy optical-thermal powder of one step 1 of embodiment preparation amplifies 60000 times;
Fig. 5 is the electromicroscopic photograph that the solar energy optical-thermal powder of one step 1 of embodiment preparation amplifies 80000 times;
Fig. 6 is the X-ray diffraction spectrogram of the solar energy optical-thermal powder of one step 1 of embodiment preparation;
Fig. 7 is the contact angle photo that super-hydrophobic photo-thermal prepared by embodiment one presses down ice coating and water;
Fig. 8 is that super-hydrophobic photo-thermal prepared by embodiment one presses down heating curve of the ice coating under xenon lamp irradiation;
Fig. 9 is the ice condition figure that aluminium sheet continues simulation sleet experiment in 25 minutes at low temperature;
Figure 10 is that super-hydrophobic photo-thermal suppression ice coating prepared by embodiment one continues simulation sleet experiment in 25 minutes at low temperature
Ice condition figure.
Specific embodiment
Specific embodiment 1: present embodiment is a kind of using iron copper manganese Metal salt and nano silica as the super thin of raw material
Water photo-thermal presses down the preparation method of ice coating, it is to sequentially include the following steps:
One, solar energy optical-thermal powder is prepared:
Nine water ferric nitrates, nitrate trihydrate copper, tetrahydrate manganese chloride and water are mixed, mixed solution is obtained, then by quality hundred
The sodium hydroxide solution that score is 3%~8% is instilled in container simultaneously and is stirred with mixed solution, obtains mixture, and be added dropwise
It is 10.5~11.5 that process control rate of addition, which keeps mixture pH, then mixture is stood 1h~4h at room temperature, discarded
Supernatant simultaneously filters, and is precipitated, and under conditions of temperature is 50 DEG C~120 DEG C, will precipitate dry 1h~3h, then grinds,
Finally with heating rate for 5 DEG C/min~20 DEG C/min, temperature is warming up to 600 DEG C~800 DEG C, and temperature be 600 DEG C~
Under 800 DEG C and air atmosphere, 1h~2h is calcined, solar energy optical-thermal powder is obtained;
The quality of the nine water ferric nitrates and the volume ratio of water are 1g:(10~20) mL;In the nine water ferric nitrates
Iron ion and nitrate trihydrate copper in copper ion molar ratio be 1:(0.9~2);Iron ion in the nine water ferric nitrates
Molar ratio with the manganese ion in tetrahydrate manganese chloride is 1:(0.9~2);The hydroxide that the mass percent is 3%~8%
Hydroxyl molal quantity in sodium solution is identical as the anion mol number in mixed solution;
Two, nanoparticles solution is prepared:
By gas phase SiO2Nano particle is added in hexamethylene, obtains gas phase SiO2Nanoparticles solution, by gas phase SiO2It receives
Rice grain solution ultrasonic disperse 5min~30min, obtains uniform SiO2Suspension, under room temperature and stirring condition, by 16
Alkyl trimethoxysilane and glacial acetic acid are added dropwise to uniform SiO2In suspension, stirs 1 day~2 days, obtain nanometer
Grain solution;
The gas phase SiO2The concentration of nanoparticles solution is 5mg/mL~25mg/mL;The gas phase SiO2Nanometer
The mass ratio of grain and hexadecyl trimethoxy silane is 1:(2~4);The gas phase SiO2The matter of nano particle and glacial acetic acid
Amount is than being 1:(0.5~1);
Three, solar heat matrix is prepared:
The curing agent of solar energy optical-thermal powder, dimethyl silicone polymer and dimethyl silicone polymer is mixed, then in ball
1h~3h is ground in grinding machine, obtains coating, and under conditions of being 100 μm~600 μm with coating thickness, coating is coated in substrate
On, obtain solar heat matrix;
The mass ratio of the solar energy optical-thermal powder and dimethyl silicone polymer is 1:(5~15);
Four, it sprays:
1., using nanoparticles solution as spray coating liquor, spray gun air pressure be 0.4MPa~0.7MPa and distance be 15cm~
Under conditions of 20cm, 15 layers~50 layers nanoparticle coating are sprayed in solar heat substrate upper surface, are then 100 DEG C in temperature
Under conditions of~135 DEG C, 10min~20min is heated, obtains the matrix after spraying for the first time;
2., using nanoparticles solution as spray coating liquor, spray gun air pressure be 0.4MPa~0.7MPa and distance be 15cm~
Under conditions of 20cm, the substrate upper surface after first time sprays continues to spray 15 layers~50 layers nanoparticle coating, then exists
Under conditions of temperature is 100 DEG C~135 DEG C, 20min~30min, the matrix after obtaining second of spraying are heated;
3., using nanoparticles solution as spray coating liquor, spray gun air pressure be 0.4MPa~0.7MPa and distance be 15cm~
Under conditions of 20cm, the substrate upper surface after spraying at second continues to spray 15 layers~50 layers nanoparticle coating, then exists
Under conditions of temperature is 100 DEG C~135 DEG C, 30min~50min is heated, obtains the matrix after third time sprays;
4., using nanoparticles solution as spray coating liquor, spray gun air pressure be 0.4MPa~0.7MPa and distance be 15cm~
Under conditions of 20cm, the substrate upper surface after third time sprays continues to spray 15 layers~50 layers nanoparticle coating, then exists
Under conditions of temperature is 100 DEG C~135 DEG C, solidify 1h~3h, obtains super-hydrophobic photo-thermal suppression ice coating.
The beneficial effect of present embodiment is:
For present embodiment using iron copper manganese Metal salt and silica as raw material, the super-hydrophobic photo-thermal being prepared presses down ice
Coating has the characteristics that economic cost is low, preparation process is simple, with short production cycle, photo-thermal effect is good, is a kind of novel suppression
Ice material.
1, use metal salt and silica as raw material, there are rich reserves, it is cheap and easy to get and environmental-friendly, easily
In recycling the features such as.
2, the photo-thermal super hydrophobic composite coating that present embodiment is prepared, the contact angle with water are 157 °, are rolled
Angle is 2 °;In -15 DEG C of low temperature environments and certain Power Xenon Light (400mW/cm2) under irradiation, coating shows excellent super-hydrophobic
Property, increasing extent of temperature keeps stable up to 40 DEG C or more, to reach suppression ice effect;It is 2000mW/cm using power in room temperature2
Xenon lamp, the super-hydrophobic photo-thermal suppression ice coating irradiation for the xenon lamp 10cm that adjusts the distance can be warming up to 185 DEG C in the time of 180s, have
Good temperature rise effect;In simulation sleet experiment in 25 minutes, surface does not have the super-hydrophobic photo-thermal suppression ice coating coating of preparation
Ice crystal is formed, can achieve complete suppression ice effect under xenon lamp irradiation;Coating under xenon lamp irradiation to the adhesion strength of ice down to
2.1KPa。
3, the photo-thermal super hydrophobic composite coating that present embodiment is prepared, can be widely applied to building appearance,
Industrial production is anti-icing, pipeline presses down ice etc..
4, present embodiment method feasibility is high, and operating procedure is simple, and capital investment is few, short preparation period, reaction
Mild condition does not need large-scale instrument and equipment, and large-scale industrial production processing may be implemented, have before being widely applied very much
Scape can be used as the suppression ice coating of building or certain particular surfaces.
Specific embodiment 2: the present embodiment is different from the first embodiment in that: gas phase described in step 2
SiO2The average grain diameter of nano particle is 200nm~300nm.It is other same as the specific embodiment one.
Specific embodiment 3: unlike one of present embodiment and specific embodiment one or two: institute in step 3
The mass ratio of the curing agent of the dimethyl silicone polymer and dimethyl silicone polymer stated is 10:1.Other and specific embodiment one
Or two is identical.
Specific embodiment 4: unlike one of present embodiment and specific embodiment one to three: in step 1
Under conditions of temperature is 80 DEG C~120 DEG C, dry 1.5h~3h will be precipitated, then ground, finally with heating rate be 10 DEG C/
Temperature is warming up to 700 DEG C~800 DEG C, and in the case where temperature is 700 DEG C~800 DEG C and air atmosphere, forged by min~20 DEG C/min
1h~2h is burnt, solar energy optical-thermal powder is obtained.It is other identical as specific embodiment one to three.
Specific embodiment 5: unlike one of present embodiment and specific embodiment one to four: institute in step 1
The quality for the nine water ferric nitrates stated and the volume ratio of water are 1g:(16~20) mL;In nine water ferric nitrate described in step 1
The molar ratio of copper ion in iron ion and nitrate trihydrate copper is 1:(1~2);Iron in nine water ferric nitrate described in step 1
The molar ratio of manganese ion in ion and tetrahydrate manganese chloride is 1:(1~2).It is other identical as specific embodiment one to four.
Specific embodiment 6: unlike one of present embodiment and specific embodiment one to five: institute in step 2
The gas phase SiO stated2The concentration of nanoparticles solution is 7mg/mL~25mg/mL;Gas phase SiO described in step 22Nano particle
Mass ratio with hexadecyl trimethoxy silane is 1:(2~3.5);Gas phase SiO described in step 22Nano particle and ice
The mass ratio of acetic acid is 1:(0.6~1).It is other identical as specific embodiment one or five.
Specific embodiment 7: unlike one of present embodiment and specific embodiment one to six: will in step 3
The curing agent of solar energy optical-thermal powder, dimethyl silicone polymer and dimethyl silicone polymer mixes, and then grinds in the ball mill
1h~2h obtains coating, under conditions of being 200 μm~600 μm with coating thickness, coating is coated in substrate, the sun is obtained
It can hot radical matter.It is other identical as specific embodiment one to six.
Specific embodiment 8: unlike one of present embodiment and specific embodiment one to seven: institute in step 3
The mass ratio of the solar energy optical-thermal powder and dimethyl silicone polymer stated is 1:(9~15).It is other with specific embodiment one to
Seven is identical.
Specific embodiment 9: unlike one of present embodiment and specific embodiment one to eight: will in step 2
Gas phase SiO2Nano particle is added in hexamethylene, obtains gas phase SiO2Nanoparticles solution, by gas phase SiO2Nanoparticles solution
Ultrasonic disperse 5min~20min obtains uniform SiO2Suspension, under room temperature and stirring condition, by cetyl trimethoxy
Base silane and glacial acetic acid are added dropwise to uniform SiO2In suspension, stirs 1 day~1.5 days, obtain nanoparticles solution.Its
It is identical as specific embodiment one to eight.
Specific embodiment 10: unlike one of present embodiment and specific embodiment one to nine: step 4 1. in
Heat 10min;Step 4 is 2. middle to heat 20min;Step 4 is 3. middle to heat 30min;Step 4 is 4. middle to solidify 1.5h.Other and tool
Body embodiment one to nine is identical.
Beneficial effects of the present invention are verified using following embodiment:
Embodiment one:
A kind of preparation method pressing down ice coating using iron copper manganese Metal salt and nano silica as the super-hydrophobic photo-thermal of raw material
It is to sequentially include the following steps:
One, solar energy optical-thermal powder is prepared:
Nine water ferric nitrates, nitrate trihydrate copper, tetrahydrate manganese chloride and water are mixed, mixed solution is obtained, then by quality hundred
The sodium hydroxide solution that score is 4.2% is instilled in container simultaneously and is stirred with mixed solution, obtains mixture, and process is added dropwise
Controlling rate of addition and keeping mixture pH is 11, then mixture is stood 3h at room temperature, discards supernatant liquid and filter, obtain
Precipitating will precipitate dry 1.5h, then grind under conditions of temperature is 80 DEG C, will finally with heating rate for 10 DEG C/min
Temperature is warming up to 800 DEG C, and in the case where temperature is 800 DEG C and air atmosphere, calcines 1h, obtain solar energy optical-thermal powder;
The quality of the nine water ferric nitrates and the volume ratio of water are 1g:16.5mL;Iron in the nine water ferric nitrates
The molar ratio of copper ion in ion and nitrate trihydrate copper is 1:1;Iron ion and four water chlorinations in the nine water ferric nitrates
The molar ratio of manganese ion in manganese is 1:1;The hydroxyl mole in sodium hydroxide solution that the mass percent is 4.2%
Number is identical as the anion mol number in mixed solution;
Two, nanoparticles solution is prepared:
By gas phase SiO2Nano particle is added in hexamethylene, obtains gas phase SiO2Nanoparticles solution, by gas phase SiO2It receives
Rice grain solution ultrasonic disperse 20min, obtains uniform SiO2Suspension, under room temperature and stirring condition, by cetyl three
Methoxy silane and glacial acetic acid are added dropwise to uniform SiO2In suspension, stirs 1 day, obtain nanoparticles solution;
The gas phase SiO2The concentration of nanoparticles solution is 7mg/mL;The gas phase SiO2Nano particle and 16
The mass ratio of alkyl trimethoxysilane is 1:3.5;The gas phase SiO2The mass ratio of nano particle and glacial acetic acid is 1:
0.6;
Three, solar heat matrix is prepared:
The curing agent of solar energy optical-thermal powder, dimethyl silicone polymer and dimethyl silicone polymer is mixed, then in ball
1h is ground in grinding machine, obtains coating, under conditions of being 200 μm with coating thickness, coating is coated in substrate, solar energy is obtained
Hot radical matter;
The mass ratio of the solar energy optical-thermal powder and dimethyl silicone polymer is 1:9;The substrate is aluminium sheet;
Four, it sprays:
1., using nanoparticles solution as spray coating liquor, under conditions of spray gun air pressure is 0.6MPa and distance is 15cm, too
The positive hot substrate upper surface of energy sprays 40 layers of nanoparticle coating, then under conditions of temperature is 100 DEG C, heats 10min, obtains
Matrix after spraying for the first time;
2., using nanoparticles solution as spray coating liquor, under conditions of spray gun air pressure is 0.6MPa and distance is 15cm,
Substrate upper surface after primary spraying continues to spray 40 layers of nanoparticle coating, then under conditions of temperature is 100 DEG C, heating
20min, the matrix after obtaining second of spraying;
3., using nanoparticles solution as spray coating liquor, under conditions of spray gun air pressure is 0.6MPa and distance is 15cm,
Substrate upper surface after secondary spraying continues to spray 40 layers of nanoparticle coating, then under conditions of temperature is 100 DEG C, heating
30min obtains the matrix after third time sprays;
4., using nanoparticles solution as spray coating liquor, under conditions of spray gun air pressure is 0.6MPa and distance is 15cm,
Substrate upper surface after spraying three times continues to spray 40 layers of nanoparticle coating, then under conditions of temperature is 100 DEG C, solidification
1.5h obtains super-hydrophobic photo-thermal suppression ice coating;
Gas phase SiO described in step 22The average grain diameter of nano particle is 200nm~300nm;
Dimethyl silicone polymer described in step 3 is DOW CORNING 184;Dimethyl silicone polymer described in step 3
Curing agent be 184 curing agent of DOW CORNING;The solidification of dimethyl silicone polymer described in step 3 and dimethyl silicone polymer
The mass ratio of agent is 10:1.
Spray gun in step 4 is Taiwan Pola 116A.
Fig. 1 is the photo in kind that super-hydrophobic photo-thermal prepared by embodiment one presses down ice coating;As seen from the figure, attached on fast black base bottom
One layer of translucent powdery white coating, illustrate nanoparticle successful deposition in photo-thermal substrate.
Fig. 2 is that super-hydrophobic photo-thermal prepared by embodiment one presses down the electromicroscopic photograph that ice coating amplifies 50000 times;Fig. 3 is to implement
Super-hydrophobic photo-thermal suppression ice coating prepared by example one amplifies 100000 times of electromicroscopic photograph;As seen from the figure, super-hydrophobic photo-thermal suppression ice applies
Layer surface has good micro-nano structure.The average grain diameter of single nanoparticle is 30nm~40nm, due to being added to hexadecane
Base trimethoxy silane is cross-linked with each other between particle, to construct higher surface roughness.
Fig. 4 is the electromicroscopic photograph that the solar energy optical-thermal powder of one step 1 of embodiment preparation amplifies 60000 times;Fig. 5 is real
The solar energy optical-thermal powder for applying the preparation of one step 1 of example amplifies 80000 times of electromicroscopic photograph;It can be seen that solar energy optical-thermal powder
Partial size average out to 80nm~100nm, it was demonstrated that powder made from present implementation has reached nano-scale particle size, to possess bigger
Specific surface area so that photothermal conversion efficiency is higher.
Fig. 6 is the X-ray diffraction spectrogram of the solar energy optical-thermal powder of one step 1 of embodiment preparation;The present embodiment method can
Purer iron copper manganese ternary metal oxide is prepared, the crystal form of powder is cubic spinel type.
Fig. 7 is the contact angle photo that super-hydrophobic photo-thermal prepared by embodiment one presses down ice coating and water;It is manufactured in the present embodiment
Super-hydrophobic photo-thermal suppression ice coating is 157 ° to the contact angle of water, and it is super-hydrophobic that spherical shape, which is presented, in water droplet on sample.And it is contacting
It is 2 ° that roll angle is measured in the experimentation of angle.
It is 2000mW/cm using power in room temperature2Xenon lamp, the super-hydrophobic photo-thermal of the xenon lamp 10cm that adjusts the distance presses down ice coating
180s is irradiated, test xenon lamp irradiates the ramp case of super-hydrophobic photo-thermal suppression ice coating, as shown in Figure 8.Fig. 8 is the preparation of embodiment one
Super-hydrophobic photo-thermal suppression ice coating xenon lamp irradiation under heating curve;As seen from the figure, the photo-thermal powder of present embodiment preparation
It can be warming up to 185 DEG C in the time of 180s, there is good temperature rise effect.
The simulated experiment of photo-thermal sleet is carried out to super-hydrophobic photo-thermal suppression ice coating: making row's drip nozzle, injection with 5 syringes
Device is connect with deionized water container, and control water droplet sinking speed is about 2.1m/s, and drop speed is maintained at 180 drops/minute, often the amount of dripping
Be maintained at 0.05mL, the temperature of deionized water container is about 0 DEG C, syringe nozzle and super-hydrophobic photo-thermal suppression ice coating between away from
From for 30cm.Super-hydrophobic photo-thermal suppression ice coating is placed on sloping platform, with respect to the horizontal plane with 30 ° of inclination angle, and
With xenon lamp (400mW/cm2) irradiation.Meanwhile xenon lamp presses down ice coating 50cm, vertical irradiation surface away from super-hydrophobic photo-thermal.By sample
It is previously positioned in chamber, is then -15 DEG C by chamber temperature setting, after twenty minutes, opens xenon lamp, opened in drip process
Surface is irradiated when the beginning.With infrared thermoviewer recording surface temperature, it is real that the simulation of photo-thermal sleet is carried out to super-hydrophobic photo-thermal suppression ice coating
It tests.Fig. 9 is the ice condition figure that aluminium sheet continues simulation sleet experiment in 25 minutes at low temperature.Figure 10 is the super of the preparation of embodiment one
Hydrophobic photo-thermal suppression ice coating continues the ice condition figure of simulation sleet experiment in 25 minutes at low temperature.As seen from the figure, embodiment one
For the super-hydrophobic photo-thermal suppression ice coating coating of preparation in simulation sleet experiment in 25 minutes, surface does not form ice crystal;In xenon lamp
It can achieve complete suppression ice effect under irradiation.
And under the conditions of above-mentioned frost rain simulated experiment, heating test is carried out to super-hydrophobic photo-thermal suppression ice coating surface ,-
15 DEG C of low temperature environment and certain Power Xenon Light (400mW/cm2) under irradiation, coating shows excellent super-hydrophobicity, increasing extent of temperature
Up to 40 DEG C or more, and keep stable, to reach suppression ice effect;
Adhesive force test is carried out to super-hydrophobic photo-thermal suppression ice coating: firstly, being by 1.5mL deionized water injection diameter
In the glass column of 1.2cm, it is placed on coating.Then, it places it in the insulating box that temperature is -25 DEG C, in coating surface
Form complete icicle.Glass column is removed after 2h, sample is placed in the trial zone equipped with tension sensor, by trial zone temperature
Degree is maintained at -20 DEG C, and the probe for being 0.7cm with diameter is measured in tension sensor with the constant speed of 1mm/s from coating table
The power of the icicle of face separation.The fracture maximum, force of measurement is recorded, and measures 5 parallel samples, to obtain average value (Fp).By Fp
Divided by contact area s, the adhesion strength of ice is calculated, contact area is 1.1304 × 10-4m2.Coating known to test shines in xenon lamp
The lower adhesion strength to ice is penetrated down to 2.1KPa.
Claims (10)
1. a kind of preparation method for pressing down ice coating using iron copper manganese Metal salt and nano silica as the super-hydrophobic photo-thermal of raw material,
It is characterized in that it is to sequentially include the following steps:
One, solar energy optical-thermal powder is prepared:
Nine water ferric nitrates, nitrate trihydrate copper, tetrahydrate manganese chloride and water are mixed, mixed solution is obtained, then by mass percent
Sodium hydroxide solution for 3%~8% is instilled in container simultaneously and is stirred with mixed solution, obtains mixture, and process is added dropwise
Controlling rate of addition and keeping mixture pH is 10.5~11.5, then mixture is stood 1h~4h at room temperature, discarded supernatant
Liquid simultaneously filters, and is precipitated, and under conditions of temperature is 50 DEG C~120 DEG C, will precipitate dry 1h~3h, then grinds, finally
With heating rate for 5 DEG C/min~20 DEG C/min, temperature is warming up to 600 DEG C~800 DEG C, and be 600 DEG C~800 DEG C in temperature
And under air atmosphere, 1h~2h is calcined, solar energy optical-thermal powder is obtained;
The quality of the nine water ferric nitrates and the volume ratio of water are 1g:(10~20) mL;Iron in the nine water ferric nitrates
The molar ratio of copper ion in ion and nitrate trihydrate copper is 1:(0.9~2);Iron ion and four in the nine water ferric nitrates
The molar ratio of manganese ion in water manganese chloride is 1:(0.9~2);The sodium hydroxide that the mass percent is 3%~8% is molten
Hydroxyl molal quantity in liquid is identical as the anion mol number in mixed solution;
Two, nanoparticles solution is prepared:
By gas phase SiO2Nano particle is added in hexamethylene, obtains gas phase SiO2Nanoparticles solution, by gas phase SiO2Nanometer
Grain solution ultrasonic disperse 5min~30min, obtains uniform SiO2Suspension, under room temperature and stirring condition, by cetyl
Trimethoxy silane and glacial acetic acid are added dropwise to uniform SiO2In suspension, stirs 1 day~2 days, it is molten to obtain nano particle
Liquid;
The gas phase SiO2The concentration of nanoparticles solution is 5mg/mL~25mg/mL;The gas phase SiO2Nano particle with
The mass ratio of hexadecyl trimethoxy silane is 1:(2~4);The gas phase SiO2The mass ratio of nano particle and glacial acetic acid
For 1:(0.5~1);
Three, solar heat matrix is prepared:
The curing agent of solar energy optical-thermal powder, dimethyl silicone polymer and dimethyl silicone polymer is mixed, then in ball mill
Middle grinding 1h~3h, obtains coating, under conditions of being 100 μm~600 μm with coating thickness, coating is coated in substrate, is obtained
To solar heat matrix;
The mass ratio of the solar energy optical-thermal powder and dimethyl silicone polymer is 1:(5~15);
Four, it sprays:
1., using nanoparticles solution as spray coating liquor, in spray gun air pressure be 0.4MPa~0.7MPa and distance is 15cm~20cm's
Under the conditions of, 15 layers~50 layers nanoparticle coating are sprayed in solar heat substrate upper surface, are then 100 DEG C~135 in temperature
Under conditions of DEG C, 10min~20min is heated, obtains the matrix after spraying for the first time;
2., using nanoparticles solution as spray coating liquor, in spray gun air pressure be 0.4MPa~0.7MPa and distance is 15cm~20cm's
Under the conditions of, the substrate upper surface after first time sprays continues to spray 15 layers~50 layers nanoparticle coating, is then in temperature
Under conditions of 100 DEG C~135 DEG C, 20min~30min, the matrix after obtaining second of spraying are heated;
3., using nanoparticles solution as spray coating liquor, in spray gun air pressure be 0.4MPa~0.7MPa and distance is 15cm~20cm's
Under the conditions of, the substrate upper surface after spraying at second continues to spray 15 layers~50 layers nanoparticle coating, is then in temperature
Under conditions of 100 DEG C~135 DEG C, 30min~50min is heated, obtains the matrix after third time sprays;
4., using nanoparticles solution as spray coating liquor, in spray gun air pressure be 0.4MPa~0.7MPa and distance is 15cm~20cm's
Under the conditions of, the substrate upper surface after third time sprays continues to spray 15 layers~50 layers nanoparticle coating, is then in temperature
Under conditions of 100 DEG C~135 DEG C, solidify 1h~3h, obtains super-hydrophobic photo-thermal suppression ice coating.
2. according to claim 1 a kind of using iron copper manganese Metal salt and nano silica as the suppression of the super-hydrophobic photo-thermal of raw material
The preparation method of ice coating, it is characterised in that gas phase SiO described in step 22The average grain diameter of nano particle be 200nm~
300nm。
3. according to claim 1 a kind of using iron copper manganese Metal salt and nano silica as the suppression of the super-hydrophobic photo-thermal of raw material
The preparation method of ice coating, it is characterised in that the solidification of dimethyl silicone polymer described in step 3 and dimethyl silicone polymer
The mass ratio of agent is 10:1.
4. according to claim 1 a kind of using iron copper manganese Metal salt and nano silica as the suppression of the super-hydrophobic photo-thermal of raw material
The preparation method of ice coating, it is characterised in that in step 1 under conditions of temperature is 80 DEG C~120 DEG C, dry 1.5h will be precipitated
~3h, then grinds, and finally with heating rate for 10 DEG C/min~20 DEG C/min, temperature is warming up to 700 DEG C~800 DEG C, and
In the case where temperature is 700 DEG C~800 DEG C and air atmosphere, 1h~2h is calcined, solar energy optical-thermal powder is obtained.
5. according to claim 1 a kind of using iron copper manganese Metal salt and nano silica as the suppression of the super-hydrophobic photo-thermal of raw material
The preparation method of ice coating, it is characterised in that the quality of nine water ferric nitrate described in step 1 and the volume ratio of water are 1g:(16
~20) mL;The molar ratio of the copper ion in iron ion and nitrate trihydrate copper in nine water ferric nitrate described in step 1 is 1:
(1~2);The molar ratio of the manganese ion in iron ion and tetrahydrate manganese chloride in nine water ferric nitrate described in step 1 is 1:(1
~2).
6. according to claim 1 a kind of using iron copper manganese Metal salt and nano silica as the suppression of the super-hydrophobic photo-thermal of raw material
The preparation method of ice coating, it is characterised in that gas phase SiO described in step 22The concentration of nanoparticles solution be 7mg/mL~
25mg/mL;Gas phase SiO described in step 22The mass ratio of nano particle and hexadecyl trimethoxy silane be 1:(2~
3.5);Gas phase SiO described in step 22The mass ratio of nano particle and glacial acetic acid is 1:(0.6~1).
7. according to claim 1 a kind of using iron copper manganese Metal salt and nano silica as the suppression of the super-hydrophobic photo-thermal of raw material
The preparation method of ice coating, it is characterised in that by solar energy optical-thermal powder, dimethyl silicone polymer and poly dimethyl in step 3
The curing agent of siloxanes mixes, and then grinds 1h~2h in the ball mill, obtains coating, with coating thickness for 200 μm~600 μm
Under conditions of, coating is coated in substrate, solar heat matrix is obtained.
8. according to claim 1 a kind of using iron copper manganese Metal salt and nano silica as the suppression of the super-hydrophobic photo-thermal of raw material
The preparation method of ice coating, it is characterised in that the quality of solar energy optical-thermal powder and dimethyl silicone polymer described in step 3
Than for 1:(9~15).
9. according to claim 1 a kind of using iron copper manganese Metal salt and nano silica as the suppression of the super-hydrophobic photo-thermal of raw material
The preparation method of ice coating, it is characterised in that by gas phase SiO in step 22Nano particle is added in hexamethylene, obtains gas phase
SiO2Nanoparticles solution, by gas phase SiO2Nanoparticles solution ultrasonic disperse 5min~20min, obtains uniform SiO2It suspends
Hexadecyl trimethoxy silane and glacial acetic acid are added dropwise to uniform SiO under room temperature and stirring condition by liquid2It suspends
In liquid, stirs 1 day~1.5 days, obtain nanoparticles solution.
10. according to claim 1 a kind of using iron copper manganese Metal salt and nano silica as the super-hydrophobic photo-thermal of raw material
Press down the preparation method of ice coating, it is characterised in that step 4 is 1. middle to heat 10min;Step 4 is 2. middle to heat 20min;Step 4 is 3.
Middle heating 30min;Step 4 is 4. middle to solidify 1.5h.
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