CN110098816A - A kind of piezo-electric resonator of narrow support frame high quality factor - Google Patents

A kind of piezo-electric resonator of narrow support frame high quality factor Download PDF

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Publication number
CN110098816A
CN110098816A CN201910380938.3A CN201910380938A CN110098816A CN 110098816 A CN110098816 A CN 110098816A CN 201910380938 A CN201910380938 A CN 201910380938A CN 110098816 A CN110098816 A CN 110098816A
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Prior art keywords
layer
air
substrate
quality factor
piezo
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CN201910380938.3A
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Chinese (zh)
Inventor
王萍
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Nanyang Institute of Technology
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Nanyang Institute of Technology
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Priority to CN201910380938.3A priority Critical patent/CN110098816A/en
Publication of CN110098816A publication Critical patent/CN110098816A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H03ELECTRONIC CIRCUITRY
    • H03HIMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
    • H03H3/00Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators
    • H03H3/007Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks
    • H03H3/02Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks for the manufacture of piezoelectric or electrostrictive resonators or networks
    • HELECTRICITY
    • H03ELECTRONIC CIRCUITRY
    • H03HIMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
    • H03H9/00Networks comprising electromechanical or electro-acoustic devices; Electromechanical resonators
    • H03H9/02Details
    • H03H9/05Holders; Supports
    • H03H9/0504Holders; Supports for bulk acoustic wave devices
    • H03H9/0509Holders; Supports for bulk acoustic wave devices consisting of adhesive elements
    • HELECTRICITY
    • H03ELECTRONIC CIRCUITRY
    • H03HIMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
    • H03H9/00Networks comprising electromechanical or electro-acoustic devices; Electromechanical resonators
    • H03H9/15Constructional features of resonators consisting of piezoelectric or electrostrictive material
    • H03H9/17Constructional features of resonators consisting of piezoelectric or electrostrictive material having a single resonator
    • H03H9/171Constructional features of resonators consisting of piezoelectric or electrostrictive material having a single resonator implemented with thin-film techniques, i.e. of the film bulk acoustic resonator [FBAR] type
    • H03H9/172Means for mounting on a substrate, i.e. means constituting the material interface confining the waves to a volume
    • H03H9/173Air-gaps
    • HELECTRICITY
    • H03ELECTRONIC CIRCUITRY
    • H03HIMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
    • H03H9/00Networks comprising electromechanical or electro-acoustic devices; Electromechanical resonators
    • H03H9/15Constructional features of resonators consisting of piezoelectric or electrostrictive material
    • H03H9/17Constructional features of resonators consisting of piezoelectric or electrostrictive material having a single resonator
    • H03H9/171Constructional features of resonators consisting of piezoelectric or electrostrictive material having a single resonator implemented with thin-film techniques, i.e. of the film bulk acoustic resonator [FBAR] type
    • H03H9/172Means for mounting on a substrate, i.e. means constituting the material interface confining the waves to a volume
    • H03H9/175Acoustic mirrors
    • HELECTRICITY
    • H03ELECTRONIC CIRCUITRY
    • H03HIMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
    • H03H3/00Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators
    • H03H3/007Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks
    • H03H3/02Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks for the manufacture of piezoelectric or electrostrictive resonators or networks
    • H03H2003/023Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks for the manufacture of piezoelectric or electrostrictive resonators or networks the resonators or networks being of the membrane type

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  • Physics & Mathematics (AREA)
  • Acoustics & Sound (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Piezo-Electric Or Mechanical Vibrators, Or Delay Or Filter Circuits (AREA)

Abstract

The invention discloses a kind of piezo-electric resonators of narrow support frame high quality factor, the surface of substrate is provided with groove and the surface of the substrate is fixed with the support layer, it is formed between the support layer and the groove in the air-gap and the air-gap filled with air, the surface of the support layer is fixed with the bottom electrode, the surface of the bottom electrode is fixed with the piezoelectric layer, the surface of the piezoelectric layer is fixed with the upper electrode, the lower section of the support layer is equipped with multiple highly-resistant material layers and low resistivity materials layer, the highly-resistant material layer and low resistivity materials interlayer every setting and the number of plies of the highly-resistant material layer and low resistivity materials layer it is identical, the highly-resistant material is fixed over the substrate, the upper surface of the low resistivity materials is fixed with the support layer, the invention also discloses a kind of narrow support frame is high The preparation method of the piezo-electric resonator of quality factor.Mechanical strength of the present invention is higher and quality factor are higher.

Description

A kind of piezo-electric resonator of narrow support frame high quality factor
Technical field
The present invention relates to resonator technologies field more particularly to a kind of piezo-electric resonators of narrow support frame high quality factor.
Background technique
Thin film bulk acoustic wave resonator is all analogous to the layer structure i.e. upper electrode of sandwich and asking for lower electrode sets There is piezoelectric thin film layer.The back side of silicon substrate forms air chamber or logical using surface micromachined technology using lithographic technique Cross filling domestic animal material method silicon upper surface formed air chamber with limited using the approximate zero impedance of air sound wave or Person's energy is leaked out from piezoelectric layer.The disadvantage of TFBAR is that act of violence greatly removes silicon substrate and leads to resonator machinery fastness substantially The reduction of degree.In general can in one layer of four silicon nitride of bottom electrode lower surface arrangement or silica as support layer to increase Add TFBAR machinery fastness, but does so the quality factor Q value for seriously reducing TFBAR.
Summary of the invention
(1) the technical issues of solving
In view of the deficiencies of the prior art, the present invention provides a kind of piezo-electric resonator of narrow support frame high quality factor and its Preparation method solves the problems, such as that existing resonator machinery fastness is not high and quality factor are not high.
(2) technical solution
To achieve the above object, the invention provides the following technical scheme: a kind of piezoelectricity of narrow support frame high quality factor is humorous Shake device, including substrate, support layer, bottom electrode, air-gap, upper electrode and piezoelectric layer, the surface of the substrate are provided with recessed The surface of slot and the substrate is fixed with the support layer, and the air-gap and institute are formed between the support layer and the groove It states filled with air in air-gap, the surface of the support layer is fixed with the bottom electrode, and the surface of the bottom electrode is solid Surely there is the piezoelectric layer, the surface of the piezoelectric layer is fixed with the upper electrode, and the lower section of the support layer is equipped with multiple high Impedance material layer and low resistivity materials layer, the highly-resistant material layer and low resistivity materials interlayer are every setting and the high resistant Anti- material layer and the number of plies of low resistivity materials layer are identical, and the highly-resistant material layer is fixed over the substrate, the low-resistance The upper surface of anti-material layer is fixed with the support layer.
Preferably, the piezoelectric layer be AIN piezoelectric membrane, the substrate be earth silicon material, the bottom electrode and Material used in upper electrode is one of Au, Mo, W, Pt.
Preferably, the air-gap contacts the lower surface of the support layer directly with air, and acoustic wave energy is limited System is in the workspace.
A kind of preparation method of the piezo-electric resonator of support frame high quality factor narrow according to above scheme, feature It is: includes the following steps:
(1): using the Si piece of standard RCA technique cleaning twin polishing, Si piece is substrate material, is then pasted at interval Then the highly-resistant material layer and low resistivity materials layer all use PECVD method to deposit one layer of 100nm/ on Si piece two sides The SiN of 100nm thickness4/SiO2Film;
(2): then use DC magnetron sputtering method deposition 100nm/10nm Pt/Ti as bottom electrode, and with photoetching, Stripping technology forms hearth electrode figure;
(3): after removing photoresist, using superconducting RF, AlN piezoelectric membrane, AlN pressure being prepared with the sputtering condition of optimization For conductive film as piezoelectric layer, thickness is about 1.8 μm, is etched later using diluted tetramethyl ammonium hydroxide solution as etching liquid Piezoelectricity layer pattern;
(4): and then again using the Au top electrode of DC magnetron sputtering method deposition 300nm, Au top electrode is as upper layer electricity Pole;
(5): finally etching SiN in the back photoetching of substrate and with reactive ion etching process4/SiO2Film is formed to be etched Cavity window is lost, cavity window is air-gap;Again using the mixed solution of KOH solution and aqueous isopropanol as etching liquid, window is etched Si piece substrate under mouthful, obtains back cavity, back cavity is air-gap.
Preferably, in step (5), air is inserted in the air-gap, the lower surface of the substrate is coated with one and leads Electric elargol slurry, the surface mount of the conductive silver rubber cement have quartz glass plate that it is in 20 DEG C of constant temperature of ring after the two bonding Solidified in border.
Preferably, the conductive silver rubber cement with a thickness of 40-60 μm.
(3) beneficial effect
The present invention provides a kind of piezo-electric resonators of narrow support frame high quality factor, have following the utility model has the advantages that originally Invention is provided with support layer and highly-resistant material layer and low resistivity materials layer on the surface of substrate, first on the surface of substrate Four silicon nitrides or silica are set as support layer to increase resonator machinery fastness, are then arranged in the bottom of support layer Highly-resistant material layer and low resistivity materials layer, using highly-resistant material layer and low resistivity materials interlayer every setting and high impedance Material layer and low resistivity materials layer form acoustic reflector to prevent sound wave or energy from being passed to substrate layer, and another angle is certain Equivalent approximate zero impedance medium is realized in degree, and mechanical firmness, much stronger than general resonator, the present invention passes through Support layer and highly-resistant material layer are set and low resistivity materials layer reinforces the mechanical fastness of resonator, additionally by high impedance Material layer and low resistivity materials layer and air serve as reflecting medium, and the quality factor of resonator can be improved in this way.
Detailed description of the invention
Fig. 1 is the structural diagram of the present invention;
In figure: 1, substrate;2, quartz glass plate;3, conductive silver rubber cement;4, air-gap;5, support layer;6, highly-resistant material Layer;7, low resistivity materials layer;8, bottom electrode;9, piezoelectric layer;10, upper electrode.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment shall fall within the protection scope of the present invention.
As shown in Figure 1, it is proposed that following embodiments:
A kind of piezo-electric resonator of narrow support frame high quality factor, including substrate 1, support layer 5, bottom electrode 8, air-gap 4, upper electrode 10 and piezoelectric layer 9, the surface of the substrate 1 is provided with groove and the surface of the substrate 1 is fixed with the branch Layer 5 is held, is formed between the support layer 5 and the groove filled with air in the air-gap 4 and the air-gap 4, it is described The surface of support layer 5 is fixed with the bottom electrode 8, and the surface of the bottom electrode 8 is fixed with the piezoelectric layer 9, the pressure The surface of electric layer 9 is fixed with the upper electrode 10, and the lower section of the support layer 5 is equipped with multiple highly-resistant material layers 6 and low Impedance material layer 7, the highly-resistant material layer 6 and low resistivity materials layer 7 interval setting and the highly-resistant material layer 6 and The number of plies of low resistivity materials layer 7 is identical, and the highly-resistant material layer 6 is fixed on the substrate 1, the low resistivity materials layer 7 Upper surface be fixed with the support layer 5.
In the present embodiment, the piezoelectric layer 9 is AIN piezoelectric membrane, and the substrate 1 is earth silicon material, the bottom Material used in layer electrode 8 and upper electrode 10 is one of Au, Mo, W, Pt.
In the present embodiment, the air-gap 4 contacts the lower surface of the support layer 5 directly with air, and by sound Wave energy is limited in workspace.
A kind of preparation method of the piezo-electric resonator of narrow support frame high quality factor according to above scheme, including such as Lower step:
(1): using the Si piece of standard RCA technique cleaning twin polishing, Si piece is substrate material, is then pasted at interval Then the highly-resistant material layer 6 and low resistivity materials layer 7 all use PECVD method to deposit one layer of 100nm/ on Si piece two sides The SiN of 100nm thickness4/SiO2Film;
(2): and then use the Pt/Ti of DC magnetron sputtering method deposition 100nm/10nm as bottom electrode 8, and use up It carves, stripping technology forms hearth electrode figure;
(3): after removing photoresist, using superconducting RF, AlN piezoelectric membrane, AlN pressure being prepared with the sputtering condition of optimization For conductive film as piezoelectric layer 9, thickness is about 18 μm, is etched later using diluted tetramethyl ammonium hydroxide solution as etching liquid Piezoelectricity layer pattern;
(4): and then again using the Au top electrode of DC magnetron sputtering method deposition 300nm, Au top electrode is as upper layer electricity Pole 10;
(5): finally etching SiN in the back photoetching of substrate 1 and with reactive ion etching process4/SiO2Film, formed to Etch cavity window, cavity window are air-gap 4;Again using the mixed solution of KOH solution and aqueous isopropanol as etching liquid, etching Si piece substrate under window obtains back cavity, and back cavity is air-gap 4, inserts air in the air-gap 4, described The lower surface of substrate 1 is coated with 40-60 μm of conductive silver rubber cement 3, and the surface mount of the conductive silver rubber cement 3 has quartz glass It is in 20 DEG C of constant temperature of environment and solidifies after the two bonding by piece 2.
The present invention is provided with support layer 5 and highly-resistant material layer 6 and low resistivity materials layer 7 on the surface of substrate, first Four silicon nitrides first are set on the surface of substrate 1 or silica increases resonator machinery fastness as support layer 5, are then existed The bottom setting highly-resistant material layer 6 and low resistivity materials layer 7 of support layer 5, utilize highly-resistant material layer 6 and Low ESR material The interval of the bed of material 7 is arranged and highly-resistant material layer 6 and low resistivity materials layer 7 form acoustic reflector to prevent sound wave or energy Incoming substrate 1, another angle realizes equivalent approximate zero impedance medium to a certain extent, and mechanical firmness is much stronger than one As resonator, the present invention reinforces resonator by setting support layer 5 and highly-resistant material layer 6 and low resistivity materials layer 7 Mechanical fastness, serve as reflecting medium additionally by highly-resistant material layer 6 and low resistivity materials layer 7 and air, in this way may be used To improve the quality factor of resonator
It should be noted that, in this document, relational terms such as first and second and the like are used merely to a reality Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation In any actual relationship or order or sequence.Moreover, the terms "include", "comprise" or its any other variant are intended to Non-exclusive inclusion, so that the process, method, article or equipment including a series of elements is not only wanted including those Element, but also including other elements that are not explicitly listed, or further include for this process, method, article or equipment Intrinsic element.In the absence of more restrictions, the element limited by sentence "including a ...", it is not excluded that There is also other identical elements in process, method, article or equipment including the element.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (6)

1. a kind of piezo-electric resonator of narrow support frame high quality factor, it is characterised in that: including substrate (1), support layer (5), bottom Layer electrode (8), air-gap (4), upper electrode (10) and piezoelectric layer (9), the surface of the substrate (1) are provided with groove and described The surface of substrate (1) is fixed with the support layer (5), and the air-gap (4) are formed between the support layer (5) and the groove And air is filled in the air-gap (4), the surface of the support layer (5) is fixed with the bottom electrode (8), the bottom The surface of electrode (8) is fixed with the piezoelectric layer (9), and the surface of the piezoelectric layer (9) is fixed with the upper electrode (10), institute The lower section for stating support layer (5) is equipped with multiple highly-resistant material layers (6) and low resistivity materials layer (7), the highly-resistant material layer (6) and low resistivity materials layer (7) interval is arranged and the number of plies of the highly-resistant material layer (6) and low resistivity materials layer (7) Identical, the highly-resistant material layer (6) is fixed on the substrate (1), and the upper surface of the low resistivity materials layer (7) is fixed with The support layer (5).
2. a kind of piezo-electric resonator of narrow support frame high quality factor according to claim 1, it is characterised in that: the pressure Electric layer (9) is AIN piezoelectric membrane, and the substrate (1) is earth silicon material, the bottom electrode (8) and upper electrode (10) Material used is one of Au, Mo, W, Pt.
3. a kind of piezo-electric resonator of narrow support frame high quality factor according to claim 1, it is characterised in that: the sky Air gap (4) contacts the lower surface of the support layer (5) directly with air, and acoustic wave energy is limited in workspace.
4. a kind of preparation side of the piezo-electric resonator of narrow support frame high quality factor according to claim 1-3 Method, characterized by the following steps:
(1): using the Si piece of standard RCA technique cleaning twin polishing, Si piece is substrate material, is then pasted at interval described Highly-resistant material layer (6) and low resistivity materials layer (7) then all use PECVD method to deposit one layer of 100nm/ on Si piece two sides The SiN of 100nm thickness4/SiO2Film;
(2): then use DC magnetron sputtering method deposition 100nm/10nm Pt/Ti as bottom electrode (8), and with photoetching, Stripping technology forms hearth electrode figure;
(3): after removing photoresist, using superconducting RF, AlN piezoelectric membrane being prepared with the sputtering condition of optimization, AlN piezoelectricity is thin For film as piezoelectric layer (9), thickness is about 1.8 μm, is etched later using diluted tetramethyl ammonium hydroxide solution as etching liquid Piezoelectricity layer pattern;
(4): and then again using the Au top electrode of DC magnetron sputtering method deposition 300nm, Au top electrode is as upper electrode (10);
(5): finally etching SiN in the back photoetching of substrate (1) and with reactive ion etching process4/SiO2Film is formed to be etched Cavity window is lost, cavity window is air-gap (4);Again using the mixed solution of KOH solution and aqueous isopropanol as etching liquid, etching Si piece substrate under window, obtains back cavity, and back cavity is air-gap (4).
5. a kind of preparation method of the piezo-electric resonator of narrow support frame high quality factor according to claim 4, feature It is: in step (5), air is inserted in the air-gap (4), the lower surface of the substrate (1) is coated with a conductive silver The surface mount of rubber cement (3), the conductive silver rubber cement (3) has quartz glass plate (2), and after the two bonding, it is in constant temperature 20 DEG C environment in solidified.
6. a kind of preparation method of the piezo-electric resonator of narrow support frame high quality factor according to claim 5, feature Be: the conductive silver rubber cement (3) with a thickness of 40-60 μm.
CN201910380938.3A 2019-05-08 2019-05-08 A kind of piezo-electric resonator of narrow support frame high quality factor Pending CN110098816A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114094970A (en) * 2022-01-20 2022-02-25 深圳新声半导体有限公司 Method for manufacturing film bulk acoustic wave resonator and resonator
US11463070B2 (en) 2022-01-18 2022-10-04 Shenzhen Newsonic Technologies Co., Ltd. FBAR structure and manufacturing method of same

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101951238A (en) * 2010-07-30 2011-01-19 中国科学院声学研究所 Piezoelectric film bulk acoustic wave resonator
CN102291095A (en) * 2011-04-27 2011-12-21 庞慰 complex acoustic wave resonator
CN103942082A (en) * 2014-04-02 2014-07-23 南阳理工学院 Complier optimization method for eliminating redundant storage access operations
CN105958956A (en) * 2016-04-26 2016-09-21 电子科技大学 Novel film bulk acoustic resonator and production method thereof
CN106130501A (en) * 2016-07-29 2016-11-16 中国电子科技集团公司第十三研究所 III group-III nitride FBAR and wave filter

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101951238A (en) * 2010-07-30 2011-01-19 中国科学院声学研究所 Piezoelectric film bulk acoustic wave resonator
CN102291095A (en) * 2011-04-27 2011-12-21 庞慰 complex acoustic wave resonator
CN103942082A (en) * 2014-04-02 2014-07-23 南阳理工学院 Complier optimization method for eliminating redundant storage access operations
CN105958956A (en) * 2016-04-26 2016-09-21 电子科技大学 Novel film bulk acoustic resonator and production method thereof
CN106130501A (en) * 2016-07-29 2016-11-16 中国电子科技集团公司第十三研究所 III group-III nitride FBAR and wave filter

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11463070B2 (en) 2022-01-18 2022-10-04 Shenzhen Newsonic Technologies Co., Ltd. FBAR structure and manufacturing method of same
CN114094970A (en) * 2022-01-20 2022-02-25 深圳新声半导体有限公司 Method for manufacturing film bulk acoustic wave resonator and resonator
CN114094970B (en) * 2022-01-20 2022-05-17 深圳新声半导体有限公司 Method for manufacturing film bulk acoustic wave resonator and resonator

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Application publication date: 20190806