CN110090610A - A kind of vertical column type microwave reactor - Google Patents

A kind of vertical column type microwave reactor Download PDF

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Publication number
CN110090610A
CN110090610A CN201910486645.3A CN201910486645A CN110090610A CN 110090610 A CN110090610 A CN 110090610A CN 201910486645 A CN201910486645 A CN 201910486645A CN 110090610 A CN110090610 A CN 110090610A
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China
Prior art keywords
microwave
solution
solution reaction
reaction slot
excitation cavity
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Pending
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CN201910486645.3A
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Chinese (zh)
Inventor
邓贱牛
余伟斌
蔡林恒
彭雪晴
王永平
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Shenzhen Hongwei Environmental Technology Co Ltd
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Shenzhen Hongwei Environmental Technology Co Ltd
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Priority to CN201910486645.3A priority Critical patent/CN110090610A/en
Publication of CN110090610A publication Critical patent/CN110090610A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/12Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
    • B01J19/122Incoherent waves
    • B01J19/126Microwaves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • B01J19/245Stationary reactors without moving elements inside placed in series
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/12Processes employing electromagnetic waves
    • B01J2219/1203Incoherent waves
    • B01J2219/1206Microwaves
    • B01J2219/1209Features relating to the reactor or vessel
    • B01J2219/1212Arrangements of the reactor or the reactors
    • B01J2219/1218Multiple reactors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/12Processes employing electromagnetic waves
    • B01J2219/1203Incoherent waves
    • B01J2219/1206Microwaves
    • B01J2219/1209Features relating to the reactor or vessel
    • B01J2219/1221Features relating to the reactor or vessel the reactor per se
    • B01J2219/1242Materials of construction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/12Processes employing electromagnetic waves
    • B01J2219/1203Incoherent waves
    • B01J2219/1206Microwaves
    • B01J2219/1248Features relating to the microwave cavity
    • B01J2219/1251Support for the reaction vessel
    • B01J2219/126Support for the reaction vessel in the form of a closed housing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/12Processes employing electromagnetic waves
    • B01J2219/1203Incoherent waves
    • B01J2219/1206Microwaves
    • B01J2219/1248Features relating to the microwave cavity
    • B01J2219/1272Materials of construction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/12Processes employing electromagnetic waves
    • B01J2219/1203Incoherent waves
    • B01J2219/1206Microwaves
    • B01J2219/1287Features relating to the microwave source
    • B01J2219/129Arrangements thereof
    • B01J2219/1296Multiple sources
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/18Details relating to the spatial orientation of the reactor
    • B01J2219/185Details relating to the spatial orientation of the reactor vertical

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

The present invention relates to consersion unit technical fields, more particularly to a kind of microwave radiation solution reaction system, including microwave excitation cavity, solution reaction slot, excitation chamber lid, inlet tube, outlet tube, microwave source, multiple row solution reaction slot is installed inside the microwave excitation cavity, it is connected by upper communicating pipe and lower communicating tube integral, and each solution reaction slot and microwave excitation cavity wall is set to keep certain distance by cushion block, inlet tube and outlet tube are connected across microwave excitation cavity with solution reaction slot by microwave inhibition pipe, and the microwave excitation cavity outer wall installs several microwave sources.The invention has the benefit that the present invention provides a kind of vertical column type microwave reactor, solve the problems, such as microwave penetration depth in the solution, make microwave irradiation uniformly, solution treating capacity it is big, improve microwave applications ability.

Description

A kind of vertical column type microwave reactor
Technical field
The present invention relates to consersion unit technical field more particularly to a kind of microwave radiation reaction systems.
Background technique
Currently, microwave-assisted reaction technology has obtained the common concern of scientist, there are also microwave reactions on the market Equipment is being sold.Microwave combines chemistry to form microwave chemical reaction, has process flow simple than conventional reaction technology, when processing Between short advantage, but since different solutions have differing dielectric constant, penetration capacity is different in the solution for microwave, and microwave technology exists Application in reactor fails to become mainstream.
In civilian industry application, microwave magnetron mainly practical 915MHz and two kinds of 2450MHz, 915MHz magnetron function Rate is big, and microwave wavelength is long, and penetration power is deep, but price is high;2450MHz power is few, and wavelength is short, and the depth of microwave penetration is shallow, but price It is low.In solution reaction application, 915MHz is primarily now biased toward.The absorption of microwave energy and the dielectric constant of solution are related, The big solution of dielectric constant, suction wave energy is strong, and the penetration depth of microwave in the solution is shallow, either still using 915MHz 2450MHz magnetron, microwave cannot all have an effect to the solution of deep layer, especially when handling the solution of big flow, due to The radiation solution of microwave is limited, and treatment effect is bad.
Presently, there are the problem of: 1 pair of solution penetration power is inadequate, is unevenly distributed, and leads to that energy consumption is high;2 may not apply to greatly In discharge capacity solution reaction.
Summary of the invention
The purpose of the present invention is to solve above-mentioned technical problems existing for microwave reactor in the prior art, and propose A kind of vertical column type microwave reactor.
To achieve the goals above, present invention employs following technical solutions:
A kind of vertical column type microwave reactor includes microwave excitation cavity, solution reaction slot, excitation chamber lid, inlet tube, outlet tube, microwave Multiple row solution reaction slot is installed in source, the microwave excitation cavity inside, is connected by upper communicating pipe and lower communicating tube integral, and lead to Crossing cushion block makes each solution reaction slot and microwave excitation cavity wall that certain distance, inlet tube and outlet tube be kept to inhibit pipe to wear by microwave It crosses microwave excitation cavity to be connected with solution reaction slot, the microwave excitation cavity outer wall installs several microwave sources.
Further, the microwave excitation cavity uses good conductor, and multiple microwave feed-in mouths and multiple microwave sources are arranged in outer wall It is connected.
Further, the solution reaction slot is intracavitary in microwave excitation, is open upwards, and arranges in vertical column type.
Further, the solution reaction slot is distributed in odd number.
Further, the solution reaction slot was connected by upper communicating pipe and lower communicating tube, upper communicating pipe 3 and lower communicating tube 4 intermittent connect with solution reaction slot 2.
Further, each microwave reaction slot keeps a fixed spacing by cushion block and microwave excitation cavity wall, it is ensured that microwave It can pass through, so that microwave is passed through solution reaction groove sidewall and microwave radiation is carried out to solution.
Further, the microwave reaction slot, cushion block are made of electromagnetic wave transparent material.
Further, the solution reaction slot lumen thickness controls solution layer thickness, and microwave is enable to penetrate solution layer.
Further, the microwave source is located on microwave excitation cavity outer wall, and the energy supply person as reactor passes through wave It leads microwave feed-in microwave excitation is intracavitary, establishes the electromagnetic field of high-frequency and high-voltage high-energy density.
Further, the excitation cavity, which covers, is provided with aperture, the gas generated during discharge solution reaction.
Further, the inlet tube and outlet tube inhibit pipe across microwave excitation cavity wall and solution reaction slot by microwave Connection.
Further, the inlet tube and outlet tube distribution are connected with solution reaction slot lower end and upper end, guarantee that solution is logical Microwave can be come into full contact with by crossing reactive tank.
Further, the microwave inhibits pipe to guarantee that microwave is not leaked from junction.
Further, the microwave excitation cavity increases microwave source power, extension solution reaction slot column by increasing volume Number realizes the reaction of solution huge discharge.
The invention has the benefit that the microwave feed-in for being generated multiple microwave sources of microwave excitation cavity outer wall by waveguide Microwave excitation is intracavitary, establishes the electromagnetic field of high-frequency and high-voltage high energy force density;Multiple row solution reaction slot is swashed with microwave by cushion block It encourages cavity wall to separate, it is ensured that microwave energy passes through, and makes microwave pass through solution reaction groove sidewall and carries out microwave radiation to solution;Pass through upper company Siphunculus and lower communicating tube make solution reaction slot connect;Solution layer thickness is controlled by solution reaction slot lumen thickness, makes microwave energy Enough penetrate solution layer;Pipe is inhibited to make to pass in and out liquid pipe and microwave excitation cavity junction not leaky wave by microwave;It is anti-by increasing solution The columns realization solution huge discharge reaction for answering the volume of slot, increasing the power of microwave source and extending solution reaction slot.The present invention mentions It is solved in microwave solution reaction for a kind of vertical column type microwave reactor, 1, microwave is in solution penetration depth problem;2 solve it is molten Liquid irradiated homogeneity question in microwave field makes solution not cause the uneven of microwave irradiation because of the depth difference of liquid Property, influence the treatment effect of solution;3 solve solution processing the problems in of the microwave solution processing techniques applied to huge discharge.
Detailed description of the invention
The present invention will be further described in detail below with reference to the accompanying drawings and specific embodiments.
Fig. 1 is front schematic view of the invention.
Fig. 2 is survey face schematic diagram of the invention
In figure: microwave excitation cavity 1, solution reaction slot 2, excitation chamber lid 3, upper communicating pipe 4, lower communicating tube 5, microwave inhibit pipe 6, Inlet tube 7, outlet tube 8, cushion block 9, microwave source 10.
Specific embodiment
Below in conjunction with attached drawing and specific embodiment, the present invention is described further.Drawn in preferred embodiment Such as "upper", "lower", "left", "right", " centre " and " one " term, only being illustrated convenient for narration, rather than to limit The enforceable range of the present invention, relativeness are altered or modified, under the content of no substantial changes in technology, when being also considered as this hair Bright enforceable scope.
According to an embodiment of the invention, providing a kind of vertical column type microwave reactor.
As depicted in figs. 1 and 2, a kind of vertical column type microwave reactor according to embodiments of the present invention, including microwave swash Chamber 1, solution reaction slot 2, excitation chamber lid 3, inlet tube 4, outlet tube 5, microwave source 10 are encouraged, is installed inside the microwave excitation cavity 1 Multiple row solution reaction slot 2 is connected integral by upper communicating pipe 4 and lower communicating tube 4, and makes each solution reaction slot 2 by cushion block 9 Keep certain distance with 1 wall of microwave excitation cavity, inlet tube 7 and outlet tube 8 by microwave inhibit pipe 6 pass through microwave excitation cavity 1 and Solution reaction slot 2 is connected, and 1 outer wall of microwave excitation cavity installs several microwave sources 10.
In one embodiment, the microwave excitation cavity 1 uses good conductor, outer wall be arranged multiple microwave feed-in mouths with it is multiple micro- Wave source 10 is connected.
In one embodiment, the solution reaction slot 2 is open upwards in microwave excitation cavity 1, is arranged in vertical column type.
In one embodiment, the solution reaction slot 2 is distributed in odd number.
In one embodiment, the solution reaction slot 2 was connected by upper communicating pipe 3 and lower communicating tube 4, upper 3 He of communicating pipe Lower communicating tube 4 is intermittent to be connect with solution reaction slot 2.
In one embodiment, each microwave reaction slot 2 keeps a fixed spacing by cushion block 9 and 1 wall of microwave excitation cavity, really It protects microwave energy to pass through, so that microwave is passed through 2 side wall of solution reaction slot and microwave radiation is carried out to solution.
In one embodiment, the microwave reaction slot 2, cushion block 9 are made of electromagnetic wave transparent material.
In one embodiment, 2 lumen thickness of solution reaction slot controls solution layer thickness, and microwave is enable to penetrate solution Layer.
In one embodiment, the microwave source 10 is located on 1 outer wall of microwave excitation cavity, the energy supply person as reactor It is by waveguide that microwave feed-in microwave excitation is intracavitary, establish the electromagnetic field of high-frequency and high-voltage high-energy density.
In one embodiment, aperture, the gas generated during discharge solution reaction are provided in the excitation chamber lid 3.
In one embodiment, the inlet tube 7 and outlet tube 8 by microwave inhibit pipe 6 pass through microwave excitation cavity wall with it is molten Liquid reactive tank 2 connects.
In one embodiment, the inlet tube 7 and the distribution of outlet tube 8 are connected with 2 lower end of solution reaction slot and upper end, guarantee Solution can come into full contact with microwave by reactive tank 2.
In one embodiment, the microwave inhibits pipe 6 to guarantee that microwave is not leaked from junction.
In one embodiment, the microwave excitation cavity 1 increases by 10 power of microwave source, extension solution is anti-by increasing volume 2 columns of slot is answered, realizes the reaction of solution huge discharge.
When concrete application, microwave excitation cavity 1 uses good conductor material, and multiple microwave feed-in mouths and multiple microwaves are arranged in outer wall Source 10 is connected, and the energy supply person as reactor, by microwave feed-in microwave excitation cavity 1, establishes high-frequency and high-voltage height by waveguide The electromagnetic field of energy density.There are multiple solution reaction slots 2 in microwave excitation cavity 1, solution reaction slot 2 opens wide upwards, in perpendicular column Formula arrangement, and 2 numbers of solution reaction slot are odd number.1 wall of microwave excitation cavity and each solution reaction slot 2 are kept by cushion block 9 One fixed spacing, it is ensured that microwave energy passes through, and makes microwave pass through 2 side wall of solution reaction slot and carries out microwave radiation to solution.Microwave reaction Slot 2, cushion block 9 are electromagnetic wave transparent material, select different electromagnetic wave transparent materials, including polytetrafluoroethylene (PTFE), PP class, quartz glass according to differential responses Equal materials.Solution layer thickness is controlled by 2 lumen thickness of liquid reactive tank, microwave is enable to penetrate solution layer.It is opened in excitation chamber lid 3 There are aperture, the gas generated during discharge solution reaction.Inhibit pipe 6 across micro- by microwave by inlet tube 7 and outlet tube 8 Wave excitation cavity wall is connect with 2 lower end of solution reaction slot and upper end respectively, and it is micro- to guarantee that solution can come into full contact with by reactive tank 2 Wave.Pipe 6 is inhibited to guarantee that microwave is not leaked from junction by microwave.By increasing by 1 volume of microwave excitation cavity, increase microwave source function Rate and extension 2 columns of solution reaction slot, realize the reaction of solution huge discharge.
In conclusion by means of above-mentioned technical proposal of the invention, by waveguide by the multiple micro- of 1 outer wall of microwave excitation cavity In the microwave feed-in microwave excitation cavity 1 that wave source 10 generates, the electromagnetic field of high-frequency and high-voltage high energy force density is established;By cushion block more Column solution reaction slot 2 is separated with microwave excitation cavity wall 1, it is ensured that microwave energy passes through, and microwave is made to pass through 2 side wall of solution reaction slot to molten Liquid carries out microwave radiation;Solution reaction slot 2 is set to connect by upper communicating pipe 4 and lower communicating tube 5;Pass through 2 inner cavity of solution reaction slot Thickness control solution layer thickness, enables microwave to penetrate solution layer;Pipe 6 is inhibited to make to pass in and out liquid pipe and microwave excitation cavity by microwave Junction not leaky wave;By increasing the volume of solution reaction slot 2, the power for increasing microwave source 10 and extension solution reaction slot 2 Columns realizes the reaction of solution huge discharge.The present invention provides a kind of vertical column type microwave reactor, and 1 solves in microwave solution reaction, Microwave is in solution penetration depth problem;2 solve solution irradiated homogeneity question in microwave field, make solution will not be because of liquid The depth difference of body and the inhomogeneities for causing microwave irradiation, influence the treatment effect of solution;3 solve microwave solution processing techniques The problems in solution processing applied to huge discharge.
Although specific embodiments of the present invention have been described above, those skilled in the art should be appreciated that this It is merely illustrative of, various changes or modifications can be made to present embodiment, without departing from the principle and substance of the present invention, Protection scope of the present invention is only limited by the claims that follow.

Claims (10)

1. a kind of vertical column type microwave reactor, which is characterized in that including microwave excitation cavity (1), solution reaction slot (2), excitation cavity (3), inlet tube (7), outlet tube (8), microwave source (10) are covered, multiple row solution reaction slot (2) are installed inside the microwave excitation cavity, It is connected by upper communicating pipe (4) and lower communicating tube (5) integral, and swash each solution reaction slot (2) and microwave by cushion block (9) Encouraging chamber (1) wall keeps certain distance, inlet tube (7) and outlet tube (8) to inhibit pipe (6) to pass through microwave excitation cavity (1) by microwave It is connected with solution reaction slot (2), microwave excitation cavity (1) outer wall installs several microwave sources.
2. a kind of vertical column type microwave reactor according to claim 1, which is characterized in that the microwave excitation cavity (1) is Good conductor material, appearance are arranged multiple microwave feed-in mouths and are connected with multiple microwave sources (10).
3. a kind of vertical column type microwave reactor according to claim 1, which is characterized in that in the microwave excitation cavity (1) Portion's installation multiple row solution reaction slot (2) is open upwards, and is arranged in vertical column type, and solution reaction slot (2) is distributed in odd number, passes through upper company Siphunculus (4) and lower communicating tube (5) series connection, upper lower communicating tube is intermittent to be connect with solution reaction slot (2).
4. a kind of vertical column type microwave reactor according to claim 1 or 3, which is characterized in that the solution reaction slot (2) Each solution reaction slot (2) and microwave excitation cavity (1) wall is set to keep certain distance by cushion block (9), it is ensured that microwave energy passes through, and makes micro- Wave passes through solution reaction slot (2) side wall and carries out microwave radiation to solution, and solution reaction slot (2) and cushion block (9) all use wave transparent material Material production.
5. a kind of vertical column type microwave reactor according to claim 1, which is characterized in that in the solution reaction slot (2) Chamber thickness controls solution layer thickness, microwave is enable to penetrate solution layer.
6. a kind of vertical column type microwave reactor according to claim 1, which is characterized in that the microwave source (10) is located at micro- On wave excitation chamber (1) outer wall, swashing as the energy supply person of reactor by waveguide by microwave feed-in microwave excitation cavity (1) Encourage the intracavitary electromagnetic field for establishing high-frequency and high-voltage high-energy density.
7. a kind of vertical column type microwave reactor according to claim 1, which is characterized in that opened on the excitation chamber lid (3) There are aperture, the gas generated during discharge solution reaction.
8. a kind of vertical column type microwave reactor according to claim 1, which is characterized in that the inlet tube (7) and out liquid Pipe (8) inhibits pipe (6) to connect across microwave excitation cavity (1) wall with solution reaction slot (2) by microwave, makes microwave not from junction Leakage, inlet tube (7) and outlet tube (8) are connected with solution reaction slot (2) lower end and upper end respectively, guarantee that solution is anti-by solution Answer slot (2) that microwave can be come into full contact with.
9. a kind of vertical column type microwave reactor according to claim 1 or 8, which is characterized in that the microwave, which swashs, inhibits pipe (6) guarantee that microwave is not leaked from junction.
10. a kind of vertical column type microwave reactor according to claim 1, which is characterized in that the microwave excitation cavity (1) is logical Increase volume is crossed, microwave source (10) power is increased, extends solution reaction slot (2) columns, realizes the reaction of solution huge discharge.
CN201910486645.3A 2019-06-05 2019-06-05 A kind of vertical column type microwave reactor Pending CN110090610A (en)

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CN101649357A (en) * 2009-08-24 2010-02-17 中国烟草总公司郑州烟草研究院 Method for preparing invert sugar by microwave reaction and special equipment thereof
CN102107987A (en) * 2010-12-03 2011-06-29 中国农业大学 Modular anaerobic digestion system
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CN102476040A (en) * 2010-11-26 2012-05-30 杭州和锦科技有限公司 Bundling tube type continuous flow chemical reactor in microwave single die cavity and application thereof
CN105470807A (en) * 2014-09-09 2016-04-06 华东师范大学 Carbon dioxide infrared hollow-core fiber laser and manufacturing method thereof
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CN102459089A (en) * 2009-06-02 2012-05-16 慧龙投资有限公司 Fluid treatment apparatus
CN101649357A (en) * 2009-08-24 2010-02-17 中国烟草总公司郑州烟草研究院 Method for preparing invert sugar by microwave reaction and special equipment thereof
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CN102107987A (en) * 2010-12-03 2011-06-29 中国农业大学 Modular anaerobic digestion system
CN105470807A (en) * 2014-09-09 2016-04-06 华东师范大学 Carbon dioxide infrared hollow-core fiber laser and manufacturing method thereof
CN108409681A (en) * 2018-05-22 2018-08-17 成都天羽新材料有限公司 A kind of serialization prepares the device and method of benzoxazine
CN208757555U (en) * 2018-07-14 2019-04-19 深圳市星聚工业自动化有限公司 One kind being longitudinally arranged High-Power Microwave single mode reactor
CN210058218U (en) * 2019-06-05 2020-02-14 深圳市弘玮环境技术有限公司 Vertical microwave reactor

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Application publication date: 20190806