CN110079133A - A kind of automatic cleaning coating material and preparation method thereof for outer surface of automobile - Google Patents

A kind of automatic cleaning coating material and preparation method thereof for outer surface of automobile Download PDF

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Publication number
CN110079133A
CN110079133A CN201910438867.8A CN201910438867A CN110079133A CN 110079133 A CN110079133 A CN 110079133A CN 201910438867 A CN201910438867 A CN 201910438867A CN 110079133 A CN110079133 A CN 110079133A
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China
Prior art keywords
nanoscale
parts
platinum
automobile
automatic cleaning
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CN201910438867.8A
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Chinese (zh)
Inventor
王恒
金洲
王华通
吴昊浩
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Suzhou Hengyi Environmental Protection Technology Co Ltd
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Suzhou Hengyi Environmental Protection Technology Co Ltd
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Priority to CN201910438867.8A priority Critical patent/CN110079133A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/10Anti-corrosive paints containing metal dust
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1687Use of special additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24Electrically-conducting paints

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention relates to a kind of automatic cleaning coating materials for outer surface of automobile, are grouped as by the group of following parts by weight: 50-70 parts of methanol;21-25 parts of water;1-5 parts of tin oxide;1.0-1.5 parts of platinum;0.5-1.0 parts of tungsten oxide;6-9 parts of silica;A kind of preparation method of the automatic cleaning coating material for outer surface of automobile, comprising: S1, stock;S2, solution is prepared;S3, mixing: compared with prior art, the invention has the advantages that there is self-cleaning effect by being formulated resulting coating, it is not easy adhering dust, and after by current scour, water droplet will not be formed on surface but form water curtain on surface, eliminating watermark and water curtain can further flush clean coat side, reduce automobile carwash frequency, to reduce living cost, improve environmental benefit, and there is high rigidity and chemical resistance, surface is still wear-resisting when automobile high-speed moves, it improves service life, and vehicle body resistance can be effectively reduced, achieve the effect that antistatic.

Description

A kind of automatic cleaning coating material and preparation method thereof for outer surface of automobile
Technical field
The present invention relates to automotive fields, and in particular to a kind of for the automatic cleaning coating material of outer surface of automobile and its preparation Method.
Background technique
In recent years, countries in Asia's economic development is rapid.The common people of countries in Asia are at present for quality of making the life better, every family Each household will buy automobile.Wherein, more rich some people, which is not merely only satisfied with, possesses automobile, they are in automobile There are higher requirement, the satisfaction lain in spiritual level more on appearance, comfort level, performance and class.From now on The maturation of countries in Asia's automobile market generates people for the various demands of automobile certainly.
The automobile industry national U.S. the most flourishing, Japan, Europe etc., car body coating is nearly all waterproof coating.
Have the self-cleaning film product of many photocatalysts on the market, just listing when get the attention, but due to construction high price, Difficulty is high, and can not play ideal effect for pollutions such as exhaust, charcoal ash, and consumers is caused more to lose such product It hopes, can not exploit market for many years.The cleaning charge of automobile is expensive on ordinary days, and the sewage that carwash generates is difficult to handle, substantially In environmental protection and energy saving core concept, we take up to study use of the automatic cleaning coating on automobile, by nanotechnology system Produce a kind of automatic cleaning coating for being used exclusively in automobile-exterior, the Nature wind and rain, allow automobile to reach self-cleaning Effect, reduce carwash number, reduce living cost, improve environmental benefit.
Summary of the invention
Object of the present invention is to: a kind of automatic cleaning coating material and preparation method thereof for outer surface of automobile is provided.
The technical scheme is that a kind of automatic cleaning coating material for outer surface of automobile, by following parts by weight Group is grouped as: 50-70 parts of methanol;21-25 parts of water;1-5 parts of tin oxide;1.0-1.5 parts of platinum;0.5-1.0 parts of tungsten oxide;Dioxy 6-9 parts of SiClx.
Further: the tin oxide is nanoscale tin particles, and the platinum is nanoscale platinum grain, the tungsten oxide For nanoscale tungsten particle, the silica is nanosized silica particles.
It is further: the nanoscale tin particles, nanoscale platinum grain, nanoscale tungsten particle and nanoscale two The partial size of silicon oxide particle is respectively less than or is equal to 30 nanometers.
A kind of preparation method of the automatic cleaning coating material for outer surface of automobile, comprising:
S1, stock: stocking up by the component of above-mentioned parts by weight, and nanoscale tin particles are made in tin oxide, will Nanoscale platinum grain is made in platinum, and nanoscale tungsten particle is made in tungsten oxide, nanometer grade silica is made in silica Particle, and control nanoscale tin particles, nanoscale platinum grain, nanoscale tungsten particle and nanosized silica particles Partial size be respectively less than or be equal to 30 nanometers;
S2, it prepares solution: the first alcohol and water of proportional quantities successively being poured into cleaning container, and stir 3-5min, stood 11-15min obtains mixed solution;
S3, mixing: by nanoscale tin particles, nanoscale platinum grain obtained in S1, nanoscale tungsten particle and Nanosized silica particles sequentially add in the resulting mixed solution of S2, and stir 30-35min, stand 40-50min, obtain To product.
Compared with prior art, not easy to stick the invention has the advantages that there is self-cleaning effect by being formulated resulting coating Attached dust, and after by current scour will not form water droplet on surface but form water curtain on surface, eliminate watermark and Water curtain can further flush clean coat side, reduce automobile carwash frequency, to reduce living cost, improve environmental benefit, and And there is high rigidity and chemical resistance, surface is still wear-resisting when automobile high-speed moves, and improves service life, and can be effective Reduce vehicle body resistance, achievees the effect that antistatic.
Detailed description of the invention
Fig. 1 is the performance test results table of embodiment products obtained therefrom;
Specific embodiment
Embodiment 1: a kind of automatic cleaning coating material for outer surface of automobile is grouped as: first by the group of following parts by weight 50 parts of alcohol;21 parts of water;1 part of tin oxide;1 part of platinum;0.5 part of tungsten oxide;6 parts of silica.The tin oxide is nanoscale Tin particles, the platinum are nanoscale platinum grain, and the tungsten oxide is nanoscale tungsten particle, and the silica is nanoscale Silica dioxide granule.And the nanoscale tin particles, nanoscale platinum grain, nanoscale tungsten particle and nanoscale two The partial size of silicon oxide particle is 30 nanometers.Nano granules of stannic oxide effectively reduces vehicle body resistance, to reduce vehicle body insulating properties, drops The electrostatic of low accumulation prevents Electrostatic Absorption dust, and nanometer silicon dioxide particle has super hydrophilic shape, is capable of forming moisture Sublayer plays the role of antistatic agent.Nano-platinum particle has chemical resistance, can resist the sour corrosions such as external rainwater, receive Rice tungsten oxide particles then effectively improve the hardness of coating, can extend coating life.
A kind of preparation method of the automatic cleaning coating material for outer surface of automobile, comprising:
S1, stock: stocking up by the component of above-mentioned parts by weight, and nanoscale tin particles are made in tin oxide, will Nanoscale platinum grain is made in platinum, and nanoscale tungsten particle is made in tungsten oxide, nanometer grade silica is made in silica Particle, and control nanoscale tin particles, nanoscale platinum grain, nanoscale tungsten particle and nanosized silica particles Partial size to 30 nanometers;
S2, it prepares solution: the first alcohol and water of proportional quantities successively being poured into cleaning container, and stir 3min, stood 11min obtains mixed solution;
S3, mixing: by nanoscale tin particles, nanoscale platinum grain obtained in S1, nanoscale tungsten particle and Nanosized silica particles sequentially add in the resulting mixed solution of S2, and stir 30min, stand 40min, obtain product.
Performance detection is as shown in Figure 1.
Embodiment 2: a kind of automatic cleaning coating material for outer surface of automobile is grouped as: first by the group of following parts by weight 70 parts of alcohol;25 parts of water;5 parts of tin oxide;1.5 parts of platinum;1.0 parts of tungsten oxide;9 parts of silica.
The tin oxide is nanoscale tin particles, and the platinum is nanoscale platinum grain, and the tungsten oxide is nanoscale Tungsten oxide particles, the silica are nanosized silica particles.The nanoscale tin particles, nanoscale platinum The partial size of grain, nanoscale tungsten particle and nanosized silica particles is respectively less than 30 nanometers.Nano granules of stannic oxide is effective Reduce vehicle body resistance, to reduce vehicle body insulating properties, reduce the electrostatic of vehicle body accumulation, prevents Electrostatic Absorption dust, and nanometer two Silicon oxide particle has super hydrophilic shape, is capable of forming water molecule layer, plays the role of antistatic agent.Nano-platinum particle has resistance toization The property learned, can resist the sour corrosions such as external rainwater, and nano oxidized tungsten particle then effectively improves the hardness of coating, can extend painting The layer service life.
A kind of preparation method of the automatic cleaning coating material for outer surface of automobile, comprising:
S1, stock: stocking up by the component of above-mentioned parts by weight, and nanoscale tin particles are made in tin oxide, will Nanoscale platinum grain is made in platinum, and nanoscale tungsten particle is made in tungsten oxide, nanometer grade silica is made in silica Particle, and control nanoscale tin particles, nanoscale platinum grain, nanoscale tungsten particle and nanosized silica particles Partial size be respectively less than or be equal to 30 nanometers;
S2, it prepares solution: the first alcohol and water of proportional quantities successively being poured into cleaning container, and stir 5min, stood 15min obtains mixed solution;
S3, mixing: by nanoscale tin particles, nanoscale platinum grain obtained in S1, nanoscale tungsten particle and Nanosized silica particles sequentially add in the resulting mixed solution of S2, and stir 35min, stand 50min, obtain product.
Performance detection is as shown in Figure 1.
Embodiment 3: a kind of automatic cleaning coating material for outer surface of automobile is grouped as: first by the group of following parts by weight 60 parts of alcohol;23 parts of water;3 parts of tin oxide;1.3 parts of platinum;0.7 part of tungsten oxide;8 parts of silica.
The tin oxide is nanoscale tin particles, and the platinum is nanoscale platinum grain, and the tungsten oxide is nanoscale Tungsten oxide particles, the silica are nanosized silica particles.Nano granules of stannic oxide effectively reduces vehicle body resistance, from And vehicle body insulating properties is reduced, the electrostatic of vehicle body accumulation is reduced, Electrostatic Absorption dust is prevented, and nanometer silicon dioxide particle is with super Hydrophilic shape, is capable of forming water molecule layer, plays the role of antistatic agent.Nano-platinum particle has chemical resistance, can resist outer The sour corrosions such as portion's rainwater, nano oxidized tungsten particle then effectively improve the hardness of coating, can extend coating life.
The nanoscale tin particles, nanoscale platinum grain, nanoscale tungsten particle and nanometer grade silica The partial size of grain is respectively less than 30 nanometers.
A kind of preparation method of the automatic cleaning coating material for outer surface of automobile, comprising:
S1, stock: stocking up by the component of above-mentioned parts by weight, and nanoscale tin particles are made in tin oxide, will Nanoscale platinum grain is made in platinum, and nanoscale tungsten particle is made in tungsten oxide, nanometer grade silica is made in silica Particle, and control nanoscale tin particles, nanoscale platinum grain, nanoscale tungsten particle and nanosized silica particles Partial size be respectively less than 30 nanometers;
S2, it prepares solution: the first alcohol and water of proportional quantities successively being poured into cleaning container, and stir 4min, stood 15min obtains mixed solution;
S3, mixing: by nanoscale tin particles, nanoscale platinum grain obtained in S1, nanoscale tungsten particle and Nanosized silica particles sequentially add in the resulting mixed solution of S2, and stir 31min, stand 45min, obtain product.
Performance detection is as shown in Figure 1.
Embodiment 4: a kind of automatic cleaning coating material for outer surface of automobile is grouped as: first by the group of following parts by weight 65 parts of alcohol;23 parts of water;3 parts of tin oxide;1.2 parts of platinum;0.8 part of tungsten oxide;7 parts of silica.
The tin oxide is nanoscale tin particles, and the platinum is nanoscale platinum grain, and the tungsten oxide is nanoscale Tungsten oxide particles, the silica are nanosized silica particles.Nano granules of stannic oxide effectively reduces vehicle body resistance, from And vehicle body insulating properties is reduced, the electrostatic of vehicle body accumulation is reduced, Electrostatic Absorption dust is prevented, and nanometer silicon dioxide particle is with super Hydrophilic shape, is capable of forming water molecule layer, plays the role of antistatic agent.Nano-platinum particle has chemical resistance, can resist outer The sour corrosions such as portion's rainwater, nano oxidized tungsten particle then effectively improve the hardness of coating, can extend coating life.
The nanoscale tin particles, nanoscale platinum grain, nanoscale tungsten particle and nanometer grade silica The partial size of grain is respectively less than 30 nanometers.
A kind of preparation method of the automatic cleaning coating material for outer surface of automobile, comprising:
S1, stock: stocking up by the component of above-mentioned parts by weight, and nanoscale tin particles are made in tin oxide, will Nanoscale platinum grain is made in platinum, and nanoscale tungsten particle is made in tungsten oxide, nanometer grade silica is made in silica Particle, and control nanoscale tin particles, nanoscale platinum grain, nanoscale tungsten particle and nanosized silica particles Partial size be respectively less than 30 nanometers;
S2, it prepares solution: the first alcohol and water of proportional quantities successively being poured into cleaning container, and stir 5min, stood 13min obtains mixed solution;
S3, mixing: by nanoscale tin particles, nanoscale platinum grain obtained in S1, nanoscale tungsten particle and Nanosized silica particles sequentially add in the resulting mixed solution of S2, and stir 33min, stand 45min, obtain product.
Performance detection is as shown in Figure 1.
Certainly the above embodiments merely illustrate the technical concept and features of the present invention, and its object is to allow be familiar with technique People can understand the content of the present invention and implement it accordingly, it is not intended to limit the scope of the present invention.It is all according to this hair The modification that the Spirit Essence of bright main technical schemes is done, should be covered by the protection scope of the present invention.

Claims (4)

1. a kind of automatic cleaning coating material for outer surface of automobile, it is characterised in that: be grouped as by the group of following parts by weight: first 50-70 parts of alcohol;21-25 parts of water;1-5 parts of tin oxide;1.0-1.5 parts of platinum;
0.5-1.0 parts of tungsten oxide;6-9 parts of silica.
2. a kind of automatic cleaning coating material for outer surface of automobile according to claim 1, it is characterised in that: the oxygen Change tin is nanoscale tin particles, and the platinum is nanoscale platinum grain, and the tungsten oxide is nanoscale tungsten particle, described Silica is nanosized silica particles.
3. a kind of automatic cleaning coating material for outer surface of automobile according to claim 2, it is characterised in that: described to receive Meter level granules of stannic oxide, nanoscale platinum grain, nanoscale tungsten particle and nanosized silica particles partial size be respectively less than Or it is equal to 30 nanometers.
4. a kind of preparation method of automatic cleaning coating material for outer surface of automobile according to claim 1 or 2 or 3, It is characterized by comprising:
S1, stock: stocking up by the component of above-mentioned parts by weight, and nanoscale tin particles are made in tin oxide, by platinum system At nanoscale platinum grain, nanoscale tungsten particle is made in tungsten oxide, nanosized silica particles are made in silica, And control the grain of nanoscale tin particles, nanoscale platinum grain, nanoscale tungsten particle and nanosized silica particles Diameter is respectively less than or is equal to 30 nanometers;
S2, it prepares solution: the first alcohol and water of proportional quantities successively being poured into cleaning container, and stir 3-5min, stand 11- 15min obtains mixed solution;
S3, mixing: by nanoscale tin particles, nanoscale platinum grain obtained in S1, nanoscale tungsten particle and nanometer Grade silicon dioxide particle sequentially adds in the resulting mixed solution of S2, and stirs 30-35min, stands 40-50min, is produced Product.
CN201910438867.8A 2019-05-24 2019-05-24 A kind of automatic cleaning coating material and preparation method thereof for outer surface of automobile Pending CN110079133A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112757710A (en) * 2021-01-09 2021-05-07 杭州晶硝子玻璃科技有限公司 Anti-deformation low-reflection glass and preparation method thereof
CN114736619A (en) * 2022-05-07 2022-07-12 惠州市鑫亚凯立科技有限公司 Adhesive tape with easy-to-clean and antibacterial functions and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0453897A1 (en) * 1990-04-25 1991-10-30 Bayer Ag Self-cleaning coatings for oven walls
CN107641345A (en) * 2017-11-03 2018-01-30 张家港外星人新材料科技有限公司 A kind of self-cleaning nona coating, inorganic transparent coating and automatically cleaning product
CN107760073A (en) * 2017-11-22 2018-03-06 广州碧然环保有限公司 Glass baseplate antistatic anti-fouling and self-cleaning plastics, preparation method and its construction method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0453897A1 (en) * 1990-04-25 1991-10-30 Bayer Ag Self-cleaning coatings for oven walls
CN107641345A (en) * 2017-11-03 2018-01-30 张家港外星人新材料科技有限公司 A kind of self-cleaning nona coating, inorganic transparent coating and automatically cleaning product
CN107760073A (en) * 2017-11-22 2018-03-06 广州碧然环保有限公司 Glass baseplate antistatic anti-fouling and self-cleaning plastics, preparation method and its construction method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112757710A (en) * 2021-01-09 2021-05-07 杭州晶硝子玻璃科技有限公司 Anti-deformation low-reflection glass and preparation method thereof
CN114736619A (en) * 2022-05-07 2022-07-12 惠州市鑫亚凯立科技有限公司 Adhesive tape with easy-to-clean and antibacterial functions and preparation method thereof

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Application publication date: 20190802