CN110054934A - A kind of dedicated bismuth glass powder of superpower dispersion performance glass ink and preparation method thereof - Google Patents
A kind of dedicated bismuth glass powder of superpower dispersion performance glass ink and preparation method thereof Download PDFInfo
- Publication number
- CN110054934A CN110054934A CN201910308804.0A CN201910308804A CN110054934A CN 110054934 A CN110054934 A CN 110054934A CN 201910308804 A CN201910308804 A CN 201910308804A CN 110054934 A CN110054934 A CN 110054934A
- Authority
- CN
- China
- Prior art keywords
- parts
- powder
- glass
- bismuth
- auxiliary agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C12/00—Powdered glass; Bead compositions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Wood Science & Technology (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a kind of superpower dedicated bismuth glass powders of dispersion performance glass ink, including dry powder and TC-1 esters auxiliary agent, wherein, in parts by weight, the dry powder includes: 80-85 parts of bismuth silicate, 5-6 parts of boron oxide, 3-4 parts of lithia, 4-6 parts of sodium oxide molybdena, 4-6 parts of calcium oxide, 0.2-0.8 parts of phosphotungstic acid；Wherein, TC-1 esters auxiliary agent is aliphatic amide type compound and lipoid substance with the mixture of 1:0.8-1.2 ratio；Wherein, aliphatic amide type compound is that poly alkyl alcohol ether amide is a kind of；Lipoid substance is one or both of methyl benzoate and butyl ester.Bismuth glass powder of the invention has the advantages that easily to disperse and do not reunite, and after the glass ink made of glass powder of the invention stores 3 months, is still able to maintain the dispersity of initial preparation.
Description
Technical field
The present invention relates to glass powders, and in particular, to a kind of superpower dispersion performance (glass ink is dedicated) bismuth glass powder
Body and preparation method thereof.
Background technique
Glassware is widely used in industry and life, and the requirement due to people to glassware is higher and higher, out
The product for being coated with various multicolour patterns on the glass article surface is showed.But ink jet-printing technology is commonly used in China,
It since ink and glassware are entirely physical connection, is easy to peel off, and the problems such as glassware is frangible, limits glassware
It is widely applied, is not able to satisfy people's further requirement, in recent years, glassware is being increased every year with 30% speed, market
The disadvantages of potentiality are big, but simple glass product is easily peelable there are frangible and spray printing pattern.
Foreign countries occur by the way of inkjet printing, and the digital pattern in computer is beaten in a non-contact manner by spray head
It is imprinted on the technology of glass surface.This technology uses dedicated printing device, will be attached to the glass ink-jet of glass surface
Marking ink is printed to glass surface, and the glass is then sintered tempering under 650-750 DEG C of high temperature, makes the table of ink and glass
Face fusion, is fixed on glass surface.Using this technology, various number patterns can be convenient, fast accurately print to
On glass, required manual operation is less, and obtained pattern quality is high, also smaller to the pollution of environment.However, this technology is still
It is not widely used in China.Reason is the dispersion of glass powder difficulty and easy to reunite, the easily ink spray of blocking printing device
Head.Such as, most outstanding glass ink-jet printing ink is that Israel produces, and it is only 3 using validity period to mesh on the market
A month.Moreover, it is printing with after high temperature sintering, colorant component and inorganic frit component sometimes can not be equal with glass surface
Even fusion leads to pattern color depth unevenness, color distortion, influences the beauty of finished product, cause certain rejection rate.
Summary of the invention
The present invention is easy to reunite for dispersion powder in Conventional glass ink, and hardly possible dispersion leads to the particle agglomeration in ink
It is dedicated to provide a kind of superpower dispersion performance glass ink for the drawbacks of partial size is excessive, and inkjet printer head is easily blocked in operation
Bismuth glass powder and preparation method thereof, its object is to solve the dispersion of simple glass ink powder difficulty and difficulty easy to reunite
Topic, bismuth glass powder of the invention have the advantages that easily to disperse and do not reunite, the glass made of glass powder of the invention
After ink stores 3 months, it is still able to maintain the dispersity of initial preparation.
To achieve the goals above, the present invention provides a kind of superpower dedicated bismuth glass powder of dispersion performance glass ink
Body, including dry powder and TC-1 esters auxiliary agent, wherein in parts by weight, the dry powder includes: 80-85 parts of bismuth silicate, boron oxide 5-
6 parts, 3-4 parts of lithia, 4-6 parts of sodium oxide molybdena, 4-6 parts of calcium oxide, 0.2-0.8 parts of phosphotungstic acid；Wherein, TC-1 esters auxiliary agent is rouge
Fat race amides compound and lipoid substance are with the mixture of 1:0.8-1.2 ratio；Wherein, aliphatic amide type compound is
Aliphatic poly ether amide is a kind of；Lipoid substance is one of methyl benzoate and butyl ester or a variety of.
The present invention also provides a kind of superpower dispersion performance bismuth glass raw powder's production technologies, comprising the following steps: (1) according to
Dry powder is included that bismuth silicate, boron oxide, lithia, sodium oxide molybdena, calcium oxide and phosphotungstic acid machinery mix by previously described raw material proportioning
It closes uniformly, melts, it is cooling, obtain M1；(2) M1 is crushed, is sieved, the powder chosen less than 1000 mesh carries out ball in high energy ball mill
Mill, makes powder reach sub-micron rank, obtains M2；(3) TC-1 esters auxiliary agent is sprayed into M2, wherein M2 and TC-1 esters auxiliary agent
Weight ratio be 100:0.8-1.2, obtain M3；(4) M3 is sanded in alkane, obtains average grain diameter less than 100 nanometers
Powder；Wherein, TC-1 esters auxiliary agent is aliphatic amide type compound and lipoid substance with the mixing of 1:0.8-1.2 ratio
Object.
In order to prove the practicability of bismuth glass powder, the present invention is prepared for a kind of glass ink using it, including institute above
Bismuth glass powder, dispersing agent, dispersing aid and the anti-settling wax stated, wherein bismuth glass powder, dispersing agent, dispersing aid and anti-settling
The mass ratio of wax is 35:28-32:4-5:0.3-0.8.
Through the above technical solutions, one aspect of the present invention uses a large amount of bismuth silicates, the content of bismuth is improved, is reduced
Sodium, potassium content, the drawbacks of avoiding dispersion extremely difficult due to sodium, potash glass powder, the preparation of bismuth glass powder is there is not yet open report
Road belongs to pioneering；On the other hand it joined TC-1 esters auxiliary agent, the surface of powder be modified, obtained bismuth glass powder
Body has the advantages that easily to disperse and do not reunite, difficult compared to the traditional powders such as soda-lime glass or potash glass dispersion and easy to reunite with not
Alternative effect, bismuth glass powder of the invention has the advantages that easily to disperse and do not reunite, with glass powder of the invention
After manufactured glass ink stores 3 months, it is still able to maintain the dispersity of initial preparation, has sufficiently achieved wanting for user
It asks.
Other features and advantages of the present invention will the following detailed description will be given in the detailed implementation section.
Detailed description of the invention
The drawings are intended to provide a further understanding of the invention, and constitutes part of specification, with following tool
Body embodiment is used to explain the present invention together, but is not construed as limiting the invention.In the accompanying drawings:
Fig. 1 is the Malvern granularity Detection figure of the glass ink in embodiment 1；
Fig. 2 is the pattern that particle in bismuth glass ink has just been prepared in embodiment 1；
Fig. 3 is the pattern of the particle after storing 3 months in embodiment 1 in glass ink.
Specific embodiment
Detailed description of the preferred embodiments below.It should be understood that described herein specific
Embodiment is merely to illustrate and explain the present invention, and is not intended to restrict the invention.
The endpoint of disclosed range and any value are not limited to the accurate range or value herein, these ranges or
Value should be understood as comprising the value close to these ranges or value.For numberical range, between the endpoint value of each range, respectively
It can be combined with each other between the endpoint value of a range and individual point value, and individually between point value and obtain one or more
New numberical range, these numberical ranges should be considered as specific open herein.
The present invention provides a kind of superpower dedicated bismuth glass powders of dispersion performance glass ink, including dry powder and TC-1 ester
Analog assistant, wherein in parts by weight, the dry powder includes: 80-85 parts of bismuth silicate, and 5-6 parts of boron oxide, 3-4 parts of lithia, oxygen
Change sodium 4-6 parts, 4-6 parts of calcium oxide, 0.2-0.8 parts of phosphotungstic acid；Wherein, TC-1 esters auxiliary agent be aliphatic amide type compound and
Lipoid substance is with the mixture of 1:0.8-1.2 ratio；Wherein, aliphatic amide type compound is aliphatic poly ether amide one
Kind；Lipoid substance is one of methyl benzoate and butyl ester or a variety of.
Through the above technical solutions, one aspect of the present invention uses a large amount of bismuth silicates, the content of bismuth is improved, is reduced
Sodium, potassium content, the drawbacks of avoiding dispersion extremely difficult due to sodium, potash glass powder, the preparation of bismuth glass powder is there is not yet open report
Road belongs to pioneering；On the other hand it joined TC-1 esters auxiliary agent, the surface of powder be modified, obtained bismuth glass powder
Body has the advantages that easily to disperse and do not reunite, difficult compared to the traditional powders such as soda-lime glass or potash glass dispersion and easy to reunite with not
Alternative effect, bismuth glass powder of the invention has the advantages that easily to disperse and do not reunite, with glass powder of the invention
After manufactured glass ink stores 3 months, it is still able to maintain the dispersity of initial preparation, has sufficiently achieved wanting for user
It asks.
Dry powder and TC-1 esters auxiliary agent can be adjusted in a wider range, in order to improve the dispersibility of bismuth glass powder,
In a kind of preferred embodiment of the present invention, the mass ratio of dry powder and TC-1 esters auxiliary agent is 100:0.8-1.2.
In order to improve the dispersibility of bismuth glass powder, in a kind of preferred embodiment of the present invention, with bismuth glass powder
Total weight be absolutely to count, the total weight of sodium oxide molybdena and calcium oxide is no more than 8% in the dry powder.
The present invention also provides a kind of superpower dedicated bismuth glass raw powder's production technologies of dispersion performance glass ink, including with
Lower step: (1) including bismuth silicate, boron oxide, lithia, sodium oxide molybdena, calcium oxide by dry powder according to previously described raw material proportioning
It is uniform with phosphotungstic acid mechanical mixture, it melts, it is cooling, obtain M1；(2) M1 is crushed, is sieved, choose the powder less than 1000 mesh in height
Energy ball mill carries out ball milling, so that powder is reached sub-micron rank, obtains M2；(3) TC-1 esters auxiliary agent is sprayed into M2, wherein M2
Weight ratio with TC-1 esters auxiliary agent is 100:0.8-1.2, obtains M3；(4) M3 is sanded in alkane, obtains average grain
Powder of the diameter less than 100 nanometers；Wherein, TC-1 esters auxiliary agent is aliphatic amide type compound and lipoid substance with 1:0.8-
The mixture of 1.2 ratios.
Through the above technical solutions, one aspect of the present invention uses a large amount of bismuth silicates, the content of bismuth is improved, is reduced
Sodium, potassium content, the drawbacks of avoiding dispersion extremely difficult due to sodium, potash glass powder, the preparation of bismuth glass powder is there is not yet open report
Road belongs to pioneering；On the other hand it joined TC-1 esters auxiliary agent, the surface of powder be modified, obtained bismuth glass powder
Body has the advantages that easily to disperse and do not reunite, difficult compared to the traditional powders such as soda-lime glass or potash glass dispersion and easy to reunite with not
Alternative effect, bismuth glass powder of the invention has the advantages that easily to disperse and do not reunite, with glass powder of the invention
After manufactured glass ink stores 3 months, it is still able to maintain the dispersity of initial preparation, has sufficiently achieved wanting for user
It asks.
The condition of melting can be adjusted in a wider range, in a kind of preferred embodiment of the present invention, melting
Condition includes: to melt 30-50 minutes at 1250-1300 DEG C.
In order to improve the dispersibility of bismuth glass powder, in a kind of preferred embodiment of the present invention, in step (4) M3 and
The weight ratio of alkane is 1:1.5-2.
Alkane can be selected in a wider range, in order to improve the dispersibility of bismuth glass powder, of the invention a kind of excellent
In the embodiment of choosing, one of n-octadecane hydrocarbon, n-pentadecane hydrocarbon, n-tetradecane hydrocarbon and n-tridecane hydrocarbon or a variety of.
The present invention also provides a kind of glass ink, including previously described bismuth glass powder, dispersing agent, dispersing aid and anti-
Heavy wax, wherein bismuth glass powder, dispersing agent, dispersing aid and anti-settling wax mass ratio be 35:28-32:4-5:0.3-0.8.
Through the above technical solutions, one aspect of the present invention uses a large amount of bismuth silicates, the content of bismuth is improved, is reduced
Sodium, potassium content, the drawbacks of avoiding dispersion extremely difficult due to sodium, potash glass powder, the preparation of bismuth glass powder is there is not yet open report
Road belongs to pioneering；On the other hand it joined TC-1 esters auxiliary agent, the surface of powder be modified, obtained bismuth glass powder
Body has the advantages that easily to disperse and do not reunite, difficult compared to the traditional powders such as soda-lime glass or potash glass dispersion and easy to reunite with not
Alternative effect, bismuth glass powder of the invention has the advantages that easily to disperse and do not reunite, with glass powder of the invention
After manufactured glass ink stores 3 months, it is still able to maintain the dispersity of initial preparation, has sufficiently achieved wanting for user
It asks.Glass ink of the invention when in use, with ink-jet printer on 60-70 DEG C of tempered glass or simple glass,
Surface drying is reached in 10 seconds, is then sintered again at 680-720 DEG C.
In a kind of preferred embodiment of the present invention, the glass ink further includes cobalt pigment, wherein bismuth glass powder
Mass ratio with cobalt pigment is 35:28-32.
In the above-mentioned technical solutions, dispersing agent can be selected in a wider range, in order to improve point of bismuth glass powder
Dissipate property, obtain stable glass ink, in a kind of preferred embodiment of the present invention, dispersing agent be poly alkyl alcohol ether amide,
One of methyl benzoate, butyl ester, octadecane, diphenyl ether, petroleum ether and butyl ether are a variety of.
In order to improve the dispersibility of bismuth glass powder, stable glass ink is obtained, in a kind of preferred implementation of the invention
In mode, it is preferable that the dispersing agent is poly alkyl alcohol ether amide, methyl benzoate, two kinds in butyl ester.
In the above-mentioned technical solutions, dispersing aid can be selected in a wider range, in order to improve bismuth glass powder
Dispersibility obtains stable glass ink, and in a kind of preferred embodiment of the present invention, dispersing aid is that TC-1 esters help
Agent；Wherein, TC-1 esters auxiliary agent is aliphatic amide type compound and lipoid substance with the mixture of 1:0.8-1.2 ratio；
Wherein, aliphatic amide type compound is poly alkyl alcohol ether amide；Lipoid substance is one of methyl benzoate and butyl ester
Or two kinds.
The present invention will be described in detail by way of examples below.In the present invention, using the Malvern grain of Britain's production
Degree detector carries out testing product partial size: taking 0.1 gram of sample dispersion into 10 ml deionized waters, mechanical stirring, ultrasonic disperse
Turbid is made within 10 minutes, then takes 1 milliliter of turbid to make sample and detected.
Preparation example 1
1, it is formulated:
Take dry powder: 8 parts of bismuth silicate, 5 parts of boron oxide, 3 parts of lithia, 4 parts of sodium oxide molybdena, 4 parts of calcium oxide and phosphotungstic acid 0.2
Part；
Take TC-1 esters auxiliary agent, the mass ratio of dry powder and TC-1 esters auxiliary agent is 100:0.8；TC-1 esters auxiliary agent is quality
Than the aliphatic poly ether amide and methyl benzoate for 1:0.8.
2, preparation method
(1) according to composition of raw materials above, by dry powder include bismuth silicate, boron oxide, lithia, sodium oxide molybdena, calcium oxide and
Phosphotungstic acid mechanical mixture is uniform, melts 30 minutes at 1250 DEG C, cooling, obtains M1；
(2) M1 is crushed, is sieved, the powder chosen less than 1000 mesh carries out ball milling in high energy ball mill, reaches powder
Sub-micron rank, obtains M2；
(3) TC-1 esters auxiliary agent is sprayed into M2, it is desirable that be greater than 30 minutes and sprayed；
(4) M3 is sanded in alkane, the weight ratio of M3 and alkane obtains average grain diameter for 1:1.5 and receives less than 100
The bismuth glass powder of rice；Wherein, alkane is n-octadecane hydrocarbon.
Preparation example 2
1, it is formulated:
Take dry powder: 85 parts of bismuth silicate, 6 parts of boron oxide, 4 parts of lithia, 6 parts of sodium oxide molybdena, 6 parts of calcium oxide and phosphotungstic acid 0.8
Part；
Take TC-1 esters auxiliary agent, the mass ratio of dry powder and TC-1 esters auxiliary agent is 100:1.2；TC-1 esters auxiliary agent is quality
Than the aliphatic poly ether amide and butyl ester for 1:1.2.
2, preparation method
(1) according to composition of raw materials above, by dry powder include bismuth silicate, boron oxide, lithia, sodium oxide molybdena, calcium oxide and
Phosphotungstic acid mechanical mixture is uniform, melts 50 minutes at 1300 DEG C, cooling, obtains M1；
(2) M1 is crushed, is sieved, the powder chosen less than 1000 mesh carries out ball milling in high energy ball mill, reaches powder
Sub-micron rank, obtains M2；
(3) TC-1 esters auxiliary agent is sprayed into M2, it is desirable that be greater than 30 minutes and sprayed；
(4) M3 is sanded in alkane, the weight ratio of M3 and alkane is that 1:2 obtains average grain diameter less than 100 nanometers
Bismuth glass powder；Wherein, alkane is positive pentadecane.
Preparation example 3
1, it is formulated:
Take dry powder: 83 parts of bismuth silicate, 5.5 parts of boron oxide, 3.5 parts of lithia, 5 parts of sodium oxide molybdena, 5 parts of calcium oxide and phosphotungstic acid
0.5 part；
Take TC-1 esters auxiliary agent, the mass ratio of dry powder and TC-1 esters auxiliary agent is 100:1；TC-1 esters auxiliary agent is mass ratio
For the aliphatic poly ether amide and methyl benzoate of 1:1.
2, preparation method
(1) according to composition of raw materials above, by dry powder include bismuth silicate, boron oxide, lithia, sodium oxide molybdena, calcium oxide and
Phosphotungstic acid mechanical mixture is uniform, melts 40 minutes at 1280 DEG C, cooling, obtains M1；
(2) M1 is crushed, is sieved, the powder chosen less than 1000 mesh carries out ball milling in high energy ball mill, reaches powder
Sub-micron rank, obtains M2；
(3) TC-1 esters auxiliary agent is sprayed into M2, it is desirable that be greater than 30 minutes and sprayed；
(4) M3 is sanded in alkane, the weight ratio of M3 and alkane obtains average grain diameter for 1:1.8 and receives less than 100
The bismuth glass powder of rice；Wherein, alkane is n-tetradecane hydrocarbon.
Embodiment 1
After above-mentioned raw materials are dispersed 3 hours in sand mill, Malvern granularity Detection result is as shown in Figure 1.
Obtain mean particle size < 200nm glass ink.
After storage 3 months, jiggle uniformly, average grain diameter < 220nm.Compared to freshly prepd glass ink, there is no bright
It is aobvious to reunite, fully meet the requirement of glass ink.
The glass ink just prepared using S-4800 transmitting scanning electron microanalyzer (Hitachi, Japan) test and storage
The pattern of glass ink after depositing 3 months.As a result as shown in Figures 2 and 3, wherein Fig. 2 is just to prepare particle in bismuth glass ink
Pattern；Fig. 3 be store 3 months after after 3 months in bismuth glass ink particle pattern.As it can be seen that glass ink after storage 3 months
Middle particle dispersion can be good, and there is no apparent agglomerations.
Embodiment 2
After dispersing 3 hours in sand mill, average grain diameter < 180nm.
After storage 3 months, jiggle uniformly, average grain diameter < 210nm.Compared to freshly prepd glass ink, there is no bright
It is aobvious to reunite, fully meet the requirement of glass ink.
The glass ink just prepared using S-4800 transmitting scanning electron microanalyzer (Hitachi, Japan) test and storage
The pattern of glass ink after depositing 3 months.As a result close with the testing result in embodiment 1, it is seen then that glass after storage 3 months
Particle dispersion can be good in ink, and there is no apparent agglomerations.
Embodiment 3
Disperse 3 hours in sand mill.
Embodiment 4
Disperse 3 hours in sand mill.
Through being detected to the glass ink in embodiment 3 and embodiment 4, it is found that after storage 3 months, jiggle uniformly, put down
Equal partial size < 220nm.Compared to freshly prepd glass ink, reunites there is no obvious, fully meet the requirement of glass ink.
The preferred embodiment of the present invention has been described above in detail, still, during present invention is not limited to the embodiments described above
Detail within the scope of the technical concept of the present invention can be with various simple variants of the technical solution of the present invention are made, this
A little simple variants all belong to the scope of protection of the present invention.
It is further to note that specific technical features described in the above specific embodiments, in not lance
In the case where shield, can be combined in any appropriate way, in order to avoid unnecessary repetition, the present invention to it is various can
No further explanation will be given for the combination of energy.
In addition, various embodiments of the present invention can be combined randomly, as long as it is without prejudice to originally
The thought of invention, it should also be regarded as the disclosure of the present invention.
Claims (7)
1. a kind of dedicated bismuth glass powder of superpower dispersion performance glass ink, which is characterized in that including dry powder and TC-1 esters
Auxiliary agent, wherein in parts by weight, the dry powder includes: 80-85 parts of bismuth silicate, 5-6 parts of boron oxide, 3-4 parts of lithia, is aoxidized
4-6 parts of sodium, 4-6 parts of calcium oxide, 0.2-0.8 parts of phosphotungstic acid；
Wherein, TC-1 esters auxiliary agent is aliphatic amide type compound and lipoid substance with the mixture of 1:0.8-1.2 ratio；
Wherein, aliphatic amide type compound is poly alkyl alcohol ether amide；
Lipoid substance is one or both of methyl benzoate and butyl ester.
2. bismuth glass powder according to claim 1, wherein the mass ratio of dry powder and TC-1 esters auxiliary agent is 1:0.8-
1.2。
3. bismuth glass powder according to claim 1 or 2, wherein by the total weight of bismuth glass powder be absolutely in terms of,
The total weight of sodium oxide molybdena and calcium oxide is no more than 8% in the dry powder.
4. a kind of dedicated bismuth glass raw powder's production technology of superpower dispersion performance glass ink, which is characterized in that including following
Step:
It (1) include bismuth silicate, boron oxide, lithia, sodium oxide molybdena, oxygen by dry powder according to raw material proportioning described in claim 1-3
Change calcium and phosphotungstic acid mechanical mixture is uniform, melts, it is cooling, obtain M1；
(2) M1 is crushed, is sieved, the powder chosen less than 1000 mesh carries out ball milling in high energy ball mill, and powder is made to reach sub-micro
Meter level is other, obtains M2；
(3) TC-1 esters auxiliary agent is sprayed into M2, wherein the weight ratio of M2 and TC-1 esters auxiliary agent is 100:0.8-1.2, is obtained
M3；
(4) M3 is sanded in alkane, obtains powder of the average grain diameter less than 100 nanometers；
Wherein, TC-1 esters auxiliary agent is aliphatic amide type compound and lipoid substance with the mixture of 1:0.8-1.2 ratio.
5. the preparation method according to claim 4, wherein the condition of melting includes: to melt 30- at 1250-1300 DEG C
50 minutes.
6. the preparation method according to claim 4, wherein the weight ratio of M3 and alkane is 1:1.5-2 in step (4).
7. the preparation method according to claim 4, wherein alkane is selected from n-octadecane hydrocarbon, n-pentadecane hydrocarbon, n-tetradecane
One of hydrocarbon and n-tridecane hydrocarbon are a variety of.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910308804.0A CN110054934A (en) | 2019-04-17 | 2019-04-17 | A kind of dedicated bismuth glass powder of superpower dispersion performance glass ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910308804.0A CN110054934A (en) | 2019-04-17 | 2019-04-17 | A kind of dedicated bismuth glass powder of superpower dispersion performance glass ink and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110054934A true CN110054934A (en) | 2019-07-26 |
Family
ID=67319235
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910308804.0A Pending CN110054934A (en) | 2019-04-17 | 2019-04-17 | A kind of dedicated bismuth glass powder of superpower dispersion performance glass ink and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110054934A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010116541A (en) * | 2008-10-16 | 2010-05-27 | Nissei Kogyo Kk | Ink for inorganic material |
| CN105153809A (en) * | 2015-09-22 | 2015-12-16 | 东莞市贝特利新材料有限公司 | Glass ink-jet printing ink |
| CN106085006A (en) * | 2016-06-16 | 2016-11-09 | 江苏大学 | Glass surface inkjet printing bismuth silicon boron system low melting point ink and preparation method thereof |
| US20170240459A1 (en) * | 2016-02-18 | 2017-08-24 | Prince Minerals Italy S.R.L. | Ceramic ink for automotive glass |
| CN107201083A (en) * | 2017-05-25 | 2017-09-26 | 山东国瓷康立泰新材料科技有限公司 | A kind of ink-jet anti slip glass ink and preparation method thereof |
| CN107523117A (en) * | 2017-08-14 | 2017-12-29 | 广东工业大学 | A kind of tempered glass of automobile ink and preparation method thereof |
-
2019
- 2019-04-17 CN CN201910308804.0A patent/CN110054934A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010116541A (en) * | 2008-10-16 | 2010-05-27 | Nissei Kogyo Kk | Ink for inorganic material |
| CN105153809A (en) * | 2015-09-22 | 2015-12-16 | 东莞市贝特利新材料有限公司 | Glass ink-jet printing ink |
| US20170240459A1 (en) * | 2016-02-18 | 2017-08-24 | Prince Minerals Italy S.R.L. | Ceramic ink for automotive glass |
| CN106085006A (en) * | 2016-06-16 | 2016-11-09 | 江苏大学 | Glass surface inkjet printing bismuth silicon boron system low melting point ink and preparation method thereof |
| CN107201083A (en) * | 2017-05-25 | 2017-09-26 | 山东国瓷康立泰新材料科技有限公司 | A kind of ink-jet anti slip glass ink and preparation method thereof |
| CN107523117A (en) * | 2017-08-14 | 2017-12-29 | 广东工业大学 | A kind of tempered glass of automobile ink and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 郝晓秀: "《包装材料学》", 30 June 2006, 印刷工业出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| WO2016176872A1 (en) | Ceramic decoration high-temperature bright red inkjet ink and preparation method and use thereof | |
| CN103911024B (en) | Glass pigment micro powder, dispersion liquid, ink-jet ink and forming method thereof | |
| EP2511353B1 (en) | Ink composition for a water-based ballpoint pen, and water-based ballpoint pen | |
| JP5375107B2 (en) | Ink jet ink, ink cartridge, image forming apparatus, image forming method, and image formed product | |
| CN109651883B (en) | Black ceramic ink and preparation method thereof | |
| EP1458819B1 (en) | Solid pigment composition for pigment ink, pigment ink containing the same, and process for preparing these | |
| CN109054452A (en) | Copper-chromium black pigment and preparation method thereof | |
| CN104858422A (en) | Stainless steel composite powder for 3D printing and preparation method of stainless steel composite powder for 3D printing | |
| JP7394929B2 (en) | water-based ballpoint pen | |
| CN105524524A (en) | Neutral ink prepared from self-dispersing pigment color paste and preparation method thereof | |
| CN110683578A (en) | Production method of high-activity electrofused zirconia | |
| CN106009892A (en) | Ink composition | |
| US5510397A (en) | Aqueous pigment ink composition for writing utensils | |
| CN110054934A (en) | A kind of dedicated bismuth glass powder of superpower dispersion performance glass ink and preparation method thereof | |
| KR100824387B1 (en) | Soluble Dispersion-Process Pigment and Method for Manufacturing thereof | |
| KR20220117322A (en) | Ink composition for water-based ballpoint pen | |
| CN111748222B (en) | High-tinting strength copper-chromium black pigment and preparation method thereof | |
| WO2017215099A1 (en) | Bismuth-silicon-boron-based low-melting-point nano glass powder suspension for glass jet drawing and preparation method | |
| JP4387044B2 (en) | Ink follower and water-based ballpoint pen having the same | |
| US10711147B2 (en) | Writing ink composition for aqueous ballpoint pen, ballpoint pen employing the same, and process for producing the writing ink composition for aqueous ballpoint pen | |
| CN115505289B (en) | Black ceramic ink, preparation method and application thereof, and ceramic product | |
| CN103694797B (en) | Brown nano-ceramics ink-jet ink and preparation method thereof | |
| JP3400836B2 (en) | Pigment dispersion method | |
| CN212263106U (en) | Device for preparing high-solid-content water-based carbon nanotube conductive slurry | |
| EP1390435B8 (en) | Method of making a pigment dispersion containing a carrier such as castor oil or vegetable wax |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190726 |
|
| RJ01 | Rejection of invention patent application after publication |