CN110053266A - A kind of complex method and PMMA composite plate of PMMA plate - Google Patents
A kind of complex method and PMMA composite plate of PMMA plate Download PDFInfo
- Publication number
- CN110053266A CN110053266A CN201910439875.4A CN201910439875A CN110053266A CN 110053266 A CN110053266 A CN 110053266A CN 201910439875 A CN201910439875 A CN 201910439875A CN 110053266 A CN110053266 A CN 110053266A
- Authority
- CN
- China
- Prior art keywords
- pmma
- plate
- film
- composite
- thickness
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920003229 poly(methyl methacrylate) Polymers 0.000 title claims abstract description 161
- 239000004926 polymethyl methacrylate Substances 0.000 title claims abstract description 161
- 239000002131 composite material Substances 0.000 title claims abstract description 47
- 238000000034 method Methods 0.000 title claims abstract description 30
- 230000004927 fusion Effects 0.000 claims abstract description 18
- 238000001816 cooling Methods 0.000 claims abstract description 11
- 239000012528 membrane Substances 0.000 claims abstract description 9
- 238000007493 shaping process Methods 0.000 claims abstract description 8
- 150000001875 compounds Chemical class 0.000 abstract description 21
- 238000004519 manufacturing process Methods 0.000 abstract description 14
- 238000010382 chemical cross-linking Methods 0.000 abstract description 3
- 239000004566 building material Substances 0.000 abstract description 2
- 239000010408 film Substances 0.000 description 30
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
- 238000005266 casting Methods 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 238000003475 lamination Methods 0.000 description 3
- -1 acryl Chemical group 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000011120 plywood Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 235000019628 coolness Nutrition 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 235000021050 feed intake Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/40—General aspects of joining substantially flat articles, e.g. plates, sheets or web-like materials; Making flat seams in tubular or hollow articles; Joining single elements to substantially flat surfaces
- B29C66/41—Joining substantially flat articles ; Making flat seams in tubular or hollow articles
- B29C66/45—Joining of substantially the whole surface of the articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2033/00—Use of polymers of unsaturated acids or derivatives thereof as moulding material
- B29K2033/04—Polymers of esters
- B29K2033/12—Polymers of methacrylic acid esters, e.g. PMMA, i.e. polymethylmethacrylate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2007/00—Flat articles, e.g. films or sheets
- B29L2007/002—Panels; Plates; Sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2009/00—Layered products
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention provides a kind of complex method of PMMA plate and PMMA composite plates, are related to building material technical field.The present invention presss from both sides one layer of PMMA film of patch between adjacent PMMA plate, successively carries out fusion and cooling shaping, obtains composite plate;The PMMA plate is PMMA transparent panel or PMMA autochromatic plate, and the PMMA film is PMMA transparent membrane or PMMA colorful film.The present invention, by fusion and cooling shaping, two pieces or muti-piece PMMA plate is combined with each other, to form the plate of new thickness using PMMA film as a kind of unique chemical crosslinking medium;Wherein, PMMA film and PMMA plate can be transparent or colour, and PMMA transparent composite sheet, PMMA colour composite plate or the double-colored composite plate of PMMA can be obtained by compound.Period of the invention is short, and production is quick, and the same day can go out finished product, and a plate can also be switched on production, and various thickness and color may customize.
Description
Technical field
The present invention relates to building material technical field, in particular to the complex method and PMMA composite plate of a kind of PMMA plate.
Background technique
Existing acrylic (PMMA, polymethyl methacrylate) clear sheet, be all by a certain given thickness (3mm,
5mm, 10mm are thicker) casting is solidified into plate or extrusion molding, i.e., and a kind of thickness production, feed intake has minimum every time
Amount requires (more than general 1000Kg or more or 15 on-gauge plate), and the production cycle is all at 5 days or more.
Existing acrylic autochromatic plate is that mill base is evenly mixed in the PMMA resin of liquid clear solidification of casting by producer
Forming, color is that entity is applied in entire acryl plates thickness.Acrylic double-colored plate refers to that there are two types of not for a plate front and back sides
With the acrylic board of color, it is chiefly used in label text engraving or lamp box production.Acrylic double-colored plate need to be poured altogether in actual production
Three times, the acrylic board of two of them color will respectively cast once for casting, during this, reaction kettle color modulation plate mill base needs one
Fixed output feeds intake and at least wants 500Kg or more, cannot achieve on a small quantity, and solidified forming needs 7 days or so;Then two kinds of face
The different-thickness autochromatic plate of color is cast on together again, and the production cycle of front and back in this way is about at 10 days or more.
Market of the production method of the above acryl plates for current customizing, multi-thickness, multicolour, small lot
For, it is far from suitable.
Summary of the invention
In view of this, the purpose of the present invention is to provide a kind of complex method of PMMA plate and PMMA composite plates.The present invention
The complex method period of offer is short, and production is quick, and a plate can also be switched on production, and various thickness and color may customize.
In order to achieve the above-mentioned object of the invention, the present invention the following technical schemes are provided:
The present invention provides a kind of complex methods of PMMA plate, comprising the following steps:
One layer of PMMA film of folder patch, successively carries out fusion and cooling shaping, it is compound to obtain PMMA between adjacent PMMA plate
Plate;The PMMA plate is PMMA transparent panel or PMMA autochromatic plate, and the PMMA film is that PMMA transparent membrane or PMMA colour are thin
Film.
Preferably, the total quantity of the PMMA plate is more than or equal to 2 pieces.
Preferably, the thickness of the PMMA plate independently is 2~50mm.
Preferably, the PMMA film with a thickness of 0.2~0.3mm.
Preferably, the temperature of the fusion is 105~150 DEG C.
Preferably, the pressure of the fusion is 0.9~1.2MPa.
Preferably, the time of the fusion is 45~50min.
The present invention provides a kind of complex method of PMMA plate, one layer of PMMA film of folder patch between adjacent PMMA plate, according to
It is secondary to carry out fusion and cooling shaping, obtain composite board;The PMMA plate is PMMA transparent panel or PMMA autochromatic plate, the PMMA
Film is PMMA transparent membrane or PMMA colorful film.The present invention using PMMA film as a kind of unique chemical crosslinking medium,
By fusing the process with cooling shaping, two pieces or muti-piece PMMA plate are combined with each other, to form the plate of new thickness;Its
In, PMMA film and PMMA plate can be transparent or colour, pass through compound available PMMA transparent composite sheet, PMMA
Colored composite plate or the double-colored composite plate of PMMA.The complex method period provided by the invention is short, and production is quick, and the same day can go out into
Product, a plate can also be switched on production, and various thickness and color are customizable.
The present invention provides the PMMA composite plates that complex method described in above scheme obtains.PMMA provided by the invention is compound
Plate can be PMMA transparent composite sheet, PMMA colour composite plate or the double-colored composite plate of PMMA of different-thickness.
Detailed description of the invention
Fig. 1 is the compound schematic diagram of PMMA transparent panel in embodiment 1, wherein 1 indicates PMMA transparent panel, 2 indicate that PMMA is saturating
Isotropic disk, 3 indicate PMMA transparent membrane.
Specific embodiment
The present invention provides a kind of complex methods of PMMA plate, comprising the following steps:
One layer of PMMA film of folder patch, successively carries out fusion and cooling shaping, obtains composite plate between adjacent PMMA plate;Institute
Stating PMMA plate is PMMA transparent panel or PMMA autochromatic plate, and the PMMA film is PMMA transparent membrane or PMMA colorful film.
In the present invention, the total quantity of the PMMA plate is preferably greater than or equal to 2 pieces, i.e., the method for the present invention can by two pieces or
The compound composite plate for obtaining different-thickness of muti-piece PMMA plate.In the present invention, the thickness of the PMMA plate is independently preferably 2
~50mm.The present invention preferably selects the thickness of the PMMA plate respectively according to the thickness of final required composite board, with two pieces
PMMA plate it is compound for: the composite board as needed for final with a thickness of 13mm, then the thickness of two blocks of PMMA plates can divide
It Wei not 3mm and 10mm;The composite board as needed for final with a thickness of 17mm, then the thickness of two blocks of PMMA plates can be respectively
5mm and 12mm.In the present invention, the PMMA plate is PMMA transparent panel or PMMA autochromatic plate.The present invention is transparent to the PMMA
The source of plate or PMMA autochromatic plate does not require particularly, is using PMMA transparent panel well known in the art or PMMA autochromatic plate
It can.Two pieces of different-thickness or muti-piece PMMA plate are combined with each other by the present invention as required, can customize answering for various thickness
Plywood material.
In the present invention, the thickness of the PMMA film is preferably 0.2~0.3mm, more preferably 0.2mm.In invention,
The size of the PMMA film is preferably identical as the size of the PMMA transparent panel.In the present invention, the PMMA film is
PMMA transparent membrane or PMMA colorful film.The present invention is using PMMA film as a kind of unique chemical crosslinking medium, by two pieces
Or muti-piece PMMA plate is combined with each other, and forms the plate of target thickness, because of the thickness very little of the PMMA film, relative to multiple
The thickness of plywood material can be ignored;And PMMA film and PMMA plate can be transparent or colour, by compound
PMMA transparent composite sheet, PMMA colour composite plate or the double-colored composite plate of PMMA of available different-thickness.With two blocks of PMMA plates
It is compound for: when the PMMA film and two blocks of PMMA plates are transparent, gained composite plate be PMMA transparent composite sheet;When
When the PMMA film and two blocks of PMMA plates are same color, gained composite plate is PMMA colour composite plate;When described two
Block PMMA plate be different color or one piece be it is colored, when one piece is transparent, gained composite plate is the double-colored composite plate of PMMA.At this
In invention, the color of the PMMA film and PMMA plate can carry out multicolour combination according to actual needs, to generate not
Same colouring effect.In the present invention, the PMMA film preferably passes through extrusion film technique and PMMA forms a film, and carries out to film
Sandization processing in surface obtains;The method that the present invention handles the extrusion film technique and surface sandization is not wanted particularly
It asks, using method well known in the art.
In the present invention, the temperature of the fusion is preferably 105~150 DEG C, and more preferably 130~140 DEG C, pressure is preferred
For 0.9~1.2MPa, more preferably 1.0MPa;The time of the fusion is preferably 45~50min, more preferably 50min.At this
In invention, the fusion is preferably carried out using compound press, i.e., the PMMA plate that folder posts PMMA film is sent into compound press,
Compacting fusion is carried out under the conditions of above-mentioned temperature and pressure.The present invention does not require the compound press particularly, using ability
Compound press known to domain.
In the present invention, the cooling preferably uses 18~25 DEG C of cooling water to recycle in the plate face of the compound press
Method carry out, so that PMMA plate through high-temperature fusion is shaped and do not rebound, fusion is integral.In the present invention, the PMMA plate with
PMMA film is similar polymer substance, is fused together after being suppressed by compound press, the composite plate obtained after cooling shaping
It will not show apparent lamination, and the case where be not in cracking, will not influence the appearance and usability of PMMA plate
Energy.The complex method period provided by the invention is short, and production is quick, and the same day can go out finished product, and a plate can also be switched on production, and
Various thickness and color are customizable.
The present invention provides the PMMA composite plates that complex method described in above scheme obtains.PMMA provided by the invention is compound
Plate can be PMMA transparent composite sheet, PMMA colour composite plate or the double-colored composite plate of PMMA of different-thickness, i.e. the present invention provides
PMMA composite plate can carry out different settings according to reality for the needs of plate thickness and color effects.For example, working as institute
When to state PMMA film and two blocks of PMMA plates be transparent, the composite plate is PMMA transparent composite sheet;When the PMMA film and
When two blocks of PMMA plates are same color, the composite plate is PMMA colour composite plate;When two blocks of PMMA plates are difference
Color or one piece be it is colored, when one piece is transparent, the composite plate is the double-colored composite plate of PMMA;Wherein, the PMMA plate
Thickness, which can according to need, makees different settings, and then obtains the PMMA composite plate of different-thickness, different color effect.
It is carried out specifically below with reference to complex method and PMMA composite plate of the embodiment to PMMA plate provided by the invention
It is bright, but they cannot be interpreted as limiting the scope of the present invention.
Embodiment 1
By the PMMA transparent membrane of 0.2mm thickness, be seated in advance two panels different-thickness transparent PMMA acryl plates it
Between, the thickness of the transparent PMMA acryl plates of two panels is respectively 5mm, 10mm, be then fed into compound press, 150 DEG C of high temperature,
It is fused 45 minutes under 1.2MPa high pressure, then after cooling, setting, obtains the transparent panel of 15mm thickness.PMMA transparent panel it is compound such as
Shown in Fig. 1.
The transparent panel obtained after compound does not show lamination, does not also occur the case where cracking in use.
Embodiment 2
By the PMMA transparent membrane of 0.3mm thickness, it is seated between the PMMA acryl plates of two panels different-thickness in advance, two
Piece PMMA acryl plates are respectively the autochromatic plate of thickness 5mm and the transparent panel of thickness 10mm, are then fed into compound press,
It is fused 50 minutes under 110 DEG C of high temperature, 1.2MPa high pressure, then after 18 DEG C of industry water coolings, setting, obtains the double-colored of 15mm thickness
Plate.
The double-colored plate obtained after compound does not show lamination, does not also occur the case where cracking in use.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered
It is considered as protection scope of the present invention.
Claims (8)
1. a kind of complex method of PMMA plate, which comprises the following steps:
One layer of PMMA film of folder patch, successively carries out fusion and cooling shaping, obtains PMMA composite plate between adjacent PMMA plate;Institute
Stating PMMA plate is PMMA transparent panel or PMMA autochromatic plate, and the PMMA film is PMMA transparent membrane or PMMA colorful film.
2. complex method according to claim 1, which is characterized in that the total quantity of the PMMA plate is more than or equal to 2 pieces.
3. complex method according to claim 1 or 2, which is characterized in that the thickness of the PMMA plate independently is 2~
50mm。
4. complex method according to claim 1, which is characterized in that the PMMA film with a thickness of 0.2~0.3mm.
5. complex method according to claim 1, which is characterized in that the temperature of the fusion is 105~150 DEG C.
6. complex method according to claim 1, which is characterized in that the pressure of the fusion is 0.9~1.2MPa.
7. complex method described according to claim 1 or 5 or 6, which is characterized in that the time of the fusion is 45~50min.
8. the PMMA composite plate that complex method described in claim 1~7 any one obtains.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201910439875.4A CN110053266A (en) | 2019-05-24 | 2019-05-24 | A kind of complex method and PMMA composite plate of PMMA plate |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201910439875.4A CN110053266A (en) | 2019-05-24 | 2019-05-24 | A kind of complex method and PMMA composite plate of PMMA plate |
Publications (1)
Publication Number | Publication Date |
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CN110053266A true CN110053266A (en) | 2019-07-26 |
Family
ID=67324438
Family Applications (1)
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CN201910439875.4A Pending CN110053266A (en) | 2019-05-24 | 2019-05-24 | A kind of complex method and PMMA composite plate of PMMA plate |
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5970514A (en) * | 1982-10-17 | 1984-04-21 | Toko Kasen Kogyo Kk | Preparation of kilting cloth |
JP2005202097A (en) * | 2004-01-15 | 2005-07-28 | Sumitomo Chemical Co Ltd | Multilayered light diffusion board |
CN104487244A (en) * | 2012-07-23 | 2015-04-01 | 电气化学工业株式会社 | Multilayer sheet, backsheet for solar cell and solar cell module |
CN205112586U (en) * | 2015-09-25 | 2016-03-30 | 深圳卡乐板实业有限公司 | Colored PETG light -passing board |
CN205112584U (en) * | 2015-09-25 | 2016-03-30 | 深圳卡乐板实业有限公司 | Colored PMMA light -passing board |
CN107787274A (en) * | 2015-05-05 | 2018-03-09 | E·特斯塔 | The manufacture method of laminated polymeric produce product |
-
2019
- 2019-05-24 CN CN201910439875.4A patent/CN110053266A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5970514A (en) * | 1982-10-17 | 1984-04-21 | Toko Kasen Kogyo Kk | Preparation of kilting cloth |
JP2005202097A (en) * | 2004-01-15 | 2005-07-28 | Sumitomo Chemical Co Ltd | Multilayered light diffusion board |
CN104487244A (en) * | 2012-07-23 | 2015-04-01 | 电气化学工业株式会社 | Multilayer sheet, backsheet for solar cell and solar cell module |
CN107787274A (en) * | 2015-05-05 | 2018-03-09 | E·特斯塔 | The manufacture method of laminated polymeric produce product |
CN205112586U (en) * | 2015-09-25 | 2016-03-30 | 深圳卡乐板实业有限公司 | Colored PETG light -passing board |
CN205112584U (en) * | 2015-09-25 | 2016-03-30 | 深圳卡乐板实业有限公司 | Colored PMMA light -passing board |
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PB01 | Publication | ||
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Application publication date: 20190726 |