CN110040978B - 一种自洁净防雾玻璃的制备工艺 - Google Patents
一种自洁净防雾玻璃的制备工艺 Download PDFInfo
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- CN110040978B CN110040978B CN201910342073.1A CN201910342073A CN110040978B CN 110040978 B CN110040978 B CN 110040978B CN 201910342073 A CN201910342073 A CN 201910342073A CN 110040978 B CN110040978 B CN 110040978B
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- Prior art keywords
- solution
- glass
- self
- titanium dioxide
- cleaning
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- 239000011521 glass Substances 0.000 title claims abstract description 117
- 238000004140 cleaning Methods 0.000 title claims abstract description 43
- 238000002360 preparation method Methods 0.000 title claims abstract description 34
- BHTBHKFULNTCHQ-UHFFFAOYSA-H zinc;tin(4+);hexahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Zn+2].[Sn+4] BHTBHKFULNTCHQ-UHFFFAOYSA-H 0.000 claims abstract description 52
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims abstract description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000000758 substrate Substances 0.000 claims abstract description 16
- 238000000576 coating method Methods 0.000 claims abstract description 15
- 239000011248 coating agent Substances 0.000 claims abstract description 14
- 229940103272 aluminum potassium sulfate Drugs 0.000 claims abstract description 7
- -1 aluminum potassium sulfate modified nano titanium dioxide Chemical class 0.000 claims abstract description 7
- 238000005507 spraying Methods 0.000 claims description 41
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 30
- 239000007788 liquid Substances 0.000 claims description 30
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 26
- 238000003756 stirring Methods 0.000 claims description 24
- 238000002156 mixing Methods 0.000 claims description 20
- 238000001035 drying Methods 0.000 claims description 15
- 229960000583 acetic acid Drugs 0.000 claims description 13
- 239000012362 glacial acetic acid Substances 0.000 claims description 13
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 claims description 12
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 10
- 238000001816 cooling Methods 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 6
- GNHOJBNSNUXZQA-UHFFFAOYSA-J potassium aluminium sulfate dodecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.[Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GNHOJBNSNUXZQA-UHFFFAOYSA-J 0.000 claims description 6
- 230000032683 aging Effects 0.000 claims description 5
- GRLPQNLYRHEGIJ-UHFFFAOYSA-J potassium aluminium sulfate Chemical compound [Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRLPQNLYRHEGIJ-UHFFFAOYSA-J 0.000 claims description 5
- 238000004528 spin coating Methods 0.000 claims description 2
- 238000003892 spreading Methods 0.000 claims description 2
- 230000007480 spreading Effects 0.000 claims description 2
- 238000002834 transmittance Methods 0.000 abstract description 13
- 230000000694 effects Effects 0.000 abstract description 10
- STZCRXQWRGQSJD-GEEYTBSJSA-M methyl orange Chemical compound [Na+].C1=CC(N(C)C)=CC=C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 STZCRXQWRGQSJD-GEEYTBSJSA-M 0.000 abstract description 10
- 229940012189 methyl orange Drugs 0.000 abstract description 10
- 230000015556 catabolic process Effects 0.000 abstract description 8
- 238000006731 degradation reaction Methods 0.000 abstract description 8
- 239000000243 solution Substances 0.000 description 119
- 239000010408 film Substances 0.000 description 64
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 40
- 230000000052 comparative effect Effects 0.000 description 28
- 239000005348 self-cleaning glass Substances 0.000 description 24
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 13
- 239000013078 crystal Substances 0.000 description 11
- 239000007921 spray Substances 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 7
- 230000001699 photocatalysis Effects 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 229910010280 TiOH Inorganic materials 0.000 description 3
- 238000002835 absorbance Methods 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 230000000670 limiting effect Effects 0.000 description 3
- 239000011259 mixed solution Substances 0.000 description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- 230000006978 adaptation Effects 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 238000001755 magnetron sputter deposition Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000002086 nanomaterial Substances 0.000 description 2
- 239000002105 nanoparticle Substances 0.000 description 2
- 238000007146 photocatalysis Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- LLZRNZOLAXHGLL-UHFFFAOYSA-J titanic acid Chemical compound O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- RYSXWUYLAWPLES-MTOQALJVSA-N (Z)-4-hydroxypent-3-en-2-one titanium Chemical compound [Ti].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O RYSXWUYLAWPLES-MTOQALJVSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 description 1
- 239000007888 film coating Substances 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 230000004298 light response Effects 0.000 description 1
- 239000008204 material by function Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 239000005543 nano-size silicon particle Substances 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 150000005837 radical ions Chemical class 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- STZCRXQWRGQSJD-UHFFFAOYSA-M sodium;4-[[4-(dimethylamino)phenyl]diazenyl]benzenesulfonate Chemical compound [Na+].C1=CC(N(C)C)=CC=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 STZCRXQWRGQSJD-UHFFFAOYSA-M 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 230000003075 superhydrophobic effect Effects 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3411—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
- C03C17/3417—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials all coatings being oxide coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/112—Deposition methods from solutions or suspensions by spraying
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Surface Treatment Of Glass (AREA)
- Catalysts (AREA)
Abstract
Description
组别 | 可见光透过率(%) |
实施例1 | 86.2 |
实施例2 | 85.6 |
实施例3 | 87.7 |
对比例1 | 85.5 |
对比例2 | 81.8 |
对比例3 | 83.4 |
对比例4 | 87.0 |
对比例5 | 85.2 |
组别 | 甲基橙的降解率(%) |
实施例1 | 85.0 |
实施例2 | 87.5 |
实施例3 | 86.2 |
对比例1 | 79.6 |
对比例2 | 82.1 |
对比例3 | 83.3 |
对比例4 | 74.0 |
对比例5 | 78.2 |
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201910342073.1A CN110040978B (zh) | 2019-04-26 | 2019-04-26 | 一种自洁净防雾玻璃的制备工艺 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201910342073.1A CN110040978B (zh) | 2019-04-26 | 2019-04-26 | 一种自洁净防雾玻璃的制备工艺 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN110040978A CN110040978A (zh) | 2019-07-23 |
CN110040978B true CN110040978B (zh) | 2020-05-15 |
Family
ID=67279479
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN201910342073.1A Active CN110040978B (zh) | 2019-04-26 | 2019-04-26 | 一种自洁净防雾玻璃的制备工艺 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN110040978B (zh) |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101822977A (zh) * | 2010-03-31 | 2010-09-08 | 山东理工大学 | ZnSn(OH)6多孔光催化材料的制备方法 |
CN104117347A (zh) * | 2013-04-28 | 2014-10-29 | 浙江高明玻璃有限公司 | 一种改性纳米二氧化钛薄膜的制备方法 |
CN106582892A (zh) * | 2016-04-28 | 2017-04-26 | 北京华钛高科科技有限公司 | 纳米TiO2涂层结构及其制备方法和用途 |
CN108079984A (zh) * | 2017-12-11 | 2018-05-29 | 河南师范大学 | 一种圆角立方体型羟基锡酸锌太阳光催化剂的制备方法 |
-
2019
- 2019-04-26 CN CN201910342073.1A patent/CN110040978B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101822977A (zh) * | 2010-03-31 | 2010-09-08 | 山东理工大学 | ZnSn(OH)6多孔光催化材料的制备方法 |
CN104117347A (zh) * | 2013-04-28 | 2014-10-29 | 浙江高明玻璃有限公司 | 一种改性纳米二氧化钛薄膜的制备方法 |
CN106582892A (zh) * | 2016-04-28 | 2017-04-26 | 北京华钛高科科技有限公司 | 纳米TiO2涂层结构及其制备方法和用途 |
CN108079984A (zh) * | 2017-12-11 | 2018-05-29 | 河南师范大学 | 一种圆角立方体型羟基锡酸锌太阳光催化剂的制备方法 |
Non-Patent Citations (1)
Title |
---|
Photocatalytic degradation of acetaminophen in modified TiO2 under visible irradiation;Maria Lourdes P. Dalida等;《Environmental Science and Pollution Research》;20130726;第21卷(第2期);第1210页第3段,1211段第3段,1212段第1-2段 * |
Also Published As
Publication number | Publication date |
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CN110040978A (zh) | 2019-07-23 |
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TA01 | Transfer of patent application right |
Effective date of registration: 20200303 Address after: No.7, Xiwu Road, Jingbei village committee, Zhangxi she autonomous Township, Dongyuan County, Heyuan City, Guangdong Province Applicant after: Wu Shanshan Address before: 528515 Guangdong province Gaoming District of Foshan City, Yang Town Yunshan FuturArc 3 building 602 Applicant before: Chen Wenxue |
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Effective date of registration: 20200518 Address after: 528200 Shijin Industrial Park workshop 3, muyuan village committee, Shishan town, Nanhai District, Foshan City, Guangdong Province Patentee after: FOSHAN SHICHENG TONGCHUANG GLASS BUILDING MATERIAL Co.,Ltd. Address before: No.7, Xiwu Road, Jingbei village committee, Zhangxi she autonomous Township, Dongyuan County, Heyuan City, Guangdong Province Patentee before: Wu Shanshan |