CN110033716A - A kind of light storage film and preparation method thereof - Google Patents

A kind of light storage film and preparation method thereof Download PDF

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Publication number
CN110033716A
CN110033716A CN201910344666.1A CN201910344666A CN110033716A CN 110033716 A CN110033716 A CN 110033716A CN 201910344666 A CN201910344666 A CN 201910344666A CN 110033716 A CN110033716 A CN 110033716A
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layer
light storage
light
film
wave point
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CN201910344666.1A
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CN110033716B (en
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陈惠彬
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Quanzhou Nightscape Reflective Materials Co Ltd
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Quanzhou Nightscape Reflective Materials Co Ltd
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    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F13/00Illuminated signs; Luminous advertising
    • G09F13/20Illuminated signs; Luminous advertising with luminescent surfaces or parts

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Theoretical Computer Science (AREA)
  • Laminated Bodies (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)

Abstract

The present invention discloses a kind of light storage film, belongs to light storage technical field of membrane, and including surface layer, light storage layer, light shield layer, gum layer and the release paper set gradually from top to bottom, the light shield layer is lighttight white PET or BOPP film;The light shield layer is provided with close to the side of light storage layer for focusing the wave point slot across light storage layer light, the surface of the wave point slot is coated with one layer of reflecting layer, the present invention can be at various locations in the clear situation of pattern displaying, the position of corresponding wave point slot focuses the light across light storage layer, so that the luminous energy that wave point groove center position absorbs is more, to keep the fluorescent lifetime of light storage film longer, it can be widely applied to the fields such as outdoor advertising, road traffic.

Description

A kind of light storage film and preparation method thereof
Technical field
The present invention discloses a kind of light storage film and preparation method thereof, belongs to light storage technical field of membrane.
Background technique
Light storage film is that high molecular material and light-accumulating powder combine, and using the technique for squeezing out or being coated with, becomes certain thickness thin Film.It is widely used in the fields such as subway, market, high building exit passageway, number, plays the role of expressing in the dark, instruct. Currently a popular light storage film, primary structure are as follows: surface layer, light storage layer, reflecting layer, adhesive layer and backing paper.Not according to use occasion Together, some is without surface layer, and some adhesive layers form before light storage layer and instead paste light storage film, but existing light storage film luminance It spends the not high, time not grow, while service life is short, it is therefore desirable to be improved.
Summary of the invention
The object of the invention is to provide a kind of good weatherability, fluorescent lifetime long light storage in order to solve the problem above-mentioned Film and preparation method thereof.
The present invention is achieved through the following technical solutions above-mentioned purpose, a kind of light storage film, including sets gradually from top to bottom Surface layer, light storage layer, light shield layer, gum layer and release paper, the light shield layer be lighttight white PET or BOPP film.
Preferably, the light shield layer is provided with close to the side of light storage layer for focusing the wave point across light storage layer light The surface of slot, the wave point slot is coated with one layer of reflecting layer.
Preferably, the reflecting layer using aluminium-vapour deposition or silver vapor deposition by the way of formed, and be deposited with a thickness of 5-10um.
Preferably, the light storage layer includes consisting of part: resin raw material accounts for 85%-90%, light-accumulating powder accounts for 10%- 12%, fire retardant accounts for 3%-6%, heat stabilizer accounts for 1%-2%.
Preferably, the resin raw material is polyacrylic resin, and the polyacrylic resin contains the work that hydroxyl value is 20-50 Hydrogen functional group is sprinkled, the fire retardant is polyphosphoric acids ester type fire retardant.
Preferably, the surface layer selects PMMA material, and the gum layer is acrylate, Corvic, gathers One of amide resin or a variety of mixtures.
Preferably, the light storage film with a thickness of 0.8-2mm.
The present invention provides a kind of preparation method of light storage film, comprising the following steps:
(1) resin raw material, light-accumulating powder, fire retardant, heat stabilizer are mixed in proportion, to squeeze out or be coated on PMMA film surface obtains the light storage layer with a thickness of 100-200um, is then dried;
(2) one side of lighttight white PET or BOPP film is subjected to membrane pressure processing by knurling rolls, so that film On one side formed array distribution wave point slot, then by film move to take-up type vacuum aluminize equipment sealed chamber in, in film band There is the one side of wave point slot to increase by one layer of evaporation plating aluminium or silver coating;
(3) by the light storage layer in step (1), perhaps BOPP film is compound and in PET or BOPP with the PET in step (2) Film is free of the coated on one side gum layer of wave point slot, then bonds release paper in the one side of gum layer;
(4) silk-screen or engraving processing are carried out on the surface of PMMA film, and in its surface bonding layer protecting film.
Preferably, the wave point diameter of embossing roller surface is 150-200um in the step (2), and the temperature of the membrane pressure is 100-150℃。
Preferably, the protective film is one kind of Polycarbonate Layer, polystyrene layer, hard polyvinyl chloride layer.
Compared with prior art, the beneficial effects of the present invention are:
1, light shield layer uses lighttight white PET or BOPP film, only needs when producing light storage film by itself and light storage Compound, the simple production process of layer improves titanium dioxide in traditional window layer and is unevenly distributed that cause light storage film light transmission occur existing The deficiency of elephant.
2, by increasing the wave point slot of array distribution close to the one side of light storage layer in light shield layer, while the surface of wave point slot is attached Have reflecting layer, overall structure is identical as concave mirror, and light passes through and is gathered in some point of light storage layer through reflecting after light storage layer On, and by light-accumulating powder by light energy absorption, compared with traditional light storage film, the light storage film in the present invention can clearly show that each position In the case where pattern, the light after absorbing reflection is concentrated in the position of corresponding wave point slot, so that the display time of light storage film is longer, And it also added fire retardant and heat stabilizer in light storage layer, it is ensured that light storage film will not under conditions of strong light and optically focused There is a phenomenon where spontaneous combustions or dissolution to fall off.
3, the surface layer of the material based on PMMA is increased by the surface in light storage layer, can carry out silk-screen or carving It carves, it, will not there is a phenomenon where turn yellow to improve the diversity of light storage film surface pattern, while its good weatherability.
Detailed description of the invention
Fig. 1 is a kind of structural schematic diagram of light storage film of the present invention;
Fig. 2 is the arrangement architecture schematic diagram of wave point slot in a kind of light storage film of the present invention.
Appended drawing reference: 1, surface layer;2, reflecting layer;3, light shield layer;4, protective film;5, light storage layer;6, wave point slot;7, gum Layer;8, release paper.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment shall fall within the protection scope of the present invention.
As depicted in figs. 1 and 2, a kind of light storage film, including surface layer 1, the light storage layer 5, light shield layer set gradually from top to bottom 3, gum layer 7 and release paper 8, light shield layer 3 are lighttight white PET or BOPP film.
Preferably, light shield layer 3 is provided with close to the side of light storage layer 5 for focusing the wave point slot across 5 light of light storage layer 6, the surface of wave point slot 6 is coated with one layer of reflecting layer 2.
Preferably, reflecting layer 2 using aluminium-vapour deposition or silver vapor deposition by the way of formed, and be deposited with a thickness of 5-10um.
Preferably, light storage layer 5 includes consisting of part: resin raw material accounts for 85%-90%, light-accumulating powder accounts for 10%-12%, Fire retardant accounts for 3%-6%, heat stabilizer accounts for 1%-2%.
Preferably, resin raw material is polyacrylic resin, and polyacrylic resin contains the active hydrogen function that hydroxyl value is 20-50 Group, fire retardant are polyphosphoric acids ester type fire retardant.
Preferably, surface layer 1 selects PMMA material, and gum layer 7 is acrylate, Corvic, polyamide resin One of rouge or a variety of mixtures.
Preferably, light storage film with a thickness of 0.8-2mm.
The present invention provides a kind of preparation method of light storage film, specifically includes the following steps:
(1) resin raw material, light-accumulating powder, fire retardant, heat stabilizer are mixed in proportion, to squeeze out or be coated on PMMA film surface obtains the light storage layer 5 with a thickness of 100-200um, is then dried;
(2) one side of lighttight white PET or BOPP film is subjected to membrane pressure processing by knurling rolls, so that film On one side formed array distribution wave point slot 6, then by film move to take-up type vacuum aluminize equipment sealed chamber in, in film band There is the one side of wave point slot 6 to increase by one layer of evaporation plating aluminium or silver coating;
(3) by the light storage layer 5 and PET in step (2) in step (1), perhaps BOPP film is compound and in PET or BOPP Film is free of the coated on one side gum layer 7 of wave point slot 6, then bonds release paper 8 in the one side of gum layer 7;
(4) silk-screen or engraving processing are carried out on the surface of PMMA film, and in its surface bonding layer protecting film 4;
Preferably, the wave point diameter of embossing roller surface is 150-200um in step (2), and the temperature of membrane pressure is 100-150 ℃。
Preferably, the protective film 4 in step (4) is one kind of Polycarbonate Layer, polystyrene layer, hard polyvinyl chloride layer.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims Variation is included within the present invention.Any reference signs in the claims should not be construed as limiting the involved claims.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art The other embodiments being understood that.

Claims (10)

1. a kind of light storage film, which is characterized in that including surface layer (1), the light storage layer (5), light shield layer set gradually from top to bottom (3), gum layer (7) and release paper (8), the light shield layer (3) are lighttight white PET or BOPP film.
2. a kind of light storage film according to claim 1, which is characterized in that the one of the light shield layer (3) close light storage layer (5) Side is provided with for focusing the wave point slot (6) across light storage layer (5) light, and the surface of the wave point slot (6) is coated with one layer instead Penetrate layer (2).
3. a kind of light storage film according to claim 2, which is characterized in that the reflecting layer (2) uses aluminium-vapour deposition or silver The mode of vapor deposition is formed, and be deposited with a thickness of 5-10um.
4. a kind of light storage film according to claim 1, which is characterized in that the light storage layer (5) includes consisting of part: Resin raw material accounts for 85%-90%, light-accumulating powder accounts for 10%-12%, fire retardant accounts for 3%-6%, heat stabilizer accounts for 1%-2%.
5. a kind of light storage film according to claim 4, which is characterized in that the resin raw material is polyacrylic resin, institute It states polyacrylic resin and contains the active hydrogen functional groups that hydroxyl value is 20-50, the fire retardant is polyphosphoric acids ester type fire retardant.
6. a kind of light storage film according to claim 1, which is characterized in that the surface layer (1) selects PMMA material, the back Glue-line (7) is one of acrylate, Corvic, polyamide or a variety of mixtures.
7. a kind of light storage film according to claim 1, which is characterized in that the light storage film with a thickness of 0.8-2mm.
8. a kind of preparation method of light storage film, which comprises the following steps:
(1) resin raw material, light-accumulating powder, fire retardant, heat stabilizer are mixed in proportion, it is thin to squeeze out or be coated on PMMA Film surface obtains the light storage layer (5) with a thickness of 100-200um, is then dried;
(2) one side of lighttight white PET or BOPP film is subjected to membrane pressure processing by knurling rolls, so that the one side of film Formed array distribution wave point slot (6), then by film move to take-up type vacuum aluminize equipment sealed chamber in, had in film The one side of wave point slot (6) increases by one layer of evaporation plating aluminium or silver coating;
(3) by the light storage layer (5) in step (1), perhaps BOPP film is compound and in PET or BOPP film with the PET in step (2) Coated on one side gum layer (7) without wave point slot (6) then bonds release paper (8) in the one side of gum layer (7);
(4) silk-screen or engraving processing are carried out on the surface of PMMA film, and in its surface bonding layer protecting film (4).
9. a kind of preparation method of light storage film according to claim 8, which is characterized in that embossing in the step (2) The wave point diameter of roller surface is 150-200um, and the temperature of the membrane pressure is 100-150 DEG C.
10. a kind of preparation method of light storage film according to claim 8, which is characterized in that the guarantor in the step (4) Cuticula (4) is one kind of Polycarbonate Layer, polystyrene layer, hard polyvinyl chloride layer.
CN201910344666.1A 2019-04-26 2019-04-26 Light storage film and preparation method thereof Active CN110033716B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112080213A (en) * 2020-08-31 2020-12-15 晋江联兴反光材料有限公司 Preparation method of flame-retardant light-storing film
CN112259014A (en) * 2020-11-23 2021-01-22 国网江苏省电力有限公司泰州供电分公司 Self-adhesive light-storing luminous label for high-voltage bare wire

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112080213A (en) * 2020-08-31 2020-12-15 晋江联兴反光材料有限公司 Preparation method of flame-retardant light-storing film
CN112259014A (en) * 2020-11-23 2021-01-22 国网江苏省电力有限公司泰州供电分公司 Self-adhesive light-storing luminous label for high-voltage bare wire

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