CN110004708A - A kind of anti-electromagnetic radiation abrasion resistant finish method of fabric - Google Patents
A kind of anti-electromagnetic radiation abrasion resistant finish method of fabric Download PDFInfo
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- CN110004708A CN110004708A CN201910315294.XA CN201910315294A CN110004708A CN 110004708 A CN110004708 A CN 110004708A CN 201910315294 A CN201910315294 A CN 201910315294A CN 110004708 A CN110004708 A CN 110004708A
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- fabric
- electromagnetic radiation
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- abrasion resistant
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- 239000004744 fabric Substances 0.000 title claims abstract description 78
- 230000005855 radiation Effects 0.000 title claims abstract description 44
- 238000000034 method Methods 0.000 title claims abstract description 33
- 238000005299 abrasion Methods 0.000 title claims abstract description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 51
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229910000077 silane Inorganic materials 0.000 claims abstract description 22
- 239000000243 solution Substances 0.000 claims abstract description 21
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229940056319 ferrosoferric oxide Drugs 0.000 claims abstract description 19
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000007788 liquid Substances 0.000 claims abstract description 17
- 239000006185 dispersion Substances 0.000 claims abstract description 16
- 238000012545 processing Methods 0.000 claims abstract description 16
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 15
- 230000008878 coupling Effects 0.000 claims abstract description 15
- 238000010168 coupling process Methods 0.000 claims abstract description 15
- 238000005859 coupling reaction Methods 0.000 claims abstract description 15
- 239000003607 modifier Substances 0.000 claims abstract description 15
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 239000000945 filler Substances 0.000 claims abstract description 13
- 238000003756 stirring Methods 0.000 claims abstract description 13
- BYLOHCRAPOSXLY-UHFFFAOYSA-N dichloro(diethyl)silane Chemical compound CC[Si](Cl)(Cl)CC BYLOHCRAPOSXLY-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000843 powder Substances 0.000 claims abstract description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000013019 agitation Methods 0.000 claims abstract description 10
- 238000001035 drying Methods 0.000 claims abstract description 10
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims abstract description 9
- 239000007864 aqueous solution Substances 0.000 claims abstract description 9
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims abstract description 9
- 239000000178 monomer Substances 0.000 claims abstract description 9
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000000576 coating method Methods 0.000 claims abstract description 8
- 239000011248 coating agent Substances 0.000 claims abstract description 7
- 239000003822 epoxy resin Substances 0.000 claims abstract description 7
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 7
- 238000004140 cleaning Methods 0.000 claims abstract description 5
- 239000008367 deionised water Substances 0.000 claims abstract description 5
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 5
- 238000007598 dipping method Methods 0.000 claims abstract description 5
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000002203 pretreatment Methods 0.000 claims abstract description 5
- 238000005096 rolling process Methods 0.000 claims abstract description 5
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 4
- 235000019441 ethanol Nutrition 0.000 claims description 26
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 16
- 238000002360 preparation method Methods 0.000 claims description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 8
- 150000001298 alcohols Chemical class 0.000 claims description 8
- 239000012530 fluid Substances 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims description 8
- 238000005406 washing Methods 0.000 claims description 8
- 239000003643 water by type Substances 0.000 claims description 8
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 claims description 6
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 claims description 4
- 239000000908 ammonium hydroxide Substances 0.000 claims description 4
- 239000010949 copper Substances 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000003599 detergent Substances 0.000 claims description 4
- 238000005516 engineering process Methods 0.000 claims description 4
- 239000011790 ferrous sulphate Substances 0.000 claims description 4
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 4
- 229910002804 graphite Inorganic materials 0.000 claims description 4
- 239000010439 graphite Substances 0.000 claims description 4
- 229910052621 halloysite Inorganic materials 0.000 claims description 4
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 4
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 4
- 239000002071 nanotube Substances 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 4
- 238000001291 vacuum drying Methods 0.000 claims description 4
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 2
- 229960000935 dehydrated alcohol Drugs 0.000 abstract 2
- 238000007711 solidification Methods 0.000 abstract 1
- 230000008023 solidification Effects 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 6
- 230000003075 superhydrophobic effect Effects 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 238000000967 suction filtration Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- 239000011358 absorbing material Substances 0.000 description 2
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 2
- 229940092714 benzenesulfonic acid Drugs 0.000 description 2
- 238000009388 chemical precipitation Methods 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- 239000002019 doping agent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000005670 electromagnetic radiation Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- -1 iron ion Chemical class 0.000 description 2
- 238000009940 knitting Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920000128 polypyrrole Polymers 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 238000010345 tape casting Methods 0.000 description 2
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 229910001448 ferrous ion Inorganic materials 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/49—Oxides or hydroxides of elements of Groups 8, 9,10 or 18 of the Periodic Table; Ferrates; Cobaltates; Nickelates; Ruthenates; Osmates; Rhodates; Iridates; Palladates; Platinates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/55—Epoxy resins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Laminated Bodies (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses a kind of anti-electromagnetic radiation abrasion resistant finish methods of fabric, the filler of silane coupler modified galapectite-ferroso-ferric oxide dispersion liquid, coupling modifier processing is uniformly mixed, the fabric of pre-treatment is impregnated wherein, second dipping and rolling, drying, then immerse in pyrrole monomer aqueous solution and vibrate, ferric chloride solution and p-methyl benzenesulfonic acid solution is added dropwise, after oxidation reaction, spent glycol and deionized water cleaning, drying obtain the fabric that anti-electromagnetic radiation arranges；Dehydrated alcohol is added into nano titanium dioxide powder, magnetic agitation is uniformly dispersed, and silane coupling agent KH590 is added and reacts to obtain component A；Epoxy resin and curing agent are dissolved in dehydrated alcohol, after magnetic agitation, mixed with component A, dichloro-diethyl silane is added dropwise, stirs evenly, on the fabric arranged it was evenly coated on gained anti-electromagnetic radiation with scraper, two layers of blade coating, solidification, obtains anti-electromagnetic radiation wear-resistant fabric.
Description
Technical field
The invention belongs in terms of garment material fiber, and in particular to a kind of anti-electromagnetic radiation abrasion resistant finish method of fabric.
Background technique
With the development of society, the popularization and application of all kinds of electric appliance and electronic equipment especially computer, so that electromagnetic radiation pollution
Have become the another big pollution after atmosphere pollution, water pollution and noise pollution.Electromagnetic radiation endangers the mankind in various aspects and is good for
Health, therefore various safeguard procedures are come into being, wherein preparing conductive fabric anti-electromagnetic radiation using coating process, not only effect is good
And it is at low cost.Conductive anti-electromagnetic radiation fabric can be made Radiation proof dress, barrier shield patch, shielding cover etc., be widely applied
In the daily work life of people.In recent years, hydro-entangled non-woven fabric is quickly grown, and output is big, clean and energy consumption is few, therefore
Carrying out anti-electromagnetic radiation top finish to hydro-entangled non-woven fabric has very big market prospects.But the disadvantage is that wear-resisting, hydrophobicity
Can be poor, the anti-electromagnetic radiation and hydrophobic wear-resisting property of fabric are improved using method provided by the invention.
Super hydrophobic surface refers to that liquid-drop contact angle is greater than 150 °, and roll angle is less than 10 °, the material with specific function attribute
Surface.
Summary of the invention
The purpose of the present invention is providing a kind of anti-electromagnetic radiation abrasion resistant finish method of fabric for existing problem,
There is excellent anti-electromagnetic radiation performance, ultra-hydrophobicity and wear-resisting property according to the fabric that this method arranges.
The present invention is achieved by the following technical solutions:
A kind of anti-electromagnetic radiation abrasion resistant finish method of fabric, which is characterized in that include the following steps, following raw materials are by weight
Meter:
(1) pre-treating technology of fabric:
Fabric is immersed in treatment fluid, at 80-85 DEG C after preceding processing 20-30min, washing is dried, then use at 60-65 DEG C
After hydrophilic agent pads, 30-60min is dried at 100-105 DEG C, is placed under the conditions of temperature is 15-25 DEG C, humidity is 55-65%
20-24h；
(2) the anti-electromagnetic radiation finishing technique of fabric:
It is filled out what 30-60 parts of silane coupler modified galapectite-ferroso-ferric oxide dispersion liquids, 20-40 parts of coupling modifiers were handled
Material is uniformly mixed, and the fabric of pre-treatment in (1) is impregnated 5-10min, second dipping and rolling, at 80-85 DEG C by bath raio 1:30 wherein
Lower drying, then immerse in 20-30 parts of pyrrole monomer aqueous solutions, after vibrating 1-2h at 4-6 DEG C, 1-2 parts of ferric chloride solutions are added dropwise
With 1-2 parts of p-methyl benzenesulfonic acid solution, after oxidation reaction 1-2h, spent glycol and deionized water cleaning, drying obtain anti-electromagnetic radiation
The fabric of arrangement；
It is conductive absorbing material by magnetic loss consumption material, polypyrrole of silane coupler modified galapectite-ferroso-ferric oxide, uses
Two-step method is prepared for anti-electromagnetic radiation fabric, first with silane coupler modified galapectite-ferroso-ferric oxide dispersion liquid to knitting
Object pads, drying mode obtains Fe 3 O 4 magnetic fabric, and as base material, using iron chloride as oxidant, to first
Benzene sulfonic acid is dopant, is prepared into anti-electromagnetic radiation fabric by in-situ polymerization；
(3) preparation of cloth abrasion coating:
40-80 parts of dehydrated alcohols are added into 4-8 parts of nano titanium dioxide powders, magnetic agitation 10-20min is uniformly dispersed, adds
Enter 1-2 parts of silane coupling agent KH590, react 4-5h at 55-65 DEG C, obtains component A；4-8 parts of epoxy resin and 4-8 parts are solidified
Agent is dissolved in 8-16 parts of dehydrated alcohols, after magnetic agitation 5-10min, is mixed with component A, and 1-2 parts of Dichlorodiethyl silicon are added dropwise
Alkane, stirring 30-50min is uniform, with scraper it was evenly coated on the fabric that gained anti-electromagnetic radiation arranges in (2), scratches
Two layers, solidify 5-20min at 80-120 DEG C, obtains anti-electromagnetic radiation wear-resistant fabric；
It carries out surface to nano-titanium dioxide using silane coupling agent KH590 to be modified, by silane coupler modified nano-silica
Change titanium to mix with the ethanol solution of epoxy resin, after dichloro-diethyl silane is modified, using knife coating in fabric table
Face obtains super-hydrophobic wear-resistant coating；
Further, treatment fluid is made of 3-5g/L sodium carbonate, 1-2g/L detergent in step (1), hydrophilic agent quality point
Number is 0.1-0.2%.
Further, galapectite-ferroso-ferric oxide dispersion liquid preparation silane coupler modified in step (2):
100-200 part water are added into 0.5-1 parts of halloysite nanotubes, after ultrasonic 10-20min, 0.1-0.2 parts of iron chloride of addition
It is dispersed with stirring 1-2h in 60-65 DEG C under nitrogen protection with 0.06-0.12 parts of ferrous sulfate, adding ammonium hydroxide to adjust pH is 9-10,
It is subsequently dispersed in 200-400 parts of ethanol waters, 2-4 parts of Silane coupling agent KH550s is added, under nitrogen protection, in 60-65
DEG C stirring 10-12h, obtain silane coupler modified galapectite-ferroso-ferric oxide dispersion liquid.
Further, in step (2) filler coupling modifier treatment process: by 10-20 parts of copper powders, the leaching of 10-20 parts of graphite
Not in hydrochloric acid, the mixed liquor that ethyl alcohol volume ratio is 1:2, filter, with ethanol washing, suction filtration, the vacuum drying at 100-105 DEG C
After handling 30-60min, it is added in 50-100 parts of ethanol waters, adds 0.04-0.06 parts of Silane coupling agent KH550s, sufficiently
It stirs evenly, obtains the filler of coupling modifier processing.
Further, pick-up is 100% in step (2), pyrrole monomer aqueous solution, ferric chloride solution and p-methyl benzenesulfonic acid
The molar concentration of solution is 0.5-0.7mol/L.
The present invention has the advantage that compared with prior art
(1) ferriferrous oxide nano-particle is uniformly first loaded on galapectite surface with chemical precipitation method, then with amino
Silane coupling agent its surface is modified, prepare silane coupler modified galapectite-ferroso-ferric oxide；First with an angstrom Lip river
The negative electrical charge absorption iron ion and ferrous ion on stone surface, are received by chemical precipitation method in galapectite area load ferroso-ferric oxide
Rice corpuscles is modified its surface with the Silane coupling agent KH550 with amino, introduces amino on its surface；
It is conductive absorbing material by magnetic loss consumption material, polypyrrole of silane coupler modified galapectite-ferroso-ferric oxide, uses
Two-step method is prepared for anti-electromagnetic radiation fabric, first with silane coupler modified galapectite-ferroso-ferric oxide dispersion liquid to knitting
Object pads, drying mode obtains Fe 3 O 4 magnetic fabric, and as base material, using iron chloride as oxidant, to first
Benzene sulfonic acid is dopant, is prepared into anti-electromagnetic radiation fabric by in-situ polymerization.
(2) it carries out surface to nano-titanium dioxide using silane coupling agent KH590 to be modified, then will be silane coupler modified
Nano-titanium dioxide is mixed with the ethanol solution of epoxy resin, after dichloro-diethyl silane is modified, utilizes knife coating
Super-hydrophobic wear-resistant coating is obtained in fabric surface.
Specific embodiment
Embodiment 1
A kind of anti-electromagnetic radiation abrasion resistant finish method of fabric, which is characterized in that include the following steps, following raw materials are by weight
Meter:
(1) pre-treating technology of fabric:
Fabric is immersed in treatment fluid, at 80 DEG C after preceding processing 30min, washing is dried, then padded with hydrophilic agent at 60 DEG C
Afterwards, 60min is dried at 100 DEG C, is placed for 24 hours under the conditions of temperature is 15 DEG C, humidity is 55%；
Wherein, treatment fluid is made of 3g/L sodium carbonate, 1g/L detergent, and hydrophilic agent mass fraction is 0.1%；
(2) the anti-electromagnetic radiation finishing technique of fabric:
The filler of 30 parts of silane coupler modified galapectite-ferroso-ferric oxide dispersion liquids, 20 parts of coupling modifier processing is mixed
Uniformly, the fabric of pre-treatment in (1) is impregnated into 5min by bath raio 1:30 wherein, second dipping and rolling is dried at 80 DEG C, then immersed
In 20 parts of pyrrole monomer aqueous solutions, after vibrating 2h at 4 DEG C, 1 part of ferric chloride solution and 1 part of p-methyl benzenesulfonic acid solution, oxygen is added dropwise
After changing reaction 1h, spent glycol and deionized water cleaning, drying obtain the fabric that anti-electromagnetic radiation arranges；
Wherein, silane coupler modified galapectite-ferroso-ferric oxide dispersion liquid preparation: into 0.5 part of halloysite nanotubes
It is added 100 parts of water, after ultrasonic 10min, adds 0.1 part of iron chloride and 0.06 part of ferrous sulfate, under nitrogen protection, stirred in 60 DEG C
Dispersion 2h is mixed, adding ammonium hydroxide to adjust pH is 9, it is subsequently dispersed in 200 parts of ethanol waters, 2 parts of Silane coupling agent KH550s is added,
Under nitrogen protection, in 60 DEG C of stirring 12h, silane coupler modified galapectite-ferroso-ferric oxide dispersion liquid is obtained；
The coupling modifier treatment process of filler: 10 parts of copper powders, 10 parts of graphite are immersed in hydrochloric acid, ethyl alcohol volume ratio is the mixed of 1:2
It closes in liquid, filters, 50 parts of ethanol waters are added at 100 DEG C after vacuum drying processing 60min with ethanol washing, suction filtration
In, 0.04 part of Silane coupling agent KH550 is added, is stirred, the filler of coupling modifier processing is obtained；
Pick-up is 100%, and the molar concentration of pyrrole monomer aqueous solution, ferric chloride solution and p-methyl benzenesulfonic acid solution is
0.5mol/L；
(3) preparation of cloth abrasion coating:
40 parts of dehydrated alcohols are added into 4 parts of nano titanium dioxide powders, magnetic agitation 10min is uniformly dispersed, and 1 part of silane is added
Coupling agent KH590 reacts 5h at 55 DEG C, obtains component A；4 parts of epoxy resin and 4 parts of curing agent are dissolved in 8 parts of dehydrated alcohols
In, after magnetic agitation 5min, mixed with component A, be added dropwise 1 part of dichloro-diethyl silane, stirring 30min is uniform, with scraper by its
It is uniformly coated on the fabric that gained anti-electromagnetic radiation arranges in (2), scratches two layers, solidify 20min at 80 DEG C, obtain anti-electric
Magnetic radiation wear-resistant fabric.
Embodiment 2
A kind of anti-electromagnetic radiation abrasion resistant finish method of fabric, which is characterized in that include the following steps, following raw materials are by weight
Meter:
(1) pre-treating technology of fabric:
Fabric is immersed in treatment fluid, at 85 DEG C after preceding processing 20min, washing is dried, then padded with hydrophilic agent at 65 DEG C
Afterwards, 30min is dried at 105 DEG C, places 20h under the conditions of temperature is 25 DEG C, humidity is 65%；
Wherein, treatment fluid is made of 5g/L sodium carbonate, 2g/L detergent, and hydrophilic agent mass fraction is 0.2%；
(2) the anti-electromagnetic radiation finishing technique of fabric:
The filler of 60 parts of silane coupler modified galapectite-ferroso-ferric oxide dispersion liquids, 40 parts of coupling modifier processing is mixed
Uniformly, the fabric of pre-treatment in (1) is impregnated into 10min by bath raio 1:30 wherein, second dipping and rolling is dried at 85 DEG C, then soaked
Enter in 30 parts of pyrrole monomer aqueous solutions, after vibrating 2h at 6 DEG C, 2 parts of ferric chloride solutions and 2 parts of p-methyl benzenesulfonic acid solution be added dropwise,
After oxidation reaction 2h, spent glycol and deionized water cleaning, drying obtain the fabric that anti-electromagnetic radiation arranges；
Wherein, silane coupler modified galapectite-ferroso-ferric oxide dispersion liquid preparation: add into 1 part of halloysite nanotubes
Enter 200 parts of water, after ultrasonic 20min, add 0.2 part of iron chloride and 0.12 part of ferrous sulfate, under nitrogen protection, is stirred in 65 DEG C
Disperse 1h, adding ammonium hydroxide to adjust pH is 10, it is subsequently dispersed in 400 parts of ethanol waters, 4 parts of Silane coupling agent KH550s is added,
Under nitrogen protection, in 65 DEG C of stirring 10h, silane coupler modified galapectite-ferroso-ferric oxide dispersion liquid is obtained；
The coupling modifier treatment process of filler: 20 parts of copper powders, 20 parts of graphite are immersed in hydrochloric acid, ethyl alcohol volume ratio is the mixed of 1:2
It closes in liquid, filters, 100 parts of ethanol waters are added at 105 DEG C after vacuum drying processing 30min with ethanol washing, suction filtration
In, 0.06 part of Silane coupling agent KH550 is added, is stirred, the filler of coupling modifier processing is obtained；
Pick-up is 100%, and the molar concentration of pyrrole monomer aqueous solution, ferric chloride solution and p-methyl benzenesulfonic acid solution is
0.7mol/L；
(3) preparation of cloth abrasion coating:
80 parts of dehydrated alcohols are added into 8 parts of nano titanium dioxide powders, magnetic agitation 20min is uniformly dispersed, and 2 parts of silane are added
Coupling agent KH590 reacts 4h at 65 DEG C, obtains component A；8 parts of epoxy resin and 8 parts of curing agent are dissolved in 16 parts of dehydrated alcohols
In, after magnetic agitation 10min, mixed with component A, be added dropwise 2 parts of dichloro-diethyl silanes, stirring 50min is uniform, with scraper by its
It is uniformly coated on the fabric that gained anti-electromagnetic radiation arranges in (2), scratches two layers, solidify 5min at 120 DEG C, obtain anti-electric
Magnetic radiation wear-resistant fabric.
Comparative example 1
This comparative example 1 compared with Example 1, is not added with the filler of coupling modifier processing, side in addition to this in step (2)
Method step is all the same.
Comparative example 2
This comparative example 2 compared with Example 2, is not added with using nano titanium dioxide powder, in addition to this in step (3)
Method and step is all the same.
Blank fabric of the control group without any modification
Herein described fabric includes cotton fabric, linen, bamboo fiber etc., and the present embodiment has selected cotton fabric to be ground
Study carefully；
In order to compare preparation of the embodiment of the present invention fabric performance, to above-described embodiment 1, embodiment 2, comparative example 1, right
Fabric obtained more corresponding than 2 method of embodiment and the corresponding blank fabric without any modification of control group, according to row
Industry standard carries out performance detection to fabric, using the electromagnetic screen of microwave radiation comparing measuring apparatus measurement fabric in 30-1500MHz
Efficiency is covered, is secured the fabric on friction wear testing machine, stops test, specific correlation data such as the following table 1 institute after 100 turns of test
Show:
Table 1
There is excellent anti-electromagnetic radiation performance, ultra-hydrophobicity and resistance to according to fabric prepared by present invention method 1,2
Grind performance, 154 ° of fabric liquid-drop contact angle average out to, 6 ° of roll angle average out to, it is known that fabric has super hydrophobic surface；It is comparing
It is not added with the filler of coupling modifier processing in embodiment 1, the electromagnet shield effect value of fabric is caused to reduce, but still is below pair
According to a group electromagnetic shielding performance for blank fabric；It is not added in comparative example 2 using nano titanium dioxide powder, leads to fabric
Abrasion loss increase, but still better than the wear-resisting property of control group blank fabric.
Claims (5)
1. a kind of anti-electromagnetic radiation abrasion resistant finish method of fabric, which is characterized in that include the following steps, following raw materials are by weight
Part meter:
(1) pre-treating technology of fabric:
Fabric is immersed in treatment fluid, at 80-85 DEG C after preceding processing 20-30min, washing is dried, then use at 60-65 DEG C
After hydrophilic agent pads, 30-60min is dried at 100-105 DEG C, is placed under the conditions of temperature is 15-25 DEG C, humidity is 55-65%
20-24h；
(2) the anti-electromagnetic radiation finishing technique of fabric:
It is filled out what 30-60 parts of silane coupler modified galapectite-ferroso-ferric oxide dispersion liquids, 20-40 parts of coupling modifiers were handled
Material is uniformly mixed, and the fabric of pre-treatment in (1) is impregnated 5-10min, second dipping and rolling, at 80-85 DEG C by bath raio 1:30 wherein
Lower drying, then immerse in 20-30 parts of pyrrole monomer aqueous solutions, after vibrating 1-2h at 4-6 DEG C, 1-2 parts of ferric chloride solutions are added dropwise
With 1-2 parts of p-methyl benzenesulfonic acid solution, after oxidation reaction 1-2h, spent glycol and deionized water cleaning, drying obtain anti-electromagnetic radiation
The fabric of arrangement；
(3) preparation of cloth abrasion coating:
40-80 parts of dehydrated alcohols are added into 4-8 parts of nano titanium dioxide powders, magnetic agitation 10-20min is uniformly dispersed, adds
Enter 1-2 parts of silane coupling agent KH590, react 4-5h at 55-65 DEG C, obtains component A；4-8 parts of epoxy resin and 4-8 parts are solidified
Agent is dissolved in 8-16 parts of dehydrated alcohols, after magnetic agitation 5-10min, is mixed with component A, and 1-2 parts of Dichlorodiethyl silicon are added dropwise
Alkane, stirring 30-50min is uniform, with scraper it was evenly coated on the fabric that gained anti-electromagnetic radiation arranges in (2), scratches
Two layers, solidify 5-20min at 80-120 DEG C, obtains anti-electromagnetic radiation wear-resistant fabric.
2. a kind of anti-electromagnetic radiation abrasion resistant finish method of fabric according to claim 1, which is characterized in that step (1)
Middle treatment fluid is made of 3-5g/L sodium carbonate, 1-2g/L detergent, and hydrophilic agent mass fraction is 0.1-0.2%.
3. a kind of anti-electromagnetic radiation abrasion resistant finish method of fabric according to claim 1, which is characterized in that step (2)
In silane coupler modified galapectite-ferroso-ferric oxide dispersion liquid preparation:
100-200 part water are added into 0.5-1 parts of halloysite nanotubes, after ultrasonic 10-20min, 0.1-0.2 parts of iron chloride of addition
It is dispersed with stirring 1-2h in 60-65 DEG C under nitrogen protection with 0.06-0.12 parts of ferrous sulfate, adding ammonium hydroxide to adjust pH is 9-10,
It is subsequently dispersed in 200-400 parts of ethanol waters, 2-4 parts of Silane coupling agent KH550s is added, under nitrogen protection, in 60-65
DEG C stirring 10-12h, obtain silane coupler modified galapectite-ferroso-ferric oxide dispersion liquid.
4. a kind of anti-electromagnetic radiation abrasion resistant finish method of fabric according to claim 1, which is characterized in that step (2)
The coupling modifier treatment process of middle filler:
10-20 parts of copper powders, 10-20 parts of graphite are immersed in hydrochloric acid, ethyl alcohol volume ratio to filter, using ethyl alcohol in the mixed liquor of 1:2
Washing filters, and at 100-105 DEG C after vacuum drying processing 30-60min, is added in 50-100 parts of ethanol waters, adds
0.04-0.06 parts of Silane coupling agent KH550s, stir, and obtain the filler of coupling modifier processing.
5. a kind of anti-electromagnetic radiation abrasion resistant finish method of fabric according to claim 1, which is characterized in that step (2)
Middle pick-up is 100%, and the molar concentration of pyrrole monomer aqueous solution, ferric chloride solution and p-methyl benzenesulfonic acid solution is 0.5-
0.7mol/L。
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115787291A (en) * | 2022-12-28 | 2023-03-14 | 艾利特控股集团有限公司 | Electromagnetic wave absorption finishing liquid and application thereof in preparation of electromagnetic radiation protection textile fabric |
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2019
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115787291A (en) * | 2022-12-28 | 2023-03-14 | 艾利特控股集团有限公司 | Electromagnetic wave absorption finishing liquid and application thereof in preparation of electromagnetic radiation protection textile fabric |
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Application publication date: 20190712 |