CN109971996B - TiB particle reinforced Ti-based composite material capable of effectively improving plasticity performance - Google Patents
TiB particle reinforced Ti-based composite material capable of effectively improving plasticity performance Download PDFInfo
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- CN109971996B CN109971996B CN201910284526.XA CN201910284526A CN109971996B CN 109971996 B CN109971996 B CN 109971996B CN 201910284526 A CN201910284526 A CN 201910284526A CN 109971996 B CN109971996 B CN 109971996B
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- 239000002245 particle Substances 0.000 title claims abstract description 66
- 239000002131 composite material Substances 0.000 title claims abstract description 49
- 239000000843 powder Substances 0.000 claims abstract description 70
- 239000011521 glass Substances 0.000 claims abstract description 25
- 239000000919 ceramic Substances 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 30
- 239000006185 dispersion Substances 0.000 claims description 17
- 239000012153 distilled water Substances 0.000 claims description 17
- 239000007788 liquid Substances 0.000 claims description 17
- 238000001132 ultrasonic dispersion Methods 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 238000010438 heat treatment Methods 0.000 claims description 13
- 239000004115 Sodium Silicate Substances 0.000 claims description 11
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 11
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 11
- 238000000462 isostatic pressing Methods 0.000 claims description 10
- 238000000137 annealing Methods 0.000 claims description 6
- 238000001704 evaporation Methods 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims description 6
- 229940048086 sodium pyrophosphate Drugs 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 235000019818 tetrasodium diphosphate Nutrition 0.000 claims description 6
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 6
- 238000000748 compression moulding Methods 0.000 claims description 3
- 238000004321 preservation Methods 0.000 claims description 3
- 239000010936 titanium Substances 0.000 description 53
- 239000011159 matrix material Substances 0.000 description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 230000003014 reinforcing effect Effects 0.000 description 3
- 229910001069 Ti alloy Inorganic materials 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
- C22C1/05—Mixtures of metal powder with non-metallic powder
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C14/00—Alloys based on titanium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C32/00—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
- C22C32/0005—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with at least one oxide and at least one of carbides, nitrides, borides or silicides as the main non-metallic constituents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
- B22F2998/10—Processes characterised by the sequence of their steps
Abstract
The invention relates to the technical field of Ti-based composite materials, and discloses a TiB particle reinforced Ti-based composite material capable of effectively improving plasticity, which comprises the following raw materials in parts by weight: 50-60 parts of micron Ti powder, 10-20 parts of micron TiB ceramic particles, 5-10 parts of micron Al powder and 5-10 microns of glass powder; wherein the micron glass powder consists of 40 percent wtPbO and 20 percent wtSiO with the average grain diameter less than or equal to 2.6um2、25%wtTiO2And 15% wtB2O3And (4) forming. The invention solves the technical problem that the plasticity of the TiB particle reinforced Ti-based composite material cannot be effectively improved while the tensile strength of the TiB particle reinforced Ti-based composite material is effectively improved.
Description
Technical Field
The invention relates to the technical field of Ti-based composite materials, in particular to a TiB particle reinforced Ti-based composite material capable of effectively improving the plasticity.
Background
The titanium-based composite material has become one of the important candidate materials of the high-performance aircraft engine due to the characteristics of high specific strength, use temperature, specific elastic modulus and the like. Titanium-based composites can be classified into three major categories, fibers, whiskers, and particulate reinforced titanium-based composites. Compared with the fiber reinforced titanium-based composite material, the whisker and particle reinforced titanium-based composite material has the technical advantages of simple manufacturing process, low cost and capability of performing subsequent thermal mechanical deformation such as forging, rolling, extruding and the like.
TiB has the advantages of high elastic modulus, fiber morphology, low solid solubility in a matrix, high thermal stability with a titanium alloy matrix and the like, so that TiB is the most ideal reinforcement of a Ti-based composite material. The TiB reinforced Ti-based composite material is prepared by adopting an in-situ generation technology of a fusion casting method, a TiB reinforcing phase is uniformly distributed and well combined with a titanium matrix, and compared with an unreinforced titanium alloy, the tensile breaking strength of the composite material at room temperature and 650 ℃ is improved, but the plasticity of the composite material is reduced to a greater extent.
The invention provides a TiB particle reinforced Ti-based composite material capable of effectively improving the plasticity, and aims to solve the technical problem that the plasticity of the TiB particle reinforced Ti-based composite material cannot be effectively improved while the tensile strength of the TiB particle reinforced Ti-based composite material is effectively improved.
Disclosure of Invention
Technical problem to be solved
Aiming at the defects of the prior art, the invention provides the TiB particle reinforced Ti-based composite material capable of effectively improving the plasticity, and solves the technical problem that the plasticity of the TiB particle reinforced Ti-based composite material cannot be effectively improved while the tensile strength of the TiB particle reinforced Ti-based composite material is effectively improved.
(II) technical scheme
In order to achieve the purpose, the invention provides the following technical scheme:
a TiB particle reinforced Ti-based composite material capable of effectively improving plasticity comprises the following raw materials in parts by weight: 50-60 parts of micron Ti powder, 10-20 parts of micron TiB ceramic particles, 5-10 parts of micron Al powder and 5-10 microns of glass powder.
Preferably, the micron glass powder consists of 40 percent wtPbO and 20 percent wtSiO with the average grain diameter less than or equal to 2.6um2、25%wtTiO2And 15% wtB2O3And (4) forming.
Preferably, the preparation method of the composite material comprises the following steps:
s101, taking 50-60 parts of micron Ti powder, 10-20 parts of micron TiB ceramic particles, 5-10 parts of micron Al powder and 5-10 microns of glass powder for later use;
s102, placing the Ti powder and sodium silicate in the step S101 into distilled water, and performing ultrasonic dispersion uniformly;
s103, placing the TiB particles and sodium pyrophosphate in the step S101 into distilled water together, and performing ultrasonic dispersion uniformly;
s104, placing the Al powder and the sodium silicate in the step S101 into distilled water together, and performing ultrasonic dispersion uniformly;
s105, adding the Ti dispersion liquid in the step S102 into a reactor provided with a stirring device and a heating device, slowly and dropwise adding the TiB dispersion liquid in the step S103 into the reactor at a stirring speed of 600r/min, slowly and dropwise adding the Al dispersion liquid in the step S104 into the reactor after dropwise adding, stirring for 2 hours at 800r/min after dropwise adding, and then evaporating and removing the solvent at the temperature of 120 ℃ and at a stirring speed of 300 r/min;
s106, adding the glass powder in the step S101 and the powder in the step S105 into a reactor provided with a stirrer, and stirring for 2 hours at the speed of 800 r/min;
s107, the powder in the step S106 is placed into an isostatic pressing rubber mold, compression molding is carried out under the pressure of 150MPa, the powder is placed into a vacuum furnace with the preheating temperature of 680 ℃, the temperature is raised to 1700-1850 ℃ at the heating rate of 10 ℃/min, heat preservation is carried out for 2 hours at the temperature of 1700-1850 ℃ and the pressure of 6-8 MPa, then the powder is taken out when the temperature is reduced to the room temperature at the annealing rate of 5 ℃/min, and the TiB particle reinforced Ti-based composite material is prepared.
Preferably, in step S107, the temperature of the composite material is raised to 1800 ℃ and maintained at 1800 ℃ and 7MPa for 2 hours.
(III) advantageous technical effects
Compared with the prior art, the invention has the following beneficial technical effects:
according to the invention, a micron Al powder and glass powder bonding phase is added between the Ti matrix and the reinforcing phase TiB ceramic particles, the micron Al powder can obviously improve the plasticity of the TiB particle reinforced Ti matrix composite material at normal temperature, and the glass powder bonding phase can enable the plasticity of the TiB particle reinforced Ti matrix composite material at high temperature to be improved between the Ti matrix and the reinforcing phase TiB ceramic particles through the self melting and solidifying effects;
the TiB particle reinforced Ti-based composite material prepared by the invention has the tensile strength of 1426-1487 MPa and the elongation of 7.1-7.9% at room temperature, and has the tensile strength of 702-731 MPa and the elongation of 33.2-37.4% at 800 ℃;
compared with the TiB particle reinforced Ti-based composite material prepared in the comparative example, the TiB particle reinforced Ti-based composite material has the advantages that the tensile strength is 1243MPa and the elongation rate is 2.1% at room temperature, and the tensile strength is 652MPa and the elongation rate is 18.5% at 800 ℃, so that the technical effect of remarkably improving the mechanical property and the plastic property of the TiB particle reinforced Ti-based composite material is achieved.
Detailed Description
The first embodiment is as follows:
the preparation method of the TiB particle reinforced Ti-based composite material comprises the following steps:
s101, taking 50g of Ti powder with the average particle size of less than or equal to 25um, 20g of TiB ceramic particles with the average particle size of less than or equal to 10um, 5g of Al powder with the average particle size of less than or equal to 6.5um and 10g of glass powder with the average particle size of less than or equal to 2.6um for later use; wherein the glass powder consists of 40 percent of wtPbO and 20 percent of wtSiO2、25%wtTiO2And 15% wtB2O3Composition is carried out;
s102, putting the Ti powder obtained in the step S101 and 5g of sodium silicate into 100mL of distilled water, and performing ultrasonic dispersion uniformly;
s103, putting the TiB particles and 2g of sodium pyrophosphate in the step S101 into 30mL of distilled water, and performing ultrasonic dispersion uniformly;
s104, putting the Al powder in the step S101 and 1g of sodium silicate into 20mL of distilled water, and performing ultrasonic dispersion uniformly;
s105, adding the Ti dispersion liquid in the step S102 into a reactor provided with a stirring device and a heating device, slowly and dropwise adding the TiB dispersion liquid in the step S103 into the reactor at a stirring speed of 600r/min, slowly and dropwise adding the Al dispersion liquid in the step S104 into the reactor after dropwise adding, stirring for 2 hours at 800r/min after dropwise adding, and then evaporating and removing the solvent at the temperature of 120 ℃ and at a stirring speed of 300 r/min;
s106, adding the glass powder in the step S101 and the powder in the step S105 into a reactor provided with a stirrer, and stirring for 2 hours at the speed of 800 r/min;
s107, the powder in the step S106 is filled into an isostatic pressing rubber mold, is pressed and molded under the pressure of 150MPa, is placed into a vacuum furnace with the preheating temperature of 680 ℃, is heated to 1800 ℃ at the heating rate of 10 ℃/min, is kept warm for 2h at 1800 ℃ and 7MPa, is cooled to room temperature at the annealing rate of 5 ℃/min, and is taken out to prepare the TiB particle reinforced Ti-based composite material.
Example two:
the preparation method of the TiB particle reinforced Ti-based composite material comprises the following steps:
s101, taking 60g of Ti powder with the average particle size of less than or equal to 25um, 10g of TiB ceramic particles with the average particle size of less than or equal to 10um, 10g of Al powder with the average particle size of less than or equal to 6.5um and 5g of glass powder with the average particle size of less than or equal to 2.6um for later use; wherein the glass powder consists of 40 percent of wtPbO and 20 percent of wtSiO2、25%wtTiO2And 15% wtB2O3Composition is carried out;
s102, putting the Ti powder obtained in the step S101 and 5g of sodium silicate into 100mL of distilled water, and performing ultrasonic dispersion uniformly;
s103, putting the TiB particles and 2g of sodium pyrophosphate in the step S101 into 30mL of distilled water, and performing ultrasonic dispersion uniformly;
s104, putting the Al powder in the step S101 and 1g of sodium silicate into 20mL of distilled water, and performing ultrasonic dispersion uniformly;
s105, adding the Ti dispersion liquid in the step S102 into a reactor provided with a stirring device and a heating device, slowly and dropwise adding the TiB dispersion liquid in the step S103 into the reactor at a stirring speed of 600r/min, slowly and dropwise adding the Al dispersion liquid in the step S104 into the reactor after dropwise adding, stirring for 2 hours at 800r/min after dropwise adding, and then evaporating and removing the solvent at the temperature of 120 ℃ and at a stirring speed of 300 r/min;
s106, adding the glass powder in the step S101 and the powder in the step S105 into a reactor provided with a stirrer, and stirring for 2 hours at the speed of 800 r/min;
s107, the powder in the step S106 is filled into an isostatic pressing rubber mold, is pressed and molded under the pressure of 150MPa, is placed into a vacuum furnace with the preheating temperature of 680 ℃, is heated to 1700 ℃ at the heating rate of 10 ℃/min, is kept at 1700 ℃ and 8MPa for 2 hours, is cooled to room temperature at the annealing rate of 5 ℃/min, and is taken out to prepare the TiB particle reinforced Ti-based composite material.
Example three:
the TiB particle reinforced Ti-based composite material comprises the following raw materials: 10g of glass powder with the average grain diameter less than or equal to 2.6um,
the preparation method of the TiB particle reinforced Ti-based composite material comprises the following steps:
s101, taking 55g of Ti powder with the average particle size of less than or equal to 25um, 15g of TiB ceramic particles with the average particle size of less than or equal to 10um, 8g of Al powder with the average particle size of less than or equal to 6.5um and 8g of glass powder with the average particle size of less than or equal to 2.6um for later use; wherein the glass powder consists of 40 percent of wtPbO and 20 percent of wtSiO2、25%wtTiO2And 15% wtB2O3Composition is carried out;
s102, putting the Ti powder obtained in the step S101 and 5g of sodium silicate into 100mL of distilled water, and performing ultrasonic dispersion uniformly;
s103, putting the TiB particles and 2g of sodium pyrophosphate in the step S101 into 30mL of distilled water, and performing ultrasonic dispersion uniformly;
s104, putting the Al powder in the step S101 and 1g of sodium silicate into 20mL of distilled water, and performing ultrasonic dispersion uniformly;
s105, adding the Ti dispersion liquid in the step S102 into a reactor provided with a stirring device and a heating device, slowly and dropwise adding the TiB dispersion liquid in the step S103 into the reactor at a stirring speed of 600r/min, slowly and dropwise adding the Al dispersion liquid in the step S104 into the reactor after dropwise adding, stirring for 2 hours at 800r/min after dropwise adding, and then evaporating and removing the solvent at the temperature of 120 ℃ and at a stirring speed of 300 r/min;
s106, adding the glass powder in the step S101 and the powder in the step S105 into a reactor provided with a stirrer, and stirring for 2 hours at the speed of 800 r/min;
s107, the powder in the step S106 is filled into an isostatic pressing rubber mold, is pressed and molded under the pressure of 150MPa, is placed into a vacuum furnace with the preheating temperature of 680 ℃, is heated to 1850 ℃ at the heating rate of 10 ℃/min, is kept warm for 2 hours at 1850 ℃ and 8MPa, is cooled to the room temperature at the annealing rate of 5 ℃/min, and is taken out to prepare the TiB particle reinforced Ti-based composite material.
Comparative example:
the preparation method of the TiB particle reinforced Ti-based composite material comprises the following steps:
s101, taking 50g of Ti powder with the average particle size of less than or equal to 25um, 20g of TiB ceramic particles with the average particle size of less than or equal to 10um and 10g of glass powder with the average particle size of less than or equal to 2.6um for later use; wherein the glass powder consists of 40 percent of wtPbO and 20 percent of wtSiO2、25%wtTiO2And 15% wtB2O3Composition is carried out;
s102, putting the Ti powder obtained in the step S101 and 5g of sodium silicate into 100mL of distilled water, and performing ultrasonic dispersion uniformly;
s103, putting the TiB particles and 2g of sodium pyrophosphate in the step S101 into 30mL of distilled water, and performing ultrasonic dispersion uniformly;
s104, adding the Ti dispersion liquid in the step S102 into a reactor provided with a stirring device and a heating device, slowly dropwise adding the TiB dispersion liquid in the step S103 into the reactor at a stirring speed of 600r/min, stirring for 2 hours at 800r/min after dropwise adding, and then evaporating and removing the solvent at a temperature of 120 ℃ and at a stirring speed of 300 r/min;
s105, adding the glass powder in the step S101 and the powder in the step S104 into a reactor provided with a stirrer, and stirring for 2 hours at the speed of 800 r/min;
s106, filling the powder in the step S106 into an isostatic pressing rubber mold, performing compression molding under the pressure of 150MPa, then placing the isostatic pressing rubber mold into a vacuum furnace with the preheating temperature of 680 ℃, heating the isostatic pressing rubber mold to 1800 ℃ at the heating rate of 10 ℃/min, performing heat preservation for 2 hours at 1800 ℃ and 7MPa, then cooling the isostatic pressing rubber mold to room temperature at the annealing rate of 5 ℃/min, and taking the isostatic pressing rubber mold out to prepare the TiB particle reinforced Ti-based composite material.
And (3) performance testing:
the TiB particle reinforced Ti-based composite materials prepared in the above examples and comparative examples were subjected to performance tests, and the performance data were as follows:
Claims (3)
1. a TiB particle reinforced Ti-based composite material capable of effectively improving plasticity is characterized by comprising the following raw materials in parts by weight: 50-60 parts of micron Ti powder, 10-20 parts of micron TiB ceramic particles, 5-10 parts of micron Al powder and 5-10 microns of glass powder; the preparation method of the composite material comprises the following steps:
s101, taking 50-60 parts of micron Ti powder, 10-20 parts of micron TiB ceramic particles, 5-10 parts of micron Al powder and 5-10 microns of glass powder for later use;
s102, placing the Ti powder and sodium silicate in the step S101 into distilled water, and performing ultrasonic dispersion uniformly;
s103, placing the TiB particles and sodium pyrophosphate in the step S101 into distilled water together, and performing ultrasonic dispersion uniformly;
s104, placing the Al powder and the sodium silicate in the step S101 into distilled water together, and performing ultrasonic dispersion uniformly;
s105, adding the Ti dispersion liquid in the step S102 into a reactor provided with a stirring device and a heating device, slowly and dropwise adding the TiB dispersion liquid in the step S103 into the reactor at a stirring speed of 600r/min, slowly and dropwise adding the Al dispersion liquid in the step S104 into the reactor after dropwise adding, stirring for 2 hours at 800r/min after dropwise adding, and then evaporating and removing the solvent at the temperature of 120 ℃ and at a stirring speed of 300 r/min;
s106, adding the glass powder in the step S101 and the powder in the step S105 into a reactor provided with a stirrer, and stirring for 2 hours at the speed of 800 r/min;
s107, the powder in the step S106 is placed into an isostatic pressing rubber mold, compression molding is carried out under the pressure of 150MPa, the powder is placed into a vacuum furnace with the preheating temperature of 680 ℃, the temperature is raised to 1700-1850 ℃ at the heating rate of 10 ℃/min, heat preservation is carried out for 2 hours at the temperature of 1700-1850 ℃ and the pressure of 6-8 MPa, then the powder is taken out when the temperature is reduced to the room temperature at the annealing rate of 5 ℃/min, and the TiB particle reinforced Ti-based composite material is prepared.
2. The composite material of claim 1, wherein the micro glass frit is composed of 40% wtPbO, 20% wtSiO with average particle size of 2.6um or less2、25%wtTiO2And 15% wtB2O3And (4) forming.
3. The composite material of claim 1, wherein in step S107, the temperature of the composite material is raised to 1800 ℃ and maintained at 1800 ℃ and 7MPa for 2 h.
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN87101815A (en) * | 1986-03-12 | 1987-09-23 | 奥林公司 | With glass is the sintering metal substrate of adhesion component |
US5908516A (en) * | 1996-08-28 | 1999-06-01 | Nguyen-Dinh; Xuan | Titanium Aluminide alloys containing Boron, Chromium, Silicon and Tungsten |
EP1657317A1 (en) * | 2004-11-12 | 2006-05-17 | General Electric Company | Article having a dispersion of ultrafine titanium boride particles in a titanium-base matrix |
CN101240382A (en) * | 2007-02-05 | 2008-08-13 | 中南大学 | Method for preparing high dense TiAl-base alloy |
CN101927341A (en) * | 2009-06-24 | 2010-12-29 | 赵凤宇 | Nepheline glass ceramic and metal powder composite material and preparation method thereof |
CN102242303B (en) * | 2011-07-26 | 2012-10-10 | 吉林大学 | In-situ nano TiC ceramic particle reinforced copper based composite material and preparation method thereof |
-
2019
- 2019-04-10 CN CN201910284526.XA patent/CN109971996B/en not_active Expired - Fee Related
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN87101815A (en) * | 1986-03-12 | 1987-09-23 | 奥林公司 | With glass is the sintering metal substrate of adhesion component |
US5908516A (en) * | 1996-08-28 | 1999-06-01 | Nguyen-Dinh; Xuan | Titanium Aluminide alloys containing Boron, Chromium, Silicon and Tungsten |
EP1657317A1 (en) * | 2004-11-12 | 2006-05-17 | General Electric Company | Article having a dispersion of ultrafine titanium boride particles in a titanium-base matrix |
CN101240382A (en) * | 2007-02-05 | 2008-08-13 | 中南大学 | Method for preparing high dense TiAl-base alloy |
CN101927341A (en) * | 2009-06-24 | 2010-12-29 | 赵凤宇 | Nepheline glass ceramic and metal powder composite material and preparation method thereof |
CN102242303B (en) * | 2011-07-26 | 2012-10-10 | 吉林大学 | In-situ nano TiC ceramic particle reinforced copper based composite material and preparation method thereof |
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