CN109944756A - A kind of solar light-heat power-generation system and method based on methane reforming energy storage - Google Patents

A kind of solar light-heat power-generation system and method based on methane reforming energy storage Download PDF

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Publication number
CN109944756A
CN109944756A CN201910292154.5A CN201910292154A CN109944756A CN 109944756 A CN109944756 A CN 109944756A CN 201910292154 A CN201910292154 A CN 201910292154A CN 109944756 A CN109944756 A CN 109944756A
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heat
outlet
entrance
methane
valve
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张纯
杨玉
张磊
白文刚
李红智
姚明宇
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Xian Thermal Power Research Institute Co Ltd
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Xian Thermal Power Research Institute Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/40Solar thermal energy, e.g. solar towers
    • Y02E10/46Conversion of thermal power into mechanical power, e.g. Rankine, Stirling or solar thermal engines
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/133Renewable energy sources, e.g. sunlight

Abstract

The invention discloses a kind of solar light-heat power-generation system and methods based on methane reforming energy storage, including heat collector, the outlet of heat collector is connected with the hot side entrance of heat exchanger 4, the hot side outlet of heat exchanger is connected with the entrance of heat-exchanger circuit compressor, and the outlet of heat-exchanging loop compressor is connected with the entrance of heat collector;The outlet of heat collector is connected with the shell side inlet of methane reforming endothermic reaction device, and the shell-side outlet of methane reforming endothermic reaction device is connected with the entrance of heat-exchanger circuit compressor;Heat collector corresponding position be provided with for by solar light focusing in the Jing Chang on heat collector, the system can be realized methane reforming energy storage and organically be combined with solar light-heat power-generation, methane reforming energy storage is combined with solar light-heat power-generation, can be realized and can be carried out steadily lasting utilization to the sun.

Description

A kind of solar light-heat power-generation system and method based on methane reforming energy storage
Technical field
The present invention relates to technical field of solar utilization technique, in particular to a kind of solar energy optical-thermal based on methane reforming energy storage Electricity generation system and method.
Background technique
Solar energy has the characteristics that cleaning, inexhaustible, but there are problems that the time is unevenly distributed, solar energy It is typically necessary when for generating electricity using technologies such as energy storage.
Heat chemistry energy storage is mainly based upon a kind of reversible thermal chemical reaction, realizes energy by the fracture recombination of chemical bond Storage and release, in energy storage reaction, energy storage material absorbs heat and resolves into two kinds of substances and individually store, when needing to energize When, two kinds of substances come into full contact with and react, and convert thermal energy for the chemical energy of storage and release.Heat chemistry energy storage density With high-efficient, suitable for solar energy high-temperature high-density storage.The volume and weight energy storage density of heat chemistry energy storage is far high In sensible heat or phase-transition heat-storage, energy storage carrier long term storage, heat chemistry energy storage can be commonly available high-grade at normal temperature Thermal energy, it is most of heat chemistry energy storage vectors safes, nontoxic, cheap, and convenient for processing.Wherein, methane reforming is a kind of Common heat chemistry energy storage system, energy storage density is high, and raw material sources are abundant.
In northwest China area, solar energy resources are abundant, if it is possible to develop a kind of new system, the system The energy storage of methane reforming heat chemistry can organically be combined with solar light-heat power-generation, solar light-heat power-generation can be brought Great variety.
Summary of the invention
In order to overcome the above-mentioned deficiencies of the prior art, the purpose of the present invention is to provide a kind of based on methane reforming energy storage Methane reforming energy storage is combined with solar light-heat power-generation, be can be realized to the sun by solar light-heat power-generation system and method It can be carried out steadily lasting utilization.
To achieve the goals above, the technical solution adopted by the present invention is that:
A kind of solar light-heat power-generation system based on methane reforming energy storage, including heat collector 2, the outlet of heat collector 2 with The hot side entrance of heat exchanger 4 is connected, and the hot side outlet of heat exchanger 4 is connected with the entrance of heat-exchanger circuit compressor 5, heat exchange The outlet of circuit compressor 5 is connected with the entrance of heat collector 2;
The outlet of the heat collector 2 is connected with the shell side inlet of methane reforming endothermic reaction device 7, methane reforming heat absorption The shell-side outlet of reactor 7 is connected with the entrance of heat-exchanger circuit compressor 5;
2 corresponding position of heat collector be provided with for by solar light focusing in the mirror field 1 on heat collector 2.
The tube side outlet of the methane reforming endothermic reaction device 7 is connected with carbon monoxide and 9 entrance of hydrogen-holder, and one The outlet of carbonoxide and hydrogen-holder 9 with release can 11 entrance of Alternative Refrigerant Compressors be connected, release can Alternative Refrigerant Compressors 11 outlet with The tube-side inlet of methane synthesis exothermic reactor 13 is connected, and methane synthesizes tube side outlet and methane and two of exothermic reactor 13 14 entrance of carbonoxide storage tank is connected, and the outlet of methane and carbon dioxide storage tank 14 is connected with 16 entrance of energy storage Alternative Refrigerant Compressors, The outlet of energy storage Alternative Refrigerant Compressors 16 is connected with the tube-side inlet of methane reforming endothermic reaction device 7.
The entrance and exit for releasing energy Alternative Refrigerant Compressors 11, which is respectively arranged with, releases 10 He of energy Alternative Refrigerant Compressors inlet valve Energy Alternative Refrigerant Compressors outlet valve 12 is released, the entrance and exit of energy storage Alternative Refrigerant Compressors 16 is respectively arranged with energy storage Alternative Refrigerant Compressors and enters Mouth valve 15 and energy storage Alternative Refrigerant Compressors outlet valve 17.
The shell-side outlet of the methane synthesis exothermic reactor 13 is connected with the hot side entrance of heat exchanger 4, heat exchanger 4 Hot side outlet with release can the entrance of circuit compressor 20 be connected, release can the outlet of circuit compressor 20 synthesize heat release with methane The shell side inlet of reactor 13 is connected.
It is provided between the shell-side outlet of methane synthesis exothermic reactor 13 and the hot side entrance of heat exchanger 4 and releases energy Circuit outlet valve 18, release can the outlet of circuit compressor 20 synthesize with methane and be provided between the shell side inlet of exothermic reactor 13 Releasing can circuit entrance valve 19.
The cold side outlet port of the heat exchanger 4 is connected with 21 entrance of electricity generation system, the outlet of electricity generation system 21 and heat exchanger 4 Cold side input port be connected.
Heat-exchanging loop valve 3 is provided between the outlet of the heat collector 2 and the hot side entrance of heat exchanger 4.
Tank circuit is provided between the shell side inlet of the heat-exchanging loop valve 3 and methane reforming endothermic reaction device 7 Inlet valve 6 is provided with energy storage between the shell-side outlet of methane reforming endothermic reaction device 7 and the entrance of heat-exchanger circuit compressor 5 Circuit outlet valve 8.
The methane reforming endothermic reaction device 7 and methane synthesis exothermic reactor 13 are shell-and-tube.
A kind of solar light-heat power-generation method based on methane reforming energy storage, comprising the following steps:
When solar radiation abundance, heat-exchanging loop valve 3, tank circuit inlet valve 6, tank circuit outlet valve 8, energy storage work Matter suction port of compressor valve 15 and energy storage Alternative Refrigerant Compressors outlet valve 17 are opened, and are released energy Alternative Refrigerant Compressors inlet valve 10, are released energy working medium Compressor outlet valve 12 releases energy circuit outlet valve 18 and releases energy circuit entrance valve 19 and closes, the heat transfer work heated by heat collector 2 Matter enters 4 hot side of heat exchanger, and after the generating working medium heat exchange of electricity generation system 21, heat-transfer working medium enters heat-exchanging loop compressor 5, warp Enter heat collector 2 after being overpressurized, completes circulation.Generating working medium, into electricity generation system 21, is done after the heat absorption of the cold side of heat exchanger 4 The cold side that heat exchanger 4 is returned to after function continues to absorb heat, and completes circulation, and a part of heat-transfer working medium enters by tank circuit inlet valve 6 The shell side of methane reforming endothermic reaction device 7, the methane and carbon dioxide in methane and carbon dioxide storage tank 14 pass through energy storage working medium Compressor 16 enters the tube side of methane reforming endothermic reaction device 7 after pressurizeing, methane and carbon dioxide occurs to reform in tube side anti- The heat of heat-transfer working medium should be absorbed, carbon monoxide and hydrogen, the heat transfer into carbon monoxide and hydrogen-holder 9, after heat exchange are generated Working medium enters heat-exchanging loop compressor 5 by tank circuit outlet valve 8, and heat collector is returned to after being overpressurized and continues to absorb heat;
When there is no solar radiation, heat-exchanging loop valve 3, tank circuit inlet valve 6, tank circuit outlet valve 8, energy storage work Matter suction port of compressor valve 15 and energy storage Alternative Refrigerant Compressors outlet valve 17 are closed, and are released energy Alternative Refrigerant Compressors inlet valve 10, are released energy working medium Compressor outlet valve 12 releases energy circuit outlet valve 18 and releases energy circuit entrance valve 19 and opens, in carbon monoxide and hydrogen-holder 9 Carbon monoxide and hydrogen enter the tube side of methane synthesis exothermic reactor 13, an oxidation after releasing energy Alternative Refrigerant Compressors 11 and pressurizeing Carbon and hydrogen reaction generate methane and carbon dioxide, release heat, after the heat-transfer working medium heat exchange of shell side, into methane and two Carbonoxide storage tank 14, the heat-transfer working medium of shell side enter the hot side entrance of heat exchanger 4 after heating by releasing energy circuit outlet valve, After the generating working medium heat exchange of electricity generation system 21, heat-transfer working medium, which enters, releases energy circuit compressor 20, and methane is entered after being overpressurized Synthesis exothermic reactor 13 continues to absorb heat, and completes circulation, generating working medium is after the heat absorption of the cold side of heat exchanger 4, into electricity generation system 21, the cold side that heat exchanger 4 is returned to after acting continues to absorb heat, and completes circulation.
Beneficial effects of the present invention:
It is of the present invention based on the solar light-heat power-generation system of methane reforming energy storage in specific works, pass through thermal-arrest Device heats heat-transfer working medium using solar energy, and a part of heat-transfer working medium is sent into methane reforming endothermic reaction device shell side In, reforming reaction occurs after the methane and carbon dioxide heat absorption in tube side, absorbs heat.In solar radiation deficiency, by one Carbonoxide and hydrogen are sent into methane and synthesize exothermic reactor tube side, react, release heat, to realize that methane reforming stores up It can be with the combination of solar light-heat power-generation.
Detailed description of the invention
Fig. 1 is system schematic of the invention.
Wherein, 1 it is Jing Chang, 2 be heat collector, 3 be heat-exchanging loop valve, 4 be heat exchanger, 5 is heat-exchanging loop compressor, 6 For tank circuit inlet valve, 7 be methane reforming endothermic reaction device, 8 be tank circuit outlet valve, 9 be carbon monoxide and hydrogen storage Tank, 10 for release can Alternative Refrigerant Compressors inlet valves, 11 for release can Alternative Refrigerant Compressors, 12 for release can Alternative Refrigerant Compressors outlet valve, 13 be Methane synthesis exothermic reactor, 14 be methane and carbon dioxide storage tank, 15 be energy storage Alternative Refrigerant Compressors inlet valve, 16 be energy storage work Matter compressor, 17 be energy storage Alternative Refrigerant Compressors outlet valve, 18 for release can circuit outlet valve, 19 for release can circuit entrance valve, 20 be Releasing can circuit compressor, 21 electricity generation systems.
Specific embodiment
The present invention is described in further detail below in conjunction with the accompanying drawings.
With reference to Fig. 1, the solar light-heat power-generation system of the present invention based on methane reforming energy storage, including heat collector 2, Heat exchanger 4, methane reforming endothermic reaction device 7, carbon monoxide and hydrogen-holder 9, methane synthesize exothermic reactor 13, methane and two Carbonoxide storage tank 14, heat-exchanging loop compressor 5, releases energy Alternative Refrigerant Compressors 11, energy storage Alternative Refrigerant Compressors 16, releases electricity generation system 21 It can circuit compressor 20.The outlet of heat collector 2 is connected with the entrance of 4 hot side of heat exchanger, the outlet and heat exchange of 4 hot side of heat exchanger 5 entrance of circuit compressor is connected, and the outlet of heat-exchanging loop compressor 5 is connected with 2 entrance of heat collector.
The outlet of heat collector 2 is connected with the shell side inlet of methane reforming endothermic reaction device 7, methane reforming endothermic reaction device 7 shell-side outlet is connected with the entrance of heat-exchanger circuit compressor 5.The tube side outlet and one of methane reforming endothermic reaction device 7 Carbonoxide is connected with 9 entrance of hydrogen-holder, the outlet of carbon monoxide and hydrogen-holder 9 with release can 11 entrance phase of Alternative Refrigerant Compressors Connection, release can the outlets of Alternative Refrigerant Compressors 11 synthesize the tube-side inlet of exothermic reactor 13 with methane and be connected, methane is synthesized and is put The tube side outlet of thermal reactor 13 is connected with 14 entrance of methane and carbon dioxide storage tank, and methane and carbon dioxide storage tank 14 exports It is connected with 16 entrance of energy storage Alternative Refrigerant Compressors, the tube side of energy storage Alternative Refrigerant Compressors 16 outlet and methane reforming endothermic reaction device 7 Entrance is connected.The shell-side outlet of methane synthesis exothermic reactor 13 is connected with the hot side entrance of heat exchanger 4, heat exchanger 4 Hot side outlet with release can the entrance of circuit compressor 20 be connected, releasing can with methane to synthesize heat release anti-the outlet of circuit compressor 20 The shell side inlet of device 13 is answered to be connected.
The cold side outlet port of heat exchanger 4 is connected with 21 entrance of electricity generation system, the cold side of electricity generation system 21 outlet and heat exchanger 4 Entrance is connected.
As the preferred embodiment of the present invention, the invention also includes heat-exchanging loop valve 3, tank circuit inlet valve 6, storages Can circuit outlet valve 8, release can Alternative Refrigerant Compressors inlet valve 10, release can Alternative Refrigerant Compressors outlet valve 12, energy storage Alternative Refrigerant Compressors enter Mouth valve 15, energy storage Alternative Refrigerant Compressors outlet valve 17 release energy circuit outlet valve 18 and release energy circuit entrance valve 19.
Preferably, electricity generation system 21 can be steam Rankine cycle electricity generation system, organic Rankine cycle power generation system or Supercritical carbon dioxide Brayton cycle electricity generation system.
Mirror field 1 gathers sunlight on heat collector 2, enters 4 heat of heat exchanger by the heat-transfer working medium that heat collector 2 heats Behind side, with the generating working medium heat exchange of electricity generation system 21, heat-transfer working medium enters heat-exchanging loop compressor 5, and collection is entered after being overpressurized Hot device 2 completes circulation.Generating working medium, into electricity generation system 21, returns to heat exchanger 4 after the heat absorption of the cold side of heat exchanger 4 after acting Cold side continue to absorb heat, complete circulation.
When solar radiation abundance, tank circuit inlet valve 6, tank circuit outlet valve 8, energy storage Alternative Refrigerant Compressors inlet valve 15 and energy storage Alternative Refrigerant Compressors outlet valve 17 open, release can Alternative Refrigerant Compressors inlet valve 10, release can Alternative Refrigerant Compressors outlet valve 12, It releases energy circuit outlet valve 18 and releases energy circuit entrance valve 19 and close.By the heat-transfer working medium that heat collector 2 heats, a part is by storage Energy circuit entrance valve 6 enters the shell side of methane reforming endothermic reaction device 7, methane and dioxy in methane and carbon dioxide storage tank 14 Change the tube side that carbon enters methane reforming endothermic reaction device 7 after the pressurization of energy storage Alternative Refrigerant Compressors 16, methane and carbon dioxide exists The heat that reforming reaction absorbs heat-transfer working medium occurs in tube side, generates carbon monoxide and hydrogen, is stored up into carbon monoxide and hydrogen Tank 9.Heat-transfer working medium after heat exchange enters heat-exchanging loop compressor 5 by tank circuit outlet valve 8, and thermal-arrest is returned to after being overpressurized Device continues to absorb heat.
When there is no solar radiation, heat-exchanging loop valve 3, tank circuit inlet valve 6, tank circuit outlet valve 8, energy storage Alternative Refrigerant Compressors inlet valve 15 and energy storage Alternative Refrigerant Compressors outlet valve 17 are closed, and are released energy Alternative Refrigerant Compressors inlet valve 10, are released energy work Matter compressor outlet valve 12 releases energy circuit outlet valve 18 and releases energy circuit entrance valve 19 and opens.In carbon monoxide and hydrogen-holder 9 Carbon monoxide and hydrogen through releasing can Alternative Refrigerant Compressors 11 pressurize after enter methane synthesis exothermic reactor 13 tube side, an oxygen Change carbon and hydrogen reaction generate methane and carbon dioxide, release heat, after the heat exchange of the heat-transfer working medium of shell side, into methane and Carbon dioxide storage tank 14, the hot side that the heat-transfer working medium of shell side enters heat exchanger 4 after heating by releasing energy circuit outlet valve enter Mouthful, after the generating working medium heat exchange of electricity generation system 21, heat-transfer working medium, which enters, releases energy circuit compressor 20, and first is entered after being overpressurized Alkane synthesis exothermic reactor 13 continues to absorb heat, and completes circulation.Generating working medium is after the heat absorption of the cold side of heat exchanger 4, into power generation system System 21, the cold side that heat exchanger 4 is returned to after acting continues to absorb heat, and completes circulation.
It should be pointed out that the technical concept and feature of above-described embodiment only to illustrate the invention, specific implementation method, The type of the type, electricity generation system 21 of such as heat-exchanging loop compressor 5 still can modify and improve, but all will not be therefrom The scope of the present invention and essence spirit of defined in claims.

Claims (10)

1. a kind of solar light-heat power-generation system based on methane reforming energy storage, which is characterized in that including heat collector (2), thermal-arrest The outlet of device (2) is connected with the hot side entrance of heat exchanger 4, the hot side outlet of heat exchanger (4) and heat-exchanger circuit compressor (5) Entrance be connected, the outlet of heat-exchanging loop compressor (5) is connected with the entrance of heat collector (2);
The outlet of the heat collector (2) is connected with the shell side inlet of methane reforming endothermic reaction device (7), methane reforming heat absorption The shell-side outlet of reactor (7) is connected with the entrance of heat-exchanger circuit compressor (5);
Heat collector (2) corresponding position be provided with for by solar light focusing in the Jing Chang (1) on heat collector (2).
2. a kind of solar light-heat power-generation system based on methane reforming energy storage according to claim 1, which is characterized in that The tube side outlet of the methane reforming endothermic reaction device (7) is connected with carbon monoxide and hydrogen-holder (9) entrance, an oxidation The outlet of carbon and hydrogen-holder (9) is connected with energy Alternative Refrigerant Compressors (11) entrance is released, and releases the outlet of energy Alternative Refrigerant Compressors (11) The tube-side inlet that exothermic reactor (13) is synthesized with methane is connected, and methane synthesizes the tube side outlet and first of exothermic reactor (13) Alkane is connected with carbon dioxide storage tank (14) entrance, methane and carbon dioxide storage tank (14) outlet and energy storage Alternative Refrigerant Compressors (16) Entrance is connected, and energy storage Alternative Refrigerant Compressors (16) outlet is connected with the tube-side inlet of methane reforming endothermic reaction device (7).
3. a kind of solar light-heat power-generation system based on methane reforming energy storage according to claim 2, which is characterized in that The entrance and exit for releasing energy Alternative Refrigerant Compressors (11), which is respectively arranged with, to be released energy Alternative Refrigerant Compressors inlet valve (10) and releases energy Alternative Refrigerant Compressors outlet valve (12), the entrance and exit of energy storage Alternative Refrigerant Compressors (16) are respectively arranged with energy storage Alternative Refrigerant Compressors and enter Mouth valve (15) and energy storage Alternative Refrigerant Compressors outlet valve (17).
4. a kind of solar light-heat power-generation system based on methane reforming energy storage according to claim 2, which is characterized in that The shell-side outlet of methane synthesis exothermic reactor (13) is connected with the hot side entrance of heat exchanger 4, the heat of heat exchanger (4) Side outlet is connected with the entrance for releasing energy circuit compressor (20), and the outlet for releasing energy circuit compressor (20) synthesizes heat release with methane The shell side inlet of reactor (13) is connected.
5. a kind of solar light-heat power-generation system based on methane reforming energy storage according to claim 2, which is characterized in that It is provided between the shell-side outlet of methane synthesis exothermic reactor (13) and the hot side entrance of heat exchanger (4) and releases energy circuit Outlet valve (18), release can the outlet of circuit compressor (20) synthesize with methane and be arranged between the shell side inlets of exothermic reactor (13) Releasing can circuit entrance valve (19).
6. a kind of solar light-heat power-generation system based on methane reforming energy storage according to claim 2, which is characterized in that The methane reforming endothermic reaction device (7) and methane synthesis exothermic reactor (13) are shell-and-tube.
7. a kind of solar light-heat power-generation system based on methane reforming energy storage according to claim 1, which is characterized in that The cold side outlet port of the heat exchanger (4) is connected with electricity generation system (21) entrance, electricity generation system (21) outlet and heat exchanger 4 Cold side input port is connected.
8. a kind of solar light-heat power-generation system based on methane reforming energy storage according to claim 1, which is characterized in that Heat-exchanging loop valve (3) are provided between the outlet of heat collector (2) and the hot side entrance of heat exchanger 4.
9. a kind of solar light-heat power-generation system based on methane reforming energy storage according to claim 8, which is characterized in that Tank circuit entrance is provided between the shell side inlet of the heat-exchanging loop valve (3) and methane reforming endothermic reaction device (7) Valve (6) is provided with storage between the shell-side outlet of methane reforming endothermic reaction device (7) and the entrance of heat-exchanger circuit compressor (5) It can circuit outlet valve (8).
10. a kind of solar light-heat power-generation method based on methane reforming energy storage, which comprises the following steps:
When solar radiation abundance, heat-exchanging loop valve (3), tank circuit inlet valve (6), tank circuit outlet valve (8), energy storage Alternative Refrigerant Compressors inlet valve (15) and energy storage Alternative Refrigerant Compressors outlet valve (17) are opened, release can Alternative Refrigerant Compressors inlet valve (10), Energy Alternative Refrigerant Compressors outlet valve (12) is released, energy circuit outlet valve (18) is released and releases energy circuit entrance valve (19) and is closed, by thermal-arrest The heat-transfer working medium of device (2) heating enters heat exchanger (4) hot side, after the generating working medium heat exchange of electricity generation system (21), heat-transfer working medium Into heat-exchanging loop compressor (5), enter heat collector (2) after being overpressurized, completes circulation.Generating working medium is in heat exchanger (4) After the heat absorption of cold side, into electricity generation system (21), the cold side that heat exchanger (4) is returned to after acting continues to absorb heat, and completes circulation, a part Heat-transfer working medium enters the shell side of methane reforming endothermic reaction device (7), methane and carbon dioxide storage by tank circuit inlet valve (6) Methane and carbon dioxide in tank (14) enters methane reforming endothermic reaction device (7) after energy storage Alternative Refrigerant Compressors (16) pressurization Tube side, the heat that reforming reaction absorbs heat-transfer working medium occurs in tube side, generates carbon monoxide and hydrogen methane and carbon dioxide Gas, into carbon monoxide and hydrogen-holder (9), the heat-transfer working medium after heat exchange enters by tank circuit outlet valve (8) to exchange heat back Road compressor (5) returns to heat collector after being overpressurized and continues to absorb heat;When there is no solar radiation, heat-exchanging loop valve (3), storage Energy circuit entrance valve (6), tank circuit outlet valve (8), energy storage Alternative Refrigerant Compressors inlet valve (15) and energy storage Alternative Refrigerant Compressors go out Mouth valve (17) is closed, and is released energy Alternative Refrigerant Compressors inlet valve (10), is released energy Alternative Refrigerant Compressors outlet valve (12), releases energy circuit outlet valve (18) and release can circuit entrance valve (19) open, carbon monoxide and carbon monoxide in hydrogen-holder (9) and hydrogen are by releasing energy Enter the tube side of methane synthesis exothermic reactor (13) after Alternative Refrigerant Compressors (11) pressurization, carbon monoxide and hydrogen reaction generate first Alkane and carbon dioxide, release heat, after the heat-transfer working medium heat exchange of shell side, into methane and carbon dioxide storage tank (14), shell The heat-transfer working medium of journey enters the hot side entrance of heat exchanger (4) after heating by releasing energy circuit outlet valve, with electricity generation system (21) after generating working medium heat exchange, heat-transfer working medium, which enters, releases energy circuit compressor (20), and methane synthesis is entered after being overpressurized and is put Thermal reactor (13) continues to absorb heat, and completes circulation, generating working medium is after the heat absorption of the cold side of heat exchanger (4), into electricity generation system (21), the cold side that heat exchanger (4) is returned to after acting continues to absorb heat, and completes circulation.
CN201910292154.5A 2019-04-12 2019-04-12 A kind of solar light-heat power-generation system and method based on methane reforming energy storage Pending CN109944756A (en)

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