CN109942866A - A kind of preparation method of new energy materials - Google Patents
A kind of preparation method of new energy materials Download PDFInfo
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- CN109942866A CN109942866A CN201910285307.3A CN201910285307A CN109942866A CN 109942866 A CN109942866 A CN 109942866A CN 201910285307 A CN201910285307 A CN 201910285307A CN 109942866 A CN109942866 A CN 109942866A
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Abstract
The invention discloses a kind of preparation method of new energy materials, new energy materials include ZrO2Abrading-ball, hydrazine hydrate solution, argon gas, sodium hydroxide solution, changes silica at graphene oxide, the corrosion resistance and coefficient of friction of polyvinyl alcohol film are improved using loose silica membrane, whole service life is long, it is whole simultaneously to have certain air permeability effect, so that whole cooling effect is outstanding.
Description
Technical field
The present invention relates to field of new materials, more particularly, to a kind of preparation method of new energy materials.
Background technique
It is well known that three-dimensional globular grapheme material have chondritic, graphene film interlayer unlike graphite-structure that
It is closely arranged together between every layer of sample by Van der Waals force, but the distance between each graphene sheet layer has been above model
The sphere of action of De Huali, arrangement relative loose between layers can effectively overcome graphene stacking and agglomeration traits.Cause
Graphene, is made into one of the optimal path that three-dimensional globular structure has become raising hydrogen storage property by this.
The base of graphene film common at present is excessively fine and close, and overall air permeability is poor, it is difficult to realize preferable heat dissipation.
Summary of the invention
The present invention is to overcome above situation insufficient, it is desirable to provide a kind of technical solution that can solve the above problem.
A kind of new energy materials include following components, ZrO by weight210-20 parts of abrading-ball, graphene oxide 2-4
Part, changes 35-48 parts of silica, polyvinyl alcohol 48- at 2-12 parts of hydrazine hydrate solution, 1-3 parts of argon gas, 2-6 parts of sodium hydroxide solution
50 parts, 4-6 parts of nano-silver thread, 1-3 parts of silane coupling agent, 2.5-3 parts of methyl-silicone oil, 5-8 parts of glycerol.
As a further solution of the present invention: a kind of new energy materials include following components, ZrO by weight2Abrading-ball
10 parts, 2 parts of graphene oxide, 2 parts of hydrazine hydrate solution, 1 part of argon gas, 2 parts of sodium hydroxide solution, change 35 parts of silica, poly- second
48 parts of enol, 4 parts of nano-silver thread, 1 part of silane coupling agent, 2.5 parts of methyl-silicone oil, 5 parts of glycerol.
As a further solution of the present invention: a kind of new energy materials include following components, ZrO by weight2Abrading-ball
20 parts, 4 parts of graphene oxide, 12 parts of hydrazine hydrate solution, 3 parts of argon gas, 6 parts of sodium hydroxide solution, change 48 parts of silica, poly- second
50 parts of enol, 6 parts of nano-silver thread, 3 parts of silane coupling agent, 3 parts of methyl-silicone oil, 8 parts of glycerol.
As a further solution of the present invention: a kind of new energy materials include following components, ZrO by weight2Abrading-ball
15 parts, 3 parts of graphene oxide, 8 parts of hydrazine hydrate solution, 2 parts of argon gas, 4 parts of sodium hydroxide solution, change 40 parts of silica, poly- second
49 parts of enol, 5 parts of nano-silver thread, 2 parts of silane coupling agent, 2.6 parts of methyl-silicone oil, 7 parts of glycerol.
A kind of preparation method of new energy materials, specifically includes the following steps:
S1, nano-silver thread and silane coupling agent are weighed according to the above ratio, be put into ultrasonic disperse in the Ultrasound Instrument sink of 35KHz
30min is uniformly mixed, for use；
S2, be proportionally added into and change silica, polyvinyl alcohol, methyl-silicone oil, glycerol, be mixed and heated to 60 °C of stirrings be made it is water-soluble
Glue；
S3, mixed-powder is added in the hydrosol, is mixed evenly, then the hydrosol for being mixed with powder is put into vacuum drying
100 °C of bubbles sloughed in solution in case later on cast coat to flat and smooth stainless steel band, are put into drying box 55 °C
PVA film is made to constant weight in heating, drying；
S4, one layer of loose silica membrane is deposited on the surface of PVA film；
S5, graphene oxide is taken to prepare a certain amount of graphene oxide suspension；
S6, by ZrO2Abrading-ball and graphene oxide suspension are put into ball grinder ball milling and process, and are passed through argon gas, at this time everywhere
Graphene oxide suspension after reason；
S7, by treated, graphene oxide suspension addition sodium hydroxide solution adjustment PH to 13 obtains mixed liquor;
S8, by mixed liquor be put into water heating kettle heat preservation 10h obtain conductive graphene material；
S9, conductive graphene material is uniformly coated on silica membrane；
S10, it takes out after film places natural drying 10h at room temperature and is removed from stainless steel band, to obtain with loose
Silica membrane is the conductive graphene membrane of matrix.
Beneficial effects of the present invention: using loose silica membrane improve the corrosion resistance of polyvinyl alcohol film with
And coefficient of friction, whole service life is long, while entirety has certain air permeability effect, so that whole cooling effect is more
Add outstanding.
Additional aspect and advantage of the invention will be set forth in part in the description, and will partially become from the following description
Obviously, or practice through the invention is recognized.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all
Belong to the scope of protection of the invention.
In the embodiment of the present invention 1, a kind of new energy materials include following components, ZrO by weight2Abrading-ball 10-20
Part, 2-6 parts of sodium hydroxide solution, changes silica 35- at 2-4 parts of graphene oxide, 2-12 parts of hydrazine hydrate solution, 1-3 parts of argon gas
48 parts, 48-50 parts of polyvinyl alcohol, 4-6 parts of nano-silver thread, 1-3 parts of silane coupling agent, 2.5-3 parts of methyl-silicone oil, 5-8 parts of glycerol.
A kind of preparation method of new energy materials, specifically includes the following steps:
S1, nano-silver thread and silane coupling agent are weighed according to the above ratio, be put into ultrasonic disperse in the Ultrasound Instrument sink of 35KHz
30min is uniformly mixed, for use；
S2, be proportionally added into and change silica, polyvinyl alcohol, methyl-silicone oil, glycerol, be mixed and heated to 60 °C of stirrings be made it is water-soluble
Glue；
S3, mixed-powder is added in the hydrosol, is mixed evenly, then the hydrosol for being mixed with powder is put into vacuum drying
100 °C of bubbles sloughed in solution in case later on cast coat to flat and smooth stainless steel band, are put into drying box 55 °C
PVA film is made to constant weight in heating, drying；
S4, one layer of loose silica membrane is deposited on the surface of PVA film；
S5, graphene oxide is taken to prepare a certain amount of graphene oxide suspension；
S6, by ZrO2Abrading-ball and graphene oxide suspension are put into ball grinder ball milling and process, and are passed through argon gas, at this time everywhere
Graphene oxide suspension after reason；
S7, by treated, graphene oxide suspension addition sodium hydroxide solution adjustment PH to 13 obtains mixed liquor;
S8, by mixed liquor be put into water heating kettle heat preservation 10h obtain conductive graphene material；
S9, conductive graphene material is uniformly coated on silica membrane；
S10, it takes out after film places natural drying 10h at room temperature and is removed from stainless steel band, to obtain with loose
Silica membrane is the conductive graphene membrane of matrix.
In the embodiment of the present invention 2, a kind of new energy materials include following components, ZrO by weight210 parts of abrading-ball, oxygen
2 parts of graphite alkene, 1 part of argon gas, 2 parts of sodium hydroxide solution, changes 35 parts of silica, polyvinyl alcohol 48 at 2 parts of hydrazine hydrate solution
Part, 4 parts of nano-silver thread, 1 part of silane coupling agent, 2.5 parts of methyl-silicone oil, 5 parts of glycerol.
A kind of preparation method of new energy materials, specifically includes the following steps:
S1, nano-silver thread and silane coupling agent are weighed according to the above ratio, be put into ultrasonic disperse in the Ultrasound Instrument sink of 35KHz
30min is uniformly mixed, for use；
S2, be proportionally added into and change silica, polyvinyl alcohol, methyl-silicone oil, glycerol, be mixed and heated to 60 °C of stirrings be made it is water-soluble
Glue；
S3, mixed-powder is added in the hydrosol, is mixed evenly, then the hydrosol for being mixed with powder is put into vacuum drying
100 °C of bubbles sloughed in solution in case later on cast coat to flat and smooth stainless steel band, are put into drying box 55 °C
PVA film is made to constant weight in heating, drying；
S4, one layer of loose silica membrane is deposited on the surface of PVA film；
S5, graphene oxide is taken to prepare a certain amount of graphene oxide suspension；
S6, by ZrO2Abrading-ball and graphene oxide suspension are put into ball grinder ball milling and process, and are passed through argon gas, at this time everywhere
Graphene oxide suspension after reason；
S7, by treated, graphene oxide suspension addition sodium hydroxide solution adjustment PH to 13 obtains mixed liquor;
S8, by mixed liquor be put into water heating kettle heat preservation 10h obtain conductive graphene material；
S9, conductive graphene material is uniformly coated on silica membrane；
S10, it takes out after film places natural drying 10h at room temperature and is removed from stainless steel band, to obtain with loose
Silica membrane is the conductive graphene membrane of matrix.
In the embodiment of the present invention 3, a kind of new energy materials include following components, ZrO by weight220 parts of abrading-ball, oxygen
4 parts of graphite alkene, 3 parts of argon gas, 6 parts of sodium hydroxide solution, changes 48 parts of silica, polyvinyl alcohol 50 at 12 parts of hydrazine hydrate solution
Part, 6 parts of nano-silver thread, 3 parts of silane coupling agent, 3 parts of methyl-silicone oil, 8 parts of glycerol.
A kind of preparation method of new energy materials, specifically includes the following steps:
S1, nano-silver thread and silane coupling agent are weighed according to the above ratio, be put into ultrasonic disperse in the Ultrasound Instrument sink of 35KHz
30min is uniformly mixed, for use；
S2, be proportionally added into and change silica, polyvinyl alcohol, methyl-silicone oil, glycerol, be mixed and heated to 60 °C of stirrings be made it is water-soluble
Glue；
S3, mixed-powder is added in the hydrosol, is mixed evenly, then the hydrosol for being mixed with powder is put into vacuum drying
100 °C of bubbles sloughed in solution in case later on cast coat to flat and smooth stainless steel band, are put into drying box 55 °C
PVA film is made to constant weight in heating, drying；
S4, one layer of loose silica membrane is deposited on the surface of PVA film；
S5, graphene oxide is taken to prepare a certain amount of graphene oxide suspension；
S6, by ZrO2Abrading-ball and graphene oxide suspension are put into ball grinder ball milling and process, and are passed through argon gas, at this time everywhere
Graphene oxide suspension after reason；
S7, by treated, graphene oxide suspension addition sodium hydroxide solution adjustment PH to 13 obtains mixed liquor;
S8, by mixed liquor be put into water heating kettle heat preservation 10h obtain conductive graphene material；
S9, conductive graphene material is uniformly coated on silica membrane；
S10, it takes out after film places natural drying 10h at room temperature and is removed from stainless steel band, to obtain with loose
Silica membrane is the conductive graphene membrane of matrix.
In the embodiment of the present invention 4, a kind of new energy materials include following components, ZrO by weight215 parts of abrading-ball, oxygen
3 parts of graphite alkene, 2 parts of argon gas, 4 parts of sodium hydroxide solution, changes 40 parts of silica, polyvinyl alcohol 49 at 8 parts of hydrazine hydrate solution
Part, 5 parts of nano-silver thread, 2 parts of silane coupling agent, 2.6 parts of methyl-silicone oil, 7 parts of glycerol.
A kind of preparation method of new energy materials, specifically includes the following steps:
S1, nano-silver thread and silane coupling agent are weighed according to the above ratio, be put into ultrasonic disperse in the Ultrasound Instrument sink of 35KHz
30min is uniformly mixed, for use；
S2, be proportionally added into and change silica, polyvinyl alcohol, methyl-silicone oil, glycerol, be mixed and heated to 60 °C of stirrings be made it is water-soluble
Glue；
S3, mixed-powder is added in the hydrosol, is mixed evenly, then the hydrosol for being mixed with powder is put into vacuum drying
100 °C of bubbles sloughed in solution in case later on cast coat to flat and smooth stainless steel band, are put into drying box 55 °C
PVA film is made to constant weight in heating, drying；
S4, one layer of loose silica membrane is deposited on the surface of PVA film；
S5, graphene oxide is taken to prepare a certain amount of graphene oxide suspension；
S6, by ZrO2Abrading-ball and graphene oxide suspension are put into ball grinder ball milling and process, and are passed through argon gas, at this time everywhere
Graphene oxide suspension after reason；
S7, by treated, graphene oxide suspension addition sodium hydroxide solution adjustment PH to 13 obtains mixed liquor;
S8, by mixed liquor be put into water heating kettle heat preservation 10h obtain conductive graphene material；
S9, conductive graphene material is uniformly coated on silica membrane；
S10, it takes out after film places natural drying 10h at room temperature and is removed from stainless steel band, to obtain with loose
Silica membrane is the conductive graphene membrane of matrix.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims
Variation is included within the present invention.
Claims (5)
1. a kind of new energy materials, which is characterized in that by weight include following components, ZrO210-20 parts of abrading-ball, oxidation stone
Black alkene 2-4 parts, 2-12 parts of hydrazine hydrate solution, 1-3 parts of argon gas, 2-6 parts of sodium hydroxide solution, change 35-48 parts of silica, poly- second
48-50 parts of enol, 4-6 parts of nano-silver thread, 1-3 parts of silane coupling agent, 2.5-3 parts of methyl-silicone oil, 5-8 parts of glycerol.
2. new energy materials according to claim 1, which is characterized in that by weight include following components, ZrO2Abrading-ball
10 parts, 2 parts of graphene oxide, 2 parts of hydrazine hydrate solution, 1 part of argon gas, 2 parts of sodium hydroxide solution, change 35 parts of silica, poly- second
48 parts of enol, 4 parts of nano-silver thread, 1 part of silane coupling agent, 2.5 parts of methyl-silicone oil, 5 parts of glycerol.
3. new energy materials according to claim 1, which is characterized in that by weight include following components, ZrO2Abrading-ball
20 parts, 4 parts of graphene oxide, 12 parts of hydrazine hydrate solution, 3 parts of argon gas, 6 parts of sodium hydroxide solution, change 48 parts of silica, poly- second
50 parts of enol, 6 parts of nano-silver thread, 3 parts of silane coupling agent, 3 parts of methyl-silicone oil, 8 parts of glycerol.
4. new energy materials according to claim 1, which is characterized in that by weight include following components, ZrO2Abrading-ball
15 parts, 3 parts of graphene oxide, 8 parts of hydrazine hydrate solution, 2 parts of argon gas, 4 parts of sodium hydroxide solution, change 40 parts of silica, poly- second
49 parts of enol, 5 parts of nano-silver thread, 2 parts of silane coupling agent, 2.6 parts of methyl-silicone oil, 7 parts of glycerol.
5. the preparation method of new energy materials according to claim 1, which is characterized in that itself specifically includes the following steps:
S1, nano-silver thread and silane coupling agent are weighed according to the above ratio, be put into ultrasonic disperse in the Ultrasound Instrument sink of 35KHz
30min is uniformly mixed, for use；
S2, be proportionally added into and change silica, polyvinyl alcohol, methyl-silicone oil, glycerol, be mixed and heated to 60 °C of stirrings be made it is water-soluble
Glue；
S3, mixed-powder is added in the hydrosol, is mixed evenly, then the hydrosol for being mixed with powder is put into vacuum drying
100 °C of bubbles sloughed in solution in case later on cast coat to flat and smooth stainless steel band, are put into drying box 55 °C
PVA film is made to constant weight in heating, drying；
S4, one layer of loose silica membrane is deposited on the surface of PVA film；
S5, graphene oxide is taken to prepare a certain amount of graphene oxide suspension；
S6, by ZrO2Abrading-ball and graphene oxide suspension are put into ball grinder ball milling and process, and are passed through argon gas, at this time everywhere
Graphene oxide suspension after reason；
S7, by treated, graphene oxide suspension addition sodium hydroxide solution adjustment PH to 13 obtains mixed liquor;
S8, by mixed liquor be put into water heating kettle heat preservation 10h obtain conductive graphene material；
S9, conductive graphene material is uniformly coated on silica membrane；
S10, it takes out after film places natural drying 10h at room temperature and is removed from stainless steel band, to obtain with loose
Silica membrane is the conductive graphene membrane of matrix.
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|---|---|---|---|
| CN201910285307.3A CN109942866A (en) | 2019-04-10 | 2019-04-10 | A kind of preparation method of new energy materials |
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| CN201910285307.3A CN109942866A (en) | 2019-04-10 | 2019-04-10 | A kind of preparation method of new energy materials |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1418196A1 (en) * | 2002-11-11 | 2004-05-12 | The Nippon Synthetic Chemical Industry Co., Ltd. | Water-soluble film |
| CN102750998A (en) * | 2012-07-09 | 2012-10-24 | 深圳市贝特瑞纳米科技有限公司 | Transparent graphene conductive thin film and preparation method thereof |
| CN108424600A (en) * | 2018-04-17 | 2018-08-21 | 河南工程学院 | A kind of polyvinyl alcohol film and preparation method thereof with open structure |
-
2019
- 2019-04-10 CN CN201910285307.3A patent/CN109942866A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1418196A1 (en) * | 2002-11-11 | 2004-05-12 | The Nippon Synthetic Chemical Industry Co., Ltd. | Water-soluble film |
| CN102750998A (en) * | 2012-07-09 | 2012-10-24 | 深圳市贝特瑞纳米科技有限公司 | Transparent graphene conductive thin film and preparation method thereof |
| CN108424600A (en) * | 2018-04-17 | 2018-08-21 | 河南工程学院 | A kind of polyvinyl alcohol film and preparation method thereof with open structure |
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Application publication date: 20190628 |
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