CN109940986A - A kind of controllable transports liquid is ink jet type printing equipment and the printing process of patterned surface - Google Patents
A kind of controllable transports liquid is ink jet type printing equipment and the printing process of patterned surface Download PDFInfo
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- CN109940986A CN109940986A CN201711382416.4A CN201711382416A CN109940986A CN 109940986 A CN109940986 A CN 109940986A CN 201711382416 A CN201711382416 A CN 201711382416A CN 109940986 A CN109940986 A CN 109940986A
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- 238000007639 printing Methods 0.000 title claims abstract description 52
- 238000000034 method Methods 0.000 title claims description 23
- 239000007788 liquid Substances 0.000 title claims description 8
- 230000032258 transport Effects 0.000 title claims description 8
- 230000008569 process Effects 0.000 title claims description 7
- 239000000835 fiber Substances 0.000 claims abstract description 78
- 239000000463 material Substances 0.000 claims abstract description 15
- 239000002086 nanomaterial Substances 0.000 claims abstract description 5
- 239000002657 fibrous material Substances 0.000 claims abstract 3
- 239000000758 substrate Substances 0.000 claims description 21
- 229920000914 Metallic fiber Polymers 0.000 claims description 7
- 241001465754 Metazoa Species 0.000 claims description 6
- 230000008859 change Effects 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 4
- 229920005594 polymer fiber Polymers 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 240000007594 Oryza sativa Species 0.000 claims description 2
- 235000007164 Oryza sativa Nutrition 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000005357 flat glass Substances 0.000 claims description 2
- 150000004676 glycans Chemical group 0.000 claims description 2
- 229920001282 polysaccharide Polymers 0.000 claims description 2
- 239000005017 polysaccharide Substances 0.000 claims description 2
- 108090000623 proteins and genes Chemical group 0.000 claims description 2
- 102000004169 proteins and genes Human genes 0.000 claims description 2
- 235000009566 rice Nutrition 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 238000005516 engineering process Methods 0.000 abstract description 16
- 238000007641 inkjet printing Methods 0.000 abstract description 7
- 239000000243 solution Substances 0.000 description 16
- 238000004590 computer program Methods 0.000 description 15
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 12
- 238000000059 patterning Methods 0.000 description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 238000003491 array Methods 0.000 description 5
- 238000002604 ultrasonography Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 239000002096 quantum dot Substances 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical group ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- 239000003365 glass fiber Substances 0.000 description 3
- 229920002521 macromolecule Polymers 0.000 description 3
- 239000002105 nanoparticle Substances 0.000 description 3
- -1 polyethylene Polymers 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- 229910001069 Ti alloy Inorganic materials 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000002322 conducting polymer Substances 0.000 description 2
- 229920001940 conductive polymer Polymers 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000002070 nanowire Substances 0.000 description 2
- 238000001259 photo etching Methods 0.000 description 2
- 239000004038 photonic crystal Substances 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 241000283973 Oryctolagus cuniculus Species 0.000 description 1
- 229920000144 PEDOT:PSS Polymers 0.000 description 1
- 229920001609 Poly(3,4-ethylenedioxythiophene) Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000002042 Silver nanowire Substances 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000013500 data storage Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910021389 graphene Inorganic materials 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 238000004377 microelectronic Methods 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000012149 noodles Nutrition 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000013307 optical fiber Substances 0.000 description 1
- 230000005693 optoelectronics Effects 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
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- 238000011160 research Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C9/00—Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important
- B05C9/08—Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important for applying liquid or other fluent material and performing an auxiliary operation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/135—Nozzles
- B41J2/14—Structure thereof only for on-demand ink jet heads
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/135—Nozzles
- B41J2/145—Arrangement thereof
- B41J2/15—Arrangement thereof for serial printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81C—PROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
- B81C99/00—Subject matter not provided for in other groups of this subclass
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
Landscapes
- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Manufacturing Of Printed Wiring (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The present invention relates to technical field of function materials.Ink jet type printing equipment of the invention, including the ink storage box circuit board (1) of ink hole group is discharged containing m and is fixed on the corresponding m spread pen frame (2) of ink storage box circuit board lower part;Every discharge ink hole group contains n ink hole (5), it is corresponding, every spread pen frame contains n group fixation hole (3), several surfaces are inserted and fixed in each fixation hole has the cone cell fiber (hair needle) (4) of micro nano structure to form one group of cone cell fiber array unit (pen hair), corresponding one group of pen hair, the upright projection of the ink hole correspond to the top position of pen hair under each ink hole;The tip of the pen hair is in 12~18 ° of angles with level downward.Cone cell fibrous material of the present invention is cheap and easy to get, and inkjet printing technology can micro-structure can uniformly be transmitted in exact position, cone cell fiber with ink controllable continuous by ink printed, solves the problems, such as many technologies into film uniformity.
Description
Technical field
The present invention relates to technical field of function materials, and in particular, to a kind of controllable transports liquid is patterned surface
Ink jet type printing equipment and printing process.
Background technique
Pattern of functional material is the necessary means for realizing electronic device and integrated processing, show in optics, electronics it is electric
Road, semiconductor devices and solar battery etc. are widely used, such as patterned photonic crystal is used for sensitivity technique
The patterning in field, conducting polymer is prepared into for the preparation of opto-electronic device, especially flexible electronic device, by quantum dot
Ink is printed, and the luminous pattern of different shape, different colours can be obtained.In view of pattern of functional material in Information of Development
The importance in the fields such as technology, medical technology, energy technology has become a hot issue of each research field.However,
Various problems present in patterning processing technology at this stage annoying always researcher.
Photoetching technique is a kind of method being widely used in semi-conductor industry, can form uniform, accurate, high score
The wiring of resolution, but this replication mode for making photoetching technique be still limited to template and product 1:1 will cause the waste of resource
With the reduction of efficiency.Silk screen print method is a kind of technology for being widely used in quick, cheap extensive deposition dye film, and
The basal region for being easy to be deposited defines pattern, and still, the patterning precision of silk screen print method is lower, generally can only achieve several
The level of micron to tens microns, and silk screen print method requires higher viscosity and lower volatilization to required solution
Property, it is higher to be formed by patterned film roughness.Can be used the method for directly printing material film realize its patterning to
Protect its performance, but the technology the patterns of high precisionization processing for realizing large area it is upper there is also the uniformity of pattern, add
The continuity of work, the dimensional discrepancy of different materials multilayer processing as caused by thermal expansion coefficient difference and alignment precision etc. are asked
Topic.Patterning inkjet printing technology is a kind of quick technology of preparing of patterning.It is fast with print speed, non-contact, positioning accurate
The advantages that exactness is high receives significant attention in field of photoelectric devices in recent years.However inkjet printing is formed by patterned film
Uniformity and film thickness be problematic in that.It can be seen that patterning techniques are still faced with great challenge.
Summary of the invention
To solve the above problems, the present invention provides the ink jet types that a kind of controllable transports liquid is patterned surface to print dress
It sets and printing process.
Controllable transports liquid of the invention is the ink jet type printing equipment of patterned surface, wherein including containing m discharge ink
The ink storage box circuit board 1 of hole group and the corresponding m spread pen frame 2 for being fixed on ink storage box circuit board lower part;Every discharge ink hole group contains
There is n ink hole 5, corresponding, every spread pen frame contains n group fixation hole 3, and several cone cell fibers are inserted and fixed in each fixation hole
4 (hair needles) form one group of cone cell fiber array unit (pen hair), corresponding one group of cone cell fiber array unit under each ink hole;Institute
The upright projection for stating ink hole corresponds to the top position of cone cell fiber array unit;The tip court of the cone cell fiber array unit
Under, it is in 12~18 ° of angles with level.
Ink jet type printing equipment according to the present invention, wherein preferably, being inserted and fixed 1 in each fixation hole
~4 cone cell fibers (hair needle) form one group of cone cell fiber array unit (pen hair).It is further preferred that each fixation hole
It is inside inserted and fixed 2 cone cell fibers and forms one group of cone cell fiber array unit.Further, when cone cell fiber array unit is
When a piece cone cell fiber, the upright projection center of the ink hole corresponds to the top position of cone cell fiber;When cone cell fiber array
When unit is two cone cell fibers or more, the upright projection of each cone cell fibers parallel Cheng Yilie, the ink hole are corresponding
The top position of cone cell fiber, also, correspond to the upright projection center of ink hole in cone cell fiber array unit
The heart (center i.e. between two hair needles of outermost), to guarantee that inkjet materials may be uniformly distributed in cone cell fiber array list
On each cone cell fiber in member.
Ink jet type printing equipment according to the present invention, wherein the cone cell fiber is polymer fiber, inorganic non-gold
Belong to fiber, metallic fiber or animal hair.The cone cell fiber shape is as shown in Figure 5.
When the cone cell fiber is animal hair, writing brush hair, stone blaireau or rabbit hair etc. can be.The animal hair is long
Degree is 1~5 centimetre, and the main body of hair is the coniform material with polysaccharide and protein structure;The diameter of the cone cell material from 0~
150 microns of variations, form the pyramidal structure of a gradual change;The pyramidal structure surface covers one layer of 50~300 nanometers of height
" flakey " oriented structure, or the nanostructure of same scale.
When the cone cell fiber is polymer fiber, when inorganic non-metallic fiber or metallic fiber, polyethylene fiber can be
Dimension, vinal, glass fibre, copper wire, filamentary silver, carbon fiber etc..The diameter of material changes from 0~500 micron, according to need
The length that material is cut into needs is generally 1~5 centimetre, then fiber is fixed on three-dimensional platform and carries out chemical attack, it is rotten
The cone structure of gradual change is lost into, which has certain coarse structure.
Ink jet type printing equipment according to the present invention, wherein the cone cell fiber array unit root is towards ink storage
The advance moving direction of box circuit board.
Ink jet type printing equipment according to the present invention, wherein preferably, the penholder and odd number of the even rows
The penholder of the row one group of cone cell fiber array unit that is staggered is staggered.
Penholder of the present invention can be any materials known in this field that can be used, for example, titanium alloy etc..This hair
Any known mode that penholder in bright can be is fixed below ink storage box circuit board, such as makes pen by screw thread or bonding way
Frame fixed part is fixed on ink storage box two sides.
The present invention also provides the printing process based on above-mentioned ink jet type printing equipment, this method specifically includes the following steps:
1) functional molecular solution is packed into ink storage box, solution droplets are dropped in cone cell through the ink hole on ink storage box circuit board
On fiber array unit, printing equipment is made;
2) printing equipment for obtaining step 1) is connected to three-dimensional mobile station, is placed in ink storage box circuit board level in substrate
Side, moving down makes cone cell fiber array unit tip contacts substrate, then pushes 0~3mm, mobile with the speed of 0~5000 μm/s,
Patterned surface is made.
Printing process according to the present invention, wherein the substrate is sheet glass, silicon wafer, polymeric substrates (PET etc.
Polymer) or paper etc..
Functional liquid mentioned by the present invention (ink) includes Polymer Solution, small molecule solution, inorganic nano-particle
Solution, quantum dot solution, nanowire solution (receive by silver nanowires, alumina nanowires, zinc oxide nanowire, microbial solution, copper
Rice noodles etc.) etc..
Ink jet type printing equipment of the invention can be used for the patterning of photonic crystal, be applied to intelligent display, optical waveguide,
The fields such as optical fiber, reflecting mirror, super prism, photocatalysis solar battery and sensing detection;For the patterning of conducting polymer, extensively
It is general to be applied to the fields such as photoelectric device, especially flexible photoelectric device;Inorganic nano-particle ink, quantum dot ink, carbon are received
The patterning of mitron ink, graphene ink and black ink can be applied to green plate-making, optics shows, electronic circuit, partly leads
Body device and solar battery etc.;For the patterning of metallic ink, can be used for no template large area prepare electronic circuit,
The microelectronic components such as data storage.
Present invention combination inkjet printing technology and writing brush directly print method, and inkjet printing technology can be accurate by ink
It is sprayed on writing brush and plays the role of accurate continuous ink feeding, by writing brush further by ink pattern, the distinctive surface of writing brush has
The cone cell fibre structure of micro nano structure may be implemented controllably uniformly by ink transport in substrate, and this method combines two kinds
The advantage of technology also solves the problems such as uniformity and thickness of film in inkjet printing technology simultaneously.
Mostly there is the problems such as technical costs, precision, film forming in patterning techniques, the prior art cannot all solve simultaneously
These problems, this method proposed by the present invention solve these urgent problems to be solved simultaneously, and used cone cell is fine
It is cheap and easy to get to tie up material, inkjet printing technology can micro-structure can with ink in exact position, cone cell fiber by ink printed
Control continuous uniform transmit, and solves the problems, such as many technologies into film uniformity.
Detailed description of the invention
Fig. 1 is ink jet type printing equipment main view of the invention (by taking two hair needles as an example, box containing ink storage);
Fig. 2 is ink jet type printing equipment side view of the invention (by taking two hair needles as an example, box containing ink storage);
Fig. 3 is the penholder main view of ink jet type printing equipment of the invention;
Fig. 4 is the penholder side view of ink jet type printing equipment of the invention;
Fig. 5 is the polymer hair needle schematic diagram of ink jet type printing equipment of the invention;
Fig. 6 is the printing schematic diagram of ink jet type printing equipment of the invention.
Appended drawing reference
1, ink storage box circuit board 2, penholder 3, fixation hole 4, cone cell fiber
5, ink hole 6, ink storage box
Specific embodiment
Technical solution of the present invention is further described below with reference to embodiment.
As shown in Figs. 1-2, control transports liquid of the invention is the ink jet type printing equipment of patterned surface, wherein packet
The corresponding m spread pen frame 2 for including the ink storage box circuit board 1 containing m discharge ink hole group and being fixed on ink storage box circuit board lower part;Often
Discharge ink hole group contains n ink hole 5, and accordingly, every spread pen frame contains n group fixation hole 3, is inserted and fixed in each fixation hole
Several cone cell fibers 4 (hair needle) form one group of cone cell fiber array unit (pen hair), and corresponding one group of cone cell is fine under each ink hole
Tie up array element;The upright projection of the ink hole corresponds to the top position of cone cell fiber array unit;The cone cell fiber array
The tip of column unit is in 12~18 ° of angles with level downward.
Advance moving direction of the pen hair root towards ink storage box circuit board.Wherein preferably, the even rows
Penholder and penholder one group of pen hair that is staggered of odd row be staggered.
The penholder structure is as shown in Figure 3-4, it is preferable to use titanium alloy penholder, consolidates penholder by screw thread or bonding way
Determine the two sides that ink storage box 6 is fixed in portion.
As shown in fig. 6, using the application ink jet type printing equipment impressing pattern film when, firstly, by functional molecular
Solution is packed into ink storage box, and solution droplets are dropped in pen hair through the ink hole on ink storage box circuit board, and printing equipment is made;So
Afterwards, printing equipment step 1) obtained is connected to three-dimensional mobile station, is placed in ink storage box circuit board level above substrate, moves down
So that pen hair head is contacted substrate, then pushes, it is mobile with the speed of 0~5000 μm/s, patterned surface is made.
Embodiment 1
(1) the cone cell fiber of the anisotropic microstructure of 1cm length is taken, respectively using 5 points of acetone, alcohol and water ultrasound
Clock cleans up, and room temperature dries;Cone cell fiber selects the new piliation of animal (writing brush fiber) for having " flakey " body structure surface;
(2) the ink storage box selected by has several different ink storage areas, and each ink storage area corresponds to respectively several different to be gone out
Ink hole, pitch of holes out of ink different pattern requirement can be adjusted between 0~1cm as needed.
(3) the writing brush fiber for obtaining step (1) chooses 2 close-packed arrays and forms pen hair, and cone cell fiber butt end is glued
It is connected to the lower section (as shown in Figure 2) of ink storage box ink hole, and with ink storage box ink hole plane at certain tilt angle (preferably 15
Degree) prepare printing equipment.Make the corresponding one group of pen hair of an ink storage box ink hole, ink storage box can be controlled its spray by computer program
Ink, and ink can be replaced at any time as needed, it is sealed after replacement;
(4) it is added in the PEDOT:PSS aqueous solution (PSS for wherein containing 0.8% PEDOT and 0.5%) for being 5% by content
5% dimethyl sulfoxide injects ink storage box to enhance its conductive capability, then by this mixed fluent material;
(5) printing equipment that step (3) obtains is linked to three-dimensional mobile station, with plane at 15 ° of angles close to substrate,
0~3mm is pushed after contacting substrate, in the pattern input computer program that will be brushed, under the manipulation of computer program, with 100 μm/s
Speed fast move, just be made patterned film.
Embodiment 2
(1) the cone cell fiber of the anisotropic microstructure of 3cm length is taken, respectively using 5 points of acetone, alcohol and water ultrasound
Clock cleans up, and room temperature dries;Cone cell fiber selects the macromolecule cone cell fiber (polyethylene fibre hair needle) for having micro-structure;
(2) the ink storage box selected by has several different ink storage areas, and each ink storage area corresponds to respectively several different to be gone out
Ink hole, pitch of holes out of ink different pattern requirement can be adjusted between 0~1cm as needed;
(3) the cone cell polyethylene fibre for obtaining step (1) chooses 2~4 close-packed arrays, and cone cell fiber butt end is glued
It is connected to the lower section of ink storage box ink hole, and is prepared with ink storage box ink hole plane at certain tilt angle (preferably 12 degree)
Printing equipment.Make the corresponding one group of hair needle of an ink hole, ink storage box can be controlled its ink-jet by computer program, and can be as needed
Ink is replaced at any time, is sealed after replacement;
(4) three kinds of quantum dot solutions of red, green, blue that the concentration prepared is 2mg/mL the different of ink storage box are respectively charged into store up
Ink-covered area.
(5) printing equipment that step (3) obtains is linked to three-dimensional mobile station, with plane at 12 ° of angles close to substrate,
0~2mm is pushed after contacting substrate, in the pattern input computer program that will be brushed, under the manipulation of computer program, with 300 μm/s
Speed fast move, just be made patterned film;
Embodiment 3
(1) the cone cell fiber of the anisotropic microstructure of 2cm length is taken, respectively using 5 points of acetone, alcohol and water ultrasound
Clock cleans up, and room temperature dries;Cone cell fiber selects the macromolecule cone cell fiber (glass fibre hair needle) for having micro-structure;
(2) the ink storage box selected by has several different ink storage areas, and each ink storage area corresponds to respectively several different to be gone out
Ink hole, pitch of holes out of ink different pattern requirement can be adjusted between 0~1cm as needed;
(3) the cone cell glass fibre for obtaining step (1) chooses 2~4 close-packed arrays, and fiber butt end is adhered to storage
The lower section of print cartridge ink hole, and printer is prepared at certain tilt angle (preferably 18 degree) with ink storage box ink hole plane
Tool.Make the corresponding one group of hair needle of ink hole, ink storage box can be controlled its ink-jet by computer program, and can as needed at any time more
Ink is changed, is sealed after replacement;
(4) polymethyl methacrylate (PMMA) solution (solvent is acetone) injection storage that mass fraction is 9% will be prepared
Print cartridge;
(5) printing equipment that step (3) obtains is linked to three-dimensional mobile station, with plane at 18 ° of angles close to substrate,
0~3mm is pushed after contacting substrate, in the pattern input computer program that will be brushed, under the manipulation of computer program, with 500 μm/s
Speed fast move, just be made patterned film.
Embodiment 4
(1) the cone cell fiber of the anisotropic microstructure of 2cm length is taken, respectively using 5 points of acetone, alcohol and water ultrasound
Clock cleans up, and room temperature dries;Cone cell fiber selects the metal cone cell fiber (copper wire) for having micro-structure;
(2) the ink storage box selected by has several different ink storage areas, and each ink storage area corresponds to respectively several different to be gone out
Ink hole, pitch of holes out of ink different pattern requirement can be adjusted between 0~1cm as needed;
(3) the cone cell copper wire fiber for obtaining step (1) chooses 3 close-packed arrays, and fiber butt end is adhered to ink storage
The lower section (as shown in the figure) of box nozzle, and print is prepared at certain tilt angle (preferably 13 degree) with ink storage box nozzle plane
Dataller's tool.Make the corresponding one group of hair needle of ink hole, ink storage box can be controlled its ink-jet by computer program, and can as needed with
Shi Genghuan ink seals after replacement;
(4) polystyrene (PS) solution (solvent is methylene chloride) that mass fraction is 5% will be prepared and injects ink storage box;
(5) printing equipment that step (3) obtains is linked to three-dimensional mobile station, with plane at 13 ° of angles close to substrate,
0~2mm is pushed after contacting substrate, in the pattern input computer program that will be brushed, under the manipulation of computer program, with 2000 μm/s
Speed fast move, just be made patterned film.
Embodiment 5
(1) the cone cell fiber of the anisotropic microstructure of 4cm length is taken, respectively using 5 points of acetone, alcohol and water ultrasound
Clock cleans up, and room temperature dries;Cone cell fiber selects macromolecule cone cell fiber (the vinal hair for having micro-structure
Needle);
(2) the ink storage box selected by has several different ink storage areas, and each ink storage area corresponds to respectively several different to be gone out
Ink hole, pitch of holes out of ink different pattern requirement can be adjusted between 0~1cm as needed;
(3) the cone cell vinal for obtaining step (1) chooses 3 close-packed arrays, and cone cell fiber butt end is glued
It is connected to the lower section of ink storage box ink hole, and is prepared with ink storage box ink hole plane at certain tilt angle (preferably 16 degree)
Printing equipment.Make the corresponding one group of hair needle of an ink hole, ink storage box can be controlled its ink-jet by computer program, and can be as needed
Ink is replaced at any time, is sealed after replacement;
(4) into silver nano-particle solution, then mixed solution is injected ink storage as stabilizer by the PVA of addition 0.1%
Box;
(5) printing equipment that step (3) obtains is linked to three-dimensional mobile station, with plane at 16 ° of angles close to substrate,
0~2mm is pushed after contacting substrate, in the pattern input computer program that will be brushed, under the manipulation of computer program, with 5000 μm/s
Speed fast move, just be made patterned film.
Certainly, the present invention can also there are many embodiments, without deviating from the spirit and substance of the present invention, are familiar with
Those skilled in the art can disclosure according to the present invention make various corresponding changes and modifications, but these it is corresponding change and
Deformation all should belong to scope of protection of the claims of the invention.
Claims (9)
1. the ink jet type printing equipment that a kind of controllable transports liquid is patterned surface, which is characterized in that the ink jet type printing
Device includes the ink storage box circuit board (1) containing m discharge ink hole group and the corresponding m row for being fixed on ink storage box circuit board lower part
Penholder (2);Every discharge ink hole group contains n ink hole (5), corresponding, and every spread pen frame contains n group fixation hole (3), each fixation
Several surfaces are inserted and fixed in hole has the cone cell fiber (4) of micro nano structure to form one group of cone cell fiber array unit, each
Corresponding one group of cone cell fiber array unit, the upright projection of the ink hole correspond to the top of cone cell fiber array unit under ink hole
Sharp position;
The tip of the cone cell fiber array unit is in 12~18 ° of angles with level downward.
2. ink jet type printing equipment according to claim 1, which is characterized in that be inserted and fixed in each fixation hole
1~4 cone cell fiber forms one group of cone cell fiber array unit.
3. ink jet type printing equipment according to claim 2, which is characterized in that be inserted and fixed in each fixation hole
2 cone cell fibers form one group of cone cell fiber array unit.
4. ink jet type printing equipment according to claim 1 to 3, which is characterized in that the cone cell fiber is polymer
Fiber, inorganic non-metallic fiber, metallic fiber or animal hair.
5. ink jet type printing equipment according to claim 4, which is characterized in that the animal hair length is 1~5 li
Rice, the main body of hair are the coniform fibrous material with polysaccharide and protein structure;The diameter of the cone cell material is from 0~150
Micron variation, forms the pyramidal structure of a gradual change;The pyramidal structure surface covers the " squama of one layer of 50~300 nanometers of height
Sheet " oriented structure, or the nanostructure of same scale.
6. ink jet type printing equipment according to claim 4, which is characterized in that the cone cell fiber is that polymer is fine
The diameter of dimension, inorganic non-metallic fiber or metallic fiber, cone cell fibrous material changes from 0~500 micron, and 1~5 centimetre of length,
There is coarse structure on the cone structure of the hair needle through chemical attack gradual change, the cone structure surface.
7. ink jet type printing equipment according to claim 1 to 3, which is characterized in that the cone cell fiber array unit
Root towards ink storage box circuit board advance moving direction.
8. a kind of printing process based on any ink jet type printing equipment of claim 1-7, comprising the following steps:
1) functional molecular solution is packed into ink storage box, solution droplets are dropped in cone cell fiber through the ink hole on ink storage box circuit board
On array element, printing equipment is made;
2) printing equipment for obtaining step 1) is connected to three-dimensional mobile station, is placed in ink storage box circuit board level above substrate,
Moving down makes every group of cone cell fiber array unit tip contacts substrate, then pushes 0~3mm, is moved with the speed of 0~5000 μm/s
It is dynamic, patterned surface is made.
9. printing process according to claim 8, which is characterized in that the substrate is sheet glass, silicon wafer, polymeric substrates
Or paper.
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CN201711382416.4A CN109940986B (en) | 2017-12-20 | 2017-12-20 | Ink-jet printing device and method with controllable liquid conveying as patterned surface |
PCT/CN2018/109054 WO2019119928A1 (en) | 2017-12-20 | 2018-09-30 | Inkjet printing device capable of controlling transport liquid to print patterned surface and printing method |
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CN201711382416.4A CN109940986B (en) | 2017-12-20 | 2017-12-20 | Ink-jet printing device and method with controllable liquid conveying as patterned surface |
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Cited By (2)
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CN112078247A (en) * | 2020-10-15 | 2020-12-15 | 南京工业职业技术大学 | Micron-order inkjet printing calculation and simulation method |
CN112757819A (en) * | 2021-01-20 | 2021-05-07 | 宁夏计量质量检验检测研究院 | Automatic sizing degree measuring equipment |
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JP4066661B2 (en) * | 2002-01-23 | 2008-03-26 | セイコーエプソン株式会社 | Organic EL device manufacturing apparatus and droplet discharge apparatus |
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JP2004241153A (en) * | 2003-02-03 | 2004-08-26 | Dainippon Printing Co Ltd | Manufacturing method of functional element |
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WO2019119928A1 (en) | 2019-06-27 |
CN109940986B (en) | 2020-06-26 |
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