CN109928653A - A method of utilizing the direct cement of molten state blast furnace slag - Google Patents

A method of utilizing the direct cement of molten state blast furnace slag Download PDF

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Publication number
CN109928653A
CN109928653A CN201910290620.6A CN201910290620A CN109928653A CN 109928653 A CN109928653 A CN 109928653A CN 201910290620 A CN201910290620 A CN 201910290620A CN 109928653 A CN109928653 A CN 109928653A
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CN
China
Prior art keywords
blast furnace
slag
molten state
furnace slag
raw material
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Pending
Application number
CN201910290620.6A
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Chinese (zh)
Inventor
张廷安
王艳秀
张子木
豆志河
王坤
吕国志
刘燕
赵秋月
傅大学
张伟光
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Northeastern University China
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Northeastern University China
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Priority to CN201910290620.6A priority Critical patent/CN109928653A/en
Priority to PCT/CN2019/090843 priority patent/WO2020206834A1/en
Publication of CN109928653A publication Critical patent/CN109928653A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B5/00Treatment of  metallurgical  slag ; Artificial stone from molten  metallurgical  slag 
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/14Cements containing slag
    • C04B7/147Metallurgical slag
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/36Manufacture of hydraulic cements in general
    • C04B7/38Preparing or treating the raw materials individually or as batches, e.g. mixing with fuel
    • C04B7/42Active ingredients added before, or during, the burning process
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/36Manufacture of hydraulic cements in general
    • C04B7/43Heat treatment, e.g. precalcining, burning, melting; Cooling
    • C04B7/44Burning; Melting
    • C04B7/46Burning; Melting electric
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/10Production of cement, e.g. improving or optimising the production methods; Cement grinding

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Manufacture Of Iron (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Furnace Details (AREA)

Abstract

A kind of method using the direct cement of molten state blast furnace slag of the invention, processing step are as follows: (1) molten state blast furnace slag is flowed into vortex induction heating type high temperature reduction furnace and is kept the temperature;(2) it is required according to cement composition, supplying calcareous raw material, siliceous raw material, ferriferous raw material etc., high-temperature homogenization;(3) liquid slag is directly becoming clinker through air-cooled cooling, broken, grinding after after component regulates and controls;(4) air-cooled process can trap raw material preheating of the hot wind for ironmaking processes.This method can realize that blast furnace slag complete resource utilizes, and can save great lot of water resources and utilize clinker thermal energy.

Description

A method of utilizing the direct cement of molten state blast furnace slag
Technical field:
The invention belongs to technical field of blast furnace utilization, and in particular to a kind of using the direct cement of molten state blast furnace slag Method.
Background technique:
Blast furnace slag is the slag industrial solid wastes of discharge during blast furnace ironmaking, according to grade of ore difference, 1 ton of iron row of every refining 0.3~1 ton of slag out, the grade of ore is lower, and bed drain purge is bigger.The various techniques that blast furnace molten slag can be used are processed into following various materials Material.China is usually that blast furnace slag is processed into grain slag, slag rubble, expanded slag and slag pearl etc..Grain slag is hot melt state Blast furnace slag be placed in water the process of rapid cooling, mainly have slag bath water quenching or stokehold water quenching two ways.Grain slag is used as building materials In production cement and concrete, since grain slag has potential hydraulic gelling property, in clinker, lime, gypsum equal excitation Under agent effect, it can be used as good cement raw material, can be made into portland slag cement, gypsum slag cement, lime kiln dust water Mud, slag brick, slag concrete etc..Slag rubble is blast furnace slag in specified pit or cinder field natural cooling or the cooling shape of water drenching After comparatively dense slag, by excavating, being crushed, a kind of crushed stone material obtained from magnetic separation and screening.
To realize that efficient utilization and the valuable element of blast furnace slag extract, China has carried out a large amount of R&D work, such as king Firm et al. invention " a kind of method of blast furnace slag and vessel slag comprehensive utilization, application number: CN201610045048.3 " first will be high Clinker powder and vessel slag powder are sufficiently mixed and stir evenly, and then react with hydrochloric acid: obtaining the first leachate and second solid phase object, so It isolates to obtain silica gel from the second solid phase object afterwards;Then the first leachate is reacted to obtain the second leaching with sodium hydroxide Then the second solid phase object is successively rinsed and is dried by liquid and second solid phase object, obtain the double hydroxides of calcium aluminum-based layered Produce product.
Molten state blast furnace slag is essential by-product in iron-making production, the recycling benefit of sensible heat resource abundant With being one of urgent problem to be solved in the following blast furnace slag treatment process.The inventions such as Li Hong " utilize molten blast furnace slag preparation Water-permeable brick and preparation method thereof, application number: CN201710891647.1 " is prepared by the raw material of following parts by weight: melting Blast furnace slag: 70~85 parts;Cement: 5~10 parts;Dolomite:, directly preparing water-permeable brick using molten blast furnace slag by 10~20 parts, by In molten blast furnace slag without Water Quenching technique, not only saved a large amount of cooling waters, but can efficiently, make full use of dross sensible heat Energy.For blast furnace slag tapping temperature up to 1400 DEG C or more, therefore slag per ton, which contains, is equivalent to the heat of 60kg standard coal, carries out height The waste heat of clinker recycles and comprehensive utilization, is the energy-saving effective way of steel industry.
Summary of the invention:
The purpose of the invention is to make full use of the mineral resources of molten state blast furnace slag and sensible heat energy, a kind of benefit is provided Molten state blast furnace slag is flowed into high temperature induction that is, using iron red mud as raw material with the method for the direct cement of molten state blast furnace slag It is formed under furnace high temperature using vortex stirring mode batching adjusting, calcareous original needed for requiring supplying cement composition according to cement composition Material, siliceous raw material etc., high-temperature homogenization, liquid slag is directly becoming clinker through cooling, broken, grinding after adjustment, utilizes height The heat of warm clinker eliminates the process for preparing clinker again.
To achieve the above object, the invention adopts the following technical scheme:
A method of utilizing the direct cement of molten state blast furnace slag, comprising the following steps:
(1) molten state blast furnace slag is flowed into vortex stirring formula induction heater, keeps the temperature 1~1.5h;
(2) according to clinker component requirements, after liquid slag is adjusted component, stirring evenly, and carry out concurrent heating temperature To 1400~1550 DEG C;
(3) liquid slag is cooled to room temperature after adjustment component, broken, grinding is directly becoming clinker, meets ordinary silicon Acid salt cement 425# national standard.
In the step (1), the charging of molten state blast furnace slag is carried out using vortex batching mode, hardly possible is added to solve ingredient The problem of.
In the step (1), molten state blast furnace slag includes chemical composition and mass percentage are as follows: and CaO 31~ 50%, SiO231~44%, Al2O36~18%, surplus is rare metal and other impurities, 1400-1550 DEG C of slag temperature.
In the step (2), liquid slag adjusts component detailed process are as follows: calcareous raw material, siliceous raw material and/or iron is added Matter raw material, in which: the calcareous raw material selects at least one of lime stone, carbide slag;Siliceous raw material is selected kaolin, is sticked At least one of soil, flyash, mine tailings;Ferriferous raw material selects at least one of iron red mud, scum, steel slag.
In the step (2), liquid slag adjustment component operation carries out in the induction furnace with heater.
In the step (3), the type of cooling is air-cooled, and can trap hot wind for ironmaking processes in air-cooled process Raw material preheating.
Compared with prior art, the features of the present invention and beneficial effect are:
(1) method of the invention using the direct cement of molten state blast furnace slag makes full use of all mineral moneys in blast furnace slag Source, while reducing the discharge of blast furnace slag;
(2) clinker per ton can be made to reduce water consume using the method for the invention using the direct cement of molten state blast furnace slag 10-15 tons.
(3) thermal energy for making full use of molten blast furnace slag, make to prepare using molten blast furnace slag the production process of clinker without It need to be additionally carried out heating roasting, also save fuel.Production energy consumption can be significantly reduced relative to traditional cement production technique.
(4) ingredient is added using vortex in the method for the present invention, can solve the problem that solid powder hardly possible is added in high temperature.
(5) the problem of timesharing of liquid slag adjustment group uses the stove with induction heater, can solve blending process concurrent heating.
Detailed description of the invention:
Fig. 1 is the method and process flow diagram of the invention using the direct cement of molten state blast furnace slag.
Specific embodiment:
Below with reference to embodiment, the present invention is described in further detail.
Process flow diagram such as Fig. 1 institute of the method using the direct cement of molten state blast furnace slag in following embodiment Show.
Embodiment 1
A method of utilizing the direct cement of molten state blast furnace slag, comprising the following steps:
Raw material molten state blast furnace slag chemical composition mass percentage is CaO 39%, SiO234%, Al2O39%, it is remaining Amount be rare metal and other impurities, 1550 DEG C of slag temperature.
(1) molten state blast furnace slag is flowed into vortex stirring induction heating high temperature furnace and keeps the temperature 1h;
(2) it is required according to cement composition, supplying lime contains scum, and carries out high-temperature homogenization at 1400 DEG C;
(3) liquid slag through it is air-cooled to room temperature, broken, grinding, clinker, CaO, SiO in clinker is made2、Al2O3、 Fe2O3Content be respectively 62%, 24%, 4%, 2.5%, meet the component requirements of clinker, strength of cement meets ordinary silicon Acid salt cement 425# national standard, air-cooled process trapping hot wind are used for the raw material preheating of ironmaking processes.
Embodiment 2
A method of utilizing the direct cement of molten state blast furnace slag, comprising the following steps:
Raw material molten state blast furnace slag chemical composition mass percentage is CaO 40%, SiO232%, Al2O310%, it is remaining Amount be rare metal and other impurities, 1500 DEG C of slag temperature.
(1) molten state blast furnace slag is flowed into stirring examination high temperature induction furnace and keeps the temperature 1.5h;
(2) it is required according to cement composition, is incorporated carbide slag, iron red mud, and carry out high-temperature homogenization at 1500 DEG C;
(3) liquid slag through it is air-cooled to room temperature, broken, grinding, clinker, CaO, SiO in clinker is made2、Al2O3、 Fe2O3Content be respectively 63%, 22%, 4%, 2.5%, meet the component requirements of clinker, strength of cement meets ordinary silicon Acid salt cement 425# national standard, air-cooled process trapping hot wind are used for the raw material preheating of ironmaking processes.
Embodiment 3
A method of utilizing the direct cement of molten state blast furnace slag, comprising the following steps:
Raw material molten state blast furnace slag chemical composition mass percentage is CaO 42%, SiO240%, Al2O312%, it is remaining Amount be rare metal and other impurities, 1400 DEG C of slag temperature.
(1) molten state blast furnace slag is flowed into stirring examination high temperature induction furnace and keeps the temperature 1.5h;
(2) it is required according to cement composition, is incorporated lime stone, scum, complies with cement requirement, and carry out at 1550 DEG C High-temperature homogenization;
(3) liquid slag through it is air-cooled to room temperature, broken, grinding, clinker, CaO, SiO in clinker is made2、Al2O3、 Fe2O3Content be respectively 63%, 23%, 5%, 2.5%, meet the component requirements of clinker, strength of cement meets ordinary silicon Acid salt cement 425# national standard, air-cooled process trapping hot wind are used for the raw material preheating of ironmaking processes.

Claims (6)

1. a kind of method using the direct cement of molten state blast furnace slag, which comprises the following steps:
(1) molten state blast furnace slag is flowed into vortex stirring formula induction heater, keeps the temperature 1~1.5h;
(2) according to clinker component requirements, after liquid slag is adjusted component, stirring evenly, and carry out concurrent heating temperature extremely 1400~1550 DEG C;
(3) liquid slag is cooled to room temperature after adjustment component, broken, grinding is directly becoming clinker, meets normal silicate Cement 425# national standard.
2. the method according to claim 1 using the direct cement of molten state blast furnace slag, which is characterized in that the step Suddenly in (1), the charging of molten state blast furnace slag is carried out using vortex batching mode, to solve the problems, such as that it is difficult that ingredient is added.
3. the method according to claim 1 using the direct cement of molten state blast furnace slag, which is characterized in that the step Suddenly in (1), molten state blast furnace slag includes chemical composition and mass percentage are as follows: CaO 31~50%, SiO231~44%, Al2O36~18%, surplus is hydrogen-oxygen and rare metal, 1400-1550 DEG C of slag temperature.
4. the method according to claim 1 using the direct cement of molten state blast furnace slag, which is characterized in that the step Suddenly in (2), liquid slag adjusts component detailed process are as follows: calcareous raw material, siliceous raw material and/or ferriferous raw material is added, in which: described Calcareous raw material select lime stone, at least one of carbide slag;Siliceous raw material selects kaolin, clay, flyash, mine tailings At least one of;Ferriferous raw material selects at least one of iron red mud, scum, steel slag.
5. the method according to claim 1 using the direct cement of molten state blast furnace slag, which is characterized in that the step Suddenly in (2), liquid slag adjustment component operation carries out in the induction furnace with heater.
6. the method according to claim 1 using the direct cement of molten state blast furnace slag, which is characterized in that the step Suddenly in (3), the type of cooling is air-cooled, and can trap raw material preheating of the hot wind for ironmaking processes in air-cooled process.
CN201910290620.6A 2019-04-11 2019-04-11 A method of utilizing the direct cement of molten state blast furnace slag Pending CN109928653A (en)

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PCT/CN2019/090843 WO2020206834A1 (en) 2019-04-11 2019-06-12 Method for directly cementing molten blast furnace slag

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110981232A (en) * 2019-11-19 2020-04-10 武汉理工大学 Steel slag doped adhesive and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85105291A (en) * 1985-07-10 1987-01-07 日本磁力选矿株式会社 Utilize the method for steel-making slag
CN1792944A (en) * 2005-12-30 2006-06-28 刘继清 Process for producing silicate cement chamotte by blast furnace liquid residue and apparatus thereof
CN101941807A (en) * 2010-07-07 2011-01-12 杨振立 Process flow and equipment for producing cement clinker by high-temperature molten-state slag
CN107721216A (en) * 2017-08-22 2018-02-23 上海驰春节能科技有限公司 A kind of technique using molten blast furnace slag liquid phase calcination of cement clinker

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN87102197A (en) * 1987-03-18 1988-11-02 孙竹良 The novel process of fechnology for direct conversion of blast furnace melting slag into cement clinker
CN101302568A (en) * 2008-05-23 2008-11-12 郑州永通特钢有限公司 Waste slag comprehensive recovery and utilization method for non-ferrous metals industry
CN101660014A (en) * 2009-09-24 2010-03-03 中钢集团鞍山热能研究院有限公司 Molten blast furnace slag sensible heat recovery method and device
KR101343813B1 (en) * 2012-10-18 2013-12-20 한국세라믹기술원 Apparatus for manufacturing the cement clinker

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85105291A (en) * 1985-07-10 1987-01-07 日本磁力选矿株式会社 Utilize the method for steel-making slag
CN1792944A (en) * 2005-12-30 2006-06-28 刘继清 Process for producing silicate cement chamotte by blast furnace liquid residue and apparatus thereof
CN101941807A (en) * 2010-07-07 2011-01-12 杨振立 Process flow and equipment for producing cement clinker by high-temperature molten-state slag
CN107721216A (en) * 2017-08-22 2018-02-23 上海驰春节能科技有限公司 A kind of technique using molten blast furnace slag liquid phase calcination of cement clinker

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110981232A (en) * 2019-11-19 2020-04-10 武汉理工大学 Steel slag doped adhesive and preparation method thereof

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Application publication date: 20190625