CN109851398A - A kind of intelligent jet printing technique of the big plate of ceramics - Google Patents
A kind of intelligent jet printing technique of the big plate of ceramics Download PDFInfo
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- CN109851398A CN109851398A CN201910147045.4A CN201910147045A CN109851398A CN 109851398 A CN109851398 A CN 109851398A CN 201910147045 A CN201910147045 A CN 201910147045A CN 109851398 A CN109851398 A CN 109851398A
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Abstract
The present invention is a kind of intelligent jet printing technique of big plate of ceramics, it uses concatenated ink-jet printer inkjet printing technology, pass through the layout distribution of each channel predetermined design and the intelligent sprayed printed system with automatic Compensating Robot, realize the production of ceramic big plate intelligence ink-jet, the production of technique compared with prior art, reduce the manpower in leaching glaze workshop, place, not only production facility simplifies, also reduce security risk, production scene is without leaching glaze, the generation because of equipment loss and waste water caused by under wet environment is reduced to greatest extent, production efficiency and the quality of production significantly improve, more meet Modern Green automatic intelligent manufacture general orientation.
Description
Technical field
The present invention relates to ceramic big plate field, in particular to the intelligent jet printing technique of a kind of big plate of ceramics.
Background technique
" without big plate, not famous ", it is seen that when the fashion trend of the big plate of pre-ceramic (brick).In recent years, either in Italy
Bologna CERSAIE exhibition still each ceramic industry the relevant technologies seminar at home and abroad, even each large size ceramic equipment
And in the publicity of manufacturing enterprise, the big plate (brick) of ceramics and its molding equipment become most noticeable product without exception.Root
It is provided according to the standard of GB/T23266-2009, the big plate (brick) of ceramics refers to thickness no more than 6 mm, surface area not
Less than the tile product of 1.62 m2.It compares for stone material, the big plate (brick) of ceramics has many advantages, such as, such as homogeneous, intensity
Height, isotropism, water absorption rate are low, anti-pollution is easy to clean etc..On decoration, with the maturation of ceramic production technology and ink-jet technology,
The decorative effect of ceramic big plate (brick) has innovative progress, becomes rich and varied, exquisite exquisiteness, and pattern pattern is stablized, and fits
It is popular among consumers together in large area, the design of overall effect expression.Currently, big plate (brick) manufacturing equipment of ceramics can suppress
3~30 mm of thickness is differed, and bigger advantage: low energy consumption, resource utilization is especially embodied on 3.5~6 mm of thickness
Height can save raw material 60% compared with the big plate (with a thickness of 10~12 mm) of the ceramics of general thickness, reduce energy consumption 50%, carbon emission
Reduce by 84% or more.And according to the difference of application places, thin plate and slab are each has something to recommend him, all are with the reality in market and application occasion
Border demand determines.In international Ceramic Tiles market, the big plate (brick) of ceramics has become the hot spot of high-end market.With big plate production,
The application field of the continuous breakthrough of the technological difficulties such as transport, paving, installation, the big plate (brick) of ceramics is more and more extensive, no longer only
Municipal works are confined to, application range is also expanded to the fields such as curtain wall, subway, screen, sales counter, artistic decoration, becomes extensive
A kind of novel decorative building materials of application.
In the prior art, for example, CN104591786A, CN105367131A production ink-jetting pattern class ceramic thin plate product,
It is generally used in the leaching/of bottom base layer surface or spray ground coat enamel (being also overglaze), plays bottoming whitening effect and forms glaze-body bonding
Layer, then printing inkjet color pattern on it, then sprayed again on colored design layer/or the transparency protected glaze of leaching technology mode,
Because the glaze of spray/or leaching glaze is all aqueous up to 25~35% or more, the preparation of ad hoc ball glaze workshop and execute-in-place, this is to production
Environmental protection, the glaze transport of line use and all bring the complexity of production process, so this spray with water operation one in front and one in back/
Or the technology mode of leaching glaze, have much room for improvement and is promoted.However, the preparation of ink jet layer directly affects pottery for plate big for ceramics
The surface color development and final aesthetic effect of the big plate of porcelain.
Above content is only used to facilitate the understanding of the technical scheme, and is not represented and is recognized that above content is existing skill
Art.
Summary of the invention
Technical problem solved by the invention is: optimizing ceramic sheet slab body component prescription, and uses concatenated pottery
Porcelain ink jet printer inkjet printing technology passes through the layout distribution of the predetermined design in each channel and the intelligence with automatic Compensating Robot
Sprayed printed system can be changed, realize the production of ceramic big plate intelligence ink-jet, the production of technique compared with prior art reduces leaching glaze
The manpower in workshop, place and operation, production facility simplify, and reduce security risk, and production scene subtracts to greatest extent without leaching glaze
Few generation because of equipment loss and waste water caused by under wet environment, production efficiency and the quality of production significantly improve, more meet existing
In generation, green automatic intelligent manufactured general orientation.
The technical solution used in the present invention is:
A kind of intelligent jet printing technique of the big plate of ceramics, comprises the technical steps that:
Firstly, body preparation: green compact each raw material component is put into ball mill and mixes to obtain slurry, slurry sieving, aging, removal of impurities
It is formed by being spray-dried to obtain powder, then by powder pressing, it is dry through dry kiln, obtain green body layer;
Secondly, 7 ink-jet printers that have been installed in series on ceramic production line, wherein 1 or 2 effective channels of First,
Two 2 effective channels, 2 effective channels of third platform, the 4th 3 effective channel, the 5th 1 effective channel, the 6th 1
Effective channel, the 7th 2 effective channels, the distance between every ink jet printer are 6m;
Ceramic production line facility and glaze line facility are completed;
Further, digital spray printing
A. inkjet printing is carried out to the green body after drying and forms ground glaze layer, ceramic ink is with adaptation ink-jet tube performance
There is the ceramic ink material of suspension characteristic, solid content mass fraction is 42% in the ceramic ink material, wherein Si:Al mass
It is no more than 1%, Ce mass fraction with Al total content mass fraction than=3.2, Si less than 15%, Zr mass fraction content and is no more than
2%;
B. the pattern needed for inkjet printing on ground glaze layer forms pattern layer;
It c. is by weight that 1:4 mixes to compound to obtain bonding glaze, then will bond glaze cloth by spraying by ceramic binder and surface glaze
It imposes in pattern layer, forms bonding glaze layer;
D. the uniform charity of dry granular will be brightened in bonding glaze layer, obtain dry granule layer;
E. ceramic binder is sprayed in dry granule layer, obtains surface bonding layer;
Further, high temperature firing: being placed in high temperature firing under the conditions of 1225-1240 DEG C of temperature for the green body after above-mentioned spray treatment,
Firing time is 130-180min, is cooled to room temperature, and obtains ceramic big board finished product after polished, waxing.
Preferably, 7 ink-jet printers are specifically configured to: sintering is packed into the channel of First ink-jet printer
It is afterwards in the ceramic ink of brilliant white glazed layer;Second each channel of ink-jet printer is respectively charged into including white, blue ink;Third platform
The channel of ink-jet printer is respectively charged into including palm fibre, yellow ink;The channel of 4th ink-jet printer be respectively charged into including it is black,
Tangerine, it is blackish green including ink;The channel of 5th ink-jet printer is respectively charged into including sanguine ink;6th ink-jet is beaten
The channel of print machine is respectively charged into including function ceramics ink or also containing the ceramic ink in metallic luster;7th ink-jet is beaten
It includes the ceramic ink for having glue totally 2 channels of protection glaze effect after sintering that print machine channel, which is respectively charged into,.
Preferably, the formula system of the ceramic sheet slab body are as follows: silica 64%, aluminum oxide 25%, potassium oxide
3.8%, sodium oxide molybdena 2.6%, calcium oxide 0.6%, magnesia 1.2%, di-iron trioxide 1%.It burns and loses 1.8%.
Preferably, the dry granule layer is uniformly laid with by brightening dry granular, and the sial content ratio for brightening dry granular is
SiO2:Al2O3=2.95-3.4.
Further, the ceramic binder include by weight percentage 1.6% sanlose, 1~5%
Activating agent, 1~3% antisettling agent and 8% glycerol, chemical constituent includes 20~40% by weight percentage
The loss on ignition of Na2O and 40~60%.
Preferably, the intelligent jet printing technique further includes having ceramic spray printing robot system, the robot system packet
Include Six-DOF industrial robot.
Further, the robot system specifically further includes spray gun, full intelligent control device, Kinect vision system, object
Material conveyer and portal frame robot.
Further, the full intelligent control device includes the mechanism compensated to robot, and uses compensation method,
The drive path in each joint of the Six-DOF industrial robot is split, the drive path in each joint is independently divided
Analysis;Corner calculating is carried out, obtains induction corner, and further finds out output corner and inputs the relational expression of corner;To defeated
Corner makees superposition out, and after being corrected three joint rotation angles and input corner relationship;The result of acquisition remakes transmission
Than conversion, the mapping relations between revised joint rotation angle and servo motor input corner are obtained, and are obtained by the mapping relations
Motion compensated schemes are converted to executable instruction file and are input to robot and execute by specific motion compensated schemes out.
The beneficial effects of the present invention are: passing through the predetermined of each channel using concatenated ceramic ink jet machine inkjet printing technology
The layout of design is distributed and the intelligent sprayed printed system with automatic Compensating Robot, realizes ceramic big plate intelligence ink-jet
Production, the production of technique compared with prior art reduces the leaching manpower in glaze workshop, place, and not only production facility simplifies, and also subtracts
Security risk is lacked, production scene is reduced to greatest extent without leaching glaze because of equipment loss caused by under wet environment and waste water
It generates, production efficiency and the quality of production significantly improve, and more meet Modern Green automatic intelligent manufacture general orientation.
Detailed description of the invention
Fig. 1 is process flow chart of the invention.
Specific embodiment
The present invention is specifically described below with reference to embodiment, in order to technical field personnel to of the invention
Understand.It is necessary to it is emphasized that embodiment is only intended to, the present invention will be further described herein, should not be understood as to this
The limitation of invention protection scope, fields person skilled in the art, the non-intrinsically safe that the present invention is made according to foregoing invention content
The modifications and adaptations of property, should still fall within protection scope of the present invention.Mentioned raw materials following simultaneously are unspecified, are
Commercial product;The processing step or preparation method not referred in detail be processing step known to a person skilled in the art or
Preparation method.
[embodiment 1]
A kind of intelligent jet printing technique of the big plate of ceramics, comprises the technical steps that:
Firstly, body preparation: green compact each raw material component is put into ball mill and mixes to obtain slurry, slurry sieving, aging, removal of impurities
It is formed by being spray-dried to obtain powder, then by powder pressing, it is dry through dry kiln, obtain green body layer;
Secondly, 7 ink-jet printers that have been installed in series on ceramic production line, wherein 1 or 2 effective channels of First,
Two 2 effective channels, 2 effective channels of third platform, the 4th 3 effective channel, the 5th 1 effective channel, the 6th 1
Effective channel, the 7th 2 effective channels, the distance between every ink jet printer are 6m;
Ceramic production line facility and glaze line facility are completed;
Further, digital spray printing
A. inkjet printing is carried out to the green body after drying and forms ground glaze layer, ceramic ink is with adaptation ink-jet tube performance
There is the ceramic ink material of suspension characteristic, solid content mass fraction is 42% in the ceramic ink material, wherein Si:Al mass
It is no more than 1%, Ce mass fraction with Al total content mass fraction than=3.2, Si less than 15%, Zr mass fraction content and is no more than
2%;
B. the pattern needed for inkjet printing on ground glaze layer forms pattern layer;
It c. is by weight that 1:4 mixes to compound to obtain bonding glaze, then will bond glaze cloth by spraying by ceramic binder and surface glaze
It imposes in pattern layer, forms bonding glaze layer;
D. the uniform charity of dry granular will be brightened in bonding glaze layer, obtain dry granule layer;
E. ceramic binder is sprayed in dry granule layer, obtains surface bonding layer;
Further, high temperature firing: being placed in high temperature firing under the conditions of 1225-1240 DEG C of temperature for the green body after above-mentioned spray treatment,
Firing time is 130-180min, is cooled to room temperature, and obtains ceramic big board finished product after polished, waxing.
[embodiment 2]
The present embodiment is with embodiment 1 the difference lies in that the setting of the ink-jet printer of above-mentioned jet printing technique specifically: in First
The ceramic ink after being sintered in brilliant white glazed layer is packed into the channel of ink-jet printer;Second each channel of ink-jet printer point
It Zhuan Ru not include white, blue ink;The channel of third platform ink-jet printer is respectively charged into including palm fibre, yellow ink;4th ink-jet
The channel of printer be respectively charged into including black, tangerine, it is blackish green including ink;The channel of 5th ink-jet printer is respectively charged into packet
Include sanguine ink;The channel of 6th ink-jet printer is respectively charged into including function ceramics ink or also containing in metal
The ceramic ink of color;It includes the glue totally 2 for having protection glaze effect after sintering that 7th ink-jet printer channel, which is respectively charged into,
The ceramic ink in a channel.
[embodiment 3]
Relative to Examples 1 and 2, the formula system of the ceramic sheet slab body in embodiment 3 specifically: silica 64%, three oxygen
Change two aluminium 25%, potassium oxide 3.8%, sodium oxide molybdena 2.6%, calcium oxide 0.6%, magnesia 1.2%, di-iron trioxide 1%.It burns and loses 1.8%.
The dry granule layer is uniformly laid with by brightening dry granular, and the sial content ratio for brightening dry granular is SiO2:Al2O3
=2.95-3.4.
Further, the ceramic binder include by weight percentage 1.6% sanlose, 1~5%
Activating agent, 1~3% antisettling agent and 8% glycerol, chemical constituent includes 20~40% by weight percentage
The loss on ignition of Na2O and 40~60%.
[embodiment 4]
Embodiment 4 is a kind of intelligent jet printing technique and device, is the intelligent jet printing technique described in embodiment 1-3
Specific implementation device, has specifically included ceramic spray printing robot system, and the robot system includes six degree of freedom industrial machine
People.
Further, the robot system specifically further includes spray gun, full intelligent control device, Kinect vision system, object
Material conveyer and portal frame robot.
Further, the full intelligent control device includes the mechanism compensated to robot, and uses compensation method,
The drive path in each joint of the Six-DOF industrial robot is split, the drive path in each joint is independently divided
Analysis;Corner calculating is carried out, obtains induction corner, and further finds out output corner and inputs the relational expression of corner;To defeated
Corner makees superposition out, and after being corrected three joint rotation angles and input corner relationship;The result of acquisition remakes transmission
Than conversion, the mapping relations between revised joint rotation angle and servo motor input corner are obtained, and are obtained by the mapping relations
Motion compensated schemes are converted to executable instruction file and are input to robot and execute by specific motion compensated schemes out.
It should be understood that the application of the present invention is not limited to the above can for the normal technician of this field
With improvement or transformation based on the above description, all these modifications and variations all should belong to the guarantor of appended claims of the present invention
Protect range.
Claims (5)
1. a kind of intelligent jet printing technique of the big plate of ceramics, which is characterized in that comprise the technical steps that:
(1) body preparation:
Green compact each raw material component is put into ball mill and mixes to obtain slurry, is spray-dried to obtain powder after slurry sieving, aging, removal of impurities
Material, then powder pressing is formed, it is dry through dry kiln, obtain green body layer;
(2) be installed in series 7 ink-jet printers on ceramic production line, wherein 1 or 2 effective channels of First, and second
2 effective channels of platform, 2 effective channels of third platform, the 4th 3 effective channel, the 5th 1 effective channel, the 6th 1 has
Channel, the 7th 2 effective channels are imitated, the distance between every ink jet printer is 6m;
(3) ceramic production line facility and glaze line facility are completed;
(4) digital spray printing:
A. inkjet printing is carried out to the green body after drying and forms ground glaze layer, ceramic ink is with adaptation ink-jet tube performance
There is the ceramic ink material of suspension characteristic, solid content mass fraction is 42% in the ceramic ink material, wherein Si:Al mass
It is no more than 1%, Ce mass fraction with Al total content mass fraction than=3.2, Si less than 15%, Zr mass fraction content and is no more than
2%;
B. the pattern needed for inkjet printing on ground glaze layer forms pattern layer;
It c. is by weight that 1:4 mixes to compound to obtain bonding glaze, then will bond glaze cloth by spraying by ceramic binder and surface glaze
It imposes in pattern layer, forms bonding glaze layer;
D. the uniform charity of dry granular will be brightened in bonding glaze layer, obtain dry granule layer;
E. ceramic binder is sprayed in dry granule layer, obtains surface bonding layer;
(5) green body after above-mentioned spray treatment high temperature firing: is placed in high temperature firing under the conditions of 1225-1240 DEG C of temperature, firing
Time is 130-180min, is cooled to room temperature, and obtains ceramic big board finished product after polished, waxing;
For the intelligence jet printing technique using ceramic spray printing robot system, the robot system includes six degree of freedom industrial machine
Device people;The robot system specifically further includes spray gun, full intelligent control device, Kinect vision system, material conveyor and
Portal frame robot;
The full intelligent control device includes the mechanism compensated to robot, and uses compensation method, certainly to described six
It is split by the drive path in each joint of degree industrial robot, the drive path in each joint is independently analyzed;Turned
Angle calculates, and obtains induction corner, and further finds out output corner and input the relational expression of corner;Output corner is folded
Add operation, and after being corrected three joint rotation angles and input corner relationship;The result of acquisition remakes gear ratio conversion, obtains
Mapping relations between revised joint rotation angle and servo motor input corner, and specific movement is obtained by the mapping relations
Motion compensated schemes are converted to executable instruction file and are input to robot and execute by compensation scheme.
2. a kind of intelligent jet printing technique of the big plate of ceramics according to claim 1, which is characterized in that 7 ink-jets
Printer is specifically configured to: the ceramic ink after being sintered in brilliant white glazed layer is packed into the channel of First ink-jet printer
Water;Second each channel of ink-jet printer is respectively charged into including white, blue ink;The channel of third platform ink-jet printer is respectively charged into
Including palm fibre, yellow ink;The channel of 4th ink-jet printer be respectively charged into including black, tangerine, it is blackish green including ink;5th
The channel of ink-jet printer is respectively charged into including sanguine ink;The channel of 6th ink-jet printer is respectively charged into including function
Can ceramic ink or also containing in metallic luster ceramic ink;It includes to burn that 7th ink-jet printer channel, which is respectively charged into,
There is the ceramic ink in glue totally 2 channels of protection glaze effect after knot.
3. a kind of intelligent jet printing technique of the big plate of ceramics according to claim 1, it is characterised in that: the big plate of ceramics
The formula system of green body are as follows: silica 64%, aluminum oxide 25%, potassium oxide 3.8%, sodium oxide molybdena 2.6%, calcium oxide 0.6%,
Magnesia 1.2%, di-iron trioxide 1% burn and lose 1.8%.
4. a kind of intelligent jet printing technique of big plate of ceramics according to claim 1, it is characterised in that: the dry granule layer by
It brightens dry granular to be uniformly laid with, the sial content ratio for brightening dry granular is SiO2:Al2O3=2.95-3.4.
5. according to claim 1 or a kind of 2 described in any item intelligent jet printing techniques of the big plate of ceramics, which is characterized in that institute
Stating ceramic binder by weight percentage includes 1.6% sanlose, 1~5% activating agent, 1~3%
Antisettling agent and 8% glycerol, chemical constituent include by weight percentage 20~40% Na2O and 40~60% burning lose
Amount.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112325650A (en) * | 2021-01-07 | 2021-02-05 | 广东中鹏热能科技有限公司 | Automatic continuous energy-saving firing production line for ceramic rock plates |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20050183603A1 (en) * | 2004-02-20 | 2005-08-25 | International Business Machines Corporation | Method and system for minimizing the appearance of image distortion in a high speed inkjet paper printing system |
JP2009290661A (en) * | 2008-05-30 | 2009-12-10 | Seiko Epson Corp | Image processing apparatus, image processing method, image processing program and printer |
CN104553422A (en) * | 2013-10-11 | 2015-04-29 | 中国印刷科学技术研究所 | 3D color surface ink-jet printing method |
CN105201171A (en) * | 2015-09-30 | 2015-12-30 | 佛山市东鹏陶瓷有限公司 | Novel stereoscopic ceramic chip and preparation method thereof |
CN106396741A (en) * | 2016-08-31 | 2017-02-15 | 广东金意陶陶瓷有限公司 | Ceramic tile with mineral crystal fancy glaze layer and preparation method thereof |
CN107471122A (en) * | 2017-09-20 | 2017-12-15 | 西安蓝想新材料科技有限公司 | A kind of high-efficiency environment friendly vehicle removes finish paint device and its control method |
CN108394008A (en) * | 2018-03-23 | 2018-08-14 | 广东萨米特陶瓷有限公司 | Big plate of ceramics of anhydrous glaze line full digital code jet printing technique and preparation method thereof |
-
2019
- 2019-02-27 CN CN201910147045.4A patent/CN109851398B/en active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20050183603A1 (en) * | 2004-02-20 | 2005-08-25 | International Business Machines Corporation | Method and system for minimizing the appearance of image distortion in a high speed inkjet paper printing system |
JP2009290661A (en) * | 2008-05-30 | 2009-12-10 | Seiko Epson Corp | Image processing apparatus, image processing method, image processing program and printer |
CN104553422A (en) * | 2013-10-11 | 2015-04-29 | 中国印刷科学技术研究所 | 3D color surface ink-jet printing method |
CN105201171A (en) * | 2015-09-30 | 2015-12-30 | 佛山市东鹏陶瓷有限公司 | Novel stereoscopic ceramic chip and preparation method thereof |
CN106396741A (en) * | 2016-08-31 | 2017-02-15 | 广东金意陶陶瓷有限公司 | Ceramic tile with mineral crystal fancy glaze layer and preparation method thereof |
CN107471122A (en) * | 2017-09-20 | 2017-12-15 | 西安蓝想新材料科技有限公司 | A kind of high-efficiency environment friendly vehicle removes finish paint device and its control method |
CN108394008A (en) * | 2018-03-23 | 2018-08-14 | 广东萨米特陶瓷有限公司 | Big plate of ceramics of anhydrous glaze line full digital code jet printing technique and preparation method thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112325650A (en) * | 2021-01-07 | 2021-02-05 | 广东中鹏热能科技有限公司 | Automatic continuous energy-saving firing production line for ceramic rock plates |
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