CN109851389A - A kind of preparation method of magnetic porous ceramics - Google Patents

Abstract

The invention discloses a kind of preparation methods of magnetic porous ceramics, belong to water-treatment technology field.The present invention according to parts by weight, by pretreating sludge, pre-processes kaolin, pre-processes potassium feldspar, pretreatment quartz, and modified graphene oxide mixing and ball milling is sieved, obtains mixed-powder；By mixed-powder, modified meerschaum, mixed bacteria liquid, modified sodium alginate liquid, iron nitrate solution, Fluorinse, water is stirred, ammonium hydroxide is then added dropwise and adjusts pH, injection molding, Frozen-thawed cycled is dry, obtains dry brick；Dry brick is carbonized, is heated up step by step, high-temperature process obtains single treatment adobe；Single treatment adobe is handled by high-temperature water vapor, it is dry to get secondary treatment adobe；Secondary treatment adobe is soaked in modification liquid, carbon dioxide is then passed through, is taken out, it is dry to get magnetic porous ceramics.The magnetic porous ceramics of gained mechanical property while porosity is promoted of the invention also gets a promotion, and has excellent wastewater treatment efficiency.

Description

A kind of preparation method of magnetic porous ceramics

Technical field

The invention discloses a kind of preparation methods of magnetic porous ceramics, belong to water-treatment technology field.

Background technique

As to the attention in terms of environmental protection, requirement of the people to urban environment is also higher and higher, causes to ring at present The disposition requirement of the environmental contaminants such as waste water, exhaust gas, solid waste that border pollutes is also higher and higher, and this requires environmental protection Worker handle deeper into thorough to pollutant.Waste sludge is easy to produce in conventional process and disposing technique The waste of secondary pollution.Original city sewage and sludge processing disposal options have been unable to meet the development of society and the need of people It asks.So it is discarded to become processing because increasing the utilization rate of waste sludge, reducing secondary pollution for the recycling and reusing of waste sludge One critically important aspect of sludge.The major technique of the recycling of sludge has: sludge composting technology, sludge prepare active carbon skill Art, sludge energy technology, sludge building materials using technology etc..It is the recycling of sludge using waste sludge production porous ceramic grain In critically important one aspect.

Sewage Biological Treatment is exactly will be in the organic of colloidal attitude and solubilised state using the metabolism of microorganism in water Pollutant is changed into stable innoxious substance.According to different growths of the microorganism in the microorganism reactor in sewage treatment State, the biological treatment mode of sewage can be divided into floating type growth technique (using activated sludge process as representative) and attached type growth work Skill (using biofilm as representative).Activated sludge process refers to the microorganism in bioreactor in the form of activated sludge in suspension State；Biofilm refers to that the microorganism in bioreactor fixes and adheres in membrane form on the surface of carrier.In the modern times Sewage treatment in, activated sludge process is most widely used biological treatment, have the advantage that effluent quality is good, handle Ability is high.Disadvantage is as follows: capital construction and running cost are high, and energy consumption is larger, is easy to happen Mud up-floating, complex management, and sludge is easy swollen It is swollen etc..Biomembrane process no advantage of active sludge in microbial cell technique for fixing: biofacies is stable, is easy to pipe Reason and maintenance maintain the higher sludge age of microorganism, denitrification functions well, to the water and water quality of sewage variation to have stronger adaptation Ability, the settling property of sludge are good.The core of biomembrane process is carrier, and common inorganic filler has haydite, active carbon, stone Sand, expansion baby continue silicate material, coke etc.；It is good that inorganic filler has the advantages that mechanical strength, but autologous density is larger, cannot Do fluidisation state operation.

Porous ceramics is because of its large specific surface area, and internal porous, chemical and thermal stability is good, preferable absorption property, easily In regeneration, it is possible to as a kind of cheap adsorbent.But the fragment of ceramic grain filter has higher wear breakage and larger Resistance to water-flow the disadvantages of, so constantly to research and develop novel ceramic filter material.Not only with waste sludge production cellular ceramic substrate The recycling range of waste sludge can be increased, and waste water can be provided as the advantage of biofilm carrier by porous ceramics Treatment effect.There is researcher to carry out magnetization modification to the porous ceramics prepared with waste sludge, can have been promoted using magnetic field Treatment effect of the porous ceramics as biofilm carrier is improved into the characteristic of the growth of microorganism.

Traditional porous ceramics hole rate and mechanical property can not be promoted simultaneously, so there is scholar with freezing injection molding preparation Alumina porous ceramic green body；Dry and sintering, obtains high-porosity alumina porous ceramics.Do not changing interior three-dimensional network Under the premise of structure, porous ceramic articles open porosity is improved.The not only aperture with higher of the alumina porous ceramic of preparation Porosity and lower bulk density make it show higher filtering, absorption property, and mechanical strength with higher, Significantly improve its mechanical property.In terms of sewage treatment, by magnetisable material and the necessary nutrition for promoting microorganism growth, breeding Element is added in polymer carrier to form a kind of novel magnetic bio hydrophilic filler together, and the filler made in this way is just It is equivalent to the miniature bioreactor for being attached with magnetic field, is made using the magnetic effect of microorganism and metabolism or Co metabolism With the mass-transfer performance and surface moist that can improve filler, so that the formation period of biomembrane subtracts in biofilm reactor It is short, improve the treatment effect of waste water.But magnetic porous ceramics traditional at present there is also porositys and mechanical property can not be same Shi Tisheng, and reunion and plug-hole easily occur for magnetic powder in preparation process, lead to the problem that product is bad to the treatment effect of sewage, We also need to carry out further explore and study to this.

Summary of the invention

The present invention solves the technical problem of: it can not be same for traditional magnetic porous ceramics hole rate and mechanical property Shi Tisheng, and reunion and plug-hole easily occur for magnetic powder in preparation process, lead to the problem that product is bad to the treatment effect of sewage, Provide a kind of preparation method of magnetic porous ceramics.

In order to solve the above-mentioned technical problem, the technical scheme adopted by the invention is that:

(1) according to parts by weight, by 40~60 parts of pretreating sludges, 10~20 parts of pretreatment kaolin, 8~10 parts of pretreatment potassium Feldspar, 20~30 parts of pretreatment quartz, 10~20 parts of modified graphene oxide mixing and ball millings, sieving obtain mixed-powder；

(2) according to parts by weight, by 40~60 parts of mixed-powders, 10~20 parts of modified meerschaums, 10~20 parts of mixed bacteria liquids, 20 ~30 parts of modified sodium alginate liquid, 10~20 parts of iron nitrate solutions, 5~8 parts of Fluorinses, 20~30 parts of water are stirred, Then ammonium hydroxide is added dropwise and adjusts pH to 8.3~8.6, injection molding, Frozen-thawed cycled is dry, obtains dry brick；

(3) dry brick is carbonized, is heated up step by step, high-temperature process obtains single treatment adobe；

(4) single treatment adobe is handled by high-temperature water vapor, it is dry to get secondary treatment adobe；

(5) secondary treatment adobe is soaked in modification liquid, is then passed through carbon dioxide, taken out, drying is more to get magnetism Hole ceramics.

The preparation process of step (1) described pretreating sludge are as follows: according to parts by weight, by 20~30 parts of municipal sludges, 20 ~30 parts of flocculation sludges, 0.2~0.3 part of protease, 0.2~0.3 part of lipase, 60~80 parts of water termostat mixed processings, then Sodium hydroxide solution is added to be stirred to react, glacial acetic acid is then added and adjusts pH to 7.3~7.6, is stirred dirty to get pretreatment Mud.

The kaolinic treatment process of step (1) pretreatment are as follows: according to parts by weight, by 40~60 parts of kaolin, 20 ~30 parts of organic acids, 3~5 parts of gutter oils, 3~5 parts of rubber powders, 60~80 parts of water mixing and ball millings, be subsequently added into ammonium hydroxide adjust pH to 6.8~7.1, it is stirred, is evaporated under reduced pressure, it is dry to get pretreatment kaolin；The organic acid is by tartaric acid and malic acid 1:3~1:5 mixed preparing in mass ratio forms；The rubber powder is that gummi arabicum pulveratum is mixed with peach gum powder 1:2~1:3 in mass ratio It is formulated.

The preparation process of step (1) the pretreatment potassium feldspar are as follows: according to parts by weight, by 20~30 parts of potassium feldspars, 2~ 3 parts of flyash, 3~5 parts of silicon ashes, 2~3 parts of serpentines, 2~3 parts of volcanic ash mixing and ball millings are sieved, and it is long must to pre-process potassium for calcining Stone.

The treatment process of step (1) the pretreatment quartz are as follows: mix chitosan and water 1:50~1:100 in mass ratio It closes, after standing swelling, heating stirring dissolution obtains chitosan liquid, according to parts by weight, by 30~50 parts of quartz, 2~3 parts of Buddha's warrior attendants Sand, 40~60 parts of chitosan liquid are stirred, and are subsequently added into the terephthalaldehyde of 0.1~0.2 times of chitosan liquid product, and stirring is mixed It closes, dry, pulverize, ball milling, calcining is to get pretreatment quartz.

The preparation process of step (1) described modified graphene oxide are as follows: by graphene oxide and water 1:20 in mass ratio~ 1:30 mixing, ultrasonic disperse are then added dropwise ammonium hydroxide and adjust pH to 9.8~10.1, Pretreatment Mixed Liauid obtained, by Chinese ephedra fiber powder It is broken, the sieve of 80 mesh is crossed, Chinese ephedra fiber powder is obtained, according to parts by weight, and 20~30 parts of Chinese ephedra fiber powder, 8~10 parts of cellulases, 40 ~60 parts of water stirring constant temperature processing, enzyme deactivation obtain Chinese ephedra fiber mixed liquor, Pretreatment Mixed Liauid and Chinese ephedra fiber mixed liquor are pressed matter Amount is mixed than 1:5~1:10 to be vibrated, and is filtered, is washed, dry, i.e. modified graphene oxide.

The preparation process of step (2) described modified meerschaum are as follows: according to parts by weight, by 20~30 parts of sepiolites, 3~5 Part carbomer, 3~5 parts of plants essential oils, 1~2 part of biogas slurry, 1~2 portion of sucrose, 40~60 parts of water mixed fermentations are subsequently added into ammonium hydroxide PH to 8.1~8.3 is adjusted, is stirred, is filtered, dry, high-temperature process cools down to get modified meerschaum；The plants essential oil It is to be formed by Schisandra chinensis essential oil and feverfew essential oil 1:2~1:3 mixed preparing in mass ratio.

The preparation process of step (2) described mixed bacteria liquid are as follows: according to parts by weight, by 1~2 part of Bacillus pasteurii, 1~ 2 parts of Escherichia coli, 1~2 part of glycerol, 1~2 part of polyethylene glycol, 30~50 parts of water, constant temperature are stirred to get mixed bacteria liquid.

The preparation process of step (2) the modified sodium alginate liquid are as follows: by sodium alginate and water 1:50~1 in mass ratio: 100, after mixing stands swelling, heating stirring dissolution is subsequently added into 0.02~0.03 times of sodium alginate quality of sodium metaperiodate, adds Thermal agitation reaction, is subsequently added into 2~3 times of sodium alginate quality of carbon nanotube, then ammonium hydroxide is added dropwise and adjusts pH to 8.6~8.9, adds Thermal agitation is reacted to get modified sodium alginate liquid.

The preparation process of step (5) the modification liquid are as follows: by (N- amidino groups) dodecylacrylamide and poly- second two 01 derivatives 1:1~2:1 in mass ratio mixing, and 0.1~0.2 times of polyethyleneglycol derivative quality of paracide is added and gathers The ferrocene that 0.07~0.10 times of ethylene glycol derivative quality is stirred to get modification liquid；The polyethylene glycol is derivative Object is novel Y-shaped polyethylene glycol, any one in multi-arm polyethylene glycol or methoxy poly (ethylene glycol).

The beneficial effects of the present invention are:

(1) present invention is by addition mixed bacteria liquid, iron nitrate solution and Fluorinse, during the preparation process, firstly, using thin Bacterium surface is negatively charged, and iron ion is positively charged, and the iron ion in system can be adsorbed by bacteria cell wall, then pass through dropwise addition Ammonium hydroxide adjusts pH, so that precipitation of iron ions, and iron hydroxide microballoon is formed, then by Frozen-thawed cycled, since iron hydroxide is micro- Containing compared with juicy inside ball, by freezing, the volume of water is expanded, and original aperture is supportted greatly by ice, is then passed through thawing, Hole in system forms connection three-dimensional network, then, under the high temperature conditions so that the organic matter in system carbonizes, then by Grade heating, under a nitrogen atmosphere, the iron oxide in system can be reduced into fe by carbonaceous, in urging for fe and sodium fluoride Under change effect, the carbonaceous of hole wall surface can generate silicon carbide supporter with the silicon dioxde reaction in system, play good Supporting role, effectively prevent the gap in system to collapse, ensure that the complete of gap so that in system porosity promoted While system mechanical property get a promotion, then pass through high-temperature water vapor reaction, the fe and high-temperature water in system steam Vapour reaction, generates ferroso-ferric oxide, the ferroso-ferric oxide of generation can be well distributed in system, so that product is to dirt The treatment effect of water gets a promotion, and is not susceptible to plug-hole；

(2) present invention is by addition modified graphene oxide, in modified graphene oxide preparation process, firstly, will pretreatment Mixed liquor is mixed with Chinese ephedra fiber mixed liquor, in water being capable of portion since carboxyl is contained in graphene oxide layer structure edge Divide and be hydrolyzed into carboxylic acid ion, keeps its negatively charged, electrostatic repulsion, Chinese ephedra fiber are generated between negatively charged graphene oxide Hydrogenbond is easily formed between graphene oxide layer structure, so that forming graphene oxide sheet-Chinese ephedra fiber-oxidation in system The structure of graphene, there are a large amount of gaps in this structure, so that the hole of system gets a promotion, in use, Negatively charged graphene oxide can enriched in iron ions, then by the way that ammonium hydroxide is added dropwise, so that precipitation of iron ions, then, in nitrogen Under the conditions of gas, the iron oxide in system can be reduced into fe by carbonaceous, under the catalytic action of fe and sodium fluoride, hole The carbonaceous of wall surface can generate silicon carbide supporter, so that porosity in system with the silicon dioxde reaction in system The mechanical property of system gets a promotion while promotion, then passes through high-temperature water vapor reaction, fe and high temperature in system Steam reaction generates ferroso-ferric oxide, and the ferroso-ferric oxide of generation can be well distributed in system, so that product The treatment effect of sewage is further promoted.

Specific embodiment

According to parts by weight, by 20~30 parts of municipal sludges, 20~30 parts of flocculation sludges, 0.2~0.3 part of protease, 0.2 ~0.3 part of lipase, 60~80 parts of water are placed in No. 1 beaker, and No. 1 beaker is then placed in digital display and is tested the speed constant temperature blender with magnetic force In, it is 30 DEG C in temperature, under the conditions of revolving speed is 100~200r/min, constant temperature is stirred 40~60min of processing, then to No. 1 The sodium hydroxide solution that mass fraction is 20~30% is added in beaker, under the conditions of revolving speed is 400~600r/min, stirring is anti- Answer 40~60min, then in No. 1 beaker be added glacial acetic acid adjust pH to 7.3~7.6, in revolving speed be 600~800r/min item Under part, 40~60min is stirred to get pretreating sludge；According to parts by weight, by 40~60 parts of kaolin, 20~30 parts Organic acid, 3~5 parts of gutter oils, 3~5 parts of rubber powders, 60~80 parts of water are placed in 40~60min of mixing and ball milling in No. 1 ball mill, obtain 1 Number ball milling material, then No. 1 ball milling material is placed in single-necked flask, and it is 20~30% that mass fraction is then added into single-necked flask Ammonium hydroxide adjusts pH to 6.8~7.1, under the conditions of revolving speed is 400~600r/min, is stirred 40~60min, obtains mixing and ball milling Mixing and ball milling homogenate is then placed in Rotary Evaporators by homogenate, is 60~70 DEG C in temperature, pressure is 500~800Pa condition Under, be evaporated under reduced pressure 40~60min after, homogenate must be concentrated, then will concentration be homogenized be placed in baking oven, in temperature be 105~110 DEG C Under the conditions of, drying to constant weight is to get pretreatment kaolin；According to parts by weight, by 20~30 parts of potassium feldspars, 2~3 parts of fine coal Ash, 3~5 parts of silicon ashes, 2~3 parts of serpentines, 2~3 parts of volcanic ash are placed in mixing and ball milling in No. 2 ball mills, cross the sieve of 120 mesh, obtain No. 2 ball milling material are then placed in Muffle furnace by No. 2 ball milling material, under the conditions of temperature is 650~750 DEG C, after calcining 2~3h, with Furnace is down to room temperature, obtains pretreatment potassium feldspar；Chitosan and water 1:50~1:100 in mass ratio are placed in No. 2 beakers, and use glass Glass stick stirs 10~20min, after standing 3~5h of swelling, No. 2 beakers is placed in digital display and are tested the speed in constant temperature blender with magnetic force, Yu Wen Degree is 90~95 DEG C, and under the conditions of revolving speed is 400~600r/min, heating stirring dissolves 40~60min, chitosan liquid is obtained, by weight Number meter is measured, by 30~50 parts of quartz, 2~3 parts of diamond dust, 40~60 parts of chitosan liquid are placed in No. 3 beakers, are in revolving speed Under the conditions of 400~600r/min, it is stirred 40~60min, chitosan liquid product 0.1~0.2 is then added into No. 3 beakers Terephthalaldehyde again is stirred 40~60min, obtains mixed gel, then under the conditions of revolving speed is 500~600r/min Mixed gel is placed in baking oven, it is dry to constant weight under the conditions of temperature is 105~110 DEG C, desiccant gel is obtained, will then be done It is crushed in dry gel pulverizer, obtains crushed material, crushed material is then placed in ball milling in No. 3 ball mills, obtain No. 3 ball milling material, then No. 3 ball milling material are placed in Muffle furnace, under the conditions of temperature is 650~750 DEG C, after calcining 2~3h, are down to room temperature with furnace, i.e., Quartz must be pre-processed；Graphene oxide and water 1:20~1:30 in mass ratio are placed in No. 4 beakers, and No. 4 beakers are placed in In ultrasonic disperse instrument, under the conditions of supersonic frequency is 55~75kHz, 40~60min of ultrasonic disperse is then dripped into No. 4 beakers Add the ammonium hydroxide that mass fraction is 20~30% to adjust pH to 9.8~10.1, obtains Pretreatment Mixed Liauid, Chinese ephedra fiber is placed in crushing It is crushed in machine, crosses the sieve of 80 mesh, obtain Chinese ephedra fiber powder, according to parts by weight, 20~30 parts of Chinese ephedra fiber powder, 8~10 parts of fibers Plain enzyme, 40~60 parts of water are placed in No. 5 beakers, are 30~35 DEG C in temperature, under the conditions of revolving speed is 300~500r/min, are stirred After constant temperature handles 40~60min, 90~95 DEG C of 20~30min of enzyme deactivation are warming up to, Chinese ephedra fiber mixed liquor is obtained, pretreatment is mixed Liquid and Chinese ephedra fiber mixed liquor 1:5~1:10 in mass ratio are placed in 5~10min of concussion in vortex oscillator, obtain mixed serum, connect Mixed serum is filtered, obtain filter residue, then the filter residue after washing be then placed in residue washing 3~5 times with deionized water In baking oven, under the conditions of temperature is 105~110 DEG C, drying is to constant weight to get modified graphene oxide；According to parts by weight, will 20~30 parts of sepiolites, 3~5 parts of carbomers, 3~5 parts of plants essential oils, 1~2 part of biogas slurry, 1~2 portion of sucrose, 40~60 parts of water are mixed Conjunction is placed in No. 1 fermentation cauldron, in temperature be 30~35 DEG C, revolving speed be 300~500r/min under the conditions of, be stirred fermentation 40~ The ammonium hydroxide that mass fraction is 20~30% is then added into No. 1 fermentation cauldron and adjusts pH to 8.1~8.3, is in revolving speed by 60min Under the conditions of 400~600r/min, after being stirred 40~60min, filtering obtains filter cake, then filter cake is placed in baking oven, Yu Wen It is dry to constant weight under the conditions of degree is 105~110 DEG C, dry cake is obtained, then dry cake is placed in sintering furnace, and with 60 ~90mL/min rate is filled with nitrogen into furnace, under the conditions of temperature is 800~900 DEG C, after 1~2h of high-temperature process, drops with furnace To room temperature to get modified meerschaum；According to parts by weight, by 1~2 part of Bacillus pasteurii, 1~2 part of Escherichia coli, 1~2 part Glycerol, 1~2 part of polyethylene glycol, 30~50 parts of water are placed in No. 6 beakers, and No. 6 beakers are then placed in digital display and are tested the speed constant temperature magnetic force In blender, under the conditions of temperature is 32 DEG C, constant temperature is stirred 40~60min to get mixed bacteria liquid；By sodium alginate and water 1:50~1:100 in mass ratio is placed in No. 7 beakers, and stirs 10~20min with glass bar, after mixing stands 3~5h of swelling, Then No. 7 beakers are placed in digital display to test the speed in constant temperature blender with magnetic force, are 90~95 DEG C in temperature, revolving speed is 400~600r/ Under the conditions of min, heating stirring dissolves 40~60min, and 0.02~0.03 times of sodium alginate quality is then added into No. 7 beakers Sodium metaperiodate is 90~95 DEG C in temperature, and under the conditions of revolving speed is 400~600r/min, heating stirring reacts 40~60min, connects 2~3 times of sodium alginate quality of carbon nanotube is added into No. 7 beakers, then be added dropwise into No. 7 beakers mass fraction be 20~ 30% ammonium hydroxide adjusts pH to 8.6~8.9, in temperature be 90~95 DEG C, under the conditions of revolving speed is 400~600r/min, heating stirring 40~60min is reacted to get modified sodium alginate liquid；(N- amidino groups) dodecylacrylamide is pressed with polyethyleneglycol derivative Mass ratio 1:1~2:1 is placed in No. 8 beakers, and 0.1~0.2 times of polyethyleneglycol derivative quality of pair is added into No. 8 beakers Dichloro-benzenes and 0.07~0.10 times of polyethyleneglycol derivative quality of ferrocene stir under the conditions of revolving speed is 300~500r/min 30~50min of mixing is mixed to get modification liquid；According to parts by weight, by 40~60 parts of pretreating sludges, 10~20 parts of pre- places Kaolin is managed, 8~10 parts of pretreatment potassium feldspars, 20~30 parts of pretreatments are quartzy, and 10~20 parts of modified graphene oxides are placed in No. 4 Mixing and ball milling in ball mill crosses the sieve of 140 mesh, obtains mixed-powder；According to parts by weight, by 40~60 parts of mixed-powders, 10~ 20 parts of modified meerschaums, 10~20 parts of mixed bacteria liquids, 20~30 parts of modified sodium alginate liquid, 10~20 parts of mass fractions are 8~ 10% iron nitrate solution, 5~8 parts of Fluorinses, 20~30 parts of water are placed in batch mixer, in revolving speed be 200~300r/min item Under part, it is stirred 40~60min, the ammonium hydroxide adjusting pH to 8.3 that then dropwise addition mass fraction is 20~30% into batch mixer~ 8.6, mixed slurry is obtained, then discarded machine oil is sprayed to die surface, then injects mixed slurry in mold, then by mold It is placed in refrigerator, is freezed under the conditions of being -1~-5 DEG C in temperature, then in melting under room temperature, such Frozen-thawed cycled 5~8 times Afterwards, it demoulds, obtains adobe, then adobe is placed in baking oven, it is dry to constant weight under the conditions of temperature is 105~110 DEG C, it obtains dry Dry adobe；Dry brick is placed in sintering furnace, and argon gas is filled with into furnace with 60~90mL/min rate, in temperature be 650 Under the conditions of~750 DEG C, after carbonizing 1~2h, 1450~1500 DEG C are warming up to the heating rate of 10~15 DEG C/min, high-temperature process After 2~3h, it is down to room temperature with furnace, obtains single treatment adobe；Single treatment adobe is placed in reaction kettle, then into reaction kettle It is passed through high-temperature water vapor, under the conditions of temperature is 260~280 DEG C, after handling 40~60min, material must be handled, then expect processing It is placed in baking oven, under the conditions of temperature is 105~110 DEG C, drying is to constant weight to get secondary treatment adobe；By secondary treatment brick Base is soaked in modification liquid, after being then passed through 1~2h of carbon dioxide into modification liquid, is taken out, is obtained immersion adobe, connect Will impregnate adobe and be placed in baking oven, under the conditions of temperature is 105~110 DEG C, it is dry to constant weight to get magnetic porous ceramics. The organic acid is formed by tartaric acid and malic acid 1:3~1:5 mixed preparing in mass ratio.The rubber powder is gummi arabicum pulveratum It is formed with peach gum powder 1:2~1:3 mixed preparing in mass ratio.The plants essential oil is by Schisandra chinensis essential oil and feverfew essential oil by matter Amount is formed than 1:2~1:3 mixed preparing.The polyethyleneglycol derivative is novel Y-shaped polyethylene glycol, multi-arm polyethylene glycol or first Any one in oxygroup polyethylene glycol.

According to parts by weight, by 30 parts of municipal sludges, 30 parts of flocculation sludges, 0.3 part of protease, 0.3 part of lipase, 80 parts Water is placed in No. 1 beaker, and No. 1 beaker is then placed in digital display and is tested the speed in constant temperature blender with magnetic force, is 30 DEG C in temperature, revolving speed is Under the conditions of 200r/min, constant temperature is stirred processing 60min, and the hydroxide that mass fraction is 30% is then added into No. 1 beaker Sodium solution, in revolving speed be 600r/min under the conditions of, be stirred to react 60min, then in No. 1 beaker be added glacial acetic acid adjust pH to 7.6, under the conditions of revolving speed is 800r/min, 60min is stirred to get pretreating sludge；According to parts by weight, by 60 parts of height Ridge soil, 30 parts of organic acids, 5 parts of gutter oils, 5 parts of rubber powders, 80 parts of water are placed in mixing and ball milling 60min in No. 1 ball mill, obtain No. 1 ball Abrasive material, then No. 1 ball milling material is placed in single-necked flask, and the ammonium hydroxide that mass fraction is 30% is then added into single-necked flask and adjusts PH to 7.1 is stirred 60min under the conditions of revolving speed is 600r/min, obtains mixing and ball milling homogenate, then that mixing and ball milling is even Slurry is placed in Rotary Evaporators, is 70 DEG C in temperature, under the conditions of pressure is 800Pa, after being evaporated under reduced pressure 60min, homogenate must be concentrated, Then concentration homogenate is placed in baking oven, under the conditions of temperature is 110 DEG C, drying to constant weight is to get pretreatment kaolin；By weight Number meter is measured, by 30 parts of potassium feldspars, 3 parts of flyash, 5 parts of silicon ashes, 3 parts of serpentines, 3 parts of volcanic ash are placed in No. 2 ball mills mixed Close ball milling, cross 120 mesh sieve, obtain No. 2 ball milling material, then No. 2 ball milling material be placed in Muffle furnace, in temperature be 750 DEG C of conditions Under, after calcining 3h, it is down to room temperature with furnace, obtains pretreatment potassium feldspar；Chitosan and water 1:100 in mass ratio are placed in No. 2 beakers In, and 20min is stirred with glass bar, after standing swelling 5h, No. 2 beakers are placed in digital display and are tested the speed in constant temperature blender with magnetic force, in Temperature is 95 DEG C, and under the conditions of revolving speed is 600r/min, heating stirring dissolves 60min, obtains chitosan liquid, according to parts by weight, will 50 parts of quartz, 3 parts of diamond dust, 60 parts of chitosan liquid are placed in No. 3 beakers, under the conditions of revolving speed is 600r/min, are stirred Chitosan liquid 0.2 times of terephthalaldehyde of product is then added in 60min into No. 3 beakers, in revolving speed be 600r/min condition Under, it is stirred 60min, mixed gel is obtained, then mixed gel is placed in baking oven, it is dry under the conditions of temperature is 110 DEG C To constant weight, desiccant gel is obtained, will then be crushed in desiccant gel pulverizer, obtain crushed material, crushed material is then placed in No. 3 ball millings Ball milling in machine obtains No. 3 ball milling material, and then No. 3 ball milling material are placed in Muffle furnace, under the conditions of temperature is 750 DEG C, calcines 3h Afterwards, room temperature is down to get pretreatment quartz with furnace；Graphene oxide and water 1:30 in mass ratio are placed in No. 4 beakers, and will No. 4 beakers are placed in ultrasonic disperse instrument, under the conditions of supersonic frequency is 75kHz, ultrasonic disperse 60min, then into No. 4 beakers The ammonium hydroxide that mass fraction is 30% is added dropwise and adjusts pH to 10.1, obtains Pretreatment Mixed Liauid, Chinese ephedra fiber is placed in powder in pulverizer It is broken, the sieve of 80 mesh is crossed, Chinese ephedra fiber powder is obtained, according to parts by weight, 30 parts of Chinese ephedra fiber powder, 10 parts of cellulases, 60 parts of water set In No. 5 beakers, it is 35 DEG C in temperature, under the conditions of revolving speed is 500r/min, after stirring constant temperature processing 60min, is warming up to 95 DEG C Enzyme deactivation 30min obtains Chinese ephedra fiber mixed liquor, and Pretreatment Mixed Liauid and Chinese ephedra fiber mixed liquor 1:10 in mass ratio are placed in vortex 10min is shaken in oscillator, mixed serum is obtained, then filters mixed serum, obtains filter residue, is then washed filter residue with deionized water It washs 5 times, then the filter residue after washing is placed in baking oven, under the conditions of temperature is 110 DEG C, drying to constant weight is to get modified oxygen Graphite alkene；According to parts by weight, by 30 parts of sepiolites, 5 parts of carbomers, 5 parts of plants essential oils, 2 parts of biogas slurries, 2 portions of sucrose, 60 parts Water mixing is placed in No. 1 fermentation cauldron, is 35 DEG C in temperature, under the conditions of revolving speed is 500r/min, is stirred fermentation 60min, connects Into No. 1 fermentation cauldron be added mass fraction be 30% ammonium hydroxide adjust pH to 8.3, in revolving speed be 600r/min under the conditions of, stirring After mixing 60min, filtering obtains filter cake, then filter cake is placed in baking oven, under the conditions of temperature is 110 DEG C, drying to constant weight, Dry cake is obtained, then dry cake is placed in sintering furnace, and nitrogen is filled with into furnace with 90mL/min rate, is in temperature Under the conditions of 900 DEG C, after high-temperature process 2h, room temperature is down to get modified meerschaum with furnace；According to parts by weight, by 2 parts of Pasteur's buds Spore bacillus, 2 parts of Escherichia coli, 2 parts of glycerol, 2 parts of polyethylene glycol, 50 parts of water are placed in No. 6 beakers, are then placed in No. 6 beakers Digital display tests the speed in constant temperature blender with magnetic force, and under the conditions of temperature is 32 DEG C, constant temperature is stirred 60min to get mixed bacteria liquid；It will Sodium alginate and water 1:100 in mass ratio are placed in No. 7 beakers, and stir 20min with glass bar, after mixing stands swelling 5h, Then No. 7 beakers digital display is placed in test the speed in constant temperature blender with magnetic force, in temperature be 95 DEG C, under the conditions of revolving speed is 600r/min, Heating stirring dissolves 60min, and 0.03 times of sodium alginate quality of sodium metaperiodate is then added into No. 7 beakers, in temperature be 95 DEG C, under the conditions of revolving speed is 600r/min, heating stirring reacts 60min, and 3 times of sodium alginate quality are then added into No. 7 beakers Carbon nanotube, then into No. 7 beakers be added dropwise mass fraction be 30% ammonium hydroxide adjust pH to 8.9, in temperature be 95 DEG C, revolving speed Under the conditions of 600r/min, heating stirring reacts 60min to get modified sodium alginate liquid；By (N- amidino groups) dodecyl propylene Amide and polyethyleneglycol derivative 2:1 in mass ratio are placed in No. 8 beakers, and polyethyleneglycol derivative is added into No. 8 beakers The paracide and 0.10 times of polyethyleneglycol derivative quality of ferrocene that 0.2 times of quality, under the conditions of revolving speed is 500r/min, 50min is stirred to get modification liquid；According to parts by weight, by 60 parts of pretreating sludges, 20 parts of pretreatment kaolin, 10 parts of pretreatment potassium feldspars, 30 parts of pretreatment quartz, 20 parts of modified graphene oxides are placed in mixing and ball milling in No. 4 ball mills, mistake The sieve of 140 mesh, obtains mixed-powder；According to parts by weight, by 60 parts of mixed-powders, 20 parts of modified meerschaums, 20 parts of mixed bacteria liquids, 30 parts of modified sodium alginate liquid, 20 parts of mass fractions are 10% iron nitrate solution, 8 parts of Fluorinses, and 30 parts of water are placed in batch mixer In, under the conditions of revolving speed is 300r/min, it is stirred 60min, the ammonium hydroxide that mass fraction is 30% is then added dropwise into batch mixer PH to 8.6 is adjusted, mixed slurry is obtained, then discarded machine oil is sprayed to die surface, then mixed slurry is injected in mold, is connect Mold is placed in refrigerator, freezed under the conditions of being -5 DEG C in temperature, then in melting under room temperature, such Frozen-thawed cycled 8 After secondary, demoulding obtains adobe, then adobe is placed in baking oven, dry to constant weight under the conditions of temperature is 110 DEG C, obtains dry brick Base；Dry brick is placed in sintering furnace, and argon gas is filled with into furnace with 90mL/min rate, under the conditions of temperature is 750 DEG C, After carbonizing 2h, 1500 DEG C are warming up to the heating rate of 15 DEG C/min, after high-temperature process 3h, room temperature is down to furnace, obtains and once locate Manage adobe；Single treatment adobe is placed in reaction kettle, high-temperature water vapor is then passed through into reaction kettle, in temperature be 280 DEG C Under the conditions of, after handling 60min, material must be handled, then processing material is placed in baking oven, under the conditions of temperature is 110 DEG C, drying is extremely Constant weight is to get secondary treatment adobe；Secondary treatment adobe is soaked in modification liquid, is then passed through into modification liquid It after carbon dioxide 2h, takes out, obtains immersion adobe, will then impregnate adobe and be placed in baking oven, under the conditions of temperature is 110 DEG C, do It is dry to constant weight to get magnetic porous ceramics.The organic acid be by tartaric acid and malic acid 1:5 mixed preparing in mass ratio and At.The rubber powder is that gummi arabicum pulveratum is formed with peach gum powder 1:3 mixed preparing in mass ratio.The plants essential oil is by Schisandra chinensis Essential oil and feverfew essential oil 1:3 mixed preparing in mass ratio form.The polyethyleneglycol derivative is novel Y-shaped polyethylene glycol.

According to parts by weight, by 30 parts of municipal sludges, 30 parts of flocculation sludges, 0.3 part of protease, 0.3 part of lipase, 80 parts Water is placed in No. 1 beaker, and No. 1 beaker is then placed in digital display and is tested the speed in constant temperature blender with magnetic force, is 30 DEG C in temperature, revolving speed is Under the conditions of 200r/min, constant temperature is stirred processing 60min, and the hydroxide that mass fraction is 30% is then added into No. 1 beaker Sodium solution, in revolving speed be 600r/min under the conditions of, be stirred to react 60min, then in No. 1 beaker be added glacial acetic acid adjust pH to 7.6, under the conditions of revolving speed is 800r/min, 60min is stirred to get pretreating sludge；According to parts by weight, by 60 parts of height Ridge soil, 30 parts of organic acids, 5 parts of gutter oils, 5 parts of rubber powders, 80 parts of water are placed in mixing and ball milling 60min in No. 1 ball mill, obtain No. 1 ball Abrasive material, then No. 1 ball milling material is placed in single-necked flask, and the ammonium hydroxide that mass fraction is 30% is then added into single-necked flask and adjusts PH to 7.1 is stirred 60min under the conditions of revolving speed is 600r/min, obtains mixing and ball milling homogenate, then that mixing and ball milling is even Slurry is placed in Rotary Evaporators, is 70 DEG C in temperature, under the conditions of pressure is 800Pa, after being evaporated under reduced pressure 60min, homogenate must be concentrated, Then concentration homogenate is placed in baking oven, under the conditions of temperature is 110 DEG C, drying to constant weight is to get pretreatment kaolin；By weight Number meter is measured, by 30 parts of potassium feldspars, 3 parts of flyash, 5 parts of silicon ashes, 3 parts of serpentines, 3 parts of volcanic ash are placed in No. 2 ball mills mixed Close ball milling, cross 120 mesh sieve, obtain No. 2 ball milling material, then No. 2 ball milling material be placed in Muffle furnace, in temperature be 750 DEG C of conditions Under, after calcining 3h, it is down to room temperature with furnace, obtains pretreatment potassium feldspar；Chitosan and water 1:100 in mass ratio are placed in No. 2 beakers In, and 20min is stirred with glass bar, after standing swelling 5h, No. 2 beakers are placed in digital display and are tested the speed in constant temperature blender with magnetic force, in Temperature is 95 DEG C, and under the conditions of revolving speed is 600r/min, heating stirring dissolves 60min, obtains chitosan liquid, according to parts by weight, will 50 parts of quartz, 3 parts of diamond dust, 60 parts of chitosan liquid are placed in No. 3 beakers, under the conditions of revolving speed is 600r/min, are stirred Chitosan liquid 0.2 times of terephthalaldehyde of product is then added in 60min into No. 3 beakers, in revolving speed be 600r/min condition Under, it is stirred 60min, mixed gel is obtained, then mixed gel is placed in baking oven, it is dry under the conditions of temperature is 110 DEG C To constant weight, desiccant gel is obtained, will then be crushed in desiccant gel pulverizer, obtain crushed material, crushed material is then placed in No. 3 ball millings Ball milling in machine obtains No. 3 ball milling material, and then No. 3 ball milling material are placed in Muffle furnace, under the conditions of temperature is 750 DEG C, calcines 3h Afterwards, room temperature is down to get pretreatment quartz with furnace；According to parts by weight, by 30 parts of sepiolites, 5 parts of carbomers, 5 parts of plant essences Oil, 2 parts of biogas slurries, 2 portions of sucrose, 60 parts of water mixing are placed in No. 1 fermentation cauldron, are 35 DEG C in temperature, revolving speed is 500r/min condition Under, be stirred fermentation 60min, then into No. 1 fermentation cauldron be added mass fraction be 30% ammonium hydroxide adjust pH to 8.3, in turn Under the conditions of speed is 600r/min, after being stirred 60min, filtering obtains filter cake, then filter cake is placed in baking oven, is in temperature It is dry to constant weight under the conditions of 110 DEG C, dry cake is obtained, then dry cake is placed in sintering furnace, and with 90mL/min rate It is filled with nitrogen into furnace, under the conditions of temperature is 900 DEG C, after high-temperature process 2h, is down to room temperature with furnace to get modified meerschaum； According to parts by weight, by 2 parts of Bacillus pasteuriis, 2 parts of Escherichia coli, 2 parts of glycerol, 2 parts of polyethylene glycol, 50 parts of water are placed in No. 6 In beaker, No. 6 beakers are then placed in digital display and are tested the speed in constant temperature blender with magnetic force, under the conditions of temperature is 32 DEG C, constant temperature stirring 60min is mixed to get mixed bacteria liquid；Sodium alginate and water 1:100 in mass ratio are placed in No. 7 beakers, and stirred with glass bar Mix 20min, after mixing stands swelling 5h, No. 7 beakers be then placed in digital display and are tested the speed in constant temperature blender with magnetic force, in temperature be 95 DEG C, under the conditions of revolving speed is 600r/min, heating stirring dissolves 60min, and sodium alginate quality 0.03 is then added into No. 7 beakers Sodium metaperiodate again is 95 DEG C in temperature, and under the conditions of revolving speed is 600r/min, heating stirring reacts 60min, then burns to No. 7 3 times of sodium alginate quality of carbon nanotube is added in cup, then the ammonium hydroxide that mass fraction is 30% is added dropwise into No. 7 beakers and adjusts pH It is 95 DEG C in temperature, under the conditions of revolving speed is 600r/min, heating stirring reacts 60min to get modified sodium alginate liquid to 8.9； (N- amidino groups) dodecylacrylamide and polyethyleneglycol derivative 2:1 in mass ratio are placed in No. 8 beakers, and burnt to No. 8 0.2 times of polyethyleneglycol derivative quality of paracide and 0.10 times of polyethyleneglycol derivative quality of ferrocene are added in cup, Under the conditions of revolving speed is 500r/min, 50min is stirred to get modification liquid；According to parts by weight, 60 parts are pre-processed Sludge, 20 parts of pretreatment kaolin, 10 parts of pretreatment potassium feldspars, 30 parts of pretreatment quartz, 20 parts of graphene oxides are placed in No. 4 balls Mixing and ball milling in grinding machine crosses the sieve of 140 mesh, obtains mixed-powder；According to parts by weight, by 60 parts of mixed-powders, 20 parts of modified seas Afrodite, 20 parts of mixed bacteria liquids, 30 parts of modified sodium alginate liquid, 20 parts of mass fractions are 10% iron nitrate solution, and 8 parts of sodium fluorides are molten Liquid, 30 parts of water are placed in batch mixer, under the conditions of revolving speed is 300r/min, is stirred 60min, is then added dropwise into batch mixer The ammonium hydroxide that mass fraction is 30% adjusts pH to 8.6, obtains mixed slurry, then sprays discarded machine oil to die surface, will then mix It closes in slurry injection mold, then mold is placed in refrigerator, freezed under the conditions of being -5 DEG C in temperature, then under room temperature Melting, after such Frozen-thawed cycled 8 times, demoulding obtains adobe, then adobe is placed in baking oven, under the conditions of temperature is 110 DEG C, Drying obtains dry brick to constant weight；Dry brick is placed in sintering furnace, and argon gas is filled with into furnace with 90mL/min rate, Under the conditions of temperature is 750 DEG C, after carbonizing 2h, 1500 DEG C are warming up to the heating rate of 15 DEG C/min, after high-temperature process 3h, with Furnace is down to room temperature, obtains single treatment adobe；Single treatment adobe is placed in reaction kettle, high-temperature water is then passed through into reaction kettle Steam after handling 60min, must handle material under the conditions of temperature is 280 DEG C, and then processing material is placed in baking oven, is in temperature Under the conditions of 110 DEG C, drying is to constant weight to get secondary treatment adobe；Secondary treatment adobe is soaked in modification liquid, then It after being passed through carbon dioxide 2h into modification liquid, takes out, obtains immersion adobe, will then impregnate adobe and be placed in baking oven, Yu Wen Under the conditions of degree is 110 DEG C, drying is to constant weight to get magnetic porous ceramics.The organic acid is by tartaric acid and malic acid by matter Amount is formed than 1:5 mixed preparing.The rubber powder is that gummi arabicum pulveratum is formed with peach gum powder 1:3 mixed preparing in mass ratio.It is described Plants essential oil is formed by Schisandra chinensis essential oil and feverfew essential oil 1:3 mixed preparing in mass ratio.The polyethyleneglycol derivative is Novel Y-shaped polyethylene glycol.

According to parts by weight, by 30 parts of municipal sludges, 30 parts of flocculation sludges, 0.3 part of protease, 0.3 part of lipase, 80 parts Water is placed in No. 1 beaker, and No. 1 beaker is then placed in digital display and is tested the speed in constant temperature blender with magnetic force, is 30 DEG C in temperature, revolving speed is Under the conditions of 200r/min, constant temperature is stirred processing 60min, and the hydroxide that mass fraction is 30% is then added into No. 1 beaker Sodium solution, in revolving speed be 600r/min under the conditions of, be stirred to react 60min, then in No. 1 beaker be added glacial acetic acid adjust pH to 7.6, under the conditions of revolving speed is 800r/min, 60min is stirred to get pretreating sludge；According to parts by weight, by 60 parts of height Ridge soil, 30 parts of organic acids, 5 parts of gutter oils, 5 parts of rubber powders, 80 parts of water are placed in mixing and ball milling 60min in No. 1 ball mill, obtain No. 1 ball Abrasive material, then No. 1 ball milling material is placed in single-necked flask, and the ammonium hydroxide that mass fraction is 30% is then added into single-necked flask and adjusts PH to 7.1 is stirred 60min under the conditions of revolving speed is 600r/min, obtains mixing and ball milling homogenate, then that mixing and ball milling is even Slurry is placed in Rotary Evaporators, is 70 DEG C in temperature, under the conditions of pressure is 800Pa, after being evaporated under reduced pressure 60min, homogenate must be concentrated, Then concentration homogenate is placed in baking oven, under the conditions of temperature is 110 DEG C, drying to constant weight is to get pretreatment kaolin；By weight Number meter is measured, by 30 parts of potassium feldspars, 3 parts of flyash, 5 parts of silicon ashes, 3 parts of serpentines, 3 parts of volcanic ash are placed in No. 2 ball mills mixed Close ball milling, cross 120 mesh sieve, obtain No. 2 ball milling material, then No. 2 ball milling material be placed in Muffle furnace, in temperature be 750 DEG C of conditions Under, after calcining 3h, it is down to room temperature with furnace, obtains pretreatment potassium feldspar；Chitosan and water 1:100 in mass ratio are placed in No. 2 beakers In, and 20min is stirred with glass bar, after standing swelling 5h, No. 2 beakers are placed in digital display and are tested the speed in constant temperature blender with magnetic force, in Temperature is 95 DEG C, and under the conditions of revolving speed is 600r/min, heating stirring dissolves 60min, obtains chitosan liquid, according to parts by weight, will 50 parts of quartz, 3 parts of diamond dust, 60 parts of chitosan liquid are placed in No. 3 beakers, under the conditions of revolving speed is 600r/min, are stirred Chitosan liquid 0.2 times of terephthalaldehyde of product is then added in 60min into No. 3 beakers, in revolving speed be 600r/min condition Under, it is stirred 60min, mixed gel is obtained, then mixed gel is placed in baking oven, it is dry under the conditions of temperature is 110 DEG C To constant weight, desiccant gel is obtained, will then be crushed in desiccant gel pulverizer, obtain crushed material, crushed material is then placed in No. 3 ball millings Ball milling in machine obtains No. 3 ball milling material, and then No. 3 ball milling material are placed in Muffle furnace, under the conditions of temperature is 750 DEG C, calcines 3h Afterwards, room temperature is down to get pretreatment quartz with furnace；Graphene oxide and water 1:30 in mass ratio are placed in No. 4 beakers, and will No. 4 beakers are placed in ultrasonic disperse instrument, under the conditions of supersonic frequency is 75kHz, ultrasonic disperse 60min, then into No. 4 beakers The ammonium hydroxide that mass fraction is 30% is added dropwise and adjusts pH to 10.1, obtains Pretreatment Mixed Liauid, Chinese ephedra fiber is placed in powder in pulverizer It is broken, the sieve of 80 mesh is crossed, Chinese ephedra fiber powder is obtained, according to parts by weight, 30 parts of Chinese ephedra fiber powder, 10 parts of cellulases, 60 parts of water set In No. 5 beakers, it is 35 DEG C in temperature, under the conditions of revolving speed is 500r/min, after stirring constant temperature processing 60min, is warming up to 95 DEG C Enzyme deactivation 30min obtains Chinese ephedra fiber mixed liquor, and Pretreatment Mixed Liauid and Chinese ephedra fiber mixed liquor 1:10 in mass ratio are placed in vortex 10min is shaken in oscillator, mixed serum is obtained, then filters mixed serum, obtains filter residue, is then washed filter residue with deionized water It washs 5 times, then the filter residue after washing is placed in baking oven, under the conditions of temperature is 110 DEG C, drying to constant weight is to get modified oxygen Graphite alkene；According to parts by weight, by 2 parts of Bacillus pasteuriis, 2 parts of Escherichia coli, 2 parts of glycerol, 2 parts of polyethylene glycol, 50 parts Water is placed in No. 6 beakers, and No. 6 beakers are then placed in digital display and are tested the speed in constant temperature blender with magnetic force, under the conditions of temperature is 32 DEG C, Constant temperature is stirred 60min to get mixed bacteria liquid；Sodium alginate and water 1:100 in mass ratio are placed in No. 7 beakers, are used in combination Glass bar stirs 20min, after mixing stands swelling 5h, No. 7 beakers is then placed in digital display and are tested the speed in constant temperature blender with magnetic force, in Temperature is 95 DEG C, and under the conditions of revolving speed is 600r/min, heating stirring dissolves 60min, and sodium alginate then is added into No. 7 beakers The sodium metaperiodate that 0.03 times of quality is 95 DEG C in temperature, and under the conditions of revolving speed is 600r/min, heating stirring reacts 60min, then 3 times of sodium alginate quality of carbon nanotube is added into No. 7 beakers, then the ammonium hydroxide that mass fraction is 30% is added dropwise into No. 7 beakers PH to 8.9 is adjusted, is 95 DEG C in temperature, under the conditions of revolving speed is 600r/min, heating stirring reacts 60min to get modified seaweed Sour sodium liquid；(N- amidino groups) dodecylacrylamide and polyethyleneglycol derivative 2:1 in mass ratio are placed in No. 8 beakers, and Be added into No. 8 beakers 0.2 times of polyethyleneglycol derivative quality paracide and 0.10 times of polyethyleneglycol derivative quality Ferrocene is stirred 50min under the conditions of revolving speed is 500r/min to get modification liquid；According to parts by weight, by 60 Part pretreating sludge, 20 parts of pretreatment kaolin, 10 parts of pretreatment potassium feldspars, 30 parts of pretreatments quartz, 20 parts of modified oxidized stones Black alkene is placed in mixing and ball milling in No. 4 ball mills, crosses the sieve of 140 mesh, obtains mixed-powder；According to parts by weight, by 60 parts of mixed powders End, 20 parts of mixed bacteria liquids, 30 parts of modified sodium alginate liquid, 20 parts of mass fractions are 10% iron nitrate solution, 8 parts of Fluorinses, 30 parts of water are placed in batch mixer, under the conditions of revolving speed is 300r/min, is stirred 60min, matter is then added dropwise into batch mixer It measures the ammonium hydroxide that score is 30% and adjusts pH to 8.6, obtain mixed slurry, then spray discarded machine oil to die surface, it then will mixing Slurry injects in mold, and then mold is placed in refrigerator, freezes under the conditions of being -5 DEG C in temperature, then in melting under room temperature Change, after such Frozen-thawed cycled 8 times, demoulding obtains adobe, then adobe is placed in baking oven, under the conditions of temperature is 110 DEG C, does It is dry to constant weight, obtain dry brick；Dry brick is placed in sintering furnace, and argon gas is filled with into furnace with 90mL/min rate, in Under the conditions of temperature is 750 DEG C, after carbonizing 2h, 1500 DEG C are warming up to the heating rate of 15 DEG C/min, after high-temperature process 3h, with furnace It is down to room temperature, obtains single treatment adobe；Single treatment adobe is placed in reaction kettle, high-temperature water steaming is then passed through into reaction kettle Vapour after handling 60min, must handle material under the conditions of temperature is 280 DEG C, and then processing material is placed in baking oven, is in temperature Under the conditions of 110 DEG C, drying is to constant weight to get secondary treatment adobe；Secondary treatment adobe is soaked in modification liquid, then It after being passed through carbon dioxide 2h into modification liquid, takes out, obtains immersion adobe, will then impregnate adobe and be placed in baking oven, Yu Wen Under the conditions of degree is 110 DEG C, drying is to constant weight to get magnetic porous ceramics.The organic acid is by tartaric acid and malic acid by matter Amount is formed than 1:5 mixed preparing.The rubber powder is that gummi arabicum pulveratum is formed with peach gum powder 1:3 mixed preparing in mass ratio.It is described Plants essential oil is formed by Schisandra chinensis essential oil and feverfew essential oil 1:3 mixed preparing in mass ratio.The polyethyleneglycol derivative is Novel Y-shaped polyethylene glycol.

According to parts by weight, by 30 parts of municipal sludges, 30 parts of flocculation sludges, 0.3 part of protease, 0.3 part of lipase, 80 parts Water is placed in No. 1 beaker, and No. 1 beaker is then placed in digital display and is tested the speed in constant temperature blender with magnetic force, is 30 DEG C in temperature, revolving speed is Under the conditions of 200r/min, constant temperature is stirred processing 60min, and the hydroxide that mass fraction is 30% is then added into No. 1 beaker Sodium solution, in revolving speed be 600r/min under the conditions of, be stirred to react 60min, then in No. 1 beaker be added glacial acetic acid adjust pH to 7.6, under the conditions of revolving speed is 800r/min, 60min is stirred to get pretreating sludge；According to parts by weight, by 60 parts of height Ridge soil, 30 parts of organic acids, 5 parts of gutter oils, 5 parts of rubber powders, 80 parts of water are placed in mixing and ball milling 60min in No. 1 ball mill, obtain No. 1 ball Abrasive material, then No. 1 ball milling material is placed in single-necked flask, and the ammonium hydroxide that mass fraction is 30% is then added into single-necked flask and adjusts PH to 7.1 is stirred 60min under the conditions of revolving speed is 600r/min, obtains mixing and ball milling homogenate, then that mixing and ball milling is even Slurry is placed in Rotary Evaporators, is 70 DEG C in temperature, under the conditions of pressure is 800Pa, after being evaporated under reduced pressure 60min, homogenate must be concentrated, Then concentration homogenate is placed in baking oven, under the conditions of temperature is 110 DEG C, drying to constant weight is to get pretreatment kaolin；By weight Number meter is measured, by 30 parts of potassium feldspars, 3 parts of flyash, 5 parts of silicon ashes, 3 parts of serpentines, 3 parts of volcanic ash are placed in No. 2 ball mills mixed Close ball milling, cross 120 mesh sieve, obtain No. 2 ball milling material, then No. 2 ball milling material be placed in Muffle furnace, in temperature be 750 DEG C of conditions Under, after calcining 3h, it is down to room temperature with furnace, obtains pretreatment potassium feldspar；Chitosan and water 1:100 in mass ratio are placed in No. 2 beakers In, and 20min is stirred with glass bar, after standing swelling 5h, No. 2 beakers are placed in digital display and are tested the speed in constant temperature blender with magnetic force, in Temperature is 95 DEG C, and under the conditions of revolving speed is 600r/min, heating stirring dissolves 60min, obtains chitosan liquid, according to parts by weight, will 50 parts of quartz, 3 parts of diamond dust, 60 parts of chitosan liquid are placed in No. 3 beakers, under the conditions of revolving speed is 600r/min, are stirred Chitosan liquid 0.2 times of terephthalaldehyde of product is then added in 60min into No. 3 beakers, in revolving speed be 600r/min condition Under, it is stirred 60min, mixed gel is obtained, then mixed gel is placed in baking oven, it is dry under the conditions of temperature is 110 DEG C To constant weight, desiccant gel is obtained, will then be crushed in desiccant gel pulverizer, obtain crushed material, crushed material is then placed in No. 3 ball millings Ball milling in machine obtains No. 3 ball milling material, and then No. 3 ball milling material are placed in Muffle furnace, under the conditions of temperature is 750 DEG C, calcines 3h Afterwards, room temperature is down to get pretreatment quartz with furnace；Graphene oxide and water 1:30 in mass ratio are placed in No. 4 beakers, and will No. 4 beakers are placed in ultrasonic disperse instrument, under the conditions of supersonic frequency is 75kHz, ultrasonic disperse 60min, then into No. 4 beakers The ammonium hydroxide that mass fraction is 30% is added dropwise and adjusts pH to 10.1, obtains Pretreatment Mixed Liauid, Chinese ephedra fiber is placed in powder in pulverizer It is broken, the sieve of 80 mesh is crossed, Chinese ephedra fiber powder is obtained, according to parts by weight, 30 parts of Chinese ephedra fiber powder, 10 parts of cellulases, 60 parts of water set In No. 5 beakers, it is 35 DEG C in temperature, under the conditions of revolving speed is 500r/min, after stirring constant temperature processing 60min, is warming up to 95 DEG C Enzyme deactivation 30min obtains Chinese ephedra fiber mixed liquor, and Pretreatment Mixed Liauid and Chinese ephedra fiber mixed liquor 1:10 in mass ratio are placed in vortex 10min is shaken in oscillator, mixed serum is obtained, then filters mixed serum, obtains filter residue, is then washed filter residue with deionized water It washs 5 times, then the filter residue after washing is placed in baking oven, under the conditions of temperature is 110 DEG C, drying to constant weight is to get modified oxygen Graphite alkene；According to parts by weight, by 30 parts of sepiolites, 5 parts of carbomers, 5 parts of plants essential oils, 2 parts of biogas slurries, 2 portions of sucrose, 60 parts Water mixing is placed in No. 1 fermentation cauldron, is 35 DEG C in temperature, under the conditions of revolving speed is 500r/min, is stirred fermentation 60min, connects Into No. 1 fermentation cauldron be added mass fraction be 30% ammonium hydroxide adjust pH to 8.3, in revolving speed be 600r/min under the conditions of, stirring After mixing 60min, filtering obtains filter cake, then filter cake is placed in baking oven, under the conditions of temperature is 110 DEG C, drying to constant weight, Dry cake is obtained, then dry cake is placed in sintering furnace, and nitrogen is filled with into furnace with 90mL/min rate, is in temperature Under the conditions of 900 DEG C, after high-temperature process 2h, room temperature is down to get modified meerschaum with furnace；By sodium alginate and water in mass ratio 1: 100 are placed in No. 7 beakers, and stir 20min with glass bar, after mixing stands swelling 5h, No. 7 beakers are then placed in digital display and are surveyed In fast constant temperature blender with magnetic force, in temperature be 95 DEG C, revolving speed be 600r/min under the conditions of, heating stirring dissolve 60min, then to 0.03 times of sodium alginate quality of sodium metaperiodate is added in No. 7 beakers, in temperature be 95 DEG C, under the conditions of revolving speed is 600r/min, Heating stirring reacts 60min, 3 times of sodium alginate quality of carbon nanotube is then added into No. 7 beakers, then into No. 7 beakers Be added dropwise mass fraction be 30% ammonium hydroxide adjust pH to 8.9, in temperature be 95 DEG C, revolving speed be 600r/min under the conditions of, heating stirring 60min is reacted to get modified sodium alginate liquid；(N- amidino groups) dodecylacrylamide and polyethyleneglycol derivative are pressed into quality It is placed in No. 8 beakers than 2:1, and 0.2 times of polyethyleneglycol derivative quality of paracide and poly- second two is added into No. 8 beakers The ferrocene that 0.10 times of 01 derivatives quality is stirred 50min under the conditions of revolving speed is 500r/min to get modification Liquid；According to parts by weight, by 60 parts of pretreating sludges, 20 parts of pretreatment kaolin, 10 parts of pretreatment potassium feldspars, 30 parts of pretreatments Quartz, 20 parts of modified graphene oxides are placed in mixing and ball milling in No. 4 ball mills, cross the sieve of 140 mesh, obtain mixed-powder；By weight Number meter, by 60 parts of mixed-powders, 20 parts of modified meerschaums, 30 parts of modified sodium alginate liquid, 20 parts of mass fractions are 10% nitric acid Ferrous solution, 8 parts of Fluorinses, 30 parts of water are placed in batch mixer, under the conditions of revolving speed is 300r/min, are stirred 60min, Then the ammonium hydroxide that mass fraction is 30% is added dropwise into batch mixer and adjusts pH to 8.6, obtains mixed slurry, is then sprayed to die surface Spill discarded machine oil, then by mixed slurry inject mold in, then mold is placed in refrigerator, in temperature be -5 DEG C under the conditions of it is cold Freeze, then in melting under room temperature, after such Frozen-thawed cycled 8 times, demoulding obtains adobe, then adobe is placed in baking oven, in It is dry to constant weight under the conditions of temperature is 110 DEG C, obtain dry brick；Dry brick is placed in sintering furnace, and with 90mL/min speed Rate is filled with argon gas into furnace, under the conditions of temperature is 750 DEG C, after carbonizing 2h, is warming up to 1500 with the heating rate of 15 DEG C/min DEG C, after high-temperature process 3h, it is down to room temperature with furnace, obtains single treatment adobe；Single treatment adobe is placed in reaction kettle, then to It is passed through high-temperature water vapor in reaction kettle, under the conditions of temperature is 280 DEG C, after handling 60min, material must be handled, then expect processing It is placed in baking oven, under the conditions of temperature is 110 DEG C, drying is to constant weight to get secondary treatment adobe；Secondary treatment adobe is impregnated It in modification liquid, after being then passed through carbon dioxide 2h into modification liquid, takes out, obtains immersion adobe, will then impregnate Adobe is placed in baking oven, and under the conditions of temperature is 110 DEG C, drying is to constant weight to get magnetic porous ceramics.The organic acid be by Tartaric acid is formed with malic acid 1:5 mixed preparing in mass ratio.The rubber powder is gummi arabicum pulveratum and peach gum powder 1:3 in mass ratio Mixed preparing forms.The plants essential oil is formed by Schisandra chinensis essential oil and feverfew essential oil 1:3 mixed preparing in mass ratio.It is described Polyethyleneglycol derivative is novel Y-shaped polyethylene glycol.

According to parts by weight, by 30 parts of municipal sludges, 30 parts of flocculation sludges, 0.3 part of protease, 0.3 part of lipase, 80 parts Water is placed in No. 1 beaker, and No. 1 beaker is then placed in digital display and is tested the speed in constant temperature blender with magnetic force, is 30 DEG C in temperature, revolving speed is Under the conditions of 200r/min, constant temperature is stirred processing 60min, and the hydroxide that mass fraction is 30% is then added into No. 1 beaker Sodium solution, in revolving speed be 600r/min under the conditions of, be stirred to react 60min, then in No. 1 beaker be added glacial acetic acid adjust pH to 7.6, under the conditions of revolving speed is 800r/min, 60min is stirred to get pretreating sludge；According to parts by weight, by 60 parts of height Ridge soil, 30 parts of organic acids, 5 parts of gutter oils, 5 parts of rubber powders, 80 parts of water are placed in mixing and ball milling 60min in No. 1 ball mill, obtain No. 1 ball Abrasive material, then No. 1 ball milling material is placed in single-necked flask, and the ammonium hydroxide that mass fraction is 30% is then added into single-necked flask and adjusts PH to 7.1 is stirred 60min under the conditions of revolving speed is 600r/min, obtains mixing and ball milling homogenate, then that mixing and ball milling is even Slurry is placed in Rotary Evaporators, is 70 DEG C in temperature, under the conditions of pressure is 800Pa, after being evaporated under reduced pressure 60min, homogenate must be concentrated, Then concentration homogenate is placed in baking oven, under the conditions of temperature is 110 DEG C, drying to constant weight is to get pretreatment kaolin；By weight Number meter is measured, by 30 parts of potassium feldspars, 3 parts of flyash, 5 parts of silicon ashes, 3 parts of serpentines, 3 parts of volcanic ash are placed in No. 2 ball mills mixed Close ball milling, cross 120 mesh sieve, obtain No. 2 ball milling material, then No. 2 ball milling material be placed in Muffle furnace, in temperature be 750 DEG C of conditions Under, after calcining 3h, it is down to room temperature with furnace, obtains pretreatment potassium feldspar；Chitosan and water 1:100 in mass ratio are placed in No. 2 beakers In, and 20min is stirred with glass bar, after standing swelling 5h, No. 2 beakers are placed in digital display and are tested the speed in constant temperature blender with magnetic force, in Temperature is 95 DEG C, and under the conditions of revolving speed is 600r/min, heating stirring dissolves 60min, obtains chitosan liquid, according to parts by weight, will 50 parts of quartz, 3 parts of diamond dust, 60 parts of chitosan liquid are placed in No. 3 beakers, under the conditions of revolving speed is 600r/min, are stirred Chitosan liquid 0.2 times of terephthalaldehyde of product is then added in 60min into No. 3 beakers, in revolving speed be 600r/min condition Under, it is stirred 60min, mixed gel is obtained, then mixed gel is placed in baking oven, it is dry under the conditions of temperature is 110 DEG C To constant weight, desiccant gel is obtained, will then be crushed in desiccant gel pulverizer, obtain crushed material, crushed material is then placed in No. 3 ball millings Ball milling in machine obtains No. 3 ball milling material, and then No. 3 ball milling material are placed in Muffle furnace, under the conditions of temperature is 750 DEG C, calcines 3h Afterwards, room temperature is down to get pretreatment quartz with furnace；Graphene oxide and water 1:30 in mass ratio are placed in No. 4 beakers, and will No. 4 beakers are placed in ultrasonic disperse instrument, under the conditions of supersonic frequency is 75kHz, ultrasonic disperse 60min, then into No. 4 beakers The ammonium hydroxide that mass fraction is 30% is added dropwise and adjusts pH to 10.1, obtains Pretreatment Mixed Liauid, Chinese ephedra fiber is placed in powder in pulverizer It is broken, the sieve of 80 mesh is crossed, Chinese ephedra fiber powder is obtained, according to parts by weight, 30 parts of Chinese ephedra fiber powder, 10 parts of cellulases, 60 parts of water set In No. 5 beakers, it is 35 DEG C in temperature, under the conditions of revolving speed is 500r/min, after stirring constant temperature processing 60min, is warming up to 95 DEG C Enzyme deactivation 30min obtains Chinese ephedra fiber mixed liquor, and Pretreatment Mixed Liauid and Chinese ephedra fiber mixed liquor 1:10 in mass ratio are placed in vortex 10min is shaken in oscillator, mixed serum is obtained, then filters mixed serum, obtains filter residue, is then washed filter residue with deionized water It washs 5 times, then the filter residue after washing is placed in baking oven, under the conditions of temperature is 110 DEG C, drying to constant weight is to get modified oxygen Graphite alkene；According to parts by weight, by 30 parts of sepiolites, 5 parts of carbomers, 5 parts of plants essential oils, 2 parts of biogas slurries, 2 portions of sucrose, 60 parts Water mixing is placed in No. 1 fermentation cauldron, is 35 DEG C in temperature, under the conditions of revolving speed is 500r/min, is stirred fermentation 60min, connects Into No. 1 fermentation cauldron be added mass fraction be 30% ammonium hydroxide adjust pH to 8.3, in revolving speed be 600r/min under the conditions of, stirring After mixing 60min, filtering obtains filter cake, then filter cake is placed in baking oven, under the conditions of temperature is 110 DEG C, drying to constant weight, Dry cake is obtained, then dry cake is placed in sintering furnace, and nitrogen is filled with into furnace with 90mL/min rate, is in temperature Under the conditions of 900 DEG C, after high-temperature process 2h, room temperature is down to get modified meerschaum with furnace；According to parts by weight, by 2 parts of Pasteur's buds Spore bacillus, 2 parts of Escherichia coli, 2 parts of glycerol, 2 parts of polyethylene glycol, 50 parts of water are placed in No. 6 beakers, are then placed in No. 6 beakers Digital display tests the speed in constant temperature blender with magnetic force, and under the conditions of temperature is 32 DEG C, constant temperature is stirred 60min to get mixed bacteria liquid；It will (N- amidino groups) dodecylacrylamide and polyethyleneglycol derivative 2:1 in mass ratio are placed in No. 8 beakers, and to No. 8 beakers 0.2 times of polyethyleneglycol derivative quality of paracide of middle addition and 0.10 times of polyethyleneglycol derivative quality of ferrocene, in Under the conditions of revolving speed is 500r/min, 50min is stirred to get modification liquid；According to parts by weight, 60 parts of pretreatments are dirty Mud, 20 parts of pretreatment kaolin, 10 parts of pretreatment potassium feldspars, 30 parts of pretreatment quartz, 20 parts of modified graphene oxides are placed in No. 4 Mixing and ball milling in ball mill crosses the sieve of 140 mesh, obtains mixed-powder；According to parts by weight, by 60 parts of mixed-powders, 20 parts of modifications Sepiolite, 20 parts of mixed bacteria liquids, 20 parts of mass fractions are 10% iron nitrate solution, 8 parts of Fluorinses, and 30 parts of water are placed in mixing In machine, under the conditions of revolving speed is 300r/min, it is stirred 60min, the ammonia that mass fraction is 30% is then added dropwise into batch mixer Water adjusts pH to 8.6, obtains mixed slurry, then sprays discarded machine oil to die surface, then injects mixed slurry in mold, Then mold is placed in refrigerator, is freezed under the conditions of being -5 DEG C in temperature, then in melting under room temperature, such Frozen-thawed cycled After 8 times, demoulding obtains adobe, then adobe is placed in baking oven, dry to constant weight under the conditions of temperature is 110 DEG C, obtains drying Adobe；Dry brick is placed in sintering furnace, and argon gas is filled with into furnace with 90mL/min rate, in temperature be 750 DEG C of conditions Under, after carbonizing 2h, 1500 DEG C are warming up to the heating rate of 15 DEG C/min, after high-temperature process 3h, room temperature is down to furnace, obtains once Handle adobe；Single treatment adobe is placed in reaction kettle, high-temperature water vapor is then passed through into reaction kettle, in temperature be 280 Under the conditions of DEG C, after handling 60min, material must be handled, then processing material is placed in baking oven, it is dry under the conditions of temperature is 110 DEG C To constant weight to get secondary treatment adobe；Secondary treatment adobe is soaked in modification liquid, is then led into modification liquid It after entering carbon dioxide 2h, takes out, obtains immersion adobe, will then impregnate adobe and be placed in baking oven, under the conditions of temperature is 110 DEG C, Drying is to constant weight to get magnetic porous ceramics.The organic acid be by tartaric acid and malic acid 1:5 mixed preparing in mass ratio and At.The rubber powder is that gummi arabicum pulveratum is formed with peach gum powder 1:3 mixed preparing in mass ratio.The plants essential oil is by Schisandra chinensis Essential oil and feverfew essential oil 1:3 mixed preparing in mass ratio form.The polyethyleneglycol derivative is novel Y-shaped polyethylene glycol.

According to parts by weight, by 30 parts of municipal sludges, 30 parts of flocculation sludges, 0.3 part of protease, 0.3 part of lipase, 80 parts Water is placed in No. 1 beaker, and No. 1 beaker is then placed in digital display and is tested the speed in constant temperature blender with magnetic force, is 30 DEG C in temperature, revolving speed is Under the conditions of 200r/min, constant temperature is stirred processing 60min, and the hydroxide that mass fraction is 30% is then added into No. 1 beaker Sodium solution, in revolving speed be 600r/min under the conditions of, be stirred to react 60min, then in No. 1 beaker be added glacial acetic acid adjust pH to 7.6, under the conditions of revolving speed is 800r/min, 60min is stirred to get pretreating sludge；According to parts by weight, by 60 parts of height Ridge soil, 30 parts of organic acids, 5 parts of gutter oils, 5 parts of rubber powders, 80 parts of water are placed in mixing and ball milling 60min in No. 1 ball mill, obtain No. 1 ball Abrasive material, then No. 1 ball milling material is placed in single-necked flask, and the ammonium hydroxide that mass fraction is 30% is then added into single-necked flask and adjusts PH to 7.1 is stirred 60min under the conditions of revolving speed is 600r/min, obtains mixing and ball milling homogenate, then that mixing and ball milling is even Slurry is placed in Rotary Evaporators, is 70 DEG C in temperature, under the conditions of pressure is 800Pa, after being evaporated under reduced pressure 60min, homogenate must be concentrated, Then concentration homogenate is placed in baking oven, under the conditions of temperature is 110 DEG C, drying to constant weight is to get pretreatment kaolin；By weight Number meter is measured, by 30 parts of potassium feldspars, 3 parts of flyash, 5 parts of silicon ashes, 3 parts of serpentines, 3 parts of volcanic ash are placed in No. 2 ball mills mixed Close ball milling, cross 120 mesh sieve, obtain No. 2 ball milling material, then No. 2 ball milling material be placed in Muffle furnace, in temperature be 750 DEG C of conditions Under, after calcining 3h, it is down to room temperature with furnace, obtains pretreatment potassium feldspar；Chitosan and water 1:100 in mass ratio are placed in No. 2 beakers In, and 20min is stirred with glass bar, after standing swelling 5h, No. 2 beakers are placed in digital display and are tested the speed in constant temperature blender with magnetic force, in Temperature is 95 DEG C, and under the conditions of revolving speed is 600r/min, heating stirring dissolves 60min, obtains chitosan liquid, according to parts by weight, will 50 parts of quartz, 3 parts of diamond dust, 60 parts of chitosan liquid are placed in No. 3 beakers, under the conditions of revolving speed is 600r/min, are stirred Chitosan liquid 0.2 times of terephthalaldehyde of product is then added in 60min into No. 3 beakers, in revolving speed be 600r/min condition Under, it is stirred 60min, mixed gel is obtained, then mixed gel is placed in baking oven, it is dry under the conditions of temperature is 110 DEG C To constant weight, desiccant gel is obtained, will then be crushed in desiccant gel pulverizer, obtain crushed material, crushed material is then placed in No. 3 ball millings Ball milling in machine obtains No. 3 ball milling material, and then No. 3 ball milling material are placed in Muffle furnace, under the conditions of temperature is 750 DEG C, calcines 3h Afterwards, room temperature is down to get pretreatment quartz with furnace；Graphene oxide and water 1:30 in mass ratio are placed in No. 4 beakers, and will No. 4 beakers are placed in ultrasonic disperse instrument, under the conditions of supersonic frequency is 75kHz, ultrasonic disperse 60min, then into No. 4 beakers The ammonium hydroxide that mass fraction is 30% is added dropwise and adjusts pH to 10.1, obtains Pretreatment Mixed Liauid, Chinese ephedra fiber is placed in powder in pulverizer It is broken, the sieve of 80 mesh is crossed, Chinese ephedra fiber powder is obtained, according to parts by weight, 30 parts of Chinese ephedra fiber powder, 10 parts of cellulases, 60 parts of water set In No. 5 beakers, it is 35 DEG C in temperature, under the conditions of revolving speed is 500r/min, after stirring constant temperature processing 60min, is warming up to 95 DEG C Enzyme deactivation 30min obtains Chinese ephedra fiber mixed liquor, and Pretreatment Mixed Liauid and Chinese ephedra fiber mixed liquor 1:10 in mass ratio are placed in vortex 10min is shaken in oscillator, mixed serum is obtained, then filters mixed serum, obtains filter residue, is then washed filter residue with deionized water It washs 5 times, then the filter residue after washing is placed in baking oven, under the conditions of temperature is 110 DEG C, drying to constant weight is to get modified oxygen Graphite alkene；According to parts by weight, by 30 parts of sepiolites, 5 parts of carbomers, 5 parts of plants essential oils, 2 parts of biogas slurries, 2 portions of sucrose, 60 parts Water mixing is placed in No. 1 fermentation cauldron, is 35 DEG C in temperature, under the conditions of revolving speed is 500r/min, is stirred fermentation 60min, connects Into No. 1 fermentation cauldron be added mass fraction be 30% ammonium hydroxide adjust pH to 8.3, in revolving speed be 600r/min under the conditions of, stirring After mixing 60min, filtering obtains filter cake, then filter cake is placed in baking oven, under the conditions of temperature is 110 DEG C, drying to constant weight, Dry cake is obtained, then dry cake is placed in sintering furnace, and nitrogen is filled with into furnace with 90mL/min rate, is in temperature Under the conditions of 900 DEG C, after high-temperature process 2h, room temperature is down to get modified meerschaum with furnace；According to parts by weight, by 2 parts of Pasteur's buds Spore bacillus, 2 parts of Escherichia coli, 2 parts of glycerol, 2 parts of polyethylene glycol, 50 parts of water are placed in No. 6 beakers, are then placed in No. 6 beakers Digital display tests the speed in constant temperature blender with magnetic force, and under the conditions of temperature is 32 DEG C, constant temperature is stirred 60min to get mixed bacteria liquid；It will Sodium alginate and water 1:100 in mass ratio are placed in No. 7 beakers, and stir 20min with glass bar, after mixing stands swelling 5h, Then No. 7 beakers digital display is placed in test the speed in constant temperature blender with magnetic force, in temperature be 95 DEG C, under the conditions of revolving speed is 600r/min, Heating stirring dissolves 60min, and 0.03 times of sodium alginate quality of sodium metaperiodate is then added into No. 7 beakers, in temperature be 95 DEG C, under the conditions of revolving speed is 600r/min, heating stirring reacts 60min, and 3 times of sodium alginate quality are then added into No. 7 beakers Carbon nanotube, then into No. 7 beakers be added dropwise mass fraction be 30% ammonium hydroxide adjust pH to 8.9, in temperature be 95 DEG C, revolving speed Under the conditions of 600r/min, heating stirring reacts 60min to get modified sodium alginate liquid；By (N- amidino groups) dodecyl propylene Amide and polyethyleneglycol derivative 2:1 in mass ratio are placed in No. 8 beakers, and polyethyleneglycol derivative is added into No. 8 beakers The paracide and 0.10 times of polyethyleneglycol derivative quality of ferrocene that 0.2 times of quality, under the conditions of revolving speed is 500r/min, 50min is stirred to get modification liquid；According to parts by weight, by 60 parts of pretreating sludges, 20 parts of pretreatment kaolin, 10 parts of pretreatment potassium feldspars, 30 parts of pretreatment quartz, 20 parts of modified graphene oxides are placed in mixing and ball milling in No. 4 ball mills, mistake The sieve of 140 mesh, obtains mixed-powder；According to parts by weight, by 60 parts of mixed-powders, 20 parts of modified meerschaums, 20 parts of mixed bacteria liquids, 30 parts of modified sodium alginate liquid, 30 parts of water are placed in batch mixer, under the conditions of revolving speed is 300r/min, is stirred 60min, is connect Into batch mixer be added dropwise mass fraction be 30% ammonium hydroxide adjust pH to 8.6, obtain mixed slurry, then to die surface spray Mixed slurry is then injected in mold, then mold is placed in refrigerator by discarded machine oil, in temperature be under the conditions of -5 DEG C it is cold Freeze, then in melting under room temperature, after such Frozen-thawed cycled 8 times, demoulding obtains adobe, then adobe is placed in baking oven, in It is dry to constant weight under the conditions of temperature is 110 DEG C, obtain dry brick；Dry brick is placed in sintering furnace, and with 90mL/min speed Rate is filled with argon gas into furnace, under the conditions of temperature is 750 DEG C, after carbonizing 2h, is warming up to 1500 with the heating rate of 15 DEG C/min DEG C, after high-temperature process 3h, it is down to room temperature with furnace, obtains single treatment adobe；Single treatment adobe is soaked in modification liquid, Then it after being passed through carbon dioxide 2h into modification liquid, takes out, obtains immersion adobe, will then impregnate adobe and be placed in baking oven, Under the conditions of temperature is 110 DEG C, drying is to constant weight to get magnetic porous ceramics.The organic acid is by tartaric acid and malic acid 1:5 mixed preparing in mass ratio forms.The rubber powder is that gummi arabicum pulveratum is formed with peach gum powder 1:3 mixed preparing in mass ratio. The plants essential oil is formed by Schisandra chinensis essential oil and feverfew essential oil 1:3 mixed preparing in mass ratio.The polyethylene glycol is derivative Object is novel Y-shaped polyethylene glycol.

According to parts by weight, by 30 parts of municipal sludges, 30 parts of flocculation sludges, 0.3 part of protease, 0.3 part of lipase, 80 parts Water is placed in No. 1 beaker, and No. 1 beaker is then placed in digital display and is tested the speed in constant temperature blender with magnetic force, is 30 DEG C in temperature, revolving speed is Under the conditions of 200r/min, constant temperature is stirred processing 60min, and the hydroxide that mass fraction is 30% is then added into No. 1 beaker Sodium solution, in revolving speed be 600r/min under the conditions of, be stirred to react 60min, then in No. 1 beaker be added glacial acetic acid adjust pH to 7.6, under the conditions of revolving speed is 800r/min, 60min is stirred to get pretreating sludge；According to parts by weight, by 60 parts of height Ridge soil, 30 parts of organic acids, 5 parts of gutter oils, 5 parts of rubber powders, 80 parts of water are placed in mixing and ball milling 60min in No. 1 ball mill, obtain No. 1 ball Abrasive material, then No. 1 ball milling material is placed in single-necked flask, and the ammonium hydroxide that mass fraction is 30% is then added into single-necked flask and adjusts PH to 7.1 is stirred 60min under the conditions of revolving speed is 600r/min, obtains mixing and ball milling homogenate, then that mixing and ball milling is even Slurry is placed in Rotary Evaporators, is 70 DEG C in temperature, under the conditions of pressure is 800Pa, after being evaporated under reduced pressure 60min, homogenate must be concentrated, Then concentration homogenate is placed in baking oven, under the conditions of temperature is 110 DEG C, drying to constant weight is to get pretreatment kaolin；By weight Number meter is measured, by 30 parts of potassium feldspars, 3 parts of flyash, 5 parts of silicon ashes, 3 parts of serpentines, 3 parts of volcanic ash are placed in No. 2 ball mills mixed Close ball milling, cross 120 mesh sieve, obtain No. 2 ball milling material, then No. 2 ball milling material be placed in Muffle furnace, in temperature be 750 DEG C of conditions Under, after calcining 3h, it is down to room temperature with furnace, obtains pretreatment potassium feldspar；Chitosan and water 1:100 in mass ratio are placed in No. 2 beakers In, and 20min is stirred with glass bar, after standing swelling 5h, No. 2 beakers are placed in digital display and are tested the speed in constant temperature blender with magnetic force, in Temperature is 95 DEG C, and under the conditions of revolving speed is 600r/min, heating stirring dissolves 60min, obtains chitosan liquid, according to parts by weight, will 50 parts of quartz, 3 parts of diamond dust, 60 parts of chitosan liquid are placed in No. 3 beakers, under the conditions of revolving speed is 600r/min, are stirred Chitosan liquid 0.2 times of terephthalaldehyde of product is then added in 60min into No. 3 beakers, in revolving speed be 600r/min condition Under, it is stirred 60min, mixed gel is obtained, then mixed gel is placed in baking oven, it is dry under the conditions of temperature is 110 DEG C To constant weight, desiccant gel is obtained, will then be crushed in desiccant gel pulverizer, obtain crushed material, crushed material is then placed in No. 3 ball millings Ball milling in machine obtains No. 3 ball milling material, and then No. 3 ball milling material are placed in Muffle furnace, under the conditions of temperature is 750 DEG C, calcines 3h Afterwards, room temperature is down to get pretreatment quartz with furnace；Graphene oxide and water 1:30 in mass ratio are placed in No. 4 beakers, and will No. 4 beakers are placed in ultrasonic disperse instrument, under the conditions of supersonic frequency is 75kHz, ultrasonic disperse 60min, then into No. 4 beakers The ammonium hydroxide that mass fraction is 30% is added dropwise and adjusts pH to 10.1, obtains Pretreatment Mixed Liauid, Chinese ephedra fiber is placed in powder in pulverizer It is broken, the sieve of 80 mesh is crossed, Chinese ephedra fiber powder is obtained, according to parts by weight, 30 parts of Chinese ephedra fiber powder, 10 parts of cellulases, 60 parts of water set In No. 5 beakers, it is 35 DEG C in temperature, under the conditions of revolving speed is 500r/min, after stirring constant temperature processing 60min, is warming up to 95 DEG C Enzyme deactivation 30min obtains Chinese ephedra fiber mixed liquor, and Pretreatment Mixed Liauid and Chinese ephedra fiber mixed liquor 1:10 in mass ratio are placed in vortex 10min is shaken in oscillator, mixed serum is obtained, then filters mixed serum, obtains filter residue, is then washed filter residue with deionized water It washs 5 times, then the filter residue after washing is placed in baking oven, under the conditions of temperature is 110 DEG C, drying to constant weight is to get modified oxygen Graphite alkene；According to parts by weight, by 30 parts of sepiolites, 5 parts of carbomers, 5 parts of plants essential oils, 2 parts of biogas slurries, 2 portions of sucrose, 60 parts Water mixing is placed in No. 1 fermentation cauldron, is 35 DEG C in temperature, under the conditions of revolving speed is 500r/min, is stirred fermentation 60min, connects Into No. 1 fermentation cauldron be added mass fraction be 30% ammonium hydroxide adjust pH to 8.3, in revolving speed be 600r/min under the conditions of, stirring After mixing 60min, filtering obtains filter cake, then filter cake is placed in baking oven, under the conditions of temperature is 110 DEG C, drying to constant weight, Dry cake is obtained, then dry cake is placed in sintering furnace, and nitrogen is filled with into furnace with 90mL/min rate, is in temperature Under the conditions of 900 DEG C, after high-temperature process 2h, room temperature is down to get modified meerschaum with furnace；According to parts by weight, by 2 parts of Pasteur's buds Spore bacillus, 2 parts of Escherichia coli, 2 parts of glycerol, 2 parts of polyethylene glycol, 50 parts of water are placed in No. 6 beakers, are then placed in No. 6 beakers Digital display tests the speed in constant temperature blender with magnetic force, and under the conditions of temperature is 32 DEG C, constant temperature is stirred 60min to get mixed bacteria liquid；It will Sodium alginate and water 1:100 in mass ratio are placed in No. 7 beakers, and stir 20min with glass bar, after mixing stands swelling 5h, Then No. 7 beakers digital display is placed in test the speed in constant temperature blender with magnetic force, in temperature be 95 DEG C, under the conditions of revolving speed is 600r/min, Heating stirring dissolves 60min, and 0.03 times of sodium alginate quality of sodium metaperiodate is then added into No. 7 beakers, in temperature be 95 DEG C, under the conditions of revolving speed is 600r/min, heating stirring reacts 60min, and 3 times of sodium alginate quality are then added into No. 7 beakers Carbon nanotube, then into No. 7 beakers be added dropwise mass fraction be 30% ammonium hydroxide adjust pH to 8.9, in temperature be 95 DEG C, revolving speed Under the conditions of 600r/min, heating stirring reacts 60min to get modified sodium alginate liquid；According to parts by weight, by 60 parts of pre- places Sludge is managed, 20 parts of pretreatment kaolin, 10 parts of pretreatment potassium feldspars, 30 parts of pretreatments are quartzy, and 20 parts of modified graphene oxides are set The mixing and ball milling in No. 4 ball mills crosses the sieve of 140 mesh, obtains mixed-powder；According to parts by weight, by 60 parts of mixed-powders, 20 parts Modified meerschaum, 20 parts of mixed bacteria liquids, 30 parts of modified sodium alginate liquid, 20 parts of mass fractions are 10% iron nitrate solution, 8 parts of fluorine Change sodium solution, 30 parts of water are placed in batch mixer, under the conditions of revolving speed is 300r/min, 60min are stirred, then to batch mixer It is middle that the ammonium hydroxide adjusting pH to 8.6 that mass fraction is 30% is added dropwise, mixed slurry is obtained, then discarded machine oil is sprayed to die surface, connects By mixed slurry inject mold in, then mold is placed in refrigerator, in temperature be -5 DEG C under the conditions of freeze, then in room temperature Under the conditions of melt, after such Frozen-thawed cycled 8 times, demoulding, obtain adobe, then adobe be placed in baking oven, in temperature be 110 DEG C of items It is dry to constant weight under part, obtain dry brick；Dry brick is placed in sintering furnace, and is filled with 90mL/min rate into furnace Argon gas after carbonizing 2h, is warming up to 1500 DEG C under the conditions of temperature is 750 DEG C with the heating rate of 15 DEG C/min, high-temperature process 3h Afterwards, it is down to room temperature with furnace, obtains single treatment adobe；Single treatment adobe is placed in reaction kettle, is then passed through into reaction kettle High-temperature water vapor after handling 60min, must handle material under the conditions of temperature is 280 DEG C, and then processing material is placed in baking oven, in Under the conditions of temperature is 110 DEG C, drying is to constant weight to get magnetic porous ceramics.The organic acid be by tartaric acid and malic acid by Mass ratio 1:5 mixed preparing forms.The rubber powder is that gummi arabicum pulveratum is formed with peach gum powder 1:3 mixed preparing in mass ratio.Institute Stating plants essential oil is formed by Schisandra chinensis essential oil and feverfew essential oil 1:3 mixed preparing in mass ratio.The polyethyleneglycol derivative For novel Y-shaped polyethylene glycol.

The magnetic porous ceramics of 1 to 7 gained of example are subjected to performance detection, the specific detection method is as follows:

The sample porosity is measured with static(al) weight method, and detects its compression strength.

The coking wastewater sample of same concentrations is taken, testing product is to the treatment effect of sewage, and COD is using potassium dichromate method survey Fixed, ammonia nitrogen is measured using Berthelot spectrophotometry.

Specific testing result is as shown in table 1:

Table 1: performance detection table

Detection content	Example 1	Example 2	Example 3	Example 4	Example 5	Example 6	Example 7
								Apparent porosity/%	66.7	59.8	58.1	60.3	61.6	55.6	59.2
Compression strength/MPa	3.8	1.7	2.1	2.0	1.8	2.5	2.3
								COD removal rate/%	95.4	88.3	90.5	87.5	89.4	88.4	91.48
Ammonia nitrogen removal frank/%	92.6	85.4	84.7	88.9	86.7	85.4	84.5

By 1 testing result of table it is found that the magnetic porous ceramics of present invention gained mechanical property while porosity is promoted also obtains It is promoted, and there is excellent wastewater treatment efficiency.

Claims (10)

1. a kind of preparation method of magnetic porous ceramics, it is characterised in that specific preparation process is as follows:

(1) according to parts by weight, by 40~60 parts of pretreating sludges, 10~20 parts of pretreatment kaolin, 8~10 parts of pretreatment potassium Feldspar, 20~30 parts of pretreatment quartz, 10~20 parts of modified graphene oxide mixing and ball millings, sieving obtain mixed-powder；

(2) according to parts by weight, by 40~60 parts of mixed-powders, 10~20 parts of modified meerschaums, 10~20 parts of mixed bacteria liquids, 20 ~30 parts of modified sodium alginate liquid, 10~20 parts of iron nitrate solutions, 5~8 parts of Fluorinses, 20~30 parts of water are stirred, Then ammonium hydroxide is added dropwise and adjusts pH to 8.3~8.6, injection molding, Frozen-thawed cycled is dry, obtains dry brick；

(3) dry brick is carbonized, is heated up step by step, high-temperature process obtains single treatment adobe；

(4) single treatment adobe is handled by high-temperature water vapor, it is dry to get secondary treatment adobe；

(5) secondary treatment adobe is soaked in modification liquid, is then passed through carbon dioxide, taken out, drying is more to get magnetism Hole ceramics.

2. a kind of preparation method of magnetic porous ceramics according to claim 1, it is characterised in that: step (1) the pre- place Manage the preparation process of sludge are as follows: according to parts by weight, by 20~30 parts of municipal sludges, 20~30 parts of flocculation sludges, 0.2~0.3 It is anti-to be subsequently added into sodium hydroxide solution stirring for part protease, 0.2~0.3 part of lipase, 60~80 parts of water termostat mixed processings It answers, glacial acetic acid is then added and adjusts pH to 7.3~7.6, is stirred to get pretreating sludge.

3. a kind of preparation method of magnetic porous ceramics according to claim 1, it is characterised in that: step (1) the pre- place Manage kaolinic treatment process are as follows: according to parts by weight, by 40~60 parts of kaolin, 20~30 parts of organic acids, 3~5 parts of trenches Oil, 3~5 parts of rubber powders, 60~80 parts of water mixing and ball millings are subsequently added into ammonium hydroxide and adjust pH to 6.8~7.1, are stirred, and decompression is steamed It evaporates, it is dry to get pretreatment kaolin；The organic acid is by tartaric acid and malic acid 1:3~1:5 mixed preparing in mass ratio It forms；The rubber powder is that gummi arabicum pulveratum is formed with peach gum powder 1:2~1:3 mixed preparing in mass ratio.

4. a kind of preparation method of magnetic porous ceramics according to claim 1, it is characterised in that: step (1) the pre- place Manage the preparation process of potassium feldspar are as follows: according to parts by weight, by 20~30 parts of potassium feldspars, 2~3 parts of flyash, 3~5 parts of silicon ashes, 2 ~3 parts of serpentines, 2~3 parts of volcanic ash mixing and ball millings are sieved, and calcining obtains pretreatment potassium feldspar.

5. a kind of preparation method of magnetic porous ceramics according to claim 1, it is characterised in that: step (1) the pre- place The treatment process of fibrous gypsum English are as follows: mix chitosan with water 1:50~1:100 in mass ratio, after standing swelling, heating stirring is molten Solution, obtains chitosan liquid, and according to parts by weight, by 30~50 parts of quartz, 2~3 parts of diamond dust, 40~60 parts of chitosan liquid stirrings are mixed It closes, is subsequently added into the terephthalaldehyde of 0.1~0.2 times of chitosan liquid product, is stirred, dry, pulverize, ball milling, calcining, i.e., Quartz must be pre-processed.

6. a kind of preparation method of magnetic porous ceramics according to claim 1, it is characterised in that: step (1) described modification The preparation process of graphene oxide are as follows: mix graphene oxide with water 1:20~1:30 in mass ratio, ultrasonic disperse then drips Add ammonium hydroxide to adjust pH to 9.8~10.1, obtain Pretreatment Mixed Liauid, Chinese ephedra fiber is crushed, crosses the sieve of 80 mesh, obtain Chinese ephedra fiber Powder, according to parts by weight, 20~30 parts of Chinese ephedra fiber powder, 8~10 parts of cellulases, the stirring constant temperature processing of 40~60 parts of water goes out Enzyme obtains Chinese ephedra fiber mixed liquor, and Pretreatment Mixed Liauid is mixed oscillation with Chinese ephedra fiber mixed liquor 1:5~1:10 in mass ratio, Filtering is washed, dry, i.e. modified graphene oxide.

7. a kind of preparation method of magnetic porous ceramics according to claim 1, it is characterised in that: step (2) described modification The preparation process of sepiolite are as follows: according to parts by weight, by 20~30 parts of sepiolites, 3~5 parts of carbomers, 3~5 parts of plants essential oils, 1~2 part of biogas slurry, 1~2 portion of sucrose, 40~60 parts of water mixed fermentations are subsequently added into ammonium hydroxide and adjust pH to 8.1~8.3, and stirring is mixed It closes, filters, dry, high-temperature process cools down to get modified meerschaum；The plants essential oil is by Schisandra chinensis essential oil and feverfew essence Oily 1:2~1:3 mixed preparing in mass ratio forms.

8. a kind of preparation method of magnetic porous ceramics according to claim 1, it is characterised in that: step (2) described mixing The preparation process of bacterium solution are as follows: according to parts by weight, by 1~2 part of Bacillus pasteurii, 1~2 part of Escherichia coli, 1~2 part of glycerol, 1~2 part of polyethylene glycol, 30~50 parts of water, constant temperature are stirred to get mixed bacteria liquid.

9. a kind of preparation method of magnetic porous ceramics according to claim 1, it is characterised in that: step (2) described modification The preparation process of sodium alginate solution are as follows: by sodium alginate and water 1:50~1:100 in mass ratio, after mixing stands swelling, heating Stirring and dissolving, is subsequently added into 0.02~0.03 times of sodium alginate quality of sodium metaperiodate, and heating stirring reaction is subsequently added into seaweed The carbon nanotube of 2~3 times of sour sodium quality, then ammonium hydroxide is added dropwise and adjusts pH to 8.6~8.9, heating stirring reaction is to get modified seaweed Sour sodium liquid.

10. a kind of preparation method of magnetic porous ceramics according to claim 1, it is characterised in that: step (5) described modification The preparation process for the treatment of fluid are as follows: by (N- amidino groups) dodecylacrylamide and polyethyleneglycol derivative 1:1~2:1 in mass ratio Mixing, and be added 0.1~0.2 times of polyethyleneglycol derivative quality paracide and polyethyleneglycol derivative quality 0.07~ 0.10 times of ferrocene is stirred to get modification liquid；The polyethyleneglycol derivative is novel Y-shaped polyethylene glycol, more Any one in arm polyethylene glycol or methoxy poly (ethylene glycol).