CN109849571A - The modified full information surface silica gel mould cadmia waste material of metal powder infuses solidification forming method - Google Patents
The modified full information surface silica gel mould cadmia waste material of metal powder infuses solidification forming method Download PDFInfo
- Publication number
- CN109849571A CN109849571A CN201811511043.0A CN201811511043A CN109849571A CN 109849571 A CN109849571 A CN 109849571A CN 201811511043 A CN201811511043 A CN 201811511043A CN 109849571 A CN109849571 A CN 109849571A
- Authority
- CN
- China
- Prior art keywords
- silica gel
- metal powder
- cadmia
- powder
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 86
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 70
- 239000002184 metal Substances 0.000 title claims abstract description 70
- 239000000741 silica gel Substances 0.000 title claims abstract description 63
- 229910002027 silica gel Inorganic materials 0.000 title claims abstract description 63
- 239000000843 powder Substances 0.000 title claims abstract description 56
- 238000007711 solidification Methods 0.000 title claims abstract description 42
- 230000008023 solidification Effects 0.000 title claims abstract description 42
- 239000002699 waste material Substances 0.000 title claims abstract description 31
- 238000000034 method Methods 0.000 title claims abstract description 10
- 229960001866 silicon dioxide Drugs 0.000 claims abstract description 62
- 238000002156 mixing Methods 0.000 claims abstract description 31
- 239000002002 slurry Substances 0.000 claims abstract description 22
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000003999 initiator Substances 0.000 claims abstract description 10
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003054 catalyst Substances 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- 239000003085 diluting agent Substances 0.000 claims abstract description 8
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims abstract description 7
- 235000015895 biscuits Nutrition 0.000 claims abstract description 7
- 238000002360 preparation method Methods 0.000 claims description 33
- 229910000906 Bronze Inorganic materials 0.000 claims description 23
- 239000010974 bronze Substances 0.000 claims description 23
- 239000000243 solution Substances 0.000 claims description 17
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 claims description 11
- 239000004927 clay Substances 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000000908 ammonium hydroxide Substances 0.000 claims description 5
- 238000000498 ball milling Methods 0.000 claims description 5
- 239000012153 distilled water Substances 0.000 claims description 5
- 229910052602 gypsum Inorganic materials 0.000 claims description 5
- 239000010440 gypsum Substances 0.000 claims description 5
- 238000002347 injection Methods 0.000 claims description 5
- 239000007924 injection Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- CQIOFKRONDXZJC-UHFFFAOYSA-N n-methylideneprop-2-enamide Chemical compound C=CC(=O)N=C CQIOFKRONDXZJC-UHFFFAOYSA-N 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 2
- 239000000178 monomer Substances 0.000 abstract description 3
- 238000006116 polymerization reaction Methods 0.000 abstract description 2
- 239000000377 silicon dioxide Substances 0.000 abstract description 2
- -1 bronze modified silica-gel Chemical class 0.000 description 12
- 238000011065 in-situ storage Methods 0.000 description 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- 230000003796 beauty Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 210000003850 cellular structure Anatomy 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000013139 quantization Methods 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Landscapes
- Dental Preparations (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The modified full information surface silica gel mould cadmia waste material of metal powder infuses solidification forming method, it is characterized in that, metal powder is added in silica gel and is stirred evenly, metal powder modified silica-gel is made, using the viscosity of silica gel diluent adjustment metal powder modified silica-gel, the additional curing agent of metal powder modified silica-gel is uniformly brushed after mixing evenly on silica gel mould surface, after cured, initiator is added in cadmia waste material note solidification forming slurry and catalyst is injected after mixing evenly in above-mentioned silica gel mould, after solidifying at a certain temperature, then demoulding, dry, repaired biscuit are burnt into.The electrochemical properties (or surface chemistry gesture characteristic) that the present invention changes Silica Surface by adding metal-powder make to infuse smooth opening under the action of initiator ammonium persulfate of C=C double bond in the organic monomer acrylamide molecules in solidification forming slurry and generate polymerization reaction, the solidification intensity of the billet surface after solidifying is made to be fully equivalent to the solidification intensity of metal die billet surface by adding metal powder modified silica-gel die surface, so that billet surface information is complete.
Description
Technical field
The present invention relates to a kind of modified full information surface silica gel mould cadmia waste materials of metal powder to infuse solidification forming method, belongs to pottery
Ceramic material preparation technical field.
Background technique
With the continuous improvement of living standards, people want the beautification of domestic environment, social public environment, ecosystem
Ask continuous improvement, and artist or artist's one works of every creation require to devote a tremendous amount of time, fund and energy, much
It can not meet pursuit of the people to beauty, therefore, being badly in need of a kind of method being capable of inexpensive massive duplication artist or artistical essence
U.S. works；
The each exquisite art work is all complete by intention figure and patterned surface texture, animal cuticle hair, concave-convex surface etc.
Information sides are expressed, and therefore, shape is extremely complex.It is in solution using soft silica gel mould and note solidification forming method in situ
State the best approach of problem；
Cadmia waste products have gas permeability, water penetration, free of contamination cellular structure, in domestic environment, megastore, enterprise
The places such as industry, park and street be arranged it is various with large-scale sculpture, clay sculpture and various designs of cadmia waste-material-preparing etc. not only
It beautifies the environment, and flowers and plants, the plant etc. of various colors can be grown in these large-scale sculpture, clay sculpture and designs,
Keep people pleasing, beautifies the environment to the utmost；
But research finds that the organic monomer acrylamide in situ infused in solidification forming slurry can generate on soft silica gel mould surface
Inhibition causes the ceramic slurry curing of surface 0.5 ~ 1mm depth incomplete, and billet surface can fall off when demoulding, will be great
The surface breakdown of expressive force.How to solve solidification forming pulp surface problem of solidification in situ of infusing becomes the key technology of the product.
Summary of the invention
The purpose of the present invention is to provide one kind can solve note solidification forming pulp surface solidification in situ, realizes the said goods batch
The modified full information surface silica gel mould cadmia waste material of the metal powder of quantization production infuses solidification forming method, technical solution are as follows:
The modified full information surface silica gel mould cadmia waste material of metal powder infuses solidification forming method, and it is equal that stirring in silica gel is added in metal powder
It is even, metal powder modified silica-gel is made, using the viscosity of silica gel diluent adjustment metal powder modified silica-gel, by metal powder modified silica-gel
Additional curing agent is uniformly brushed after mixing evenly on silica gel mould surface, and after cured, cadmia waste material note solidification forming slurry is added
Enter initiator and catalyst to inject after mixing evenly in above-mentioned silica gel mould, after solidifying at a certain temperature, demoulding, is repaired at drying
Then base is burnt into, wherein metal powder includes metal yttrium powder, metallic titanium powder, hafnium metal powfer, manganese powder, metal iron powder, metallic cobalt
Powder, metal nickel powder, copper powder, silver powder, metal bronze, metal zinc, metallic silicon power, the specific steps are as follows:
1, the preparation of metal powder modified silica-gel: the metal-powder for being 10 ~ 100 μm by granularity: silica gel with weight percent be 0.05 ~
Metal powder modified silica-gel is made after the ratio uniform mixing of 0.3:1, using the viscous of silica gel diluent adjustment metal powder modified silica-gel
Degree；
2, the preparation of full information surface silica gel mould: by the intention figure of artistic creation and patterned surface texture, animal cuticle hair
Gypsum or timber model is made by engraving in hair, concave-convex surface full information surface, then turns over and full information surface silica gel mould is made；
3, the preparation of the modified full information surface silica gel mould of metal powder: by metal powder modified silica-gel made from step (1) with weight
1 ~ 3% silica gel curing agent is added outside percentage, is uniformly applied to full information surface silica gel made from step (2) after mixing evenly
The modified full information surface silica gel mould of metal powder is made in the inner surface of mold after solidification；
4, the preparation of premixed solution: by acrylamide: N, N- methylene acrylamide are the ratio of 20:1 ~ 3 with weight percent
Uniformly mixing, then take 5 ~ 10 grams of the mixture to be dissolved in 100ml distilled water and premixed solution is made；
5, the preparation of cadmia powder: cadmia powder is made in the common clay of cadmia waste material additional 10 ~ 50% after mixing；
6, the preparation of cadmia waste material note solidification forming slurry: above-mentioned premixed solution 100ml is taken, 3 ~ 10ml ammonium hydroxide is added, adds dense
Degree is the cadmia powder warp that 30% 3 ~ 10ml of aqueous sodium polyacrylate is added that 200 ~ 500 gram particle degree are 3 ~ 200 μm after mixing
Cadmia waste material note solidification forming slurry is made after ball milling；
7, above-mentioned cadmia waste material note solidification forming slurry 100ml is taken, the initiator that 0.1 ~ 1ml concentration is 5% ammonium persulfate is added, then
The N, N, N of 0.1 ~ 1ml is added, N- entprol catalyst stirs evenly rapidly, the time less than 3 minutes, injection step immediately
(3) in the modified full information surface silica gel mould of the metal powder prepared in, after the curing be complete at 80 ~ 100 DEG C, demoulding, drying, so
Afterwards by the green body after drying after repaired biscuit 1050 ~ 1200 DEG C at a temperature of be fired into product within 30 ~ 120 minutes.
The present invention the advantage is that:
1, the electrochemical properties (or surface chemistry gesture characteristic) that the present invention changes Silica Surface by adding metal-powder make to infuse
C=C double bond in organic monomer acrylamide molecules in solidification forming slurry smooth opening under the action of initiator ammonium persulfate
Generate polymerization reaction；
2, by adding metal powder modified silica-gel die surface the solidification intensity of the billet surface after solidifying is fully equivalent to
The solidification intensity of metal die billet surface, so that billet surface information is complete.
Embodiment 1
1, the preparation of metal bronze modified silica-gel: the metallic gold powder for being 10 μm by granularity: silica gel is with weight percent for 0.05:
Metal bronze modified silica-gel is made after 1 ratio uniform mixing, additional 3% silica gel diluent adjustment metal bronze modified silica-gel
Viscosity；
2, the preparation of full information surface silica gel mould: by the intention figure of artistic creation and patterned surface texture, animal cuticle hair
Gypsum or timber model is made by engraving in hair, concave-convex surface full information surface, then turns over and full information surface silica gel mould is made；
3, the preparation of the modified full information surface silica gel mould of metal bronze: by metal bronze modified silica-gel made from step (1) with
1% silica gel curing agent is added outside weight percent, is uniformly applied to full information surface silicon made from step (2) after mixing evenly
The modified full information surface silica gel mould of metal bronze is made in the inner surface of sealing rubber die after solidification；
4, the preparation of premixed solution: by acrylamide: N, N- methylene acrylamide are equal for the ratio of 20:1 with weight percent
Even mixing, then take 5 grams of the mixture to be dissolved in 100ml distilled water and premixed solution is made；
5, the preparation of cadmia powder: cadmia powder is made in the common clay of cadmia waste material additional 10% after mixing；
6, the preparation of cadmia waste material note solidification forming slurry: above-mentioned premixed solution 100ml is taken, 3ml ammonium hydroxide is added, adding concentration is
30% aqueous sodium polyacrylate 3ml the cadmia powder that 200 gram particle degree are 3 μm is added after mixing, cadmia is made after ball milling
Waste material infuses solidification forming slurry；
7, above-mentioned cadmia waste material note solidification forming slurry 100ml is taken, 0.1ml concentration is added as the initiator of 5% ammonium persulfate, then plus
Enter the N of 0.1ml, N, N, N- entprol catalyst stirs evenly rapidly, the time less than 3 minutes, immediately in injection step (3)
In the modified full information surface silica gel mould of the metal bronze of preparation, after the curing be complete at 80 DEG C, then demoulding, drying will be done
Green body after dry after repaired biscuit 1050 DEG C at a temperature of be fired into product within 30 minutes.
Embodiment 2
1, the preparation of metal bronze modified silica-gel: the metallic gold powder for being 50 μm by granularity: silica gel is with weight percent for 0.15:
Metal bronze modified silica-gel is made after 1 ratio uniform mixing, additional 10% silica gel diluent adjustment metal bronze modified silica-gel
Viscosity；
2, the preparation of full information surface silica gel mould: by the intention figure of artistic creation and patterned surface texture, animal cuticle hair
Gypsum or timber model is made by engraving in hair, concave-convex surface full information surface, then turns over and full information surface silica gel mould is made；
3, the preparation of the modified full information surface silica gel mould of metal bronze: by metal bronze modified silica-gel made from step (1) with
2% silica gel curing agent is added outside weight percent, is uniformly applied to full information surface silicon made from step (2) after mixing evenly
The modified full information surface silica gel mould of metal bronze is made in the inner surface of sealing rubber die after solidification；
4, the preparation of premixed solution: by acrylamide: N, N- methylene acrylamide are equal for the ratio of 20:2 with weight percent
Even mixing, then take 8 grams of the mixture to be dissolved in 100ml distilled water and premixed solution is made；
5, the preparation of cadmia powder: cadmia powder is made in the common clay of cadmia waste material additional 30% after mixing；
6, the preparation of cadmia waste material note solidification forming slurry: above-mentioned premixed solution 100ml is taken, 7ml ammonium hydroxide is added, adding concentration is
30% aqueous sodium polyacrylate 7ml the cadmia powder that 350 gram particle degree are 100 μm is added after mixing, zinc is made after ball milling
Slag waste material infuses solidification forming slurry；
7, above-mentioned cadmia waste material note solidification forming slurry 100ml is taken, 0.5ml concentration is added as the initiator of 5% ammonium persulfate, then plus
Enter the N of 0.5ml, N, N, N- entprol catalyst stirs evenly rapidly, the time less than 3 minutes, immediately in injection step (3)
In the modified full information surface silica gel mould of the metal bronze of preparation, after the curing be complete at 90 DEG C, then demoulding, drying will be done
Green body after dry after repaired biscuit 1130 DEG C at a temperature of be fired into product within 90 minutes.
Embodiment 3
1, the preparation of metal bronze modified silica-gel: the metallic gold powder for being 100 μm by granularity: silica gel is with weight percent for 0.3:
Metal bronze modified silica-gel is made after 1 ratio uniform mixing, additional 17% silica gel diluent adjustment metal bronze modified silica-gel
Viscosity；
2, the preparation of full information surface silica gel mould: by the intention figure of artistic creation and patterned surface texture, animal cuticle hair
Gypsum or timber model is made by engraving in hair, concave-convex surface full information surface, then turns over and full information surface silica gel mould is made；
3, the preparation of the modified full information surface silica gel mould of metal bronze: by metal bronze modified silica-gel made from step (1) with
3% silica gel curing agent is added outside weight percent, is uniformly applied to full information surface silicon made from step (2) after mixing evenly
The modified full information surface silica gel mould of metal bronze is made in the inner surface of sealing rubber die after solidification；
4, the preparation of premixed solution: by acrylamide: N, N- methylene acrylamide are equal for the ratio of 20:3 with weight percent
Even mixing, then take 10 grams of the mixture to be dissolved in 100ml distilled water and premixed solution is made；
5, the preparation of cadmia powder: cadmia powder is made in the common clay of cadmia waste material additional 50% after mixing；
6, the preparation of cadmia waste material note solidification forming slurry: above-mentioned premixed solution 100ml is taken, 10ml ammonium hydroxide is added, adds concentration
The cadmia powder that 500 gram particle degree are 200 μm is added after mixing for 30% aqueous sodium polyacrylate 10ml to be made after ball milling
Cadmia waste material infuses solidification forming slurry；
7, above-mentioned cadmia waste material note solidification forming slurry 100ml is taken, the initiator that 1ml concentration is 5% ammonium persulfate is added, adds
The N of 1ml, N, N, N- entprol catalyst stir evenly rapidly, and the time less than 3 minutes, prepares in injection step (3) immediately
The modified full information surface silica gel mould of metal bronze in, it is after the curing be complete at 100 DEG C, demoulding, dry, then will it is dry after
Green body after repaired biscuit 1200 DEG C at a temperature of be fired into product within 120 minutes.
Claims (1)
1. the modified full information surface silica gel mould cadmia waste material of metal powder infuses solidification forming method, which is characterized in that by metal powder plus
Enter in silica gel and stir evenly, metal powder modified silica-gel is made, it, will using the viscosity of silica gel diluent adjustment metal powder modified silica-gel
The additional curing agent of metal powder modified silica-gel is uniformly brushed after mixing evenly on silica gel mould surface, after cured, by cadmia waste material
Initiator is added for note solidification forming slurry and catalyst is injected after mixing evenly in above-mentioned silica gel mould, solidifies at a certain temperature
Afterwards, it demoulds, is dry, then repaired biscuit is burnt into, wherein metal powder includes metal yttrium powder, metallic titanium powder, hafnium metal powfer, manganese powder,
Metal iron powder, metal cobalt powder, metallic nickel, copper powder, silver powder, metal bronze, metal zinc, metallic silicon power are specific to walk
It is rapid as follows:
(1) preparation of metal powder modified silica-gel: the metal-powder for being 10 ~ 100 μm by granularity: silica gel is with weight percent for 0.05
Metal powder modified silica-gel is made after the ratio uniform mixing of ~ 0.3:1, using the viscous of silica gel diluent adjustment metal powder modified silica-gel
Degree；
(2) preparation of full information surface silica gel mould: by the intention figure of artistic creation and patterned surface texture, animal cuticle hair
Gypsum or timber model is made by engraving in hair, concave-convex surface full information surface, then turns over and full information surface silica gel mould is made；
(3) preparation of the modified full information surface silica gel mould of metal powder: by metal powder modified silica-gel made from step (1) with weight
1 ~ 3% silica gel curing agent is added outside percentage, is uniformly applied to full information surface silica gel made from step (2) after mixing evenly
The modified full information surface silica gel mould of metal powder is made in the inner surface of mold after solidification；
(4) preparation of premixed solution: by acrylamide: N, N- methylene acrylamide are the ratio of 20:1 ~ 3 with weight percent
Uniformly mixing, then take 5 ~ 10 grams of the mixture to be dissolved in 100ml distilled water and premixed solution is made；
(5) preparation of cadmia powder: cadmia powder is made in the common clay of cadmia waste material additional 10 ~ 50% after mixing；
(6) preparation of cadmia waste material note solidification forming slurry: above-mentioned premixed solution 100ml is taken, 3 ~ 10ml ammonium hydroxide is added, adds dense
Degree is the cadmia powder warp that 30% 3 ~ 10ml of aqueous sodium polyacrylate is added that 200 ~ 500 gram particle degree are 3 ~ 200 μm after mixing
Cadmia waste material note solidification forming slurry is made after ball milling；
(7) above-mentioned cadmia waste material note solidification forming slurry 100ml is taken, the initiator that 0.1 ~ 1ml concentration is 5% ammonium persulfate is added, then
The N, N, N of 0.1 ~ 1ml is added, N- entprol catalyst stirs evenly rapidly, the time less than 3 minutes, injection step immediately
(3) in the modified full information surface silica gel mould of the metal powder prepared in, after the curing be complete at 80 ~ 100 DEG C, demoulding, drying, so
Afterwards by the green body after drying after repaired biscuit 1050 ~ 1200 DEG C at a temperature of be fired into product within 30 ~ 120 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811511043.0A CN109849571A (en) | 2018-12-11 | 2018-12-11 | The modified full information surface silica gel mould cadmia waste material of metal powder infuses solidification forming method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811511043.0A CN109849571A (en) | 2018-12-11 | 2018-12-11 | The modified full information surface silica gel mould cadmia waste material of metal powder infuses solidification forming method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109849571A true CN109849571A (en) | 2019-06-07 |
Family
ID=66891151
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811511043.0A Pending CN109849571A (en) | 2018-12-11 | 2018-12-11 | The modified full information surface silica gel mould cadmia waste material of metal powder infuses solidification forming method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109849571A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1120212A1 (en) * | 1998-08-14 | 2001-08-01 | Seagull Decor Co., Ltd. | A method of producing pottery ornament densely covered with tiny edges and corners |
| CN102787009A (en) * | 2012-08-17 | 2012-11-21 | 葛秀林 | Mould release agent for precision forging forming and preparation method of mould release agent |
| CN106747457A (en) * | 2017-01-13 | 2017-05-31 | 华南协同创新研究院 | A kind of preparation method of accurate SiC ceramic based on silica gel mould gel casting forming and its accurate SiC ceramic |
-
2018
- 2018-12-11 CN CN201811511043.0A patent/CN109849571A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1120212A1 (en) * | 1998-08-14 | 2001-08-01 | Seagull Decor Co., Ltd. | A method of producing pottery ornament densely covered with tiny edges and corners |
| CN102787009A (en) * | 2012-08-17 | 2012-11-21 | 葛秀林 | Mould release agent for precision forging forming and preparation method of mould release agent |
| CN106747457A (en) * | 2017-01-13 | 2017-05-31 | 华南协同创新研究院 | A kind of preparation method of accurate SiC ceramic based on silica gel mould gel casting forming and its accurate SiC ceramic |
Non-Patent Citations (1)
| Title |
|---|
| 任海军、门清毅、李秒玲: "《建筑机械安装与维修》", 30 September 2013, 武汉理工大学出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104446623B (en) | Mullite porous ceramic and preparation method thereof | |
| CN102010204B (en) | Colloidal forming process method for preparing silicon nitride bonded silicon carbide composite ceramic | |
| CN109626958A (en) | The modified full information surface silica gel mould vanadium titanium tailing of metal powder infuses solidification forming method | |
| CN103910821A (en) | A high-pressure-resistant water-permeable porous material and a preparation method thereof | |
| CN109467408A (en) | Oxide modifying full information surface silica gel mould cinder infuses solidification forming method | |
| CN109849571A (en) | The modified full information surface silica gel mould cadmia waste material of metal powder infuses solidification forming method | |
| CN109456023A (en) | The modified full information surface silica gel mould nickel slag waste material of metal powder infuses solidification forming method | |
| CN109456025A (en) | The modified full information surface silica gel mould red mud waste material of metal powder infuses solidification forming method | |
| CN109592967A (en) | The modified full information surface silica gel mould boccaro waste material of metal powder infuses solidification forming method | |
| CN109516776A (en) | The modified full information surface silica gel mould cinder of metal powder infuses solidification forming method | |
| CN109467392A (en) | The modified full information surface silica gel mould municipal sludge of metal powder infuses solidification forming method | |
| CN109467404A (en) | Oxide modifying full information surface silica gel mould nickel slag waste material infuses solidification forming method | |
| CN109574629A (en) | Oxide modifying full information surface silica gel mould red mud waste material infuses solidification forming method | |
| CN109467397A (en) | Oxide modifying full information surface silica gel mould boron slag waste material infuses solidification forming method | |
| CN109456034A (en) | Oxide modifying full information surface silica gel mould vanadium titanium tailing infuses solidification forming method | |
| CN109467391A (en) | Oxide modifying full information surface silica gel mould cadmia waste material infuses solidification forming method | |
| CN108676111A (en) | A kind of preparation method of field drives intelligent flexible material | |
| CN109534784A (en) | Oxide modifying full information surface silica gel mould boccaro waste material infuses solidification forming method | |
| CN109467401A (en) | The modified full information surface silica gel mould nickel slag waste material of ceramic powder infuses solidification forming method | |
| CN109467396A (en) | The modified full information surface silica gel mould boccaro waste material of aluminium powder infuses solidification forming method | |
| CN109467393A (en) | The modified full information surface silica gel mould nickel slag waste material of aluminium powder infuses solidification forming method | |
| CN109336483A (en) | The modified full information surface silica gel mould boccaro waste material of ceramic powder infuses solidification forming method | |
| CN109467398A (en) | Oxide modifying full information surface silica gel mould municipal sludge infuses solidification forming method | |
| CN109467402A (en) | The modified full information surface silica gel mould cadmia waste material of aluminium powder infuses solidification forming method | |
| CN109467399A (en) | The modified full information surface silica gel mould cadmia waste material of ceramic powder infuses solidification forming method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190607 |