CN109830381A - MXene/MoS for electrode of super capacitor2Composite material and preparation method thereof - Google Patents
MXene/MoS for electrode of super capacitor2Composite material and preparation method thereof Download PDFInfo
- Publication number
- CN109830381A CN109830381A CN201910268631.4A CN201910268631A CN109830381A CN 109830381 A CN109830381 A CN 109830381A CN 201910268631 A CN201910268631 A CN 201910268631A CN 109830381 A CN109830381 A CN 109830381A
- Authority
- CN
- China
- Prior art keywords
- mxene
- mos
- dispersion liquid
- electrode
- super capacitor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
Abstract
It for the MXene/MoS2 composite material and preparation method thereof of electrode of super capacitor, the steps include: that single layer MXene powder ultrasonic is dispersed in water to obtain MXene dispersion liquid, polyethylene imine is added, i.e. PEI solution obtains positively charged MXene dispersion liquid；By single layer MoS2Powder dispersion is in deionized water and ultrasonic, obtains single layer MoS2Dispersion liquid；By positively charged MXene and negatively charged MoS2Dispersion liquid is successively sprayed at polyethylene terephthalate, i.e., in PET base, obtains the MXene/MoS for electrode material for super capacitor after dry2Laminar composite.
Description
Technical field
The present invention relates to the MXene/MoS for electrode of super capacitor2The technology of preparing of composite material.
Background technique
Supercapacitor has power density as a kind of energy storage device between secondary cell and traditional capacitor
High, the advantages that charge/discharge speed is fast, good cycling stability.Electrode material be directly affect performance of the supercapacitor it is primary because
Element.MXene and MoS2Due to its unique two-dimensional layered structure, the channel quickly spread can be provided for electrolyte ion,
Electrode material for super capacitor as great development prospect.But the phenomenon that MXene will appear in use from stacking, make
Its surface cannot be fully utilized, and hinder the quick transmission of electrolyte ion, cause its theoretical capacity relatively low.MoS2
Although specific capacity is high, conductivity is low compared with MXene, keeps its high rate performance limited.Therefore it is prepared by electrostatic self-assembled method
MXene/MoS2Laminar composite can have both MXene and MoS2The advantages of, it is a kind of ideal fake capacitance electrode material.So
And the self-assembling method reported at present is mainly by the MoS with opposite charges2It is mixed with MXene dispersion liquid, makes MoS2With
MXene is combined by electrostatic interaction, to form MXene/MoS2Laminar composite.The self-assembling method controllability compared with
Difference, it is difficult to accurately control MXene/MoS2The number of plies and thickness of laminar composite.Therefore, the present invention proposes to use spraying from group
Dress method prepares MXene/MoS2Laminar composite will have the MoS of opposite charges by using spray gun2With MXene dispersion liquid
Successively it is sprayed on substrate.
Summary of the invention
The object of the present invention is to provide a kind of MXene/MoS for electrode of super capacitor2Composite material and preparation method thereof.
The present invention is the MXene/MoS for electrode of super capacitor2Composite material and preparation method thereof the steps include: list
Layer MXene powder ultrasonic is dispersed in water to obtain MXene dispersion liquid, and polyethylene imine, i.e. PEI solution is added, obtains positively charged
The MXene dispersion liquid of lotus；By single layer MoS2Powder dispersion is in deionized water and ultrasonic, obtains single layer MoS2Dispersion liquid；Just by band
The MXene of charge and negatively charged MoS2Dispersion liquid is successively sprayed at polyethylene terephthalate, i.e., in PET base, does
The MXene/MoS for electrode material for super capacitor is obtained after dry2Laminar composite.
Usefulness of the present invention is: compared to traditional liquid phase electrostatic self-assembled, this method is efficiently avoided from group
Randomness when dress has good controllability, is not only able to make two kinds of stratified material alternating intercalation distributions, and can be accurate
The number of plies and thickness for controlling composite material are important innovation and supplement to current existing self-assembling technique.
Specific embodiment
The present invention is the MXene/MoS for electrode of super capacitor2Composite material and preparation method thereof the steps include: list
Layer MXene powder ultrasonic is dispersed in water to obtain MXene dispersion liquid, and polyethylene imine, i.e. PEI solution is added, obtains positively charged
The MXene dispersion liquid of lotus；By single layer MoS2Powder dispersion is in deionized water and ultrasonic, obtains single layer MoS2Dispersion liquid；Just by band
The MXene of charge and negatively charged MoS2Dispersion liquid is successively sprayed at polyethylene terephthalate, i.e., in PET base, does
The MXene/MoS for electrode material for super capacitor is obtained after dry2Laminar composite.
The above-described MXene/MoS for electrode of super capacitor2Composite material and preparation method thereof, specific steps
Are as follows:
(1) 30 mg MXene powder are added in 120 mL deionized waters, 1 h of ultrasound obtains MXene dispersion liquid；
(2) taking 120 mL concentration is the PEI aqueous solution of 8 mg/mL, and MXene points that step (1) obtains are added under stirring
Dispersion liquid, 60 DEG C of 12 h of water-bath；
(3) by dispersion liquid obtained by step (2), the centrifuge washing at 4000 rad/min, 5 min every time, until supernatant PH=7,
Obtain positively charged MXene dispersion liquid；
(4) 100 mg single layer MoS are taken2Powder is scattered in 50 mL deionized waters, and 1 h of ultrasound obtains MoS2Dispersion liquid；
It (5) will be with spray gun by MXene and MoS obtained by step (3) and step (4)2Dispersion liquid is successively sprayed on pet substrate, and 60
Pet substrate removing, can be obtained the MXene/MoS for being used for electrode material for super capacitor by DEG C dry 24 h2Lamellar composite material
Material.
The above-described MXene/MoS for electrode of super capacitor2Composite material and preparation method thereof, described MXene
For Ti3C2TX,Or Ti2CTxOr V2CTxOr Mo3C2Tx。
The above-described MXene/MoS for electrode of super capacitor2Composite material and preparation method thereof, described stirring are
Magnetic agitation.
The above-described MXene/MoS for electrode of super capacitor2Composite material and preparation method thereof uses Germany
Schutze KA-2 automatic spray gun, the nozzle diameter using spray gun are 0.2 mm and 0.3 mm.
The above-described MXene/MoS for electrode of super capacitor2Composite material and preparation method thereof, the atomization pressure of spray gun
Power is 4 bar perhaps 4.5 bar perhaps 5 bar perhaps 5.5 bar or 6 bar.
The above-described MXene/MoS for electrode of super capacitor2Composite material and preparation method thereof, when spraying, are used
Pet substrate with a thickness of 0.5 mm.
Embodiment 1:
(1) 30 mg MXene powder are added in 120 mL deionized waters, 1 h of ultrasound obtains MXene dispersion liquid；
(2) taking 120 mL concentration is the PEI aqueous solution of 8 mg/mL, and MXene points that step (1) obtains are added under stirring
Dispersion liquid, 60 DEG C of 12 h of water-bath；
(3) by dispersion liquid obtained by step (2), the centrifuge washing at 4000 rad/min, 5 min every time, until supernatant PH=7,
Obtain positively charged MXene dispersion liquid；
(4) 100 mg single layer MoS are taken2Powder is scattered in 50 mL deionized waters, and 1 h of ultrasound obtains MoS2Dispersion liquid；
(5) Germany's schutze KA-2 automatic spray gun is used, nozzle diameter is 0.2 mm, and adjusting atomizing pressure is 4 bar, will be walked
Suddenly (3) and step (4) gained MXene and MoS2Dispersion liquid is successively sprayed on pet substrate, 60 DEG C of 24 h of drying, by PET base
The MXene/MoS for electrode material for super capacitor can be obtained in plate removing2Laminar composite.
Embodiment 2:
(1) 30 mg MXene powder are added in 120 mL deionized waters, 1 h of ultrasound obtains MXene dispersion liquid；
(2) taking 120 mL concentration is the PEI aqueous solution of 8 mg/mL, and MXene points that step (1) obtains are added under stirring
Dispersion liquid, 60 DEG C of 12 h of water-bath；
(3) by dispersion liquid obtained by step (2), the centrifuge washing at 4000 rad/min, 5 min every time, until supernatant PH=7,
Obtain positively charged MXene dispersion liquid；
(4) 100 mg single layer MoS are taken2Powder is scattered in 50 mL deionized waters, and 1 h of ultrasound obtains MoS2Dispersion liquid；
(5) Germany's schutze KA-2 automatic spray gun is used, nozzle diameter is 0.2 mm, and adjusting atomizing pressure is 4.5 bar, will
MXene and MoS obtained by step (3) and step (4)2Dispersion liquid is successively sprayed on pet substrate, 60 DEG C of 24 h of drying, by PET
The MXene/MoS for electrode material for super capacitor can be obtained in strippable substrate2Laminar composite.
Embodiment 3:
(1) 30 mg MXene powder are added in 120 mL deionized waters, 1 h of ultrasound obtains MXene dispersion liquid；
(2) taking 120 mL concentration is the PEI aqueous solution of 8 mg/mL, and MXene points that step (1) obtains are added under stirring
Dispersion liquid, 60 DEG C of 12 h of water-bath；
(3) by dispersion liquid obtained by step (2), the centrifuge washing at 4000 rad/min, 5 min every time, until supernatant PH=7,
Obtain positively charged MXene dispersion liquid；
(4) 100 mg single layer MoS are taken2Powder is scattered in 50 mL deionized waters, and 1 h of ultrasound obtains MoS2Dispersion liquid；
(5) Germany's schutze KA-2 automatic spray gun is used, nozzle diameter is 0.2 mm, and adjusting atomizing pressure is 5 bar, will be walked
Suddenly (3) and step (4) gained MXene and MoS2Dispersion liquid is successively sprayed on pet substrate, 60 DEG C of 24 h of drying, by PET base
The MXene/MoS for electrode material for super capacitor can be obtained in plate removing2Laminar composite.
Embodiment 4:
(1) 30 mg MXene powder are added in 120 mL deionized waters, 1 h of ultrasound obtains MXene dispersion liquid；
(2) taking 120 mL concentration is the PEI aqueous solution of 8 mg/mL, and MXene points that step (1) obtains are added under stirring
Dispersion liquid, 60 DEG C of 12 h of water-bath；
(3) by dispersion liquid obtained by step (2), the centrifuge washing at 4000 rad/min, 5 min every time, until supernatant PH=7,
Obtain positively charged MXene dispersion liquid；
(4) 100 mg single layer MoS are taken2Powder is scattered in 50 mL deionized waters, and 1 h of ultrasound obtains MoS2Dispersion liquid；
(5) Germany's schutze KA-2 automatic spray gun is used, nozzle diameter is 0.3 mm, and adjusting atomizing pressure is 5.5 bar, will
MXene and MoS obtained by step (3) and step (4)2Dispersion liquid is successively sprayed on pet substrate, 60 DEG C of 24 h of drying, by PET
The MXene/MoS for electrode material for super capacitor can be obtained in strippable substrate2Laminar composite.
Embodiment 5:
(1) 30 mg MXene powder are added in 120 mL deionized waters, 1 h of ultrasound obtains MXene dispersion liquid；
(2) taking 120 mL concentration is the PEI aqueous solution of 8 mg/mL, and MXene points that step (1) obtains are added under stirring
Dispersion liquid, 60 DEG C of 12 h of water-bath；
(3) by dispersion liquid obtained by step (2), the centrifuge washing at 4000 rad/min, 5 min every time, until supernatant PH=7,
Obtain positively charged MXene dispersion liquid；
(4) 100 mg single layer MoS are taken2Powder is scattered in 50 mL deionized waters, and 1 h of ultrasound obtains MoS2Dispersion liquid；
(5) Germany's schutze KA-2 automatic spray gun is used, nozzle diameter is 0.3 mm, and adjusting atomizing pressure is 6 bar, will be walked
Suddenly (3) and step (4) gained MXene and MoS2Dispersion liquid is successively sprayed on pet substrate, 60 DEG C of 24 h of drying, by PET base
The MXene/MoS for electrode material for super capacitor can be obtained in plate removing2Laminar composite.
The above is the embodiment of the present invention, is not intended to limit the scope of the invention, all to be said using the present invention
Equivalent structure or equivalent flow shift made by bright book content is applied directly or indirectly in other relevant field technologies,
It similarly include in the invention patent protection scope.
Claims (7)
1. being used for the MXene/MoS of electrode of super capacitor2Composite material and preparation method thereof, which is characterized in that the steps include: list
Layer MXene powder ultrasonic is dispersed in water to obtain MXene dispersion liquid, and polyethylene imine, i.e. PEI solution is added, obtains positively charged
The MXene dispersion liquid of lotus；By single layer MoS2Powder dispersion is in deionized water and ultrasonic, obtains single layer MoS2Dispersion liquid；Just by band
The MXene of charge and negatively charged MoS2Dispersion liquid is successively sprayed at polyethylene terephthalate, i.e., in PET base, does
The MXene/MoS for electrode material for super capacitor is obtained after dry2Laminar composite.
2. the MXene/MoS according to claim 1 for electrode of super capacitor2Composite material and preparation method thereof, feature
It is, the specific steps are that:
(1) 30 mg MXene powder are added in 120 mL deionized waters, 1 h of ultrasound obtains MXene dispersion liquid；
(2) taking 120 mL concentration is the PEI aqueous solution of 8 mg/mL, and MXene points that step (1) obtains are added under stirring
Dispersion liquid, 60 DEG C of 12 h of water-bath；
(3) by dispersion liquid obtained by step (2), the centrifuge washing at 4000 rad/min, 5 min every time, until supernatant PH=7,
Obtain positively charged MXene dispersion liquid；
(4) 100 mg single layer MoS are taken2Powder is scattered in 50 mL deionized waters, and 1 h of ultrasound obtains MoS2Dispersion liquid；
(5) with spray gun by MXene and MoS obtained by step (3) and step (4)2Dispersion liquid is successively sprayed on pet substrate, and 60 DEG C
The MXene/MoS for being used for electrode material for super capacitor can be obtained in pet substrate removing by dry 24 h2Laminar composite.
3. the MXene/MoS according to claim 1 for electrode of super capacitor2Composite material and preparation method thereof, feature
Be: described MXene is Ti3C2TX,Or Ti2CTxOr V2CTxOr Mo3C2Tx。
4. the MXene/MoS according to claim 2 for electrode of super capacitor2Composite material and preparation method thereof, feature
Be: described stirring is magnetic agitation.
5. the MXene/MoS according to claim 2 for electrode of super capacitor2Composite material and preparation method thereof, feature
Be: the nozzle diameter using spray gun is 0.2 mm and 0.3 mm.
6. the MXene/MoS according to claim 2 for electrode of super capacitor2Composite material and preparation method thereof, feature
Be: the atomizing pressure of spray gun is 4 bar perhaps 4.5 bar perhaps 5 bar perhaps 5.5 bar or 6 bar.
7. the MXene/MoS according to claim 1 for electrode of super capacitor2Composite material and preparation method thereof, feature
It is: used pet substrate with a thickness of 0.5 mm when spraying.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910268631.4A CN109830381B (en) | 2019-04-04 | 2019-04-04 | MXene/MoS for supercapacitor electrodes2Method for preparing composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910268631.4A CN109830381B (en) | 2019-04-04 | 2019-04-04 | MXene/MoS for supercapacitor electrodes2Method for preparing composite material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109830381A true CN109830381A (en) | 2019-05-31 |
| CN109830381B CN109830381B (en) | 2021-01-19 |
Family
ID=66874777
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910268631.4A Active CN109830381B (en) | 2019-04-04 | 2019-04-04 | MXene/MoS for supercapacitor electrodes2Method for preparing composite material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109830381B (en) |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103035409A (en) * | 2011-10-09 | 2013-04-10 | 海洋王照明科技股份有限公司 | Graphene composite electrode and preparation method and application |
| CN103855380A (en) * | 2012-12-06 | 2014-06-11 | 三星精密化学株式会社 | Cathode active material, method for preparing the same, and lithium secondary batteries including the same |
| CN104321912A (en) * | 2013-05-23 | 2015-01-28 | 株式会社Lg化学 | Lithium secondary battery comprising multilayered active material layer |
| CN104616908A (en) * | 2015-01-29 | 2015-05-13 | 西南石油大学 | Composite material of nickel hydroxide/graphene or graphite and preparation method for composite material |
| CN105609319A (en) * | 2016-01-29 | 2016-05-25 | 西北师范大学 | Flaky titanium carbide-loaded manganese dioxide composite material for super capacitor electrode material and preparation of flaky titanium carbide-loaded manganese dioxide composite material |
| CN106571244A (en) * | 2016-11-02 | 2017-04-19 | 南京工业大学 | Two-dimensional transition metal carbon (nitrogen) compound and two-dimensional transition metal sulfide nano-composite powder, and preparation and application thereof |
| CN107112533A (en) * | 2014-10-27 | 2017-08-29 | 蔚山科学技术院 | Lithium secondary battery for the active material of cathode of lithium secondary battery, its preparation method and comprising it |
| US20180277373A1 (en) * | 2016-08-31 | 2018-09-27 | Micron Technology, Inc. | Semiconductor device structures including two-dimensional material structures, and related semiconductor devices and electronic systems |
| US20190056654A1 (en) * | 2015-10-22 | 2019-02-21 | Asml Netherlands B.V. | Method of manufacturing a pellicle for a lithographic apparatus, a pellicle for a lithographic apparatus, a lithographic apparatus, a device manufacturing method, an apparatus for processing a pellicle, and a method for processing a pellicle |
-
2019
- 2019-04-04 CN CN201910268631.4A patent/CN109830381B/en active Active
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103035409A (en) * | 2011-10-09 | 2013-04-10 | 海洋王照明科技股份有限公司 | Graphene composite electrode and preparation method and application |
| CN103855380A (en) * | 2012-12-06 | 2014-06-11 | 三星精密化学株式会社 | Cathode active material, method for preparing the same, and lithium secondary batteries including the same |
| CN104321912A (en) * | 2013-05-23 | 2015-01-28 | 株式会社Lg化学 | Lithium secondary battery comprising multilayered active material layer |
| CN107112533A (en) * | 2014-10-27 | 2017-08-29 | 蔚山科学技术院 | Lithium secondary battery for the active material of cathode of lithium secondary battery, its preparation method and comprising it |
| CN104616908A (en) * | 2015-01-29 | 2015-05-13 | 西南石油大学 | Composite material of nickel hydroxide/graphene or graphite and preparation method for composite material |
| US20190056654A1 (en) * | 2015-10-22 | 2019-02-21 | Asml Netherlands B.V. | Method of manufacturing a pellicle for a lithographic apparatus, a pellicle for a lithographic apparatus, a lithographic apparatus, a device manufacturing method, an apparatus for processing a pellicle, and a method for processing a pellicle |
| CN105609319A (en) * | 2016-01-29 | 2016-05-25 | 西北师范大学 | Flaky titanium carbide-loaded manganese dioxide composite material for super capacitor electrode material and preparation of flaky titanium carbide-loaded manganese dioxide composite material |
| US20180277373A1 (en) * | 2016-08-31 | 2018-09-27 | Micron Technology, Inc. | Semiconductor device structures including two-dimensional material structures, and related semiconductor devices and electronic systems |
| CN106571244A (en) * | 2016-11-02 | 2017-04-19 | 南京工业大学 | Two-dimensional transition metal carbon (nitrogen) compound and two-dimensional transition metal sulfide nano-composite powder, and preparation and application thereof |
Non-Patent Citations (1)
| Title |
|---|
| ELECTROSTATICALLY CHARGED MOS2/GRAPHENE OXIDE HYBRID COMPOSITES: "Electrostatically Charged MoS2/Graphene Oxide Hybrid Composites for Excellent Electrochemical Energy Storage Devices", 《APPLIED MATERIALS &INTERFACES》 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109830381B (en) | 2021-01-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101410915B (en) | Composite particles for electrochemical element electrode, process for producing composite particles for electrochemical element electrode, and electrochemical element electrode | |
| CN102549693B (en) | Electrode for electrochemical-element, and electrochemical element | |
| US7972535B2 (en) | Composite particles for electrochemical device electrode, method of production of composite particles for electrochemical device electrode, and electrochemical device electrode | |
| CN101160635B (en) | Composite particles for electrochemical element electrode | |
| CN108305977A (en) | A kind of caking property polymer-coated lithium ion battery separator and preparation method thereof | |
| US20140342225A1 (en) | Electrode for electrochemical device | |
| US20090034158A1 (en) | Electric Double Layer Capacitor | |
| CN102203891A (en) | Electrode for lithium ion capacitor and lithium ion capacitor | |
| JP5522364B2 (en) | Slurry composition for electrode | |
| US9685658B2 (en) | Composite particles for electrochemical device electrode, material for electrochemical device electrode, and electrochemical device electrode | |
| CN106784532A (en) | The preparation method of aqueous PVDF and its copolymer composite coated barrier film | |
| CN109244322A (en) | A kind of lithium ion battery separator aqueous coating and preparation method thereof, application | |
| CN106560943A (en) | Silicon-carbon negative electrode and preparation method thereof, and lithium ion battery | |
| CN102295898B (en) | Configuration and coating method of aluminium foil precoat nano conductive carbon primary coat liquid | |
| JP2010278125A (en) | Method of manufacturing electrode for electrochemical element, and electrochemical element | |
| JP5471307B2 (en) | Electrochemical element manufacturing method, electrochemical element electrode, and electrochemical element | |
| CN105355470A (en) | Preparation method for ultrathin lithium titanate electrode | |
| CN105633340A (en) | Composite pole plate of lithium ion battery and preparation method of composite pole plate | |
| CN104600232B (en) | A kind of method of modifying of ultra-high molecular mass polyethylene micropore film | |
| CN105470464A (en) | Preparation method of lithium ion battery negative electrode for reducing irreversible capacity loss | |
| CN109830381A (en) | MXene/MoS for electrode of super capacitor2Composite material and preparation method thereof | |
| CN102760864A (en) | Preparation method for positive plate of AlNiCo acid lithium battery | |
| CN106745251A (en) | A kind of preparation method and application for being suitable to the nanometer vanadic anhydride positive electrode of industrialized production | |
| WO2017054297A1 (en) | Electrode for electrochemical power supply and manufacturing method therefor | |
| JP7352665B2 (en) | Separator with adhesive for lithium ion batteries, its manufacturing method and application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20210719 Address after: 310018 room 1201, 12th floor, Yifu science and technology building, East District, China University of metrology, No. 258 Xueyuan street, economic and Technological Development Zone, Hangzhou, Zhejiang Province Patentee after: Hangzhou Realistic New Materials Technology Co.,Ltd. Address before: 730050, No. 287 Lan Ping Road, Qilihe District, Gansu, Lanzhou Patentee before: LANZHOU University OF TECHNOLOGY |
|
| TR01 | Transfer of patent right |