CN109822856A - A kind of extruder and method preparing low smell polyolefine material - Google Patents
A kind of extruder and method preparing low smell polyolefine material Download PDFInfo
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- CN109822856A CN109822856A CN201910224213.5A CN201910224213A CN109822856A CN 109822856 A CN109822856 A CN 109822856A CN 201910224213 A CN201910224213 A CN 201910224213A CN 109822856 A CN109822856 A CN 109822856A
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- 239000000463 material Substances 0.000 title claims abstract description 68
- 229920000098 polyolefin Polymers 0.000 title claims abstract description 56
- 238000000034 method Methods 0.000 title claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 58
- 238000001125 extrusion Methods 0.000 claims abstract description 17
- 239000002994 raw material Substances 0.000 claims description 14
- 238000002347 injection Methods 0.000 claims description 10
- 239000007924 injection Substances 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- GZEDKDBFUBPZNG-UHFFFAOYSA-N tridec-1-yne Chemical compound CCCCCCCCCCCC#C GZEDKDBFUBPZNG-UHFFFAOYSA-N 0.000 claims description 3
- 238000002604 ultrasonography Methods 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 2
- 230000008901 benefit Effects 0.000 abstract description 2
- 238000005516 engineering process Methods 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 8
- 230000000694 effects Effects 0.000 description 5
- 150000003384 small molecules Chemical class 0.000 description 5
- 125000003003 spiro group Chemical group 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 150000004291 polyenes Chemical class 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- -1 polypropylene Polymers 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000012805 post-processing Methods 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
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- 238000013461 design Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
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- 238000009434 installation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
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- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
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Landscapes
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
The present invention provides a kind of extruder and method for preparing low smell polyolefine material, and extruder includes driving part, warehouse, feed inlet and discharge port；Driving part is set to the starting point of warehouse, and connect with the intracorporal screw drive in storehouse；Feed inlet is set to the starting point of warehouse along the vertical direction；Discharge port is set to the end of warehouse；Warehouse is equipped with constant flow high pressure water pump and ultrasonic generator, and constant flow high pressure water pump is set to the front end of ultrasonic generator along the extrusion direction of polyolefine material；Scheme provided by the invention can be effectively reduced the smell in polyolefine material, with advantage that is high-efficient, at low cost, being more widely applied.
Description
Technical field
The invention belongs to prepare low smell polyolefin technical field, and in particular to a kind of to prepare low smell polyolefine material
Extruder and method.
Background technique
The features such as polyolefine material is from a wealth of sources because of function admirable, and cost performance is high becomes key basic material, extensive
For every field；But add during catalyst residual and short chain oligomer and following process during prepared by polyolefine material
Add the factors such as agent to influence, can there are problems that discharging volatile matter pollution environment to some extent and endangers people's health, it is special
It is not for fields such as the higher automobile interior decoration of environmental requirement, medical and food packagings；Low smell polyolefine material is prepared at present
Public technology and method mainly include the following types:
It the first, is addition absorbent or photocatalysis Decomposition agent；This method mainly adds active carbon in polyolefin, porous
Silica, porous molecular screen, the physical absorbents such as activated alumina are blended in screw extruder and are granulated；Such as Chinese patent
CN200510026762.X etc.；But it facts proved that adding low-boiling extractant and porous mass for composite material, plays and changes
The smell problem of kind composite material；But cannot exclude there are still a certain amount of compared with small molecule in polymer, even if small molecule into
Enter " storage " into this porous mass, but the storing mode of this open loop is very unstable, the later period is also one
The problem of process of a slow release, smell, still cannot fundamentally solve；It is organic by decomposing to add inorganic photochemical catalyst
Small molecule reduces VOC content, such as Chinese patent CN201711428464.2, but it is there are catalytic efficiency not high the problems such as；
It the second, is devolatilization processing technique；Devolatilization processing technique is segmented into devolatilization technology in the course of the polymerization process again and adds afterwards
Devolatilization technology during work；Devolatilization is high-efficient in polymerization process, but production technology and equipment have limitation, and higher cost is not easy wide
General application；Devolatilization relies primarily on exhaust extruding technology by addition expellent such as taste removal master batch etc. to realize during post-processing,
Such as Chinese patent CN201410673916.3；But this current technical effect is bad, is extremely difficult to 3 grades and 3 grades ratings above
It is required that.
Based on technical problem present in the production of said polyolefins material, there has been no relevant solutions；Therefore urgent
Need to seek effective scheme to solve the above problems.
Summary of the invention
The purpose of the present invention is shortcoming present in view of the above technology, propose a kind of to prepare low smell polyolefin material
The extruder and method of material, it is intended to solve in existing polyolefine material production process, the heavier problem of smell.
The present invention provide a kind of extruder for preparing low smell polyolefine material, including driving part, warehouse, feed inlet with
And discharge port；Driving part is set to the starting point of warehouse, and connect with the intracorporal screw drive in storehouse；Feed inlet is along the vertical direction
It is set to the starting point of warehouse；Discharge port is set to the end of warehouse；Warehouse is equipped with constant flow high pressure water pump and ultrasonic generator,
Constant flow high pressure water pump is set to the front end of ultrasonic generator along the extrusion direction of polyolefine material.
Further, positional distance feed inlet 1/2-2/3 screw rod strong point is arranged in constant flow high pressure water pump.
Further, positional distance feed inlet 2/3-3/4 screw rod strong point is arranged in ultrasonic generator.
Further, vacuum pump is additionally provided on warehouse, vacuum pump is set to ultrasonic hair along the extrusion direction of polyolefine material
The rear end of raw device.
Further, positional distance feed inlet 3/4-4/5 screw rod strong point is arranged in vacuum pump.
Further, it is located at vacuum pump on warehouse and is equipped with vacuum port；Gas vent is additionally provided on warehouse, gas vent is along polyene
The extrusion direction of hydrocarbon material is set to the front end of constant flow high pressure water pump.
Further, warehouse includes being formed by connecting by 12 areas Ge Cang；Feed inlet is set to the first Cang Qu；Discharge port setting
In the exit in the area Shi Ercang；Constant flow high pressure water pump is set to the 7th Cang Qu；Ultrasonic generator is set to the 8th Cang Qu；9th
Cang Qu is equipped with vacuum pump；Screw rod is located at the 4th Cang Qu, the 8th Cang Qu and the tenth storehouse section and is respectively equipped with cutout, cutout packet
11 pieces are included to tridecyne.
Correspondingly, the present invention also provides a kind of methods for preparing low smell polyolefine material, applied to system described above
The extruder of standby low smell polyolefine material；It is further comprising the steps of:
S1: by polyolefinic raw materials by driving screw rod to the intracorporal polyene in storehouse by driving part in feed inlet investment warehouse
Hydrocarbon raw material is conveyed；
S2: pure water is conveyed in warehouse by constant flow high pressure water pump, water injection rate is low smell polyolefine material yield
11% to 15%, the pressure of constant flow high pressure water pump is greater than 0.8MPa；
S3: microwave is provided into warehouse by ultrasonic generator, microwave, which does medium by pure water, makes polyolefinic raw materials
Volatile substance forms hydrone microvesicle；Ultrasonic frequency is set as 15KHz-200KHz；
S4: warehouse out is extracted hydrone microvesicle by vacuum pump, the intracorporal vacuum area vacuum degree in storehouse is greater than 0.8；
S5: smell polyolefine material is squeezed out from discharge port by screw rod.
Further, in S2 step: the pressure of constant flow high pressure water pump is greater than 1.3MPa；In S3 step: ultrasonic frequency is set
It is set to 15KHz-100KHz；In S4 step: the intracorporal vacuum area vacuum degree in storehouse is greater than 1.0.
Further, in S2 step: the conveying capacity of pure water and resin extruded output quantity are controlled 5% to 30%.
Using the above scheme, even if so that polyolefine material product does not carry out prolonged baking material and other processing, particle
Smell reaches 3 grades of examination criterias；Scheme provided by the invention can be avoided the very long baking material time, to be greatly improved
Production efficiency, product qualification rate are also significantly promoted, while can satisfy the polyolefine material product requirement of low smell.
Detailed description of the invention
The present invention will be further described in detail below with reference to the accompanying drawings and specific embodiments.
Below with reference to attached drawing, the invention will be further described:
Fig. 1 is a kind of extruder structure schematic diagram for preparing low smell polyolefine material of the present invention；
Fig. 2 is a kind of method flow diagram for preparing low smell polyolefine material of the present invention.
In figure: 1, motor；2, transmission case；3, feed inlet；4, warehouse；41, gas vent；42, water injection hole；43, ultrasound occurs
Device；44, vacuum port；5, discharge port.
Specific embodiment
It should be noted that in the absence of conflict, the features in the embodiments and the embodiments of the present application can phase
Mutually combination.The present invention will be described in detail below with reference to the accompanying drawings and embodiments.
In the description of the present invention, it is to be understood that, term " center ", " longitudinal direction ", " transverse direction ", " length ", " width ",
" thickness ", "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom" "inner", "outside", " up time
The orientation or positional relationship of the instructions such as needle ", " counterclockwise ", " axial direction ", " radial direction ", " circumferential direction " be orientation based on the figure or
Positional relationship is merely for convenience of description of the present invention and simplification of the description, rather than the device or element of indication or suggestion meaning must
There must be specific orientation, be constructed and operated in a specific orientation, therefore be not considered as limiting the invention.
In addition, term " first ", " second " are used for descriptive purposes only and cannot be understood as indicating or suggesting relative importance
Or implicitly indicate the quantity of indicated technical characteristic.Define " first " as a result, the feature of " second " can be expressed or
Implicitly include at least one this feature.In the description of the present invention, the meaning of " plurality " is at least two, such as two, three
It is a etc., unless otherwise specifically defined.
In the present invention unless specifically defined or limited otherwise, term " installation ", " connected ", " connection ", " fixation " etc.
Term shall be understood in a broad sense, for example, it may be being fixedly connected, may be a detachable connection, or integral；It can be mechanical connect
It connects, is also possible to be electrically connected or can communicate each other；It can be directly connected, can also indirectly connected through an intermediary, it can be with
It is the interaction relationship of the connection or two elements inside two elements, unless otherwise restricted clearly.For this field
For those of ordinary skill, the specific meanings of the above terms in the present invention can be understood according to specific conditions.
As shown in Figure 1 to Figure 2, the present invention provides a kind of extruder for preparing low smell polyolefine material, including driving portion
Part, warehouse 4, feed inlet 3 and discharge port 5；Driving part is set to the starting point of warehouse 4, and with the screw drive in warehouse 4
Connection, to drive screw rod to carry out feeding；Specifically, driving part includes motor 1 and transmission case 2, motor 1 by transmission case 2 with
Screw rod is sequentially connected；Feed inlet 3 is set to the starting point of warehouse 4 along the vertical direction；Discharge port 5 is set to the end of warehouse 4
It holds, water injection hole 42 is additionally provided on warehouse 4, water injection hole 42 is for connecting water receiving pipe；Further, warehouse 4 is equipped with constant flow high pressure
Water pump and ultrasonic generator, and before constant flow high pressure water pump is set to ultrasonic generator along the extrusion direction of polyolefine material
End, i.e. ultrasonic generator are arranged next to constant flow high pressure water pump, and constant flow high pressure water pump is close to 3 side of feed inlet, ultrasonic generator
Close to 5 side of discharge port；Specifically, constant flow high pressure water pump is matched for conveying pure water into warehouse 4, and according to certain toward crowded
Pure water is continually conveyed in the warehouse 4 of machine out, specifically, matching is 5% to 30%,；Water injection rate is low smell polyolefin
The pressure of the 11% to 15% of material yield, constant flow high pressure water pump is greater than 0.8MPa；Ultrasonic generator provides microwave into warehouse,
Microwave, which does medium by pure water, makes the volatile substance of polyolefinic raw materials form hydrone microvesicle；Ultrasonic frequency is set as
15KHz-200KHz；Further, pure water enters the condition of high temperature in more than 200 degree in warehouse, and hot water washes off small molecule
Grease effect is good, then by ultrasonic-microwave, makes that the effect for washing grease is more preferable, level is deeper；Extruder provided by the invention is just
It is the process device that polyolefinic raw materials pass through melting dispersion extrusion molding in a device, technology is washed and be vacuum-evacuated using ultrasound
The small-molecule substance for causing smell is disposably removed during polyolefin post-processing, is really achieved and is efficiently prepared low smell polyene
The purpose of hydrocarbon material.
Preferably, in conjunction with above scheme, as shown in Figure 1, constant flow high pressure water pump is arranged positional distance and feeds in the present embodiment
Mouth 1/2-2/3 screw rod strong point；Specifically, 1/2 screw rod strong point of positional distance feed inlet is arranged in constant flow high pressure water pump, and too early plastics are also
It does not melt, does not have effect, cannot exclude to come too late completely again；Further, positional distance feed inlet is arranged in ultrasonic generator
Screw rod strong point；Specifically, 2/3 screw rod strong point of positional distance feed inlet is arranged in ultrasonic generator 43.
Preferably, in conjunction with above scheme, as shown in Figure 1, being additionally provided with vacuum pump, vacuum pump edge on warehouse 4 in the present embodiment
The extrusion direction of polyolefine material is set to the rear end of ultrasonic generator；Specifically, positional distance feed inlet 3/ is arranged in vacuum pump
Screw rod strong point；Further, it is located at vacuum pump on warehouse and is equipped with vacuum port；It is additionally provided with gas vent 41 on warehouse, is vented
Hole 41 is set to the front end of constant flow high pressure water pump along the extrusion direction of polyolefine material.
Preferably, in conjunction with above scheme, as shown in Figure 1, in the present embodiment, access the position of constant flow high pressure water injecting pump away from
At feed hole 1/2-2/3 spiro rod length, it is preferably close to neighbouring position at 1/2 spiro rod length；In production due at water filling with into
Material mouth farther out, avoids vapor and emerges at feed inlet, the case where making feed inlet returning charge occurs；The conveying capacity of pure water and tree
Rouge squeezes out output quantity control in 5-30%, more preferably controls in 8-20%, optimal control is in 10-15%；Further, constant current
High pressure water injection pump pressure is greater than 0.8MPa, preferably greater than 1.3MPa；The position of ultrasonic-microwave device is in the 2/3-3/4 apart from feed hole
At spiro rod length, neighbouring position at preferably 2/3 spiro rod length；Ultrasonic frequency is set as 15KHz-200KHz, preferably 15KHz-
100KHz；Vacuum pump position is located at 3/4-4/5 spiro rod length, and at preferably 3/4, vacuum degree is greater than 0.8, preferably greater than 0.9,
More preferably greater than 1.0.
Preferably, in conjunction with above scheme, as shown in Figure 1, in the present embodiment, warehouse include by the connection of 12 areas Ge Cang and
At, i.e. C1, C2, C3, C4 ... ... C12 shown in Fig. 1, each isometric design in storehouse area；Specifically, feed inlet 3 is set to the first storehouse
Area, discharge port 5 are set to the exit in the area Shi Ercang；Constant flow high pressure water pump is set to the 7th Cang Qu；Ultrasonic generator 43 is set
It is placed in the 8th Cang Qu；9th Cang Qu is equipped with vacuum pump, and the 9th Cang Qu and the area Shi Yicang are respectively equipped with vacuum port 44, so that
9th Cang Qu and the area Shi Yicang are vacuum area, and vacuum port 44 is for extracting vacuum；Further, screw rod is located at the 4th storehouse
Area, the 8th Cang Qu and the tenth storehouse section are respectively equipped with cutout；Specifically, cutout includes 11 pieces to tridecyne, preferably
It is 12 pieces；Cutout be screw thread a part, be to play the role of dispersion, cannot too much can not be very little, influence production capacity too much,
Also it is easy aging, smell is bigger instead, influences material property very little.
Correspondingly, in conjunction with above scheme, as shown in Figure 1 and Figure 2, low smell polyolefin material is prepared the present invention also provides a kind of
The method of material, applied to the extruder for preparing low smell polyolefine material described above；It is further comprising the steps of:
S1: by polyolefinic raw materials by driving screw rod to the intracorporal polyene in storehouse by driving part in feed inlet investment warehouse
Hydrocarbon raw material is conveyed；Specifically, by starting motor, motor drives screw rod to convey the intracorporal polyolefinic raw materials in storehouse；
S2: pure water is conveyed in warehouse by constant flow high pressure water pump, water injection rate is low smell polyolefine material yield
11% to 15%, the pressure of constant flow high pressure water pump is greater than 0.8MPa；Preferably, the pressure of constant flow high pressure water pump is greater than 1.3MPa；
S3: microwave is provided into warehouse by ultrasonic generator, microwave, which does medium by pure water, makes polyolefinic raw materials
Volatile substance forms hydrone microvesicle；Ultrasonic frequency is set as 15KHz-200KHz；Preferably, ultrasonic frequency is set as
15KHz-100KHz；
S4: warehouse out is extracted hydrone microvesicle by vacuum pump, the intracorporal vacuum area vacuum degree in storehouse is greater than 0.8；It is preferred that
Ground, the intracorporal vacuum area vacuum degree in storehouse are greater than 1.0；
S5: low smell polyolefine material is squeezed out from discharge port by screw rod, extrusion temperature is 190 DEG C to 220 DEG C；It is preferred that
Ground, extrusion temperature are 190 DEG C, 200 DEG C, 210 DEG C.
Preferably, in conjunction with above scheme, as shown in Figure 1, in the present embodiment, in the S2 step: the conveying capacity of pure water
It controls with resin extruded output quantity 5% to 30%；The conveying capacity of pure water and resin extruded output quantity are with low gas hourly
Taste polyolefine material output has much relations, and into few, effect is bad, and too many production capacity is affected.
Preferably, according to above embodiments, extrusion temperature is 190-200 DEG C, using polypropylene material trade mark k7726 as raw material
The product A of preparation is tested according to masses standard VDA270, as a result reaches 3.0 grades；
Comparative example 1 is squeezed out using conventional screw, high pressure water-injection pump, ultrasonic vibration wave and vacuum pump is not added, with polypropylene material
Trade mark K7726 is raw material, and extrusion temperature is 190-220 DEG C, is tested according to masses standard VDA270, as a result reaches 4 grades；
Comparative example 2, using the Screw Extrusion for having vacuum pump, high pressure water-injection pump and ultrasonic vibration wave is not added, with polypropylene material
Material trade mark K7726 is raw material, and extrusion temperature is 190-220 DEG C, is tested according to masses standard VDA270, as a result reaches 3 grades.
Using the above scheme, even if so that polyolefine material product does not carry out prolonged baking material and other processing, particle
Smell reaches 3 grades of examination criterias, can be avoided the very long baking material time, so that production efficiency be greatly improved, product is qualified
Rate is also significantly promoted, while can satisfy the polyolefine material product requirement of low smell.
Scheme provided by the invention can be effectively reduced the smell in polyolefine material, have it is high-efficient, at low cost, answer
With more extensive advantage.
The above, only presently preferred embodiments of the present invention not do limitation in any form to the present invention.It is any ripe
Those skilled in the art is known, without departing from the scope of the technical proposal of the invention, all using technology contents described above
Many possible changes and modifications or equivalent example modified to equivalent change are made to technical solution of the present invention.Therefore, all
It is the content without departing from technical solution of the present invention, any change modification made to the above embodiment of technology according to the present invention,
Equivalent variations and modification belong to the protection scope of the technical program.
Claims (10)
1. a kind of extruder for preparing low smell polyolefine material, which is characterized in that including driving part, warehouse, feed inlet with
And discharge port；The driving part is set to the starting point of the warehouse, and connect with the intracorporal screw drive in the storehouse；It is described
Feed inlet is set to the starting point of the warehouse along the vertical direction；The discharge port is set to the end of the warehouse；The storehouse
Body is equipped with constant flow high pressure water pump and ultrasonic generator, and the constant flow high pressure water pump is set to along the extrusion direction of polyolefine material
The front end of the ultrasonic generator.
2. the extruder according to claim 1 for preparing low smell polyolefine material, which is characterized in that the constant flow high pressure
Feed inlet 1/2-2/3 screw rod strong point described in positional distance is arranged in water pump.
3. the extruder according to claim 2 for preparing low smell polyolefine material, which is characterized in that the ultrasound occurs
Feed inlet 2/3-3/4 screw rod strong point described in positional distance is arranged in device.
4. the extruder according to claim 3 for preparing low smell polyolefine material, which is characterized in that on the warehouse also
Equipped with vacuum pump, the vacuum pump is set to the rear end of the ultrasonic generator along the extrusion direction of polyolefine material.
5. the extruder according to claim 4 for preparing low smell polyolefine material, which is characterized in that the vacuum pump is set
Seated position is apart from the feed inlet 3/4-4/5 screw rod strong point.
6. the extruder according to claim 5 for preparing low smell polyolefine material, which is characterized in that the warehouse is upper
Vacuum port is equipped at the vacuum pump；Gas vent, extrusion of the gas vent along polyolefine material are additionally provided on the warehouse
Direction is set to the front end of the constant flow high pressure water pump.
7. the extruder according to claim 1 for preparing low smell polyolefine material, which is characterized in that the warehouse includes
It is formed by connecting by 12 areas Ge Cang；The feed inlet is set to the first Cang Qu；The discharge port is set to going out for the area Shi Ercang
At mouthful；The constant flow high pressure water pump is set to the 7th Cang Qu；The ultrasonic generator is set to the 8th Cang Qu；9th Cang Qu is equipped with
Vacuum pump；The screw rod is located at the 4th Cang Qu, the 8th Cang Qu and the tenth storehouse section and is respectively equipped with cutout, the cutout packet
11 pieces are included to tridecyne.
8. a kind of method for preparing low smell polyolefine material, which is characterized in that applied to preparation described in the claims 1
The extruder of low smell polyolefine material；It is further comprising the steps of:
S1: by polyolefinic raw materials by driving screw rod to the intracorporal polyolefin in storehouse original by driving part in feed inlet investment warehouse
Material is conveyed；
S2: pure water is conveyed in warehouse by constant flow high pressure water pump, water injection rate is the 11% of low smell polyolefine material yield
To 15%, the pressure of constant flow high pressure water pump is greater than 0.8MPa；
S3: microwave is provided into warehouse by ultrasonic generator, microwave, which does medium by pure water, makes the volatilization of polyolefinic raw materials
Substance forms hydrone microvesicle；Ultrasonic frequency is set as 15KHz-200KHz；
S4: warehouse out is extracted hydrone microvesicle by vacuum pump, the intracorporal vacuum area vacuum degree in storehouse is greater than 0.8；
S5: smell polyolefine material is squeezed out from discharge port by screw rod.
9. the method according to claim 8 for preparing low smell polyolefine material, which is characterized in that in the S2 step:
The pressure of constant flow high pressure water pump is greater than 1.3MPa；In the S3 step: ultrasonic frequency is set as 15KHz-100KHz；The S4
In step: the intracorporal vacuum area vacuum degree in storehouse is greater than 1.0.
10. the method according to claim 8 for preparing low smell polyolefine material, which is characterized in that in the S2 step:
The conveying capacity of pure water and resin extruded output quantity are controlled 5% to 30%.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114053761A (en) * | 2021-11-08 | 2022-02-18 | 常州市福欧车辆配件有限公司 | Preparation equipment for water injection devolatilization of sound insulation board |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4994217A (en) * | 1988-12-29 | 1991-02-19 | General Electric Company | Low odor polyphenylene ether/polystyrene process |
| CN101326045A (en) * | 2005-12-06 | 2008-12-17 | 出光兴产株式会社 | Ultrasonic vibration applying method and resin composition |
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| US4994217A (en) * | 1988-12-29 | 1991-02-19 | General Electric Company | Low odor polyphenylene ether/polystyrene process |
| CN101326045A (en) * | 2005-12-06 | 2008-12-17 | 出光兴产株式会社 | Ultrasonic vibration applying method and resin composition |
| CN103788387A (en) * | 2012-10-29 | 2014-05-14 | 中国石油化工股份有限公司 | Preparation method of low-VOC polypropylene resin |
| CN104448763A (en) * | 2014-12-18 | 2015-03-25 | 上海锦湖日丽塑料有限公司 | Preparation method of low-diffusion PC/ABS alloy |
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| CN114053761A (en) * | 2021-11-08 | 2022-02-18 | 常州市福欧车辆配件有限公司 | Preparation equipment for water injection devolatilization of sound insulation board |
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