CN109796800A - Spray liniment and its preparation process in a kind of nano photo-catalytic room - Google Patents

Spray liniment and its preparation process in a kind of nano photo-catalytic room Download PDF

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Publication number
CN109796800A
CN109796800A CN201711143344.8A CN201711143344A CN109796800A CN 109796800 A CN109796800 A CN 109796800A CN 201711143344 A CN201711143344 A CN 201711143344A CN 109796800 A CN109796800 A CN 109796800A
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China
Prior art keywords
nano
catalytic
preparation process
nano photo
photo
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CN201711143344.8A
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Chinese (zh)
Inventor
杨晓阳
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Shanghai Green Wood Environmental Protection Engineering Co Ltd
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Shanghai Green Wood Environmental Protection Engineering Co Ltd
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Priority to CN201711143344.8A priority Critical patent/CN109796800A/en
Publication of CN109796800A publication Critical patent/CN109796800A/en
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Abstract

The invention discloses spray liniment and its preparation process in a kind of nano photo-catalytic room, primary raw material is deionization moisture content, nano photo-catalytic part, film forming agent part, surfactant, stabilizer, dispersing agent, filler, nano-meter flame retardants;After proportionally weighing, it is mixed and Namas's photocatalytic spray agent is made;The present invention is relative to traditional handicraft, preparation section is simple, environment and human body, which is not present, in raw material influences, performance more improves, and the harmful organic substance that product itself PARA FORMALDEHYDE PRILLS(91,95), benzene, ammonia, sulfur dioxide, carbon monoxide, nitrogen oxides etc. influence human health has good purification function.

Description

Spray liniment and its preparation process in a kind of nano photo-catalytic room
Technical field
The present invention relates to spray liniment and its preparation processes in a kind of nano photo-catalytic room, belong to nano photo-catalytic technology neck Domain.
Background technique
The release of the harmful substances such as formaldehyde, benzene in home decoration material needs 10-15 or even longer time, sternly People's lives health is affected again.Therefore, requirement of the people in household decoration process to ornament materials environmental-protecting performance is more next It is higher.Main material one of of the wall finiss as interior decoration, environmental-protecting performance are particularly subject to pay close attention to.Currently, commonly using on the market Environment protection type wall covering paint primary water-soluble coating, emulsion paint and multi-color and ceramic paint etc..However, although this kind of wall finiss is basic Without the harmful organic substances such as formaldehyde and benzene, but the harmful substances such as formaldehyde, the benzene of the release of other ornament materials are not also absorbed With the effect of removing.
The present invention provides a kind of preparation method of nano photo-catalytic spray liniment for applying to the surfaces such as indoor wall, furniture, Relative to traditional handicraft, preparation section is simple, and on environment and human body there is no influence, performance more improves raw material, and produces The harmful organic substance of the influence human health such as product PARA FORMALDEHYDE PRILLS(91,95) itself, benzene, ammonia, sulfur dioxide, carbon monoxide, nitrogen oxides With good purification function.
Summary of the invention
The present invention provides spray liniment and its preparation process in a kind of nano photo-catalytic room.
In order to solve the above-mentioned technical problems, the present invention provides the following technical solutions:
Spray liniment and its preparation process in a kind of nano photo-catalytic room of the present invention, are made of the proportion of following parts by weight: 85-95 parts of deionized water, 0.01-0.05 parts of film forming agent, 0.1-1 parts of surfactant, is stablized 0.1-1.5 parts of nano photo-catalytic 0.1-1 parts of agent, 0.01-0.05 parts of dispersing agent, 1-5 parts of filler, 0.01-0.1 parts of nano-meter flame retardants.
As a preferred technical solution of the present invention, nano photo-catalytic is nano-titanium dioxide, nano zine oxide, nanometer Silver.
As a preferred technical solution of the present invention, dispersing agent is phosphoric acid salt, polyacrylate, polycarboxylic acid salt One of, two or more composition.
As a preferred technical solution of the present invention, filler is calcium carbonate, talcum powder, wollastonite, kaolin, titanium dioxide Silicon, one kind of barium sulfate and diatomite, two or more composition.
As a preferred technical solution of the present invention, nano-meter flame retardants are silicate nano fire retardant and nanometer hydroxide One or two kinds of compositions of magnesium fire retardant.
The preparation process of spray liniment in a kind of nano photo-catalytic room of the present invention are as follows:
Step (1) weighs following each components by following mass percent respectively;95 parts of deionized water, nano photo-catalytic 1 Part, 0.05 part of film forming agent, 0.7 part of surfactant, 0.1 part of stabilizer, 0.05 part of dispersing agent, 3 parts of filler, nano-meter flame retardants 0.1 part.
Nano photo-catalytic by weight with weighing is poured into deionized water and is slowly stirred by step (2), and 5-10 points of stirring Film forming agent, surfactant and nano-meter flame retardants are poured into planet stirring kettle together and are dispersed with stirring uniformly by clock;It is mixed after discharging It closes object and adds stabilizer, dispersing agent, filler and be uniformly dispersed in high speed disperser and obtain finished product.
Wherein nano-titanium dioxide is main nano photo-catalytic, when it absorbs the energy in sunlight or other light sources Afterwards, the electronics of particle surface is activated, and escapes from original track, while the hole that Surface Creation is positively charged.The electronics of evolution has Active oxygen can be generated after having strong reducing property, hole that then there is strong oxidizing property, the two to react with the aqueous vapor in air and hydrogen-oxygen is free Base.Active oxygen, hydroxyl free radical can be by oxygenolysis such as most of organic matter, pollutant, foul smell, bacteriums at harmless titanium dioxide Carbon and water.
The effect of stabilizer is to improve the chemical stability of spray liniment, can slow down reaction, keeps chemical balance, reduces table Face tension, the effects of preventing light, thermal decomposition or oxygenolysis.
The ability for increasing its degranulation is added in deionized water in dispersing agent.Nano-meter flame retardants are to confer to spray liniment flame retardancy Functional aid.
It is had the advantage that using spray liniment in nano photo-catalytic room prepared by the present invention
1. on air-cleaning function: PARA FORMALDEHYDE PRILLS(91,95), benzene, ammonia, sulfur dioxide, carbon monoxide, nitrogen oxides etc. influence the mankind The harmful organic substance of health plays catharsis.
2. sterilizing function: there are biocidal efficacies to Escherichia coli, staphylococcus aureus etc., can also be tapped while sterilization By the harmful compound discharged on bacterium dead volume.
3. deodorization functions: smelly to cigarette, lavatory is smelly, rubbish is smelly, animal odor etc. has deodouring effect.
4. anti-pollution function: preventing greasy dirt, dust etc. from generating.To in bathroom mould, scale, the yellow alkali of closet and iron rust and Applying phenomena such as dye face is faded equally has effects that prevent its generation.
5, purification function: the purification function of harmful substance in purification and water with water pollution, and surface is with super hydrophilic Property, have antifog, easy to wash, easily dry and other effects.
6, relative to traditional handicraft, preparation section is simple, and on environment and human body there is no influence, performance more changes raw material It is good.
Specific embodiment
Hereinafter, preferred embodiments of the present invention will be described, it should be understood that preferred embodiment described herein is only used In the description and interpretation present invention, it is not intended to limit the present invention.
Embodiment
Embodiment 1
Spray liniment and its preparation process in a kind of nano photo-catalytic room of the present invention, which is characterized in that its composition is as follows:
Further, nano photo-catalytic is nano-titanium dioxide, nano zine oxide, nano silver.
Further, dispersing agent is one of phosphoric acid salt, polyacrylate, polycarboxylic acid salt, two kinds or two kinds Above composition.
Further, filler is calcium carbonate, talcum powder, wollastonite, kaolin, silica, barium sulfate and diatomite A kind of, two or more composition.
Further, nano-meter flame retardants are the one or two of silicate nano fire retardant and nano-magnesium hydrate fire retardant Composition.
The said goods process flow: including the following steps,
S1) following each components are weighed respectively by following mass percent;
S2) nano photo-catalytic by weight with weighing be poured into deionized water and slowly be stirred, stirred 5-10 minutes, it will be at Film, surfactant and nano-meter flame retardants, which are poured into together in planet stirring kettle, to be dispersed with stirring uniformly;Mixture after discharging is again Stabilizer, dispersing agent, filler is added to be uniformly dispersed in high speed disperser and obtain finished product.
Embodiment 2
The said goods process flow: including the following steps,
S1) following each components are weighed respectively by following mass percent;
S2) nano photo-catalytic by weight with weighing be poured into deionized water and slowly be stirred, stirred 5-10 minutes, it will be at Film, surfactant and nano-meter flame retardants, which are poured into together in planet stirring kettle, to be dispersed with stirring uniformly;Mixture after discharging is again Stabilizer, dispersing agent, filler is added to be uniformly dispersed in high speed disperser and obtain finished product.
Embodiment 3
The said goods process flow: including the following steps,
S1) following each components are weighed respectively by following mass percent;
S2) nano photo-catalytic by weight with weighing be poured into deionized water and slowly be stirred, stirred 5-10 minutes, it will be at Film, surfactant and nano-meter flame retardants, which are poured into together in planet stirring kettle, to be dispersed with stirring uniformly;Mixture after discharging is again Stabilizer, dispersing agent, filler is added to be uniformly dispersed in high speed disperser and obtain finished product.
To spray liniment in 1,2,3 nano photo-catalytic room of above embodiments and commonly go methanal paint after one week of use into Row data test, result is as shown in following table:
Detection project Control sample Embodiment 1 Embodiment 2 Embodiment 3 Standard value
Formaldehyde 0.19 0.05 0.04 0.03 ≤0.12
Nitrogen 0.7 0.3 0.2 0.22 ≤0.5
Benzene 0.1 0.05 0.06 0.04 ≤0.09
TVOC 0.8 0.25 0.3 0.32 ≤0.6
It is had the advantage that using spray liniment in nano photo-catalytic room prepared by the present invention
1, on air-cleaning function: PARA FORMALDEHYDE PRILLS(91,95), benzene, ammonia, sulfur dioxide, carbon monoxide, nitrogen oxides etc. influence the mankind The harmful organic substance of health plays catharsis.
2, sterilizing function: having biocidal efficacies to Escherichia coli, staphylococcus aureus etc., can also tap while sterilization By the harmful compound discharged on bacterium dead volume.
3, deodorization functions: smelly to cigarette, lavatory is smelly, rubbish is smelly, animal odor etc. has deodouring effect.
4, anti-pollution function: prevent greasy dirt, dust etc. from generating.To in bathroom mould, scale, the yellow alkali of closet and iron rust and Applying phenomena such as dye face is faded equally has effects that prevent its generation.
5, purification function: the purification function of harmful substance in purification and water with water pollution, and surface is with super hydrophilic Property, have antifog, easy to wash, easily dry and other effects.
6, relative to traditional handicraft, preparation section is simple, and on environment and human body there is no influence, performance more changes raw material It is good.
Finally, it should be noted that the foregoing is only a preferred embodiment of the present invention, it is not intended to restrict the invention, Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used To modify the technical solutions described in the foregoing embodiments or equivalent replacement of some of the technical features. All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in of the invention Within protection scope.

Claims (6)

1. spray liniment and its preparation process in a kind of nano photo-catalytic room, which is characterized in that its composition is as follows:
2. spray liniment and its preparation process in a kind of nano photo-catalytic room according to claim 1, which is characterized in that described Nano photo-catalytic be nano-titanium dioxide, nano zine oxide, nano silver.
3. spray liniment and its preparation process in a kind of nano photo-catalytic room according to claim 1, which is characterized in that described Dispersing agent be one of phosphoric acid salt, polyacrylate, polycarboxylic acid salt, two or more composition.
4. spray liniment and its preparation process in a kind of nano photo-catalytic room according to claim 1, which is characterized in that described Filler be calcium carbonate, talcum powder, wollastonite, kaolin, silica, one kind of barium sulfate and diatomite, two kinds or two kinds Above composition.
5. spray liniment and its preparation process in a kind of nano photo-catalytic room according to claim 1, which is characterized in that described Nano-meter flame retardants be silicate nano fire retardant and nano-magnesium hydrate fire retardant one or two kinds of compositions.
6. spray liniment and its preparation process in a kind of nano photo-catalytic room according to claim 1, which is characterized in that including Following steps,
S1) following each components are weighed respectively by following mass percent;
S2) nano photo-catalytic by weight with weighing is poured into deionized water and is slowly stirred, stirs 5-10 minutes, will form a film Agent, surfactant and nano-meter flame retardants, which are poured into together in planet stirring kettle, to be dispersed with stirring uniformly;Mixture after discharging adds again Enter stabilizer, dispersing agent, filler and be uniformly dispersed in high speed disperser to obtain finished product.
CN201711143344.8A 2017-11-17 2017-11-17 Spray liniment and its preparation process in a kind of nano photo-catalytic room Pending CN109796800A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111298641A (en) * 2019-12-25 2020-06-19 江苏倪师傅环保科技有限公司 N2 type nano composite photocatalyst scavenger and preparation method thereof
CN111849239A (en) * 2019-07-08 2020-10-30 中科森之初环保科技有限公司 Negative ion spraying solvent and preparation process thereof
CN111838181A (en) * 2020-08-04 2020-10-30 常州吉娜泰盛地板有限公司 Nano photocatalyst formaldehyde-removing antibacterial mildew-proof liquid and decorative material using same
CN113331210A (en) * 2021-05-31 2021-09-03 浙江先拓环保科技有限公司 Photocatalyst mildew-proof antibacterial agent and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102051075A (en) * 2010-11-15 2011-05-11 莱阳子西莱环保科技有限公司 Environment-friendly spraying agent for nanometer photocatalyst wall and preparation method thereof
CN105754464A (en) * 2016-03-02 2016-07-13 东莞市可享光电科技有限公司 Spray agent for hardening and flame retardance of lamp glass products and preparation method thereof
CN106280761A (en) * 2016-07-29 2017-01-04 *** Magnesium oxide photocatalytic spray liquid can be cleaned

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102051075A (en) * 2010-11-15 2011-05-11 莱阳子西莱环保科技有限公司 Environment-friendly spraying agent for nanometer photocatalyst wall and preparation method thereof
CN105754464A (en) * 2016-03-02 2016-07-13 东莞市可享光电科技有限公司 Spray agent for hardening and flame retardance of lamp glass products and preparation method thereof
CN106280761A (en) * 2016-07-29 2017-01-04 *** Magnesium oxide photocatalytic spray liquid can be cleaned

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111849239A (en) * 2019-07-08 2020-10-30 中科森之初环保科技有限公司 Negative ion spraying solvent and preparation process thereof
CN111298641A (en) * 2019-12-25 2020-06-19 江苏倪师傅环保科技有限公司 N2 type nano composite photocatalyst scavenger and preparation method thereof
CN111838181A (en) * 2020-08-04 2020-10-30 常州吉娜泰盛地板有限公司 Nano photocatalyst formaldehyde-removing antibacterial mildew-proof liquid and decorative material using same
CN113331210A (en) * 2021-05-31 2021-09-03 浙江先拓环保科技有限公司 Photocatalyst mildew-proof antibacterial agent and preparation method thereof

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