CN109762389A - A kind of Ceramic Tiles metal effect surface treating agent and preparation method thereof - Google Patents
A kind of Ceramic Tiles metal effect surface treating agent and preparation method thereof Download PDFInfo
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- CN109762389A CN109762389A CN201811578073.3A CN201811578073A CN109762389A CN 109762389 A CN109762389 A CN 109762389A CN 201811578073 A CN201811578073 A CN 201811578073A CN 109762389 A CN109762389 A CN 109762389A
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- surface treating
- treating agent
- ceramic tiles
- sodium
- metal effect
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Abstract
The invention discloses a kind of Ceramic Tiles metal effect surface treating agents, include following component by material quality percentages: 0.4~2% sodium hydroxide, 0.1~0.4% sodium thiosulfate, 0.06~0.4% sodium sulfite, 0.5~1% sulphur, 0.2~0.5% cleaning agent, 0.02~0.1% natural plant gum, 1.5~2% sodium chromate, 0.01~0.02% chromium and surplus distilled water.Surface treating agent of the invention can go to dechlorinate and prevent silver element hyperoxidation and lead to coating flavescence, blackening, bleach and fall off, while also have the function of improving coating and substrate surface adhesive force, so that coating is stronger more attractive.The invention also discloses the preparation method of the surface treating agent, simple process, strong operability is conducive to large-scale industrial production.
Description
Technical field
The present invention relates to field of surface treatment, in particular to a kind of ceramic brick surface inorganic agent.
Background technique
With the increasingly raising of people's living standard, people also constantly mention the decorative effect of Ceramic Tiles and the requirement of quality
It is high.Wherein the Ceramic Tiles with metal-like are deep due to surface metal special-effect is favored by people.Aqueous spray is mostly used at present
Depositing process is surface-treated Ceramic Tiles to make it have metal decorative effect, and existing on the market for aqueous spraying plating process
Surface treatment is based on stannic chloride, palladium chloride, hydrogen chloride, boron hydrogen sodium.However, these surface treating agents can have chlorine element residual
The drawbacks of, silver oxidation transition occurs as soon as coating easily in 15~30 days different degrees of when the later period being caused to use silver-colored solid agent
Yellowing phenomenon, to the problem of Deposit appearance less effective occur.In addition, carrying out surface using these traditional surface treating agents
Processing be easy to cause coating and the bad defect of substrate surface viscosity, that is, there is the inadequate drawback of the binding force of coating and substrate,
Seriously affect the effect of aqueous spraying plating process.
Summary of the invention
It is an object of the invention in view of the above shortcomings of the prior art, provide a kind of Ceramic Tiles metal effect surface treatment
Agent, while the preparation method of the surface treating agent being provided.
The technical solution used in the present invention is: a kind of Ceramic Tiles metal effect surface treating agent, by material quality hundred
Point than meter include following component: 0.4~2% sodium hydroxide, 0.1~0.4% sodium thiosulfate, 0.06~0.4% Asia
Sodium sulphate, 0.5~1% sulphur, 0.2~0.5% cleaning agent, 0.02~0.1% natural plant gum, 1.5~2% chromic acid
Sodium, 0.01~0.02% chromium and the distilled water of surplus.
Specifically, the sodium hydroxide play the role of corrode substrate surface so that base surface roughness increase to
Increase the adhesive force of substrate surface;The sulphur, sodium thiosulfate, sodium sulfite compounding play the role of dechlorination, can be effective
Prevent silver-colored chlorination;The cleaning agent can remove impurity;The natural plant gum can improve the viscosity of substrate surface, to enhance coating
Adhesive force;The sodium chromate is for washing nitric acid dark brown entrapped contaminants;It is anticorrosive, resistance to that the chromium primarily serves enhancing coating
The effects of mill, high temperature resistant, resistance to oxidation.
It as a further improvement of the foregoing solution, include following component by material quality percentages: 0.4~0.8%
Sodium hydroxide, 0.12~0.14% sodium thiosulfate, 0.08~0.12% sodium sulfite, 0.7~0.8% sulphur, 0.3
~0.4% cleaning agent, 0.05~0.07% natural plant gum, 1.8~2% sodium chromate, 0.01~0.02% chromium and surplus
Distilled water.Specifically, each raw material component additive amount advanced optimizes, and is conducive to provide the comprehensive of the surface treating agent
Energy.
As a further improvement of the foregoing solution, the cleaning agent is metal cleaner.
As a further improvement of the foregoing solution, the metal cleaner is acid aqua type cleaning agent.
As a further improvement of the foregoing solution, the natural plant gum is flaxseed gum.
Another technical solution adopted by the present invention is: a kind of Ceramic Tiles metal effect surface treating agent as described above
Preparation method comprising following processing step: each raw material component is placed in and is stirred evenly at room temperature until be completely dissolved, is stood
0.5~1h obtains finished product.
The beneficial effects of the present invention are:
Surface treating agent of the invention can go to dechlorinate and prevent silver element hyperoxidation and lead to coating flavescence, blackening, change
It is white and fall off, while also having the function of improving coating and substrate surface adhesive force, so that coating is stronger more attractive.
Preparation method simple process of the invention, strong operability are conducive to large-scale industrial production.
Specific embodiment
The present invention is specifically described below with reference to embodiment, in order to technical field personnel to of the invention
Understand.It is necessary to it is emphasized that embodiment is only intended to, the present invention will be further described herein, should not be understood as to this
The limitation of invention protection scope, fields person skilled in the art, the non-intrinsically safe that the present invention is made according to foregoing invention content
The modifications and adaptations of property, should still fall within protection scope of the present invention.Mentioned raw materials following simultaneously are unspecified, are
Commercial product;The processing step or preparation method not referred in detail be processing step known to a person skilled in the art or
Preparation method.
Embodiment 1
A kind of Ceramic Tiles metal effect surface treating agent includes following component by material quality percentages: 0.4%
Sodium hydroxide, 0.14% sodium thiosulfate, 0.08% sodium sulfite, 0.8% sulphur, 0.3% acid aqua type are clear
Lotion, 0.07% flaxseed gum, 1.8% sodium chromate, 0.02% chromium and the distilled water of surplus.
Preparation method: above-mentioned each raw material component is placed in and is stirred evenly at room temperature until being completely dissolved, standing 0.5h obtains reality
Apply 1 finished product of example.
1 finished product of embodiment is used for aqueous spraying plating process, through 1 product handling system of embodiment after spraying plating substrate surface, is waited for
Spraying plating substrate surface effect is good, and impurity residual is few, is not in the open defects such as turn yellow, and after aqueous spraying plating processing its coating with
There is excellent binding force to spraying plating substrate surface, tested through hundred lattice, can reach 3 to 5 grades of European industrial standard, than using biography
The surface treating agent of system carries out the aqueous resulting coating of spraying plating process and wants 1 to 2 grades high.
Embodiment 2
A kind of Ceramic Tiles metal effect surface treating agent includes following component by material quality percentages: 0.8%
Sodium hydroxide, 0.12% sodium thiosulfate, 0.12% sodium sulfite, 0.7% sulphur, 0.4% acid aqua type are clear
Lotion, 0.05% flaxseed gum, 2% sodium chromate, 0.01% chromium and the distilled water of surplus.
Preparation method: above-mentioned each raw material component is placed in and is stirred evenly at room temperature until being completely dissolved, standing 1h must be implemented
2 finished product of example.
2 finished product of embodiment is used for aqueous spraying plating process, through 2 product handling system of embodiment after spraying plating substrate surface, is waited for
Spraying plating substrate surface effect is good, and impurity residual is few, is not in the open defects such as turn yellow, and after aqueous spraying plating processing its coating with
There is excellent binding force to spraying plating substrate surface, tested through hundred lattice, can reach 3 to 5 grades of European industrial standard, than using biography
The surface treating agent of system carries out the aqueous resulting coating of spraying plating process and wants 1 to 2 grades high.
Embodiment 3
A kind of Ceramic Tiles metal effect surface treating agent includes following component by material quality percentages: 0.5%
Sodium hydroxide, 0.13% sodium thiosulfate, 0.1% sodium sulfite, 0.75% sulphur, 0.35% acid aqua type are clear
Lotion, 0.06% flaxseed gum, 1.9% sodium chromate, 0.01% chromium and the distilled water of surplus.
Preparation method: above-mentioned each raw material component is placed in and is stirred evenly at room temperature until being completely dissolved, standing 0.6h obtains reality
Apply 3 finished product of example.
3 finished product of embodiment is used for aqueous spraying plating process, through 3 product handling system of embodiment after spraying plating substrate surface, is waited for
Spraying plating substrate surface effect is good, and impurity residual is few, is not in the open defects such as turn yellow, and after aqueous spraying plating processing its coating with
There is excellent binding force to spraying plating substrate surface, tested through hundred lattice, can reach 3 to 5 grades of European industrial standard, than using biography
The surface treating agent of system carries out the aqueous resulting coating of spraying plating process and wants 1 to 2 grades high.
Embodiment 4
A kind of Ceramic Tiles metal effect surface treating agent includes following component by material quality percentages: 0.6%
Sodium hydroxide, 0.14% sodium thiosulfate, 0.1% sodium sulfite, 0.8% sulphur, the cleaning of 0.4% acid aqua type
Agent, 0.05% flaxseed gum, 2% sodium chromate, 0.02% chromium and the distilled water of surplus.
Preparation method: above-mentioned each raw material component is placed in and is stirred evenly at room temperature until being completely dissolved, standing 1h must be implemented
4 finished product of example.
4 finished product of embodiment is used for aqueous spraying plating process, through 4 product handling system of embodiment after spraying plating substrate surface, is waited for
Spraying plating substrate surface effect is good, and impurity residual is few, is not in the open defects such as turn yellow, and after aqueous spraying plating processing its coating with
There is excellent binding force to spraying plating substrate surface, tested through hundred lattice, can reach 3 to 5 grades of European industrial standard, than using biography
The surface treating agent of system carries out the aqueous resulting coating of spraying plating process and wants 1 to 2 grades high.
Above-described embodiment is the preferred embodiment of the present invention, all with similar technique of the invention and made equivalence changes,
It should belong to protection category of the invention.
Claims (6)
1. a kind of Ceramic Tiles metal effect surface treating agent, it is characterised in that by material quality percentages include following component:
0.4~2% sodium hydroxide, 0.1~0.4% sodium thiosulfate, 0.06~0.4% sodium sulfite, 0.5~1% sulphur
Sulphur, 0.2~0.5% cleaning agent, 0.02~0.1% natural plant gum, 1.5~2% sodium chromate, 0.01~0.02% chromium and
The distilled water of surplus.
2. a kind of Ceramic Tiles metal effect surface treating agent according to claim 1, it is characterised in that: press material quality hundred
Dividing than meter includes following component: 0.4~0.8% sodium hydroxide, 0.12~0.14% sodium thiosulfate, 0.08~0.12%
Sodium sulfite, 0.7~0.8% sulphur, 0.3~0.4% cleaning agent, 0.05~0.07% natural plant gum, 1.8~2%
Sodium chromate, 0.01~0.02% chromium and the distilled water of surplus.
3. a kind of Ceramic Tiles metal effect surface treating agent according to claim 1 or 2, it is characterised in that: the cleaning
Agent is metal cleaner.
4. a kind of Ceramic Tiles metal effect surface treating agent according to claim 3, it is characterised in that: the metal cleaning
Agent is acid aqua type cleaning agent.
5. a kind of Ceramic Tiles metal effect surface treating agent according to claim 1 or 2, it is characterised in that: the plant
Glue is flaxseed gum.
6. a kind of preparation method of Ceramic Tiles metal effect surface treating agent as claimed in any one of claims 1 to 5, feature
It is to comprise the technical steps that: each raw material component is placed in and is stirred evenly at room temperature up to being completely dissolved, 0.5~1h of standing,
Obtain finished product.
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CN201811578073.3A CN109762389A (en) | 2018-12-21 | 2018-12-21 | A kind of Ceramic Tiles metal effect surface treating agent and preparation method thereof |
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CN201811578073.3A CN109762389A (en) | 2018-12-21 | 2018-12-21 | A kind of Ceramic Tiles metal effect surface treating agent and preparation method thereof |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111763072A (en) * | 2020-07-17 | 2020-10-13 | 佛山市品为先陶瓷有限公司 | Metallic ceramic tile and preparation method thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB290458A (en) * | 1927-06-24 | 1928-05-17 | James Harvey Gravell | Improvements in cleansing compositions for iron and steel |
CN102516936A (en) * | 2011-12-14 | 2012-06-27 | 温州市汇泰隆科技有限公司 | Surface conditioning agent used for nano coating process |
-
2018
- 2018-12-21 CN CN201811578073.3A patent/CN109762389A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB290458A (en) * | 1927-06-24 | 1928-05-17 | James Harvey Gravell | Improvements in cleansing compositions for iron and steel |
CN102516936A (en) * | 2011-12-14 | 2012-06-27 | 温州市汇泰隆科技有限公司 | Surface conditioning agent used for nano coating process |
Non-Patent Citations (2)
Title |
---|
《矿产资源工业要求手册》编委会编: "《矿产资源工业要求手册》", 31 August 2010, 地质出版社 * |
马瑞特: "《食品卫生原理》", 30 June 2001, 中国轻工业出版社 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111763072A (en) * | 2020-07-17 | 2020-10-13 | 佛山市品为先陶瓷有限公司 | Metallic ceramic tile and preparation method thereof |
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