CN109735140A - A kind of thermal jet electric-heating coatings, electric heating heating board and electric heating conversion coating and preparation method thereof - Google Patents
A kind of thermal jet electric-heating coatings, electric heating heating board and electric heating conversion coating and preparation method thereof Download PDFInfo
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- CN109735140A CN109735140A CN201910041193.8A CN201910041193A CN109735140A CN 109735140 A CN109735140 A CN 109735140A CN 201910041193 A CN201910041193 A CN 201910041193A CN 109735140 A CN109735140 A CN 109735140A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
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Abstract
The present invention provides a kind of thermal jet electric-heating coatings, electric heating heating board and electric heating conversion coatings and preparation method thereof.The coating is by mass percentage, comprising: silver chlorate 0.1-1%;Aluminium chloride 0.1-1%;Lithium chloride 1-5%;Copper chloride 10-35%;Anhydrous stannic chloride 10-35%;Gas-phase silica 0.1-1%;Graphene 1-5%;Antimony trichloride 1-5%;Graphite powder 1-5%;Nickel dichloride hexahydrate 10-25%;Cobalt chloride 0.1-1%;Iron chloride 0.1-1%;Magnesium chloride 0.1-1%.The maximum operating temperature of coating adstante febre can be up to 700 degree or so, and the speed that heats up is fast, and electric conversion efficiency reaches 96%-98%, and service life, which is stablized, to be used in room temperature up to 25000 hours;New breakthrough is realized on heating temperature value, heating rate, electric conversion rate, the service life the problems such as, is expanded in military, civilian and industrial or agricultural application range.
Description
Technical field
The present invention relates to electrothermal conversion body coating technology fields, and in particular to a kind of electrothermal conversion body coating and preparation side
Method.
Background technique
Electrothermal conversion body coating heating technique, be nano-grade matter thermal spraying glass, ceramics, etc. insulating materials table
Face forms certain thickness coating, after becoming the membranaceous coating of attachment.An electricity is respectively installed additional at the membranaceous coating both ends of formation
Pole forms an electric heating conversion heater, powers in two electrodes, coating can be heating up at once, realizes electricity
Heating process.
Also there is similar material because composition of raw materials is not scientific enough in the past, preparation method is not reasonable (please to enumerate previous formula, system
The example of Preparation Method Shortcomings, the example of citing can be paper document or patent document, and need the example point to citing
Analysis explanation is existing insufficient, such as: Chinese patent notification number is that the patent of 102843793 B of CN discloses a kind of electric heating conversion
Coating, the coating are raw material with zinc chloride, stannic chloride, graphite, copper carbonate, boric acid, ammonium fluoride, fluoboric acid, silica, are existed
The not high deficiency of integral material heatproof, example coating processes: coating slurry silk-screen sprays to insulating body surface, with stove heating liter
Temperature is to 400-500 degree and keeps the temperature 20 minutes, takes out natural cooling later up to electrification hot-cast socket coating, brushing silver paste production electricity
Pole, then the baking and curing in 200-400 degree furnace, is able to electrode after cooling.Electric heating conversion coating material is caused to ask there are many
Topic and deficiency:
(1) heating temperature is low, usually within 300 DEG C;Integral material heatproof is in 400-500 degree, so electric heating conversion applies
Layer adstante febre can only work within 300 degree.
(2) heating rate is slower;Integral material is all in 400-500 degree, in order to avoid being more than maximum operating temperature, heating
It spends slower.
(3) electric conversion efficiency is not high, usually 60%~80%;Power instrument test is lower when electrothermal conversion body applies in the distance
Close at 300 degree, power increases with temperature and is increased for layer work, so usually electric conversion efficiency is in 60%-80%.
(4) service life is not grown, usually at 3000 hours or so;
Integral material is all in 400-500 degree, and when electrothermal conversion body coating duty is close at 300 degree, power is with temperature liter
It is high and increases, service life reduction 2/3rds, usually at 3000 hours or so.
(5) application range is not wide, is only applicable in and low temperature environment heating material;
Integral material heatproof in 400-500 degree, so electric heating conversion coating adstante febre can only within 300 degree job applications
Range is not wide, is only applicable in and low temperature environment heating material.
Summary of the invention
In view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to provide a kind of electrothermal conversion body coating.The electric heating turns
It changes body coating to arrange in pairs or groups by the ingredient and ratio of control raw material, in heating temperature value, heating rate, electric conversion rate, uses the longevity
New breakthrough is realized on the problems such as life and environmental protection.
The object of the invention is also to provide a kind of preparation methods of electrothermal conversion body coating.The preparation method
For dehydrated alcohol and electrothermal conversion body coating material after mixing, are obtained electrothermal conversion body coating solution, then electric heating is converted
On the insulating material, high-temperature process obtains the electrothermal conversion body coating to the thermal spraying of body coating solution.
The purpose of the present invention is realized at least through one of following technical solution.
A kind of thermal jet electric-heating coatings, by mass percentage, including following component:
Silver chlorate 0.1-1%;Aluminium chloride 0.1-1%;Lithium chloride 1-5%;Copper chloride 10-35%;Anhydrous stannic chloride 10-
35%;Gas-phase silica 0.1-1%;Graphene 1-5%;Antimony trichloride 1-5%;Graphite powder 1-5%;Nickel dichloride hexahydrate 10-
25%;Cobalt chloride 0.1-1%;Iron chloride 0.1-1%;Magnesium chloride 0.1-1%.
Further, the coating includes following component: silver chlorate 0.1-1%;Aluminium chloride 0.1-1%;Lithium chloride 1-
5%;Copper chloride 10-45%;Anhydrous stannic chloride 20-35%;Gas-phase silica 0.1-1%;Graphene 1-5%;Antimony trichloride 1-
5%;Graphite powder 1-5%;Nickel dichloride hexahydrate 10-15%;Cobalt chloride 0.1-1%;Iron chloride 0.1-1%;Magnesium chloride 0.1-
1%.
The present invention also provides a kind of methods that thermal jet electric-heating coatings prepare electrothermal conversion body coating comprising following step
It is rapid:
(1) mass percent is pressed, by gas-phase silica (anti-settling agent), graphene, silver chlorate, antimony trichloride and graphite
Powder mixing, stirs evenly, and dehydrated alcohol is added, and after being fully ground, stands, obtains mixed liquor A;
(2) mass percent is pressed, Nickel dichloride hexahydrate, lithium chloride, aluminium chloride, copper chloride and anhydrous stannic chloride are mixed
It closes, stirs evenly, dehydrated alcohol is added, after being fully ground, stand, obtain mixed liquid B;
(3) mixed liquor A and mixed liquid B are mixed, are stirred evenly, stood, then by the mass percent be added iron chloride,
Cobalt chloride and magnesium chloride, stir evenly, and stand, obtain electrothermal conversion body coating solution;
(4) the electrothermal conversion body coating solution that will be obtained, when insulating materials just locates high temperature, thermal spraying carries out, in insulation material
The surface of material forms electrothermal conversion body coating.
Further, step (1)~(3) described standing time is 25-30 minutes.
Further, in step (4), the painting is carried out is carried out using thermal spraying, is specifically included: being sprayed to insulating materials surface
Sand processing, blasting treatment is placed on baking 12-15 minutes in 805-850 DEG C of high temperature ovens, by electric heating conversion coating liquid thermal spraying
To 805-850 DEG C of insulating materials is in through on the face of blasting treatment, electric heating is formed on the surface of insulating materials after natural cooling
Conversion body coating.
Further, the blasting treatment further includes being cleaned after sandblasting, being dried.
Further, in step (4), the painting, which is carried out, uses thermal spraying, specifically includes: carrying out sandblasting to insulating materials surface
Processing, blasting treatment are placed on baking 12-15 minutes in 805-850 DEG C of high temperature ovens, electric heating conversion coating liquid thermal jet are coated onto
805-850 DEG C of insulating materials is in through electric heating being formed on the surface of insulating materials after natural cooling and being turned on the face of blasting treatment
Change body coating.
It is that silver wire electricity is printed on the electrothermal conversion body coating the present invention also provides a kind of preparation method of electric heating heating board
Pole and be made, specifically include:
Cleaning treatment is carried out to the electrothermal conversion body coating on insulating materials surface, silver paste is printed onto insulating body surface
On electric heating conversion coating, it is placed in baking in 120-150 DEG C of low temperature oven and is taken out after 20-30 minutes, place into high temperature stove heating liter
Temperature forms silver wire electrode to 805-850 DEG C or so rear taking-up on electrothermal conversion body coating after natural cooling.
Compared with prior art, the invention has the advantages that and the utility model has the advantages that
(1) existing electric heating conversion coating heating temperature is low, and usually within 300 DEG C, integral material heatproof is in 400-500
Degree, so electric heating conversion coating adstante febre can only work within 300 degree.And coating integral material heatproof of the invention is in 805-
850 degree so electric heating conversion coating adstante febre can work within 700 degree.
(2) heating rate is slower;Existing electric heating conversion coating integral material all in 400-500 degree, so heating rate compared with
Slowly;And electric heating conversion coating integral material of the invention is all in 805-850 degree, so heating speed is very fast when work.
(3) electric conversion efficiency is not high, usually 60%~80%;Power instrument test is lower when electrothermal conversion body applies in the distance
Close at 300 degree, power increases with temperature and is increased for layer work, so usually electric conversion efficiency is in 60%-80%;And this
Under the test of power instrument in the distance of invention when electrothermal conversion body coating duty is close at 700 degree, power is steady with temperature raising
It is fixed, so usually electric conversion efficiency is in 96%-98%,
(4) service life is not grown, usually at 3000 hours or so;Existing electric heating conversion coating integral material is all in 400-
500 degree, when electrothermal conversion body coating duty is close at 300 degree, power increases with temperature and is increased, and service life reduces three points
Two, usually at 3000 hours or so.Electric heating conversion coating integral material of the invention is all in 805-850 degree, when electric heating is converted
Close at 700 degree, power increases with temperature and stablizes body coating duty, and service life is stablized, usually 25000 hours with
On.
(5) application range is not wide, is only applicable in and low temperature environment heating material;Existing major part electric heating conversion coating entirety material
Expect that heatproof is only fitted in 400-500 degree so electric heating conversion coating adstante febre can only job applications range be wide within 300 degree
With with low temperature environment heating material.Electric heating conversion coating integral material heatproof of the invention is in 805-850 degree so electric heating is converted
Coating adstante febre can within 700 degree job applications range it is wide.
The present invention heating temperature value, heating rate, electric conversion rate, the service life the problems such as on realize it is new prominent
Broken, military, civilian and industrial or agricultural application range expands comprehensively, has good economy and political value.
Specific embodiment
Technical solution of the present invention is described in further detail below in conjunction with specific embodiment, but protection of the invention
Range is without being limited thereto.
In specific embodiment, the insulating materials for preparing electrothermal conversion body coating is various insulating materials of different shapes, packet
Silicon crystal slate, microcrystal glass plate, silicon boron glass pipe or ceramic tube are included, and prepares after electrothermal conversion body coating i.e. shape on the insulating material
Heat generating member is converted at electric heating, electric heating conversion heat generating member can be widely used in the products such as household electrical appliance or industrial electrical equipment and equipment.
Table 1
Coating prepares embodiment 1
The method for preparing electrothermal conversion body coating, specifically comprises the following steps:
(1) mass percent is pressed, by gas-phase silica (anti-settling agent), graphene, silver chlorate, antimony trichloride and graphite
Powder mixing, stirs evenly, and dehydrated alcohol is added, and after being fully ground, stands, obtains mixed liquor A;
(2) mass percent is pressed, Nickel dichloride hexahydrate, lithium chloride, aluminium chloride, copper chloride and anhydrous stannic chloride are mixed
It closes, stirs evenly, dehydrated alcohol is added, after being fully ground, stand, obtain mixed liquid B;
(3) mixed liquor A and mixed liquid B are mixed, are stirred evenly, stood, then by the mass percent be added iron chloride,
Cobalt chloride and magnesium chloride, stir evenly, and stand, obtain electrothermal conversion body coating solution;
Electric heating conversion coating is made in electric heating conversion coating liquid prepared by examples detailed above, and forms electric heating conversion heat generating member,
The insulating materials of selection is microcrystal glass plate, can choose following three kinds of modes (the data employing mode b. in table 2):
(1) after the one side of the microcrystal glass plate of a. long 400mm, width 150mm, thickness 4mm carries out blasting treatment, 805 DEG C are put into
High temperature ovens in baking 15 minutes;
B. after the one side of the microcrystal glass plate of long 400mm, width 150mm, thickness 4mm carries out blasting treatment, it is put into 750 DEG C of height
Baking 15 minutes in warm oven;
(2) after the one side of the microcrystal glass plate of a. long 400mm, width 150mm, thickness 4mm carries out blasting treatment, 825 DEG C are put into
High temperature ovens in baking 14 minutes;
B. after the one side of the microcrystal glass plate of long 400mm, width 150mm, thickness 4mm carries out blasting treatment, it is put into 775 DEG C of height
Baking 14 minutes in warm oven;
(3) after the one side of the microcrystal glass plate of a. long 400mm, width 150mm, thickness 4mm carries out blasting treatment, 850 DEG C are put into
High temperature ovens in baking 12 minutes;
B. after the one side of the microcrystal glass plate of long 400mm, width 150mm, thickness 4mm carries out blasting treatment, it is put into 800 DEG C of height
Baking 12 minutes in warm oven;
(2) by microcrystal glass plate (such as above-mentioned b obtain) taking-up after high-temperature baking, rapidly by electric heating conversion coating liquid
Thermal jet is coated onto microcrystal glass plate and did on the face of blasting treatment, by the electrothermal conversion body clad plate alcohol washes after natural cooling
Afterwards, the silver paste line that a 10mm wide is respectively brushed in devitrified glass electrothermal conversion body coating board ends places into 120-150 DEG C low
Baking 20 minutes in warm oven;
(3) microcrystal glass plate is put into rapidly again 805 DEG C (corresponding aforesaid way a), 825 DEG C (corresponding aforesaid way b),
850 DEG C (baking 15 minutes in the high temperature ovens of corresponding aforesaid way c), is placed on normal temperature environment cooling, obtains crystallite after taking-up
Glass heating panel.
In this example, the electric heating conversion coating liquid being typically formulated interior spraying within three hours is finished.
So far, electric hot plate completes.As long as the upper surface of two silver wires are separately connected two poles, heating board when use
It can work.
Under identical testing conditions, the thermometric of triumph is respectively adopted in electric heating conversion coating made from 1 Examples 1 to 4 of table
Instrument and distant place power instrument test its maximum operating temperature and changed power.When it is temperature-resistant so that power is become larger when electric conversion efficiency
It is lower, when changed power is not in direct ratio with temperature, electric conversion efficiency is lower.Maximum operating temperature refers to exist in its work
Power stability works when maximum temperature.Maximum operating temperature, electric conversion efficiency, service life are as shown in table 2.
Table 2 (uses aforesaid way b)
Embodiment | Maximum operating temperature | Electric conversion efficiency | Service life |
1 | 700 degree | 60% | 10000 hours |
2 | 680 degree | 82% | 15000 hours |
3 | 650 degree | 88% | 20000 hours |
4 | 605 degree | 96%-98% | 25000 hours |
Comparative example | Maximum operating temperature | Electric conversion efficiency | Service life |
1 | 600 degree | 50% | 1000 hours |
2 | 580 degree | 80% | 3000 hours |
3 | 550 degree | 85% | 5000 hours |
4 | 500 degree | 90-95% | 9000 hours |
Contrast on effect is as it can be seen that integral material heatproof is in 805-850 degree in preparation process of the invention, by chlorination is such as added
Copper, silver chlorate, iron chloride, cobalt chloride, Nickel dichloride hexahydrate, anhydrous stannic chloride synergistic effect so that finally obtained electric heating turn
The maximum operating temperature for changing coating adstante febre can be up to 700 degree, since operating temperature can be higher, so that heating speed is also very fast.
In the distance under power instrument test when electrothermal conversion body coating duty is close at 605 degree, since graphene, graphite powder, three is added
The synergistic effect of antimony chloride is so that power increases with temperature and stablized, so usually electric conversion efficiency is in 96%-98%.Work as electricity
Close at 605 degree, power increases with temperature and stablizes heat exchange body coating duty, since aluminium chloride, lithium chloride, chlorination is added
Magnesium, gas-phase silica sufficiently merge that the service life is longer and stablizes with devitrified glass, usually at 25000 hours or more;Using model
It encloses wide.
This example sprays to the dosage of the coating slurry on insulating body surface as follows and parameter is calculated;
A. for making the electrothermal conversion body of heating liquid with 8-10w/cm2(power coefficient g1), every watt of 0.02-0.05g
The dosage of (dose factor a1) sprays;
B. for making the electrothermal conversion body of heating air with 2.5-4w/cm2(power coefficient g2), every watt of 0.02-0.04g
The dosage of (dose factor a2) sprays.
Use example 1:
Rapid water heater quartz electrothermal tube, outer dimension;Diameter 45mm overall length 600mm heats liquid according to production
Body is in electrothermal conversion body calculation method, the machinable maximum power of the size members:
W=S*g1 (S- surface area)
That is (3.14*2.25*2.25*50) * 10=7948w
Need to be sprayed on dosage L=W*a1 i.e. 7948*0.05=397g
Then pipe fitting is removed into surface and oil contaminant with sandblasting, after cleaning, drying, be placed in heating furnace, temperature rises to 825 DEG C simultaneously
Heat preservation 10 minutes, any coating solution for calculating dosage of Example 1-4, is all sprayed on quartz components surface, later respectively
Take out natural cooling.
Component after cooling is dried in 825 DEG C of furnaces by requirement brushing silver paste production electrode, then, is solidified, it is cold
But, power supply wiring is drawn with mechanical connection manner after cooling, electrothermal conversion body completes.
Be powered test, and electrothermal conversion body is powered on energization test, after inspection, the quartzy electric heating of rapid water heater
Pipe completes.
Use example 2:
The silicon wafer electric hot plate of oven dry combustion method is made, outer dimension: 400mm*150mm, according to the electricity of production heating air
Heat exchange body calculation method, the machinable maximum power of the size members:
W=S*g2 (S- surface area)
That is (40*15) * 4=2400w
The dosage L=W*a2 i.e. 2400*0.04=96g for needing to spray
Then it by after panels sandblasting cleaning, drying, is placed in heating furnace, temperature rises to 850 DEG C and keeps the temperature 10 minutes, takes
Any coating solution for calculating dosage, is all sprayed on silicon crystal slate component surface, takes out natural cooling later in embodiment 1-4.
Component after cooling is made into electrode by requirement brushing silver paste, is then dried in 850 DEG C of furnaces, is solidified, is cold
But power supply wiring is drawn with mechanical connection manner afterwards, electrothermal conversion body completes.
Be powered test, electrothermal conversion body is powered on energization test, after inspection, far infrared silicon wafer electric hot plate has been made
At.
The foregoing is only a preferred embodiment of the present invention, not does restriction in any form to the present invention.It is all
Any equivalent variation that those skilled in the art makes above-described embodiment using technical solution of the present invention is modified or is drilled
Become etc., all of which are still within the scope of the technical scheme of the invention.
Claims (10)
1. a kind of thermal jet electric-heating coatings, it is characterised in that by mass percentage, including following component:
Silver chlorate 0.1-1%;Aluminium chloride 0.1-1%;Lithium chloride 1-5%;Copper chloride 10-35%;Anhydrous stannic chloride 10-35%;Gas phase is white
Carbon black 0.1-1%;Graphene 1-5%;Antimony trichloride 1-5%;Graphite powder 1-5%;Nickel dichloride hexahydrate 10-25%;Cobalt chloride 0.1-
1%;Iron chloride 0.1-1%;Magnesium chloride 0.1-1%.
2. a kind of thermal jet electric-heating coatings according to claim 1, it is characterised in that including following component: silver chlorate 0.1-
1%;Aluminium chloride 0.1-1%;Lithium chloride 1-5%;Copper chloride 10-45%;Anhydrous stannic chloride 20-35%;Gas-phase silica 0.1-1%;Stone
Black alkene 1-5%;Antimony trichloride 1-5%;Graphite powder 1-5%;Nickel dichloride hexahydrate 10-15%;Cobalt chloride 0.1-1%;Iron chloride 0.1-
1%;Magnesium chloride 0.1-1%.
3. being existed using a kind of method that thermal jet electric-heating coatings prepare electrothermal conversion body coating, feature described in as claimed in claim 1 or 22
In including the following steps:
(1) mass percent is pressed, gas-phase silica, graphene, silver chlorate, antimony trichloride and graphite powder are mixed, stirring
Uniformly, dehydrated alcohol is added, after being fully ground, stands, obtains mixed liquor A;
(2) mass percent is pressed, Nickel dichloride hexahydrate, lithium chloride, aluminium chloride, copper chloride and anhydrous stannic chloride are mixed,
It stirs evenly, dehydrated alcohol is added, after being fully ground, stand, obtain mixed liquid B;
(3) mixed liquor A and mixed liquid B are mixed, is stirred evenly, stood, then iron chloride, chlorination is added by the mass percent
Cobalt and magnesium chloride, stir evenly, and stand, obtain electrothermal conversion body coating solution;
(4) the electrothermal conversion body coating solution that will be obtained, when insulating materials just locates high temperature, thermal spraying carries out, in insulating materials
Surface forms electrothermal conversion body coating.
4. according to the method described in claim 3, it is characterized in that step (1) ~ (3) described standing time is 25-30 points
Clock.
5. according to the method described in claim 3, it is characterized in that
In step (4), the painting is carried out is carried out using thermal spraying, is specifically included: blasting treatment is carried out to insulating materials surface, at sandblasting
Reason is placed on baking 12-15 minutes in 805-850 DEG C of high temperature ovens, and electric heating conversion coating liquid thermal jet is coated onto and is in 805-
850 DEG C of insulating materials are through forming electrothermal conversion body coating on the surface of insulating materials after natural cooling on the face of blasting treatment.
6. the method according to claim 5, it is characterised in that the blasting treatment further includes being cleaned after sandblasting, being dried
It is dry.
7. the method according to claim 5, it is characterised in that in step (4), the painting, which is carried out, uses thermal spraying, specific to wrap
It including: blasting treatment is carried out to insulating materials surface, blasting treatment is placed on baking 12-15 minutes in 805-850 DEG C of high temperature ovens,
Electric heating conversion coating liquid thermal jet is coated onto and is in 805-850 DEG C of insulating materials through on the face of blasting treatment, after natural cooling
The surface of insulating materials forms electrothermal conversion body coating.
8. a kind of electrothermal conversion body coating as made from claim 3 the method.
9. a kind of preparation method of electric heating heating board, it is characterized in that printing silver wire on the electrothermal conversion body coating described in claim 8
Electrode and be made, specifically include:
Cleaning treatment is carried out to the electrothermal conversion body coating on insulating materials surface, silver paste is printed onto the electric heating on insulating body surface
On conversion coating, it is placed in baking in 120-150 DEG C of low temperature oven and is taken out after 20-30 minutes, place into high temperature furnace and be heated to
805-850 DEG C or so rear taking-up forms silver wire electrode after natural cooling on electrothermal conversion body coating.
10. a kind of electric heating heating board made from the preparation method as described in claim 9.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113194556A (en) * | 2021-04-20 | 2021-07-30 | 广东温道百镒健康科技有限公司 | Graphene radiation heating film and preparation method thereof |
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JPS5778463A (en) * | 1980-10-31 | 1982-05-17 | Matsushita Electric Ind Co Ltd | Electrically conductive paint |
CN1085038A (en) * | 1993-04-14 | 1994-04-06 | 刘秋云 | The manufacturing of infrared electrothermal film heater and application thereof |
JP2004107558A (en) * | 2002-09-20 | 2004-04-08 | Nekken Kagaku Kogyo Kk | Heat-resistant and anticorrosive coating and heat-resistant and anticorrosive coating film |
CN107949080A (en) * | 2017-11-17 | 2018-04-20 | 广东中科智道热源科技有限公司 | A kind of electrothermal conversion body coating and preparation method |
-
2019
- 2019-01-16 CN CN201910041193.8A patent/CN109735140A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5778463A (en) * | 1980-10-31 | 1982-05-17 | Matsushita Electric Ind Co Ltd | Electrically conductive paint |
CN1085038A (en) * | 1993-04-14 | 1994-04-06 | 刘秋云 | The manufacturing of infrared electrothermal film heater and application thereof |
JP2004107558A (en) * | 2002-09-20 | 2004-04-08 | Nekken Kagaku Kogyo Kk | Heat-resistant and anticorrosive coating and heat-resistant and anticorrosive coating film |
CN107949080A (en) * | 2017-11-17 | 2018-04-20 | 广东中科智道热源科技有限公司 | A kind of electrothermal conversion body coating and preparation method |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN113194556A (en) * | 2021-04-20 | 2021-07-30 | 广东温道百镒健康科技有限公司 | Graphene radiation heating film and preparation method thereof |
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