CN109734842A - A kind of electrically conducting transparent flexibility bacteria cellulose composite material and preparation method thereof - Google Patents
A kind of electrically conducting transparent flexibility bacteria cellulose composite material and preparation method thereof Download PDFInfo
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Abstract
The invention belongs to field of compound material, a kind of electrically conducting transparent flexibility bacteria cellulose composite material and preparation method thereof is disclosed.Bacteria cellulose aquagel is placed in NaOH solution after cropped, heating stirring is reacted under air-proof condition, removes reaction solution after reaction, and washing, which is placed in acrylic acid, impregnates；Then by treated, bacteria cellulose aquagel is immersed in the eutectic solvent of photopolymerization, is protected from light heated sealed isothermal holding, then the polymerizing curable under ultraviolet lighting, obtains the electrically conducting transparent flexibility bacteria cellulose composite material.The method of the present invention simple process, reaction condition is mild, preparation process green, not high to equipment requirement, is conducive to industrialized production, at low cost.The bacteria cellulose composite material flexibility of preparation is good, and mechanical performance is strong, and transparency is high, conductive, is with a wide range of applications in fields such as flexible display device, Organic Light Emitting Diode, energy storage device, solar battery, wearable sensors.
Description
Technical field
The invention belongs to field of compound material, and in particular to a kind of electrically conducting transparent flexibility bacteria cellulose composite material and its
Preparation method.
Background technique
The flexible electronic device of high transparency is with a wide range of applications, and such as flexible circuit, flexible display, flexibility is too
Positive energy battery, pressure sensor, electronic skin and wearable electronic sensor etc..Traditional method, it is mostly conductive using metal/semiconductor
The elastomer of nano material (such as carbon nanotube, silver nanowires, graphene oxide) coated high transparency, but this method may
Soft or hard material interface is caused to fail, so as to cause transparency decline.Ionic gel elastomer has the tensility of inherence because of it,
And electric conductivity and high transparency, the traditional ionic gel of more and more concern is caused usually by high-cost or need
The group of complicated post-processing is wanted to be grouped as, the application after polymerizeing which has limited them as functional material.Low brilliant solvent altogether
Appear in the beginning of this century as a new class of ionic liquid, and it many advantages, Ru at low cost, (constituent be can be
Biomass or derivative from fossil deposit), (by very economical route and process is simply mixed) in manufacturing process green,
Biodegradable, good biocompatibility, nontoxicity etc..However, component generally passes through weak hydrogen bond company in low brilliant solvent altogether
It connects, so that its mechanical performance is poor, especially, after absorbing water in air, mechanical performance is further decreased.
Bacteria cellulose be a kind of molecular formula is β-Isosorbide-5-Nitrae-glycosidic bond polysaccharide as plant cellulose, but and papermaking
Plant cellulose used is compared, and has several clear advantages.From the perspective of ingredient, bacteria cellulose is pure cellulose
Rather than other plant ingredient, such as hemicellulose, lignin and pectin.Therefore, bacteria cellulose does not need to carry out additional place
Reason is to remove these unwanted impurity.In terms of microstructure, bacteria cellulose has fine and complicated three-dimensional porous net
Network structure, by with high-aspect-ratio and diameter is that the cellulose nano-fibrous of 20~100nm forms, to provide high-ratio surface
Long-pending and porosity, to can get the big mass loading of active material.Bacteria cellulose also shows high-strength mechanical performance,
Young's modulus and tensile strength can achieve 20.8GPa and 357.3MPa, this may make flexible electrode to have good mechanicalness
Energy.And due to many hydroxyls on surface, bacteria cellulose also has superelevation hydrophily, be advantageous to aqueous electrolyte from
The transmission of son, and these functional groups can keep active material closer with bacteria cellulose under the action of hydrogen bond and electrostatic force
Combination.In addition, bacteria cellulose also shows some other unique physical properties, including high-crystallinity (70~80%),
High polymerization degree (up to 8000) and high plasticity.Meanwhile as a kind of cellulose, bacteria cellulose also has good biofacies
Capacitive, it is non-toxic.These features illustrate that bacteria cellulose is the flexible electrode base material of great potential.
Summary of the invention
In place of the above shortcoming and defect of the existing technology, the primary purpose of the present invention is that providing a kind of transparent
The preparation method of conductive flexible bacteria cellulose composite material.The preparation method has a simple process, reaction condition is relatively mild, material
Preparation cost is low, is easy to industrialize.
Another object of the present invention is to provide a kind of electrically conducting transparent flexibility bacterium being prepared by the above method is fine
Tie up plain composite material.
The object of the invention is achieved through the following technical solutions:
A kind of preparation method of electrically conducting transparent flexibility bacteria cellulose composite material, including following preparation step:
(1) bacteria cellulose aquagel is placed in NaOH solution after cropped, heating stirring is reacted under air-proof condition, instead
Reaction solution is removed after answering, washing, which is placed in acrylic acid, impregnates；
(2) by step (1), treated, and bacteria cellulose aquagel is immersed in the eutectic solvent of photopolymerization, is protected from light
Heated sealed isothermal holding；
(3) it by step (2) treated bacteria cellulose aquagel polymerizing curable under ultraviolet lighting, obtains described transparent
Conductive flexible bacteria cellulose composite material.
Preferably, bacteria cellulose aquagel described in step (1) with a thickness of 0.01~10mm.
Preferably, the concentration of NaOH solution described in step (1) is 0.1~0.5mol/L.
Preferably, the temperature of the reaction of heating stirring described in step (1) is 70~90 DEG C, and the time is 4~8h.
Preferably, the propylene acid soak 1~2 impregnated and referred to purity >=98% in acrylic acid is placed in described in step (1)
It is secondary, every time 12~for 24 hours.
Preferably, the eutectic solvent of photopolymerization described in step (2) configures by the following method:
After mixing by choline chloride and acrylic acid heating stirring, it is cooled to room temperature, adds two acrylic acid of polyethylene glycol
Ester and photoinitiator, stirring and dissolving is complete, obtains the eutectic solvent of the photopolymerization.
It is furthermore preferred that the molar ratio of the choline chloride and acrylic acid is 1:(2~6)；The acrylic acid and polyethylene glycol
The molar ratio of dipropyl dilute acid ester is 100:(1~2).
It is furthermore preferred that the mass concentration that the photoinitiator is added is 0.2%~1%.
It is further preferred that the photoinitiator includes photoinitiator 2959.
Preferably, the temperature that heated sealed isothermal holding is protected from light described in step (2) is 90 DEG C, and the time is 20~30min.
Preferably, the time of polymerizing curable described in step (3) is 5~20s.
A kind of electrically conducting transparent flexibility bacteria cellulose composite material, is prepared by the above method.
The principle of the present invention are as follows:
Remove remaining protein in bacteria cellulose with NaOH solution, after solvent is replaced, by refractive index and sample at
Split-phase matching, and the optically transparent liquid eutectic solvent of itself penetrates into bacterial cellulose gel template, infiltration is thin
The more abortive haul networks of three-dimensional of fungin, initiated polymerization obtains cured flexible and transparent conductive material under light source.Due to thin
Fungin contains a large amount of hydroxyl, has a large amount of hydrogen bond to connect between liquid eutectic solvent, also, bacterial cellulose three-dimensional
Porous network structure is kept, and prepared electrically conducting transparent flexible material shows excellent mechanical performance, high optical clear
Property and electric conductivity.This multifunctional biomass sill light weight, at low cost, manufacturing process is simply green, is suitble to extensive
Production, has in flexible display device, Organic Light Emitting Diode, energy storage device, solar battery, wearable sensors etc. and answers extensively
Use prospect.
Preparation method of the invention and obtained product have the following advantages that and the utility model has the advantages that
(1) during the flexible bacteria cellulose composite material of the invention for preparing transparent and electrically conductive, conductive compositions selection
Relatively inexpensive choline chloride, instead of expensive silver nanowires ink；Bacteria cellulose is selected to do the base of transparent conductive material
Bottom reduces the dependence to metal, glass, plastics etc..Using the hydroxyl that can largely form hydrogen bond in bacteria cellulose molecule,
The high-strength mechanical performance of bacteria cellulose itself, greatlys improve the mechanical performance of material.
(2) the entire technique preparation process of the method for the present invention is simple, and reaction condition is mild, not high to equipment requirement, is conducive to
Industrialized production, raw material cost is low and renewable, reduces the dependence to synthetic polymer.
(3) composite flexibility of the method for the present invention preparation is good, mechanical performance is strong, transparency is high, conductive, is
The biomass-based composite material of high added value, flexible display device, Organic Light Emitting Diode, energy storage device, solar battery,
Wearable sensors etc. have wide application prospects.
Specific embodiment
Below with reference to embodiment, the present invention is described in further detail, and embodiments of the present invention are not limited thereto.
Embodiment 1
A kind of electrically conducting transparent flexibility bacteria cellulose composite material of the present embodiment, is prepared via a method which to obtain:
By bacteria cellulose aquagel, (production of Wang Quanwei, Liu Sixin, Gao Shilong, Li Congfa bacteria cellulose is ground with application
Study carefully progress biotechnology communications 2007；18:152-154.) it is cut into the regular film of 50 × 50 × 1mm, merging 200ml water
In the beaker of the mixed aqueous solution of the 0.8g NaOH of dissolution, NaOH 0.1mol/L seals up preservative film, delays under the conditions of 80 DEG C
Slow agitating and heating 6 hours, reaction solution is outwelled, is impregnated 2 days with a large amount of deionized waters, bacteria cellulose aquagel is taken out, pours into third
Olefin(e) acid submerges bacteria cellulose aquagel, seals up preservative film, places 12 hours, and replacement acrylic acid repeats to impregnate 12 hours.In addition,
13.96g choline chloride is dissolved in 21.62g acrylic acid (purity >=98%), 90 DEG C oil bath 4 hours, then be added the poly- second two of 1.2g
Alcohol dipropyl dilute acid ester (200) finally adds 0.368g photoinitiator 2959, stirs under room temperature to polyethylene glycol dipropyl dilute acid ester
It is dissolved with photoinitiator 2959, the eutectic solvent for obtaining photopolymerization (joined the eutectic of the photopolymerization of photoinitiator
Solvent should not be placed on the place of intense light irradiation, and solvent is preferably ready-to-use, should not place for a long time).By propylene acid soak
Bacterial cellulose gel afterwards, which takes out, places beaker bottom, and eutectic solvent is added into beaker and submerges bacterial cellulose gel,
Heated sealed is protected from light to being slowly stirred 20 minutes under the conditions of 90 DEG C, solvent penetration is made to enter bacteria cellulose network.It will then seep
Good bacterial cellulose gel is attached on transparent polytetrafluoroethylene film thoroughly, 6 seconds irradiate under Uv lamp to solvent polymeric solidification, from
Removing obtains electrically conducting transparent flexibility bacteria cellulose composite material on polytetrafluoroethylene film.
The bacteria cellulose aquagel selected in the present embodiment is with a thickness of 1mm, in molar ratio, choline chloride: acrylic acid=
1:3.In molar ratio, acrylic acid: polyethylene glycol dipropyl dilute acid ester (200)=100:2.Photoinitiator 2959 accounts for mixed system quality
1%, the Uv light irradiation time be 6s.Obtained electrically conducting transparent flexibility bacteria cellulose composite material conductivity 0.16S m-1, thoroughly
Light rate 90%, tensile stress maximum load 0.45Mpa, elasticity modulus 0.416MPa stretch maximum strain 180%.Choline chloride
Make material that there is conductive characteristic as conducting element, is crosslinked with flexible molecule chain acrylic acid, with three-dimensional porous bacteria cellulose
As substrate, so that material has good mechanical performance, eutectic solvent refractive index matches with bacteria cellulose ingredient, makes
It obtains composite material and shows excellent optical transparence.
Embodiment 2
A kind of electrically conducting transparent flexibility bacteria cellulose composite material of the present embodiment, is prepared via a method which to obtain:
Bacteria cellulose aquagel is cut to the regular film of 50 × 50 × 4mm, the 2g that merging is dissolved with 200ml water
In the beaker of the mixed aqueous solution of NaOH, NaOH 0.25mol/L seals up preservative film, is slowly stirred heating 6 under the conditions of 80 DEG C
Hour, reaction solution is outwelled, is impregnated 2 days with a large amount of deionized waters, bacteria cellulose aquagel is taken out, pours into acrylic acid submergence bacterium
Cellulose aquagel seals up preservative film, places 12 hours, and replacement acrylic acid repeats to impregnate 12 hours.In addition, by 13.96g chlorination
Choline is dissolved in 21.62g acrylic acid, 90 DEG C oil bath 4 hours, 1.2g polyethylene glycol dipropyl dilute acid ester (200) then are added, finally again
0.368g photoinitiator 2959 is added, stirring to polyethylene glycol dipropyl dilute acid ester and photoinitiator 2959 dissolves under room temperature, obtains
The eutectic solvent of photopolymerization.Bacterial cellulose gel after propylene acid soak is taken out and places beaker bottom, into beaker
Eutectic solvent is added and submerges bacterial cellulose gel, is protected from light heated sealed to being slowly stirred 20 minutes under the conditions of 90 DEG C, makes molten
Agent penetrates into bacteria cellulose network.The bacterial cellulose gel permeated is then attached to transparent polytetrafluoroethylene film
On, it irradiates under Uv lamp 6 seconds and solidifies to solvent polymeric, removing obtains electrically conducting transparent flexibility bacterial fibers from polytetrafluoroethylene film
Plain composite material.
The bacteria cellulose aquagel that the present embodiment is selected is with a thickness of 4mm, in molar ratio, choline chloride: acrylic acid=1:
3.In molar ratio, acrylic acid: polyethylene glycol dipropyl dilute acid ester (200)=100:2.Photoinitiator 2959 accounts for mixed system quality
1%, Uv the light irradiation time are 6s.Obtained electrically conducting transparent flexibility bacteria cellulose composite material conductivity 0.16S m-1, light transmission
Rate 80%, tensile stress maximum load 0.6Mpa, elasticity modulus 0.458MPa stretch maximum strain 150%.Choline chloride conduct
Conducting element make material have conductive characteristic, with flexible molecule chain acrylic acid be crosslinked, using three-dimensional porous bacteria cellulose as
Substrate, so that material has good mechanical performance, eutectic solvent refractive index matches with bacteria cellulose ingredient, so that multiple
Condensation material shows excellent optical transparence.
Embodiment 3
A kind of electrically conducting transparent flexibility bacteria cellulose composite material of the present embodiment, is prepared via a method which to obtain:
Bacteria cellulose aquagel is cut to the regular film of 50 × 50 × 10mm, the 4g that merging is dissolved with 200ml water
In the beaker of the mixed aqueous solution of NaOH, NaOH 0.5mol/L seals up preservative film, is slowly stirred heating 8 under the conditions of 90 DEG C
Hour, reaction solution is outwelled, is impregnated 2 days with a large amount of deionized waters, bacteria cellulose aquagel is taken out, pours into acrylic acid submergence bacterium
Cellulose aquagel seals up preservative film, places 12 hours, and replacement acrylic acid repeats to impregnate 12 hours.In addition, by 13.96g chlorination
Choline is dissolved in 21.62g acrylic acid, 90 DEG C oil bath 4 hours, 1.2g polyethylene glycol dipropyl dilute acid ester (200) then are added, finally again
0.368g photoinitiator 2959 is added, stirring to polyethylene glycol dipropyl dilute acid ester and photoinitiator 2959 dissolves under room temperature, obtains
The eutectic solvent of photopolymerization.Bacterial cellulose gel after propylene acid soak is taken out and places beaker bottom, into beaker
Eutectic solvent is added and submerges bacterial cellulose gel, is protected from light heated sealed to being slowly stirred 20 minutes under the conditions of 90 DEG C, makes molten
Agent penetrates into bacteria cellulose network.The bacterial cellulose gel permeated is then attached to transparent polytetrafluoroethylene film
On, it irradiates under Uv lamp 6 seconds and solidifies to solvent polymeric, removing obtains electrically conducting transparent flexibility bacterial fibers from polytetrafluoroethylene film
Plain composite material.
The bacteria cellulose aquagel that the present embodiment is selected is with a thickness of 1mm, in molar ratio, choline chloride: acrylic acid=1:
3.In molar ratio, acrylic acid: polyethylene glycol dipropyl dilute acid ester (200)=100:2.Photoinitiator 2959 accounts for mixed system quality
1%.Obtained electrically conducting transparent flexibility bacteria cellulose composite material conductivity 0.16S m-1, light transmittance 60%, tensile stress is most
Big load 0.8Mpa, elasticity modulus 0.522MPa stretch maximum strain 80%.Choline chloride has material as conducting element
There is conductive characteristic, be crosslinked with flexible molecule chain acrylic acid, using three-dimensional porous bacteria cellulose as substrate, so that material is with good
Good mechanical performance, eutectic solvent refractive index matches with bacteria cellulose ingredient, so that composite material shows excellent light
Learn the transparency.
Embodiment 4
A kind of electrically conducting transparent flexibility bacteria cellulose composite material of the present embodiment, is prepared via a method which to obtain:
Bacteria cellulose aquagel is cut to the regular film of 50 × 50 × 1mm, the 0.8g that merging is dissolved with 200ml water
In the beaker of the mixed aqueous solution of NaOH, NaOH 0.1mol/L seals up preservative film, is slowly stirred heating 6 under the conditions of 80 DEG C
Hour, reaction solution is outwelled, is impregnated 2 days with a large amount of deionized waters, bacteria cellulose aquagel is taken out, pours into acrylic acid submergence bacterium
Cellulose aquagel seals up preservative film, places 12 hours, and replacement acrylic acid repeats to impregnate 12 hours.In addition, by 20.94g chlorination
Choline is dissolved in 21.62g acrylic acid, 90 DEG C oil bath 4 hours, 1.2g polyethylene glycol dipropyl dilute acid ester (200) then are added, finally again
0.4256g photoinitiator 2959 is added, stirring to polyethylene glycol dipropyl dilute acid ester and photoinitiator 2959 dissolves under room temperature, obtains
The eutectic solvent of photopolymerization.Bacterial cellulose gel after propylene acid soak is taken out and places beaker bottom, into beaker
Eutectic solvent is added and submerges bacterial cellulose gel, is protected from light heated sealed to being slowly stirred 30 minutes under the conditions of 90 DEG C, makes molten
Agent penetrates into bacteria cellulose network.The bacterial cellulose gel permeated is then attached to transparent polytetrafluoroethylene film
On, it irradiates under Uv lamp 6 seconds and solidifies to solvent polymeric, removing obtains electrically conducting transparent flexibility bacterial fibers from polytetrafluoroethylene film
Plain composite material.
The bacteria cellulose aquagel that the present embodiment is selected is with a thickness of 1mm, in molar ratio, choline chloride: acrylic acid=1:
2.In molar ratio, acrylic acid: polyethylene glycol dipropyl dilute acid ester (200)=100:2.Photoinitiator 2959 accounts for mixed system quality
1%, Uv the light irradiation time are 6s.Obtained electrically conducting transparent flexibility bacteria cellulose composite material conductivity 0.2S m-1, light transmittance
90%, tensile stress maximum load 0.5Mpa, elasticity modulus 0.426MPa stretch maximum strain 180%.Choline chloride is used as and leads
Electric device makes material have conductive characteristic, is crosslinked with flexible molecule chain acrylic acid, using three-dimensional porous bacteria cellulose as base
Bottom, so that material has good mechanical performance, eutectic solvent refractive index matches with bacteria cellulose ingredient, so that compound
Material shows excellent optical transparence.
Embodiment 5
A kind of electrically conducting transparent flexibility bacteria cellulose composite material of the present embodiment, is prepared via a method which to obtain:
Bacteria cellulose aquagel is cut to the regular film of 50 × 50 × 1mm, the 0.8g that merging is dissolved with 200ml water
In the beaker of the mixed aqueous solution of NaOH, NaOH 0.1mol/L seals up preservative film, is slowly stirred heating 6 under the conditions of 80 DEG C
Hour, reaction solution is outwelled, is impregnated 2 days with a large amount of deionized waters, bacteria cellulose aquagel is taken out, pours into acrylic acid submergence bacterium
Cellulose aquagel seals up preservative film, places 12 hours, and replacement acrylic acid repeats to impregnate 12 hours.In addition, by 20.94g chlorination
Choline is dissolved in 21.62g acrylic acid, 90 DEG C oil bath 4 hours, 1.2g polyethylene glycol dipropyl dilute acid ester (200) then are added, finally again
0.4256g photoinitiator 2959 is added, stirring to polyethylene glycol dipropyl dilute acid ester and photoinitiator 2959 dissolves under room temperature, obtains
The eutectic solvent of photopolymerization.Bacterial cellulose gel after propylene acid soak is taken out and places beaker bottom, into beaker
Eutectic solvent is added and submerges bacterial cellulose gel, is protected from light heated sealed to being slowly stirred 30 minutes under the conditions of 90 DEG C, makes molten
Agent penetrates into bacteria cellulose network.The bacterial cellulose gel permeated is then attached to transparent polytetrafluoroethylene film
On, it irradiates under Uv lamp 12 seconds and solidifies to solvent polymeric, it is fine to obtain electrically conducting transparent flexibility bacterium for removing from polytetrafluoroethylene film
Tie up plain composite material.
The bacteria cellulose aquagel that the present embodiment is selected is with a thickness of 1mm, in molar ratio, choline chloride: acrylic acid=1:
2.In molar ratio, acrylic acid: polyethylene glycol dipropyl dilute acid ester (200)=100:2.Photoinitiator 2959 accounts for mixed system quality
1%, Uv the light irradiation time are 12s.Obtained electrically conducting transparent flexibility bacteria cellulose composite material conductivity 0.2S m-1, light transmission
Rate 90%, tensile stress maximum load 0.6Mpa, elasticity modulus 0.463MPa stretch maximum strain 150%.Choline chloride conduct
Conducting element make material have conductive characteristic, with flexible molecule chain acrylic acid be crosslinked, using three-dimensional porous bacteria cellulose as
Substrate, so that material has good mechanical performance, eutectic solvent refractive index matches with bacteria cellulose ingredient, so that multiple
Condensation material shows excellent optical transparence.
Embodiment 6
A kind of electrically conducting transparent flexibility bacteria cellulose composite material of the present embodiment, is prepared via a method which to obtain:
Bacteria cellulose aquagel is cut to the regular film of 50 × 50 × 1mm, the 0.8g that merging is dissolved with 200ml water
In the beaker of the mixed aqueous solution of NaOH, NaOH 0.1mol/L seals up preservative film, is slowly stirred heating 6 under the conditions of 80 DEG C
Hour, reaction solution is outwelled, is impregnated 2 days with a large amount of deionized waters, bacteria cellulose aquagel is taken out, pours into acrylic acid submergence bacterium
Cellulose aquagel seals up preservative film, places 12 hours, and replacement acrylic acid repeats to impregnate 12 hours.In addition, by 20.94g chlorination
Choline is dissolved in 21.62g acrylic acid, 90 DEG C oil bath 4 hours, 0.6g polyethylene glycol dipropyl dilute acid ester (200) then are added, finally again
0.2128g photoinitiator 2959 is added, stirring to polyethylene glycol dipropyl dilute acid ester and photoinitiator 2959 dissolves under room temperature, obtains
The eutectic solvent of photopolymerization.Bacterial cellulose gel after propylene acid soak is taken out and places beaker bottom, into beaker
Eutectic solvent is added and submerges bacterial cellulose gel, is protected from light heated sealed to being slowly stirred 30 minutes under the conditions of 90 DEG C, makes molten
Agent penetrates into bacteria cellulose network.The bacterial cellulose gel permeated is then attached to transparent polytetrafluoroethylene film
On, it irradiates under Uv lamp 12 seconds and solidifies to solvent polymeric, it is fine to obtain electrically conducting transparent flexibility bacterium for removing from polytetrafluoroethylene film
Tie up plain composite material.
The bacteria cellulose aquagel that the present embodiment is selected is with a thickness of 1mm, in molar ratio, choline chloride: acrylic acid=1:
2.In molar ratio, acrylic acid: polyethylene glycol dipropyl dilute acid ester (200)=100:2.Photoinitiator 2959 accounts for mixed system quality
1%, Uv the light irradiation time are 12s.Obtained electrically conducting transparent flexibility bacteria cellulose composite material conductivity 0.22S m-1, light transmission
Rate 90%, tensile stress maximum load 0.4Mpa, elasticity modulus 0.411MPa stretch maximum strain 180%.Choline chloride conduct
Conducting element make material have conductive characteristic, with flexible molecule chain acrylic acid be crosslinked, using three-dimensional porous bacteria cellulose as
Substrate, so that material has good mechanical performance, eutectic solvent refractive index matches with bacteria cellulose ingredient, so that multiple
Condensation material shows excellent optical transparence.
The above embodiment is a preferred embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment
Limitation, other any changes, modifications, substitutions, combinations, simplifications made without departing from the spirit and principles of the present invention,
It should be equivalent substitute mode, be included within the scope of the present invention.
Claims (10)
1. a kind of preparation method of electrically conducting transparent flexibility bacteria cellulose composite material, it is characterised in that including preparing step as follows
It is rapid:
(1) bacteria cellulose aquagel is placed in NaOH solution after cropped, heating stirring is reacted under air-proof condition, reaction knot
Reaction solution is removed after beam, washing, which is placed in acrylic acid, impregnates；
(2) by step (1), treated, and bacteria cellulose aquagel is immersed in the eutectic solvent of photopolymerization, is protected from light sealing
Heating and thermal insulation processing；
(3) by step (2) treated bacteria cellulose aquagel polymerizing curable under ultraviolet lighting, the electrically conducting transparent is obtained
Flexible bacteria cellulose composite material.
2. a kind of preparation method of electrically conducting transparent flexibility bacteria cellulose composite material according to claim 1, feature
Be: bacteria cellulose aquagel described in step (1) with a thickness of 0.01~10mm.
3. a kind of preparation method of electrically conducting transparent flexibility bacteria cellulose composite material according to claim 1, feature
Be: the concentration of NaOH solution described in step (1) is 0.1~0.5mol/L；The temperature of heating stirring reaction is 70~
90 DEG C, the time is 4~8h.
4. a kind of preparation method of electrically conducting transparent flexibility bacteria cellulose composite material according to claim 1, feature
It is: is placed in impregnate in acrylic acid described in step (1) and refers to propylene acid soak 1~2 time with purity >=98%, every time 12~
24h。
5. a kind of preparation method of electrically conducting transparent flexibility bacteria cellulose composite material according to claim 1, feature
It is that the eutectic solvent of photopolymerization described in step (2) configures by the following method:
After mixing by choline chloride and acrylic acid heating stirring, be cooled to room temperature, add polyethylene glycol dipropyl dilute acid ester with
And photoinitiator, stirring and dissolving is complete, obtains the eutectic solvent of the photopolymerization.
6. a kind of preparation method of electrically conducting transparent flexibility bacteria cellulose composite material according to claim 5, feature
Be: the molar ratio of the choline chloride and acrylic acid is 1:(2~6)；The acrylic acid and polyethylene glycol dipropyl dilute acid ester
Molar ratio is 100:(1~2).
7. a kind of preparation method of electrically conducting transparent flexibility bacteria cellulose composite material according to claim 5, feature
Be: the mass concentration that the photoinitiator is added is 0.2%~1%.
8. a kind of preparation method of electrically conducting transparent flexibility bacteria cellulose composite material according to claim 1, feature
Be: the temperature that heated sealed isothermal holding is protected from light described in step (2) is 90 DEG C, and the time is 20~30min.
9. a kind of preparation method of electrically conducting transparent flexibility bacteria cellulose composite material according to claim 1, feature
Be: the time of polymerizing curable described in step (3) is 5~20s.
10. a kind of electrically conducting transparent flexibility bacteria cellulose composite material, it is characterised in that: pass through any one of claim 1~9 institute
The method stated is prepared.
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| CN115010862A (en) * | 2022-07-04 | 2022-09-06 | 南京林业大学 | Preparation method of cellulose-based ionic conductive elastomer |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012145522A3 (en) * | 2011-04-19 | 2014-05-01 | Georgia Tech Research Corporation | Deep eutectic solvent systems and methods |
| CN105916807A (en) * | 2013-09-24 | 2016-08-31 | 康斯乔最高科学研究公司 | Exfoliation of graphite with deep eutectic solvents |
| CN106883607A (en) * | 2017-03-13 | 2017-06-23 | 北京科技大学 | Flexible double conducing composite materials of ionization BC/PANI and its production and use |
| CN107177024A (en) * | 2017-05-23 | 2017-09-19 | 广州纽楷美新材料科技有限公司 | Application of the polymerizable eutectic solvent in electrically conducting transparent elastomer is prepared |
| CN107760739A (en) * | 2017-09-30 | 2018-03-06 | 江南大学 | A kind of new dihydrogen bond eutectic solvent and the method for combining sodium carbonate pretreated water rice straw |
-
2018
- 2018-12-04 CN CN201811472009.7A patent/CN109734842B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012145522A3 (en) * | 2011-04-19 | 2014-05-01 | Georgia Tech Research Corporation | Deep eutectic solvent systems and methods |
| CN105916807A (en) * | 2013-09-24 | 2016-08-31 | 康斯乔最高科学研究公司 | Exfoliation of graphite with deep eutectic solvents |
| CN106883607A (en) * | 2017-03-13 | 2017-06-23 | 北京科技大学 | Flexible double conducing composite materials of ionization BC/PANI and its production and use |
| CN107177024A (en) * | 2017-05-23 | 2017-09-19 | 广州纽楷美新材料科技有限公司 | Application of the polymerizable eutectic solvent in electrically conducting transparent elastomer is prepared |
| CN107760739A (en) * | 2017-09-30 | 2018-03-06 | 江南大学 | A kind of new dihydrogen bond eutectic solvent and the method for combining sodium carbonate pretreated water rice straw |
Non-Patent Citations (1)
| Title |
|---|
| LI REN"AI等: "Green polymerizable deep eutectic solvent (PDES) type conductive paper for origami 3D circuits", 《CHEMICAL COMMUNICATIONS》 * |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112301803A (en) * | 2019-07-30 | 2021-02-02 | 华南理工大学 | High-transparency conductive nano paper and convenient preparation method and application thereof |
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| CN115181334A (en) * | 2022-08-22 | 2022-10-14 | 南京林业大学 | Bacterial cellulose-based salt difference energy composite hydrogel film material and preparation method and application thereof |
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